US20110086887A1 - Oil-Based Suspension Concentrates - Google Patents
Oil-Based Suspension Concentrates Download PDFInfo
- Publication number
- US20110086887A1 US20110086887A1 US11/912,069 US91206906A US2011086887A1 US 20110086887 A1 US20110086887 A1 US 20110086887A1 US 91206906 A US91206906 A US 91206906A US 2011086887 A1 US2011086887 A1 US 2011086887A1
- Authority
- US
- United States
- Prior art keywords
- oil
- alkyl
- insects
- suspension concentrate
- dispersant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- YWTYJOPNNQFBPC-UHFFFAOYSA-N [H]N1CCN(CC2=CC=C(Cl)N=C2)/C1=N/[N+](=O)[O-] Chemical compound [H]N1CCN(CC2=CC=C(Cl)N=C2)/C1=N/[N+](=O)[O-] YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 2
- 0 *C(=C)N(*)CC Chemical compound *C(=C)N(*)CC 0.000 description 1
- WCXDHFDTOYPNIE-RIYZIHGNSA-N C/C(=N\C#N)N(C)CC1=CC=C(Cl)N=C1 Chemical compound C/C(=N\C#N)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 1
- CFRPSFYHXJZSBI-DHZHZOJOSA-N CCN(CC1=CC=C(Cl)N=C1)/C(=C/[N+](=O)[O-])NC Chemical compound CCN(CC1=CC=C(Cl)N=C1)/C(=C/[N+](=O)[O-])NC CFRPSFYHXJZSBI-DHZHZOJOSA-N 0.000 description 1
- NWWZPOKUUAIXIW-DHZHZOJOSA-N CN1COCN(CC2=CN=C(Cl)S2)/C1=N/[N+](=O)[O-] Chemical compound CN1COCN(CC2=CN=C(Cl)S2)/C1=N/[N+](=O)[O-] NWWZPOKUUAIXIW-DHZHZOJOSA-N 0.000 description 1
- HOKKPVIRMVDYPB-UVTDQMKNSA-N N#C/N=C1\SCCN1CC1=CC=C(Cl)N=C1 Chemical compound N#C/N=C1\SCCN1CC1=CC=C(Cl)N=C1 HOKKPVIRMVDYPB-UVTDQMKNSA-N 0.000 description 1
- PGOOBECODWQEAB-UHFFFAOYSA-N [H]N(CC1=CN=C(Cl)S1)/C(=N/[N+](=O)[O-])NC Chemical compound [H]N(CC1=CN=C(Cl)S1)/C(=N/[N+](=O)[O-])NC PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 description 1
- YKBZOVFACRVRJN-UHFFFAOYSA-N [H]N(CC1CCOC1)/C(=N/[N+](=O)[O-])NC Chemical compound [H]N(CC1CCOC1)/C(=N/[N+](=O)[O-])NC YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
Definitions
- the present invention relates to new, oil-based suspension concentrates of active agrochemicals, to a process for producing these formulations and to their use for applying the active substances comprised.
- WO 03/000053 describes formulations of this type which in addition to active substance and oil comprise alkanol alkoxylates as penetrants.
- non-aqueous suspension concentrates are already known in which besides active agrochemical, penetrant and surfactant or surfactant mixture there is an organic solvent, suitable solvents of this type including liquid paraffin or vegetable oil esters.
- suitable solvents of this type including liquid paraffin or vegetable oil esters.
- oil-based suspension concentrates of the invention can be produced by mixing
- oil-based suspension concentrates of the invention are highly suitable for applying the active agrochemicals comprised to plants and/or their habitat.
- the oil-based suspension concentrates of the invention exhibit very good stability despite containing no thickener. Also unexpected is the fact that they display a better biological activity than the existing formulations most similar in composition. Surprisingly, moreover, in terms of their activity, the oil-based suspension concentrates of the invention also surpass similar preparations which besides the other components contain either only penetrant or only vegetable oil. No such synergistic effect was foreseeable from the above-described prior art.
- oil-based suspension concentrates of the invention exhibit better biological activity than commercially customary formulations. It is common knowledge that formulations of systemic active substances in which the substance is present in solution are generally more effective than those in which the active substance is dispersed as solid particles, as is the case in the formulations of the invention. The very rapid uptake of systemic active substances with the formulation of the invention results, for example, in an absence of dependency on temperature and atmospheric humidity, and enhances rain resistance.
- the oil-based suspension concentrates of the invention are also notable for a series of further advantages. For instance, their production is less complex than the preparation of corresponding formulations in which thickeners are present. A further advantage is that, when the concentrates of the invention are diluted with water, there is neither significant creaming nor disruptive flocculation, which is frequently the case with existing preparations of this kind. Finally, the formulations of the invention promote the biological activity of the active components comprised, so that in comparison to conventional preparations either a higher activity is obtained or less active substance is needed.
- Appropriate active substances are insecticides from the class of the neonicotinoids. They are outstandingly suitable for controlling animal pests (in this regard see the cited documents).
- Insecticides from the class of the neonicotinoids can be described by formula (II) below
- One compound used with preference in accordance with the invention is thiamethoxam.
- a further compound used with preference in accordance with the invention is clothianidin.
- Clothianidin has the formula
- a further compound used with preference in accordance with the invention is thiacloprid.
- a further compound used with preference in accordance with the invention is dinotefuran.
- a further compound used with preference according to the invention is acetamiprid.
- Acetamiprid has the formula
- a further compound used with preference according to the invention is nitenpyram.
- Nitenpyram has the formula
- a further compound used with preference according to the invention is imidacloprid.
- Imidacloprid has the formula
- Suitable penetrants in the present context are compounds of the formula (I) described earlier on above.
- Preferred compounds of the formula (I) are those
- alkanol alkoxylates A general definition of the alkanol alkoxylates is given by the above formula (I). These substances are mixtures of substances of the stated type with different chain lengths. The indices therefore have average values which may also deviate from whole numbers.
- alkanol alkoxylates of the formulae indicated are known or can be prepared by known methods (cf. WO 98-35 553, WO 00-35 278 and EP-A 0 681 865).
- Suitable vegetable oils include all oils which can normally be used in agrochemical compositions and can be obtained from plants. Examples that may be mentioned include sunflower oil, rapeseed oil, olive oil, castor oil, colza oil, maize seed oil, cottonseed oil and soya-bean oil.
- the oil-based suspension concentrates of the invention comprise at least one nonionic surfactant or dispersant and/or at least one anionic surfactant or dispersant.
- Suitable nonionic surfactants or dispersants include all substances of this type that can normally be used in agrochemical compositions.
- Suitable anionic surfactants include all substances of this type that can normally be used in agrochemical compositions. Preference is given to alkali metal salts and alkaline earth metal salts of alkylsulphonic acids or alkylarylsulphonic acids.
- a further preferred group of anionic surfactants or dispersants includes the following salts that are of low solubility in vegetable oil: salts of polystyrenesulphonic acids, salts of polyvinylsulphonic acids, salts of naphthalenesulphonic acid-formaldehyde condensation products, salts of condensation products of naphthalenesulphonic acid, phenolsulphonic acid and formaldehyde, and salts of ligninsulphonic acid.
- Suitable additives which may be included in the formulations of the invention are emulsifiers, foam inhibitors, preservatives, antioxidants, colorants and inert fillers.
- Preferred emulsifiers are ethoxylated nonylphenols, reaction products of alkylphenols with ethylene oxide and/or propylene oxide, ethoxylated arylalkylphenols, and also ethoxylated and propoxylated arylalkylphenols, and also sulphated or phosphated arylalkyl ethoxylates and/or arylalkyl ethoxy-propoxylates, it being possible to mention, by way of example, sorbitan derivatives, such as polyethylene oxide-sorbitan fatty acid esters and sorbitan fatty acid esters.
- Suitable foam inhibitors include all substances that can normally be used for this purpose in agrochemical compositions. Preference is given to silicone oils and magnesium stearate.
- Suitable preservatives include all substances that can normally be used for this purpose in agrochemical compositions of this type. Examples that may be mentioned include Preventol® (Bayer AG) and Proxel®.
- Suitable antioxidants include all substances that can normally be used for this purpose in agrochemical compositions. Preference is given to butylated hydroxytoluene.
- Suitable colorants include all substances that can normally be used for this purpose in agrochemical compositions. Mention may be made, by way of example, of titanium dioxide, pigmentary carbon black, zinc oxide and blue pigments, and also Permanent Red FGR.
- Suitable inert fillers include all substances that can normally be used for this purpose in agrochemical compositions but do not function as thickeners. Preference is given to inorganic particles, such as carbonates, silicates and oxides, and also organic substances, such as urea-formaldehyde condensates. By way of example mention may be made of kaolin, rutile, silicon dioxide, so-called highly disperse silica, silica gels, and also natural and synthetic silicates, and additionally talc.
- the formulations of the invention may further comprise at least one additional active substance (insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulators or herbicides).
- the insecticides include, for example, phosphates, carbamates, carboxylic esters, chlorinated hydrocarbons, phenylureas, substances produced by microorganisms, etc.
- Oxidative Phosphorylation Decouplers Acting by Interrupting the H-Proton Gradient
- the amount of the individual components can be varied within a relatively wide range in the oil-based suspension concentrates of the invention.
- concentrations can be varied within a relatively wide range in the oil-based suspension concentrates of the invention.
- the oil-based suspension concentrates of the invention are produced by mixing the components with one another in the respectively desired proportions.
- the order in which the constituents are combined with one another is arbitrary.
- the solid components are used in a finely ground state. It is, however, also possible to subject the suspension which results after the constituents have been combined first to a coarse grinding and then to a fine grinding, so that the mean particle size is below 20 ⁇ m.
- Preferred suspension concentrates are those in which the solid particles have a mean size between 1 and 10 ⁇ m.
- the temperatures when carrying out the process of the invention can be varied within a certain range.
- the work is carried out generally at temperatures between 10° C. and 60° C., preferably between 15° C. and 40° C.
- Equipment suitable for carrying out the process of the invention includes customary mixing and grinding apparatus which is used for producing agrochemical formulations.
- the oil-based suspension concentrates of the invention constitute formulations which remain stable even following prolonged storage at elevated temperatures or in the cold, since no crystal growth is observed. By dilution with water they can be converted into homogeneous spray liquids. These spray liquids are applied by customary methods, i.e., for example, by spraying, pouring or injecting.
- the application rate of the oil-based suspension concentrates of the invention can be varied within a relatively wide range. It is guided by the particular active agrochemicals and by their amount in the formulations.
- plants here are meant all plants and plant populations, such as desirable and unwanted wild plants or crop plants (including naturally occurring crop plants).
- Crop plants may be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and gene-technological methods or combinations of these methods, including the transgenic plants and including the plant cultivars which can or cannot be protected by varietal property rights.
- plant parts are to be meant all above-ground and below-ground parts and organs of the plants, such as shoot, leaf, flower and root, an exemplary listing embracing leaves, needles, stems, trunks, flowers, fruit bodies, fruits and seeds and also roots, tubers and rhizomes.
- the plant parts also include harvested material and also vegetative and generative propagation material, examples being seedlings, tubers, rhizomes, cuttings and seeds.
- compositions according to the invention with regard to their use in cereal plants such as, for example, wheat, oats, barley, spelt, triticale and rye, but also in maize, sorghum and millet, rice, sugar cane, soya beans, sunflowers, potatoes, cotton, oilseed rape, canola, tobacco, sugar beet, fodder beet, asparagus, hops and fruit plants (comprising pome fruit such as, for example, apples and pears, stone fruit such as, for example, peaches, nectarines, cherries, plums and apricots, citrus fruits such as, for example, oranges, grapefruits, limes, lemons, kumquats, tangerines and satsumas, nuts such as, for example, pistachios, almonds, walnuts and pecan nuts, tropical fruits such as, for example, mango, paw-paw, pineapple, dates and bananas, and grape
- acephala var. sabellica L. (curly kale, feathered cabbage), kohlrabi, Brussels sprouts, red cabbage, white cabbage and Savoy cabbage
- fruit vegetables such as, for example, aubergines, cucumbers, capsicums, table pumpkins, tomatoes, courgettes and sweetcorn
- root vegetables such as, for example celeriac, wild turnips, carrots, including yellow cultivars, Raphanus sativus var. niger and var. radicula , beetroot, scorzonera and celery
- legumes such as, for example, peas and beans, and vegetables from the Allium family such as, for example, leeks and onions).
- the treatment of the plants and plant parts in accordance with the invention with the suspension concentrates is carried out directly or by action on their environment, habitat or storage area in accordance with the customary treatment methods, for example by dipping, spraying, vaporizing, atomizing, broadcasting or painting on and, in the case of propagation material, especially seeds, additionally by single or multiple coating.
- the active agrochemicals comprised develop a better biological activity than when applied in the form of the corresponding conventional formulations.
- the mixture is stirred at room temperature for a further 10 minutes.
- the resultant homogeneous suspension is subjected first to coarse grinding and then to fine grinding, giving a suspension in which 90% of the solid particles have a size below 6 ⁇ m.
- the mixture is stirred at room temperature for a further 10 minutes.
- the resultant homogeneous suspension is subjected first to coarse grinding and then to fine grinding, giving a suspension in which 90% of the solid particles have a size below 6 ⁇ m.
- the mixture is stirred at room temperature for a further 10 minutes.
- the resultant homogeneous suspension is subjected first to coarse grinding and then to fine grinding, giving a suspension in which 90% of the solid particles have a size below 6 ⁇ m.
- the mixture is stirred at room temperature for a further 10 minutes.
- the resultant homogeneous suspension is subjected first to coarse grinding and then to fine grinding, giving a suspension in which 90% of the solid particles have a size below 6 ⁇ m.
- the mixture is stirred at room temperature for a further 10 minutes.
- the resultant homogeneous suspension is subjected first to coarse grinding and then to fine grinding, giving a suspension in which 90% of the solid particles have a size below 6 ⁇ m.
- the mixture is stirred at room temperature for a further 10 minutes.
- the resultant homogeneous suspension is subjected first to coarse grinding and then to fine grinding, giving a suspension in which 90% of the solid particles have a size below 6 ⁇ m.
- Antifoam 1500 silicone material Arlaton T(V): polyoxyethylene-sorbitol oleate Atlas G 1281: polyoxyalkylene-fatty acid glyceride Atlox MBA 13/20: singly branched alcohol ethoxylate (20 EO) Atlox 4838 B: mixture of alkylarylsulphonate and ethylhexanol Borresperse NA: lignin sulphonate Lutensol TO 6: alkanol alkoxylate of formula R—O-(EO) 6 -H Silfoam 1132: polydimethylsiloxane Vulkanox BHT: butylated hydroxytoluene Zephrym PD 7000: polyoxyalkyleneamine derivative
- This test measures the penetration of active substances through enzymatically isolated cuticles of apple leaves.
- the leaves used were cut in the fully developed state from apple trees of the Golden Delicious variety.
- the cuticles were isolated as follows:
- the cuticular membranes obtained in this way were placed in stainless steel diffusion cells (transport chambers) for the purpose of membrane transport investigations.
- the cuticles were placed centrally using tweezers on the edges of the diffusion cells, which were coated with silicone grease, and sealed with a ring, which was likewise greased.
- the arrangement was chosen so that the morphological outer face of the cuticles was directed outwards, in other words to the air, while the original inner side was facing the interior of the diffusion cell.
- the diffusion cells were filled with a 1% phospholipid suspension. Penetration was determined by applying 10 ⁇ l of the spray liquor of the composition below, containing radiolabelled imidacloprid, to the outer face of each cuticle.
- the spray liquor is prepared using local mains water of average hardness.
- the water was evaporated and then the chambers were inverted and placed in thermostatted troughs, in which the temperature and air humidity over the cuticle was adjustable by means of a gentle air stream onto the cuticles with the spray covering (20° C., 60% rh). At regular intervals, an autosampler took aliquots which were subjected to measurement in a scintillation counter.
- Imidacloprid applied by spraying to citrus fruits and stone fruits (0.05% by weight, 1000 l/ha) against Dysaphis plantaginea.
- the table below contains average values from a number of field trials in Spain, comparing the formulation as per Example 2 (0.05% by weight concentration at 1000 l/ha) with the commercial formulation Confidor SL 200.
- Spray liquor A 0.1 g imidacloprid 0.32 g sunflower oil 0.05 g polyoxyethylene-sorbitol oleate 0.025 g polyoxyalkyleneamine derivative 0.01 g lignin sulphonate in 1 litre of water.
- Spray liquor B 0.1 g imidacloprid 0.2 g alkanol alkoxylate from Preparation Example 1 0.05 g polyoxyethylene-sorbitol oleate 0.025 g polyoxyalkyleneamine derivative 0.01 g lignin sulphonate in 1 litre of water.
- Spray liquor C 0.1 g imidacloprid 0.44 g sunflower oil 0.1 g alkanol alkoxylate from Preparation Example 1 0.05 g polyoxyethylene-sorbitol oleate 0.025 g polyoxyalkyleneamine derivative 0.01 g lignin sulphonate in 1 litre of water.
- Spray liquor D 0.1 g imidacloprid 0.03 g acrylic graft copolymer (Atlox 4913) 0.01 g tristyrylphenol ethoxylate 0.1 g glycerol in 1 litre of water.
- the water used in each of the spray liquors was CIPAC water.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005018262.3 | 2005-04-20 | ||
DE102005018262A DE102005018262A1 (de) | 2005-04-20 | 2005-04-20 | Suspensionskonzentrate auf Ölbasis |
PCT/EP2006/003202 WO2006111279A1 (de) | 2005-04-20 | 2006-04-07 | Suspensionskonzentrate auf ölbasis |
Publications (1)
Publication Number | Publication Date |
---|---|
US20110086887A1 true US20110086887A1 (en) | 2011-04-14 |
Family
ID=36588943
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/912,069 Abandoned US20110086887A1 (en) | 2005-04-20 | 2006-04-07 | Oil-Based Suspension Concentrates |
Country Status (17)
Country | Link |
---|---|
US (1) | US20110086887A1 (zh) |
EP (1) | EP1874115A1 (zh) |
JP (1) | JP2008536882A (zh) |
KR (1) | KR20080002969A (zh) |
CN (1) | CN101193553A (zh) |
AR (1) | AR053362A1 (zh) |
AU (1) | AU2006237085B2 (zh) |
BR (1) | BRPI0610045A2 (zh) |
CA (1) | CA2605219A1 (zh) |
DE (1) | DE102005018262A1 (zh) |
IL (1) | IL186679A0 (zh) |
MA (1) | MA29410B1 (zh) |
RU (1) | RU2416198C2 (zh) |
TW (1) | TW200704366A (zh) |
UA (1) | UA89230C2 (zh) |
WO (1) | WO2006111279A1 (zh) |
ZA (1) | ZA200708894B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100179228A1 (en) * | 2007-06-12 | 2010-07-15 | Bayer Cropscience Ag | Novel Oil-Based Adjuvant Composition |
US20110003875A1 (en) * | 2008-02-25 | 2011-01-06 | Bayer Cropscience Ag | Oil-Based Suspension Concentrates |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005048539A1 (de) * | 2005-10-11 | 2007-04-12 | Bayer Cropscience Ag | Suspensionskonzentrate auf Ölbasis |
EP1905302A1 (de) * | 2006-09-30 | 2008-04-02 | Bayer CropScience AG | Suspensionskonzentrate |
US20120122696A1 (en) * | 2010-05-27 | 2012-05-17 | Bayer Cropscience Ag | Use of oil based suspension concentrates for reducing drift during spray application |
CN103079407A (zh) * | 2010-06-29 | 2013-05-01 | 拜耳知识产权有限责任公司 | 改进的包含环羰基脒的杀虫组合物 |
EP2422619A1 (en) | 2010-08-31 | 2012-02-29 | Cheminova A/S | Neonicotinyl formulations |
CN107484767A (zh) * | 2017-08-14 | 2017-12-19 | 江苏龙灯化学有限公司 | 一种油基悬浮剂及其制备方法和用途 |
EP3878279A1 (en) | 2020-03-10 | 2021-09-15 | Bayer Aktiengesellschaft | Use of oil based suspo-emulsion concentrates for reducing drift during spray application |
CN113749089B (zh) * | 2020-06-02 | 2023-11-03 | 江苏龙灯化学有限公司 | 一种具有改善的稳定性的油分散组合物 |
GB202207660D0 (en) * | 2022-05-25 | 2022-07-06 | Upl Mauritius Ltd | Fungicide composition |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040157745A1 (en) * | 2001-06-21 | 2004-08-12 | Ronald Vermeer | Oil-based suspension concentrates |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10118076A1 (de) * | 2001-04-11 | 2002-10-17 | Bayer Ag | Verwendung von Fettalkoholethoxylaten als Penetrationsförderer |
DE102004011007A1 (de) * | 2004-03-06 | 2005-09-22 | Bayer Cropscience Ag | Suspensionskonzentrate auf Ölbasis |
-
2005
- 2005-04-20 DE DE102005018262A patent/DE102005018262A1/de not_active Withdrawn
-
2006
- 2006-04-07 EP EP06724140A patent/EP1874115A1/de not_active Withdrawn
- 2006-04-07 AU AU2006237085A patent/AU2006237085B2/en not_active Expired - Fee Related
- 2006-04-07 UA UAA200712888A patent/UA89230C2/ru unknown
- 2006-04-07 KR KR1020077026675A patent/KR20080002969A/ko not_active Application Discontinuation
- 2006-04-07 BR BRPI0610045-7A patent/BRPI0610045A2/pt not_active IP Right Cessation
- 2006-04-07 CA CA002605219A patent/CA2605219A1/en not_active Abandoned
- 2006-04-07 RU RU2007142432/21A patent/RU2416198C2/ru not_active IP Right Cessation
- 2006-04-07 US US11/912,069 patent/US20110086887A1/en not_active Abandoned
- 2006-04-07 CN CNA2006800209326A patent/CN101193553A/zh active Pending
- 2006-04-07 JP JP2008506964A patent/JP2008536882A/ja not_active Withdrawn
- 2006-04-07 WO PCT/EP2006/003202 patent/WO2006111279A1/de active Application Filing
- 2006-04-18 AR ARP060101524A patent/AR053362A1/es not_active Application Discontinuation
- 2006-04-19 TW TW095113867A patent/TW200704366A/zh unknown
-
2007
- 2007-10-16 IL IL186679A patent/IL186679A0/en unknown
- 2007-10-17 ZA ZA200708894A patent/ZA200708894B/xx unknown
- 2007-10-29 MA MA30329A patent/MA29410B1/fr unknown
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040157745A1 (en) * | 2001-06-21 | 2004-08-12 | Ronald Vermeer | Oil-based suspension concentrates |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100179228A1 (en) * | 2007-06-12 | 2010-07-15 | Bayer Cropscience Ag | Novel Oil-Based Adjuvant Composition |
US20110003875A1 (en) * | 2008-02-25 | 2011-01-06 | Bayer Cropscience Ag | Oil-Based Suspension Concentrates |
Also Published As
Publication number | Publication date |
---|---|
BRPI0610045A2 (pt) | 2010-05-25 |
MA29410B1 (fr) | 2008-04-01 |
TW200704366A (en) | 2007-02-01 |
AR053362A1 (es) | 2007-05-02 |
DE102005018262A1 (de) | 2006-10-26 |
UA89230C2 (ru) | 2010-01-11 |
ZA200708894B (en) | 2009-05-27 |
WO2006111279A1 (de) | 2006-10-26 |
RU2416198C2 (ru) | 2011-04-20 |
JP2008536882A (ja) | 2008-09-11 |
AU2006237085B2 (en) | 2011-04-28 |
CA2605219A1 (en) | 2006-10-26 |
AU2006237085A1 (en) | 2006-10-26 |
CN101193553A (zh) | 2008-06-04 |
EP1874115A1 (de) | 2008-01-09 |
KR20080002969A (ko) | 2008-01-04 |
RU2007142432A (ru) | 2009-05-27 |
IL186679A0 (en) | 2008-02-09 |
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