US20160268269A1 - Nonvolatile semiconductor memory device and method of manufacturing the same - Google Patents
Nonvolatile semiconductor memory device and method of manufacturing the same Download PDFInfo
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- US20160268269A1 US20160268269A1 US14/849,772 US201514849772A US2016268269A1 US 20160268269 A1 US20160268269 A1 US 20160268269A1 US 201514849772 A US201514849772 A US 201514849772A US 2016268269 A1 US2016268269 A1 US 2016268269A1
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- conducting layers
- selection transistor
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- conducting layer
- nonvolatile semiconductor
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Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/30—EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region
- H10B43/35—EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region with cell select transistors, e.g. NAND
-
- H01L27/1157—
-
- H01L27/11524—
-
- H01L27/11556—
-
- H01L27/11582—
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/20—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels
- H10B43/23—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels
- H10B43/27—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels the channels comprising vertical portions, e.g. U-shaped channels
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/50—EEPROM devices comprising charge-trapping gate insulators characterised by the boundary region between the core and peripheral circuit regions
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C16/00—Erasable programmable read-only memories
- G11C16/02—Erasable programmable read-only memories electrically programmable
- G11C16/04—Erasable programmable read-only memories electrically programmable using variable threshold transistors, e.g. FAMOS
- G11C16/0483—Erasable programmable read-only memories electrically programmable using variable threshold transistors, e.g. FAMOS comprising cells having several storage transistors connected in series
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C2213/00—Indexing scheme relating to G11C13/00 for features not covered by this group
- G11C2213/70—Resistive array aspects
- G11C2213/75—Array having a NAND structure comprising, for example, memory cells in series or memory elements in series, a memory element being a memory cell in parallel with an access transistor
Definitions
- Embodiments described herein relate generally to a nonvolatile semiconductor memory device and a method of manufacturing the nonvolatile semiconductor memory device.
- This type of three-dimensional NAND-type flash memory includes a laminated body and a semiconductor layer.
- a laminated body In the laminated body, a plurality of conductive films and interlayer insulating films are alternately laminated.
- the conductive film functions as word lines and selection gate lines.
- the semiconductor layer is formed to pass through these laminated films.
- This semiconductor layer functions as a body of a memory string. Between the semiconductor layer and the conductive film, a memory film that includes a charge storage film is formed.
- the ON/OFF characteristics (selection characteristics) of selection transistors are important, and it is required to cause a flow of a sufficient cell current during selection and keep preferable characteristics of a selection gate electrode.
- FIG. 1 is a perspective view schematically illustrating one example of the structure a nonvolatile semiconductor memory device 100 according to a first embodiment
- FIG. 2 is a perspective view illustrating the structure of a part of memory cell arrays 11 ;
- FIG. 3 is an equivalent circuit diagram of one NAND cell unit NU
- FIG. 4A is a cross-sectional perspective view of one memory cell MC
- FIG. 4B is a schematic perspective view of one of a drain-side selection transistor S 1 and a source-side selection transistor S 2 ;
- FIG. 5 is a plan view of a part of the memory cell array 11 ;
- FIGS. 6A and 6B are a partial cross-sectional view and a plan view of one configuration example of a wiring portion 20 ;
- FIG. 7 is a schematic perspective view illustrating one example of the configuration of the wiring portion 20 ;
- FIG. 8 is a schematic perspective view illustrating another example of the configuration of the wiring portion 20 ;
- FIG. 9 is a process diagram illustrating a method of manufacturing the memory cell array 11 and the wiring portion 20 ;
- FIGS. 10 to 14B are process diagrams illustrating the method of manufacturing the memory cell array 11 and the wiring portion 20 ;
- FIGS. 15A to 15C are a partial cross-sectional view and a plan view illustrating the configuration of the wiring portion 20 of a nonvolatile semiconductor memory device according to a second embodiment.
- FIGS. 16 to 19 illustrate a modification.
- a nonvolatile semiconductor memory device includes a memory cell array and a wiring portion.
- the memory cell array includes: a memory string where a plurality of memory cells is series-coupled together; and a selection transistor coupled to one end of the memory string.
- the memory string is formed to extend to have the longitudinal direction in a first direction.
- the wiring portion is formed by alternately laminating a first conducting layer and an interlayer insulating film over a plurality of layers.
- the first conducting layers function as gate electrodes for the memory cells and the selection transistor.
- One of the selection transistors includes a plurality of the first conducting layers, and the plurality of the first conducting layers are electrically coupled in common to a second conducting layer that is a common contact formed on the sidewall of the wiring portion.
- nonvolatile semiconductor memory devices according to embodiments in detail with reference to the accompanying drawings.
- these embodiments are only examples.
- the nonvolatile semiconductor memory device described below has a structure where a memory string extends in a straight line in the vertical direction with respect to a substrate.
- the similar structure is also applicable to the structure having a U shape where a memory string is folded to the opposite side in the middle.
- the respective drawings of the nonvolatile semiconductor memory devices used in the following embodiments are schematically illustrated.
- the thickness, the width, the ratio, and similar parameter of the layer are not necessarily identical to actual parameters.
- This embodiment relates to a nonvolatile semiconductor memory device in a structure where a plurality of metal-oxide-nitride-oxide-semiconductor (MONOS) type memory cells (transistors) is disposed in a height direction.
- the MONOS type memory cell includes: a semiconductor film disposed in a columnar shape vertical to the substrate as a channel, and a gate electrode film disposed on the side surface of the semiconductor film via a charge storage layer.
- a similar structure is applicable to another type of charge storage film, for example, a semiconductor-oxide-nitride-oxide-semiconductor type (SONOS) memory cell or a floating-gate type memory cell.
- SONOS semiconductor-oxide-nitride-oxide-semiconductor type
- FIG. 1 is a perspective view schematically illustrating an exemplary structure of a nonvolatile semiconductor memory device 100 of a first embodiment.
- the nonvolatile semiconductor memory device 100 includes a memory cell array 11 , word-line driving circuits 12 , source-side selection-gate-line driving circuits 13 , drain-side selection-gate-line driving circuits 14 , a sense amplifier 15 , word lines WL, source-side selection gate lines SGS, drain-side selection gate lines SGD, bit lines BL, a wiring portion 20 , and similar portion.
- the memory cell array 11 includes memory strings MS, drain-side selection transistors S 1 , and source-side selection transistors S 2 on a semiconductor substrate (not illustrated in FIG. 1 ).
- the memory string MS is constituted such that a plurality of memory cells MC (memory transistors) are coupled together in series.
- the respective drain-side selection transistor S 1 and source-side selection transistor S 2 are coupled to both ends of the memory string MS.
- the memory string MS, and the drain-side selection transistor S 1 and the source-side selection transistor S 2 coupled to both ends of the memory string MS are hereinafter referred to as a “NAND cell unit NU.”
- the memory cell MC has the structure, where a control gate electrode (word line) is disposed on the side surface of a columnar semiconductor film, becomes a channel via a memory film including a charge storage layer.
- the drain-side selection transistor and the source-side selection transistor each have the structure where a selection gate electrode (selection gate line) is disposed on the side surface of a columnar semiconductor film via the memory film.
- FIG. 1 illustrates the case where four memory cells MC are disposed in one memory string MS as the example. Obviously, the number of the memory cells MC in one memory string MS is not limited to this.
- the word line WL is coupled in common to the adjacent memory cells along the X direction (the word-line direction) in FIG. 1 .
- the source-side selection gate line SGS is coupled in common to the adjacent source-side selection transistors S 2 along the word-line direction.
- the drain-side selection gate line SGD is coupled in common to the adjacent drain-side selection transistor S 1 along the word-line direction.
- the source-side selection gate line SGS and the drain-side selection gate line SGD are collectively referred to simply as “selection gate lines” in some cases.
- the drain-side selection transistor and the source-side selection transistor are collectively referred to simply as “selection transistors” in some cases.
- one or a plurality of the memory cells MC close to the source-side selection gate line SGS and the drain-side selection gate line SGD might be treated as a dummy cell that is not used for data storage.
- a description will be given of the example where one dummy cell is disposed at each of both ends of the memory string MS. This, however, should not be construed in a limiting sense. Two or more dummy cells may be disposed or the dummy cell may be omitted.
- bit lines BL are disposed to extend having the longitudinal direction in the Y direction (the bit-line direction) intersecting with the X direction (the word-line direction), and are collocated at a predetermined pitch in the X direction.
- the bit line BL is coupled to a plurality of the memory strings MS via the drain-side selection transistors S 1 .
- Source lines SL which are omitted in FIG. 1 , are disposed having the longitudinal direction, similarly, in the Y direction and coupled to the memory strings MS via the source-side selection transistors S 2 .
- the word-line driving circuit 12 is a circuit that controls the voltage to be applied to the word line WL.
- the source-side selection-gate-line driving circuit 13 is a circuit that controls the voltage to be applied to the source-side selection gate line SGS.
- the drain-side selection-gate-line driving circuit 14 is a circuit that controls the voltage to be applied to the drain-side selection gate line SGD.
- the sense amplifier 15 is a circuit for amplifying a signal (voltage) read out from a selected memory cell to the bit line BL.
- the wiring portion 20 is a wiring portion for coupling the word lines WL and the selection gate lines SGD and SGS to the contacts.
- the word lines WL, the selection gate lines SGS and SGD have a structure processed in a staircase pattern such that the respective upper portions can independently be coupled to the contacts.
- FIG. 2 is a perspective view illustrating the structure of a part of the memory cell array 11 .
- FIG. 3 is an equivalent circuit diagram of one NAND cell unit NU.
- FIG. 4A is a cross-sectional perspective view of one memory cell MC and similar member.
- FIG. 4B is a schematic perspective view of one of the drain-side selection transistor S 1 and the source-side selection transistor S 2 .
- the memory cell array 11 has the structure where interlayer insulating films 21 and conducting layers 22 are alternately laminated on a semiconductor substrate SB.
- This conducting layer 22 functions as the control gate (word line WL) of the memory cell MC, the source-side selection gate line SGS, and the drain-side selection gate line SGD.
- the interlayer insulating film 21 is disposed in the above-and-below direction of the conducting layer 22 and electrically insulates the conducting layers 22 from one another.
- the conducting layer 22 can be formed of, for example, tungsten (W), tungsten nitride (WN), tungsten silicide (WSix), tantalum (Ta), tantalum nitride (TaN), tantalum silicide (TaSix), palladium silicide (PdSix), erbium silicide (ErSix), yttrium silicide (YSix), platinum silicide (PtSix), hafnium silicide (HfSix), nickel silicide (NiSix), cobalt silicide (CoSix), titanium silicide (TiSix), vanadium silicide (VSix), chrome silicide (CrSix), manganese silicide (MnSix), iron silicide (FeSix), ruthenium (Ru), molybdenum (Mo), titanium (Ti), titanium nitride (TiN), vanadium (V), chrome (Cr), manganese (Mn),
- a memory film 24 including a charge storage layer is formed between: the semiconductor layer 23 ; and the conducting layer 22 and the interlayer insulating film 21 .
- the memory film 24 can be formed by a laminated structure of: a charge storage film such as a silicon nitride film, and an oxide film such as a silicon oxide film.
- the threshold voltage of the memory cell MC changes. The memory cell MC holds data corresponding to this threshold voltage.
- the semiconductor layers 23 function as the channel regions (body) of the memory cell MC, the dummy cells DMC 1 and DMC 2 , and the selection transistors S 1 and S 2 that are included in the NAND cell unit NU. These semiconductor layers 23 are coupled, on their upper ends, to the bit lines BL via contacts Cb.
- the bit lines BL having the longitudinal direction in the Y direction are collocated at a predetermined pitch along the X direction.
- the lower end of the semiconductor layer 23 is coupled to the semiconductor substrate SB. Then, the lower end of the semiconductor layer 23 is coupled to the source line SL via this semiconductor substrate SB and a source contact LI, which is described later.
- the source lines SL are collocated while having their longitudinal directions in the Y direction, similarly to the bit lines BL.
- the laminated body of the interlayer insulating film 21 and the conducting layer 22 in the memory cell array 11 is separated by blocks as the smallest unit of data erasure.
- a trench Tb is formed.
- an interlayer insulating film (not illustrated) is implanted.
- the source contact LI described above is formed passing through the interlayer insulating film.
- This source contact LI has a lower end coupled to the semiconductor substrate SB while having an upper end coupled to the source line SL.
- FIG. 3 is an equivalent circuit diagram of one NAND cell unit NU.
- the one NAND cell unit includes the memory string MS, the drain-side selection transistor S 1 , and the source-side selection transistor S 2 .
- the memory string MS is constituted of a plurality of the memory cells MC and dummy cells DMC 1 and DMC 2 .
- the drain-side selection transistor S 1 is coupled between the upper end of the memory string MS and the bit line BL.
- the source-side selection transistor S 2 is coupled between the lower end of the memory string MS and the source line SL.
- FIG. 4A illustrates one example of a specific structure of one of the memory cell MC and the dummy cell DMC.
- the semiconductor layer 23 includes an oxide-film core 101 and a semiconductor columnar portion 102 , which surrounds the peripheral area of the oxide-film core 101 .
- the oxide-film core 101 is formed of, for example, a silicon oxide film (SiO 2 ).
- the semiconductor columnar portion 102 is formed of, for example, silicon (Si), silicon-germanium (SiGe), silicon carbide (SiC), germanium (Ge), or carbon (C).
- the memory film 24 is formed to surround the semiconductor columnar portion 102 .
- the memory film 24 includes a tunnel insulating film 103 , a charge storage layer 104 , and a block insulating film 105 .
- the tunnel insulating film 103 is constituted of, for example, a silicon oxide film (SiOx), and functions as the tunnel insulating film of the memory cell MC or the dummy cell DMC.
- the charge storage layer 104 is constituted of, for example, a silicon nitride film (SiN), and has a function that traps electrons injected from the semiconductor columnar portion 102 via the tunnel insulating film 103 by a write operation.
- the block insulating film 105 can be formed of, for example, a silicon oxide film.
- the tunnel insulating film 103 , the charge storage layer 104 , and the block insulating film 105 are illustrated to be formed in the whole region of the side surface of the semiconductor columnar portion 102 . This, however, should not be construed in a limiting sense. These members can be formed only on the side surface of the word line WL.
- the memory film 24 illustrated in FIG. 4A has a three-layered structure, but can employ various materials, laminated structures, and similar parameter. The memory film 24 is not limited to the configuration in FIG. 4A or the material described above. However, at a minimum, the charge storage layer is included to provide the function as a memory film.
- the materials of the tunnel insulating film 103 and the block insulating film 105 can employ, for example, Al 2 O 3 , Y 2 O 3 , La 2 O 3 , Gd 2 O 3 , Ce 2 O 3 , CeO 2 , Ta 2 O 5 , HfO 2 , ZrO 2 , TiO 2 , HfSiO, HfAlO, ZrSiO, ZrAlO, and AlSiO other than the silicon oxide film (SiOx).
- FIG. 4B is a perspective view illustrating the structure of one of the drain-side selection transistor S 1 and the source-side selection transistor S 2 .
- One of the drain-side selection transistor S 1 and the source-side selection transistor S 2 is constituted of: a plurality of the conducting layers 22 ; and the memory film 24 and the semiconductor layer 23 that are adjacent to these layers in the XY plane.
- the plurality of the conducting layers 22 coupled to one of the selection transistors S 1 and S 2 are electrically coupled together by a contact conductive film (not illustrated in FIG. 4B ) formed on the sidewall of a plurality of conductive films as described later, and function as a single gate electrode.
- one of the selection transistors S 1 and S 2 includes the plurality of the conducting layers 22 coupled together. This configuration is employed to enhance the selection characteristics of the selection transistor S 1 or S 2 . That is, in the non-selected selection transistors S 1 and S 2 , it is necessary to reduce the leak current as much as possible. Otherwise, it is impossible to appropriately perform a read operation, a write operation and an erase operation, and this might cause a read error, a write error, an erase error, and similar error. This also increases the power consumption.
- One of the selection transistors S 1 and S 2 has the plurality of the conducting layers 22 as the gate electrode so as to improve the selectivity of the selection transistor.
- FIG. 5 is a plan view of a part of the memory cell array 11 .
- FIGS. 6A and 6B are a partial cross-sectional view and a plan view of the wiring portion 20 .
- the semiconductor layers 23 are arrayed in one row in the oblique direction with respect to the X direction (the word-line direction) and the Y direction (the bit-line direction). This increases the array density of the semiconductor layer 23 , thus increasing the array density of the memory cell MC.
- the semiconductor layers 23 can be disposed along the X direction and the Y direction.
- the source contact LI is formed in a stripe shape to have the longitudinal direction in the X direction, and is implanted in the trench Tb via an interlayer insulating film 21 ′.
- This source contact LI is implanted in the trench Tb, which divides the memory cell array 11 by blocks, via the interlayer insulating film 21 ′.
- the source contact LI has the lower end in contact with the diffusion layer, which is formed on the surface of the substrate SB, and has the upper end coupled to the source line SL via upper-layer wiring.
- FIG. 6A is a partial cross-sectional view of the wiring portion 20
- FIG. 6B is a plan view of the wiring portion 20
- the wiring portion 20 is a wiring portion for coupling the conducting layer 22 , which functions as the word line WL or the selection gate line SGD or SGS (SGD is illustrated alone in FIG. 6A ), to an external circuit via a contact.
- the drain-side selection gate line SGD is described as an example.
- the illustrations of the substrate SB and the source-side selection gate lines SGS arranged at the substrate SB side are omitted. The same applies to the other drawings after FIG. 6A .
- the conducting layers 22 that function as the word lines WL are processed in a staircase pattern together with the interlayer insulating films 21 in this wiring portion 20 . Accordingly, the respective upper portions of the word lines WL can be independently coupled to contacts Cw.
- the conducting layers 22 that function as the word lines WL are coupled to the word-line driving circuit 12 illustrated in FIG. 1 by the contacts Cw.
- the contact Cw is implanted in a trench formed in an insulating film 27 that fills the wiring portion 20 , via an insulating film (not illustrated).
- the conducting layers 22 that function as the drain-side selection gate line SGD are processed not in a staircase pattern, but such that their end portions have the identical length in the X direction (the longitudinal direction of the selection gate line) as illustrated in FIGS. 6A and 6B .
- the selection gate line SGD coupled to one drain-side selection transistor S 1 includes a plurality of the conducting layers 22 (the first conducting layers) where their end portions having the identical length described above are electrically coupled in common to a conducting layer 25 (the second conducting layer), which is formed in these end portions.
- the conducting layer 25 in the end portion of the selection gate line is arranged to electrically couple the plurality of the conducting layers 22 in common, so as to obtain a selection transistor with preferable selection characteristics compared with the selection transistor having a single conducting layer as a gate electrode.
- the conducting layers 22 that function as the source-side selection gate line SGS, which is formed in the lower portion of the laminated body, are also formed similarly to the drain-side selection gate line SGD.
- the end portions of the conducting layers 22 are processed to be aligned in the longitudinal direction.
- the selection gate line SGS coupled to one source-side selection transistor S 2 includes a plurality of the conducting layers 22 (the first conducting layers) electrically coupled in common to a conducting layer (the second conducting layer) arranged in these end portions, similarly to the drain-side selection gate line SGD.
- the conducting layer 22 can be formed by removing a sacrifice film by wet etching and then filling a conductive material in the void from which the sacrifice film has been removed.
- the wiring portion 20 includes slit portions CC arranged at predetermined intervals as illustrated in FIG. 6B .
- the sacrifice film is removed by a wet etching solution entering from this slit portion CC.
- the conducting layer 22 described above is formed as a film using a CVD method or similar method.
- an insulating film is filled in the slit portion CC.
- the removal of the sacrifice film and the film formation of the conducting layer 22 are performed by pouring the materials in the Y direction using the slit CC.
- the conducting layer 25 is formed in the end portions of the conducting layers 22 in the X direction. This does not affect the pouring of the materials in the Y direction at the time of the removal of the sacrifice film and the film formation of the conducting layer.
- the conducting layer 25 is formed from the material different from that of the sacrifice film 22 ′, the conducting layer 25 is not removed simultaneously when a sacrifice film 22 ′ is removed. Therefore, the conducting layer 25 can be formed as a film at any timing before the sacrifice film is removed, after the sacrifice film is removed and the conducting layer 22 is formed as a film, or similar timing.
- the conducting layer 22 constituting the word line WL may be a staircase portion that one-dimensionally expands only in the X direction as illustrated in FIG. 7 or may be a staircase portion that two-dimensionally expands in both the X direction and the Y direction as illustrated in FIG. 8 .
- a plurality of the sacrifice films 22 ′ made of, for example, silicon nitride films and a plurality of the interlayer insulating films 21 made of, for example, silicon oxide films are laminated so as to form a laminated body.
- a part of the upper portion of the laminated body is removed by photolithography and dry etching as a whole.
- the drain-side selection gate line SGD is formed on the sidewall, that is, in the end portion of the portion where the laminated body is removed.
- the conducting layer 25 made of, for example, silicon doped with B is formed as a film on the sidewall of the drain-side selection gate line SGD.
- This conducting layer 25 electrically couples the plurality of the laminated conducting layers 22 of the drain-side selection gate line SGD to one another.
- the laminated films under the drain-side selection gate line SGD are processed in a staircase pattern by photolithography and etching again.
- an insulating layer 26 made of alumina or similar material is deposited as a stopper material at the time of the subsequent formation of the contacts Cw.
- the insulating film 27 for protecting the upper portion of the drain-side selection gate line SGD is deposited.
- memory holes are formed by photolithography and etching to form memory layers (not illustrated) including charge storage layers.
- Silicon to be channels is deposited to form the semiconductor layers 23 in columnar shapes.
- the contacts Cw are formed and, additionally, the sacrifice films 22 ′ are replaced by metal films made of, for example, tungsten so as to obtain the configurations in FIGS. 4A and 4B .
- the sacrifice films 22 ′ are replaced by the conducting layers 22 as the metal films above.
- the conducting layers which are made of silicon doped with impurities or similar material, and the interlayer insulating films from the start, so as to form the laminated body without replacement.
- the insulating layer 26 can employ various materials such as silicon nitride other than alumina described above.
- the plurality of the conducting layers 22 of the selection gate line are electrically coupled in common to the conducting layer 25 , which is arranged in their end portions. This allows obtaining a nonvolatile semiconductor memory device in a three-dimensional structure having a selection transistor with high selectivity.
- FIGS. 15A to 15C The following describes a nonvolatile semiconductor memory device according to a second embodiment with reference to FIGS. 15A to 15C .
- the overall configuration of this second embodiment is approximately identical to that of the first embodiment (in FIG. 1 to FIG. 6B ). However, this second embodiment differs from the first embodiment in the structure of the end portion of the selection gate line and the configuration of the conducting layer 25 (the second conducting layer).
- FIG. 15A is a partial cross-sectional view of the wiring portion 20 of the nonvolatile semiconductor memory device according to the second embodiment.
- FIG. 15B is a plan view of the wiring portion 20 .
- the end portions of the interlayer insulating films 21 retreat in the inward direction of the drain-side selection gate line SGD compared with the end portions of the conducting layers 22 .
- the end portions of the conducting layers 22 project in the longitudinal direction compared with the end portions of the interlayer insulating films 21 .
- the conducting layer 25 formed on the sidewall of the drain-side selection gate line SGD is formed extending into the voids caused by retreating of the interlayer insulating films 21 .
- the method of manufacturing the wiring portion 20 according to the second embodiment is approximately identical to the manufacturing method used in the first embodiment, but is differs from the first embodiment in the phase of forming the conducting layer 25 described using FIG. 10 in the first embodiment. That is, in the second embodiment, as illustrated in FIG. 15C , wet etching using a chemical liquid is performed on the end portion of the laminated body to be the drain-side selection gate line SGD before the conducting layer 25 is formed, so as to retreat the interlayer insulating films 21 .
- the conducting layer 25 is formed on the sidewall of the drain-side selection gate line SGD to be present also in the void portion caused by retreating of the interlayer insulating films 21 .
- the end portions of the interlayer insulating films 21 are etched so as to cause the voids between the end portions of the conducting layers 22 .
- the conducting layer 25 is formed not only on the sidewalls of the conducting layers 22 , but also inside these voids. The subsequent processes are similar to those in the first embodiment, and the configuration in FIG. 15A is thus obtained.
- This second embodiment also allows providing effects identical to those in the first embodiment. Furthermore, in this second embodiment, the conducting layer is formed extending to the inner side of the end portion of the selection gate. This further increases the contacted area between the conducting layer and the conducting layers of the selection gate, thus reducing the resistance. This consequently provides preferable current characteristics, thus realizing excellent cell characteristics.
- the plurality of the conducting layers 22 of the selection gate line are coupled in common to one conducting layer 25 , which is formed in the end portion of the selection gate line aligned in the longitudinal direction.
- the selection gate line portion for example, in a staircase pattern for each of two layers whose end portions are aligned in the longitudinal direction; and form the conducting layers 25 in the end portions for each of the two layers aligned in the longitudinal direction so as to ensure electrical coupling.
- the plurality of the conducting layers 22 are formed as the staircase structure, and the conducting layers 22 having the identical steps are electrically coupled in common to the conducting layer 25 .
- the portions that are not aligned in the longitudinal direction are electrically independent from one another. Accordingly, it is possible to employ various usages, for example, a method for applying different electric potentials to the respective portions.
- the plurality of the conducting layers 22 electrically coupled in common to the conducting layer 25 are aligned in the longitudinal direction.
- the plurality of the conducting layers 22 can have the end portions having mutually different lengths, and a plurality of the conducting layers 22 having mutually different lengths can be electrically coupled in common to the conducting layer 25 (in the example of FIG. 17 , the conducting layers having different lengths are electrically coupled in common for each of two layers).
- the conducting layers 22 function as the gate electrodes of the selection gate lines.
- a part of the conducting layers 22 can also be used as the dummy cells DMC without being used as the gate electrodes.
- the conducting layer 22 as the dummy cell DMC is one layer. In this case, the conducting layer 25 is not necessarily needed.
- the above-described nonvolatile semiconductor memory device according to the modification can also provide effects similar to those in the first and second embodiments that have been described.
- the silicon nitride film As the material of the charge storage layer 104 , the silicon nitride film (SiN) is described in the above-described embodiment as an example. However, the following oxides can also be selected.
- the following oxynitrides can also be selected.
- one insulating layer and a plurality of insulating layers are each preferred to be selected from the group consisting of SiO 2 , SiN, Si 3 N 4 , Al 2 O 3 , SiON, HfO 2 , HfSiON, Ta 2 O 5 , TiO 2 , and SrTiO 3 .
- the respective concentrations of the oxygen elements and the nitrogen elements can be set to be equal to or more than 1 ⁇ 10 18 atoms/cm 3 .
- the barrier heights of the plurality of insulating layers are different from one another.
- the insulating layer can include a material including impurity atoms that forms a defect level or semiconductor/metal dots (the quantum dots).
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Abstract
Description
- This application is based upon and claims the benefit of priority from U.S. Provisional Patent Application No. 62/132,254, filed on Mar. 12, 2015, the entire contents of which are incorporated herein by reference.
- Embodiments described herein relate generally to a nonvolatile semiconductor memory device and a method of manufacturing the nonvolatile semiconductor memory device.
- Recently, in the field of NAND-type flash memories, attention has been focused on a laminated-type (three-dimensional) NAND-type flash memory as a device that can achieve high integration without being restricted by the limit of resolution of the lithography technology. This type of three-dimensional NAND-type flash memory includes a laminated body and a semiconductor layer. In the laminated body, a plurality of conductive films and interlayer insulating films are alternately laminated. The conductive film functions as word lines and selection gate lines. The semiconductor layer is formed to pass through these laminated films. This semiconductor layer functions as a body of a memory string. Between the semiconductor layer and the conductive film, a memory film that includes a charge storage film is formed.
- In this three-dimensional NAND-type flash memory, the ON/OFF characteristics (selection characteristics) of selection transistors are important, and it is required to cause a flow of a sufficient cell current during selection and keep preferable characteristics of a selection gate electrode.
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FIG. 1 is a perspective view schematically illustrating one example of the structure a nonvolatilesemiconductor memory device 100 according to a first embodiment; -
FIG. 2 is a perspective view illustrating the structure of a part ofmemory cell arrays 11; -
FIG. 3 is an equivalent circuit diagram of one NAND cell unit NU; -
FIG. 4A is a cross-sectional perspective view of one memory cell MC; -
FIG. 4B is a schematic perspective view of one of a drain-side selection transistor S1 and a source-side selection transistor S2; -
FIG. 5 is a plan view of a part of thememory cell array 11; -
FIGS. 6A and 6B are a partial cross-sectional view and a plan view of one configuration example of awiring portion 20; -
FIG. 7 is a schematic perspective view illustrating one example of the configuration of thewiring portion 20; -
FIG. 8 is a schematic perspective view illustrating another example of the configuration of thewiring portion 20; -
FIG. 9 is a process diagram illustrating a method of manufacturing thememory cell array 11 and thewiring portion 20; -
FIGS. 10 to 14B are process diagrams illustrating the method of manufacturing thememory cell array 11 and thewiring portion 20; -
FIGS. 15A to 15C are a partial cross-sectional view and a plan view illustrating the configuration of thewiring portion 20 of a nonvolatile semiconductor memory device according to a second embodiment; and -
FIGS. 16 to 19 illustrate a modification. - A nonvolatile semiconductor memory device according to embodiments described below includes a memory cell array and a wiring portion. The memory cell array includes: a memory string where a plurality of memory cells is series-coupled together; and a selection transistor coupled to one end of the memory string. The memory string is formed to extend to have the longitudinal direction in a first direction. The wiring portion is formed by alternately laminating a first conducting layer and an interlayer insulating film over a plurality of layers. The first conducting layers function as gate electrodes for the memory cells and the selection transistor. One of the selection transistors includes a plurality of the first conducting layers, and the plurality of the first conducting layers are electrically coupled in common to a second conducting layer that is a common contact formed on the sidewall of the wiring portion.
- The following describes nonvolatile semiconductor memory devices according to embodiments in detail with reference to the accompanying drawings. Here, these embodiments are only examples. For example, the nonvolatile semiconductor memory device described below has a structure where a memory string extends in a straight line in the vertical direction with respect to a substrate. The similar structure is also applicable to the structure having a U shape where a memory string is folded to the opposite side in the middle. The respective drawings of the nonvolatile semiconductor memory devices used in the following embodiments are schematically illustrated. The thickness, the width, the ratio, and similar parameter of the layer are not necessarily identical to actual parameters.
- Examples will be described below. This embodiment relates to a nonvolatile semiconductor memory device in a structure where a plurality of metal-oxide-nitride-oxide-semiconductor (MONOS) type memory cells (transistors) is disposed in a height direction. The MONOS type memory cell includes: a semiconductor film disposed in a columnar shape vertical to the substrate as a channel, and a gate electrode film disposed on the side surface of the semiconductor film via a charge storage layer. However, a similar structure is applicable to another type of charge storage film, for example, a semiconductor-oxide-nitride-oxide-semiconductor type (SONOS) memory cell or a floating-gate type memory cell.
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FIG. 1 is a perspective view schematically illustrating an exemplary structure of a nonvolatilesemiconductor memory device 100 of a first embodiment. The nonvolatilesemiconductor memory device 100 includes amemory cell array 11, word-line driving circuits 12, source-side selection-gate-line driving circuits 13, drain-side selection-gate-line driving circuits 14, asense amplifier 15, word lines WL, source-side selection gate lines SGS, drain-side selection gate lines SGD, bit lines BL, awiring portion 20, and similar portion. - The
memory cell array 11 includes memory strings MS, drain-side selection transistors S1, and source-side selection transistors S2 on a semiconductor substrate (not illustrated inFIG. 1 ). The memory string MS is constituted such that a plurality of memory cells MC (memory transistors) are coupled together in series. The respective drain-side selection transistor S1 and source-side selection transistor S2 are coupled to both ends of the memory string MS. Here, the memory string MS, and the drain-side selection transistor S1 and the source-side selection transistor S2 coupled to both ends of the memory string MS are hereinafter referred to as a “NAND cell unit NU.” - As described later, the memory cell MC has the structure, where a control gate electrode (word line) is disposed on the side surface of a columnar semiconductor film, becomes a channel via a memory film including a charge storage layer. The drain-side selection transistor and the source-side selection transistor each have the structure where a selection gate electrode (selection gate line) is disposed on the side surface of a columnar semiconductor film via the memory film. For simplification of the illustration,
FIG. 1 illustrates the case where four memory cells MC are disposed in one memory string MS as the example. Obviously, the number of the memory cells MC in one memory string MS is not limited to this. - The word line WL is coupled in common to the adjacent memory cells along the X direction (the word-line direction) in
FIG. 1 . The source-side selection gate line SGS is coupled in common to the adjacent source-side selection transistors S2 along the word-line direction. The drain-side selection gate line SGD is coupled in common to the adjacent drain-side selection transistor S1 along the word-line direction. Here, in the following description, the source-side selection gate line SGS and the drain-side selection gate line SGD are collectively referred to simply as “selection gate lines” in some cases. The drain-side selection transistor and the source-side selection transistor are collectively referred to simply as “selection transistors” in some cases. Here, in the memory cells MC in the memory string MS, one or a plurality of the memory cells MC close to the source-side selection gate line SGS and the drain-side selection gate line SGD might be treated as a dummy cell that is not used for data storage. Also in the example described as follows, a description will be given of the example where one dummy cell is disposed at each of both ends of the memory string MS. This, however, should not be construed in a limiting sense. Two or more dummy cells may be disposed or the dummy cell may be omitted. - Furthermore, the bit lines BL are disposed to extend having the longitudinal direction in the Y direction (the bit-line direction) intersecting with the X direction (the word-line direction), and are collocated at a predetermined pitch in the X direction. The bit line BL is coupled to a plurality of the memory strings MS via the drain-side selection transistors S1. Source lines SL, which are omitted in
FIG. 1 , are disposed having the longitudinal direction, similarly, in the Y direction and coupled to the memory strings MS via the source-side selection transistors S2. - The word-
line driving circuit 12 is a circuit that controls the voltage to be applied to the word line WL. The source-side selection-gate-line driving circuit 13 is a circuit that controls the voltage to be applied to the source-side selection gate line SGS. The drain-side selection-gate-line driving circuit 14 is a circuit that controls the voltage to be applied to the drain-side selection gate line SGD. Thesense amplifier 15 is a circuit for amplifying a signal (voltage) read out from a selected memory cell to the bit line BL. - The
wiring portion 20 is a wiring portion for coupling the word lines WL and the selection gate lines SGD and SGS to the contacts. The word lines WL, the selection gate lines SGS and SGD have a structure processed in a staircase pattern such that the respective upper portions can independently be coupled to the contacts. - The following describes the detail of the structure of the
memory cell array 11 with reference toFIG. 2 toFIG. 4B .FIG. 2 is a perspective view illustrating the structure of a part of thememory cell array 11.FIG. 3 is an equivalent circuit diagram of one NAND cell unit NU.FIG. 4A is a cross-sectional perspective view of one memory cell MC and similar member.FIG. 4B is a schematic perspective view of one of the drain-side selection transistor S1 and the source-side selection transistor S2. - As illustrated in
FIG. 2 , thememory cell array 11 has the structure whereinterlayer insulating films 21 and conductinglayers 22 are alternately laminated on a semiconductor substrate SB. This conductinglayer 22 functions as the control gate (word line WL) of the memory cell MC, the source-side selection gate line SGS, and the drain-side selection gate line SGD. Theinterlayer insulating film 21 is disposed in the above-and-below direction of the conductinglayer 22 and electrically insulates the conducting layers 22 from one another. - The conducting
layer 22 can be formed of, for example, tungsten (W), tungsten nitride (WN), tungsten silicide (WSix), tantalum (Ta), tantalum nitride (TaN), tantalum silicide (TaSix), palladium silicide (PdSix), erbium silicide (ErSix), yttrium silicide (YSix), platinum silicide (PtSix), hafnium silicide (HfSix), nickel silicide (NiSix), cobalt silicide (CoSix), titanium silicide (TiSix), vanadium silicide (VSix), chrome silicide (CrSix), manganese silicide (MnSix), iron silicide (FeSix), ruthenium (Ru), molybdenum (Mo), titanium (Ti), titanium nitride (TiN), vanadium (V), chrome (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), gold (Au), silver (Ag) or copper (Cu), or can be formed of a compound of these materials. The conductinglayer 22 may be formed of polysilicon with the addition of impurities. - Semiconductor layers 23 having the longitudinal direction in the lamination direction (the Z direction) and passing through this laminated body of the
interlayer insulating film 21 and theconducting layer 22 are disposed at a predetermined pitch in the XY plane. Between: thesemiconductor layer 23; and theconducting layer 22 and theinterlayer insulating film 21, amemory film 24 including a charge storage layer is formed. As described later, thememory film 24 can be formed by a laminated structure of: a charge storage film such as a silicon nitride film, and an oxide film such as a silicon oxide film. Depending on the storage amount of the electric charge to this charge storage film, the threshold voltage of the memory cell MC changes. The memory cell MC holds data corresponding to this threshold voltage. - The semiconductor layers 23 function as the channel regions (body) of the memory cell MC, the dummy cells DMC1 and DMC2, and the selection transistors S1 and S2 that are included in the NAND cell unit NU. These semiconductor layers 23 are coupled, on their upper ends, to the bit lines BL via contacts Cb. The bit lines BL having the longitudinal direction in the Y direction are collocated at a predetermined pitch along the X direction.
- The lower end of the
semiconductor layer 23 is coupled to the semiconductor substrate SB. Then, the lower end of thesemiconductor layer 23 is coupled to the source line SL via this semiconductor substrate SB and a source contact LI, which is described later. The source lines SL are collocated while having their longitudinal directions in the Y direction, similarly to the bit lines BL. - Here, the laminated body of the
interlayer insulating film 21 and theconducting layer 22 in thememory cell array 11 is separated by blocks as the smallest unit of data erasure. At the boundary of the separation, a trench Tb is formed. In this trench Tb, an interlayer insulating film (not illustrated) is implanted. Further, the source contact LI described above is formed passing through the interlayer insulating film. This source contact LI has a lower end coupled to the semiconductor substrate SB while having an upper end coupled to the source line SL. -
FIG. 3 is an equivalent circuit diagram of one NAND cell unit NU. In thismemory cell array 11, the one NAND cell unit includes the memory string MS, the drain-side selection transistor S1, and the source-side selection transistor S2. The memory string MS is constituted of a plurality of the memory cells MC and dummy cells DMC1 and DMC2. The drain-side selection transistor S1 is coupled between the upper end of the memory string MS and the bit line BL. The source-side selection transistor S2 is coupled between the lower end of the memory string MS and the source line SL. -
FIG. 4A illustrates one example of a specific structure of one of the memory cell MC and the dummy cell DMC. Thesemiconductor layer 23 includes an oxide-film core 101 and asemiconductor columnar portion 102, which surrounds the peripheral area of the oxide-film core 101. The oxide-film core 101 is formed of, for example, a silicon oxide film (SiO2). Thesemiconductor columnar portion 102 is formed of, for example, silicon (Si), silicon-germanium (SiGe), silicon carbide (SiC), germanium (Ge), or carbon (C). - In the peripheral area of this
semiconductor columnar portion 102, thememory film 24 is formed to surround thesemiconductor columnar portion 102. Thememory film 24 includes atunnel insulating film 103, acharge storage layer 104, and ablock insulating film 105. Thetunnel insulating film 103 is constituted of, for example, a silicon oxide film (SiOx), and functions as the tunnel insulating film of the memory cell MC or the dummy cell DMC. Thecharge storage layer 104 is constituted of, for example, a silicon nitride film (SiN), and has a function that traps electrons injected from thesemiconductor columnar portion 102 via thetunnel insulating film 103 by a write operation. Theblock insulating film 105 can be formed of, for example, a silicon oxide film. In this example, thetunnel insulating film 103, thecharge storage layer 104, and theblock insulating film 105 are illustrated to be formed in the whole region of the side surface of thesemiconductor columnar portion 102. This, however, should not be construed in a limiting sense. These members can be formed only on the side surface of the word line WL. Thememory film 24 illustrated inFIG. 4A has a three-layered structure, but can employ various materials, laminated structures, and similar parameter. Thememory film 24 is not limited to the configuration inFIG. 4A or the material described above. However, at a minimum, the charge storage layer is included to provide the function as a memory film. - Here, the materials of the
tunnel insulating film 103 and theblock insulating film 105 can employ, for example, Al2O3, Y2O3, La2O3, Gd2O3, Ce2O3, CeO2, Ta2O5, HfO2, ZrO2, TiO2, HfSiO, HfAlO, ZrSiO, ZrAlO, and AlSiO other than the silicon oxide film (SiOx). -
FIG. 4B is a perspective view illustrating the structure of one of the drain-side selection transistor S1 and the source-side selection transistor S2. One of the drain-side selection transistor S1 and the source-side selection transistor S2 is constituted of: a plurality of the conducting layers 22; and thememory film 24 and thesemiconductor layer 23 that are adjacent to these layers in the XY plane. The plurality of the conducting layers 22 coupled to one of the selection transistors S1 and S2 are electrically coupled together by a contact conductive film (not illustrated inFIG. 4B ) formed on the sidewall of a plurality of conductive films as described later, and function as a single gate electrode. As just described, one of the selection transistors S1 and S2 according to this first embodiment includes the plurality of the conducting layers 22 coupled together. This configuration is employed to enhance the selection characteristics of the selection transistor S1 or S2. That is, in the non-selected selection transistors S1 and S2, it is necessary to reduce the leak current as much as possible. Otherwise, it is impossible to appropriately perform a read operation, a write operation and an erase operation, and this might cause a read error, a write error, an erase error, and similar error. This also increases the power consumption. One of the selection transistors S1 and S2 has the plurality of the conducting layers 22 as the gate electrode so as to improve the selectivity of the selection transistor. - The following describes the structures of the
memory cell array 11 and thewiring portion 20 further in detail with reference toFIG. 5 toFIG. 6B .FIG. 5 is a plan view of a part of thememory cell array 11.FIGS. 6A and 6B are a partial cross-sectional view and a plan view of thewiring portion 20. - As illustrated in
FIG. 5 , the semiconductor layers 23 (the semiconductor columnar portion 102) are arrayed in one row in the oblique direction with respect to the X direction (the word-line direction) and the Y direction (the bit-line direction). This increases the array density of thesemiconductor layer 23, thus increasing the array density of the memory cell MC. However, this is only one example, and the semiconductor layers 23 can be disposed along the X direction and the Y direction. The source contact LI is formed in a stripe shape to have the longitudinal direction in the X direction, and is implanted in the trench Tb via aninterlayer insulating film 21′. - This source contact LI is implanted in the trench Tb, which divides the
memory cell array 11 by blocks, via theinterlayer insulating film 21′. The source contact LI has the lower end in contact with the diffusion layer, which is formed on the surface of the substrate SB, and has the upper end coupled to the source line SL via upper-layer wiring. - The following describes the structure of the
wiring portion 20 with reference toFIG. 6A andFIG. 6B .FIG. 6A is a partial cross-sectional view of thewiring portion 20, andFIG. 6B is a plan view of thewiring portion 20. As described above, thewiring portion 20 is a wiring portion for coupling theconducting layer 22, which functions as the word line WL or the selection gate line SGD or SGS (SGD is illustrated alone inFIG. 6A ), to an external circuit via a contact. Here, inFIG. 6A , the drain-side selection gate line SGD is described as an example. The illustrations of the substrate SB and the source-side selection gate lines SGS arranged at the substrate SB side are omitted. The same applies to the other drawings afterFIG. 6A . - The conducting layers 22 that function as the word lines WL are processed in a staircase pattern together with the interlayer insulating
films 21 in thiswiring portion 20. Accordingly, the respective upper portions of the word lines WL can be independently coupled to contacts Cw. The conducting layers 22 that function as the word lines WL are coupled to the word-line driving circuit 12 illustrated inFIG. 1 by the contacts Cw. Here, while not illustrated inFIGS. 6A and 6B , the contact Cw is implanted in a trench formed in an insulatingfilm 27 that fills thewiring portion 20, via an insulating film (not illustrated). - On the other hand, the conducting layers 22 that function as the drain-side selection gate line SGD are processed not in a staircase pattern, but such that their end portions have the identical length in the X direction (the longitudinal direction of the selection gate line) as illustrated in
FIGS. 6A and 6B . The selection gate line SGD coupled to one drain-side selection transistor S1 includes a plurality of the conducting layers 22 (the first conducting layers) where their end portions having the identical length described above are electrically coupled in common to a conducting layer 25 (the second conducting layer), which is formed in these end portions. The conductinglayer 25 in the end portion of the selection gate line is arranged to electrically couple the plurality of the conducting layers 22 in common, so as to obtain a selection transistor with preferable selection characteristics compared with the selection transistor having a single conducting layer as a gate electrode. - While not illustrated, the conducting layers 22 that function as the source-side selection gate line SGS, which is formed in the lower portion of the laminated body, are also formed similarly to the drain-side selection gate line SGD. The end portions of the conducting layers 22 are processed to be aligned in the longitudinal direction. The selection gate line SGS coupled to one source-side selection transistor S2 includes a plurality of the conducting layers 22 (the first conducting layers) electrically coupled in common to a conducting layer (the second conducting layer) arranged in these end portions, similarly to the drain-side selection gate line SGD.
- Here, as described in detail later, the conducting
layer 22 can be formed by removing a sacrifice film by wet etching and then filling a conductive material in the void from which the sacrifice film has been removed. In the case where this wet etching is performed, thewiring portion 20 includes slit portions CC arranged at predetermined intervals as illustrated inFIG. 6B . The sacrifice film is removed by a wet etching solution entering from this slit portion CC. Via the gap remaining after removing the sacrifice film in the slit portion CC, the conductinglayer 22 described above is formed as a film using a CVD method or similar method. After theconducting layer 22 is formed as a film, an insulating film is filled in the slit portion CC. - As apparent from this description, the removal of the sacrifice film and the film formation of the conducting
layer 22 are performed by pouring the materials in the Y direction using the slit CC. On the other hand, the conductinglayer 25 is formed in the end portions of the conducting layers 22 in the X direction. This does not affect the pouring of the materials in the Y direction at the time of the removal of the sacrifice film and the film formation of the conducting layer. Additionally, because theconducting layer 25 is formed from the material different from that of thesacrifice film 22′, the conductinglayer 25 is not removed simultaneously when asacrifice film 22′ is removed. Therefore, the conductinglayer 25 can be formed as a film at any timing before the sacrifice film is removed, after the sacrifice film is removed and theconducting layer 22 is formed as a film, or similar timing. - Here, the conducting
layer 22 constituting the word line WL may be a staircase portion that one-dimensionally expands only in the X direction as illustrated inFIG. 7 or may be a staircase portion that two-dimensionally expands in both the X direction and the Y direction as illustrated inFIG. 8 . - Next, a description will be given of a method of manufacturing the
wiring portion 20 with reference toFIG. 9 toFIG. 14B . - Firstly, as illustrated in
FIG. 9 , on the substrate SB made of silicon or similar material, a plurality of thesacrifice films 22′ made of, for example, silicon nitride films and a plurality of the interlayer insulatingfilms 21 made of, for example, silicon oxide films are laminated so as to form a laminated body. Then, as illustrated inFIG. 10 , a part of the upper portion of the laminated body is removed by photolithography and dry etching as a whole. On the sidewall, that is, in the end portion of the portion where the laminated body is removed, the drain-side selection gate line SGD is formed. Then, to ensure the contact, that is, the electrical coupling between these plurality of the conducting layers, the conductinglayer 25 made of, for example, silicon doped with B is formed as a film on the sidewall of the drain-side selection gate line SGD. This conductinglayer 25 electrically couples the plurality of the laminated conducting layers 22 of the drain-side selection gate line SGD to one another. Subsequently, as illustrated inFIG. 11 , the laminated films under the drain-side selection gate line SGD are processed in a staircase pattern by photolithography and etching again. Then, as illustrated inFIG. 12 , for example, an insulatinglayer 26 made of alumina or similar material is deposited as a stopper material at the time of the subsequent formation of the contacts Cw. Subsequently, as illustrated inFIG. 13 , the insulatingfilm 27 for protecting the upper portion of the drain-side selection gate line SGD is deposited. Then, as illustrated inFIG. 14A andFIG. 14B , memory holes are formed by photolithography and etching to form memory layers (not illustrated) including charge storage layers. Silicon to be channels is deposited to form the semiconductor layers 23 in columnar shapes. Lastly, the contacts Cw are formed and, additionally, thesacrifice films 22′ are replaced by metal films made of, for example, tungsten so as to obtain the configurations inFIGS. 4A and 4B . - Here, a description is given of the case where the
sacrifice films 22′ are replaced by the conducting layers 22 as the metal films above. However, for example, it is possible to laminate the conducting layers, which are made of silicon doped with impurities or similar material, and the interlayer insulating films from the start, so as to form the laminated body without replacement. - The insulating
layer 26 can employ various materials such as silicon nitride other than alumina described above. - According to the first embodiment described above, the plurality of the conducting layers 22 of the selection gate line are electrically coupled in common to the
conducting layer 25, which is arranged in their end portions. This allows obtaining a nonvolatile semiconductor memory device in a three-dimensional structure having a selection transistor with high selectivity. - The following describes a nonvolatile semiconductor memory device according to a second embodiment with reference to
FIGS. 15A to 15C . The overall configuration of this second embodiment is approximately identical to that of the first embodiment (inFIG. 1 toFIG. 6B ). However, this second embodiment differs from the first embodiment in the structure of the end portion of the selection gate line and the configuration of the conducting layer 25 (the second conducting layer). -
FIG. 15A is a partial cross-sectional view of thewiring portion 20 of the nonvolatile semiconductor memory device according to the second embodiment.FIG. 15B is a plan view of thewiring portion 20. - Regarding the
wiring portion 20 illustrated inFIG. 15A andFIG. 15B , in the end portion of the drain-side selection gate line SGD, the end portions of the interlayer insulatingfilms 21 retreat in the inward direction of the drain-side selection gate line SGD compared with the end portions of the conducting layers 22. In other words, the end portions of the conducting layers 22 project in the longitudinal direction compared with the end portions of the interlayer insulatingfilms 21. The conductinglayer 25 formed on the sidewall of the drain-side selection gate line SGD is formed extending into the voids caused by retreating of the interlayer insulatingfilms 21. - The method of manufacturing the
wiring portion 20 according to the second embodiment is approximately identical to the manufacturing method used in the first embodiment, but is differs from the first embodiment in the phase of forming theconducting layer 25 described usingFIG. 10 in the first embodiment. That is, in the second embodiment, as illustrated inFIG. 15C , wet etching using a chemical liquid is performed on the end portion of the laminated body to be the drain-side selection gate line SGD before the conductinglayer 25 is formed, so as to retreat theinterlayer insulating films 21. Then, after thesacrifice films 22′ are replaced by metal films made of, for example, tungsten as the conducting layers 22, the conductinglayer 25 is formed on the sidewall of the drain-side selection gate line SGD to be present also in the void portion caused by retreating of the interlayer insulatingfilms 21. In other words, the end portions of the interlayer insulatingfilms 21 are etched so as to cause the voids between the end portions of the conducting layers 22. Accordingly, the conductinglayer 25 is formed not only on the sidewalls of the conducting layers 22, but also inside these voids. The subsequent processes are similar to those in the first embodiment, and the configuration inFIG. 15A is thus obtained. - This second embodiment also allows providing effects identical to those in the first embodiment. Furthermore, in this second embodiment, the conducting layer is formed extending to the inner side of the end portion of the selection gate. This further increases the contacted area between the conducting layer and the conducting layers of the selection gate, thus reducing the resistance. This consequently provides preferable current characteristics, thus realizing excellent cell characteristics.
- A description will be given of other examples of the wiring portion with reference to
FIGS. 16 to 19 . - In the first and second embodiments, the plurality of the conducting layers 22 of the selection gate line are coupled in common to one
conducting layer 25, which is formed in the end portion of the selection gate line aligned in the longitudinal direction. However, likeFIG. 16 , it is also possible to: form the selection gate line portion, for example, in a staircase pattern for each of two layers whose end portions are aligned in the longitudinal direction; and form the conducting layers 25 in the end portions for each of the two layers aligned in the longitudinal direction so as to ensure electrical coupling. In other words, the plurality of the conducting layers 22 are formed as the staircase structure, and the conducting layers 22 having the identical steps are electrically coupled in common to theconducting layer 25. With this configuration, the portions that are not aligned in the longitudinal direction are electrically independent from one another. Accordingly, it is possible to employ various usages, for example, a method for applying different electric potentials to the respective portions. - In
FIG. 16 , the plurality of the conducting layers 22 electrically coupled in common to theconducting layer 25 are aligned in the longitudinal direction. However, as illustrated inFIG. 17 , the plurality of the conducting layers 22 can have the end portions having mutually different lengths, and a plurality of the conducting layers 22 having mutually different lengths can be electrically coupled in common to the conducting layer 25 (in the example ofFIG. 17 , the conducting layers having different lengths are electrically coupled in common for each of two layers). - As illustrated in
FIG. 18 , it is possible to employ the configuration where the plurality of the conducting layers 22 are formed as the staircase structure, one conductinglayer 25 is formed in the end portion of this staircase pattern, and all the plurality of the conducting layers 22 as the staircase pattern are electrically coupled in common. - In the above-described embodiments and modification, a description is given of the case where all the conducting layers 22 function as the gate electrodes of the selection gate lines. However, as illustrated in
FIG. 19 , a part of the conducting layers 22 can also be used as the dummy cells DMC without being used as the gate electrodes. Here, inFIG. 19 , the conductinglayer 22 as the dummy cell DMC is one layer. In this case, the conductinglayer 25 is not necessarily needed. - As apparent from the first and second embodiments and the modification described above, it is possible to employ various shapes of the conducting
layer 22 constituting the selection gate line and various arrangement methods of the conductinglayer 25 arranged in the end portion of the selection gate line, depending on the usage or similar condition. In the drawings used in the above description, there are always four layers of the conducting layers 22 and there are one or two layers of the conducting layers 25. Obviously, the number of laminations of the conducting layers 22 and the number of the conducting layers 25 are not limited to these. - The above-described nonvolatile semiconductor memory device according to the modification can also provide effects similar to those in the first and second embodiments that have been described.
- As the material of the
charge storage layer 104, the silicon nitride film (SiN) is described in the above-described embodiment as an example. However, the following oxides can also be selected. -
- SiO2, Al2O3, Y2O3, La2O3, Gd2O3, Ce2O3, CeO2, Ta2O5, HfO2, ZrO2, TiO2, HfSiO, HfAlO, ZrSiO, ZrAlO, and AlSiO
- AB2O4 (However, A and B are identical or different elements, and, are one of Al, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, and Ge. For example, Fe3O4, FeAl2O4, Mn1|xAl2 XO4|y, Co1|XAl2 XO4|y, and MnOx are employed.)
- ABO3 (However, A and B are identical or different elements, and, are one of Al, La, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, Bi, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, In, and Sn. For example, LaAlO3, SrHfO3, SrZrO3, and SrTiO3 are employed.)
- As the material of the
charge storage layer 104, the following oxynitrides can also be selected. -
- SiON, AlON, YON, LaON, GdON, CeON, TaON, HfON, ZrON, TiON, LaAlON, SrHfON, SrZrON, SrTiON, HfSiON, HfAlON, ZrSiON, ZrAlON, and AlSiON
- Further, it is also possible to employ the materials obtained by replacing a part of the oxygen elements of the oxides described above by nitrogen elements. In particular, one insulating layer and a plurality of insulating layers are each preferred to be selected from the group consisting of SiO2, SiN, Si3N4, Al2O3, SiON, HfO2, HfSiON, Ta2O5, TiO2, and SrTiO3.
- In particular, regarding silicon-based insulating films such as SiO2, SiN, and SiON, the respective concentrations of the oxygen elements and the nitrogen elements can be set to be equal to or more than 1×1018 atoms/cm3. However, the barrier heights of the plurality of insulating layers are different from one another. The insulating layer can include a material including impurity atoms that forms a defect level or semiconductor/metal dots (the quantum dots).
- While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the novel embodiments described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the embodiments described herein may be made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the inventions.
Claims (16)
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US16/941,106 US11309325B2 (en) | 2015-03-12 | 2020-07-28 | Nonvolatile semiconductor memory device and method of manufacturing the same |
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