US20190322552A1 - Water treatment apparatus and water treatment method - Google Patents
Water treatment apparatus and water treatment method Download PDFInfo
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- US20190322552A1 US20190322552A1 US16/341,553 US201716341553A US2019322552A1 US 20190322552 A1 US20190322552 A1 US 20190322552A1 US 201716341553 A US201716341553 A US 201716341553A US 2019322552 A1 US2019322552 A1 US 2019322552A1
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F1/46114—Electrodes in particulate form or with conductive and/or non conductive particles between them
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D35/00—Filtering devices having features not specifically covered by groups B01D24/00 - B01D33/00, or for applications not specifically covered by groups B01D24/00 - B01D33/00; Auxiliary devices for filtration; Filter housing constructions
- B01D35/16—Cleaning-out devices, e.g. for removing the cake from the filter casing or for evacuating the last remnants of liquid
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/4604—Treatment of water, waste water, or sewage by electrochemical methods for desalination of seawater or brackish water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/4608—Treatment of water, waste water, or sewage by electrochemical methods using electrical discharges
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46119—Cleaning the electrodes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46152—Electrodes characterised by the shape or form
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46152—Electrodes characterised by the shape or form
- C02F2001/46157—Perforated or foraminous electrodes
- C02F2001/46161—Porous electrodes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/46115—Electrolytic cell with membranes or diaphragms
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/005—Processes using a programmable logic controller [PLC]
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/005—Processes using a programmable logic controller [PLC]
- C02F2209/006—Processes using a programmable logic controller [PLC] comprising a software program or a logic diagram
Definitions
- the present invention relates to a water treatment apparatus and a water treatment method for treating treatment target water using an electrical double layer capacitor.
- Electric desalination technology using an electrical double layer capacitor is technology of adsorbing and removing ions contained in treatment target water such as sea water or contaminated water using a Coulomb force, thereby desalinating the treatment target water.
- an electrical double layer capacitor having a flat-plate shape is configured such that activated carbon layers mainly formed from activated carbon having a high specific surface area are provided on both sides of a separator formed from an electrically-insulating porous liquid-permeable sheet, collector electrodes are provided on the outer sides of the activated carbon layers, and holder plates are provided on the outer sides of the collector electrodes. Then, while a liquid containing an ionic substance is passed through the electrical double layer capacitor, application of DC low voltage to the collector electrodes and short-circuit or reverse connection between both collector electrodes are repeated alternately (see, for example, Patent Document 1).
- ozone is generated from treatment water before desalination, and treatment target water is sterilized by the ozone, thereby preventing generation of biofilm on the surfaces of electrodes, and the polarities of the electrodes are changed alternately during operation, thereby decomposing and dissolving biofilm and/or scale that has been already generated on the surfaces of the electrodes and thus removing the biofilm and/or scale (see, for example, Patent Document 2).
- the present invention has been made to solve the above problems, and an object of the present invention is to obtain a water treatment apparatus and a water treatment method that are capable of more reliably removing biofilm and/or scale adhered to the surfaces of electrodes.
- a water treatment apparatus includes: a first electrode and a second electrode stored in a water treatment unit and provided so as to be separated from each other by a separator; a power supply unit which applies voltage between the first electrode and the second electrode so that ions contained in treatment target water supplied from one side of the water treatment unit are adsorbed to the first electrode and the second electrode, thereby performing desalination and generating desalinated water; and a washing water supply pump which causes washing water to flow from the other side of the water treatment unit to the one side of the water treatment unit, thereby washing the first electrode and the second electrode, wherein the first electrode and the second electrode each include a plurality of flowable granular electrode members.
- the first electrode and the second electrode for adsorbing and removing ions contained in treatment target water each include a plurality of flowable granular electrode members, and thus it is possible to further reliably remove biofilm and/or scale adhered to the surfaces of the electrodes.
- FIG. 1 is a configuration diagram of a water treatment apparatus according to embodiment 1 of the present invention.
- FIG. 2 is a flowchart showing a water treatment method according to embodiment 1 of the present invention.
- FIG. 3 shows other examples of a water treatment unit according to embodiment 1.
- FIG. 4 is a configuration diagram of a water treatment apparatus according to embodiment 2 of the present invention.
- FIG. 5 is a flowchart illustrating a reverse washing step in a water treatment method according to embodiment 2 of the present invention.
- FIG. 6 is a configuration diagram of a water treatment apparatus according to embodiment 3 of the present invention.
- FIG. 7 is a configuration diagram of a water treatment apparatus according to embodiment 4 of the present invention.
- FIG. 8 is a configuration diagram of a water treatment apparatus according to embodiment 5 of the present invention.
- FIG. 9 is a configuration diagram of a water treatment apparatus according to embodiment 6 of the present invention.
- FIG. 10 is a configuration diagram of a water treatment apparatus according to embodiment 7 of the present invention.
- FIG. 11 is a configuration diagram of a water treatment apparatus according to embodiment 8 of the present invention.
- FIG. 12 is a configuration diagram of a water treatment apparatus according to embodiment 9 of the present invention.
- FIG. 13 is a perspective view showing a water treatment unit according to embodiment 16 of the present invention.
- FIG. 14 is a top view showing the water treatment unit according to embodiment 16 of the present invention.
- FIG. 15 is a sectional view along P-P line in FIG. 14 .
- FIG. 16 is a sectional view along Q-Q line in FIG. 14 .
- FIG. 17 is a perspective view showing a water treatment unit according to embodiment 17 of the present invention.
- treatment target water refers to raw water that has not undergone desalination yet
- desalinated water refers to treatment target water that has been desalinated.
- FIG. 1 is a configuration diagram of a water treatment apparatus according to embodiment 1 of the present invention.
- a water treatment apparatus 100 includes: a water treatment unit 1 having an inlet port 1 a through which treatment target water flows in, an outlet port 1 b through which desalinated water flows out, and a washing water inlet port 1 c through which washing water or additive containing washing water flows in at the time of reverse washing, the water treatment unit 1 being configured to perform desalination for the treatment target water; a raw water tank 2 which is connected to the water treatment unit 1 via a treatment target water measurement unit 11 , a treatment target water supply valve 5 , and then a treatment target water supply pump 3 , and which stores treatment target water; a treated water tank 15 which is connected to the water treatment unit 1 via a desalinated water measurement unit 12 and then a desalinated water sending valve 7 and which stores treatment target water that has been desalinated by the water treatment unit 1 ; and a reverse washing water tank 17 which is connected to the water treatment unit 1 via the desal
- the reverse washing water tank 17 is connected to the water treatment unit 1 also through a route passing a washing water supply pump 4 for supplying washing water to the water treatment unit 1 at the time of reverse washing, a washing water supply valve 9 , and then a washing water measurement unit 13 .
- the reverse washing water tank 17 , the washing water supply pump 4 , and the washing water supply valve 9 are configured to be capable of supplying washing water to the water treatment unit 1 in a direction opposite to the flow direction of the treatment target water.
- a combination of the reverse washing water tank 17 , the washing water supply pump 4 , and the washing water supply valve 9 serves as a “supply unit”.
- Washing water supplied to the water treatment unit 1 can be drained from the water treatment unit 1 via the treatment target water measurement unit 11 and then a drain valve 6 .
- the reverse washing water tank 17 is connected to an additive storage tank 16 via an additive supply valve 10 and then an additive supply pump 37 .
- the reverse washing water tank 17 is provided with a stirrer 36 for stirring and mixing an additive and washing water when the additive is supplied. Washing water in the reverse washing water tank 17 can be drained via the drain valve 29 .
- a combination of the additive storage tank 16 , the additive supply pump 37 , and the additive supply valve 10 serves as an “additive supply unit”.
- the additive stored in the additive storage tank 16 contains a substance such as an oxidizing agent, an acid, or an alkali having a property of decomposing biofilm and/or scale.
- a pair of collectors 28 a , 28 b connected to a power supply unit 20 are provided at both ends, and between the collectors 28 a , 28 b , a first granular electrode member 18 , i.e., a first electrode, and a second granular electrode member 19 , i.e., a second electrode are provided so as to be opposed to each other and separated from each other by a separator 21 .
- the first granular electrode member 18 and the second granular electrode member 19 each include a plurality of granular electrode members.
- the first granular electrode members 18 or the second granular electrode members 19 are in contact with each other, but the first granular electrode member 18 and the second granular electrode member 19 are prevented from coming into contact with each other, by the separator 21 .
- the pair of collectors 28 a , 28 b are provided for passing electricity throughout the first granular electrode member 18 and the second granular electrode member 19 at the time of charging, and collecting electricity from the first granular electrode member 18 and the second granular electrode member 19 at the time of discharging, and the pair of collectors 28 a , 28 b are in contact with the first granular electrode member 18 and the second granular electrode member 19 , respectively.
- the pair of collectors 28 a , 28 b are made from a good electric conductor such as a graphite sheet, a graphite plate, GRAFOIL (registered trademark), a titanium plate, a stainless plate, or a copper plate.
- the first granular electrode member 18 and the second granular electrode member 19 serve to adsorb ions in the treatment target water when voltage is applied. Therefore, the first granular electrode member 18 and the second granular electrode member 19 are made from activated carbon, porous carbon, porous conductive beads, porous metal, or the like having a great conductivity and a great specific surface area and having a great capacitance as a capacitor.
- the granular electrode members included in the first granular electrode member 18 and the second granular electrode member 19 in the present embodiment are not made into a sheet form or the like, and are provided in the water treatment unit 1 in a state in which the granules are not fixed to each other. That is, the first granular electrode member 18 and the second granular electrode member 19 are each configured to include a plurality of flowable granular electrode members.
- the separator 21 is provided for preventing short-circuit between the first granular electrode member 18 and the second granular electrode member 19 , and is made from filter paper, a porous film, nonwoven fabric, a foamed material, or the like through which a liquid easily passes and which has an electric insulation property.
- an electric conductivity meter or the like that is capable of measuring the electric conductivity or electric resistance of a liquid and capable of outputting a result of the measurement as a signal, is used.
- the treatment target water supply pump 3 , the washing water supply pump 4 , the additive supply pump 37 , the treatment target water measurement unit 11 , the desalinated water measurement unit 12 , the washing water measurement unit 13 , the treatment target water supply valve 5 , the drain valves 6 , 29 , the desalinated water sending valves 7 , 8 , the washing water supply valve 9 , the additive supply valve 10 , and the power supply unit 20 are connected to a control unit 14 , and are controlled by the control unit 14 during execution of each processing step.
- a programmable logic controller (PLC) a sequencer, a numerical control device, or the like for operating a device in accordance with a specified condition, is used.
- washing of the water treatment unit 1 includes two washing methods, i.e., reverse washing and addition reverse washing.
- FIG. 2 is a flowchart showing the water treatment method according to embodiment 1.
- a “desalination step” is executed in which treatment target water is desalinated using the water treatment unit 1 , and the desalinated water is stored into the reverse washing water tank 17 and the treated water tank 15 (step ST 1 ).
- washing method execution control is performed for determining whether to execute a “reverse washing step” of performing reverse washing in which the water treatment unit 1 is washed by injecting washing water into the water treatment unit 1 in the direction opposite to the treatment target water flow-in direction, or an “addition reverse washing step” of washing the water treatment unit 1 by injecting additive containing washing water or an additive into the water treatment unit 1 in the direction opposite to the treatment target water flow-in direction (step ST 2 ).
- the washing method execution control in step ST 2 if the reverse washing step is determined to be executed, the process proceeds to step ST 3 , and if the addition reverse washing step is determined to be executed, the process proceeds to step ST 4 .
- step ST 3 After washing of the water treatment unit 1 in the reverse washing step (step ST 3 ) or washing of the water treatment unit 1 in the addition reverse washing step (step ST 4 ) is finished, the process returns to step ST 1 to execute the desalination step. Thereafter, the same cycle is repeated.
- step ST 4 After washing of the water treatment unit 1 in the reverse washing step (step ST 3 ) or washing of the water treatment unit 1 in the addition reverse washing step (step ST 4 ) is finished, the process returns to step ST 1 to execute the desalination step. Thereafter, the same cycle is repeated.
- the “desalination step”, the “reverse washing step”, the “addition reverse washing step”, and the “washing method execution control” will be described in detail.
- the treatment target water supply valve 5 is opened, and the drain valve 6 is closed.
- the treatment target water supply pump 3 is activated to send treatment target water in the raw water tank 2 so as to be supplied to the water treatment unit 1 .
- the treatment target water is supplied through the upper inlet port 1 a of the water treatment unit 1 into the water treatment unit 1 , and then flows downward.
- DC voltage is applied to the pair of collectors 28 a , 28 b by the power supply unit 20 .
- the pair of collectors 28 a , 28 b are in contact with the first granular electrode member 18 and the second granular electrode member 19 , and therefore DC voltage is applied also between the first granular electrode member 18 and the second granular electrode member 19 , and the first granular electrode member 18 and the second granular electrode member 19 are attracted by a Coulomb force so as to be in contact with the pair of collectors 28 a , 28 b , respectively, whereby the electrically connected state is maintained.
- the state in which DC voltage is applied to the first granular electrode member 18 and the second granular electrode member 19 is maintained, and ions contained in the treatment target water flowing in the water treatment unit 1 are adsorbed and removed by a Coulomb force to the first granular electrode member 18 and the second granular electrode member 19 , whereby the treatment target water is desalinated.
- the desalinated treatment target water is discharged as desalinated water through the lower outlet port 1 b of the water treatment unit 1 .
- the desalinated water sending valve 7 is closed and the desalinated water sending valve 8 is opened so that the treatment target water that has undergone the desalination is sent and stored into the reverse washing water tank 17 .
- the desalinated water stored in the reverse washing water tank 17 is used as washing water in the reverse washing step or the addition reverse washing step.
- the desalinated water sending valve 8 is closed and the desalinated water sending valve 7 is opened so that the treatment target water that has undergone the desalination is sent to the treated water tank 15 .
- the treatment target water supply pump 3 is stopped and the treatment target water supply valve 5 and the desalinated water sending valve 7 are closed.
- application of DC voltage by the power supply unit 20 is stopped, whereby the desalination step is finished.
- the inlet port 1 a and the outlet port 1 b are provided so that treatment target water flows downward in the water treatment unit 1 .
- the inlet port 1 a and the outlet port 1 b may be provided so that treatment target water flows upward or in the horizontal direction in the water treatment unit 1 .
- the time period during which the desalination step is executed is 3 to 200 minutes, or desirably, 5 to 50 minutes. If the time period is shorter than 3 minutes, the frequency of switching between desalination and washing increases and thus efficiency in the entire cycle is reduced. On the other hand, if the time period is longer than 200 minutes, ions are adsorbed into a deep part of each granular electrode member and the ions are less likely to be desorbed. As a result, a time period taken for washing is prolonged. Therefore, 5 to 50 minutes are desirable from the perspective of the frequency of switching between desalination and washing and ease of desorption of the adsorbed ions.
- the control unit 14 executes execution control to determine whether to execute the reverse washing step or the addition reverse washing step, using an ion removal rate in the water treatment unit 1 as a determination index.
- the “ion removal rate” is a value obtained by dividing the difference between the electric conductivity of treatment target water and the electric conductivity of desalinated water by the electric conductivity of the treatment target water and then converting the result into percentage, and thus indicates the height of desalination efficiency in the water treatment unit 1 .
- control unit 14 acquires the electric conductivity of the treatment target water and the electric conductivity of the desalinated water from the treatment target water measurement unit 11 and the desalinated water measurement unit 12 , to calculate the present ion removal rate in the water treatment unit 1 , and stores the ion removal rate into a storage unit (not shown).
- control unit 14 reads, from the storage unit (not shown), the greater one (hereinafter, referred to as “reference ion removal rate”) of the ion removal rate at the time when the first-time desalination step is finished after the water treatment apparatus 100 has been activated, and the ion removal rate at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed, and compares the reference ion removal rate with the present ion removal rate.
- reference ion removal rate the greater one of the ion removal rate at the time when the first-time desalination step is finished after the water treatment apparatus 100 has been activated
- the control unit 14 determines to execute the addition reverse washing step. If the present ion removal rate is equal to or greater than 1.0 times the reference ion removal rate, or desirably, equal to or greater than 0.9 times the reference ion removal rate, the ion removal rate in the water treatment unit 1 has not been reduced or has been slightly reduced and thus it is not necessary to execute the addition reverse washing. Therefore, the control unit 14 determines to execute the reverse washing step.
- the control unit 14 determines that it is difficult to restore the ion removal rate by the addition reverse washing step.
- the control unit 14 causes a display unit (not shown) to display an alarm indication for notification that it is necessary to replace the first granular electrode member 18 and the second granular electrode member 19 , thereby prompting a user to replace the first granular electrode member 18 and the second granular electrode member 19 .
- the washing water supply pump 4 is activated to inject the washing water in the reverse washing water tank 17 into the water treatment unit 1 in a direction from the lower washing water inlet port 1 c to the upper inlet port 1 a of the water treatment unit 1 , i.e., the direction opposite to the flow of the treatment target water.
- the washing water injected into the water treatment unit 1 flows upward and flows out through the inlet port 1 a to the upper side of the water treatment unit 1 , and thereafter, is drained through the drain valve 6 .
- Biofilm and/or scale that has been already adhered to the surfaces of the first granular electrode member 18 and the second granular electrode member are removed by a shear force acting on the surfaces of the granular electrode members owing to the flow of the washing water.
- biofilm and/or scale is strongly adhered or fixed to the surfaces of the granular electrode members, and it might be difficult to remove the biofilm and/or scale merely by the washing water flowing on the surfaces of the granular electrode members.
- the first granular electrode member 18 and the second granular electrode member 19 in the present embodiment are provided in the water treatment unit 1 such that the granules are not fixed to each other.
- the first granular electrode member 18 and the second granular electrode member 19 also flow.
- contact or collision occurs between the granular electrode members, whereby biofilm, scale, and the like that are strongly adhered or fixed to the surfaces of the granular electrode members can be removed by being torn off by a physical force.
- the electric conductivity of the washing water before injection into the water treatment unit 1 is measured by the washing water measurement unit 13 and the electric conductivity of the washing water after passing through the water treatment unit 1 is measured by the treatment target water measurement unit 11 , and then a result of the measurement by the treatment target water measurement unit 11 is compared with a result of the measurement by the washing water measurement unit 13 .
- the result of measurement by the treatment target water measurement unit 11 is 1 to 1.5 times, or desirably, 1 to 1.2 times the result of measurement by the washing water measurement unit 13 , it is considered that washing has been sufficiently performed, and therefore the washing water supply pump 4 is stopped and the washing water supply valve 9 is closed, to finish the reverse washing step.
- the washing water used in the reverse washing step is water obtained by storing the desalinated water generated in the desalination step, into the reverse washing water tank 17 . Therefore, in the case where the amount of necessary washing water is large, the prescribed amount of desalinated water to be stored into the reverse washing water tank 17 also increases, and the desalinated water stored into the treated water tank 15 decreases, leading to reduction in the recovery rate for the desalinated water.
- the contact area thereof with the washing water increases and contact and collision between the electrode members become more likely to occur. Therefore, from the perspective of effective physical washing, it is desirable that a certain degree of expansion occurs.
- the expansion rate of the first granular electrode member 18 and the second granular electrode member 19 in the reverse washing step are set to 0 to 200%, or desirably, 20 to 50%.
- the “expansion rate” indicates the percentage by which the volume of the first granular electrode member 18 and the second granular electrode member 19 in the washing step has increased as compared to the volume at the time of the desalination step.
- the expansion rate is 0%.
- the expansion rate is determined by the flow rate of the washing water, and therefore it is possible to set the expansion rate to a desired value by the control unit 14 controlling the flow rate of the washing water.
- the additive supply valve 10 is opened and the additive supply pump 37 is activated to add a predetermined amount of additive to the washing water in the reverse washing water tank 17 from the additive storage tank 16 .
- the stirrer 36 stirs and mixes the additive and the washing water to generate additive containing washing water.
- the additive is added to the reverse washing water tank 17 so that the hydrogen peroxide concentration in the reverse washing water tank 17 becomes 0.0001 to 5%, or desirably, 0.001 to 1%.
- the hydrogen peroxide concentration in the reverse washing water tank 17 is smaller than 0.0001%, the hydrogen peroxide concentration is too low so that, when the additive containing washing water is injected into the water treatment unit 1 , the hydrogen peroxide is consumed before being distributed over the entirety of the first granular electrode member 18 and the second granular electrode member 19 , and therefore the washing effect is small.
- the hydrogen peroxide concentration is greater than 5%, foaming by reaction with the first granular electrode member 18 and the second granular electrode member 19 occurs vigorously, so that bubbles remain in pores of the activated carbon. The bubbles remaining in pores of the activated carbon hampers ion adsorption in the desalination step, thus deteriorating efficiency of the desalination.
- the washing water supply pump 4 is activated to inject the additive containing washing water in the reverse washing water tank 17 into the water treatment unit 1 in a direction from the lower washing water inlet port 1 c to the upper inlet port 1 a of the water treatment unit 1 , i.e., the direction opposite to the flow of the treatment target water.
- the additive containing washing water injected into the water treatment unit 1 flows upward and flows out through the inlet port 1 a to the upper side of the water treatment unit 1 , and thereafter, is drained through the drain valve 6 .
- the addition reverse washing step as in the case of the reverse washing step, biofilm and/or scale that has been already adhered to the surfaces of the first granular electrode member 18 and the second granular electrode member 19 is removed by a shear force acting on the surfaces of the granular electrode members owing to the flow of the additive containing washing water.
- the first granular electrode member 18 and the second granular electrode member 19 in the present embodiment by the flow of the additive containing washing water, the first granular electrode member 18 and the second granular electrode member 19 also flow. Therefore, the additive containing washing water spreads over the entirety of the first granular electrode member 18 and the second granular electrode member 19 , and thus biofilm, scale, and the like adhered to the surfaces of the granular electrode members can be uniformly removed.
- the flow rate of the additive containing washing water is controlled by the control unit 14 so that the expansion rate of the first granular electrode member 18 and the second granular electrode member 19 is 10 to 200%, or desirably, 10 to 100%. If the expansion rate is greater than 200%, the amount of necessary washing water becomes too large, and the prescribed amount of desalinated water to be stored into the reverse washing water tank 17 in the desalination step increases. As a result, the desalinated water stored into the treated water tank 15 decreases, leading to reduction in the recovery rate for the desalinated water.
- the washing water supply pump 4 is stopped and the washing water supply valve 9 is closed. If the amount of the additive containing washing water injected into the water treatment unit 1 is smaller than 2 times the volume of the first granular electrode member 18 and the second granular electrode member 19 , the additive is not sufficiently distributed to the surfaces of the granular electrode members and therefore biofilm and/or scale adhered to the surfaces of the granular electrode members is not completely decomposed and removed.
- the amount of the additive containing washing water injected into the water treatment unit 1 is larger than 10 times the volume of the first granular electrode member 18 and the second granular electrode member 19 , the prescribed amount of desalinated water to be stored into the reverse washing water tank 17 in the desalination step increases. As a result, the desalinated water stored into the treated water tank 15 decreases, leading to reduction in the recovery rate for the desalinated water.
- the treatment target water supply valve 5 , the desalinated water sending valve 8 , and the drain valve 29 are opened, and the treatment target water supply pump 3 is activated to send the treatment target water from the raw water tank 2 to the water treatment unit 1 , so that the additive containing washing water remaining in the water treatment unit 1 is caused to flow out and is drained from the reverse washing water tank 17 through the drain valve 29 .
- the treatment target water supply pump 3 is stopped, and the treatment target water supply valve 5 and the drain valve 29 are closed, to finish the addition reverse washing step.
- the amount of treatment target water used for causing the additive containing washing water to flow out from the water treatment unit 1 is 1 to 10 times, or desirably, 2 to 5 times the volume of the first granular electrode member 18 and the second granular electrode member 19 . If the amount of treatment target water used for causing the additive containing washing water to flow out is smaller than 1 times the volume of the first granular electrode member 18 and the second granular electrode member 19 , it is impossible to cause the entire additive containing washing water to flow out from the water treatment unit 1 .
- the amount of treatment target water is larger than 10 times the volume of the first granular electrode member 18 and the second granular electrode member 19 , the amount of treatment target water used for causing the additive containing washing water to flow out increases, so that the recovery rate for the desalinated water is reduced.
- a time period required for causing the additive containing washing water to flow out is prolonged and thus a time period taken for the addition reverse washing step is also prolonged, whereby efficiency of the entire cycle is reduced.
- FIG. 1 an example in which the inlet port 1 a is provided on one side of the water treatment unit 1 , and the outlet port 1 b and the washing water inlet port 1 c are provided on the other side of the water treatment unit 1 , has been shown.
- the water treatment unit 1 may be configured as shown in other examples in FIG. 3 .
- the inlet port 1 a and the washing water inlet port 1 c are provided on one side of the water treatment unit 1
- the outlet port 1 b and a washing water outlet port 1 d are provided on the other side of the water treatment unit 1 .
- a second washing water measurement unit 131 for measuring the electric conductivity or the like of washing water having flowed through the water treatment unit 1 is provided to a pipe connected to the washing water outlet port 1 d . After the electric conductivity is measured by the second washing water measurement unit 131 , the washing water is discharged to outside of the system.
- the reverse washing step and the addition reverse washing step whether or not washing has been sufficiently performed is determined through comparison between a result of measurement by the washing water measurement unit 13 and a result of measurement by the second washing water measurement unit 131 .
- the flow direction of the washing water in the reverse washing step and the flow direction of the additive containing washing water in the addition reverse washing step are the same as the flow direction of the treatment target water in the desalination step.
- the expansion rate of the first granular electrode member 18 and the second granular electrode member 19 in the addition reverse washing step needs to be equal to or greater than 10%.
- the expansion rate of the first granular electrode member 18 and the second granular electrode member 19 in the addition reverse washing step may be 0%.
- the washing water outlet port 1 d may be connected to the treatment target water measurement unit 11 , whereby the second washing water measurement unit 131 may be omitted.
- the washing water outlet port 1 d may be connected to the desalinated water measurement unit 12 , and also in this case, the second washing water measurement unit 131 may be omitted.
- the washing water inlet port 1 c and the washing water outlet port 1 d may be provided to the collector 28 a and the collector 28 b .
- the second washing water measurement unit 131 may be provided to a pipe connected to the washing water outlet port 1 d , or as shown in the example in FIG. 3( d ) , the washing water outlet port 1 d may be connected to the treatment target water measurement unit 11 , whereby the second washing water measurement unit 131 may be omitted.
- the washing water outlet port 1 d may be connected to the desalinated water measurement unit 12 , and also in this case, the second washing water measurement unit 131 may be omitted. Also in the example in FIG. 3( d ) , the expansion rate of the first granular electrode member 18 and the second granular electrode member 19 in the addition reverse washing step may be 0%.
- water obtained by filtering urban sewage water having electric conductivity of 2 mS/cm and DOC of 10 mg/L was used as treatment target water.
- Granular activated carbon was used as the first granular electrode member 18 and the second granular electrode member 19 , and the amount of the activated carbon is 10 L.
- the flow speed of the treatment target water in the desalination step was 0.1 m/min, and the flow speeds of the washing water in the reverse washing step and the additive containing washing water in the addition reverse washing step were 0.5 m/min.
- a hydrogen peroxide solution was used as the additive, and the hydrogen peroxide concentration in the additive containing washing water was 1%.
- a condition for executing the addition reverse washing step was as follows. In the case where the ion removal rate at the time when the desalination step was finished had been reduced by 5% or more as compared to the ion removal rate at the time when the first-time desalination step was finished after the water treatment apparatus 100 was activated or the ion removal rate at the time when the first-time desalination step was finished after the previous addition reverse washing step was executed, the addition reverse washing step was executed after the desalination step. In the case where the above condition was not satisfied, the reverse washing step was executed. On the basis of the above condition for executing the addition reverse washing step, in example 2, the addition reverse washing step was executed after the desalination step was finished for the third time and the sixth time. As a result of inspection in example 2, the following table 2 was obtained.
- the ion removal rate is restored at regular intervals.
- control unit compares the present ion removal rate with a reference ion removal rate which is the greater one of the ion removal rate at the time when the first-time desalination step is finished and the ion removal rate at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed. Then, in the case where the present ion removal rate is smaller than 0.5 to 1.0 times the reference ion removal rate, the control unit performs control so as to execute reverse washing using washing water to which the additive is added. Thus, it becomes possible to efficiently and effectively execute washing and desalination, whereby the desalination can be performed stably and continuously.
- washing water since desalinated water is used as washing water, it is not necessary to introduce washing water from outside or provide equipment for washing water, so that the equipment can be simplified and the drain amount of washing water can be reduced, and also, the amount of contaminated water can be reduced.
- FIG. 4 is a configuration diagram of a water treatment apparatus according to embodiment 2 of the present invention.
- a water treatment apparatus 200 includes: the water treatment unit 1 which performs desalination for treatment target water; the raw water tank 2 which is connected to the water treatment unit 1 via the treatment target water measurement unit 11 , a three-way valve 22 , and then the treatment target water supply pump 3 , and which stores treatment target water; the treated water tank 15 which is connected to the water treatment unit 1 via the desalinated water measurement unit 12 and then the desalinated water sending valve 7 and which stores treatment target water that has been desalinated by the water treatment unit 1 ; and the reverse washing water tank 17 which is connected to the water treatment unit 1 via the desalinated water measurement unit 12 and then a three-way valve 24 and which stores washing water for reverse washing.
- Washing water supplied to the water treatment unit 1 can be drained from the water treatment unit 1 via the treatment target water measurement unit 11 and then a three-way valve 23 , and also, can circulate via the treatment target water measurement unit 11 , the three-way valve 22 , the three-way valve 23 , the three-way valve 24 , the washing water supply pump 4 , and then the washing water measurement unit 13 .
- the washing water supply pump 4 serves as a circulation pump.
- the three-way valve 22 , the three-way valve 23 , and the three-way valve 24 are connected to the control unit 14 , and are controlled by the control unit 14 during execution of each step.
- the three-way valve 22 is opened in a direction from the raw water tank 2 to the water treatment unit 1 , and the three-way valve 23 is closed.
- the treatment target water supply pump 3 is activated to send the treatment target water in the raw water tank 2 so as to be supplied to the water treatment unit 1 .
- the treatment target water is supplied through the upper inlet port 1 a of the water treatment unit 1 into the water treatment unit 1 , and then flows downward.
- DC voltage is applied to the first granular electrode member 18 and the second granular electrode member 19 via the pair of collectors 28 a , 28 b by the power supply unit 20 , and ions contained in the treatment target water are adsorbed and removed by a Coulomb force to the first granular electrode member 18 and the second granular electrode member 19 , whereby the treatment target water is desalinated.
- the washing water supply pump 4 is activated to inject washing water in the reverse washing water tank 17 into the water treatment unit 1 in a direction from the lower washing water inlet port 1 c to the upper inlet port 1 a of the water treatment unit 1 , i.e., the direction opposite to the flow of the treatment target water.
- the three-way valve 23 is opened in a direction from the three-way valve 22 to the drain side so that the washing water flowing out from the inlet port 1 a is drained.
- the three-way valve 23 is opened in a direction from the three-way valve 22 to the three-way valve 24 , and the three-way valve 24 is opened in a direction from the three-way valve 23 to the washing water measurement unit 13 and the water treatment unit 1 .
- a circulation path for the washing water is formed, and the washing water circulates by a driving force from the washing water supply pump 4 .
- FIG. 5 is a flowchart illustrating the reverse washing step in the water treatment method according to embodiment 2, and shows a processing flow after circulation of washing water is started.
- the electric conductivity of the washing water before injection into the water treatment unit 1 is measured by the washing water measurement unit 13 and the electric conductivity of the washing water after passing through the water treatment unit 1 is measured by the treatment target water measurement unit 11 , and then a result of the measurement by the treatment target water measurement unit 11 is compared with a result of the measurement by the washing water measurement unit 13 at the time of injection of the washing water.
- step ST 03 the process proceeds to step ST 02 to continue the circulation (step ST 01 ).
- step ST 01 If the condition is not satisfied in step ST 01 , that is, if the result of the measurement by the treatment target water measurement unit 11 does not exceed the predetermined multiple of the result of the measurement by the washing water measurement unit 13 , the washing water is circulated as it is, to continue the reverse washing (step ST 02 ).
- step ST 01 If the condition is satisfied in step ST 01 , that is, if the result of the measurement by the treatment target water measurement unit 11 is greater than the predetermined multiple of the result of the measurement by the washing water measurement unit 13 at the time of injection of the washing water, the three-way valve 23 is switched to be opened in a direction from the three-way valve 22 to the drain side, to drain the circulating washing water (step ST 03 ).
- step ST 01 the result of the measurement by the treatment target water measurement unit 11 does not become smaller than 1 times the result of the measurement by the washing water measurement unit 13 .
- the result of the measurement by the treatment target water measurement unit 11 is greater than 5 times the result of the measurement by the washing water measurement unit 13 , the ion concentration in the washing water is close to saturation, so that the ions adsorbed to the first granular electrode member 18 and the second granular electrode member 19 are less likely to be desorbed into the washing water and thus it is considered that washing efficiency has been reduced. If such washing water is circulated, the first granular electrode member 18 , the second granular electrode member 19 , and the separator 21 might be contaminated again by pollution in the washing water.
- step ST 04 If the reverse washing in which the washing water is circulated has been executed a predetermined number of times in a range of 1 to 10 times, or desirably, 1 to 5 times, washing of the water treatment unit 1 by circulation of the washing water is finished and the process proceeds to step ST 05 , and on the other hand, if this condition is not satisfied, the process returns to step ST 02 to continue the reverse washing by circulation (step ST 04 ). It is noted that, regarding the number of times of the reverse washing in which washing water is circulated, operation from the start of circulation of the washing water to draining in step ST 03 is counted as one time. In addition, the predetermined multiple in step ST 01 may be set per number of times in step ST 04 .
- step ST 04 If the condition is satisfied in step ST 04 , the three-way valve 23 is kept being opened in a direction from the three-way valve 22 to the drain side and the three-way valve 24 is switched to be opened in a direction from the reverse washing water tank 17 to the washing water measurement unit 13 and the water treatment unit 1 , to newly inject the washing water in the reverse washing water tank 17 into the water treatment unit 1 (step ST 05 ). It is noted that, if the number of times of the washing by circulation in step ST 04 is larger than 10, the amount of necessary washing water becomes too large, leading to reduction in the recovery rate for the desalinated water.
- the electric conductivity of the washing water before injection into the water treatment unit 1 is measured by the washing water measurement unit 13 and the electric conductivity of the washing water after passing through the water treatment unit 1 is measured by the treatment target water measurement unit 11 , and then a result of the measurement by the treatment target water measurement unit 11 is compared with the result of the measurement by the washing water measurement unit 13 .
- step ST 07 step ST 06
- step ST 06 If the condition in step ST 06 is not satisfied, that is, if the result of the measurement by the treatment target water measurement unit 11 is greater than 1.5 times the result of the measurement by the washing water measurement unit 13 , biofilm and/or scale still remains in the water treatment unit 1 and thus the washing is insufficient. Therefore, the washing water is injected into the water treatment unit 1 to continue the reverse washing step (step ST 07 ), and then the process returns to step ST 06 , whereby the injection of the washing water is continued until the condition is satisfied.
- the flow rate of the washing water is controlled by the control unit 14 so that the expansion rate of the first granular electrode member 18 and the second granular electrode member 19 is 0 to 200%, or desirably, 0 to 100%.
- the expansion rate of the first granular electrode member 18 and the second granular electrode member 19 is greater than 200%, the amount of necessary washing water becomes too large, leading to reduction in the recovery rate for the desalinated water.
- a certain degree of expansion is desirable from the perspective of effective physical washing, but in embodiment 2, efficiency of physical washing is ensured by circulation of washing water, and therefore the first granular electrode member 18 and the second granular electrode member 19 may not be expanded.
- the additive supply valve 10 is opened and the additive supply pump 37 is activated to add a predetermined amount of additive to the washing water in the reverse washing water tank 17 from the additive storage tank 16 .
- the stirrer 36 stirs and mixes the additive and the washing water to generate additive containing washing water.
- the additive is added to the reverse washing water tank 17 so that the hydrogen peroxide concentration in the reverse washing water tank 17 becomes 0.0001 to 5%, or desirably, 0.001 to 1%.
- the washing water supply pump 4 is activated to inject the additive containing washing water in the reverse washing water tank 17 into the water treatment unit 1 in a direction from the lower washing water inlet port 1 c to the upper inlet port 1 a of the water treatment unit 1 , i.e., the direction opposite to the flow of the treatment target water.
- the three-way valve 23 is opened in a direction from the three-way valve 22 to the drain side so that the additive containing washing water flowing out from the inlet port 1 a is drained.
- the three-way valve 23 is opened in a direction from the three-way valve 22 to the three-way valve 24 , and the three-way valve 24 is opened in a direction from the three-way valve 23 to the washing water measurement unit 13 and the water treatment unit 1 .
- a circulation path for the additive containing washing water is formed, and the additive containing washing water circulates by a driving force from the washing water supply pump 4 .
- the three-way valve 23 is switched to be opened in a direction from the three-way valve 22 to the drain side, to drain the circulating additive containing washing water. If the result of the measurement by the treatment target water measurement unit 11 does not exceed the predetermined multiple of the result of the measurement by the washing water measurement unit 13 , the additive containing washing water is circulated as it is, to continue the washing.
- the washing water supply pump 4 is stopped and the three-way valve 24 is closed. Thereafter, as in embodiment 1, the operation of causing the additive containing washing water to flow out from the water treatment unit 1 is executed, and thus the addition reverse washing step is finished.
- washing water in the reverse washing step and the additive containing washing water in the addition reverse washing step can be used to be circulated, the washing water can be efficiently used and the amount of water needed for washing is decreased, whereby the recovery rate for the desalinated water can be increased.
- FIG. 6 is a configuration diagram of a water treatment apparatus according to embodiment 3 of the present invention.
- the water treatment unit 1 is connected to the treated water tank 15 via the desalinated water measurement unit 12 and then the desalinated water sending valve 7 .
- the water treatment unit 1 is not connected to the reverse washing water tank 17 via the desalinated water measurement unit 12 and then the desalinated water sending valve 8 .
- the water treatment unit 1 is connected to the reverse washing water tank 17 via the treated water tank 15 which is connected to the reverse washing water tank 17 via a desalinated water sending pump 26 and then the desalinated water sending valve 8 .
- the water treatment unit 1 is capable of drainage via a drain valve 30 .
- the reverse washing water tank 17 is connected to three additive storage tanks 16 a , 16 b , 16 c via the additive supply pump 37 and a four-way valve 25 .
- the additive storage tanks 16 a , 16 b , 16 c store different types of additives (hereinafter, referred to as additive A, additive B, additive C).
- the four-way valve 25 allows the reverse washing water tank 17 to be connected to one of the three additive storage tanks 16 a , 16 b , 16 c in accordance with an additive to be used.
- the additive supply pump 37 and the four-way valve 25 are connected to the control unit 14 , and are controlled by the control unit 14 during execution of each processing step.
- reverse washing by washing water in which the additive A, B, C stored in each additive storage tank 16 a , 16 b , 16 c is added is defined as first reverse washing, second reverse washing, and third reverse washing, respectively, and the case of performing the addition reverse washing step in order of the first reverse washing, the second reverse washing, and then the third reverse washing will be described.
- the three-way valve 22 is opened in a direction from the raw water tank 2 to the water treatment unit 1 , and the three-way valve 23 is closed. Also, the desalinated water sending valve 7 is opened. Next, the treatment target water supply pump 3 is activated to send the treatment target water in the raw water tank 2 so as to be supplied to the water treatment unit 1 . The treatment target water is supplied through the upper inlet port 1 a of the water treatment unit 1 into the water treatment unit 1 , and then flows downward.
- DC voltage is applied to the first granular electrode member 18 and the second granular electrode member 19 via the pair of collectors 28 a , 28 b by the power supply unit 20 , whereby ions contained in the treatment target water are adsorbed and removed by a Coulomb force to the first granular electrode member 18 and the second granular electrode member 19 , and thus the treatment target water is desalinated.
- the desalinated treatment target water is discharged as desalinated water through the lower outlet port 1 b of the water treatment unit 1 and flows through the desalinated water measurement unit 12 and the desalinated water sending valve 7 to the treated water tank 15 .
- the desalinated water sending valve 8 When a predetermined amount of the desalinated water has been supplied to the treated water tank 15 , the desalinated water sending valve 8 is opened and the desalinated water sending pump 26 is activated to send the desalinated water from the treated water tank 15 to the reverse washing water tank 17 until the amount thereof reaches a prescribed amount.
- the four-way valve 25 is opened in a direction from the additive storage tank 16 a to the reverse washing water tank 17 and the additive supply pump 37 is activated to add a predetermined amount of additive A to the washing water in the reverse washing water tank 17 from the additive storage tank 16 a .
- the stirrer 36 stirs and mixes the additive A and the washing water to generate additive-A containing washing water.
- the washing water supply pump 4 is activated to inject the additive-A containing washing water in the reverse washing water tank 17 into the water treatment unit 1 in a direction from the lower washing water inlet port 1 c to the upper inlet port 1 a of the water treatment unit 1 , i.e., the direction opposite to the flow of the treatment target water.
- the three-way valve 23 is opened in a direction from the three-way valve 22 to the drain side so that the washing water flowing out from the inlet port 1 a is drained.
- the three-way valve 23 is opened in a direction from the three-way valve 22 to the three-way valve 24 , and the three-way valve 24 is opened in a direction from the three-way valve 23 to the washing water measurement unit 13 and the water treatment unit 1 .
- a circulation path for the additive-A containing washing water is formed, and the additive containing washing water is circulated by a driving force from the washing water supply pump 4 . Washing of the water treatment unit 1 by the additive-A containing washing water is the same as the reverse washing in the addition reverse washing step in embodiment 2.
- the drain valve 29 is opened so that the additive-A containing washing water is drained from the reverse washing water tank 17 .
- the desalinated water sending valve 8 is opened and the desalinated water sending pump 26 is activated to send the desalinated water from the treated water tank 15 to the reverse washing water tank 17 .
- the desalinated water sending pump 26 is stopped and the desalinated water sending valve 8 is closed.
- the four-way valve 25 is opened in a direction from the additive storage tank 16 b to the reverse washing water tank 17 , and the additive supply pump 37 is activated to add a predetermined amount of additive B to the washing water in the reverse washing water tank 17 from the additive storage tank 16 b .
- the stirrer 36 stirs and mixes the additive B and the washing water to generate additive-B containing washing water.
- the second reverse washing by the additive-B containing washing water is executed in the same manner as in case of the first reverse washing.
- the additive is switched from the additive B to the additive C and the third reverse washing is executed.
- the washing water supply pump 4 is stopped, the desalinated water sending valve 7 is closed, and the drain valve 30 is opened.
- the three-way valve 22 is opened in a direction from the raw water tank 2 to the water treatment unit 1 , and the treatment target water supply pump 3 is activated to send the treatment target water to the water treatment unit 1 , so that the additive-C containing washing water remaining in the water treatment unit 1 is caused to flow out and is drained through the drain valve 30 .
- the treatment target water supply pump 3 is stopped, and the treatment target water supply valve 5 and the drain valve 30 are closed, to finish the addition reverse washing step.
- the amount of treatment target water to be used for causing the additive containing washing water to flow out from the water treatment unit 1 is the same as that in embodiment 1.
- the additive A used for the first reverse washing is an oxidizing agent having a property of removing biofilm
- the additive B used for the second reverse washing is an acid for removing scale such as calcium carbonate which ionizes under acidic condition
- the additive C used for the third reverse washing is an alkali for removing scale such as silica which ionizes under basic condition.
- a plurality of additive storage tanks storing different types of additives are provided, biofilm is removed by the first reverse washing using the oxidizing agent, scale such as calcium carbonate which ionizes under acidic condition is removed by the second reverse washing using the acid, and scale such as silica which ionizes under basic condition is removed by the third reverse washing using the alkali.
- the reverse washing is executed using the washing waters to which different additives are added, whereby biofilm and/or scale accumulated in the water treatment unit 1 can be removed efficiently and effectively.
- FIG. 7 is a configuration diagram of a water treatment apparatus according to embodiment 4 of the present invention.
- the water treatment unit 1 is connected to the treated water tank 15 via the washing water supply pump 4 , the washing water measurement unit 13 , and the four-way valve 25 .
- the water treatment unit 1 is capable of drainage via the drain valve 30 .
- the water treatment apparatus 400 does not include the reverse washing water tank 17 , and also, does not include the stirrer 36 and the drain valve 29 .
- the treated water tank 15 is connected to an additive generation unit 27 via the desalinated water sending valve 8 and the desalinated water sending pump 26 .
- the additive generation unit 27 is for generating an additive and injecting the additive into the water treatment unit 1 , and corresponds to the additive supply unit in embodiment 1.
- the additive generation unit 27 is connected to an additive injection port 1 e of the water treatment unit 1 via an additive measurement unit 31 for measuring the additive concentration and the additive supply valve 10 .
- the additive generation unit 27 and the additive measurement unit 31 are connected to the control unit 14 , and are controlled by the control unit 14 during execution of each processing step.
- an electrolyzer or the like that generates hypochlorous acid, hypochlorite, ozone, or hydrogen peroxide through electrolysis of desalinated water e.g., an ozonizer for generating ozone from the air or oxygen gas supplied from outside
- an ozonizer for generating ozone from the air or oxygen gas supplied from outside
- ion-exchange resin, ion-exchange membrane, or the like may be used as the additive generation unit 27 .
- the additive generation unit 27 may be connected to the raw water tank 2 , whereby an additive may be generated from the treatment target water.
- the four-way valve 25 is connected also to the desalinated water measurement unit 12 and the three-way valve 23 as well as the washing water measurement unit 13 and the treated water tank 15 , so that the desalinated water flowing out from the water treatment unit 1 can circulate via the desalinated water measurement unit 12 , the four-way valve 25 , the three-way valve 23 , the three-way valve 22 , and the treatment target water measurement unit 11 .
- the three-way valve 22 is opened in a direction from the raw water tank 2 to the water treatment unit 1 , and the three-way valve 23 is closed.
- the four-way valve 25 is opened in a direction from the desalinated water measurement unit 12 to the treated water tank 15 .
- the treatment target water supply pump 3 is activated to send the treatment target water in the raw water tank 2 so as to be supplied to the water treatment unit 1 .
- the treatment target water is supplied through the upper inlet port 1 a of the water treatment unit 1 into the water treatment unit 1 , and then flows downward.
- DC voltage is applied to the first granular electrode member 18 and the second granular electrode member 19 via the pair of collectors 28 a , 28 b by the power supply unit 20 , whereby ions contained in the treatment target water are adsorbed and removed by a Coulomb force to the first granular electrode member 18 and the second granular electrode member 19 , and thus the treatment target water is desalinated.
- the desalinated treatment target water is discharged as desalinated water through the lower outlet port 1 b of the water treatment unit 1 and flows through the desalinated water measurement unit 12 and the four-way valve 25 to the treated water tank 15 .
- the washing water supply pump 4 is activated to inject, as washing water, the desalinated water in the treated water tank 15 into the water treatment unit 1 in a direction from the lower washing water inlet port 1 c to the upper inlet port 1 a of the water treatment unit 1 , i.e., the direction opposite to the flow of the treatment target water.
- the three-way valve 23 is opened in a direction from the three-way valve 22 to the drain side so that the washing water flowing out from the inlet port 1 a is drained.
- the three-way valve 23 is opened in a direction from the three-way valve 22 to the four-way valve 25 , and the four-way valve 25 is opened in a direction from the three-way valve 23 to the washing water measurement unit 13 and the water treatment unit 1 .
- a circulation path for the desalinated water as the washing water is formed, and the desalinated water circulates by a driving force from the washing water supply pump 4 .
- the electric conductivity of the desalinated water before injection into the water treatment unit 1 is measured by the washing water measurement unit 13 and the electric conductivity of the desalinated water after passing through the water treatment unit 1 is measured by the treatment target water measurement unit 11 , and then a result of measurement by the treatment target water measurement unit 11 is compared with a result of measurement by the washing water measurement unit 13 .
- the three-way valve 23 is switched to be opened in a direction from the three-way valve 22 to the drain side, to drain the circulating desalinated water.
- the four-way valve 25 is opened in a direction from the treated water tank 15 to the washing water measurement unit 13 and the water treatment unit 1 , and thus the reverse washing by circulation is finished.
- the electric conductivity of the desalinated water before injection into the water treatment unit 1 is measured by the washing water measurement unit 13 and the electric conductivity of the desalinated water after passing through the water treatment unit 1 is measured by the treatment target water measurement unit 11 , and then a result of the measurement by the treatment target water measurement unit 11 is compared with a result of the measurement by the washing water measurement unit 13 .
- the washing water supply pump 4 is stopped and the washing water supply valve 9 is closed, whereby the reverse washing step is finished. If this condition is not satisfied, that is, if the result of the measurement by the treatment target water measurement unit 11 is greater than 1.5 times the result of the measurement by the washing water measurement unit 13 , it is considered that biofilm and/or scale still remains in the water treatment unit 1 and thus the washing is insufficient. Therefore, the desalinated water is injected into the water treatment unit 1 and the reverse washing step is continued until the condition is satisfied.
- the washing water supply pump 4 is activated to inject, as washing water, the desalinated water in the treated water tank 15 into the water treatment unit 1 in a direction from the lower washing water inlet port is to the upper inlet port 1 a of the water treatment unit 1 , i.e., the direction opposite to the flow of the treatment target water.
- the three-way valve 23 is opened in a direction from the three-way valve 22 to the drain side so that the washing water flowing out from the inlet port 1 a is drained.
- the three-way valve 23 is opened in a direction from the three-way valve 22 to the four-way valve 25 , and the four-way valve 25 is opened in a direction from the three-way valve 23 to the washing water measurement unit 13 and the water treatment unit 1 .
- a circulation path for the desalinated water as the washing water is formed, and the desalinated water circulates by a driving force from the washing water supply pump 4 .
- the additive supply valve 10 is opened and the additive generated by the additive generation unit 27 is injected through the additive injection port 1 e into the water treatment unit 1 .
- the desalinated water sending valve 8 is opened and the desalinated water sending pump 26 is activated to send the desalinated water in the treated water tank 15 to the additive generation unit 27 , whereby the additive is diluted by the desalinated water and the diluted additive is injected into the water treatment unit 1 .
- the water treatment apparatus 400 does not include the drain valve 29 and therefore, regarding the flowing-out of the additive containing washing water which is performed at the end of the addition reverse washing step, the additive containing washing water is drained through the drain valve 30 .
- the reverse washing water tank for mixing an additive with the washing water to generate additive containing washing water can be omitted.
- the time period for generating the additive containing washing water can be omitted and thus the time period of the addition reverse washing step is shortened, whereby the desalination can be efficiently performed.
- Embodiment 5 is different from embodiment 1 in that a plurality of water treatment units are provided and connected in series.
- one of the water treatment units is defined as an A-system
- the other one is defined as a B-system
- the components in the A-system are denoted by adding “A” to the ends of their reference characters
- the components in the B-system are denoted by adding “B” to the ends of their reference characters.
- FIG. 1 is a configuration diagram of a water treatment apparatus according to embodiment 5 of the present invention.
- a water treatment apparatus 500 includes a water treatment unit 1 A and a water treatment unit 1 B.
- the water treatment unit 1 A has an inlet port 1 a A through which treatment target water flows in, an outlet port 1 b A through which desalinated water flows out, and a washing water inlet port 1 c A through which washing water or additive containing washing water flows in at the time of reverse washing, and the water treatment unit 1 A is connected via a treatment target water measurement unit 11 A, the treatment target water supply valve 5 , and then the treatment target water supply pump 3 to the raw water tank 2 for storing the treatment target water, and performs desalination for the treatment target water supplied from the raw water tank 2 .
- the water treatment unit 1 B has an inlet port 1 a B through which treatment target water flows in, an outlet port 1 b B through which desalinated water flows out, and a washing water inlet port 1 c B through which washing water or additive containing washing water flows in at the time of reverse washing, and the water treatment unit 1 B is connected via a desalinated water measurement unit 12 A, a treatment target water supply valve 5 B, and then a treatment target water measurement unit 11 B to the water treatment unit 1 A, and performs further desalination for the treatment target water that has undergone desalination by the water treatment unit 1 A.
- the water treatment unit 1 B is connected via a desalinated water measurement unit 12 B and then the desalinated water sending valve 7 to the treated water tank 15 for storing the treatment target water that has undergone further desalination by the water treatment unit 1 B, and also, the water treatment unit 1 B is connected via the desalinated water measurement unit 12 B and then the desalinated water sending valve 8 to the reverse washing water tank 17 for storing washing water for reverse washing.
- the reverse washing water tank 17 is shared by the water treatment unit 1 A and the water treatment unit 1 B.
- the reverse washing water tank 17 is connected to the water treatment unit 1 B also through a route passing a washing water supply pump 4 B for supplying washing water to the water treatment unit 1 B at the time of reverse washing, a washing water supply valve 9 B, and then a washing water measurement unit 13 B, and is connected to the water treatment unit 1 A via a washing water supply pump 4 A for supplying washing water to the water treatment unit 1 A, a washing water supply valve 9 A, and then a washing water measurement unit 13 A.
- Washing water supplied to the water treatment unit 1 A and washing water supplied to the water treatment unit 1 B can be drained via the treatment target water measurement unit 11 A and the treatment target water measurement unit 11 B, and then the drain valve 6 A and the drain valve 6 B, respectively, from the water treatment unit 1 A and the water treatment unit 1 B.
- the reverse washing water tank 17 is connected to the additive storage tank 16 via the additive supply valve 10 and then the additive supply pump 37 , and the reverse washing water tank 17 is provided with the stirrer 36 for stirring and mixing an additive and washing water when the additive is supplied. Washing water in the reverse washing water tank 17 can be drained via the drain valve 29 .
- a pair of collectors 28 a A, 28 b A connected to the power supply unit 20 are provided at both ends, and between the pair of collectors 28 a A, 28 b A, a first granular electrode member 18 A and a second granular electrode member 19 A are provided so as to be opposed to each other and separated from each other by a separator 21 A.
- a plurality of the first granular electrode members 18 A and a plurality of the second granular electrode members 19 A are provided.
- the first granular electrode members 18 A or the second granular electrode members 19 A are in contact with each other, but the first granular electrode member 18 A and the second granular electrode member 19 A are prevented from coming into contact with each other, by the separator 21 A.
- a pair of collectors 28 a B, 28 b B connected to the power supply unit 20 are provided at both ends, and between the pair of collectors 28 a B, 28 b B, a first granular electrode member 18 B and a second granular electrode member 19 B are provided so as to be opposed to each other and separated from each other by a separator 21 B.
- a plurality of the first granular electrode members 18 B and a plurality of the second granular electrode members 19 B are provided.
- the first granular electrode members 18 B or the second granular electrode members 19 B are in contact with each other, but the first granular electrode member 18 B and the second granular electrode member 19 B are prevented from coming into contact with each other, by the separator 21 B.
- the materials and functions of the collectors 28 a A, 28 b A, 28 a B, 28 b B, the first granular electrode members 18 A, 18 B, the second granular electrode members 19 A, 19 B, and the separators 21 A, 21 B are the same as those of the collectors 28 a , 28 b , the first granular electrode members 18 , the second granular electrode members 19 , and the separator 21 described in embodiment 1.
- the treatment target water measurement unit 11 A and the treatment target water measurement unit 11 B, the desalinated water measurement unit 12 A and the desalinated water measurement unit 12 B, and the washing water measurement unit 13 A and the washing water measurement unit 13 B, which are respectively connected to the water treatment unit 1 A and the water treatment unit 1 B, are the same as the treatment target water measurement unit 11 , the desalinated water measurement unit 12 , and the washing water measurement unit 13 of embodiment 1.
- valves, the pumps, and the measurement units are connected to the control unit 14 as in embodiment 1, and are controlled by the control unit 14 during execution of each processing step.
- water treatment units are provided in embodiment 5, the number thereof is not limited thereto and three or more water treatment units may be provided.
- the treatment target water supply valve 5 A and the treatment target water supply valve 5 B are opened, and the drain valve 6 A and the drain valve 6 B are closed.
- the treatment target water supply pump 3 is activated to send the treatment target water in the raw water tank 2 so as to be supplied to the water treatment unit 1 A.
- the treatment target water is supplied through the upper inlet port 1 a A of the water treatment unit 1 A into the water treatment unit 1 A, and then flows downward.
- DC voltage is applied to the first granular electrode members 18 A and the second granular electrode members 19 A via the pair of collectors 28 a A, 28 b A by the power supply unit 20 , and ions contained in the treatment target water are adsorbed and removed by a Coulomb force to the first granular electrode members 18 A and the second granular electrode members 19 A, whereby the treatment target water is desalinated.
- the desalinated treatment target water is discharged as desalinated water through the lower outlet port 1 b A of the water treatment unit 1 A, and passes through the desalinated water measurement unit 12 A, the treatment target water supply valve 5 B, and then the treatment target water measurement unit 11 B so as to be supplied to the water treatment unit 1 B through the inlet port 1 a B. Also in the water treatment unit 1 B, similarly, ions contained in the treatment target water that has undergone desalination by the water treatment unit 1 A are adsorbed and removed to the first granular electrode members 18 B and the second granular electrode members 19 B, whereby further desalination is performed.
- the treatment target water that has undergone further desalination by the water treatment unit 1 B is discharged through the lower outlet port 1 b B of the water treatment unit 1 B. Then, as in embodiment 1, the discharged water is sent to the reverse washing water tank 17 until a prescribed amount of the water is stored, and after the prescribed amount is reached, the discharged water is sent to the treated water tank 15 . After a predetermined time has elapsed since the start of the desalination step, the treatment target water supply pump 3 is stopped, and the treatment target water supply valve 5 A, the treatment target water supply valve 5 B, and the desalinated water sending valve 7 are closed. In addition, application of DC voltage by the power supply unit 20 is stopped, whereby the desalination step is finished.
- the control unit 14 executes execution control to determine whether to execute the reverse washing step or the addition reverse washing step, using the ion removal rate in the water treatment unit 1 as a determination index. Since the water treatment apparatus 500 of embodiment 5 includes two water treatment units 1 A and 1 B, the washing method execution control is performed for each of the water treatment unit 1 A and the water treatment unit 1 B. The washing method execution control for each water treatment unit is performed using the ion removal rate as a determination index, as in embodiment 1.
- the washing water supply pump 4 A is activated to inject the washing water in the reverse washing water tank 17 into the water treatment unit 1 A in a direction from the lower washing water inlet port 1 c A to the upper inlet port 1 a A of the water treatment unit 1 A, i.e., the direction opposite to the flow of the treatment target water.
- the washing water supply pump 4 B is activated to inject the washing water in the reverse washing water tank 17 into the water treatment unit 1 B in the direction opposite to the flow of the treatment target water.
- the washing water injected into the water treatment unit 1 A flows upward in the drawing and flows out through the inlet port 1 a A to the upper side of the water treatment unit 1 A, and thereafter, is drained through the drain valve 6 A.
- the washing water injected into the water treatment unit 1 B flows upward in the drawing and flows out through the inlet port 1 a B to the upper side of the water treatment unit 1 B, and thereafter, is drained through the drain valve 6 B.
- the electric conductivities of the washing water before and after injection into the water treatment unit are measured and compared, whereby whether or not the reverse washing step can be finished is determined.
- the determination is performed for each of the water treatment unit 1 A and the water treatment unit 1 B, and unless the reverse washing step is finished in both of the A-system and the B-system, the process does not proceed to the desalination step.
- a circulation path may be formed to execute reverse washing in which washing water is circulated.
- the additive supply valve 10 is opened and the additive supply pump 37 is activated to add a predetermined amount of additive to the washing water in the reverse washing water tank 17 from the additive storage tank 16 .
- the stirrer 36 stirs and mixes the additive and the washing water to generate additive containing washing water.
- the additive containing washing water is injected into each of the water treatment unit 1 A and the water treatment unit 1 B.
- the washing water supply pump 4 A is stopped and the washing water supply valve 9 A is closed.
- the washing water supply pump 4 B is stopped and the washing water supply valve 9 B is closed.
- the treatment target water supply valve 5 A, the treatment target water supply valve 5 B, the desalinated water sending valve 8 , and the drain valve 29 are opened, and the treatment target water supply pump 3 is activated to send the treatment target water from the raw water tank 2 to the water treatment unit 1 A and then the water treatment unit 1 B, thereby causing the additive containing washing water remaining in the water treatment unit 1 A and the water treatment unit 1 B to flow out and be drained from the reverse washing water tank 17 through the drain valve 29 .
- the treatment target water supply pump 3 is stopped and the treatment target water supply valve 5 A, the treatment target water supply valve 5 B, and the drain valve 29 are closed, whereby the addition reverse washing step is finished.
- a circulation path may be formed to execute reverse washing in which additive containing washing water is circulated.
- the treatment target water can be desalinated to a further decreased ion concentration.
- the reverse washing water tank is shared among the plurality of water treatment units, one reverse washing water tank is enough and the entire apparatus can be made compact.
- FIG. 9 is a configuration diagram of a water treatment apparatus according to embodiment 6 of the present invention.
- a water treatment apparatus 600 a plurality of additive injection ports 1 e for injecting an additive from the additive generation unit 27 are provided at the lower part in the drawing, of the water treatment unit 1 .
- additive injection ports 1 e are provided also to the pair of collectors 28 a , 28 b.
- the additive injection ports are provided at a plurality of locations of the water treatment unit, the additive is injected through the plurality of locations, whereby the additive containing washing water spreads faster over the entire granular electrode members, and thus the granular electrode members can be washed within a short time in the addition reverse washing step.
- FIG. 10 is a configuration diagram of a water treatment apparatus according to embodiment 7 of the present invention.
- the water treatment unit 1 which performs desalination for treatment target water is connected to the treated water tank 15 via the desalinated water sending valve 7 and then the desalinated water measurement unit 12 , and is connected to the treated water tank 15 also through a route passing the washing water supply valve 9 , the washing water measurement unit 13 , and the washing water supply pump 4 .
- the water treatment unit 1 is capable of drainage via the drain valve 30 .
- the additive storage tank 16 is connected via the additive supply pump 37 and then the additive supply valve 10 to an additive injection portion 38 provided to a pipe connecting the washing water measurement unit 13 and the washing water supply pump 4 .
- the water treatment apparatus 700 does not include the reverse washing water tank 17 , and also, does not include the desalinated water sending valve 8 , the stirrer 36 , and the drain valve 29 .
- the treatment target water supply valve 5 is opened and the drain valve 6 is closed.
- the desalinated water sending valve 7 is opened.
- the treatment target water supply pump 3 is activated to send the treatment target water in the raw water tank 2 so as to be supplied to the water treatment unit 1 .
- the treatment target water is supplied through the upper inlet port 1 a of the water treatment unit 1 into the water treatment unit 1 , and then flows downward.
- DC voltage is applied to the first granular electrode member 18 and the second granular electrode member 19 via the pair of collectors 28 a , 28 b by the power supply unit 20 , and ions contained in the treatment target water are adsorbed and removed by a Coulomb force to the first granular electrode member 18 and the second granular electrode member 19 , whereby the treatment target water is desalinated.
- the desalinated treatment target water is discharged as desalinated water through the lower outlet port 1 b of the water treatment unit 1 , and flows through the desalinated water sending valve 7 and the desalinated water measurement unit 12 to the treated water tank 15 .
- the washing water supply pump 4 is activated to inject, as washing water, the desalinated water in the treated water tank 15 into the water treatment unit 1 in a direction from the lower washing water inlet port 1 c to the upper inlet port 1 a of the water treatment unit 1 , i.e., the direction opposite to the flow of the treatment target water.
- the additive supply valve 10 is opened and the additive supply pump 37 is activated to send the additive from the additive storage tank 16 to the additive injection portion 38 and inject the additive into the pipe connecting the washing water measurement unit 13 and the washing water supply pump 4 .
- the desalinated water as the washing water flowing through the pipe is mixed with the additive while flowing to the water treatment unit 1 , whereby additive containing washing water is generated.
- the generated additive containing washing water is injected into the water treatment unit 1 through the washing water inlet port 1 c .
- the additive containing washing water flows upward and flows out to the upper side of the water treatment unit 1 through the inlet port 1 a , and then is drained through the drain valve 6 .
- the water treatment apparatus 700 does not include the drain valve 29 and therefore, regarding the flowing-out of the additive containing washing water which is performed at the end of the addition reverse washing step, the additive containing washing water is drained through the drain valve 30 .
- the reverse washing water tank can be omitted and thus the entire apparatus can be simplified.
- the additive is injected and mixed only to the desalinated water flowing from the treated water tank to the water treatment unit to generate the additive containing washing water, surplus additive containing washing water as in the case of mixing the additive to the washing water stored in the reverse washing water tank is not generated, and thus the generation amount of the additive containing washing water can be suppressed to the minimum necessary amount. As a result, the amount of desalinated water that can be recovered increases, whereby the recovery rate for desalinated water can be increased.
- FIG. 11 is a configuration diagram of a water treatment apparatus according to embodiment 8 of the present invention.
- a water treatment apparatus 800 includes an air pump 39 for injecting air into the water treatment unit 1 from the lower side of the water treatment unit 1 .
- the air pump 39 is connected to the control unit 14 , and is controlled by the control unit 14 during execution of each processing step.
- the washing water supply pump 4 is activated to inject the washing water in the reverse washing water tank 17 into the water treatment unit 1 in a direction from the lower washing water inlet port 1 c to the upper inlet port 1 a of the water treatment unit 1 , i.e., the direction opposite to the flow of the treatment target water.
- the washing water is injected into the water treatment unit 1 through the washing water inlet port 1 c
- the washing water flows upward and flows out to the upper side of the water treatment unit 1 through the inlet port 1 a , and then is drained through the drain valve 6 .
- the air pump 39 injects air into the water treatment unit 1 in a direction from the lower side to the upper side of the water treatment unit 1 , i.e., the direction opposite to the flow of the treatment target water.
- the air injected by the air pump 39 flows in the water treatment unit 1 together with the washing water.
- a shear force acts on the surfaces of the first granular electrode member 18 and the second granular electrode member 19 , thereby removing biofilm and/or scale adhered to the surfaces of the granular electrode members.
- the flow speed of the air injected by the air pump 39 is 0.5 to 1.5 m/min, or desirably, 0.7 to 0.9 m/min, and the air injection time is 1 to 10 minutes, or desirably, 2 to 5 minutes. If the flow speed is too high, the shear force acting on the surfaces of the granular electrode members becomes excessive and thus the surfaces are worn out, so that the specific surface area is reduced, leading to decrease in capacitor.
- the additive supply valve 10 is opened and the additive supply pump 37 is activated to add a predetermined amount of additive to the washing water in the reverse washing water tank 17 from the additive storage tank 16 .
- the stirrer 36 stirs and mixes the additive and the washing water to generate additive containing washing water.
- the washing water supply pump 4 is activated to inject the additive containing washing water in the reverse washing water tank 17 into the water treatment unit 1 in a direction from the lower washing water inlet port 1 c to the upper inlet port 1 a of the water treatment unit 1 , i.e., the direction opposite to the flow of the treatment target water.
- the additive containing washing water is injected into the water treatment unit 1 through the washing water inlet port 1 c
- the additive containing washing water flows upward and flows out to the upper side of the water treatment unit 1 through the inlet port 1 a , and then is drained through the drain valve 6 .
- the air pump 39 injects air into the water treatment unit 1 in a direction from the lower side to the upper side in the drawing, i.e., the direction opposite to the flow of the treatment target water.
- the air injected by the air pump 39 flows in the water treatment unit 1 together with the additive containing washing water.
- a shear force acts on the surfaces of the first granular electrode member 18 and the second granular electrode member 19 , thereby removing and injecting biofilm and/or scale adhered to the surfaces of the granular electrode members.
- the flow speed and the injection time for the air are the same as in the reverse washing step.
- FIG. 12 is a configuration diagram of a water treatment apparatus according to embodiment 9 of the present invention.
- the water treatment unit 1 is provided with a water treatment unit state measurement unit 40 for measuring the state in the water treatment unit 1 .
- the water treatment unit state measurement unit 40 is an electric conductivity meter for measuring the electric conductivity of the treatment target water during desalination in the water treatment unit 1 .
- the water treatment unit state measurement unit 40 is connected to the control unit 14 , and is controlled by the control unit 14 during execution of each processing step.
- the water treatment unit state measurement unit 40 measures the electric conductivity of treatment target water that is being subjected to desalination in the water treatment unit 1 , at predetermined time intervals, during execution of the desalination step.
- a result of the measurement after x has elapsed since the start of the desalination step is defined as A(x)
- A(x+y) is defined as A(x+y).
- the desalination step is finished when A(x+y) is smaller than 0.8 times A(x), the desalination step is finished in a state in which the desalination still can be performed, and thus the desalination is insufficient.
- the desalination step is finished when A(x+y) is greater than 1.0 times A(x)
- ions have been adsorbed to a deep part of each granular electrode member and thus a time is required for washing. Therefore, the time periods of the washing step and the addition reverse washing step are prolonged, so that desalination efficiency is reduced.
- desalinated water needed for washing increases, and thus the recovery amount of the desalinated water decreases.
- x is an optional value
- y is 1 to 15 minutes, or desirably, 1 to 10 minutes. If y is too great, the time period of the desalination step is prolonged, so that ions are adsorbed to a deep part of each granular electrode member and a time is required for washing. Thus, the time periods of the washing step and the addition reverse washing step are prolonged and desalination efficiency is reduced. In addition, the amount of desalinated water needed for washing increases, and thus the recovery amount of the desalinated water decreases. On the other hand, if y is too small, the desalination step is finished even though the electric conductivity temporarily decreases, leading to insufficient desalination.
- the electric conductivity of the treatment target water during desalination is used as the finish determination index for the desalination step, determination as to finish of the desalination step is performed while the ion concentration in the treatment target water is reflected therein. Since the ion concentration in the treatment target water directly relates to desalination performance of the water treatment unit, it is possible to perform more effective and efficient desalination while maximally using the desalination performance of the water treatment unit.
- Embodiment 10 is different from embodiment 1 in that an execution period is used as a finish determination index for the reverse washing step and the addition reverse washing step.
- the other matters are the same as in embodiment 1, and therefore the description thereof is omitted.
- the “reverse washing step” and the “addition reverse washing step” will be described in detail.
- Control of the valves and the like and the flow of washing water in the reverse washing step are the same as in embodiment 1.
- the reverse washing step is finished. If the execution period of the reverse washing step is too long, a time is taken for the washing, so that the amount of desalinated water that is recovered is decreased, leading to reduction in desalination efficiency.
- the execution period of the reverse washing step is too short, each granular electrode member is not sufficiently washed, leading to reduction in the ion removal rate, and thus desalination efficiency in the next desalination step is reduced.
- Control of the valves and the like and the flows of the additive and the additive containing washing water in the addition reverse washing step are the same as in embodiment 1.
- the execution period of the reverse washing has reached 1 to 60 minutes, or desirably, 3 to 30 minutes since the start of the reverse washing using additive containing washing water, the reverse washing using additive containing washing water is finished. If the time period of the reverse washing using additive containing washing water is too long, a time is taken for the washing and the amount of desalinated water that is recovered decreases, leading to reduction in desalination efficiency.
- the time period of the flowing-out of the additive containing washing water is too long, the treatment target water needed for causing the additive containing washing water to flow out from the water treatment unit 1 increases, leading to reduction in the recovery rate for the desalinated water.
- the time period of the addition reverse washing step is prolonged, and thus the number of times of the desalination step decreases, leading to reduction in the recovery rate for the desalinated water.
- Embodiment 11 is different from embodiment 1 in that the ion concentration of the removal target ion is used as a determination index in the washing method execution control.
- a desalinated water ion concentration measurement unit (not shown) for measuring the ion concentration of the removal target ion in the desalinated water is connected to the water treatment unit 1 .
- the desalinated water ion concentration measurement unit (not shown), an absorption photometer for measuring the ultraviolet absorbance or an ion selective electrode is used.
- the removal target ion include chloride ion, sodium ion, calcium ion, magnesium ion, potassium ion, sulfuric acid ion, and nitrate ion.
- the control unit 14 acquires the removal target ion concentration in the desalinated water from the desalinated water ion concentration measurement unit (not shown) and stores the removal target ion concentration into the storage unit (not shown).
- the control unit 14 reads, from the storage unit (not shown), the greater one (hereinafter, referred to as “reference removal target ion concentration”) of the removal target ion concentration at the time when the first-time desalination step is finished after the water treatment apparatus 100 has been activated, and the removal target ion concentration at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed, and compares the reference removal target ion concentration with the present removal target ion concentration.
- the control unit 14 determines to execute the addition reverse washing step. If the present removal target ion concentration is 1 to 2 times, or desirably, 1 to 1.5 times the reference removal target ion concentration, the desalination performance of the water treatment unit 1 has been reduced, and therefore the control unit 14 determines to execute the addition reverse washing step. If the present removal target ion concentration is smaller than 1 times the reference removal target ion concentration, the desalination performance of the water treatment unit 1 has not been reduced and it is not necessary to execute the addition reverse washing. Therefore, the control unit 14 determines to execute the reverse washing step.
- the control unit 14 determines that it is difficult to restore the desalination performance by the addition reverse washing step.
- the control unit 14 causes a display unit (not shown) to display an alarm indication for notification that it is necessary to replace the first granular electrode member 18 and the second granular electrode member 19 , thereby prompting a user to replace the first granular electrode member 18 and the second granular electrode member 19 .
- the ion concentration of the removal target ion as a determination index in the washing method execution control, it is possible to determine whether to execute the reverse washing step or the addition reverse washing in accordance with the ion concentration of an ion that is a main removal target. Therefore, a specific ion can be removed efficiently.
- the configuration in which the ion concentration of the removal target ion is used as a determination index in the washing method execution control as in embodiment 11, is also applicable to embodiments 2 to 10.
- Embodiment 12 is different from embodiment 1 in that hardness is used as a determination index in the washing method execution control.
- a desalinated water hardness measurement unit (not shown) for measuring the hardness of desalinated water is connected to the water treatment unit 1 .
- a hardness meter or a hardness sensor is used as the desalinated water hardness measurement unit (not shown).
- the control unit 14 acquires the hardness of desalinated water from the desalinated water hardness measurement unit (not shown) and stores the hardness into the storage unit (not shown).
- the control unit 14 reads, from the storage unit (not shown), the greater one (hereinafter, referred to as “reference hardness”) of the hardness of desalinated water at the time when the first-time desalination step is finished after the water treatment apparatus 100 has been activated, and the hardness of desalinated water at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed, and compares the reference hardness with the present hardness of the desalinated water.
- the control unit 14 determines to execute the addition reverse washing step. If the present hardness of the desalinated water is smaller than 1 times the reference hardness, the desalination performance of the water treatment unit 1 has not been reduced and it is not necessary to execute the addition reverse washing. Therefore, the control unit 14 determines to execute the reverse washing step.
- the control unit 14 determines that it is difficult to restore the desalination performance by the addition reverse washing step.
- the control unit 14 causes a display unit (not shown) to display an alarm indication for notification that it is necessary to replace the first granular electrode member 18 and the second granular electrode member 19 , thereby prompting a user to replace the first granular electrode member 18 and the second granular electrode member 19 .
- the addition reverse washing step can be executed at an effective timing.
- Embodiment 13 is different from embodiment 9 in that the current value of current flowing through the water treatment unit during execution of the desalination step is used as a determination index in the washing method execution control.
- Embodiment 13 uses a phenomenon in which, in electric desalination technology using electrical double layer capacitor technology, desalination performance is reduced when the capacitances of the first granular electrode member and the second granular electrode member in the water treatment unit are reduced due to adhesion of scale and/or biofilm, and the reduction of the capacitances is detected on the basis of measurement of current flowing through the water treatment unit during desalination.
- the water treatment unit state measurement unit 40 is a current meter for measuring the value of current flowing through the water treatment unit 1 .
- the control unit 14 acquires the current value of current flowing through the water treatment unit 1 at the start of the desalination step, from the water treatment unit state measurement unit 40 which is a current meter, and stores the current value into the storage unit (not shown). Control of the valves and the like and the flows of treatment target water and desalinated water are the same as in embodiment 1.
- the control unit 14 reads, from the storage unit (not shown), the greater one (hereinafter, referred to as “reference current value”) of the current value of current flowing through the water treatment unit at the time when the first-time desalination step is finished after the water treatment apparatus 900 has been activated, and the current value at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed, and compares the reference current value with the present current value. If the present current value is smaller than 0.5 to 1.0 times, or desirably, 0.7 to 0.9 times the reference current value, the current flowing through the water treatment unit 1 has been reduced and thus desalination performance of the water treatment unit 1 has been reduced. Therefore, the control unit 14 determines to execute the addition reverse washing step.
- the control unit 14 determines to execute the reverse washing step. If the present current value is smaller than 0.5 times, or desirably, 0.7 times the reference current value, the desalination performance has been significantly reduced and therefore the control unit 14 determines that it is difficult to restore the desalination performance by the addition reverse washing step.
- control unit 14 causes a display unit (not shown) to display an alarm indication for notification that it is necessary to replace the first granular electrode member 18 and the second granular electrode member 19 , thereby prompting a user to replace the first granular electrode member 18 and the second granular electrode member 19 .
- the current value of current flowing through the water treatment unit 1 at the start of the desalination step is used as a determination index for the washing method execution control in embodiment 13, the current value at the time when the desalination step is finished or the integral value of the current value during execution of the desalination step may be used as the determination index.
- the determination index is less likely to be influenced by contamination of treatment target water or desalinated water and thus it is possible to perform appropriate determination in the washing method execution control.
- the water treatment unit state measurement unit can be simplified.
- the configuration in which the current value of current flowing through the water treatment unit during the desalination step is used as a determination index in the washing method execution control as in embodiment 13, is also applicable to embodiments 2 to 10.
- Embodiment 14 is different from embodiment 9 in that the voltage value between both ends of the water treatment unit at the time when the desalination step is finished and voltage drop thereof at the time of discharging after the desalination step is finished, are used as determination indices in the washing method execution control.
- Embodiment 14 uses a phenomenon in which, in electric desalination technology using electrical double layer capacitor technology, when the capacitances of the first granular electrode member and the second granular electrode member in the water treatment unit are reduced due to adhesion of scale and/or biofilm, desalination performance is reduced, and when the internal resistance in the water treatment unit is increased due to adhesion of scale and/or biofilm, desalination performance is reduced and the internal resistance is increased.
- the reduction in the capacitances is detected on the basis of measurement of the voltage value between both ends of the water treatment unit at the time when the desalination step is finished, and the increase in the internal resistance is detected on the basis of measurement of voltage drop at the time of discharging after the desalination step.
- the water treatment unit state measurement unit 40 is a voltage meter for measuring the voltage value between both ends of the water treatment unit 1 , i.e., between the pair of collectors 28 a , 28 b.
- the control unit 14 acquires the voltage value between both ends of the water treatment unit 1 at the time when the desalination step is finished and voltage drop thereof at the time of discharging after the desalination step, from the water treatment unit state measurement unit 40 which is a voltage meter, and stores the voltage value and voltage drop into the storage unit (not shown). Control of the valves and the like and the flows of the treatment target water and the desalinated water are the same as in embodiment 1.
- the control unit 14 reads, from the storage unit (not shown), the greater one (hereinafter, referred to as “reference voltage value”) of the voltage value between both ends of the water treatment unit 1 at the time when the first-time desalination step is finished after the water treatment apparatus 900 has been activated, and the voltage value at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed, and the smaller one (hereinafter, referred to as “reference voltage drop”) of the voltage drop between the both ends of the water treatment unit 1 at the time of discharging immediately after the first-time desalination step is finished after activation of the water treatment apparatus 900 , and the voltage drop at the time of discharging immediately after the first-time desalination step is finished after the previous execution of the addition reverse washing step.
- reference voltage value the greater one of the voltage value between both ends of the water treatment unit 1 at the time when the first-time desalination step is finished after the water treatment apparatus 900 has been activated
- the control unit 14 compares the reference voltage value and the reference voltage drop with the present voltage value and the present voltage drop, respectively. If the present voltage value is smaller than 0.5 to 1.0 times, or desirably, 0.7 to 0.9 times the reference current value, or if the present voltage drop is 1 to 5 times, or desirably, 1 to 2 times the reference voltage drop, biofilm and/or scale has been adhered to the first granular electrode member 18 and the second granular electrode member 19 and thus desalination performance of the water treatment unit 1 has been reduced. Therefore, the control unit 14 determines to execute the addition reverse washing step.
- the washing method execution control since the voltage value between both ends of the water treatment unit at the time when the desalination step is finished and voltage drop thereof at the time of discharging after the desalination step is finished are used as determination indices in the washing method execution control, the determination indices are less likely to be influenced by contamination of treatment target water or desalinated water and thus it is possible to perform appropriate determination in the washing method execution control.
- the water treatment unit state measurement unit can be simplified.
- the configuration in which the voltage value between both ends of the water treatment unit at the time when the desalination step is finished and voltage drop at the time of discharging after the desalination step is finished are used as determination indices in the washing method execution control as in embodiment 14, is also applicable to embodiments 2 to 10.
- Embodiment 15 is different from embodiment 1 in that pressure loss in the water treatment unit at the time when the desalination step is finished is used as a determination index in the washing method execution control.
- Embodiment 15 uses a phenomenon in which, in electric desalination technology using electrical double layer capacitor technology, while the desalination step is repeated, accumulation of biofilm and/or scale and contraction of the granular electrode members due to wearing occur and thus their surface areas are reduced, and the capacitances are reduced, whereby desalination performance is reduced and the occlusion degree of the first granular electrode member and the second granular electrode member is increased. Increase in the occlusion degree is detected on the basis of measurement of pressure loss.
- the treatment target water measurement unit 11 and the desalinated water measurement unit 12 include pressure meters for measuring the pressures of treatment target water and desalinated water, respectively.
- the control unit 14 acquires the pressures of treatment target water flowing into the water treatment unit 1 and desalinated water flowing out from the water treatment unit 1 , from the treatment target water measurement unit 11 and the desalinated water measurement unit 12 , when the desalination step is finished, and then the control unit 14 calculates pressure loss in the water treatment unit 1 and stores the pressure loss into the storage unit (not shown). Control of the valves and the like and the flows of the treatment target water and the desalinated water are the same as in embodiment 1.
- the control unit 14 reads, from the storage unit (not shown), the greater one (hereinafter, referred to as “reference pressure loss”) of the pressure loss in the water treatment unit 1 at the time when the first-time desalination step is finished after the water treatment apparatus 100 has been activated, and the pressure loss at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed, and compares the reference pressure loss with the present pressure loss. If the present pressure loss is 1 to 5 times, or desirably, 1.5 to 3 times the reference pressure loss, biofilm and/or scale has been accumulated and the first granular electrode member 18 and the second granular electrode member 19 have contracted, whereby desalination performance has been reduced.
- the control unit 14 determines to execute the addition reverse washing step. If the present pressure loss is smaller than 1 times, or desirably, 1.5 times the reference pressure loss, the ion removal rate of the water treatment unit 1 has not been reduced or has been slightly reduced and thus it is not necessary to execute the addition reverse washing. Therefore, the control unit 14 determines to execute the reverse washing step. If the present pressure loss is 5 times, or desirably, 3 times the reference pressure loss, desalination performance has been significantly reduced and therefore the control unit 14 determines that it is difficult to restore desalination performance by the addition reverse washing step.
- control unit 14 causes a display unit (not shown) to display an alarm indication for notification that it is necessary to replace the first granular electrode member 18 and the second granular electrode member 19 , thereby prompting a user to replace the first granular electrode member 18 and the second granular electrode member 19 .
- the determination index is less likely to be influenced by contamination of treatment target water or desalinated water, and therefore it is possible to comprehensively and easily grasp increase in the occlusion degree of the first granular electrode member and the second granular electrode member. Thus, it is possible to easily perform appropriate determination in the washing method execution control.
- FIG. 13 is a perspective view showing the water treatment unit according to embodiment 16
- FIG. 14 is a top view showing the water treatment unit according to embodiment 16
- FIG. 15 and FIG. 16 are sectional views along P-P line and Q-Q line in FIG. 14 . As shown in FIG.
- a water treatment unit 101 is configured such that a first granular electrode member 181 , a second granular electrode member 191 , a pair of collectors 281 a , 281 b , and a separator 211 , which correspond to the first granular electrode member 18 , the second granular electrode member 19 , and the pair of collectors 28 a , 28 b , and the separator 21 described in the above embodiments 1 to 15, are stored in a treatment container 48 .
- the treatment container 48 is, for example, a rectangular parallelepiped, and a plate-shaped lid 49 is placed above the upper surface of the treatment container 48 while a packing 43 formed from an elastic member is provided therebetween.
- the lid 49 has a predetermined thickness, and is fastened to the treatment container 48 by four screws 44 passing through-holes (not shown) formed at the four corners.
- the pair of collectors 281 a , 281 b are placed with the separator 211 therebetween, and the first granular electrode member 181 and the second granular electrode member 191 are placed between the separator 211 and the pair of collectors 281 a , 281 b .
- a resin material having an insulation property or metal having an electrically insulating coat is used as the materials of the treatment container 48 and the lid 49 .
- the lower surface of the lid 49 has a pair of collector grooves 51 a , 51 b into which the upper ends of the pair of collectors 281 a , 281 b are inserted, and a separator groove 50 into which the upper end of the separator 211 is inserted.
- the pair of collectors 281 a , 281 b are positioned by their upper ends being fitted to the collector grooves 51 a , 51 b
- the separator 21 is positioned by its upper end being fitted to the separator groove 50 .
- the first granular electrode member 181 and the second granular electrode member 191 serve to adsorb ions in treatment target water when voltage is applied.
- the granular electrode members included in the first granular electrode member 181 and the second granular electrode member 191 in the present embodiment are not made into a sheet form or the like, and are provided in the treatment container 48 in a state in which the granules are not fixed to each other. That is, the first granular electrode member 181 and the second granular electrode member 191 are each configured to include a plurality of flowable granular electrode members.
- a conductive material which has conductivity and a great specific surface area and has a great capacitance as a capacitor is used.
- activated carbon, porous carbon, porous conductive beads, or porous metal is used.
- These conductive materials may be formed in a powder shape, a granular shape, or the like, and in the case of powder shape or granular shape, the outer diameter thereof is 50 nm to 10 mm.
- the interval between the separator 211 and each collector 281 a , 281 b may be 1 to 100 times, or desirably, 5 to 20 times the outer diameter of the granular electrode members included in the first granular electrode member 181 and the second granular electrode member 191 . If the interval between the separator 211 and each collector 281 a , 281 b is smaller than 1 times the outer diameter of the granular electrode members included in the first granular electrode member 181 and the second granular electrode member 191 , the first granular electrode member 181 and the second granular electrode member 191 cannot be provided between the separator 211 and the collectors 281 a , 281 b .
- the interval is greater than 100 times the outer diameter, the electric resistances of the entire first granular electrode member 181 and the entire second granular electrode member 191 are increased, so that desalination performance in the desalination step is reduced.
- the thicknesses of the first granular electrode member 181 and the second granular electrode member 191 are increased, the number of granules of the granular electrode members included in each of them is increased, leading to formation of a large number of contact portions between granules, which have a great electric resistance due to contact resistance.
- the pair of collectors 281 a , 281 b are for applying electricity to the first granular electrode member 181 and the second granular electrode member 191 , and collecting electricity at the time of discharging.
- the pair of collectors 281 a , 281 b are formed from a conductive and flexible material.
- the pair of collectors 281 a , 281 b are formed from a graphite sheet, GRAFOIL (registered trademark), conductive rubber, or a metal sheet/plate sandwiched between or coated with such materials.
- terminals 45 a and 45 b are respectively formed at the upper ends of the pair of collectors 281 a , 281 b .
- the terminals 45 a and 45 b protrude from a pair of through-holes 46 a and 46 b formed in the lid 49 so as to be exposed to outside, and are used for making electric connection between a power supply (not shown), and the pair of collectors 281 a , 281 b and the first granular electrode member 181 and the second granular electrode member 191 .
- a power supply not shown
- the pair of collectors 281 a , 281 b and the first granular electrode member 181 and the second granular electrode member 191 .
- the separator 211 prevents short-circuit between the first granular electrode member 181 and the second granular electrode member 191 , and is formed from a material such as filter paper, a porous film, nonwoven fabric, a foamed material, or the like which allows transmission of liquid but blocks a conductive material so as to make electric insulation.
- An inlet port 101 a of the water treatment unit 101 is provided at one side surface of the treatment container 48 , and communicates between outside of the treatment container 48 and a space between the pair of collectors 281 a , 281 b , i.e., a space in which the first granular electrode member 181 , the second granular electrode member 191 , and the separator 211 are placed.
- the water treatment unit 101 allows treatment target water to be directly injected into the space in which the first granular electrode member 181 , the second granular electrode member 191 , and the separator 211 are placed.
- An outlet port 101 b of the water treatment unit 101 is provided on another side surface of the treatment container 48 , and communicates between outside of the treatment container 48 and a space between the pair of collectors 281 a , 281 b .
- the water treatment unit 101 allows treatment target water to be directly discharged from the space in which the first granular electrode member 181 , the second granular electrode member 191 , and the separator 211 are placed.
- the inlet port 101 a and the outlet port 101 b are formed from a resin material having insulation property, such as acrylic resin, or metal having an electrically insulating coat, such as fluorine-coated stainless steel, in order to prevent short-circuit between the first granular electrode member 181 and the second granular electrode member 191 .
- flow-out preventing members 52 are attached for preventing conductive materials constituting the first granular electrode member 181 and the second granular electrode member 191 from flowing out from the treatment container 48 .
- the flow-out preventing members 52 are formed by a resin net having an insulating property or a metal mesh having an insulating coat, for example.
- the inlet port 101 a is located at the lower part of the side surface of the treatment container 48
- the outlet port 101 b is located at the upper part of the side surface of the treatment container 48 .
- the locations of the inlet port 101 a and the outlet port 101 b are not limited thereto.
- the inlet port 101 a may be located at the upper part of the side surface of the treatment container 48 and the outlet port 101 b may be located at the lower part of the side surface of the treatment container 48 .
- both or one of the inlet port 101 a and the outlet port 101 b may be located near the center of the side surface of the treatment container 48 . Still alternatively, they may be located at the lid 49 .
- a pressing portion 47 is formed above the first granular electrode member 181 and the second granular electrode member 191 as shown in FIGS. 13, 15, and 16 .
- the pressing portion 47 is formed in a projection shape so as to protrude toward inside of the treatment container 48 , and has a lower surface formed in a flat shape so that a pressing force can be applied uniformly to the first granular electrode member 181 and the second granular electrode member 191 .
- the size of the pressing portion 47 is designed so that the first granular electrode member 181 and the second granular electrode member 191 come into a predetermined pressed state when the screws 44 are screwed to the end.
- the pressing portion 47 gradually presses the first granular electrode member 181 and the second granular electrode member 191 in the treatment container 48 from above, and when the screws 44 are screwed to the end, the first granular electrode member 181 and the second granular electrode member 191 are brought into a predetermined pressed state.
- the water treatment unit 101 brings the first granular electrode member 181 and the second granular electrode member 191 into a predetermined pressed state by the lid 49 of the treatment container 48 , and keeps the pressed state of the first granular electrode member 181 and the second granular electrode member 191 by the fastening force of the screws 44 during a period in which the treatment target water is treated in the treatment container 48 in the desalination step.
- the granules of the conductive materials constituting the first granular electrode member 181 and the second granular electrode member 191 are fixed and thus no longer flow.
- the granules of the first granular electrode member 181 and the second granular electrode member 191 are not fixed to each other and therefore can flow in a non-pressed state such as a state before the pressing and a state after cancelation of the pressing.
- A is the volume of the first granular electrode member 181 and the second granular electrode member 191 before the lid 49 is attached to the treatment container 48
- B is the volume of the first granular electrode member 181 and the second granular electrode member 191 when the lid 49 is attached to the treatment container 48 and the screws 44 are screwed to the end.
- the compression rate P is equal to the ratio between a height H 1 of the lid 49 when the lid 49 is merely placed on the first granular electrode member 181 and the second granular electrode member 191 and the screws 44 are not screwed at all, and a height H 2 of the lid 49 after the screws 44 are screwed to the end.
- the first granular electrode member 181 and the second granular electrode member 191 are placed between the collector 281 a and the separator 211 and between the collector 281 b and the separator 211 , and the pair of collectors 281 a , 281 b and the separator 211 are positioned by the collector grooves 51 a , 51 b and the separator groove 50 .
- the values of A and B can be acquired by actually measuring the dimensions of the first granular electrode member 181 and the second granular electrode member 191 , and the compression rate P can be calculated from the acquired values of A and B.
- the compression rate P is calculated from the height H 1 of the lid 49 when the lid 49 is merely placed on the first granular electrode member 181 and the second granular electrode member 191 and the screws 44 are not screwed at all, and the height H 2 of the lid 49 after the screws 44 are screwed to the end.
- the compression rate P is prescribed in a range of 0.5 to 0.99, or desirably, 0.7 to 0.95. If the compression rate P is greater than 0.99, the contact area between the conductive materials constituting the first granular electrode member 181 and the second granular electrode member 191 decreases and the electric resistance increases, and this is not preferable. If the compression rate P is smaller than 0.5, the conductive materials are crushed and flow out from the treatment container 48 together with treatment target water, and this is not preferable.
- the pressed state of the first granular electrode member 181 and the second granular electrode member 191 may be prescribed by the value of the electric resistance between the pair of collectors 281 a , 281 b or the value of pressure loss when treatment target water is passed in the desalination step.
- the pressed state may be prescribed by both values of the electric resistance and pressure loss.
- a value in a range of 0.01 to 100 ⁇ , or desirably, 0.05 to 50 ⁇ is used. Since the conductive materials constituting the separator 211 , the first granular electrode member 181 , and the second granular electrode member 191 have a resistance, the value of electric resistance cannot be made smaller than 0.01 ⁇ . On the other hand, in the case of being greater than 100 ⁇ , desalination performance is deteriorated, and this is not preferable.
- a value in a range of 0.001 to 1000 kPa/m, or desirably, 0.05 to 500 kPa/m is used. Since the conductive materials constituting the first granular electrode member 181 and the second granular electrode member 191 have a water passing resistance, the pressure loss cannot be made smaller than 0.001 kPa/m. On the other hand, in the case of being greater than 1000 kPa/m, energy consumption relevant to water injection into the water treatment unit 101 increases, and this is not preferable.
- the gaps in the conductive materials constituting the first granular electrode member 181 and the second granular electrode member 191 are finely divided, and flow of treatment target water into the gaps is also finely divided.
- the distance between ions in the treatment target water and the conductive materials constituting the first granular electrode member 181 and the second granular electrode member 191 is shortened, whereby adsorption of the ions to the first granular electrode member and the second granular electrode member is promoted.
- the flow of the treatment target water has a uniform thickness in the first granular electrode member 181 and the second granular electrode member 191 .
- the contact area between the conductive materials constituting the first granular electrode member 181 and the second granular electrode member 191 increases, and the electric resistance decreases.
- the water treatment unit is configured such that the pair of collectors are placed with the separator therebetween in the treatment container, the first granular electrode member and the second granular electrode member are placed between the separator and the pair of collectors, and the pressing portion for pressing the first granular electrode member and the second granular electrode member and keeping the pressed state is formed at the lid of the treatment container.
- the first granular electrode member and the second granular electrode member are formed by only conductive materials without using an additive such as a binder. Therefore, in the desalination step, the pores and the gaps in the conductive materials constituting the first granular electrode member and the second granular electrode member can be prevented from being occluded, and pressure loss due to injection of treatment target water can be decreased.
- the gaps in the conductive materials constituting the first granular electrode member and the second granular electrode member are finely divided, and therefore flow of treatment target water into the gaps is also finely divided, whereby the distance between the ions in the treatment target water and the conductive materials is shortened, and thus adsorption of ions to the first granular electrode member and the second granular electrode member is promoted. Further, owing to the fine division of the water flow, flow of treatment target water in the first granular electrode member and the second granular electrode member has a uniform thickness, and therefore adsorption of ions is uniformly performed. Since promotion of ion adsorption and uniform ion adsorption are achieved, desalination performance can be further improved.
- the electric resistance of the first granular electrode member and the second granular electrode member is reduced, and therefore applied electricity can be passed throughout the first granular electrode member and the second granular electrode member, and the pores in the conductive materials constituting the first granular electrode member and the second granular electrode member can be used without waste.
- the treatment container is provided with the inlet port communicating between outside of the treatment container and the space in which the first granular electrode member, the second granular electrode member, and the separator are placed, so that the treatment target water directly flows into the first granular electrode member, the second granular electrode member, and the separator. Therefore, the treatment target water can spread over the entirety of the separator, the first granular electrode member, and the second granular electrode member.
- the pressing portion is formed at the lid of the treatment container.
- the lid and the pressing portion may be separate members. In this case, only the pressing portion may be fastened by screws, and the lid may be fixed to the treatment container by another fixation member.
- the separator groove and the pair of collector grooves are formed on the lid.
- the separator groove and the pair of collector grooves may be formed in the treatment container, or may be formed for both of the lid and the treatment container.
- Embodiment 17 relates to a configuration in which, in the water treatment unit described in any of embodiments 1 to 15, a pressing portion for pressing the first granular electrode member and the second granular electrode member is provided to the water treatment unit, and the pair of collectors and the separator are arranged in the vertical direction.
- FIG. 17 is a perspective view showing a water treatment unit 102 according to embodiment 17 of the present invention. As shown in FIG.
- a water treatment unit 102 is configured such that a first granular electrode member 182 , a second granular electrode member 192 , a pair of collectors 282 a , 282 b , and a separator 212 , which correspond to the first granular electrode member 18 , the second granular electrode member 19 , the pair of collectors 28 a , 28 b , and the separator 21 described in the above embodiments 1 to 15, are stored in a cylindrical treatment container 58 .
- a cylindrical lid 59 is placed above the upper surface of the treatment container 58 while a packing 53 formed from an elastic member is provided therebetween.
- the lid 59 has a predetermined height, and is fastened to the treatment container 58 by four screws 54 passing through-holes (not shown).
- the treatment container 48 is provided with an inlet port 102 a through which treatment target water flows into the treatment container 48 from outside, and the lid 49 is provided with an outlet port 102 b through which treatment target water flows to outside from inside of the treatment container 48 .
- the pair of collectors 282 a , 282 b are placed with the disk-shaped separator 212 therebetween, and the cylindrical first granular electrode member 182 and the cylindrical second granular electrode member 192 are placed between the separator 212 and the collectors 282 a , 282 b .
- the pair of collectors 282 a , 282 b are formed in a disk shape, and have terminals 55 a , 55 b protruding on the side surfaces thereof.
- the first granular electrode member 182 and the second granular electrode member 192 are not made into a sheet form or the like, and are provided in the treatment container 48 in a state in which the granules are not fixed to each other.
- the first granular electrode member 182 and the second granular electrode member 192 are each configured to include a plurality of flowable granular electrode members.
- the thicknesses of the first granular electrode member 182 and the second granular electrode member 192 are not prescribed, and the thicknesses of the first granular electrode member 182 and the second granular electrode member 192 can be changed by change of the amount of the conductive materials, whereby desalination performance can be adjusted.
- a pressing portion 57 which comes into contact with the upper surface of the collector 282 a is formed at the lid 59 .
- the pressing portion 57 presses the first granular electrode member 182 and the second granular electrode member 192 via the collector 282 a , by the lid 59 being fastened to the treatment container 58 by the four screws 54 .
- the granules of the first granular electrode member 182 and the second granular electrode member 192 are fixed and thus no longer flow.
- the granules of the first granular electrode member 182 and the second granular electrode member 192 are not fixed to each other and therefore can flow in a non-pressed state such as a state before the pressing and a state after the pressing is canceled.
- Terminals 551 a , 551 b are formed at the other ends of the terminal bars 56 a , 56 b , respectively.
- the terminal 551 a is connected to the plus side of a power supply (not shown), and the terminal 551 b is connected to the minus side of the power supply (not shown), whereby plus electricity and minus electricity are applied to the pair of collectors 282 a , 282 b , the first granular electrode member 182 , and the second granular electrode member 192 , and thus treatment target water is desalinated.
- the pressed state of the first granular electrode member 182 and the second granular electrode member 192 by the pressing portion 57 is kept.
- the thicknesses of the first granular electrode member and the second granular electrode member can be changed by change of the amount of conductive materials, whereby desalination performance can be adjusted.
- adjustment of desalination performance can be easily performed.
- the pressing portion 57 the first granular electrode member and the second granular electrode member are pressed in a direction in which they are sandwiched between the pair of collectors. Therefore, the pair of collectors, and the first granular electrode member and the second granular electrode member, can be brought into close contact with each other, whereby the electric resistance during desalination can be decreased.
- the above embodiments may be freely combined with each other, or each of the above embodiments may be modified or simplified as appropriate, whereby the present invention is applicable to water treatment for water purification, sewage, drainage, desalination, or the like.
- the present invention is also applicable to, for example, generation of sprinkling water, cooling water, production water, or washing water for air conditioners.
- the present invention can be used in combination with a water heater, a dishwasher, a laundry machine, a cold/hot water system, an electric water heater, or a humidifier, and also, can be used as a water purifier.
- the present invention can be used in combination with a device that needs desalinated water, or can be mounted thereto.
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Abstract
A water treatment apparatus includes: a first granular electrode member and a second granular electrode member stored in a water treatment unit and provided so as to be separated from each other; a power supply unit which applies voltage between the first granular electrode member and the second granular electrode member so that ions contained in treatment target water supplied from one side of the water treatment unit are adsorbed to the first granular electrode member and the second granular electrode member; and a washing water supply pump which causes washing water to flow from the other side of the water treatment unit to the one side of the water treatment unit, thereby washing the first granular electrode member and the second granular electrode member, wherein the first granular electrode member and the second granular electrode member each include a plurality of flowable granular electrode members.
Description
- The present invention relates to a water treatment apparatus and a water treatment method for treating treatment target water using an electrical double layer capacitor.
- Electric desalination technology using an electrical double layer capacitor is technology of adsorbing and removing ions contained in treatment target water such as sea water or contaminated water using a Coulomb force, thereby desalinating the treatment target water. In one example of conventional electric desalination, an electrical double layer capacitor having a flat-plate shape is configured such that activated carbon layers mainly formed from activated carbon having a high specific surface area are provided on both sides of a separator formed from an electrically-insulating porous liquid-permeable sheet, collector electrodes are provided on the outer sides of the activated carbon layers, and holder plates are provided on the outer sides of the collector electrodes. Then, while a liquid containing an ionic substance is passed through the electrical double layer capacitor, application of DC low voltage to the collector electrodes and short-circuit or reverse connection between both collector electrodes are repeated alternately (see, for example, Patent Document 1).
- As another example, in an electrical double layer capacitor for performing desalination, ozone is generated from treatment water before desalination, and treatment target water is sterilized by the ozone, thereby preventing generation of biofilm on the surfaces of electrodes, and the polarities of the electrodes are changed alternately during operation, thereby decomposing and dissolving biofilm and/or scale that has been already generated on the surfaces of the electrodes and thus removing the biofilm and/or scale (see, for example, Patent Document 2).
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- Patent Document 1: Japanese Patent No. 3302443
- Patent Document 2: Japanese Laid-Open Patent Publication No. 2009-190016
- However, merely alternately repeating application and short-circuit/reverse connection between both collector electrodes as in
Patent Document 1 cannot prevent reduction in desalination efficiency due to biofilm or scale adhered to the surfaces of the electrodes while desalination is performed. In addition, performing only sterilization by ozone and alternate change of the polarities of the electrodes as inPatent Document 2 can remove biofilm and/or scale to a certain extent, but cannot remove biofilm and/or scale strongly adhered or fixed to the surfaces of the electrodes, and there is a possibility that such biofilm and/or scale remains on the surfaces of the electrodes. - The present invention has been made to solve the above problems, and an object of the present invention is to obtain a water treatment apparatus and a water treatment method that are capable of more reliably removing biofilm and/or scale adhered to the surfaces of electrodes.
- A water treatment apparatus according to the present invention includes: a first electrode and a second electrode stored in a water treatment unit and provided so as to be separated from each other by a separator; a power supply unit which applies voltage between the first electrode and the second electrode so that ions contained in treatment target water supplied from one side of the water treatment unit are adsorbed to the first electrode and the second electrode, thereby performing desalination and generating desalinated water; and a washing water supply pump which causes washing water to flow from the other side of the water treatment unit to the one side of the water treatment unit, thereby washing the first electrode and the second electrode, wherein the first electrode and the second electrode each include a plurality of flowable granular electrode members.
- In the present invention, the first electrode and the second electrode for adsorbing and removing ions contained in treatment target water each include a plurality of flowable granular electrode members, and thus it is possible to further reliably remove biofilm and/or scale adhered to the surfaces of the electrodes.
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FIG. 1 is a configuration diagram of a water treatment apparatus according toembodiment 1 of the present invention. -
FIG. 2 is a flowchart showing a water treatment method according toembodiment 1 of the present invention. -
FIG. 3 shows other examples of a water treatment unit according toembodiment 1. -
FIG. 4 is a configuration diagram of a water treatment apparatus according toembodiment 2 of the present invention. -
FIG. 5 is a flowchart illustrating a reverse washing step in a water treatment method according toembodiment 2 of the present invention. -
FIG. 6 is a configuration diagram of a water treatment apparatus according toembodiment 3 of the present invention. -
FIG. 7 is a configuration diagram of a water treatment apparatus according toembodiment 4 of the present invention. -
FIG. 8 is a configuration diagram of a water treatment apparatus according toembodiment 5 of the present invention. -
FIG. 9 is a configuration diagram of a water treatment apparatus according toembodiment 6 of the present invention. -
FIG. 10 is a configuration diagram of a water treatment apparatus according toembodiment 7 of the present invention. -
FIG. 11 is a configuration diagram of a water treatment apparatus according toembodiment 8 of the present invention. -
FIG. 12 is a configuration diagram of a water treatment apparatus according toembodiment 9 of the present invention. -
FIG. 13 is a perspective view showing a water treatment unit according toembodiment 16 of the present invention. -
FIG. 14 is a top view showing the water treatment unit according toembodiment 16 of the present invention. -
FIG. 15 is a sectional view along P-P line inFIG. 14 . -
FIG. 16 is a sectional view along Q-Q line inFIG. 14 . -
FIG. 17 is a perspective view showing a water treatment unit according toembodiment 17 of the present invention. - Hereinafter, with reference to the accompanying drawings, embodiments of a water treatment apparatus and a water treatment method disclosed in the present application will be described in detail. It is noted that the embodiments shown below are merely examples and the present invention is not limited to these embodiments. It is noted that, hereinafter, “treatment target water” refers to raw water that has not undergone desalination yet, and “desalinated water” refers to treatment target water that has been desalinated.
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FIG. 1 is a configuration diagram of a water treatment apparatus according toembodiment 1 of the present invention. Awater treatment apparatus 100 includes: awater treatment unit 1 having aninlet port 1 a through which treatment target water flows in, anoutlet port 1 b through which desalinated water flows out, and a washingwater inlet port 1 c through which washing water or additive containing washing water flows in at the time of reverse washing, thewater treatment unit 1 being configured to perform desalination for the treatment target water; araw water tank 2 which is connected to thewater treatment unit 1 via a treatment targetwater measurement unit 11, a treatment targetwater supply valve 5, and then a treatment targetwater supply pump 3, and which stores treatment target water; a treatedwater tank 15 which is connected to thewater treatment unit 1 via a desalinatedwater measurement unit 12 and then a desalinatedwater sending valve 7 and which stores treatment target water that has been desalinated by thewater treatment unit 1; and a reversewashing water tank 17 which is connected to thewater treatment unit 1 via the desalinatedwater measurement unit 12 and then a desalinatedwater sending valve 8 and which stores washing water for reverse washing. In thewater treatment unit 1, theinlet port 1 a is provided on one side of thewater treatment unit 1, and theoutlet port 1 b and the washingwater inlet port 1 c are provided on the other side of thewater treatment unit 1. - The reverse
washing water tank 17 is connected to thewater treatment unit 1 also through a route passing a washingwater supply pump 4 for supplying washing water to thewater treatment unit 1 at the time of reverse washing, a washingwater supply valve 9, and then a washingwater measurement unit 13. The reversewashing water tank 17, the washingwater supply pump 4, and the washingwater supply valve 9 are configured to be capable of supplying washing water to thewater treatment unit 1 in a direction opposite to the flow direction of the treatment target water. Inembodiment 1, a combination of the reversewashing water tank 17, the washingwater supply pump 4, and the washingwater supply valve 9 serves as a “supply unit”. - Washing water supplied to the
water treatment unit 1 can be drained from thewater treatment unit 1 via the treatment targetwater measurement unit 11 and then adrain valve 6. The reversewashing water tank 17 is connected to anadditive storage tank 16 via anadditive supply valve 10 and then anadditive supply pump 37. The reversewashing water tank 17 is provided with astirrer 36 for stirring and mixing an additive and washing water when the additive is supplied. Washing water in the reversewashing water tank 17 can be drained via thedrain valve 29. Inembodiment 1, a combination of theadditive storage tank 16, theadditive supply pump 37, and theadditive supply valve 10 serves as an “additive supply unit”. The additive stored in theadditive storage tank 16 contains a substance such as an oxidizing agent, an acid, or an alkali having a property of decomposing biofilm and/or scale. - In the
water treatment unit 1, a pair ofcollectors power supply unit 20 are provided at both ends, and between thecollectors granular electrode member 18, i.e., a first electrode, and a secondgranular electrode member 19, i.e., a second electrode are provided so as to be opposed to each other and separated from each other by aseparator 21. The firstgranular electrode member 18 and the secondgranular electrode member 19 each include a plurality of granular electrode members. The firstgranular electrode members 18 or the secondgranular electrode members 19 are in contact with each other, but the firstgranular electrode member 18 and the secondgranular electrode member 19 are prevented from coming into contact with each other, by theseparator 21. - The pair of
collectors granular electrode member 18 and the secondgranular electrode member 19 at the time of charging, and collecting electricity from the firstgranular electrode member 18 and the secondgranular electrode member 19 at the time of discharging, and the pair ofcollectors granular electrode member 18 and the secondgranular electrode member 19, respectively. The pair ofcollectors - The first
granular electrode member 18 and the secondgranular electrode member 19 serve to adsorb ions in the treatment target water when voltage is applied. Therefore, the firstgranular electrode member 18 and the secondgranular electrode member 19 are made from activated carbon, porous carbon, porous conductive beads, porous metal, or the like having a great conductivity and a great specific surface area and having a great capacitance as a capacitor. The granular electrode members included in the firstgranular electrode member 18 and the secondgranular electrode member 19 in the present embodiment are not made into a sheet form or the like, and are provided in thewater treatment unit 1 in a state in which the granules are not fixed to each other. That is, the firstgranular electrode member 18 and the secondgranular electrode member 19 are each configured to include a plurality of flowable granular electrode members. - The
separator 21 is provided for preventing short-circuit between the firstgranular electrode member 18 and the secondgranular electrode member 19, and is made from filter paper, a porous film, nonwoven fabric, a foamed material, or the like through which a liquid easily passes and which has an electric insulation property. - As the treatment target
water measurement unit 11, the desalinatedwater measurement unit 12, and the washingwater measurement unit 13 connected to thewater treatment unit 1, for example, an electric conductivity meter or the like that is capable of measuring the electric conductivity or electric resistance of a liquid and capable of outputting a result of the measurement as a signal, is used. - The treatment target
water supply pump 3, the washingwater supply pump 4, theadditive supply pump 37, the treatment targetwater measurement unit 11, the desalinatedwater measurement unit 12, the washingwater measurement unit 13, the treatment targetwater supply valve 5, thedrain valves water sending valves water supply valve 9, theadditive supply valve 10, and thepower supply unit 20 are connected to acontrol unit 14, and are controlled by thecontrol unit 14 during execution of each processing step. As thecontrol unit 14, a programmable logic controller (PLC), a sequencer, a numerical control device, or the like for operating a device in accordance with a specified condition, is used. - Next, operation will be described. In the water treatment method according to the present embodiment, while a cycle of desalination of treatment target water in the
water treatment unit 1 and washing of thewater treatment unit 1 is repeated, desalination of the treatment target water is sequentially performed, and as described later, washing of thewater treatment unit 1 includes two washing methods, i.e., reverse washing and addition reverse washing. -
FIG. 2 is a flowchart showing the water treatment method according toembodiment 1. After thewater treatment apparatus 100 is activated, a “desalination step” is executed in which treatment target water is desalinated using thewater treatment unit 1, and the desalinated water is stored into the reversewashing water tank 17 and the treated water tank 15 (step ST1). After the desalination step is finished, “washing method execution control” is performed for determining whether to execute a “reverse washing step” of performing reverse washing in which thewater treatment unit 1 is washed by injecting washing water into thewater treatment unit 1 in the direction opposite to the treatment target water flow-in direction, or an “addition reverse washing step” of washing thewater treatment unit 1 by injecting additive containing washing water or an additive into thewater treatment unit 1 in the direction opposite to the treatment target water flow-in direction (step ST2). As a result of the washing method execution control in step ST2, if the reverse washing step is determined to be executed, the process proceeds to step ST3, and if the addition reverse washing step is determined to be executed, the process proceeds to step ST4. - After washing of the
water treatment unit 1 in the reverse washing step (step ST3) or washing of thewater treatment unit 1 in the addition reverse washing step (step ST4) is finished, the process returns to step ST1 to execute the desalination step. Thereafter, the same cycle is repeated. Hereinafter, the “desalination step”, the “reverse washing step”, the “addition reverse washing step”, and the “washing method execution control” will be described in detail. - <Desalination Step>
- In the desalination step, first, the treatment target
water supply valve 5 is opened, and thedrain valve 6 is closed. Next, the treatment targetwater supply pump 3 is activated to send treatment target water in theraw water tank 2 so as to be supplied to thewater treatment unit 1. The treatment target water is supplied through theupper inlet port 1 a of thewater treatment unit 1 into thewater treatment unit 1, and then flows downward. In addition, DC voltage is applied to the pair ofcollectors power supply unit 20. As described above, the pair ofcollectors granular electrode member 18 and the secondgranular electrode member 19, and therefore DC voltage is applied also between the firstgranular electrode member 18 and the secondgranular electrode member 19, and the firstgranular electrode member 18 and the secondgranular electrode member 19 are attracted by a Coulomb force so as to be in contact with the pair ofcollectors granular electrode member 18 and the secondgranular electrode member 19 is maintained, and ions contained in the treatment target water flowing in thewater treatment unit 1 are adsorbed and removed by a Coulomb force to the firstgranular electrode member 18 and the secondgranular electrode member 19, whereby the treatment target water is desalinated. The desalinated treatment target water is discharged as desalinated water through thelower outlet port 1 b of thewater treatment unit 1. - While the desalination is being performed as described above, until a prescribed amount of the water is stored in the reverse
washing water tank 17, the desalinatedwater sending valve 7 is closed and the desalinatedwater sending valve 8 is opened so that the treatment target water that has undergone the desalination is sent and stored into the reversewashing water tank 17. The desalinated water stored in the reversewashing water tank 17 is used as washing water in the reverse washing step or the addition reverse washing step. When the prescribed amount of the water is stored in the reversewashing water tank 17, the desalinatedwater sending valve 8 is closed and the desalinatedwater sending valve 7 is opened so that the treatment target water that has undergone the desalination is sent to the treatedwater tank 15. After a predetermined time has elapsed since the start of the desalination step, the treatment targetwater supply pump 3 is stopped and the treatment targetwater supply valve 5 and the desalinatedwater sending valve 7 are closed. In addition, application of DC voltage by thepower supply unit 20 is stopped, whereby the desalination step is finished. In the desalination step of the present embodiment, theinlet port 1 a and theoutlet port 1 b are provided so that treatment target water flows downward in thewater treatment unit 1. However, theinlet port 1 a and theoutlet port 1 b may be provided so that treatment target water flows upward or in the horizontal direction in thewater treatment unit 1. - The time period during which the desalination step is executed is 3 to 200 minutes, or desirably, 5 to 50 minutes. If the time period is shorter than 3 minutes, the frequency of switching between desalination and washing increases and thus efficiency in the entire cycle is reduced. On the other hand, if the time period is longer than 200 minutes, ions are adsorbed into a deep part of each granular electrode member and the ions are less likely to be desorbed. As a result, a time period taken for washing is prolonged. Therefore, 5 to 50 minutes are desirable from the perspective of the frequency of switching between desalination and washing and ease of desorption of the adsorbed ions.
- <Washing Method Execution Control>
- After the desalination step is finished, the
control unit 14 executes execution control to determine whether to execute the reverse washing step or the addition reverse washing step, using an ion removal rate in thewater treatment unit 1 as a determination index. Here, the “ion removal rate” is a value obtained by dividing the difference between the electric conductivity of treatment target water and the electric conductivity of desalinated water by the electric conductivity of the treatment target water and then converting the result into percentage, and thus indicates the height of desalination efficiency in thewater treatment unit 1. - First, the
control unit 14 acquires the electric conductivity of the treatment target water and the electric conductivity of the desalinated water from the treatment targetwater measurement unit 11 and the desalinatedwater measurement unit 12, to calculate the present ion removal rate in thewater treatment unit 1, and stores the ion removal rate into a storage unit (not shown). Next, thecontrol unit 14 reads, from the storage unit (not shown), the greater one (hereinafter, referred to as “reference ion removal rate”) of the ion removal rate at the time when the first-time desalination step is finished after thewater treatment apparatus 100 has been activated, and the ion removal rate at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed, and compares the reference ion removal rate with the present ion removal rate. If the present ion removal rate is smaller than 0.5 to 1.0 times, or desirably, smaller than 0.7 to 0.9 times the reference ion removal rate, the ion removal rate has been reduced due to biofilm and/or scale, and therefore thecontrol unit 14 determines to execute the addition reverse washing step. If the present ion removal rate is equal to or greater than 1.0 times the reference ion removal rate, or desirably, equal to or greater than 0.9 times the reference ion removal rate, the ion removal rate in thewater treatment unit 1 has not been reduced or has been slightly reduced and thus it is not necessary to execute the addition reverse washing. Therefore, thecontrol unit 14 determines to execute the reverse washing step. If the present ion removal rate is smaller than 0.5 times the reference ion removal rate, or desirably, smaller than 0.7 times the reference ion removal rate, the ion removal rate has been significantly reduced and therefore thecontrol unit 14 determines that it is difficult to restore the ion removal rate by the addition reverse washing step. In such a case, for example, thecontrol unit 14 causes a display unit (not shown) to display an alarm indication for notification that it is necessary to replace the firstgranular electrode member 18 and the secondgranular electrode member 19, thereby prompting a user to replace the firstgranular electrode member 18 and the secondgranular electrode member 19. - <Reverse Washing Step>
- In the reverse washing step, first, in a state in which the
drain valve 6 and the washingwater supply valve 9 are opened and the treatment targetwater supply valve 5 is closed, the washingwater supply pump 4 is activated to inject the washing water in the reversewashing water tank 17 into thewater treatment unit 1 in a direction from the lower washingwater inlet port 1 c to theupper inlet port 1 a of thewater treatment unit 1, i.e., the direction opposite to the flow of the treatment target water. The washing water injected into thewater treatment unit 1 flows upward and flows out through theinlet port 1 a to the upper side of thewater treatment unit 1, and thereafter, is drained through thedrain valve 6. - In the reverse washing step, DC voltage is not applied to the pair of
collectors granular electrode member 18 and the secondgranular electrode member 19 are not attracted to the pair ofcollectors granular electrode member 18 and the secondgranular electrode member 19, the firstgranular electrode member 18 and the secondgranular electrode member 19 do not adsorb ions in the washing water and therefore scale is not newly generated. In addition, a phenomenon in which microorganisms and the like in the washing water are attracted to newly generate biofilm, does not occur. - Biofilm and/or scale that has been already adhered to the surfaces of the first
granular electrode member 18 and the second granular electrode member are removed by a shear force acting on the surfaces of the granular electrode members owing to the flow of the washing water. In some cases, biofilm and/or scale is strongly adhered or fixed to the surfaces of the granular electrode members, and it might be difficult to remove the biofilm and/or scale merely by the washing water flowing on the surfaces of the granular electrode members. However, as described above, the firstgranular electrode member 18 and the secondgranular electrode member 19 in the present embodiment are provided in thewater treatment unit 1 such that the granules are not fixed to each other. Therefore, by the flow of the washing water, the firstgranular electrode member 18 and the secondgranular electrode member 19 also flow. Thus, as the washing water flows, contact or collision occurs between the granular electrode members, whereby biofilm, scale, and the like that are strongly adhered or fixed to the surfaces of the granular electrode members can be removed by being torn off by a physical force. - During execution of the reverse washing step, the electric conductivity of the washing water before injection into the
water treatment unit 1 is measured by the washingwater measurement unit 13 and the electric conductivity of the washing water after passing through thewater treatment unit 1 is measured by the treatment targetwater measurement unit 11, and then a result of the measurement by the treatment targetwater measurement unit 11 is compared with a result of the measurement by the washingwater measurement unit 13. In the case where the result of measurement by the treatment targetwater measurement unit 11 is 1 to 1.5 times, or desirably, 1 to 1.2 times the result of measurement by the washingwater measurement unit 13, it is considered that washing has been sufficiently performed, and therefore the washingwater supply pump 4 is stopped and the washingwater supply valve 9 is closed, to finish the reverse washing step. In the case where the result of measurement by the treatment targetwater measurement unit 11 is greater than 1.5 times the result of measurement by the washingwater measurement unit 13, biofilm and/or scale still remains in thewater treatment unit 1 and the washing is insufficient, and therefore the reverse washing step is continued. It is noted that, in the reverse washing step, since DC voltage is not applied to the pair ofcollectors granular electrode member 18 and the secondgranular electrode member 19 by thepower supply unit 20, a phenomenon in which ions contained in the washing water injected into thewater treatment unit 1 are adsorbed and removed to the firstgranular electrode member 18 and the secondgranular electrode member 19 and the electric conductivity of the washing water is reduced, does not occur. Therefore, the result of measurement by the treatment targetwater measurement unit 11 does not become smaller than 1 times the result of measurement by the washingwater measurement unit 13. - As described above, the washing water used in the reverse washing step is water obtained by storing the desalinated water generated in the desalination step, into the reverse
washing water tank 17. Therefore, in the case where the amount of necessary washing water is large, the prescribed amount of desalinated water to be stored into the reversewashing water tank 17 also increases, and the desalinated water stored into the treatedwater tank 15 decreases, leading to reduction in the recovery rate for the desalinated water. On the other hand, if each electrode member expands and the surface area thereof increases, the contact area thereof with the washing water increases and contact and collision between the electrode members become more likely to occur. Therefore, from the perspective of effective physical washing, it is desirable that a certain degree of expansion occurs. Accordingly, from the perspective of balance between the recovery rate for the treated water and effective physical washing, the expansion rate of the firstgranular electrode member 18 and the secondgranular electrode member 19 in the reverse washing step are set to 0 to 200%, or desirably, 20 to 50%. Here, the “expansion rate” indicates the percentage by which the volume of the firstgranular electrode member 18 and the secondgranular electrode member 19 in the washing step has increased as compared to the volume at the time of the desalination step. When expansion does not occur, i.e., when the volume does not differ from the volume at the time of the desalination step, the expansion rate is 0%. The expansion rate is determined by the flow rate of the washing water, and therefore it is possible to set the expansion rate to a desired value by thecontrol unit 14 controlling the flow rate of the washing water. - <Addition Reverse Washing Step>
- In the addition reverse washing step, first, the
additive supply valve 10 is opened and theadditive supply pump 37 is activated to add a predetermined amount of additive to the washing water in the reversewashing water tank 17 from theadditive storage tank 16. Next, thestirrer 36 stirs and mixes the additive and the washing water to generate additive containing washing water. In the case where the additive is hydrogen peroxide, the additive is added to the reversewashing water tank 17 so that the hydrogen peroxide concentration in the reversewashing water tank 17 becomes 0.0001 to 5%, or desirably, 0.001 to 1%. If the hydrogen peroxide concentration in the reversewashing water tank 17 is smaller than 0.0001%, the hydrogen peroxide concentration is too low so that, when the additive containing washing water is injected into thewater treatment unit 1, the hydrogen peroxide is consumed before being distributed over the entirety of the firstgranular electrode member 18 and the secondgranular electrode member 19, and therefore the washing effect is small. On the other hand, if the hydrogen peroxide concentration is greater than 5%, foaming by reaction with the firstgranular electrode member 18 and the secondgranular electrode member 19 occurs vigorously, so that bubbles remain in pores of the activated carbon. The bubbles remaining in pores of the activated carbon hampers ion adsorption in the desalination step, thus deteriorating efficiency of the desalination. - Next, in a state in which the
drain valve 6 and the washingwater supply valve 9 are opened and the treatment targetwater supply valve 5 is closed, the washingwater supply pump 4 is activated to inject the additive containing washing water in the reversewashing water tank 17 into thewater treatment unit 1 in a direction from the lower washingwater inlet port 1 c to theupper inlet port 1 a of thewater treatment unit 1, i.e., the direction opposite to the flow of the treatment target water. The additive containing washing water injected into thewater treatment unit 1 flows upward and flows out through theinlet port 1 a to the upper side of thewater treatment unit 1, and thereafter, is drained through thedrain valve 6. - Also in the addition reverse washing step, as in the case of the reverse washing step, biofilm and/or scale that has been already adhered to the surfaces of the first
granular electrode member 18 and the secondgranular electrode member 19 is removed by a shear force acting on the surfaces of the granular electrode members owing to the flow of the additive containing washing water. In addition, regarding the firstgranular electrode member 18 and the secondgranular electrode member 19 in the present embodiment, by the flow of the additive containing washing water, the firstgranular electrode member 18 and the secondgranular electrode member 19 also flow. Therefore, the additive containing washing water spreads over the entirety of the firstgranular electrode member 18 and the secondgranular electrode member 19, and thus biofilm, scale, and the like adhered to the surfaces of the granular electrode members can be uniformly removed. - In the addition reverse washing step, the flow rate of the additive containing washing water is controlled by the
control unit 14 so that the expansion rate of the firstgranular electrode member 18 and the secondgranular electrode member 19 is 10 to 200%, or desirably, 10 to 100%. If the expansion rate is greater than 200%, the amount of necessary washing water becomes too large, and the prescribed amount of desalinated water to be stored into the reversewashing water tank 17 in the desalination step increases. As a result, the desalinated water stored into the treatedwater tank 15 decreases, leading to reduction in the recovery rate for the desalinated water. It is noted that, in the reverse washing step, a value of 0 to 10% is also possible for the expansion rate, but in the addition reverse washing step, in the case where the expansion rate is smaller than 10%, expansion of the firstgranular electrode member 18 and the secondgranular electrode member 19 is small and therefore physical washing of the surfaces of the granular electrode members cannot be performed effectively. - After the additive containing washing water the amount of which is 2 to 10 times, or desirably, 3 to 5 times the volume of the first
granular electrode member 18 and the secondgranular electrode member 19 is injected into thewater treatment unit 1, the washingwater supply pump 4 is stopped and the washingwater supply valve 9 is closed. If the amount of the additive containing washing water injected into thewater treatment unit 1 is smaller than 2 times the volume of the firstgranular electrode member 18 and the secondgranular electrode member 19, the additive is not sufficiently distributed to the surfaces of the granular electrode members and therefore biofilm and/or scale adhered to the surfaces of the granular electrode members is not completely decomposed and removed. On the other hand, if the amount of the additive containing washing water injected into thewater treatment unit 1 is larger than 10 times the volume of the firstgranular electrode member 18 and the secondgranular electrode member 19, the prescribed amount of desalinated water to be stored into the reversewashing water tank 17 in the desalination step increases. As a result, the desalinated water stored into the treatedwater tank 15 decreases, leading to reduction in the recovery rate for the desalinated water. - Next, in a state in which the desalinated
water sending valve 7 is closed, the treatment targetwater supply valve 5, the desalinatedwater sending valve 8, and thedrain valve 29 are opened, and the treatment targetwater supply pump 3 is activated to send the treatment target water from theraw water tank 2 to thewater treatment unit 1, so that the additive containing washing water remaining in thewater treatment unit 1 is caused to flow out and is drained from the reversewashing water tank 17 through thedrain valve 29. After the flowing-out of the additive containing washing water is finished, the treatment targetwater supply pump 3 is stopped, and the treatment targetwater supply valve 5 and thedrain valve 29 are closed, to finish the addition reverse washing step. The amount of treatment target water used for causing the additive containing washing water to flow out from thewater treatment unit 1 is 1 to 10 times, or desirably, 2 to 5 times the volume of the firstgranular electrode member 18 and the secondgranular electrode member 19. If the amount of treatment target water used for causing the additive containing washing water to flow out is smaller than 1 times the volume of the firstgranular electrode member 18 and the secondgranular electrode member 19, it is impossible to cause the entire additive containing washing water to flow out from thewater treatment unit 1. On the other hand, if the amount of treatment target water is larger than 10 times the volume of the firstgranular electrode member 18 and the secondgranular electrode member 19, the amount of treatment target water used for causing the additive containing washing water to flow out increases, so that the recovery rate for the desalinated water is reduced. In addition, a time period required for causing the additive containing washing water to flow out is prolonged and thus a time period taken for the addition reverse washing step is also prolonged, whereby efficiency of the entire cycle is reduced. - It is noted that, in the case where, in light of the property of the desalinated water, there is no adverse effect even if the additive remains in the
water treatment unit 1, the operation of causing the additive containing washing water to flow out from thewater treatment unit 1 may be omitted. - In
FIG. 1 , an example in which theinlet port 1 a is provided on one side of thewater treatment unit 1, and theoutlet port 1 b and the washingwater inlet port 1 c are provided on the other side of thewater treatment unit 1, has been shown. However, thewater treatment unit 1 may be configured as shown in other examples inFIG. 3 . In the example shown inFIG. 3(a) , theinlet port 1 a and the washingwater inlet port 1 c are provided on one side of thewater treatment unit 1, and theoutlet port 1 b and a washingwater outlet port 1 d are provided on the other side of thewater treatment unit 1. A second washingwater measurement unit 131 for measuring the electric conductivity or the like of washing water having flowed through thewater treatment unit 1, is provided to a pipe connected to the washingwater outlet port 1 d. After the electric conductivity is measured by the second washingwater measurement unit 131, the washing water is discharged to outside of the system. In the example inFIG. 3(a) , in the reverse washing step and the addition reverse washing step, whether or not washing has been sufficiently performed is determined through comparison between a result of measurement by the washingwater measurement unit 13 and a result of measurement by the second washingwater measurement unit 131. - In the example in
FIG. 3(a) , the flow direction of the washing water in the reverse washing step and the flow direction of the additive containing washing water in the addition reverse washing step are the same as the flow direction of the treatment target water in the desalination step. In the case where the flow direction of the washing water and the flow direction of the additive containing washing water are opposite to the flow direction of the treatment target water, as described above, the expansion rate of the firstgranular electrode member 18 and the secondgranular electrode member 19 in the addition reverse washing step needs to be equal to or greater than 10%. However, in the case where the flow direction of the washing water and the flow direction of the additive containing washing water are the same as the flow direction of the treatment target water, the expansion rate of the firstgranular electrode member 18 and the secondgranular electrode member 19 in the addition reverse washing step may be 0%. Thus, there is an advantage that the amounts of washing water and additive containing washing water needed for washing are decreased. As shown in the example inFIG. 3(b) , the washingwater outlet port 1 d may be connected to the treatment targetwater measurement unit 11, whereby the second washingwater measurement unit 131 may be omitted. Although not shown, the washingwater outlet port 1 d may be connected to the desalinatedwater measurement unit 12, and also in this case, the second washingwater measurement unit 131 may be omitted. - As shown in the examples in
FIG. 3(c) andFIG. 3(d) , the washingwater inlet port 1 c and the washingwater outlet port 1 d may be provided to thecollector 28 a and thecollector 28 b. Also in this case, as shown in the example inFIG. 3(c) , the second washingwater measurement unit 131 may be provided to a pipe connected to the washingwater outlet port 1 d, or as shown in the example inFIG. 3(d) , the washingwater outlet port 1 d may be connected to the treatment targetwater measurement unit 11, whereby the second washingwater measurement unit 131 may be omitted. Although not shown, the washingwater outlet port 1 d may be connected to the desalinatedwater measurement unit 12, and also in this case, the second washingwater measurement unit 131 may be omitted. Also in the example inFIG. 3(d) , the expansion rate of the firstgranular electrode member 18 and the secondgranular electrode member 19 in the addition reverse washing step may be 0%. - The configurations of the water treatment units shown in
FIG. 3(a) toFIG. 3(d) are applicable also inembodiment 2 and the subsequent embodiments. - Hereinafter, the present invention will be further described using examples. In the examples, water obtained by filtering urban sewage water having electric conductivity of 2 mS/cm and DOC of 10 mg/L was used as treatment target water. Granular activated carbon was used as the first
granular electrode member 18 and the secondgranular electrode member 19, and the amount of the activated carbon is 10 L. The flow speed of the treatment target water in the desalination step was 0.1 m/min, and the flow speeds of the washing water in the reverse washing step and the additive containing washing water in the addition reverse washing step were 0.5 m/min. A hydrogen peroxide solution was used as the additive, and the hydrogen peroxide concentration in the additive containing washing water was 1%. - Under the above condition of the treatment target water, the activated carbon amount, and the flow speed, the desalination step and the reverse washing step were executed for eight cycles. In example 1, the addition reverse washing step was not executed. As a result of inspection in example 1, the following table 1 was obtained.
-
TABLE 1 First Second Third Fourth Fifth Sixth Seventh Eighth Cycle time time time time time time time time Ion removal rate (%) 70 66 61 60 58 56 53 52 when desalination step was finished Reduction width (%) of — 4 9 10 12 14 17 18 ion removal rate from when first-time desalination step was finished - Under the above condition of the treatment target water, the activated carbon amount, and the flow speed, the desalination step and the reverse washing step or the addition reverse washing step were executed for eight cycles. A condition for executing the addition reverse washing step was as follows. In the case where the ion removal rate at the time when the desalination step was finished had been reduced by 5% or more as compared to the ion removal rate at the time when the first-time desalination step was finished after the
water treatment apparatus 100 was activated or the ion removal rate at the time when the first-time desalination step was finished after the previous addition reverse washing step was executed, the addition reverse washing step was executed after the desalination step. In the case where the above condition was not satisfied, the reverse washing step was executed. On the basis of the above condition for executing the addition reverse washing step, in example 2, the addition reverse washing step was executed after the desalination step was finished for the third time and the sixth time. As a result of inspection in example 2, the following table 2 was obtained. -
TABLE 2 First Second Third Fourth Fifth Sixth Seventh Eighth Cycle time time time time time time time time Ion removal rate (%) when 70 66 61 68 65 60 67 63 desalination step was finished Reduction width (%) of — 4 9 — 3 8 — 4 ion removal rate from when first-time desalination step was finished or when first- time desalination step was finished after addition reverse washing step Whether or not addition No No Yes No No Yes No No reverse washing step was performed - Under the above condition of the treatment target water, the activated carbon amount, and the flow speed, the desalination step was executed for eight cycles, and the reverse washing step and the addition reverse washing step were not executed. As a result of inspection in comparative example 1, the following table 3 was obtained.
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TABLE 3 First Second Third Fourth Fifth Sixth Seventh Eighth Cycle time time time time time time time time Ion removal rate (%) 70 66 61 55 49 44 38 35 when desalination step was finished Reduction width (%) of — 4 9 15 21 26 32 35 ion removal rate from when first-time desalination step was finished - The above results of examples 1, 2 and comparative example 1 are collectively shown in Table 4. As shown in table 4, in example 1 and comparative example 1, the ion removal rate is reduced as the number of times of execution increases, but in comparison between example 1 and comparative example 1, the ion removal rate is sharply reduced in the fourth and subsequent cycles in comparative example 1, whereas the ion removal rate is maintained at high level even in the fourth and subsequent cycles in example 1. Thus, it is found that biofilm and/or scale which is adhered to the electrode members and hampers desalination is removed through execution of the reverse washing step of the present embodiment, whereby reduction in the ion removal rate is suppressed and thus the ion removal rate can be maintained at high level. In addition, in example 2, the ion removal rate is restored at regular intervals. Thus, it is found that biofilm and/or scale that is more strongly adhered to the electrode members and cannot be fully removed by only the reverse washing step can be uniformly removed through execution of the addition reverse washing step, whereby the ion removal rate can be stably maintained at further high level.
-
TABLE 4 First Second Third Fourth Fifth Sixth Seventh Eighth Cycle time time time time time time time time Ion removal rate (%) in 70 66 61 60 58 56 53 52 example 1 Ion removal rate (%) in 70 66 61 68 65 60 67 63 example 2 Ion removal rate (%) in 70 66 61 55 49 44 38 35 comparative example 1 - In
embodiment 1, since the plurality of granular electrodes included in the first granular electrode member and the second granular electrode member are each flowable in the reverse washing step and the addition reverse washing step, washing of the granular electrode members is performed while each granular electrode member is caused to flow by the washing water or the additive containing washing water flowing therethrough. Thus, it is possible to more reliably remove biofilm, scale, and the like strongly adhered or fixed to the electrode surfaces of the granular electrode members, and uniformly wash the entire electrode members. - In addition, by performing reverse washing using additive containing washing water in which an additive having a property of decomposing biofilm and/or scale is contained in washing water, it is possible to more reliably remove biofilm and/or scale that cannot be fully removed by only the reverse washing step.
- In addition, the control unit compares the present ion removal rate with a reference ion removal rate which is the greater one of the ion removal rate at the time when the first-time desalination step is finished and the ion removal rate at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed. Then, in the case where the present ion removal rate is smaller than 0.5 to 1.0 times the reference ion removal rate, the control unit performs control so as to execute reverse washing using washing water to which the additive is added. Thus, it becomes possible to efficiently and effectively execute washing and desalination, whereby the desalination can be performed stably and continuously.
- In addition, since desalinated water is used as washing water, it is not necessary to introduce washing water from outside or provide equipment for washing water, so that the equipment can be simplified and the drain amount of washing water can be reduced, and also, the amount of contaminated water can be reduced.
- Hereinafter,
embodiment 2 of the present invention will be described on the basis ofFIG. 4 andFIG. 5 . Parts that are the same as or correspond to those inFIG. 1 are denoted by the same reference characters, and the description thereof is omitted.Embodiment 2 is different fromembodiment 1 in that washing water or additive containing washing water is allowed to circulate.FIG. 4 is a configuration diagram of a water treatment apparatus according toembodiment 2 of the present invention. Awater treatment apparatus 200 includes: thewater treatment unit 1 which performs desalination for treatment target water; theraw water tank 2 which is connected to thewater treatment unit 1 via the treatment targetwater measurement unit 11, a three-way valve 22, and then the treatment targetwater supply pump 3, and which stores treatment target water; the treatedwater tank 15 which is connected to thewater treatment unit 1 via the desalinatedwater measurement unit 12 and then the desalinatedwater sending valve 7 and which stores treatment target water that has been desalinated by thewater treatment unit 1; and the reversewashing water tank 17 which is connected to thewater treatment unit 1 via the desalinatedwater measurement unit 12 and then a three-way valve 24 and which stores washing water for reverse washing. Washing water supplied to thewater treatment unit 1 can be drained from thewater treatment unit 1 via the treatment targetwater measurement unit 11 and then a three-way valve 23, and also, can circulate via the treatment targetwater measurement unit 11, the three-way valve 22, the three-way valve 23, the three-way valve 24, the washingwater supply pump 4, and then the washingwater measurement unit 13. In circulation of washing water, the washingwater supply pump 4 serves as a circulation pump. The three-way valve 22, the three-way valve 23, and the three-way valve 24 are connected to thecontrol unit 14, and are controlled by thecontrol unit 14 during execution of each step. - The other configurations are the same as in
embodiment 1 and therefore the description thereof is omitted. - Next, operation will be described. The operation is the same as in
embodiment 1 in that desalination of treatment target water is sequentially performed while a cycle of desalination of treatment target water in thewater treatment unit 1 and washing of thewater treatment unit 1 is repeated. Hereinafter, the “desalination step”, the “reverse washing step”, and the “addition reverse washing step” will be described in detail. The “washing method execution control” is the same as inembodiment 1 and therefore the description thereof is omitted. - <Desalination Step>
- In the desalination step, first, the three-
way valve 22 is opened in a direction from theraw water tank 2 to thewater treatment unit 1, and the three-way valve 23 is closed. Next, the treatment targetwater supply pump 3 is activated to send the treatment target water in theraw water tank 2 so as to be supplied to thewater treatment unit 1. The treatment target water is supplied through theupper inlet port 1 a of thewater treatment unit 1 into thewater treatment unit 1, and then flows downward. In addition, DC voltage is applied to the firstgranular electrode member 18 and the secondgranular electrode member 19 via the pair ofcollectors power supply unit 20, and ions contained in the treatment target water are adsorbed and removed by a Coulomb force to the firstgranular electrode member 18 and the secondgranular electrode member 19, whereby the treatment target water is desalinated. - The other matters are the same as in
embodiment 1. - <Reverse Washing Step>
- In the reverse washing step, first, in a state in which the three-
way valve 24 is opened in a direction from the reversewashing water tank 17 to the washingwater supply pump 4, the washingwater measurement unit 13, and thewater treatment unit 1, and the three-way valve 22 is opened in a direction from thewater treatment unit 1 to the three-way valve 23, the washingwater supply pump 4 is activated to inject washing water in the reversewashing water tank 17 into thewater treatment unit 1 in a direction from the lower washingwater inlet port 1 c to theupper inlet port 1 a of thewater treatment unit 1, i.e., the direction opposite to the flow of the treatment target water. At this time, until a predetermined amount of the washing water is stored in thewater treatment unit 1, the three-way valve 23 is opened in a direction from the three-way valve 22 to the drain side so that the washing water flowing out from theinlet port 1 a is drained. - After the predetermined amount of washing water is stored in the
water treatment unit 1, the three-way valve 23 is opened in a direction from the three-way valve 22 to the three-way valve 24, and the three-way valve 24 is opened in a direction from the three-way valve 23 to the washingwater measurement unit 13 and thewater treatment unit 1. Thus, a circulation path for the washing water is formed, and the washing water circulates by a driving force from the washingwater supply pump 4. - Washing of the
water treatment unit 1 by circulation of the washing water is performed as follows.FIG. 5 is a flowchart illustrating the reverse washing step in the water treatment method according toembodiment 2, and shows a processing flow after circulation of washing water is started. - While the washing water is circulated, the electric conductivity of the washing water before injection into the
water treatment unit 1 is measured by the washingwater measurement unit 13 and the electric conductivity of the washing water after passing through thewater treatment unit 1 is measured by the treatment targetwater measurement unit 11, and then a result of the measurement by the treatment targetwater measurement unit 11 is compared with a result of the measurement by the washingwater measurement unit 13 at the time of injection of the washing water. As a result of the comparison, if the result of the measurement by the treatment targetwater measurement unit 11 exceeds a predetermined multiple in a range of 1 to 5 times, or desirably, 1 to 3 times with respect to the result of the measurement by the washingwater measurement unit 13, the process proceeds to step ST03, and on the other hand, if this condition is not satisfied, the process proceeds to step ST02 to continue the circulation (step ST01). - If the condition is not satisfied in step ST01, that is, if the result of the measurement by the treatment target
water measurement unit 11 does not exceed the predetermined multiple of the result of the measurement by the washingwater measurement unit 13, the washing water is circulated as it is, to continue the reverse washing (step ST02). - If the condition is satisfied in step ST01, that is, if the result of the measurement by the treatment target
water measurement unit 11 is greater than the predetermined multiple of the result of the measurement by the washingwater measurement unit 13 at the time of injection of the washing water, the three-way valve 23 is switched to be opened in a direction from the three-way valve 22 to the drain side, to drain the circulating washing water (step ST03). - When voltage or current is not applied, the first
granular electrode member 18 and the secondgranular electrode member 19 do not adsorb ions. Therefore, in step ST01, the result of the measurement by the treatment targetwater measurement unit 11 does not become smaller than 1 times the result of the measurement by the washingwater measurement unit 13. On the other hand, if the result of the measurement by the treatment targetwater measurement unit 11 is greater than 5 times the result of the measurement by the washingwater measurement unit 13, the ion concentration in the washing water is close to saturation, so that the ions adsorbed to the firstgranular electrode member 18 and the secondgranular electrode member 19 are less likely to be desorbed into the washing water and thus it is considered that washing efficiency has been reduced. If such washing water is circulated, the firstgranular electrode member 18, the secondgranular electrode member 19, and theseparator 21 might be contaminated again by pollution in the washing water. - If the reverse washing in which the washing water is circulated has been executed a predetermined number of times in a range of 1 to 10 times, or desirably, 1 to 5 times, washing of the
water treatment unit 1 by circulation of the washing water is finished and the process proceeds to step ST05, and on the other hand, if this condition is not satisfied, the process returns to step ST02 to continue the reverse washing by circulation (step ST04). It is noted that, regarding the number of times of the reverse washing in which washing water is circulated, operation from the start of circulation of the washing water to draining in step ST03 is counted as one time. In addition, the predetermined multiple in step ST01 may be set per number of times in step ST04. - If the condition is satisfied in step ST04, the three-
way valve 23 is kept being opened in a direction from the three-way valve 22 to the drain side and the three-way valve 24 is switched to be opened in a direction from the reversewashing water tank 17 to the washingwater measurement unit 13 and thewater treatment unit 1, to newly inject the washing water in the reversewashing water tank 17 into the water treatment unit 1 (step ST05). It is noted that, if the number of times of the washing by circulation in step ST04 is larger than 10, the amount of necessary washing water becomes too large, leading to reduction in the recovery rate for the desalinated water. - While the washing water is being injected into the
water treatment unit 1, the electric conductivity of the washing water before injection into thewater treatment unit 1 is measured by the washingwater measurement unit 13 and the electric conductivity of the washing water after passing through thewater treatment unit 1 is measured by the treatment targetwater measurement unit 11, and then a result of the measurement by the treatment targetwater measurement unit 11 is compared with the result of the measurement by the washingwater measurement unit 13. As a result of the comparison, if the result of the measurement by the treatment targetwater measurement unit 11 is 1 to 1.5 times, or desirably, 1 to 1.2 times the result of the measurement by the washingwater measurement unit 13, it is considered that the washing has been sufficiently performed, and thus the washingwater supply pump 4 is stopped and the washingwater supply valve 9 is closed, whereby the reverse washing step is finished. If this condition is not satisfied, the process proceeds to step ST07 (step ST06). - If the condition in step ST06 is not satisfied, that is, if the result of the measurement by the treatment target
water measurement unit 11 is greater than 1.5 times the result of the measurement by the washingwater measurement unit 13, biofilm and/or scale still remains in thewater treatment unit 1 and thus the washing is insufficient. Therefore, the washing water is injected into thewater treatment unit 1 to continue the reverse washing step (step ST07), and then the process returns to step ST06, whereby the injection of the washing water is continued until the condition is satisfied. - In the reverse washing step in
embodiment 2, the flow rate of the washing water is controlled by thecontrol unit 14 so that the expansion rate of the firstgranular electrode member 18 and the secondgranular electrode member 19 is 0 to 200%, or desirably, 0 to 100%. As inembodiment 1, if the expansion rate of the firstgranular electrode member 18 and the secondgranular electrode member 19 is greater than 200%, the amount of necessary washing water becomes too large, leading to reduction in the recovery rate for the desalinated water. It is noted that, inembodiment 1, a certain degree of expansion is desirable from the perspective of effective physical washing, but inembodiment 2, efficiency of physical washing is ensured by circulation of washing water, and therefore the firstgranular electrode member 18 and the secondgranular electrode member 19 may not be expanded. - The other matters are the same as in
embodiment 1. - <Addition Reverse Washing Step>
- In the addition reverse washing step, as in
embodiment 1, first, theadditive supply valve 10 is opened and theadditive supply pump 37 is activated to add a predetermined amount of additive to the washing water in the reversewashing water tank 17 from theadditive storage tank 16. Next, thestirrer 36 stirs and mixes the additive and the washing water to generate additive containing washing water. In the case where the additive is hydrogen peroxide, the additive is added to the reversewashing water tank 17 so that the hydrogen peroxide concentration in the reversewashing water tank 17 becomes 0.0001 to 5%, or desirably, 0.001 to 1%. Next, in a state in which the three-way valve 24 is opened in a direction from the reversewashing water tank 17 to the washingwater measurement unit 13 and thewater treatment unit 1, and the three-way valve 22 is opened in a direction from thewater treatment unit 1 to the three-way valve 23, the washingwater supply pump 4 is activated to inject the additive containing washing water in the reversewashing water tank 17 into thewater treatment unit 1 in a direction from the lower washingwater inlet port 1 c to theupper inlet port 1 a of thewater treatment unit 1, i.e., the direction opposite to the flow of the treatment target water. At this time, until a predetermined amount of the additive containing washing water is stored in thewater treatment unit 1, the three-way valve 23 is opened in a direction from the three-way valve 22 to the drain side so that the additive containing washing water flowing out from theinlet port 1 a is drained. - After the predetermined amount of additive containing washing water is stored in the
water treatment unit 1, the three-way valve 23 is opened in a direction from the three-way valve 22 to the three-way valve 24, and the three-way valve 24 is opened in a direction from the three-way valve 23 to the washingwater measurement unit 13 and thewater treatment unit 1. Thus, a circulation path for the additive containing washing water is formed, and the additive containing washing water circulates by a driving force from the washingwater supply pump 4. - In washing of the
water treatment unit 1 by circulation of the additive containing washing water, as in the case of the reverse washing step described above, while the additive containing washing water is circulated, the electric conductivity of the additive containing washing water before injection into thewater treatment unit 1 is measured by the washingwater measurement unit 13 and the electric conductivity of the additive containing washing water after passing through thewater treatment unit 1 is measured by the treatment targetwater measurement unit 11, and then a result of the measurement by the treatment targetwater measurement unit 11 is compared with a result of the measurement by the washingwater measurement unit 13 at the time of injection of the additive containing washing water. As a result of the comparison, if the result of the measurement by the treatment targetwater measurement unit 11 exceeds a predetermined multiple in a range of 1 to 5 times, or desirably, 1 to 3 times with respect to the result of the measurement by the washingwater measurement unit 13, the three-way valve 23 is switched to be opened in a direction from the three-way valve 22 to the drain side, to drain the circulating additive containing washing water. If the result of the measurement by the treatment targetwater measurement unit 11 does not exceed the predetermined multiple of the result of the measurement by the washingwater measurement unit 13, the additive containing washing water is circulated as it is, to continue the washing. - After the additive containing washing water the amount of which is 2 to 10 times, or desirably, 3 to 5 times the volume of the first
granular electrode member 18 and the secondgranular electrode member 19 is injected into thewater treatment unit 1, the washingwater supply pump 4 is stopped and the three-way valve 24 is closed. Thereafter, as inembodiment 1, the operation of causing the additive containing washing water to flow out from thewater treatment unit 1 is executed, and thus the addition reverse washing step is finished. - In
embodiment 2, the same effects as inembodiment 1 can be obtained. - In addition, since the washing water in the reverse washing step and the additive containing washing water in the addition reverse washing step can be used to be circulated, the washing water can be efficiently used and the amount of water needed for washing is decreased, whereby the recovery rate for the desalinated water can be increased.
- Hereinafter,
embodiment 3 of the present invention will be described with reference toFIG. 6 . Parts that are the same as or correspond to those inFIG. 4 are denoted by the same reference characters, and the description thereof is omitted.Embodiment 3 is different fromembodiment 2 in that plural types of additives are provided.FIG. 6 is a configuration diagram of a water treatment apparatus according toembodiment 3 of the present invention. In awater treatment apparatus 300, as inembodiment 2, thewater treatment unit 1 is connected to the treatedwater tank 15 via the desalinatedwater measurement unit 12 and then the desalinatedwater sending valve 7. On the other hand, unlikeembodiment 2, thewater treatment unit 1 is not connected to the reversewashing water tank 17 via the desalinatedwater measurement unit 12 and then the desalinatedwater sending valve 8. Thewater treatment unit 1 is connected to the reversewashing water tank 17 via the treatedwater tank 15 which is connected to the reversewashing water tank 17 via a desalinatedwater sending pump 26 and then the desalinatedwater sending valve 8. Thewater treatment unit 1 is capable of drainage via adrain valve 30. - The reverse
washing water tank 17 is connected to threeadditive storage tanks additive supply pump 37 and a four-way valve 25. Theadditive storage tanks way valve 25 allows the reversewashing water tank 17 to be connected to one of the threeadditive storage tanks additive supply pump 37 and the four-way valve 25 are connected to thecontrol unit 14, and are controlled by thecontrol unit 14 during execution of each processing step. - The other configurations are the same as in
embodiment 2 and therefore the description thereof is omitted. - Next, operation will be described. The operation is the same as in
embodiment 2 in that desalination of treatment target water is sequentially performed while a cycle of desalination of treatment target water in thewater treatment unit 1 and washing of thewater treatment unit 1 is repeated. In addition, the “reverse washing step” and the “washing method execution control” inembodiment 3 are the same as inembodiment 2 and therefore the description thereof is omitted. The “desalination step” and the “addition reverse washing step” will be described in detail. - In the addition reverse washing step, reverse washing by washing water in which the additive A, B, C stored in each
additive storage tank - <Desalination Step>
- In the desalination step, as in
embodiment 2, first, the three-way valve 22 is opened in a direction from theraw water tank 2 to thewater treatment unit 1, and the three-way valve 23 is closed. Also, the desalinatedwater sending valve 7 is opened. Next, the treatment targetwater supply pump 3 is activated to send the treatment target water in theraw water tank 2 so as to be supplied to thewater treatment unit 1. The treatment target water is supplied through theupper inlet port 1 a of thewater treatment unit 1 into thewater treatment unit 1, and then flows downward. In addition, DC voltage is applied to the firstgranular electrode member 18 and the secondgranular electrode member 19 via the pair ofcollectors power supply unit 20, whereby ions contained in the treatment target water are adsorbed and removed by a Coulomb force to the firstgranular electrode member 18 and the secondgranular electrode member 19, and thus the treatment target water is desalinated. The desalinated treatment target water is discharged as desalinated water through thelower outlet port 1 b of thewater treatment unit 1 and flows through the desalinatedwater measurement unit 12 and the desalinatedwater sending valve 7 to the treatedwater tank 15. When a predetermined amount of the desalinated water has been supplied to the treatedwater tank 15, the desalinatedwater sending valve 8 is opened and the desalinatedwater sending pump 26 is activated to send the desalinated water from the treatedwater tank 15 to the reversewashing water tank 17 until the amount thereof reaches a prescribed amount. - The other matters are the same as in
embodiment 1. - <Addition Reverse Washing Step>
- In the first reverse washing, first, the four-
way valve 25 is opened in a direction from theadditive storage tank 16 a to the reversewashing water tank 17 and theadditive supply pump 37 is activated to add a predetermined amount of additive A to the washing water in the reversewashing water tank 17 from theadditive storage tank 16 a. Next, thestirrer 36 stirs and mixes the additive A and the washing water to generate additive-A containing washing water. Next, in a state in which the three-way valve 24 is opened in a direction from the reversewashing water tank 17 to the washingwater measurement unit 13 and thewater treatment unit 1, and the three-way valve 22 is opened in a direction from thewater treatment unit 1 to the three-way valve 23, the washingwater supply pump 4 is activated to inject the additive-A containing washing water in the reversewashing water tank 17 into thewater treatment unit 1 in a direction from the lower washingwater inlet port 1 c to theupper inlet port 1 a of thewater treatment unit 1, i.e., the direction opposite to the flow of the treatment target water. At this time, until a predetermined amount of the washing water is stored in thewater treatment unit 1, the three-way valve 23 is opened in a direction from the three-way valve 22 to the drain side so that the washing water flowing out from theinlet port 1 a is drained. - After the predetermined amount of additive-A containing washing water is stored in the
water treatment unit 1, the three-way valve 23 is opened in a direction from the three-way valve 22 to the three-way valve 24, and the three-way valve 24 is opened in a direction from the three-way valve 23 to the washingwater measurement unit 13 and thewater treatment unit 1. Thus, a circulation path for the additive-A containing washing water is formed, and the additive containing washing water is circulated by a driving force from the washingwater supply pump 4. Washing of thewater treatment unit 1 by the additive-A containing washing water is the same as the reverse washing in the addition reverse washing step inembodiment 2. - After the first reverse washing is finished, the
drain valve 29 is opened so that the additive-A containing washing water is drained from the reversewashing water tank 17. After the additive-A containing washing water is drained, the desalinatedwater sending valve 8 is opened and the desalinatedwater sending pump 26 is activated to send the desalinated water from the treatedwater tank 15 to the reversewashing water tank 17. When a predetermined amount of the desalinated water has been sent to the reversewashing water tank 17, the desalinatedwater sending pump 26 is stopped and the desalinatedwater sending valve 8 is closed. - The four-
way valve 25 is opened in a direction from theadditive storage tank 16 b to the reversewashing water tank 17, and theadditive supply pump 37 is activated to add a predetermined amount of additive B to the washing water in the reversewashing water tank 17 from theadditive storage tank 16 b. Next, thestirrer 36 stirs and mixes the additive B and the washing water to generate additive-B containing washing water. Thereafter, the second reverse washing by the additive-B containing washing water is executed in the same manner as in case of the first reverse washing. After the second reverse washing is finished, similarly, the additive is switched from the additive B to the additive C and the third reverse washing is executed. - After the third reverse washing is finished, the washing
water supply pump 4 is stopped, the desalinatedwater sending valve 7 is closed, and thedrain valve 30 is opened. The three-way valve 22 is opened in a direction from theraw water tank 2 to thewater treatment unit 1, and the treatment targetwater supply pump 3 is activated to send the treatment target water to thewater treatment unit 1, so that the additive-C containing washing water remaining in thewater treatment unit 1 is caused to flow out and is drained through thedrain valve 30. After the flowing-out of the additive-C containing washing water is finished, the treatment targetwater supply pump 3 is stopped, and the treatment targetwater supply valve 5 and thedrain valve 30 are closed, to finish the addition reverse washing step. The amount of treatment target water to be used for causing the additive containing washing water to flow out from thewater treatment unit 1 is the same as that inembodiment 1. - It is noted that, in the case where, in light of the property of the desalinated water, there is no adverse effect even if the additive C remains in the
water treatment unit 1, the operation of causing the additive-C containing washing water to flow out may be omitted. - Regarding the respective additives, the additive A used for the first reverse washing is an oxidizing agent having a property of removing biofilm, and the additive B used for the second reverse washing is an acid for removing scale such as calcium carbonate which ionizes under acidic condition. In addition, the additive C used for the third reverse washing is an alkali for removing scale such as silica which ionizes under basic condition. Desirably, it is preferable to use hydrogen peroxide, ozone, hypochlorous acid, or the like as the oxidizing agent, and use sulfuric acid, hydrochloric acid, or the like as the acid. In addition, it is preferable to use sodium hydroxide, sodium carbonate, sodium sesquicarbonate, sodium bicarbonate, or the like as the alkali.
- In
embodiment 3, the same effects as inembodiment 2 can be obtained. - In addition, a plurality of additive storage tanks storing different types of additives are provided, biofilm is removed by the first reverse washing using the oxidizing agent, scale such as calcium carbonate which ionizes under acidic condition is removed by the second reverse washing using the acid, and scale such as silica which ionizes under basic condition is removed by the third reverse washing using the alkali. In this way, the reverse washing is executed using the washing waters to which different additives are added, whereby biofilm and/or scale accumulated in the
water treatment unit 1 can be removed efficiently and effectively. - Hereinafter,
embodiment 4 of the present invention will be described with reference toFIG. 7 . Parts that are the same as or correspond to those inFIG. 4 are denoted by the same reference characters, and the description thereof is omitted.Embodiment 4 is different fromembodiment 2 in that an additive is directly injected into thewater treatment unit 1.FIG. 7 is a configuration diagram of a water treatment apparatus according toembodiment 4 of the present invention. In awater treatment apparatus 400, thewater treatment unit 1 is connected to the treatedwater tank 15 via the washingwater supply pump 4, the washingwater measurement unit 13, and the four-way valve 25. Thewater treatment unit 1 is capable of drainage via thedrain valve 30. Thewater treatment apparatus 400 does not include the reversewashing water tank 17, and also, does not include thestirrer 36 and thedrain valve 29. - The treated
water tank 15 is connected to anadditive generation unit 27 via the desalinatedwater sending valve 8 and the desalinatedwater sending pump 26. Theadditive generation unit 27 is for generating an additive and injecting the additive into thewater treatment unit 1, and corresponds to the additive supply unit inembodiment 1. Theadditive generation unit 27 is connected to anadditive injection port 1 e of thewater treatment unit 1 via anadditive measurement unit 31 for measuring the additive concentration and theadditive supply valve 10. Theadditive generation unit 27 and theadditive measurement unit 31 are connected to thecontrol unit 14, and are controlled by thecontrol unit 14 during execution of each processing step. As theadditive generation unit 27, an electrolyzer or the like that generates hypochlorous acid, hypochlorite, ozone, or hydrogen peroxide through electrolysis of desalinated water, e.g., an ozonizer for generating ozone from the air or oxygen gas supplied from outside, is used. Alternatively, ion-exchange resin, ion-exchange membrane, or the like may be used as theadditive generation unit 27. In this case, it is possible to generate an acid or alkali from desalinated water. Although not shown, theadditive generation unit 27 may be connected to theraw water tank 2, whereby an additive may be generated from the treatment target water. - The four-
way valve 25 is connected also to the desalinatedwater measurement unit 12 and the three-way valve 23 as well as the washingwater measurement unit 13 and the treatedwater tank 15, so that the desalinated water flowing out from thewater treatment unit 1 can circulate via the desalinatedwater measurement unit 12, the four-way valve 25, the three-way valve 23, the three-way valve 22, and the treatment targetwater measurement unit 11. - The other configurations are the same as in
embodiment 2 and therefore the description thereof is omitted. - Next, operation will be described. The operation is the same as in
embodiment 1 in that desalination of treatment target water is sequentially performed while a cycle of desalination of treatment target water in thewater treatment unit 1 and washing of thewater treatment unit 1 is repeated. Hereinafter, the “desalination step”, the “reverse washing step”, and the “addition reverse washing step” will be described in detail. The “washing method execution control” is the same as inembodiment 1 and therefore the description thereof is omitted. - <Desalination Step>
- In the desalination step, first, the three-
way valve 22 is opened in a direction from theraw water tank 2 to thewater treatment unit 1, and the three-way valve 23 is closed. In addition, the four-way valve 25 is opened in a direction from the desalinatedwater measurement unit 12 to the treatedwater tank 15. Next, the treatment targetwater supply pump 3 is activated to send the treatment target water in theraw water tank 2 so as to be supplied to thewater treatment unit 1. The treatment target water is supplied through theupper inlet port 1 a of thewater treatment unit 1 into thewater treatment unit 1, and then flows downward. In addition, DC voltage is applied to the firstgranular electrode member 18 and the secondgranular electrode member 19 via the pair ofcollectors power supply unit 20, whereby ions contained in the treatment target water are adsorbed and removed by a Coulomb force to the firstgranular electrode member 18 and the secondgranular electrode member 19, and thus the treatment target water is desalinated. The desalinated treatment target water is discharged as desalinated water through thelower outlet port 1 b of thewater treatment unit 1 and flows through the desalinatedwater measurement unit 12 and the four-way valve 25 to the treatedwater tank 15. - The other matters are the same as in
embodiment 2. - <Reverse Washing Step>
- In the reverse washing step, first, in a state in which the four-
way valve 25 is opened in a direction from the treatedwater tank 15 to the washingwater measurement unit 13 and thewater treatment unit 1, and the three-way valve 22 is opened in a direction from thewater treatment unit 1 to the three-way valve 23, the washingwater supply pump 4 is activated to inject, as washing water, the desalinated water in the treatedwater tank 15 into thewater treatment unit 1 in a direction from the lower washingwater inlet port 1 c to theupper inlet port 1 a of thewater treatment unit 1, i.e., the direction opposite to the flow of the treatment target water. At this time, until a predetermined amount of the washing water is stored in thewater treatment unit 1, the three-way valve 23 is opened in a direction from the three-way valve 22 to the drain side so that the washing water flowing out from theinlet port 1 a is drained. - After the predetermined amount of desalinated water as washing water is stored in the
water treatment unit 1, the three-way valve 23 is opened in a direction from the three-way valve 22 to the four-way valve 25, and the four-way valve 25 is opened in a direction from the three-way valve 23 to the washingwater measurement unit 13 and thewater treatment unit 1. Thus, a circulation path for the desalinated water as the washing water is formed, and the desalinated water circulates by a driving force from the washingwater supply pump 4. - While the desalinated water as washing water is circulated, the electric conductivity of the desalinated water before injection into the
water treatment unit 1 is measured by the washingwater measurement unit 13 and the electric conductivity of the desalinated water after passing through thewater treatment unit 1 is measured by the treatment targetwater measurement unit 11, and then a result of measurement by the treatment targetwater measurement unit 11 is compared with a result of measurement by the washingwater measurement unit 13. As a result of comparison, if the result of the measurement by the treatment targetwater measurement unit 11 is 0 to 5 times, or desirably, 0.5 to 3 times the result of the measurement by the washingwater measurement unit 13, the three-way valve 23 is switched to be opened in a direction from the three-way valve 22 to the drain side, to drain the circulating desalinated water. After the reverse washing in which the desalinated water is circulated has been executed 1 to 10 times, or desirably, 1 to 5 times, the four-way valve 25 is opened in a direction from the treatedwater tank 15 to the washingwater measurement unit 13 and thewater treatment unit 1, and thus the reverse washing by circulation is finished. - After the reverse washing by circulation is finished, while the desalinated water as washing water is being injected into the
water treatment unit 1 from the treatedwater tank 15, the electric conductivity of the desalinated water before injection into thewater treatment unit 1 is measured by the washingwater measurement unit 13 and the electric conductivity of the desalinated water after passing through thewater treatment unit 1 is measured by the treatment targetwater measurement unit 11, and then a result of the measurement by the treatment targetwater measurement unit 11 is compared with a result of the measurement by the washingwater measurement unit 13. As a result of the comparison, if the result of the measurement by the treatment targetwater measurement unit 11 is 1 to 1.5 times, or desirably, 1 to 1.2 times the result of the measurement by the washingwater measurement unit 13, it is considered that the washing has been sufficiently performed, and thus the washingwater supply pump 4 is stopped and the washingwater supply valve 9 is closed, whereby the reverse washing step is finished. If this condition is not satisfied, that is, if the result of the measurement by the treatment targetwater measurement unit 11 is greater than 1.5 times the result of the measurement by the washingwater measurement unit 13, it is considered that biofilm and/or scale still remains in thewater treatment unit 1 and thus the washing is insufficient. Therefore, the desalinated water is injected into thewater treatment unit 1 and the reverse washing step is continued until the condition is satisfied. - The other matters are the same as in
embodiment 2. - <Addition Reverse Washing Step>
- In the addition reverse washing step, first, in a state in which the four-
way valve 25 is opened in a direction from the treatedwater tank 15 to the washingwater measurement unit 13 and thewater treatment unit 1, and the three-way valve 22 is opened in a direction from thewater treatment unit 1 to the three-way valve 23, the washingwater supply pump 4 is activated to inject, as washing water, the desalinated water in the treatedwater tank 15 into thewater treatment unit 1 in a direction from the lower washing water inlet port is to theupper inlet port 1 a of thewater treatment unit 1, i.e., the direction opposite to the flow of the treatment target water. At this time, until a predetermined amount of the washing water is stored in thewater treatment unit 1, the three-way valve 23 is opened in a direction from the three-way valve 22 to the drain side so that the washing water flowing out from theinlet port 1 a is drained. - After the predetermined amount of desalinated water as washing water is stored in the
water treatment unit 1, the three-way valve 23 is opened in a direction from the three-way valve 22 to the four-way valve 25, and the four-way valve 25 is opened in a direction from the three-way valve 23 to the washingwater measurement unit 13 and thewater treatment unit 1. Thus, a circulation path for the desalinated water as the washing water is formed, and the desalinated water circulates by a driving force from the washingwater supply pump 4. - While the desalinated water is circulated as described above, the
additive supply valve 10 is opened and the additive generated by theadditive generation unit 27 is injected through theadditive injection port 1 e into thewater treatment unit 1. If the additive is used in a diluted state, the desalinatedwater sending valve 8 is opened and the desalinatedwater sending pump 26 is activated to send the desalinated water in the treatedwater tank 15 to theadditive generation unit 27, whereby the additive is diluted by the desalinated water and the diluted additive is injected into thewater treatment unit 1. - It is noted that the
water treatment apparatus 400 does not include thedrain valve 29 and therefore, regarding the flowing-out of the additive containing washing water which is performed at the end of the addition reverse washing step, the additive containing washing water is drained through thedrain valve 30. - The other matters are the same as in
embodiment 2. - In
embodiment 4, the same effects as inembodiment 2 can be obtained. - In addition, since the additive is directly injected into the water treatment unit from the additive generation unit, the reverse washing water tank for mixing an additive with the washing water to generate additive containing washing water can be omitted. In addition, the time period for generating the additive containing washing water can be omitted and thus the time period of the addition reverse washing step is shortened, whereby the desalination can be efficiently performed.
- It is noted that, since, in
embodiment 4, plural types of additives can be generated by the additive generation unit, it is possible to execute the addition reverse washing step while switching the type of the additive for the first washing, the second washing, and the third washing as inembodiment 3. - Hereinafter,
embodiment 5 of the present invention will be described with reference toFIG. 8 . Parts that are the same as or correspond to those inFIG. 1 are denoted by the same reference characters, and the description thereof is omitted.Embodiment 5 is different fromembodiment 1 in that a plurality of water treatment units are provided and connected in series. Hereinafter, one of the water treatment units is defined as an A-system, the other one is defined as a B-system, and the components in the A-system are denoted by adding “A” to the ends of their reference characters, and the components in the B-system are denoted by adding “B” to the ends of their reference characters. -
FIG. 1 is a configuration diagram of a water treatment apparatus according toembodiment 5 of the present invention. A water treatment apparatus 500 includes awater treatment unit 1A and awater treatment unit 1B. Thewater treatment unit 1A has aninlet port 1 aA through which treatment target water flows in, anoutlet port 1 bA through which desalinated water flows out, and a washingwater inlet port 1 cA through which washing water or additive containing washing water flows in at the time of reverse washing, and thewater treatment unit 1A is connected via a treatment targetwater measurement unit 11A, the treatment targetwater supply valve 5, and then the treatment targetwater supply pump 3 to theraw water tank 2 for storing the treatment target water, and performs desalination for the treatment target water supplied from theraw water tank 2. Thewater treatment unit 1B has aninlet port 1 aB through which treatment target water flows in, anoutlet port 1 bB through which desalinated water flows out, and a washingwater inlet port 1 cB through which washing water or additive containing washing water flows in at the time of reverse washing, and thewater treatment unit 1B is connected via a desalinatedwater measurement unit 12A, a treatment targetwater supply valve 5B, and then a treatment targetwater measurement unit 11B to thewater treatment unit 1A, and performs further desalination for the treatment target water that has undergone desalination by thewater treatment unit 1A. Thewater treatment unit 1B is connected via a desalinatedwater measurement unit 12B and then the desalinatedwater sending valve 7 to the treatedwater tank 15 for storing the treatment target water that has undergone further desalination by thewater treatment unit 1B, and also, thewater treatment unit 1B is connected via the desalinatedwater measurement unit 12B and then the desalinatedwater sending valve 8 to the reversewashing water tank 17 for storing washing water for reverse washing. - The reverse
washing water tank 17 is shared by thewater treatment unit 1A and thewater treatment unit 1B. The reversewashing water tank 17 is connected to thewater treatment unit 1B also through a route passing a washingwater supply pump 4B for supplying washing water to thewater treatment unit 1B at the time of reverse washing, a washingwater supply valve 9B, and then a washingwater measurement unit 13B, and is connected to thewater treatment unit 1A via a washingwater supply pump 4A for supplying washing water to thewater treatment unit 1A, a washingwater supply valve 9A, and then a washingwater measurement unit 13A. - Washing water supplied to the
water treatment unit 1A and washing water supplied to thewater treatment unit 1B can be drained via the treatment targetwater measurement unit 11A and the treatment targetwater measurement unit 11B, and then thedrain valve 6A and thedrain valve 6B, respectively, from thewater treatment unit 1A and thewater treatment unit 1B. In addition, the reversewashing water tank 17 is connected to theadditive storage tank 16 via theadditive supply valve 10 and then theadditive supply pump 37, and the reversewashing water tank 17 is provided with thestirrer 36 for stirring and mixing an additive and washing water when the additive is supplied. Washing water in the reversewashing water tank 17 can be drained via thedrain valve 29. - In the
water treatment unit 1A, a pair of collectors 28 aA, 28 bA connected to thepower supply unit 20 are provided at both ends, and between the pair of collectors 28 aA, 28 bA, a firstgranular electrode member 18A and a secondgranular electrode member 19A are provided so as to be opposed to each other and separated from each other by aseparator 21A. A plurality of the firstgranular electrode members 18A and a plurality of the secondgranular electrode members 19A are provided. The firstgranular electrode members 18A or the secondgranular electrode members 19A are in contact with each other, but the firstgranular electrode member 18A and the secondgranular electrode member 19A are prevented from coming into contact with each other, by theseparator 21A. - Similarly, in the
water treatment unit 1B, a pair of collectors 28 aB, 28 bB connected to thepower supply unit 20 are provided at both ends, and between the pair of collectors 28 aB, 28 bB, a firstgranular electrode member 18B and a secondgranular electrode member 19B are provided so as to be opposed to each other and separated from each other by aseparator 21B. A plurality of the firstgranular electrode members 18B and a plurality of the secondgranular electrode members 19B are provided. The firstgranular electrode members 18B or the secondgranular electrode members 19B are in contact with each other, but the firstgranular electrode member 18B and the secondgranular electrode member 19B are prevented from coming into contact with each other, by theseparator 21B. - The materials and functions of the collectors 28 aA, 28 bA, 28 aB, 28 bB, the first
granular electrode members granular electrode members separators collectors granular electrode members 18, the secondgranular electrode members 19, and theseparator 21 described inembodiment 1. - The treatment target
water measurement unit 11A and the treatment targetwater measurement unit 11B, the desalinatedwater measurement unit 12A and the desalinatedwater measurement unit 12B, and the washingwater measurement unit 13A and the washingwater measurement unit 13B, which are respectively connected to thewater treatment unit 1A and thewater treatment unit 1B, are the same as the treatment targetwater measurement unit 11, the desalinatedwater measurement unit 12, and the washingwater measurement unit 13 ofembodiment 1. - The valves, the pumps, and the measurement units are connected to the
control unit 14 as inembodiment 1, and are controlled by thecontrol unit 14 during execution of each processing step. - Although two water treatment units are provided in
embodiment 5, the number thereof is not limited thereto and three or more water treatment units may be provided. - Next, operation will be described. The operation is the same as in
embodiment 1 in that desalination of treatment target water is sequentially performed while a cycle of desalination of treatment target water in thewater treatment unit 1A and thewater treatment unit 1B and washing of thewater treatment unit 1A and thewater treatment unit 1B is repeated. Hereinafter, the “desalination step”, the “reverse washing step”, and the “addition reverse washing step” will be described in detail. - <Desalination Step>
- In the desalination step, first, the treatment target
water supply valve 5A and the treatment targetwater supply valve 5B are opened, and thedrain valve 6A and thedrain valve 6B are closed. Next, the treatment targetwater supply pump 3 is activated to send the treatment target water in theraw water tank 2 so as to be supplied to thewater treatment unit 1A. The treatment target water is supplied through theupper inlet port 1 aA of thewater treatment unit 1A into thewater treatment unit 1A, and then flows downward. In addition, DC voltage is applied to the firstgranular electrode members 18A and the secondgranular electrode members 19A via the pair of collectors 28 aA, 28 bA by thepower supply unit 20, and ions contained in the treatment target water are adsorbed and removed by a Coulomb force to the firstgranular electrode members 18A and the secondgranular electrode members 19A, whereby the treatment target water is desalinated. The desalinated treatment target water is discharged as desalinated water through thelower outlet port 1 bA of thewater treatment unit 1A, and passes through the desalinatedwater measurement unit 12A, the treatment targetwater supply valve 5B, and then the treatment targetwater measurement unit 11B so as to be supplied to thewater treatment unit 1B through theinlet port 1 aB. Also in thewater treatment unit 1B, similarly, ions contained in the treatment target water that has undergone desalination by thewater treatment unit 1A are adsorbed and removed to the firstgranular electrode members 18B and the secondgranular electrode members 19B, whereby further desalination is performed. The treatment target water that has undergone further desalination by thewater treatment unit 1B is discharged through thelower outlet port 1 bB of thewater treatment unit 1B. Then, as inembodiment 1, the discharged water is sent to the reversewashing water tank 17 until a prescribed amount of the water is stored, and after the prescribed amount is reached, the discharged water is sent to the treatedwater tank 15. After a predetermined time has elapsed since the start of the desalination step, the treatment targetwater supply pump 3 is stopped, and the treatment targetwater supply valve 5A, the treatment targetwater supply valve 5B, and the desalinatedwater sending valve 7 are closed. In addition, application of DC voltage by thepower supply unit 20 is stopped, whereby the desalination step is finished. - The other matters are the same as in
embodiment 1. - <Washing Method Execution Control>
- After the desalination step is finished, the
control unit 14 executes execution control to determine whether to execute the reverse washing step or the addition reverse washing step, using the ion removal rate in thewater treatment unit 1 as a determination index. Since the water treatment apparatus 500 ofembodiment 5 includes twowater treatment units water treatment unit 1A and thewater treatment unit 1B. The washing method execution control for each water treatment unit is performed using the ion removal rate as a determination index, as inembodiment 1. - <Reverse Washing Step>
- In the reverse washing step, first, in a state in which the
drain valve 6A and the washingwater supply valve 9A are opened and the treatment targetwater supply valve 5A is closed, the washingwater supply pump 4A is activated to inject the washing water in the reversewashing water tank 17 into thewater treatment unit 1A in a direction from the lower washingwater inlet port 1 cA to theupper inlet port 1 aA of thewater treatment unit 1A, i.e., the direction opposite to the flow of the treatment target water. In addition, in a state in which thedrain valve 6B and the washingwater supply valve 9B are opened and the treatment targetwater supply valve 5B is closed, the washingwater supply pump 4B is activated to inject the washing water in the reversewashing water tank 17 into thewater treatment unit 1B in the direction opposite to the flow of the treatment target water. The washing water injected into thewater treatment unit 1A flows upward in the drawing and flows out through theinlet port 1 aA to the upper side of thewater treatment unit 1A, and thereafter, is drained through thedrain valve 6A. The washing water injected into thewater treatment unit 1B flows upward in the drawing and flows out through theinlet port 1 aB to the upper side of thewater treatment unit 1B, and thereafter, is drained through thedrain valve 6B. - During execution of the reverse washing step, as in
embodiment 1, the electric conductivities of the washing water before and after injection into the water treatment unit are measured and compared, whereby whether or not the reverse washing step can be finished is determined. Inembodiment 5, the determination is performed for each of thewater treatment unit 1A and thewater treatment unit 1B, and unless the reverse washing step is finished in both of the A-system and the B-system, the process does not proceed to the desalination step. - The other matters are the same as in
embodiment 1. - Also in
embodiment 5, as inembodiments 2 to 4, a circulation path may be formed to execute reverse washing in which washing water is circulated. - <Addition Reverse Washing Step>
- In the addition reverse washing step, first, the
additive supply valve 10 is opened and theadditive supply pump 37 is activated to add a predetermined amount of additive to the washing water in the reversewashing water tank 17 from theadditive storage tank 16. Next, thestirrer 36 stirs and mixes the additive and the washing water to generate additive containing washing water. Thereafter, in the same manner as in the above reverse washing step, the additive containing washing water is injected into each of thewater treatment unit 1A and thewater treatment unit 1B. - After the additive containing washing water the amount of which is 2 to 10 times, or desirably, 3 to 5 times the volume of the first
granular electrode members 18A and the secondgranular electrode members 19A is injected into thewater treatment unit 1A, the washingwater supply pump 4A is stopped and the washingwater supply valve 9A is closed. In addition, after the additive containing washing water the amount of which is 2 to 10 times, or desirably, 3 to 5 times the volume of the firstgranular electrode members 18B and the secondgranular electrode members 19B is injected into thewater treatment unit 1B, the washingwater supply pump 4B is stopped and the washingwater supply valve 9B is closed. - After the washing
water supply pump 4A and the washingwater supply pump 4B are stopped, in a state in which the desalinatedwater sending valve 7 is closed, the treatment targetwater supply valve 5A, the treatment targetwater supply valve 5B, the desalinatedwater sending valve 8, and thedrain valve 29 are opened, and the treatment targetwater supply pump 3 is activated to send the treatment target water from theraw water tank 2 to thewater treatment unit 1A and then thewater treatment unit 1B, thereby causing the additive containing washing water remaining in thewater treatment unit 1A and thewater treatment unit 1B to flow out and be drained from the reversewashing water tank 17 through thedrain valve 29. After the flowing-out of the additive containing washing water is finished, the treatment targetwater supply pump 3 is stopped and the treatment targetwater supply valve 5A, the treatment targetwater supply valve 5B, and thedrain valve 29 are closed, whereby the addition reverse washing step is finished. - The other matters are the same as in
embodiment 1. However, as in the reverse washing step, inembodiment 5, determination is performed for each of thewater treatment unit 1A and thewater treatment unit 1B, and unless the addition reverse washing step is finished in both of the A-system and the B-system, the process does not proceed to the desalination step. - Also in
embodiment 5, as inembodiments 2 to 4, a circulation path may be formed to execute reverse washing in which additive containing washing water is circulated. - In
embodiment 5, the same effects as inembodiment 1 can be obtained. - In addition, since a plurality of water treatment units are connected in series, the treatment target water can be desalinated to a further decreased ion concentration.
- In addition, since the reverse washing water tank is shared among the plurality of water treatment units, one reverse washing water tank is enough and the entire apparatus can be made compact.
- Hereinafter,
embodiment 6 of the present invention will be described with reference toFIG. 9 . Parts that are the same as or correspond to those inFIG. 7 are denoted by the same reference characters, and the description thereof is omitted.Embodiment 6 is different fromembodiment 4 in thatadditive injection ports 1 e for injecting an additive are provided at a plurality of locations.FIG. 9 is a configuration diagram of a water treatment apparatus according toembodiment 6 of the present invention. In awater treatment apparatus 600, a plurality ofadditive injection ports 1 e for injecting an additive from theadditive generation unit 27 are provided at the lower part in the drawing, of thewater treatment unit 1. In addition,additive injection ports 1 e are provided also to the pair ofcollectors - The other matters are the same as in
embodiment 4, and therefore the description thereof is omitted. - In
embodiment 6, the same effects as inembodiment 4 can be obtained. - In addition, since the additive injection ports are provided at a plurality of locations of the water treatment unit, the additive is injected through the plurality of locations, whereby the additive containing washing water spreads faster over the entire granular electrode members, and thus the granular electrode members can be washed within a short time in the addition reverse washing step.
- Hereinafter,
embodiment 7 of the present invention will be described with reference toFIG. 10 . Parts that are the same as or correspond to those inFIG. 1 are denoted by the same reference characters, and the description thereof is omitted.Embodiment 7 is different fromembodiment 1 in that washing water and an additive can be mixed in a pipe connecting the water treatment unit and the treated water tank.FIG. 10 is a configuration diagram of a water treatment apparatus according toembodiment 7 of the present invention. In a water treatment apparatus 700, thewater treatment unit 1 which performs desalination for treatment target water is connected to the treatedwater tank 15 via the desalinatedwater sending valve 7 and then the desalinatedwater measurement unit 12, and is connected to the treatedwater tank 15 also through a route passing the washingwater supply valve 9, the washingwater measurement unit 13, and the washingwater supply pump 4. Thewater treatment unit 1 is capable of drainage via thedrain valve 30. - The
additive storage tank 16 is connected via theadditive supply pump 37 and then theadditive supply valve 10 to anadditive injection portion 38 provided to a pipe connecting the washingwater measurement unit 13 and the washingwater supply pump 4. The water treatment apparatus 700 does not include the reversewashing water tank 17, and also, does not include the desalinatedwater sending valve 8, thestirrer 36, and thedrain valve 29. - The other matters are the same as in
embodiment 1, and therefore the description thereof is omitted. - Next, operation will be described. The operation is the same as in
embodiment 1 in that desalination of treatment target water is sequentially performed while a cycle of desalination of treatment target water in thewater treatment unit 1 and washing of thewater treatment unit 1 is repeated. Hereinafter, the “desalination step”, the “reverse washing step”, and the “addition reverse washing step” will be described in detail. The “washing method execution control” is the same as inembodiment 1, and therefore the description thereof is omitted. - <Desalination Step>
- In the desalination step, first, the treatment target
water supply valve 5 is opened and thedrain valve 6 is closed. In addition, the desalinatedwater sending valve 7 is opened. Next, the treatment targetwater supply pump 3 is activated to send the treatment target water in theraw water tank 2 so as to be supplied to thewater treatment unit 1. The treatment target water is supplied through theupper inlet port 1 a of thewater treatment unit 1 into thewater treatment unit 1, and then flows downward. In addition, DC voltage is applied to the firstgranular electrode member 18 and the secondgranular electrode member 19 via the pair ofcollectors power supply unit 20, and ions contained in the treatment target water are adsorbed and removed by a Coulomb force to the firstgranular electrode member 18 and the secondgranular electrode member 19, whereby the treatment target water is desalinated. The desalinated treatment target water is discharged as desalinated water through thelower outlet port 1 b of thewater treatment unit 1, and flows through the desalinatedwater sending valve 7 and the desalinatedwater measurement unit 12 to the treatedwater tank 15. - The other matters are the same as in
embodiment 1. - <Reverse Washing Step>
- In the reverse washing step, first, in a state in which the
drain valve 6 and the washingwater supply valve 9 are opened and the treatment targetwater supply valve 5 is closed, the washingwater supply pump 4 is activated to inject, as washing water, the desalinated water in the treatedwater tank 15 into thewater treatment unit 1 in a direction from the lower washingwater inlet port 1 c to theupper inlet port 1 a of thewater treatment unit 1, i.e., the direction opposite to the flow of the treatment target water. - The other matters are the same as in
embodiment 1. - <Addition Reverse Washing Step>
- In the addition reverse washing step, first, the
additive supply valve 10 is opened and theadditive supply pump 37 is activated to send the additive from theadditive storage tank 16 to theadditive injection portion 38 and inject the additive into the pipe connecting the washingwater measurement unit 13 and the washingwater supply pump 4. The desalinated water as the washing water flowing through the pipe is mixed with the additive while flowing to thewater treatment unit 1, whereby additive containing washing water is generated. The generated additive containing washing water is injected into thewater treatment unit 1 through the washingwater inlet port 1 c. Thereafter, the additive containing washing water flows upward and flows out to the upper side of thewater treatment unit 1 through theinlet port 1 a, and then is drained through thedrain valve 6. - It is noted that the water treatment apparatus 700 does not include the
drain valve 29 and therefore, regarding the flowing-out of the additive containing washing water which is performed at the end of the addition reverse washing step, the additive containing washing water is drained through thedrain valve 30. - The other matters are the same as in
embodiment 1. - In
embodiment 7, the same effects as inembodiment 1 can be obtained. - In addition, since the additive is injected from the additive generation unit into the pipe connecting the water treatment unit and the treated water tank and the additive containing washing water is generated in the pipe, the reverse washing water tank can be omitted and thus the entire apparatus can be simplified.
- In addition, since the additive is injected and mixed only to the desalinated water flowing from the treated water tank to the water treatment unit to generate the additive containing washing water, surplus additive containing washing water as in the case of mixing the additive to the washing water stored in the reverse washing water tank is not generated, and thus the generation amount of the additive containing washing water can be suppressed to the minimum necessary amount. As a result, the amount of desalinated water that can be recovered increases, whereby the recovery rate for desalinated water can be increased.
- Hereinafter,
embodiment 8 of the present invention will be described with reference toFIG. 11 . Parts that are the same as or correspond to those inFIG. 1 are denoted by the same reference characters, and the description thereof is omitted.Embodiment 8 is different fromembodiment 1 in that air is injected into the water treatment unit in the reverse washing step and the addition reverse washing step.FIG. 11 is a configuration diagram of a water treatment apparatus according toembodiment 8 of the present invention. A water treatment apparatus 800 includes anair pump 39 for injecting air into thewater treatment unit 1 from the lower side of thewater treatment unit 1. Theair pump 39 is connected to thecontrol unit 14, and is controlled by thecontrol unit 14 during execution of each processing step. - The other matters are the same as in
embodiment 1, and therefore the description thereof is omitted. - Next, operation will be described. The operation is the same as in
embodiment 1 in that desalination of treatment target water is sequentially performed while a cycle of desalination of treatment target water in thewater treatment unit 1 and washing of thewater treatment unit 1 is repeated. Hereinafter, the “reverse washing step” and the “addition reverse washing step” will be described in detail. The “desalination step” and the “washing method execution control” are the same as inembodiment 1, and therefore the description thereof is omitted. - <Reverse Washing Step>
- In the reverse washing step, first, in a state in which the
drain valve 6 and the washingwater supply valve 9 are opened and the treatment targetwater supply valve 5 is closed, the washingwater supply pump 4 is activated to inject the washing water in the reversewashing water tank 17 into thewater treatment unit 1 in a direction from the lower washingwater inlet port 1 c to theupper inlet port 1 a of thewater treatment unit 1, i.e., the direction opposite to the flow of the treatment target water. After the washing water is injected into thewater treatment unit 1 through the washingwater inlet port 1 c, the washing water flows upward and flows out to the upper side of thewater treatment unit 1 through theinlet port 1 a, and then is drained through thedrain valve 6. At this time, theair pump 39 injects air into thewater treatment unit 1 in a direction from the lower side to the upper side of thewater treatment unit 1, i.e., the direction opposite to the flow of the treatment target water. - The air injected by the
air pump 39 flows in thewater treatment unit 1 together with the washing water. By the flow of the air, a shear force acts on the surfaces of the firstgranular electrode member 18 and the secondgranular electrode member 19, thereby removing biofilm and/or scale adhered to the surfaces of the granular electrode members. The flow speed of the air injected by theair pump 39 is 0.5 to 1.5 m/min, or desirably, 0.7 to 0.9 m/min, and the air injection time is 1 to 10 minutes, or desirably, 2 to 5 minutes. If the flow speed is too high, the shear force acting on the surfaces of the granular electrode members becomes excessive and thus the surfaces are worn out, so that the specific surface area is reduced, leading to decrease in capacitor. On the other hand, if the flow speed is too low, the effect of washing by air is reduced. In addition, if the injection time is too long, a time is taken for washing, leading to reduction of desalination efficiency. On the other hand, if the injection time is too short, the effect of washing by air is reduced. - The other matters are the same as in
embodiment 1. - <Addition Reverse Washing Step>
- In the addition reverse washing step, first, the
additive supply valve 10 is opened and theadditive supply pump 37 is activated to add a predetermined amount of additive to the washing water in the reversewashing water tank 17 from theadditive storage tank 16. Next, thestirrer 36 stirs and mixes the additive and the washing water to generate additive containing washing water. - Next, in a state in which the
drain valve 6 and the washingwater supply valve 9 are opened and the treatment targetwater supply valve 5 is closed, the washingwater supply pump 4 is activated to inject the additive containing washing water in the reversewashing water tank 17 into thewater treatment unit 1 in a direction from the lower washingwater inlet port 1 c to theupper inlet port 1 a of thewater treatment unit 1, i.e., the direction opposite to the flow of the treatment target water. After the additive containing washing water is injected into thewater treatment unit 1 through the washingwater inlet port 1 c, the additive containing washing water flows upward and flows out to the upper side of thewater treatment unit 1 through theinlet port 1 a, and then is drained through thedrain valve 6. At this time, theair pump 39 injects air into thewater treatment unit 1 in a direction from the lower side to the upper side in the drawing, i.e., the direction opposite to the flow of the treatment target water. The air injected by theair pump 39 flows in thewater treatment unit 1 together with the additive containing washing water. By the flow of the air, a shear force acts on the surfaces of the firstgranular electrode member 18 and the secondgranular electrode member 19, thereby removing and injecting biofilm and/or scale adhered to the surfaces of the granular electrode members. The flow speed and the injection time for the air are the same as in the reverse washing step. - The other matters are the same as in
embodiment 1. - In
embodiment 8, the same effects as inembodiment 1 can be obtained. - In addition, air is injected into the water treatment unit in the reverse washing step and the addition reverse washing step, and by the flow of the air, a shear force acts on the surfaces of the granular electrode members, whereby a high washing effect can be obtained. In addition, a shear force applied between the granules of the granular electrode members increases, whereby a further increased washing effect can be obtained.
- Hereinafter,
embodiment 9 of the present invention will be described with reference toFIG. 12 . Parts that are the same as or correspond to those inFIG. 1 are denoted by the same reference characters, and the description thereof is omitted.Embodiment 9 is different fromembodiment 1 in that temporal change in the electric conductivity of the treatment target water during desalination is used as a finish determination index for the desalination step.FIG. 12 is a configuration diagram of a water treatment apparatus according toembodiment 9 of the present invention. In awater treatment apparatus 900, thewater treatment unit 1 is provided with a water treatment unitstate measurement unit 40 for measuring the state in thewater treatment unit 1. Inembodiment 9, the water treatment unitstate measurement unit 40 is an electric conductivity meter for measuring the electric conductivity of the treatment target water during desalination in thewater treatment unit 1. The water treatment unitstate measurement unit 40 is connected to thecontrol unit 14, and is controlled by thecontrol unit 14 during execution of each processing step. - The other matters are the same as in
embodiment 1, and therefore the description thereof is omitted. - Next, operation will be described. The operation is the same as in
embodiment 1 in that desalination of treatment target water is sequentially performed while a cycle of desalination of treatment target water in thewater treatment unit 1 and washing of thewater treatment unit 1 is repeated. Hereinafter, the “desalination step” will be described in detail. The “reverse washing step”, the “addition reverse washing step”, and the “washing method execution control” are the same as inembodiment 1, and therefore the description thereof is omitted. - <Desalination Step>
- Control of the valves and the like and the flows of the treatment target water and the desalinated water in the desalination step are the same as in
embodiment 1. The water treatment unitstate measurement unit 40 measures the electric conductivity of treatment target water that is being subjected to desalination in thewater treatment unit 1, at predetermined time intervals, during execution of the desalination step. A result of the measurement after x has elapsed since the start of the desalination step is defined as A(x), and a result of the measurement after (x+y) has elapsed is defined as A(x+y). When A(x+y) has become 0.8 to 1.0 times, or desirably, 0.95 to 1.0 times A(x), the desalination step is finished. If the desalination step is finished when A(x+y) is smaller than 0.8 times A(x), the desalination step is finished in a state in which the desalination still can be performed, and thus the desalination is insufficient. On the other hand, if the desalination step is finished when A(x+y) is greater than 1.0 times A(x), ions have been adsorbed to a deep part of each granular electrode member and thus a time is required for washing. Therefore, the time periods of the washing step and the addition reverse washing step are prolonged, so that desalination efficiency is reduced. In addition, desalinated water needed for washing increases, and thus the recovery amount of the desalinated water decreases. It is noted that x is an optional value, and y is 1 to 15 minutes, or desirably, 1 to 10 minutes. If y is too great, the time period of the desalination step is prolonged, so that ions are adsorbed to a deep part of each granular electrode member and a time is required for washing. Thus, the time periods of the washing step and the addition reverse washing step are prolonged and desalination efficiency is reduced. In addition, the amount of desalinated water needed for washing increases, and thus the recovery amount of the desalinated water decreases. On the other hand, if y is too small, the desalination step is finished even though the electric conductivity temporarily decreases, leading to insufficient desalination. - In
embodiment 9, the same effects as inembodiment 1 can be obtained. - In addition, since the electric conductivity of the treatment target water during desalination is used as the finish determination index for the desalination step, determination as to finish of the desalination step is performed while the ion concentration in the treatment target water is reflected therein. Since the ion concentration in the treatment target water directly relates to desalination performance of the water treatment unit, it is possible to perform more effective and efficient desalination while maximally using the desalination performance of the water treatment unit.
- Although not shown, the configuration in which temporal change in the electric conductivity of the treatment target water during desalination is used as a finish determination index for the desalination step as in
embodiment 9, is also applicable toembodiments 2 to 8. - Hereinafter,
embodiment 10 of the present invention will be described with reference toFIG. 1 .Embodiment 10 is different fromembodiment 1 in that an execution period is used as a finish determination index for the reverse washing step and the addition reverse washing step. The other matters are the same as inembodiment 1, and therefore the description thereof is omitted. The “reverse washing step” and the “addition reverse washing step” will be described in detail. - <Reverse Washing Step>
- Control of the valves and the like and the flow of washing water in the reverse washing step are the same as in
embodiment 1. When the execution period of the reverse washing has reached 1 to 60 minutes, or desirably, 3 to 30 minutes since the start of the reverse washing, the reverse washing step is finished. If the execution period of the reverse washing step is too long, a time is taken for the washing, so that the amount of desalinated water that is recovered is decreased, leading to reduction in desalination efficiency. On the other hand, if the execution period of the reverse washing step is too short, each granular electrode member is not sufficiently washed, leading to reduction in the ion removal rate, and thus desalination efficiency in the next desalination step is reduced. - <Addition Reverse Washing Step>
- Control of the valves and the like and the flows of the additive and the additive containing washing water in the addition reverse washing step are the same as in
embodiment 1. When the execution period of the reverse washing has reached 1 to 60 minutes, or desirably, 3 to 30 minutes since the start of the reverse washing using additive containing washing water, the reverse washing using additive containing washing water is finished. If the time period of the reverse washing using additive containing washing water is too long, a time is taken for the washing and the amount of desalinated water that is recovered decreases, leading to reduction in desalination efficiency. On the other hand, the time period of the reverse washing using additive containing washing water is too short, each granular electrode member is not sufficiently washed and materials adhered to the electrode members remain, leading to reduction in the ion removal rate, and thus desalination efficiency in the next desalination step is reduced. - After the reverse washing using the additive containing washing water, flowing-out of the additive containing washing water from the
water treatment unit 1 by the treatment target water is started, and then, when the execution period of the flowing-out has reached 1 to 30 minutes, or desirably, 1 to 15 minutes since the start of the flowing-out, the flowing-out of the additive containing washing water is finished. If the time period of the flowing-out of the additive containing washing water is too short, the additive containing washing water cannot be caused to sufficiently flow out from thewater treatment unit 1. On the other hand, if the time period of the flowing-out of the additive containing washing water is too long, the treatment target water needed for causing the additive containing washing water to flow out from thewater treatment unit 1 increases, leading to reduction in the recovery rate for the desalinated water. In addition, if the time period required for causing the additive containing washing water to flow out from thewater treatment unit 1 is prolonged, the time period of the addition reverse washing step is prolonged, and thus the number of times of the desalination step decreases, leading to reduction in the recovery rate for the desalinated water. - In
embodiment 10, the same effects as inembodiment 1 can be obtained. - In addition, since the execution period is used as a finish determination index in the reverse washing step and the addition reverse washing, all of the desalination step, the reverse washing step, and the addition reverse washing step can be controlled on the basis of time, whereby operation of the water treatment apparatus can be simplified.
- The configuration in which the execution period is used as a finish determination index in the reverse washing step and the addition reverse washing as in
embodiment 10, is also applicable toembodiments 2 to 9. - Hereinafter,
embodiment 11 of the present invention will be described with reference toFIG. 1 .Embodiment 11 is different fromembodiment 1 in that the ion concentration of the removal target ion is used as a determination index in the washing method execution control. Inembodiment 11, a desalinated water ion concentration measurement unit (not shown) for measuring the ion concentration of the removal target ion in the desalinated water is connected to thewater treatment unit 1. As the desalinated water ion concentration measurement unit (not shown), an absorption photometer for measuring the ultraviolet absorbance or an ion selective electrode is used. Examples of the removal target ion include chloride ion, sodium ion, calcium ion, magnesium ion, potassium ion, sulfuric acid ion, and nitrate ion. - The other matters are the same as in
embodiment 1, and therefore the description thereof is omitted. The “washing method execution control” will be described in detail. - <Washing Method Execution Control>
- First, the
control unit 14 acquires the removal target ion concentration in the desalinated water from the desalinated water ion concentration measurement unit (not shown) and stores the removal target ion concentration into the storage unit (not shown). Next, thecontrol unit 14 reads, from the storage unit (not shown), the greater one (hereinafter, referred to as “reference removal target ion concentration”) of the removal target ion concentration at the time when the first-time desalination step is finished after thewater treatment apparatus 100 has been activated, and the removal target ion concentration at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed, and compares the reference removal target ion concentration with the present removal target ion concentration. If the present removal target ion concentration is 1 to 2 times, or desirably, 1 to 1.5 times the reference removal target ion concentration, the desalination performance of thewater treatment unit 1 has been reduced, and therefore thecontrol unit 14 determines to execute the addition reverse washing step. If the present removal target ion concentration is smaller than 1 times the reference removal target ion concentration, the desalination performance of thewater treatment unit 1 has not been reduced and it is not necessary to execute the addition reverse washing. Therefore, thecontrol unit 14 determines to execute the reverse washing step. If the present removal target ion concentration is greater than 2 times, or desirably, 1.5 times the reference removal target ion concentration, the desalination performance has been significantly reduced and therefore thecontrol unit 14 determines that it is difficult to restore the desalination performance by the addition reverse washing step. In such a case, for example, thecontrol unit 14 causes a display unit (not shown) to display an alarm indication for notification that it is necessary to replace the firstgranular electrode member 18 and the secondgranular electrode member 19, thereby prompting a user to replace the firstgranular electrode member 18 and the secondgranular electrode member 19. - In
embodiment 11, the same effects as inembodiment 1 can be obtained. - In addition, by using the ion concentration of the removal target ion as a determination index in the washing method execution control, it is possible to determine whether to execute the reverse washing step or the addition reverse washing in accordance with the ion concentration of an ion that is a main removal target. Therefore, a specific ion can be removed efficiently.
- The configuration in which the ion concentration of the removal target ion is used as a determination index in the washing method execution control as in
embodiment 11, is also applicable toembodiments 2 to 10. - Hereinafter,
embodiment 12 of the present invention will be described with reference toFIG. 1 .Embodiment 12 is different fromembodiment 1 in that hardness is used as a determination index in the washing method execution control. Inembodiment 12, a desalinated water hardness measurement unit (not shown) for measuring the hardness of desalinated water is connected to thewater treatment unit 1. As the desalinated water hardness measurement unit (not shown), a hardness meter or a hardness sensor is used. - The other matters are the same as in
embodiment 1, and therefore the description thereof is omitted. The “washing method execution control” will be described in detail. - <Washing Method Execution Control>
- First, the
control unit 14 acquires the hardness of desalinated water from the desalinated water hardness measurement unit (not shown) and stores the hardness into the storage unit (not shown). Next, thecontrol unit 14 reads, from the storage unit (not shown), the greater one (hereinafter, referred to as “reference hardness”) of the hardness of desalinated water at the time when the first-time desalination step is finished after thewater treatment apparatus 100 has been activated, and the hardness of desalinated water at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed, and compares the reference hardness with the present hardness of the desalinated water. If the present hardness of the desalinated water is 1 to 2 times, or desirably, 1 to 1.5 times the reference hardness, the desalination performance of thewater treatment unit 1 has been reduced, and therefore thecontrol unit 14 determines to execute the addition reverse washing step. If the present hardness of the desalinated water is smaller than 1 times the reference hardness, the desalination performance of thewater treatment unit 1 has not been reduced and it is not necessary to execute the addition reverse washing. Therefore, thecontrol unit 14 determines to execute the reverse washing step. If the present hardness of the desalinated water is greater than 2 times, or desirably, 1.5 times the reference hardness, the desalination performance has been significantly reduced, and therefore thecontrol unit 14 determines that it is difficult to restore the desalination performance by the addition reverse washing step. In such a case, for example, thecontrol unit 14 causes a display unit (not shown) to display an alarm indication for notification that it is necessary to replace the firstgranular electrode member 18 and the secondgranular electrode member 19, thereby prompting a user to replace the firstgranular electrode member 18 and the secondgranular electrode member 19. - In
embodiment 12, the same effects as inembodiment 1 can be obtained. - In addition, by using the hardness as a determination index in the washing method execution control, it is possible to measure the ion concentration of calcium ion, magnesium ion, or the like which is a cause of generation of scale which hampers stable desalination. Therefore, while the possibility of adhesion of scale is grasped, the addition reverse washing step can be executed at an effective timing.
- The configuration in which the hardness is used as a determination index in the washing method execution control as in
embodiment 12, is also applicable toembodiments 2 to 10. - Hereinafter,
embodiment 13 of the present invention will be described with reference toFIG. 12 .Embodiment 13 is different fromembodiment 9 in that the current value of current flowing through the water treatment unit during execution of the desalination step is used as a determination index in the washing method execution control.Embodiment 13 uses a phenomenon in which, in electric desalination technology using electrical double layer capacitor technology, desalination performance is reduced when the capacitances of the first granular electrode member and the second granular electrode member in the water treatment unit are reduced due to adhesion of scale and/or biofilm, and the reduction of the capacitances is detected on the basis of measurement of current flowing through the water treatment unit during desalination. Inembodiment 13, the water treatment unitstate measurement unit 40 is a current meter for measuring the value of current flowing through thewater treatment unit 1. - The other matters are the same as in
embodiment 1, and therefore the description thereof is omitted. The “desalination step” and the “washing method execution control” will be described in detail. - <Desalination Step>
- The
control unit 14 acquires the current value of current flowing through thewater treatment unit 1 at the start of the desalination step, from the water treatment unitstate measurement unit 40 which is a current meter, and stores the current value into the storage unit (not shown). Control of the valves and the like and the flows of treatment target water and desalinated water are the same as inembodiment 1. - <Washing Method Execution Control>
- The
control unit 14 reads, from the storage unit (not shown), the greater one (hereinafter, referred to as “reference current value”) of the current value of current flowing through the water treatment unit at the time when the first-time desalination step is finished after thewater treatment apparatus 900 has been activated, and the current value at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed, and compares the reference current value with the present current value. If the present current value is smaller than 0.5 to 1.0 times, or desirably, 0.7 to 0.9 times the reference current value, the current flowing through thewater treatment unit 1 has been reduced and thus desalination performance of thewater treatment unit 1 has been reduced. Therefore, thecontrol unit 14 determines to execute the addition reverse washing step. If the present current value is equal to or greater than 1.0 times, or desirably, 0.9 times the reference current value, the ion removal rate of thewater treatment unit 1 has not been reduced or has been slightly reduced and thus it is not necessary to execute the addition reverse washing. Therefore, thecontrol unit 14 determines to execute the reverse washing step. If the present current value is smaller than 0.5 times, or desirably, 0.7 times the reference current value, the desalination performance has been significantly reduced and therefore thecontrol unit 14 determines that it is difficult to restore the desalination performance by the addition reverse washing step. In such a case, for example, thecontrol unit 14 causes a display unit (not shown) to display an alarm indication for notification that it is necessary to replace the firstgranular electrode member 18 and the secondgranular electrode member 19, thereby prompting a user to replace the firstgranular electrode member 18 and the secondgranular electrode member 19. - Although the current value of current flowing through the
water treatment unit 1 at the start of the desalination step is used as a determination index for the washing method execution control inembodiment 13, the current value at the time when the desalination step is finished or the integral value of the current value during execution of the desalination step may be used as the determination index. - In
embodiment 13, the same effects as inembodiment 1 can be obtained. - In addition, since the current value of current flowing through the water treatment unit during execution of the desalination step is used as a determination index in the washing method execution control, the determination index is less likely to be influenced by contamination of treatment target water or desalinated water and thus it is possible to perform appropriate determination in the washing method execution control.
- In addition, since measurement of the current value is easy and can be performed stably, the water treatment unit state measurement unit can be simplified.
- Although not shown, the configuration in which the current value of current flowing through the water treatment unit during the desalination step is used as a determination index in the washing method execution control as in
embodiment 13, is also applicable toembodiments 2 to 10. - Hereinafter,
embodiment 14 of the present invention will be described with reference toFIG. 12 .Embodiment 14 is different fromembodiment 9 in that the voltage value between both ends of the water treatment unit at the time when the desalination step is finished and voltage drop thereof at the time of discharging after the desalination step is finished, are used as determination indices in the washing method execution control.Embodiment 14 uses a phenomenon in which, in electric desalination technology using electrical double layer capacitor technology, when the capacitances of the first granular electrode member and the second granular electrode member in the water treatment unit are reduced due to adhesion of scale and/or biofilm, desalination performance is reduced, and when the internal resistance in the water treatment unit is increased due to adhesion of scale and/or biofilm, desalination performance is reduced and the internal resistance is increased. The reduction in the capacitances is detected on the basis of measurement of the voltage value between both ends of the water treatment unit at the time when the desalination step is finished, and the increase in the internal resistance is detected on the basis of measurement of voltage drop at the time of discharging after the desalination step. Inembodiment 14, the water treatment unitstate measurement unit 40 is a voltage meter for measuring the voltage value between both ends of thewater treatment unit 1, i.e., between the pair ofcollectors - The other matters are the same as in
embodiment 1, and therefore the description thereof is omitted. The “desalination step” and the “washing method execution control” will be described in detail. - <Desalination Step>
- The
control unit 14 acquires the voltage value between both ends of thewater treatment unit 1 at the time when the desalination step is finished and voltage drop thereof at the time of discharging after the desalination step, from the water treatment unitstate measurement unit 40 which is a voltage meter, and stores the voltage value and voltage drop into the storage unit (not shown). Control of the valves and the like and the flows of the treatment target water and the desalinated water are the same as inembodiment 1. - <Washing Method Execution Control>
- The
control unit 14 reads, from the storage unit (not shown), the greater one (hereinafter, referred to as “reference voltage value”) of the voltage value between both ends of thewater treatment unit 1 at the time when the first-time desalination step is finished after thewater treatment apparatus 900 has been activated, and the voltage value at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed, and the smaller one (hereinafter, referred to as “reference voltage drop”) of the voltage drop between the both ends of thewater treatment unit 1 at the time of discharging immediately after the first-time desalination step is finished after activation of thewater treatment apparatus 900, and the voltage drop at the time of discharging immediately after the first-time desalination step is finished after the previous execution of the addition reverse washing step. Then, thecontrol unit 14 compares the reference voltage value and the reference voltage drop with the present voltage value and the present voltage drop, respectively. If the present voltage value is smaller than 0.5 to 1.0 times, or desirably, 0.7 to 0.9 times the reference current value, or if the present voltage drop is 1 to 5 times, or desirably, 1 to 2 times the reference voltage drop, biofilm and/or scale has been adhered to the firstgranular electrode member 18 and the secondgranular electrode member 19 and thus desalination performance of thewater treatment unit 1 has been reduced. Therefore, thecontrol unit 14 determines to execute the addition reverse washing step. - In
embodiment 14, the same effects as inembodiment 1 can be obtained. - In addition, in the washing method execution control, since the voltage value between both ends of the water treatment unit at the time when the desalination step is finished and voltage drop thereof at the time of discharging after the desalination step is finished are used as determination indices in the washing method execution control, the determination indices are less likely to be influenced by contamination of treatment target water or desalinated water and thus it is possible to perform appropriate determination in the washing method execution control.
- In addition, since measurement of the voltage value is easy and can be performed stably, the water treatment unit state measurement unit can be simplified.
- Although not shown, the configuration in which the voltage value between both ends of the water treatment unit at the time when the desalination step is finished and voltage drop at the time of discharging after the desalination step is finished are used as determination indices in the washing method execution control as in
embodiment 14, is also applicable toembodiments 2 to 10. - Hereinafter,
embodiment 15 of the present invention will be described with reference toFIG. 1 .Embodiment 15 is different fromembodiment 1 in that pressure loss in the water treatment unit at the time when the desalination step is finished is used as a determination index in the washing method execution control.Embodiment 15 uses a phenomenon in which, in electric desalination technology using electrical double layer capacitor technology, while the desalination step is repeated, accumulation of biofilm and/or scale and contraction of the granular electrode members due to wearing occur and thus their surface areas are reduced, and the capacitances are reduced, whereby desalination performance is reduced and the occlusion degree of the first granular electrode member and the second granular electrode member is increased. Increase in the occlusion degree is detected on the basis of measurement of pressure loss. Inembodiment 15, the treatment targetwater measurement unit 11 and the desalinatedwater measurement unit 12 include pressure meters for measuring the pressures of treatment target water and desalinated water, respectively. - The other matters are the same as in
embodiment 1, and therefore the description thereof is omitted. The “desalination step” and the “washing method execution control” will be described in detail. - <Desalination Step>
- The
control unit 14 acquires the pressures of treatment target water flowing into thewater treatment unit 1 and desalinated water flowing out from thewater treatment unit 1, from the treatment targetwater measurement unit 11 and the desalinatedwater measurement unit 12, when the desalination step is finished, and then thecontrol unit 14 calculates pressure loss in thewater treatment unit 1 and stores the pressure loss into the storage unit (not shown). Control of the valves and the like and the flows of the treatment target water and the desalinated water are the same as inembodiment 1. - <Washing Method Execution Control>
- The
control unit 14 reads, from the storage unit (not shown), the greater one (hereinafter, referred to as “reference pressure loss”) of the pressure loss in thewater treatment unit 1 at the time when the first-time desalination step is finished after thewater treatment apparatus 100 has been activated, and the pressure loss at the time when the first-time desalination step is finished after the previous addition reverse washing step has been executed, and compares the reference pressure loss with the present pressure loss. If the present pressure loss is 1 to 5 times, or desirably, 1.5 to 3 times the reference pressure loss, biofilm and/or scale has been accumulated and the firstgranular electrode member 18 and the secondgranular electrode member 19 have contracted, whereby desalination performance has been reduced. Therefore, thecontrol unit 14 determines to execute the addition reverse washing step. If the present pressure loss is smaller than 1 times, or desirably, 1.5 times the reference pressure loss, the ion removal rate of thewater treatment unit 1 has not been reduced or has been slightly reduced and thus it is not necessary to execute the addition reverse washing. Therefore, thecontrol unit 14 determines to execute the reverse washing step. If the present pressure loss is 5 times, or desirably, 3 times the reference pressure loss, desalination performance has been significantly reduced and therefore thecontrol unit 14 determines that it is difficult to restore desalination performance by the addition reverse washing step. In such a case, for example, thecontrol unit 14 causes a display unit (not shown) to display an alarm indication for notification that it is necessary to replace the firstgranular electrode member 18 and the secondgranular electrode member 19, thereby prompting a user to replace the firstgranular electrode member 18 and the secondgranular electrode member 19. - In
embodiment 15, the same effects as inembodiment 1 can be obtained. - In addition, in the washing method execution control, since pressure loss in the water treatment unit at the time when the desalination step is finished is used as a determination index in the washing method execution control, the determination index is less likely to be influenced by contamination of treatment target water or desalinated water, and therefore it is possible to comprehensively and easily grasp increase in the occlusion degree of the first granular electrode member and the second granular electrode member. Thus, it is possible to easily perform appropriate determination in the washing method execution control.
- Although not shown, the configuration in which pressure loss in the water treatment unit at the time when the desalination step is finished is used as a determination index in the washing method execution control as in
embodiment 15, is also applicable toembodiments 2 to 10. - Hereinafter,
embodiment 16 of the present invention will be described with reference toFIGS. 13 to 16 . Inembodiment 16, a pressing portion for pressing the first granular electrode member and the second granular electrode member is provided to the water treatment unit described in any ofembodiments 1 to 15.FIG. 13 is a perspective view showing the water treatment unit according toembodiment 16,FIG. 14 is a top view showing the water treatment unit according toembodiment 16, andFIG. 15 andFIG. 16 are sectional views along P-P line and Q-Q line inFIG. 14 . As shown inFIG. 13 , awater treatment unit 101 is configured such that a firstgranular electrode member 181, a secondgranular electrode member 191, a pair ofcollectors separator 211, which correspond to the firstgranular electrode member 18, the secondgranular electrode member 19, and the pair ofcollectors separator 21 described in theabove embodiments 1 to 15, are stored in atreatment container 48. Thetreatment container 48 is, for example, a rectangular parallelepiped, and a plate-shapedlid 49 is placed above the upper surface of thetreatment container 48 while a packing 43 formed from an elastic member is provided therebetween. Thelid 49 has a predetermined thickness, and is fastened to thetreatment container 48 by fourscrews 44 passing through-holes (not shown) formed at the four corners. Inside thetreatment container 48, the pair ofcollectors separator 211 therebetween, and the firstgranular electrode member 181 and the secondgranular electrode member 191 are placed between theseparator 211 and the pair ofcollectors granular electrode member 181 and the secondgranular electrode member 191, a resin material having an insulation property or metal having an electrically insulating coat is used as the materials of thetreatment container 48 and thelid 49. - As shown in
FIG. 13 andFIG. 14 , the lower surface of thelid 49 has a pair ofcollector grooves collectors separator groove 50 into which the upper end of theseparator 211 is inserted. The pair ofcollectors collector grooves separator 21 is positioned by its upper end being fitted to theseparator groove 50. - The first
granular electrode member 181 and the secondgranular electrode member 191 serve to adsorb ions in treatment target water when voltage is applied. The granular electrode members included in the firstgranular electrode member 181 and the secondgranular electrode member 191 in the present embodiment are not made into a sheet form or the like, and are provided in thetreatment container 48 in a state in which the granules are not fixed to each other. That is, the firstgranular electrode member 181 and the secondgranular electrode member 191 are each configured to include a plurality of flowable granular electrode members. As the materials of the granular electrode members included in the firstgranular electrode member 181 and the secondgranular electrode member 191, a conductive material which has conductivity and a great specific surface area and has a great capacitance as a capacitor is used. For example, activated carbon, porous carbon, porous conductive beads, or porous metal is used. These conductive materials may be formed in a powder shape, a granular shape, or the like, and in the case of powder shape or granular shape, the outer diameter thereof is 50 nm to 10 mm. - The interval between the
separator 211 and eachcollector granular electrode member 181 and the secondgranular electrode member 191. If the interval between theseparator 211 and eachcollector granular electrode member 181 and the secondgranular electrode member 191, the firstgranular electrode member 181 and the secondgranular electrode member 191 cannot be provided between theseparator 211 and thecollectors granular electrode member 181 and the entire secondgranular electrode member 191 are increased, so that desalination performance in the desalination step is reduced. This is because, as the thicknesses of the firstgranular electrode member 181 and the secondgranular electrode member 191 are increased, the number of granules of the granular electrode members included in each of them is increased, leading to formation of a large number of contact portions between granules, which have a great electric resistance due to contact resistance. - The pair of
collectors granular electrode member 181 and the secondgranular electrode member 191, and collecting electricity at the time of discharging. The pair ofcollectors collectors terminals collectors terminals holes lid 49 so as to be exposed to outside, and are used for making electric connection between a power supply (not shown), and the pair ofcollectors granular electrode member 181 and the secondgranular electrode member 191. Thus, when electricity is applied to theterminals granular electrode member 181 and the secondgranular electrode member 191. - The
separator 211 prevents short-circuit between the firstgranular electrode member 181 and the secondgranular electrode member 191, and is formed from a material such as filter paper, a porous film, nonwoven fabric, a foamed material, or the like which allows transmission of liquid but blocks a conductive material so as to make electric insulation. - An
inlet port 101 a of thewater treatment unit 101 is provided at one side surface of thetreatment container 48, and communicates between outside of thetreatment container 48 and a space between the pair ofcollectors granular electrode member 181, the secondgranular electrode member 191, and theseparator 211 are placed. Thus, thewater treatment unit 101 allows treatment target water to be directly injected into the space in which the firstgranular electrode member 181, the secondgranular electrode member 191, and theseparator 211 are placed. Anoutlet port 101 b of thewater treatment unit 101 is provided on another side surface of thetreatment container 48, and communicates between outside of thetreatment container 48 and a space between the pair ofcollectors water treatment unit 101 allows treatment target water to be directly discharged from the space in which the firstgranular electrode member 181, the secondgranular electrode member 191, and theseparator 211 are placed. Theinlet port 101 a and theoutlet port 101 b are formed from a resin material having insulation property, such as acrylic resin, or metal having an electrically insulating coat, such as fluorine-coated stainless steel, in order to prevent short-circuit between the firstgranular electrode member 181 and the secondgranular electrode member 191. - At the end of the
inlet port 101 a on the inner side of thetreatment container 48 and the end of theoutlet port 101 b on the inner side of thetreatment container 48, as shown inFIG. 16 , flow-out preventingmembers 52 are attached for preventing conductive materials constituting the firstgranular electrode member 181 and the secondgranular electrode member 191 from flowing out from thetreatment container 48. The flow-out preventingmembers 52 are formed by a resin net having an insulating property or a metal mesh having an insulating coat, for example. Inembodiment 16, theinlet port 101 a is located at the lower part of the side surface of thetreatment container 48, and theoutlet port 101 b is located at the upper part of the side surface of thetreatment container 48. However, the locations of theinlet port 101 a and theoutlet port 101 b are not limited thereto. For example, theinlet port 101 a may be located at the upper part of the side surface of thetreatment container 48 and theoutlet port 101 b may be located at the lower part of the side surface of thetreatment container 48. Alternatively, both or one of theinlet port 101 a and theoutlet port 101 b may be located near the center of the side surface of thetreatment container 48. Still alternatively, they may be located at thelid 49. - At the
lid 49, apressing portion 47 is formed above the firstgranular electrode member 181 and the secondgranular electrode member 191 as shown inFIGS. 13, 15, and 16 . Thepressing portion 47 is formed in a projection shape so as to protrude toward inside of thetreatment container 48, and has a lower surface formed in a flat shape so that a pressing force can be applied uniformly to the firstgranular electrode member 181 and the secondgranular electrode member 191. The size of thepressing portion 47 is designed so that the firstgranular electrode member 181 and the secondgranular electrode member 191 come into a predetermined pressed state when thescrews 44 are screwed to the end. - Next, operation will be described. As the four
screws 44 are screwed into the screw holes of thetreatment container 48, thepressing portion 47 gradually presses the firstgranular electrode member 181 and the secondgranular electrode member 191 in thetreatment container 48 from above, and when thescrews 44 are screwed to the end, the firstgranular electrode member 181 and the secondgranular electrode member 191 are brought into a predetermined pressed state. In this way, thewater treatment unit 101 brings the firstgranular electrode member 181 and the secondgranular electrode member 191 into a predetermined pressed state by thelid 49 of thetreatment container 48, and keeps the pressed state of the firstgranular electrode member 181 and the secondgranular electrode member 191 by the fastening force of thescrews 44 during a period in which the treatment target water is treated in thetreatment container 48 in the desalination step. In the pressed state, the granules of the conductive materials constituting the firstgranular electrode member 181 and the secondgranular electrode member 191 are fixed and thus no longer flow. However, as described above, the granules of the firstgranular electrode member 181 and the secondgranular electrode member 191 are not fixed to each other and therefore can flow in a non-pressed state such as a state before the pressing and a state after cancelation of the pressing. - Here, the pressed state by the
pressing portion 47 will be described. The pressed state by thepressing portion 47 is prescribed by a compression rate P defined as P=B/A. In this definition, A is the volume of the firstgranular electrode member 181 and the secondgranular electrode member 191 before thelid 49 is attached to thetreatment container 48, and B is the volume of the firstgranular electrode member 181 and the secondgranular electrode member 191 when thelid 49 is attached to thetreatment container 48 and thescrews 44 are screwed to the end. In the case where the horizontal sectional area of the firstgranular electrode member 181 and the secondgranular electrode member 191 is constant between before and after pressing, the compression rate P is equal to the ratio between a height H1 of thelid 49 when thelid 49 is merely placed on the firstgranular electrode member 181 and the secondgranular electrode member 191 and thescrews 44 are not screwed at all, and a height H2 of thelid 49 after thescrews 44 are screwed to the end. In the present embodiment, the firstgranular electrode member 181 and the secondgranular electrode member 191 are placed between thecollector 281 a and theseparator 211 and between thecollector 281 b and theseparator 211, and the pair ofcollectors separator 211 are positioned by thecollector grooves separator groove 50. Therefore, it can be said that the horizontal sectional area of the firstgranular electrode member 181 and the secondgranular electrode member 191 is constant between before and after pressing, and thus the compression rate P can be considered to be equal to the ratio between the height H1 of thelid 49 when thelid 49 is merely placed on the firstgranular electrode member 181 and the secondgranular electrode member 191 and thescrews 44 are not screwed at all, and the height H2 of thelid 49 after thescrews 44 are screwed to the end, i.e., P=H2/H1. - In the case where the
treatment container 48 is transparent and thus the inside of thetreatment container 48 is visible, the values of A and B can be acquired by actually measuring the dimensions of the firstgranular electrode member 181 and the secondgranular electrode member 191, and the compression rate P can be calculated from the acquired values of A and B. In the case where thetreatment container 48 is not transparent and the inside of thetreatment container 48 is not visible, the compression rate P is calculated from the height H1 of thelid 49 when thelid 49 is merely placed on the firstgranular electrode member 181 and the secondgranular electrode member 191 and thescrews 44 are not screwed at all, and the height H2 of thelid 49 after thescrews 44 are screwed to the end. - The compression rate P is prescribed in a range of 0.5 to 0.99, or desirably, 0.7 to 0.95. If the compression rate P is greater than 0.99, the contact area between the conductive materials constituting the first
granular electrode member 181 and the secondgranular electrode member 191 decreases and the electric resistance increases, and this is not preferable. If the compression rate P is smaller than 0.5, the conductive materials are crushed and flow out from thetreatment container 48 together with treatment target water, and this is not preferable. - The pressed state of the first
granular electrode member 181 and the secondgranular electrode member 191 may be prescribed by the value of the electric resistance between the pair ofcollectors - In the case of prescribing the pressed state by the value of electric resistance, a value in a range of 0.01 to 100Ω, or desirably, 0.05 to 50Ω is used. Since the conductive materials constituting the
separator 211, the firstgranular electrode member 181, and the secondgranular electrode member 191 have a resistance, the value of electric resistance cannot be made smaller than 0.01Ω. On the other hand, in the case of being greater than 100Ω, desalination performance is deteriorated, and this is not preferable. - In the case of prescribing the pressed state by pressure loss, a value in a range of 0.001 to 1000 kPa/m, or desirably, 0.05 to 500 kPa/m is used. Since the conductive materials constituting the first
granular electrode member 181 and the secondgranular electrode member 191 have a water passing resistance, the pressure loss cannot be made smaller than 0.001 kPa/m. On the other hand, in the case of being greater than 1000 kPa/m, energy consumption relevant to water injection into thewater treatment unit 101 increases, and this is not preferable. - If the pressed state by the
pressing portion 47 is prescribed in an appropriate range as described above, the gaps in the conductive materials constituting the firstgranular electrode member 181 and the secondgranular electrode member 191 are finely divided, and flow of treatment target water into the gaps is also finely divided. Thus, the distance between ions in the treatment target water and the conductive materials constituting the firstgranular electrode member 181 and the secondgranular electrode member 191 is shortened, whereby adsorption of the ions to the first granular electrode member and the second granular electrode member is promoted. In addition, owing to the fine division, the flow of the treatment target water has a uniform thickness in the firstgranular electrode member 181 and the secondgranular electrode member 191. In addition, the contact area between the conductive materials constituting the firstgranular electrode member 181 and the secondgranular electrode member 191 increases, and the electric resistance decreases. - In
embodiment 16, the same effects as inembodiment 1 can be obtained. - In addition, the water treatment unit is configured such that the pair of collectors are placed with the separator therebetween in the treatment container, the first granular electrode member and the second granular electrode member are placed between the separator and the pair of collectors, and the pressing portion for pressing the first granular electrode member and the second granular electrode member and keeping the pressed state is formed at the lid of the treatment container. Thus, the first granular electrode member and the second granular electrode member are formed by only conductive materials without using an additive such as a binder. Therefore, in the desalination step, the pores and the gaps in the conductive materials constituting the first granular electrode member and the second granular electrode member can be prevented from being occluded, and pressure loss due to injection of treatment target water can be decreased.
- By keeping the pressed state of the first granular electrode member and the second granular electrode member, the gaps in the conductive materials constituting the first granular electrode member and the second granular electrode member are finely divided, and therefore flow of treatment target water into the gaps is also finely divided, whereby the distance between the ions in the treatment target water and the conductive materials is shortened, and thus adsorption of ions to the first granular electrode member and the second granular electrode member is promoted. Further, owing to the fine division of the water flow, flow of treatment target water in the first granular electrode member and the second granular electrode member has a uniform thickness, and therefore adsorption of ions is uniformly performed. Since promotion of ion adsorption and uniform ion adsorption are achieved, desalination performance can be further improved.
- In addition, by keeping the pressed state of the first granular electrode member and the second granular electrode member, the electric resistance of the first granular electrode member and the second granular electrode member is reduced, and therefore applied electricity can be passed throughout the first granular electrode member and the second granular electrode member, and the pores in the conductive materials constituting the first granular electrode member and the second granular electrode member can be used without waste.
- In addition, the treatment container is provided with the inlet port communicating between outside of the treatment container and the space in which the first granular electrode member, the second granular electrode member, and the separator are placed, so that the treatment target water directly flows into the first granular electrode member, the second granular electrode member, and the separator. Therefore, the treatment target water can spread over the entirety of the separator, the first granular electrode member, and the second granular electrode member.
- In
embodiment 16, the pressing portion is formed at the lid of the treatment container. However, without limitation thereto, for example, the lid and the pressing portion may be separate members. In this case, only the pressing portion may be fastened by screws, and the lid may be fixed to the treatment container by another fixation member. Inembodiment 16, the separator groove and the pair of collector grooves are formed on the lid. However, without limitation thereto, for example, the separator groove and the pair of collector grooves may be formed in the treatment container, or may be formed for both of the lid and the treatment container. - Hereinafter,
embodiment 17 of the present invention will be described with reference toFIG. 17 .Embodiment 17 relates to a configuration in which, in the water treatment unit described in any ofembodiments 1 to 15, a pressing portion for pressing the first granular electrode member and the second granular electrode member is provided to the water treatment unit, and the pair of collectors and the separator are arranged in the vertical direction.FIG. 17 is a perspective view showing awater treatment unit 102 according toembodiment 17 of the present invention. As shown inFIG. 17 , awater treatment unit 102 is configured such that a firstgranular electrode member 182, a secondgranular electrode member 192, a pair ofcollectors separator 212, which correspond to the firstgranular electrode member 18, the secondgranular electrode member 19, the pair ofcollectors separator 21 described in theabove embodiments 1 to 15, are stored in acylindrical treatment container 58. Acylindrical lid 59 is placed above the upper surface of thetreatment container 58 while a packing 53 formed from an elastic member is provided therebetween. Thelid 59 has a predetermined height, and is fastened to thetreatment container 58 by fourscrews 54 passing through-holes (not shown). Thetreatment container 48 is provided with aninlet port 102 a through which treatment target water flows into thetreatment container 48 from outside, and thelid 49 is provided with anoutlet port 102 b through which treatment target water flows to outside from inside of thetreatment container 48. - Inside the
treatment container 58, the pair ofcollectors separator 212 therebetween, and the cylindrical firstgranular electrode member 182 and the cylindrical secondgranular electrode member 192 are placed between theseparator 212 and thecollectors collectors terminals granular electrode member 182 and the secondgranular electrode member 192 are not made into a sheet form or the like, and are provided in thetreatment container 48 in a state in which the granules are not fixed to each other. That is, the firstgranular electrode member 182 and the secondgranular electrode member 192 are each configured to include a plurality of flowable granular electrode members. The thicknesses of the firstgranular electrode member 182 and the secondgranular electrode member 192 are not prescribed, and the thicknesses of the firstgranular electrode member 182 and the secondgranular electrode member 192 can be changed by change of the amount of the conductive materials, whereby desalination performance can be adjusted. - A
pressing portion 57 which comes into contact with the upper surface of thecollector 282 a is formed at thelid 59. Thepressing portion 57 presses the firstgranular electrode member 182 and the secondgranular electrode member 192 via thecollector 282 a, by thelid 59 being fastened to thetreatment container 58 by the fourscrews 54. In a pressed state, the granules of the firstgranular electrode member 182 and the secondgranular electrode member 192 are fixed and thus no longer flow. However, as described above, the granules of the firstgranular electrode member 182 and the secondgranular electrode member 192 are not fixed to each other and therefore can flow in a non-pressed state such as a state before the pressing and a state after the pressing is canceled. - One end of a
terminal bar 56 a provided so as to penetrate thelid 59 is connected to the terminal 55 a protruding on the side surface of thecollector 282 a, and one end of aterminal bar 56 b provided so as to penetrate the bottom surface of thetreatment container 58 is connected to the terminal 55 b protruding on the side surface of thecollector 282 b.Terminals collectors granular electrode member 182, and the secondgranular electrode member 192, and thus treatment target water is desalinated. As inembodiment 16, during the desalination step, the pressed state of the firstgranular electrode member 182 and the secondgranular electrode member 192 by thepressing portion 57 is kept. - In
embodiment 17, the same effects as inembodiment 1 can be obtained. - In addition, the thicknesses of the first granular electrode member and the second granular electrode member can be changed by change of the amount of conductive materials, whereby desalination performance can be adjusted. Thus, adjustment of desalination performance can be easily performed.
- In addition, by the
pressing portion 57, the first granular electrode member and the second granular electrode member are pressed in a direction in which they are sandwiched between the pair of collectors. Therefore, the pair of collectors, and the first granular electrode member and the second granular electrode member, can be brought into close contact with each other, whereby the electric resistance during desalination can be decreased. - It is noted that, within the scope of the present invention, the above embodiments may be freely combined with each other, or each of the above embodiments may be modified or simplified as appropriate, whereby the present invention is applicable to water treatment for water purification, sewage, drainage, desalination, or the like. In addition, the present invention is also applicable to, for example, generation of sprinkling water, cooling water, production water, or washing water for air conditioners. Further, the present invention can be used in combination with a water heater, a dishwasher, a laundry machine, a cold/hot water system, an electric water heater, or a humidifier, and also, can be used as a water purifier. Besides the above devices, the present invention can be used in combination with a device that needs desalinated water, or can be mounted thereto.
-
-
- 1, 1A, 1B, 101, 102 water treatment unit
- 1 e additive injection port
- 4, 4A, 4B washing water supply pump
- 14 control unit
- 16, 16 a, 16 b, 16 c additive storage tank
- 17 reverse washing water tank
- 18, 18A, 18B, 181, 182 first granular electrode member
- 19, 19A, 19B, 191, 192 second granular electrode member
- 20 power supply unit
- 21, 21A, 21B, 211, 212 separator
- 27 additive generation unit
- 37 additive supply pump
- 38 additive injection portion
- 39 air pump
- 47, 57 pressing portion
- 100, 200, 300, 400, 500, 600, 700, 800, 900 water treatment apparatus
Claims (21)
1: A water treatment apparatus comprising:
a first electrode and a second electrode stored in a water treatment unit and provided so as to be separated from each other by a separator which has an electric insulation property and allows a liquid to pass therethrough;
a power supplier which is connected to a pair of collectors provided at both ends of the water treatment unit and applies voltage between the first electrode and the second electrode via the pair of collectors so that ions contained in treatment target water supplied from one side of the water treatment unit via an inlet port are adsorbed to the first electrode and the second electrode, thereby performing desalination and generating desalinated water; and
a washing water supply pump which causes washing water to flow from the other side of the water treatment unit to the one side of the water treatment unit, thereby washing the first electrode and the second electrode, wherein
the first electrode and the second electrode each include a plurality of flowable granular electrode members, and the inlet port is provided with a flow-out preventing member for preventing the granular electrode members from flowing out from the water treatment unit.
2: The water treatment apparatus according to claim 1 , wherein
the water treatment unit includes a pressing portion for pressing the first electrode and the second electrode.
3: The water treatment apparatus according to claim 1 , further comprising:
an additive supplier which supplies an additive to the washing water; and
a controller which determines whether or not to add the additive to the washing water.
4: The water treatment apparatus according to claim 3 , further comprising a reverse washing water tank which stores the desalinated water as the washing water.
5: The water treatment apparatus according to claim 4 , wherein
the additive supplier supplies the additive to the washing water stored in the reverse washing water tank.
6. (canceled)
7: The water treatment apparatus according to claim 5 , wherein
the additive supplier is provided to a pipe connecting the water treatment unit and the washing water supply pump.
8: The water treatment apparatus according to claim 3 , wherein
the additive supplier generates the additive and directly injects the additive through an additive injection port provided to the water treatment unit.
9: The water treatment apparatus according to claim 8 , wherein
a plurality of additive injection ports are provided to the water treatment unit.
10-16. (canceled)
17: The water treatment apparatus according to claim 1 , further comprising a circulation path through which the washing water flowing from the one side of the water treatment unit is sent to the other side of the water treatment unit.
18: The water treatment apparatus according to claim 1 , wherein
the water treatment unit comprises a plurality of water treatment units connected in series and sharing a reverse washing water tank which stores the desalinated water as the washing water.
19. (canceled)
20: The water treatment apparatus according to claim 1 , further comprising an air pump which injects air into the water treatment unit during washing of the first electrode and the second electrode.
21: A water treatment method comprising:
a desalination step of supplying treatment target water from one side of a water treatment unit which stores a first electrode and a second electrode provided so as to be separated from each other by a separator which has an electric insulation property and allows a liquid to pass therethrough, and applying voltage to the first electrode and the second electrode via a pair of collectors provided at both ends of the water treatment unit, so that ions contained in the treatment target water are adsorbed to the first electrode and the second electrode, thereby performing desalination and generating desalinated water; and
a washing step of washing the first electrode and the second electrode by causing washing water to flow from the other side of the water treatment unit to the one side of the water treatment unit, wherein
in the washing step, the first electrode and the second electrode are washed while granular electrode members contained in the first electrode and the second electrode are caused to flow in the water treatment unit.
22: The water treatment method according to claim 21 , wherein
the first electrode and the second electrode are pressed so as to be brought into a pressed state, the desalination step is executed while the pressed state is kept, and the washing step is executed after the pressed state is released.
23: The water treatment method according to claim 21 , further comprising a step of determining whether or not to add an additive to the washing water, between after the desalination step and before the washing step.
24: The water treatment method according to claim 21 , wherein
the desalinated water generated in the desalination step is stored, and the stored desalinated water is used as the washing water.
25: The water treatment method according to claim 23 , wherein
after the first electrode and the second electrode are washed using the washing water to which a first additive is added, the first electrode and the second electrode are washed using the washing water to which a second additive is added.
26-32. (canceled)
33: The water treatment method according to claim 21 , wherein
in the washing step, the washing water flowing out from the one side of the water treatment unit is sent to the other side of the water treatment unit, whereby the washing water is circulated.
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US20160039688A1 (en) * | 2013-03-29 | 2016-02-11 | Mitsubishi Heavy Industries Mechatronics Systems, Ltd. | Water reclamation system and deionization treatment device, and water reclamation method |
ITPD20130280A1 (en) * | 2013-10-09 | 2015-04-10 | Idropan Dell Orto Depuratori S R L | EQUIPMENT FOR THE TREATMENT OF A FLUID |
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IL246694A0 (en) * | 2016-07-10 | 2016-09-29 | Technion Res & Dev Foundation | Fluidized bed and hybrid suspension electrodes for energy storage and water desalination systems |
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2017
- 2017-08-02 US US16/341,553 patent/US20190322552A1/en not_active Abandoned
- 2017-08-02 JP JP2017550949A patent/JP6395952B1/en active Active
- 2017-08-02 CN CN201780065807.5A patent/CN109890765B/en active Active
- 2017-08-02 WO PCT/JP2017/027975 patent/WO2018083849A1/en active Application Filing
- 2017-08-02 KR KR1020197012108A patent/KR102049726B1/en active IP Right Grant
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2019
- 2019-08-05 US US16/531,945 patent/US10961135B2/en active Active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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US10797472B1 (en) * | 2019-11-18 | 2020-10-06 | Groon Co., Ltd. | Electron generation apparatus capable of multi-stage boosting for variable capacity |
WO2022082260A1 (en) * | 2020-10-20 | 2022-04-28 | Saltfree Desalination Australia Pty Ltd | Systems and methods for managing desalination systems |
Also Published As
Publication number | Publication date |
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WO2018083849A1 (en) | 2018-05-11 |
JP6395952B1 (en) | 2018-09-26 |
CN109890765A (en) | 2019-06-14 |
US20190352201A1 (en) | 2019-11-21 |
JPWO2018083849A1 (en) | 2018-11-01 |
CN109890765B (en) | 2020-02-14 |
US10961135B2 (en) | 2021-03-30 |
KR102049726B1 (en) | 2019-11-28 |
KR20190049901A (en) | 2019-05-09 |
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