US20140209590A1

US20140209590A1 - Modified flux system in cored electrode

Info

Publication number: US20140209590A1
Application number: US14/227,175
Authority: US
Inventors: Badri K. Narayanan; Russell K. Myers; Patrick T. Soltis
Original assignee: Lincoln Global Inc
Current assignee: Lincoln Global Inc
Priority date: 2006-01-20
Filing date: 2014-03-27
Publication date: 2014-07-31
Also published as: US8704135B2; US20070170163A1

Abstract

A welding system and cored welding electrode composition is disclosed for performing a short arc welding process between an advancing wire electrode and a workpiece. The system comprises a power source with a controller for creating a current pulse introducing energy into the electrode to melt the end of the electrode and a low current quiescent metal transfer section following the end of the melting pulse during which the melted electrode short circuits against the workpiece; a timer to measure the actual time between the end of the pulse and the short circuit; a device for setting a desired time from the pulse to the short circuit; a circuit to create a corrective signal based upon the difference between the actual time and the desired time; and, a circuit responsive to the corrective signal to control a given parameter of the current pulse.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS

The application claims priority to, is a divisional of and fully incorporates by reference, U.S. patent application Ser. No. 11/336,506 filed 20 Jan. 2006.

TECHNICAL FIELD

The present invention relates to the art of electric arc welding and more particularly to an improved short arc welding system, methods of welding with self-shielded flux cored arc welding (FCAW-S) electrodes, and the composition of the electrodes.

BACKGROUND OF THE INVENTION

This invention involves a novel short arc welding process employing a novel cored electrode. There is a synergistic relationship when combining the novel welding process and the novel flux cored electrode. As an attribute of the overall invention, there are independent advantages of the novel process combined with the flux cored electrode.

Short Arc Welding

Short-circuit arc welding systems, techniques, and associated concepts, as well as pipe welding methods and apparatuses are generally set forth in the following United States patents, the contents of which are hereby incorporated by reference as background information: Parks U.S. Pat. No. 4,717,807; Parks U.S. Pat. No. 4,954,691; Parker U.S. Pat. No. 5,676,857; Stava U.S. Pat. No. 5,742,029; Stava U.S. Pat. No. 5,961,863; Parker U.S. Pat. No. 5,981,906; Nicholson U.S. Pat. No. 6,093,906; Stava U.S. Pat. No. 6,160,241; Stava U.S. Pat. No. 6,172,333; Nicholson U.S. Pat. No. 6,204,478; Stava U.S. Pat. No. 6,215,100; Houston U.S. Pat. No. 6,472,634; and Stava U.S. Pat. No. 6,501,049.

Power Source

The electric arc welding field uses a variety of welding processes between the end of a consumable advancing electrode and a workpiece, which workpiece may include two or more components to be welded together. This invention relates to the short arc process wherein the advancing electrode is melted by the heat of the arc during a current pulse and then, after the molten metal forms into a ball by surface tension action, the molten metal ball is transferred to the workpiece by a short circuit action. The short circuit occurs when the advancing wire moves the ball into contact with the molten metal puddle on the workpiece, which short is sensed by a plunge in the welding voltage. Thereafter, the short circuit is broken and the short arc welding process is repeated. The invention is an improvement in short arc welding and is preferably performed by using a power source wherein the profile of the welding waveform is controlled by a waveform generator operating a pulse width modulator of a high switching speed inverter, as disclosed in several patents by assignee, such as shown in Parks U.S. Pat. No. 4,866,247; Blankenship U.S. Pat. No. 5,278,390; and, Houston U.S. Pat. No. 6,472,634, each of which is hereby incorporated by reference. These three patents illustrate the type of high switching speed power source employed for practicing the preferred embodiment of the present invention and are incorporated herein as background technology. The waveform of the waveform generator is stored in memory as a state table, which table is selected and outputted to the waveform generator in accordance with standard technology pioneered by The Lincoln Electric Company of Cleveland, Ohio. Such selection of a table for creating the waveform profile in the waveform generator is disclosed in several prior art patents, such as the previously mentioned Blankenship U.S. Pat. No. 5,278,390. Consequently, a power source used in practicing the present invention is now commonly known and constitutes background technology used in the present invention. An aspect of the novel short arc welding system of the present invention employs a circuit to determine the total energy of the melting pulse forming the molten metal ball of the advancing electrode, such as described in Parks U.S. Pat. No. 4,866,247. The total energy of the melting pulse is sensed by a watt meter having an integrated output over the time of the melting pulse. This technology is incorporated by reference herein since it is employed in one aspect of the present invention. After a short has been created in a short arc welding system, the short is cleared by a subsequent increase in the welding current. Such procedure is well known in short arc welding systems and is described generally in lhde U.S. Pat. No. 6,617,549 and in Parks U.S. Pat. No. 4,866,247. Consequently, the technology described in lhde U.S. Pat. No. 6,617,549 is also incorporated herein as background technology. The preferred embodiment of the invention is a modification of a standard AC pulse welding system well known in the welding industry. A prior pending application of assignee describes standard pulse welding, both DC and AC, with an energy measurement circuit or program for a high frequency switching power source of the type used in practicing the AC short circuit preferred implementation of the present invention. Although not necessary for understanding the present invention or practicing the present invention, this prior application, which is U.S. patent application Ser. No. 11/103,040 filed Apr. 11, 2005, (now U.S. Pat. No. 7,271,365) is incorporated by reference herein. Also incorporated herein by reference is U.S. patent application Ser. No. 10/959,587 filed Oct. 6, 2004.
The present invention relates to a cored electrode and a short arc welding system for controlling the melting pulse of the system for depositing a special cored electrode so no shielding gas is needed. The system maintains a desired time between the pulse and the actual short circuit. This time is controlled by a feedback loop involving a desired timing of the short circuit and the pulse, so that the size of the ball of the pulse is varied to maintain a consistent short circuit timing. This process is a substantial improvement of other short arc control arrangements, such as disclosed in Pijls U.S. Pat. No. 4,020,320 using two power sources. A first source maintains a constant size melting pulse and there is a fixed time between the short circuit and the subsequent clearing pulse. There is no feedback between the pulsed timing and a parameter of the melting pulse, as employed in the present invention. A desired time is maintained between the end of the melting pulse and the short circuit event. By fixing the desired time using a feedback loop concept, arc stability is improved. This invention is applicable to a DC process, as shown in Pijls U.S. Pat. No. 4,020,320, but is primarily advantageous when using an AC short arc welding system. Consequently, Pijls U.S. Pat. No. 4,020,320 is incorporated by reference herein as background technology showing a control circuit for a DC short arc system wherein two unrelated timings are maintained constant without a closed loop control of the melting pulse.

Cored Electrode

The invention involves a novel welding method employing a novel flux cored electrode or welding wire. Details of arc welding electrodes or wires and specifically, cored electrodes for welding are provided in U.S. Pat. Nos. 5,369,244; 5,365,036; 5,233,160; 5,225,661; 5,132,514; 5,120,931; 5,091,628; 5,055,655; 5,015,823; 5,003,155; 4,833,296; 4,723,061; 4,717,536; 4,551,610; and 4,186,293; all of which are hereby incorporated by reference.
Also, United States prior patent applications filed Sep. 8, 2003 as Ser. No. 10/655,685 (now U.S. Pat. No. 7,064,290); filed Apr. 29, 2004 as Ser. No. 10/834,141 (now U.S. Pat. No. 7,166,817); filed Oct. 6, 2004 as Ser. No. 10/959,587; and filed Oct. 31, 2005 as Ser. No. 11/263,064 (now U.S. Pat. No. 7,842,903) are each incorporated by reference as background, non-prior art technology.

SUMMARY OF THE INVENTION

In accordance with a first aspect of the invention as it relates to the method, the melting pulse of the short arc waveform is controlled interactively by a feedback loop and not by fixing constant values of the melting pulse. The time between the end of the melting pulse and the short circuit is maintained by reactively changing parameters of the melting pulse in a short arc welding system. The system is preferably an AC system, but can be used in a DC system of the type generally described in Pijis U.S. Pat. No. 4,020,320. Novel manipulation of the short arc waveform is facilitated by using a single power source having the waveform controlled by a waveform generator operating the pulse width modulator of a high switching speed inverter, such as disclosed in Houston U.S. Pat. No. 6,472,634. The advance realized by implementation of the present invention is an improvement over short arc welding using two separate power sources, as shown in the prior art.
In accordance with the preferred embodiment of the first aspect of the present invention, the short arc welding system is an AC system wherein the melting pulse has a negative polarity. To maintain a constant molten metal bead, there is a joule threshold switch to shift the power supply to a low level positive current so the molten metal on the end of the advancing electrode forms into a ball and then short circuits against the workpiece weld puddle. This AC waveform is preferably controlled by a waveform generator controlling the profile of the individual current segments of the waveform and determining the polarity of the waveform segments. In the prior art, a joule threshold switch was used to provide a constant energy to the melting pulse. In accordance with the present invention, there is a timer to measure the time for the electrode to short after the melting pulse. A feedback loop is employed to maintain a consistent time between the melting pulse and the short circuit event. This control of time stabilizes the arc and the shorting cycle. Ideally the time between the melting pulse and the short is about 1.0 ms. Depending upon the electrode size and deposition rate, the time between the melting pulse and the short circuit event is adjusted to a fixed value in the general range of 0.5 ms to 2.0 ms. Control of the timing is primarily applicable to AC short arc welding; however, the same concept is applicable to straight DC positive polarity. In both instances, the advancing wire with molten metal formed by the melting pulse is held at a low quiescent positive current facilitating the formation of a ball preparatory to the short circuit event. In either implementation of the invention, the joules or other parameter of the melting pulse is controlled by a feedback loop conditioned to maintain a preset time to the short circuit event.
The AC implementation of the first aspect of the present invention is primarily useful for tubular electrodes of the flux cored type and especially a novel implementation of a flux core electrode with alloy ingredients in the core. Control of the melting cycle of a flux cored electrode based upon feedback from the short circuit time is a very precise procedure to maintain stability of the AC short circuit welding process. The invention is also especially applicable to pipe welding with a cored electrode (especially the novel version of a flux cored electrode). The welding current for such electrode, when using the novel method, is below the threshold current for spray welding. Thus, the metal transfer to the pipe joint must involve some type of short circuit, normally a globular short circuit transfer of the type to which the present invention is directed. Improving the weld stability by using AC short arc welding still resulted in instability of the arc. This instability has been overcome by implementing the present invention. Thus, the present invention is particularly applicable to AC short arc welding of a pipe joint using a cored electrode.
In accordance with the first aspect of the present invention there is provided a welding system for performing a short arc welding process between an advancing wire electrode and a workpiece, where the system comprises a power source with a controller for creating a current pulse introducing energy into the electrode to melt the end of the electrode and a low current quiescent metal transfer section allowing the melted metal on the end of the electrode to be deposited into the weld puddle of the workpiece. During the low current metal transfer section, the molten metal short circuits against the molten metal puddle. A timer measures the actual time between the end of the melting pulse and the short circuit event. A device is used to set a desired time between the pulse and short circuit event and a circuit is used to create a corrective signal based upon the difference between the actual time and the desired time. This corrective signal is used to control a given parameter of the melting pulse, such as the total energy introduced into the wire during the melting pulse.
In accordance with the preferred implementation of the first aspect of the present invention, the short arc welding process is an AC process wherein the melting pulse is performed with a negative current and the quiescent low current metal transfer section of the waveform is at a positive polarity. The AC version of the present invention is particularly applicable for welding with a flux cored electrode in several environments, such as the root pass of a pipe welding joint.
In accordance with another aspect of the novel power source, the controller of the short arc welding system includes a circuit to create a short circuit clearing pulse after the short circuit. In the preferred power source a waveform generator determines the polarity and profile of the welding waveform at any given time. The welding system of the present invention is used to maintain the time between the melting pulse and the short at a fixed value, which fixed value is in the general range 0.5-2.0 ms and is preferably approximately 1.0 ms.
In accordance with another aspect of the power source or method performed by the power source, the short arc system is performed DC positive with both the melting pulse and the quiescent section being positive and followed by a short circuit positive clearing pulse. This implementation of the present invention does not involve a polarity change from the waveform generator during the processing of the waveform to practice the short arc welding process. The short arc welding system is AC and there is a circuit to control the current pulse for causing the actual time between the melting pulse and short circuit so it is the same as the desired time. Indeed, this implementation of the invention maintains a constant time, as does the preferred embodiment of the invention.
The principal implementation of the present invention controls the energy of the melting pulse to control the time between the melting pulse and the ultimate short circuit event.
Yet another aspect of the first aspect of the invention is the provision of a method for controlling the melting pulse of a short arc welding process so that the process has a selected time between the melting pulse and the short circuit event. The parameter controlled by this method is preferably the total energy of the melting pulse. The invention is particularly applicable for use in the root pass of a circular open root pipe joint using a flux cored electrode.
The present second aspect of the invention relates at least in part, to a discovery that by utilizing a relatively short arc length during AC welding as obtained by this novel short arc method, contamination of the weld from the atmosphere can be significantly reduced. The invention also relates at least in part, to a discovery of a particular flux alloy system, which when used in an electrode according to the second aspect. The flux/alloy system of the cored electrode enables and promotes a short arc length. Combining these aspects in accordance with the present invention, provides a synergistic phenomenon, i.e. the novel method and novel flux cored electrode that produces a sound and tough weld metal with strength of over 60 to 70 ksi. These alloys allow use of thinner pipes and there is no need for shielding gas in the pipe welding area.
Waveform technology as pioneered by The Lincoln Electric Company of Cleveland, Ohio has been modified for use in AC welding with flux cored electrodes. Cored electrodes allow the welding operation to be more precisely controlled with the alloy of the weld bead being tailored to the desired mechanical characteristics for the bead and with the position of the welding operation being less limited. However, to provide arc stability and appropriate melting temperatures and rates, the actual control of the waveform for the AC process is quite complicated. Contamination of the weld metal during arc welding is still a problem using AC welding for cored electrodes. Contaminants, in the weld metal after the welding operation can cause porosity, cracking and other types of defects in the weld metal. Consequently, a major challenge confronting designers of arc welding processes has been to develop techniques for excluding elements, such as contaminants from the atmosphere, from the arc environment or for neutralizing the potentially harmful effects of such impurities. The potential source of contamination, includes the materials that comprise the welding electrode, impurities in the workpiece itself and ambient atmosphere. Cored electrodes may contain “killing” agents, such as aluminum, magnesium, zirconium and titanium which agents combine chemically with potential contaminates to prevent them from forming porosity and harmful inclusion in the weld metal. The present invention involves the use of a unique, novel electrode composition that reduces the tendency of a cored electrode to allow inclusion of contaminants in the weld metal. The method also reduces the amount of material required as a “killing” agent.
Specifically, the present invention provides a self-shielded flux cored arc welding (FCAW-S) electrode particularly adapted for forming welds having reduced levels of contaminants using an AC waveform. The electrode has an alloy/flux system comprising from about 35 to about 55% barium fluoride, from about 2 to about 12% lithium fluoride, from about 0 to about 15% lithium oxide, from about 0 to about 15% barium oxide, from about 5 to about 20% iron oxide, and up to about 25% of a deoxidation and denitriding agent. This agent can be selected from aluminum, magnesium, titanium, zirconium, and combinations thereof.
The present invention provides a method of arc welding using a flux cored electrode that utilizes a particular alloy/flux system. The method comprises applying a first negative voltage between an electrode and a substrate to cause at least partial melting of the electrode proximate the substrate. The method also comprises applying a positive voltage between the electrode and the substrate to promote formation of a flowable mass of material from the electrode. The method further comprises monitoring for occurrence of an electrical short between the electrode and the substrate through the flowable mass. The method further comprises upon detecting an electrical short, applying a second negative voltage between the electrode and the substrate. And, the method comprises increasing the magnitude of the second negative voltage, to thereby clear the electrical short and form a weld on the substrate from the flowable mass. The flux cored electrode can comprise from about 35 to about 55% barium fluoride, from about 2 to about 12% lithium fluoride, from about 2 to about 15% lithium oxide, from about 5 to about 20% iron oxide, and up to about 25% of a deoxidation and denitriding agent selected from the group consisting of aluminum, magnesium, titanium, zirconium, and combinations thereof.
An object of the present invention is the provision of a short arc welding system, which system controls the spacing of the short circuit events during the process, especially when the process is performed in the AC mode.
Another object of the present invention is the provision of a method for short arc welding, which method controls the melting pulse based upon the time between the melting pulse and short so this time remains fixed at a desired value.
Yet another object of the present invention is the provision of an improved electrode composition, and particularly an electrode fill composition which is particularly adapted for use in combination with the novel short arc welding system and method.
A further object of the present invention is to provide a synergistic system comprising a short arc process and flux cored electrode to stabilize the arc at the shortest possible arc length. Thus, the contamination from the atmosphere is minimized. The combination of an alloy system and a weld process allows the arc to be stable at such short arc lengths and result in a sound and tough weld metal.
These and other objects and advantages will become apparent from the following description taken together with the accompanying drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a block diagram of a short arc welding system used in the preferred embodiment of the present invention;

FIG. 1A is an enlarged cross-sectional view taken generally along line 1A-1A of FIG. 1;

FIG. 2 is a series of side elevational views showing the stages I-IV in a short arc welding process;

FIG. 3 is a combined current and voltage waveform graph showing the waveform implementing the preferred embodiment of the present invention as disclosed in FIG. 4 for the various stages as shown in FIG. 2;

FIG. 4 is a flow chart block diagram illustrating a modification of the system in FIG. 1 to perform the preferred embodiment of the present invention;

FIG. 5 and FIG. 6 are flow chart block diagrams of a portion of the welding system shown in FIG. 1 for implementing two further embodiments of the present invention;

FIG. 7 and FIG. 8 are partial flow chart block diagrams of the welding system as shown in FIG. 1 combining the preferred embodiment of the present invention shown in FIG. 4 with a combined waveform control from the embodiments of the invention shown in FIG. 5 and FIG. 6, respectively;

FIG. 9 is a current waveform for the DC positive implementation of the present invention;

FIG. 10 is a schematic elevational view showing the invention used in the root pass or tacking pass of a pipe welding joint;

FIG. 11 is a side elevational view with a block diagram illustrating the use of a representative welding system and an electrode;

FIG. 12 is an enlarged cross-sectioned pictorial view taken generally along line 12-12 of FIG. 11, depicting the electrode in greater detail;

FIG. 13 is an enlarged, schematic view representing a cored electrode where the sheath and core are melted at different rates;

FIG. 14 is a view similar to FIG. 13 illustrating the disadvantage of a failure to employ a tailored waveform for welding with cored electrodes;

FIG. 15 is a view similar to FIGS. 13 & 14; and

FIG. 16 is a partial, side elevational view illustrating a cored electrode in accordance with the present invention and showing the arc length, which length is minimized by use of the present invention.

These and other modifications of the discussed embodiments, as well as other embodiments of the invention, will be obvious and suggested to those skilled in the art from the disclosure herein, whereby it is to be distinctly understood that the foregoing descriptive matter is to be interpreted merely as illustrative of the present invention and not as a limitation thereof.

DETAILED DESCRIPTION OF THE INVENTION

Novel Power Source/Method

In the electric arc welding industry, short arc welding is a common practice and involves the four stages I, II, III and IV as schematically disclosed in FIG. 2. The power source for performing short arc welding can be a transformer based power source; however, in accordance with the preferred embodiment of the present invention, system A, shown in FIG. 1, utilizes a high switching speed inverter based power source B having an AC supply across lines 10, 14, or a three phase supply, directed to inverter 14 creating a first DC signal across lines 14 a, 14 b. In accordance with standard architecture, boost or buck converter 20 is used in power source B for correcting the input power factor by creating a controlled second DC signal across output lines 22, 24. High switching speed inverter 30 converts the second DC signal across lines 22, 24 to a waveform created by a large number of current pulses across output leads 32, 34. In accordance with the preferred embodiment of the present invention, the waveform across leads 32, 34 is either DC positive or AC; therefore, inverter 30 has an output stage, not shown, that dictates the polarity of the profiled waveform across leads 32, 34. These leads are connected to electrode E and workpiece WP, respectively. In accordance with standard short arc technology, electrode E is an advancing end of wire W supplied through contact tip 42 from supply spool or drum 40. Thus, wire W is driven toward workpiece WP at a given WFS as a controlled waveform having the desired polarity is created across the gap between electrode E and workpiece WP. Wire W is preferably a flux cored wire schematically illustrated in FIG. 1A and shown to include an outer low carbon steel sheath 50 surrounding an internal flux core 52 having a fluxing agent and normally including alloying particles. Shunt 60 drives feedback current device 62 so the voltage signal on line 64 is representative of the instantaneous arc current of the welding process. In a like manner, device 70 creates a signal on output line 72 representative of the instantaneous voltage of the welding process. Controller C of inverter 30 is a digital device, such as a DSP or microprocessor, that performs functions schematically illustrated in generally analog architecture. As a central component of controller C a waveform generator 100 processes a specific waveform from a state table stored in memory unit 102 and selected according to the desired welding process by device or circuit 104. Upon selecting the desired short arc welding process a select signal 104 a is directed to memory unit 102 so that the state table defining the attributes and parameters of the desired short arc welding waveform is loaded into waveform generator 100 as indicated by line 102 a. Generator 100 outputs the profile of the waveform at any given time on output line 100 a with the desired polarity indicated by the logic on line 100 b. Illustrated power source B controlled by digital controller C is of the current control feedback type wherein the current representative voltage on line 64 is combined with the waveform profile signal on line 100 a by error amplifier 110 having an output signal on line 110 a to control pulse width modulator 112 in accordance with standard waveform control technology. The output signal on line 112 a controls the shape of the waveform across lines 32, 34 and the polarity of the particular waveform profile being implemented is set by the logic on line 100 b. In this manner, waveform generator 100 controls pulse width modulator 112 to have pulses in line 112 a controlling the high frequency operation of inverter 30. This inverter switching frequency is generally greater than 18 kHz and preferably greater than about 40 kHz. As so far described, power source B with controller C operates in accordance with standard technology pioneered by The Lincoln Electric Company of Cleveland, Ohio. Controller C is digital, but illustrated in analog format. To implement a short arc welding process, it is necessary for controller C to receive feedback information regarding a short circuit condition between electrode E and workpiece WP. This feature of controller C is schematically illustrated as a short circuit detector 120 that creates a logic on line 122 to announce the existence of a short circuit event SC to waveform generator 100. Thus, the generator is informed when there is a short circuit and implements a waveform in accordance with processing a short circuit as accomplished in any short arc welding process. As so far described, controller C is standard technology, with the exception of controlling a polarity switch at the output of inverter 30 by the logic on line 100 b.
To practice the invention, controller C is provided with a circuit 150 for controlling the melting pulse preparatory to the short circuit. Circuit 150 is digital, but schematically illustrated in analog architecture. The functions are implemented by the digital processor of controller C to control the energy of the melting pulse. Such energy control circuitry is described in prior copending U.S. patent application Ser. No. 11/103,040 filed by applicant on Apr. 11, 2005 (now U.S. Pat. No. 7,271,365). This prior application is incorporated by reference herein not as prior art, but as related technology. As shown in the prior application, the energy of the melting pulse of a pulsed welding waveform can be controlled by circuit 150 including multiplier 152 for multiplying the instantaneous signal on lines 64, 72 to provide a signal on line 154 representing the instantaneous watts of the welding process. The wattage signal or line 154 is accumulated by a standard integrator 156 as described in Parks U.S. Pat. No. 4,866,247. Integration of the watt signal on line 154 is controlled by waveform generator 100 that creates a pulse start command shown as block 160 to correspond to the start of the melting pulse indicated by logic on line 162. The starting point is the time t₁when the melting pulse is started by waveform generator 100. Output signal on line 164 starts integration of the watt signal on line 154 by integrator 156. The integration process is stopped by a logic on line 170 produced by activation of stop pulse device or circuit 172 upon receipt of logic on input line 172 a. Logic on line 172 a toggles device 172 to change the logic in output lines 172 a and 172 c. The logic on line 172 c informs the waveform generator that the melting pulse is to stop to change the profile on output line 100 a. At the same time, the signal on line 172 b toggles reset device or circuit 174 to change the logic on line 170 to stop integration of the instantaneous watt signal. The digital number on output line 156 a is loaded into digital register 180 having an output 182 representing the total energy of a given melting pulse in the short art welding process. This total energy signal is compared with a desired energy level stored in register 190 to provide a digital number or signal on line 192. Comparator 194 compares the actual energy for a given pulse represented by a number on line 182 with a desired energy level indicated by the number on line 192. The relationship between the actual energy and the desired energy controls the logic on line 172 a. When the signal from line 182 equals the signal on line 192, comparator 194 changes the logic on line 172 a to stop the pulse as indicated by device or circuit 172. This stops integration and stops the melting pulse being created by waveform generator 100. Circuit 150 is employed for performing the preferred embodiment of the present invention which changes the reference or desired energy for the melting pulse by changing the number on line 192 through adjustment of circuit 200. The pulse is stopped when the adjusted energy or energy threshold is reached as determined by the number signal on line 182 as compared to the signal on line 192. The preferred embodiment of the novel power source and method used in the combined invention adjusts circuit 200 to change the reference energy for performing a novel short arc welding process by changing the melting pulse.
Short arc welding system A using power source B with digital controller C is operated by adjusting circuit 200 to perform the waveform shown in FIG. 3. AC current waveform 200 has a negative melting pulse 212 represented by stage I in FIG. 2 where the melting pulse produces molten metal 220 on the end of electrode E. The level of current in pulse 212 is below current needed for spray arc so there is a transfer by a short. The time t₁starts the Joule measurement as explained later. The pulse has a start position 212 a at time t₁and a stop position 212 b at time t₂. Following the melting pulse, in accordance with standard practice, there is a positive low current quiescent transfer section 214, as represented by stage II of FIG. 2. In this stage, the molten metal 220 on the end of advancing electrode E is formed into a ball by surface tension action awaiting a short circuit which occurs at time t₃and is shown as stage III. Consequently, the time between t₂and t₃is the time between the end of the melting pulse and the short circuit event, which time is indicated by the logic on line 122 as shown in FIG. 1. After stage II, a current pinch action shown as neck 222 separates the molten metal 220 from puddle 224. This electrical pinching action shown in stage IV is accelerated in accordance with standard practice by a negative short circuit pulse 216 having a first current section 216 a with a steep slope and followed by a second current section 216 b with a more gradual slope. Ultimately, the shorted metal separates and the SC logic on line 122 shifts to start the next current pulse at time t₁indicated by a transition section 218. Waveform 210 is an AC waveform having a negative melting pulse 212, a low current quiescent section 214 and a clearance pulse 216 transitioning into the next negative pulse 212 at time t₁. The corresponding voltage has a waveform 230 with negative section 232, a low level positive section 234 that plunges at short 236 and is followed by a negative voltage section 238 that transitions at section 240 into the next melting pulse voltage 232. The total cycle time is from t₁to the next t₁and the positive transfer 214 has a time less than 20% of the total cycle time. This prevents stubbing.
The present invention involves a novel power source and method for controlling waveform 210 by waveform generator 100 of controller C so the time between the end of melting pulse 212 at t₂and the time of the actual short event t₃is constant based upon adjustment of circuit 200. This time delay adjustment, in the preferred embodiment, is accomplished by the circuit 250 shown in FIG. 4. In this circuit, the time between the melting pulse and at time t₂and the short circuit at time t₃is set to a desired level between 0.5 to 2.0 ms. Preferably, the set desired time delay is 1.0 ms, which is the level of the signal on line 254. Thus, the numerical number on line 254 is the desired time t₂to t₃. The actual time between t₂and t₃is determined by timer 260 which is started at time t₂and stopped at time t₃. The timer is reset for the next measurement by an appropriate time indicated as t₅which can be adjusted to be located at various positions after t₃, which position is illustrated to be during the melting pulse in FIG. 3. The number on line 262 is the actual time between t₂and t₃. This actual time is stored in register 270 which is reset at any appropriate time such as time t₂. Thus, the digital data on line 272 is the actual measured time between t₂and t₃. This time is compared to the desired time on line 254. Any error amplifier can be used to digitally process the relationship of actual time to the set time. The process is schematically illustrated as a summing junction 280 and digital filter 282 having an output 284 for adjusting circuit 200. The difference between the desired time and the actual time is an error signal in line 284 which increases or decreases the desired total energy of circuit 200. The desired total energy is periodically updated at an appropriate time indicated as t₂by an update circuit 290. Thus, at all times the signal in line 192 of FIG. 1 is the desired total energy for pulse 212 of the short arc process. This total energy is adjusted by any difference between time t₂and time t₃so the energy of pulse 212 maintains a constant or desired time delay for the upcoming short circuit. This time control stabilizes the short arc welding process of system A.
In FIG. 4, the preferred embodiment of the novel power source is implemented by changing the energy threshold for the melting pulse to change the timing between the pulse and the short event. This time can also be changed by voltage or power of the melting pulse as schematically illustrated in FIGS. 5 & 6. In both of these embodiments, the time of the melting pulse t₁to t₂is maintained fixed as indicated by block 300. During this constant time melting pulse, the voltage or power is changed to control the time between the pulse and the short circuit event. In FIG. 5, the number on output line 284 from filter 282 controls feedback loop 310 to adjust the voltage of the melting pulse, as indicated by the numerical data on line 312. To adjust the power for controlling the delay time of the short circuit event, the number on output line 284 is used to adjust feedback loop 320, which is compared to the instantaneous power on line 154 by waveform generator 100. The change in power is a numerical value on line 322 which is compared to the digital number on line 154 for controlling the power of the melting pulse. Thus, in the first three embodiments of the present invention, the total energy of the waveform, the voltage of the waveform or the power of the waveform is adjusted to maintain a constant time between t₂to t₃to stabilize the arc and control the short circuit events of system A shown in FIG. 1.
In accordance with another embodiment of the novel power source, the energy adjustment of melting pulse 212 is combined with the two modifications of the present invention illustrated in FIGS. 5 & 6. Such combination controls are shown in FIGS. 7 & 8 wherein prior summing junction 280 and digital filter 282 are illustrated as combined in analog error amplifier 330. The component or program has output 332 with a logic for stopping the melting pulse when the threshold energy has been reached, as indicated by the logic on line 182. Thus, the total energy of the pulse is controlled together with the pulse voltage control circuit 310 in FIG. 7 and the pulse power control 320 as shown in FIG. 8. Output 312 is combined with output 172 c for controlling the waveform profile in line 100 a of generator 100. In a like manner, the energy level is controlled by logic on line 172 c in combination with the digital information on output line 322 of power pulse control circuit 320. Other combinations of parameters can be used to control melting pulse 212 to assure an accurate control of the time between the melting pulse and the short circuit event. Such other parameters are within the skill of the art in controlling a waveform generator by closed feedback loops.
The invention is preferably an AC process, as shown in FIG. 4; however, DC positive waveform 400 can be used as shown in FIG. 9. Melting pulse 402 has a high positive current 402 a until the pulse is terminated at time t₂. The current, in the DC positive mode, is limited to a level below that needed for spray arc so the metal is not detached without shorting. This concept defines the short arc welding process. Then the waveform transitions into a low level positive current section 404 awaiting the short at time t₃. This low level positive current is used in the preferred embodiment of the present invention and terminates at time t₃. Thereafter, short clearing pulse 410 is created by the waveform generator. Pulse 410 has high ramp area 412 and a stepped area 414 to bring the current back up to the high current level 402 a. Various illustrated embodiments of the present invention can be used in implementing the positive current waveform 400; however, the logic on line 100 b for controlling the polarity of the output waveform on lines 32, 34 is not necessary.

Novel Flux Cored Electrode

The preferred implementation of the inventive power source is in pipe welding operation using a novel flux cored electrode as schematically represented in FIG. 1A. Such pipe welding operation is schematically illustrated in FIG. 10 wherein pipe sections 420, 422 define an open root 424. The present invention as shown in FIG. 4 controls the waveform on wire W as it moves through contact tip 42 to open root 424 of the pipe joint. FIG. 10 shows a particular embodiment using the present invention for welding the root pass of a pipe joint to tack the pipe sections together for subsequent joining with standard welding techniques.
In certain embodiments, the power sources and/or welding operations according to the present invention exhibit one or more of the following aspects. The current density is generally less than that required for spray welding since the primary mode of metal transfer is short circuit welding. As in many short circuit processes, a pinch current is established depending upon the wire diameter, for example for a 5/64 inch flux cored wire, a current of 625 amps can be used. Generally, the positive current tends to set the arc length. If the positive current is allowed to reach the same level as the negative current arc length, even for half a millisecond, the positive current arc will reach a non-desirable length. Generally, positive side control current is in the range of from about 50 amps to about 125 amps, and preferably about 75 amps. The negative portion of the wave shape can either be a constant power or voltage with a slope of from about 5 to 15 percent current. Typically, welding can be performed at about 60 hertz, 10 percent positive. Since the positive current is set at a relatively low level, the portion that the wave shape is positive is typically less than 20 percent.
FIGS. 11 & 12 schematically illustrate a waveform technology welder and/or welding system 510, and a cored electrode 530. The welding system comprises a welder 510 having a torch 520 for directing an electrode 530 toward workpiece W. The welding system 510 includes a three phase input power supply L1, L2, and L3, which is rectified through rectifier 550, 560, and a power source 540. The power source 540 provides an output, and specifically, an AC waveform as described in U.S. patent application Ser. No. 11/263,064, filed Oct. 31, 2005, (now U.S. Pat. No. 7,842,903) previously incorporated by reference. An arc AC is created between the end of electrode 530 and workpiece W. The electrode is a cored electrode with a sheath 600 and an internal filled core 610. The core includes flux ingredients, such as represented by particles 610 a. The purpose of these ingredients 610 a is to (a) shield the molten weld metal from atmospheric contamination by covering the molten metal with slag, (b) combine chemically with any atmospheric contaminants such that their negative impact on the weld quality is minimized and/or (c) generate arc shielding gases. In accordance with standard practice, core 610 also includes alloying ingredients, referred to as particles 610 b, together with other miscellaneous particles 610 c that are combined to provide the fill of core 610. To optimize the welding operation, it has been necessary to use solid wire with an external shielding gas. However, in order to produce a weld with specific mechanical and metallurgical properties, specific alloys are required, which can be difficult to obtain in the form of a solid wire. Gas shielding is not always a feasible alternative due to access to gas or difficulty to achieve adequate shielding due to windy conditions, accessibility to clean gas mixtures and difficult terrains. It would be advantageous to therefore use a self shielding cored electrode, so that the environment does not affect the welding.
A common problem caused when using cored electrodes without control of the welding waveform profile is illustrated in FIG. 13. The welding process melts sheath 600 to provide a portion of molten metal 630 melted upwardly around the electrode, as indicated by melted upper end 640. Thus, the sheath of the electrode is melted more rapidly than the core. This causes a molten metal material to exist at the output end of electrode 530 without protective gas or chemical reaction created by melting of the internal constituents of core 610. Thus, arc AC melts the metal of electrode 610 in an unprotected atmosphere. The necessary shielding for the molten metal is formed when the sheath and core are melted at the same rate. The problem of melting the molten metal more rapidly than the core is further indicated by the pictorial representation of FIG. 14. Molten metal 650 from sheath 600 has already joined workpiece W before the core 610 has had an opportunity to be melted. Thus, the core 610 cannot provide the necessary shielding for the welding process. FIGS. 13 & 14 show the reason why AC welding using cored electrodes has not been used for off-shore pipeline welding and other pipeline welding. However, an AC waveform can be utilized to control the heat input when using a cored electrode.
By controlling the precise profile for the AC waveform used in the welding process, sheath 600 and core 610 can be made to melt at approximately the same rate. The failure to adequately coordinate the melting of the sheath with the melting of the core is one reason why a shielding gas SG, as shown in FIG. 15 may be used. The advantage of controlling the profile of the AC waveform is that external shielding gas SG, may be avoided.
Although control of the AC waveform can lead to significant advantages, as previously noted, in order to provide arc stability and appropriate melting temperatures and rates, the actual control of the AC waveform, is quite complicated. And, even with the use of sophisticated AC waveforms, contamination of the weld is possible. Contamination of welds formed by using sophisticated AC waveforms, is still possible, even if shielding gas is used. Accordingly, in a preferred aspect of the present invention, certain electrode compositions are provided that, when used in conjunction with AC waveforms, can form strong, tough, and durable welds, without significant contamination problems, and without the degree of control otherwise required for the AC waveforms.

Novel Electrodes

When welding by the novel method or power source with a cored electrode, it is desired to have the sheath and core melt at the same rate. This operation promotes homogeneous mixing of certain core materials with the outer sheath, such that the mixture of molten materials chemically resists the effects of atmospheric contamination. Alloying elements required to produce desired weld metal mechanical and metallurgical characteristics are uniformly distributed in the weld metal. In addition, the protective benefits derived from slag and/or gas-forming constituents are optimized. As previously noted, this situation is illustrated in FIG. 15. In contrast, FIG. 14 illustrates a situation where the sheath has melted more rapidly than the core. In this deleterious situation, molten metal 650 from sheath 500 has already joined workpiece W before core 610 has had an opportunity to be melted. Metal 650 has not been protected from the effects of atmospheric contamination to the degree that it would have been if the unmelted core constituents had actually been melted. Additionally, alloying elements needed to achieve desired mechanical and metallurgical characteristics may be missing from molten metal 650.
As previously indicated, an electric welder of the type using waveform technology can be used for AC welding using a cored electrode, such as electrode 700 shown in FIG. 16. Such electrode includes an outer steel sheath 710 surrounding core 720 formed of particulate material, including alloying metals and slag or flux materials. By having internal flux or slag materials, there is no need for external shielding gas during the welding operation. By including alloying material in core 720, the puddle of weld metal 740 on workpiece 730 can be modified to have exact alloy constituents. This is a substantial advantage and reason for using cored electrodes, instead of solid welding wire where alloying must be accomplished by the actual constituent of the welding wire. Adjustment of alloying for the weld metal is quite difficult when using solid welding wire. Therefore, it is extremely advantageous in high quality welding to employ a cored electrode. Arc AR melts sheath 710 and melts constituents or fill in core 720 at a rate which can be controlled to be essentially the same. Contamination in weld metal 740, such as hydrogen, nitrogen and oxygen can cause porosity problems, cracking and other types of physical defects in the weld metal. Thus, it is a challenge to design the welding process to exclude contaminates from the molten weld metal. It is common to use “killing” agents, typically silicon, aluminum, titanium and/or zirconium which will combine chemically with potential contaminates to prevent them from forming porosity or harmful inclusions in the weld metal. Furthermore, “scavengers” may also be added to react with hydrogen containing a species in order to remove hydrogen from the weld. In order to deposit consistently sound weld metal 740, it has often been necessary to add such killing agents in quantities that are themselves detrimental to properties of the weld metal, such as ductility and low temperature toughness. Thus, it is desirable to reduce the exposure of the molten metal in arc AR to prevent contamination of the metal passing from electrode 700 to workpiece 730 so the killing agents can be minimized.
The novel electrode compositions when used in AC welding, produce desirable welds that are durable, tough, and which are not susceptible to problems otherwise associated with the use of conventional electrode compositions. The electrode compositions of the present invention are preferably used in conjunction with AC waveforms where the positive and negative shapes of the AC waveform are modified to reduce the overall arc length LA. In this manner, there is less exposure to the atmosphere and less time during which the metal is molten. A detailed description of the AC waveforms and related welding processes, for which the present invention electrode compositions are designed, is set forth in U.S. patent application Ser. No. 11/263,064, filed Oct. 31, 2005, (now U.S. Pat. No. 7,842,903) previously incorporated by reference. Indeed, by reducing the arc length, the temperature of the molten metal can be reduced as it travels from the electrode 700 to weld metal puddle 740. Only by using a welder that can perform an AC welding process with different shapes for the negative and positive sections, can AC welding with cored electrodes be used effectively in the field. Parameters of the positive and negative portions of the alternating waveform can be independently adjusted to compensate for and optimize the melting of both sheath 710 and core 720 for selected electrode 700.
More specifically, the overall invention involves the combination of a novel electrode and an AC welding wherein the positive and negative sections of the waveform are individually adjusted to accomplish the objective of a low arc length and reduce contamination. Using this strategy, the inventive electrode composition, particularly because it is self-shielding, can provide significant advantages. The electrodes are used without shielding gas and depending upon the particular application, can rely on deoxidizing and denitriding agents in the core for additional protection from atmospheric contamination.
The invention provides a synergistic system of a novel welding method with a unique set of alloying and flux components in the core of a FCAW-S electrode. As noted, a cored electrode is a continuously fed tubular metal sheath with a core of powdered flux and/or alloying ingredients. These may include fluxing elements, deoxidizing and denitriding agents, and alloying materials, as well as elements that increase toughness and strength, improve corrosion resistance, and stabilize the arc. Typical core materials may include aluminum, calcium, carbon, chromium, iron, manganese, and other elements and materials. While flux cored electrodes are more widely used, metal-cored products are useful for adjusting the filler metal composition when welding alloy steels. The powders in metal-cored electrodes generally are metal and alloy powders, rather than compounds, producing only small islands of slag on the face of the weld. By contrast, flux cored electrodes produce an extensive slag cover during welding, which supports and shapes the bead.
The alloy/flux system of the present invention comprises particular amounts of a barium source, particular amounts of a lithium source, lithium oxide, iron oxide, and optional amounts of calcium oxide, silicon oxide, and manganese oxide. One or more fluoride, oxide and/or carbonate salts of barium can be used for the barium source. And, one or more fluoride and/or carbonate salts of lithium can be used for the lithium source. The alloy/flux system is included in the electrode fill. The electrode fill generally constitutes from about 18 to about 24% of the electrode. A preferred alloy/flux system comprises:


Percentages	Component

from ~35% to ~55%	barium fluoride as the barium source
from ~2% to ~12%	lithium fluoride as the lithium source
from ~0% to ~8%	barium carbonate as a secondary barium source
from ~0% to ~8%	lithium carbonate as the secondary lithium source
from ~0% to ~15%	lithium oxide
from ~0% to ~15%	barium oxide
from ~5% to ~20%	iron oxide
from ~0% to ~5%	calcium oxide
from ~0% to ~5%	silicon oxide
from ~0% to ~5%	manganese oxide
up to ~25%	Al, Mg, Ti, Zr or combinations thereof,
	for deoxidation and denitriding

and the remaining metallics optionally including iron, nickel, manganese, silicon, or combinations thereof. All percentages expressed herein are percentages by weight unless noted otherwise.

Preferably, the electrode fill composition comprises from about 35 to about 55% barium fluoride, from about 2 to about 12% lithium fluoride, from about 0 to about 15% lithium oxide, from about 0 to about 15% barium oxide, from about 5 to about 20% iron oxide, and up to about 25% of a deoxidizing and denitriding agent as previously noted. In other embodiments, the previously noted preferred electrode fill composition can also include from about 0 to about 8% barium carbonate. In yet another embodiment, the preferred electrode fill composition may additionally include from about 0 to about 8% lithium carbonate. In yet another embodiment, the preferred fill composition can include from about 0 to about 5% calcium oxide. In yet a further embodiment, the electrode fill composition can include from about 0 to about 5% silicon oxide. And, in another embodiment, the preferred electrode fill composition can comprise from about 0 to about 5% manganese oxide. Other embodiments include the use of one or more of these agents, i.e. the barium carbonate, lithium carbonate, calcium oxide, silicon oxide, manganese oxide, and combinations thereof.
The preferred embodiment of the novel method comprises applying a first negative voltage between an electrode and a substrate to cause at least partial melting of the electrode near the substrate. The method also comprises applying a positive voltage between the electrode and the substrate to promote formation of a flowable mass of material from the electrode. The method further comprises monitoring for occurrence of an electrical short between the electrode and the substrate through the flowable mass. The method further comprises upon detecting an electrical short, applying a second negative voltage between the electrode and the substrate. And, the method comprises increasing the magnitude of the second negative voltage, to thereby clear the electrical short and form a weld on the substrate from the flowable mass.
The preferred composition of the electrode fill in a flux cored electrode comprises from about 35 to about 55% barium fluoride, from about 2 to about 12% lithium fluoride, from about 0 to about 15% lithium oxide, from about 0 to about 15% barium oxide, from about 5 to about 20% iron oxide, and up to about 25% of a deoxidation and denitriding agent selected from the group consisting of aluminum, magnesium, titanium, zirconium, and combinations thereof. In other embodiments, additional agents can be incorporated in the preferred electrode fill. For instance, from about 0 to about 8% barium carbonate can be included. Another embodiment of the electrode fill composition includes from about 0 to about 8% lithium carbonate. Yet another embodiment includes from about 0 to about 5% calcium oxide. Another embodiment includes from about 0 to about 5% silicon oxide. And, yet another embodiment includes from about 0 to about 5% manganese oxide. In yet a further embodiment, one or more of these agents can be added or otherwise included in the electrode fill composition. For example, the preferred electrode fill can also comprise, in addition to the previously noted proportions of barium fluoride, lithium fluoride, lithium oxide, barium oxide, iron oxide, and one or more particular deoxidation and denitriding agents from about 0 to about 8% barium carbonate, from about 0 to about 8% lithium carbonate, from about 0 to about 5% calcium oxide, from about 0 to about 5% silicon oxide, and from about 0 to about 5% manganese oxide.
The novel flux/alloy system is modified from traditional flux/alloy systems used for FCAW-S electrodes to achieve the short arc length and to weld at low heat inputs that result from the unique waveforms used in this process. The short arc length and the stable arc is a result of the combination of the alloy and flux system and the unique characteristics of the waveform. In essence, both the welding consumable and the process are optimized in tandem to achieve the final weld product requirements.
In certain embodiments, the present invention provides methods of forming weld metals having attractive properties. Generally, these methods involve providing a welding wire or electrode having a core with the previously described composition. Preferably, the welding wire or electrode is used free of shielding gas, or rather agents that form such a gas. The methods also include an operation in which the wire or electrode is moved toward the region of interest, such as a joint formed between two sections of pipe. Preferably such movement is made at a controlled feed speed. The method also includes creating a welding current to melt the wire or electrode by an arc between the wire and the pipe sections to thereby form a molten metal bead in the joint. The method also includes transferring the melted wire to the molten metal bead by a succession of short circuit events. The method is particularly well suited for application to welding of a joint between two sections of pipe formed from a metal having a yield strength of at least about 70 ksi and a thickness less than about 0.75 inches. However, it will be appreciated that the present invention can be used in applications on pipes having thicknesses greater than or less than 0.75 inches. The resulting bead that is formed generally has a tensile strength greater than 70 ksi and in certain applications, greater than about 90 ksi. In particular aspects, the melting current can be negative. If the melting current is negative, the metal transferring operation can be performed by a positive current. The metal transferring can however, be performed by a positive current independent of the melting current. When performing the previously described method, it is generally preferred that the average arc length is less than 0.30 inches, preferably less than 0.20 inches, and most preferably less than 0.10 inches. In the previously described method, the rate of the short circuit events is preferably automatically controlled. The rate of short circuit events is generally from about 40 to about 100 cycles per second.
In other embodiments, the previously described concepts, i.e. using the power sources and control techniques in combination with the novel electrode compositions noted herein, can be utilized to produce a weld metal having a minimum Charpy V-Notch toughness of 60 J at −20° C. Similarly, the methods can be used to produce a weld metal having a minimum Charpy V-Notch toughness of 40 J at −40° C. And, the methods can be used to produce a weld metal having a tensile strength exceeding 90 ksi. Thus, thin pipe of less than about 0.75 inches can be used with the resultant savings. No shielding gas is needed, so the cost of on-site gas is eliminated.
The present application can be utilized in a wide array of applications. The system, process, and/or compositions described herein are particularly adapted for use in welding X80 pipe (the designation X80 being in accordance with the API 5L:2000 industry specification) with self-shielded flux core wire. However, the present invention can be utilized in conjunction with other pipe grades. The present invention can also be utilized in “root pass” or tack welding operations performed on pipes. The present invention can be utilized to melt greater amounts of welding wire with less arc force as compared to currently known practices of using a buried short arc for the initial welding pass. Yet another application for the present invention is in robotic welding applications for high speed welding of thin gauge metals.
The present invention has been described with certain embodiments and applications. These can be combined and interchanged without departing from the scope of the invention as defined in the appended claims. The systems, methods, electrodes and combinations thereof as defined in these appended claims are incorporated by reference herein as if part of the description of the novel features of the synergistic invention.

Claims

What is claimed is:

1. A self-shielded flux cored arc welding (FCAW-S) electrode particularly adapted for forming welds having reduced levels of contaminants using an AC waveform, the electrode fill having an alloy/flux system comprising:

from ˜35 wt % to ˜55 wt % barium fluoride;

from ˜2 wt % to ˜12 wt % lithium fluoride;

up to ˜15 wt % lithium oxide;

up to ˜15 wt % of barium oxide; and

from ˜5 wt % to ˜20 wt % iron oxide.

2. The electrode as defined in claim 1, the alloy/flux system further comprising:

up to ˜25 wt % of at least one deoxidation and denitriding agent selected from the group consisting of aluminum, magnesium, titanium, zirconium, and combinations thereof.

3. The electrode as defined in claim 1 wherein the alloy/flux system further comprises:

up to ˜8 wt % barium carbonate.

4. The electrode as defined in claim 1 wherein the alloy/flux system further comprises:

up to ˜8 wt % lithium carbonate.

5. The electrode as defined in claim 1 wherein the alloy/flux system further comprises:

up to ˜5 wt % calcium oxide.

6. The electrode as defined in claim 1 wherein the alloy/flux system further comprises:

up to ˜5 wt % silicon oxide.

7. The electrode as defined in claim 1 wherein the alloy/flux system further comprises:

up to ˜5 wt % manganese oxide.

8. The electrode of claim 2 wherein the alloy/flux system further comprises:

up to ˜8 wt % barium carbonate;

up to ˜8 wt % lithium carbonate;

up to ˜5 wt % calcium oxide;

up to ˜5 wt % silicon oxide; and

up to ˜5 wt % manganese oxide.

9. The electrode of claim 1 wherein the electrode fill constitutes

from ˜18 wt % to ˜24 wt % of the electrode.

10. A flux cored electrode adapted to form a weld metal having a minimum Charpy V-Notch toughness of 60 J at −20° C. upon short arc welding, the electrode comprising a core having an alloy/flux system comprising:

from ˜35 wt % to ˜55% wt % barium fluoride;

from ˜2 wt % to ˜12 wt % lithium fluoride;

up to ˜15 wt % lithium oxide;

up to ˜15 wt % barium oxide; and

from ˜5 wt % to ˜20 wt % iron oxide.

11. The electrode as defined in claim 10 wherein the alloy/flux system further comprising

up to ˜25 wt % of a deoxidation and denitriding agent selected from the group consisting of aluminum, magnesium, titanium, zirconium, and combinations thereof.

12. The electrode as defined in claim 10 wherein the electrode further comprises:

up to ˜8 wt % barium carbonate.

13. The electrode as defined in claim 10 wherein the electrode further comprises:

up to ˜8 wt % lithium carbonate.

14. The electrode as defined in claim 10 wherein the electrode further comprises:

up to ˜5 wt % calcium oxide.

15. The electrode as defined in claim 10 wherein the electrode further comprises:

up to ˜5 wt % silicon oxide.

16. The electrode as defined in claim 10 wherein the electrode further comprises:

up to ˜5 wt % manganese oxide.

17. The electrode as defined in claim 10 wherein the alloy/flux system further comprises:

up to ˜8 wt % barium carbonate;

up to ˜8 wt % lithium carbonate;

up to ˜5 wt % calcium oxide;

up to ˜5 wt % silicon oxide; and

up to ˜5 wt % manganese oxide.

18. A flux cored electrode adapted to produce weld metal having a tensile strength greater than 90 ksi upon short arc welding, the electrode comprising a core having an alloy/flux system comprising:

from ˜35 wt % to ˜55% barium fluoride;

from ˜2 wt % to ˜12 wt % lithium fluoride;

up to ˜15 wt % lithium oxide;

up to ˜15% barium oxide; and

from ˜5 wt % to ˜20 wt % iron oxide.

19. The electrode as defined in claim 18 wherein the alloy/flux system further comprising

20. The electrode as defined in claim 18 wherein the electrode further comprises:

up to ˜8 wt % barium carbonate.

21. The electrode as defined in claim 18 wherein the electrode further comprises:

up to ˜8 wt % lithium carbonate.

22. The electrode as defined in claim 18 wherein the electrode further comprises:

up to ˜5 wt % calcium oxide.

23. The electrode as defined in claim 18 wherein the electrode further comprises:

up to ˜5 wt % silicon oxide.

24. The electrode as defined in claim 18 wherein the electrode further comprises:

up to ˜5 wt % manganese oxide.

25. The electrode as defined in claim 18 wherein the alloy/flux system further comprises:

up to ˜8 wt % barium carbonate;

up to ˜8 wt % lithium carbonate;

up to ˜5 wt % calcium oxide;

up to ˜5 wt % silicon oxide; and

up to ˜5 wt % manganese oxide.