US20110067342A1 - Embedded clip attachment for cast architectural element - Google Patents

Embedded clip attachment for cast architectural element Download PDF

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Publication number
US20110067342A1
US20110067342A1 US12/956,610 US95661010A US2011067342A1 US 20110067342 A1 US20110067342 A1 US 20110067342A1 US 95661010 A US95661010 A US 95661010A US 2011067342 A1 US2011067342 A1 US 2011067342A1
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Prior art keywords
clip
core
mesh
disposed
portions
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Abandoned
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US12/956,610
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Wesley E. Hotchkiss, III
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Individual
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Individual
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Priority to US12/956,610 priority Critical patent/US20110067342A1/en
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/14Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
    • E04F13/144Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass with an outer layer of marble or other natural stone
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C1/00Building elements of block or other shape for the construction of parts of buildings
    • E04C1/40Building elements of block or other shape for the construction of parts of buildings built-up from parts of different materials, e.g. composed of layers of different materials or stones with filling material or with insulating inserts
    • E04C1/41Building elements of block or other shape for the construction of parts of buildings built-up from parts of different materials, e.g. composed of layers of different materials or stones with filling material or with insulating inserts composed of insulating material and load-bearing concrete, stone or stone-like material
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0801Separate fastening elements
    • E04F13/0832Separate fastening elements without load-supporting elongated furring elements between wall and covering elements
    • E04F13/0833Separate fastening elements without load-supporting elongated furring elements between wall and covering elements not adjustable
    • E04F13/0835Separate fastening elements without load-supporting elongated furring elements between wall and covering elements not adjustable the fastening elements extending into the back side of the covering elements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0885Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements specially adapted for being adhesively fixed to the wall; Fastening means therefor; Fixing by means of plastics materials hardening after application
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T24/00Buckles, buttons, clasps, etc.
    • Y10T24/44Clasp, clip, support-clamp, or required component thereof
    • Y10T24/44983Clasp, clip, support-clamp, or required component thereof formed from single rigid piece of material
    • Y10T24/44991Clasp, clip, support-clamp, or required component thereof formed from single rigid piece of material having specific surface irregularity on or along engaging face

Definitions

  • the present invention generally relates to cast architectural elements, and more specifically to such elements used as simulated stone blocks for replacing more expensive and heavy solid ornamental stone on building exteriors and interiors.
  • stone exteriors are preferred.
  • the use of solid stone blocks requires significantly more fuel for transportation due to vehicle weight restrictions.
  • cast architectural elements have a facing of relatively expensive pure or composite stone, with backings of less expensive, and typically relatively lighter weight materials.
  • foam core architectural element that is coated to resemble stone and is sold under the trademark ELEGANT STONETM by L&W Supply of Chicago, Illinois (www.lwsupply.com).
  • such products include an exterior surface of ornamental stone, such as limestone, marble, quartz, silica or the like in a cement matrix with aggregate in a castable formulation.
  • the element is produced so that the exterior shell is fused to an interior core of expanded polystyrene foam (EPS).
  • EPS expanded polystyrene foam
  • the interior core is thus significantly lighter and easier to handle and install than conventional solid stone blocks.
  • this type of architectural element costs a fraction of solid stone.
  • the present embedded clip attachment for a cast architectural element, which features the ability to install such elements on building exterior or interior substrates with fasteners as well as adhesive.
  • an attachment clip is embedded in the interior of the block, and is virtually impossible to pull out without destroying the block.
  • the present attachment fully encases the foam core in stone or cement or settable matrix.
  • a single integral clip has a portion for accommodating a fastener for securing the block to the building exterior or interior, and a second portion for engaging the foam core.
  • a cast architectural element including a stone shell having front, end, side and rear walls defining an internal cavity, the rear walls defining a rear opening.
  • a core is disposed in the internal cavity, and at least one attachment clip is provided having a first portion extending from the shell, and a second portion engaged in the core.
  • a layer of mesh is disposed upon the core and the second clip portion, and a settable filler layer is disposed upon the mesh in the rear opening, such that upon setting, the filler retains the clip in position.
  • a method of forming a cast architectural element includes the steps of providing a pre-cast element having a front, end, side and rear walls defining an internal cavity, the rear walls defining a rear opening, and forming edges of the rear walls to angle inwardly; providing a foam core disposed in the internal cavity; providing at least one attachment clip having a first portion extending from the shell, and a second portion with at least one tooth configured for insertion into the core, and placing the clips on said element so that the second portion engages the core; placing a layer of mesh upon the core and the second clip portion, so that edges of the mesh are beneath an inner corner of each edge; and applying a settable filler layer upon the mesh in the rear opening, such that upon setting, the filler retains the clip in position.
  • a clip for use in securing a cast architectural element to a substrate wherein the element has a stone shell having front, end, side and rear walls defining an internal cavity, the rear walls defining a rear opening, a core is disposed in the internal cavity, a layer of mesh is disposed upon the core, and a settable filler layer is disposed upon the mesh in the rear opening, such that upon setting, the filler retains the clip in position.
  • the clip includes a first clip portion with an eyelet, a second clip portion with at least one core engaging tooth, a transition portion between the first and second clip portions which axially displaces the first and second portions, which are parallel to each other.
  • FIG. 1 is a fragmentary top perspective view of the present block with embedded clip
  • FIG. 2 is an exploded perspective view of the block of FIG. 1 ;
  • FIG. 3 is a partially exploded view of the block of FIG. 2 ;
  • FIG. 4 is a top perspective view of the present block partially assembled
  • FIG. 5 is a top perspective view of the final assembly of the present block
  • FIG. 6 is a top perspective of the block of FIG. 6 fully assembled
  • FIG. 7 is a bottom perspective of a clip suitable for use with the present block.
  • FIG. 8 is a fragmentary elevation of a wall having a plurality of the present blocks attached thereto.
  • a cast architectural element is generally designated 10 and is shown as an ornamental facade construction block; however other types of cast architectural elements are contemplated, including but not limited to trim pieces, moldings, baseboard moldings, mantles, wainscoting, window sills, window jams, columns, column bases, column caps, cornices, headboards, and the like.
  • a stone shell 12 having a front wall 14 , a pair of side walls 16 , a pair of end walls 18 , and a pair of rear walls 20 defining an internal cavity 22 (shown hidden).
  • the rear walls 20 each have a corresponding edge 24 spaced from each other to define a rear opening 26 . It will be seen in FIG. 1 that the edges 24 are angled inwardly so that an inner corner 28 of each edge is closer to an adjacent one of the side walls 16 than an outer corner 30 .
  • a core 32 is disposed in the internal cavity 22 , and as is known in the art, the core is made of expanded polystyrene foam (EPS) which becomes fused to inner surfaces of the stone shell 12 through the casting process.
  • EPS expanded polystyrene foam
  • the stone shell 12 is preferably made of a cement matrix with aggregate, as described above, and may be made of marble, quartz, limestone, silica or the like, as well as mixtures of the above.
  • approximately 3 ⁇ 8-5 ⁇ 8 inch (0.9525-1.588 cm) of the core 32 is removed from the rear edge 24 , creating a recess 34 in the core ( FIG. 2 ).
  • each cast element 10 will preferably have four attachment clips 36 , a pair at the upper edge and a pair at the lower edge.
  • the number and placement of the clips 36 may vary to suit the application.
  • Each clip 36 has a first portion 40 resting on the ledge 38 , extending from the shell 12 and defining at least one eyelet 42 .
  • a second portion 44 is engaged in the core 32 .
  • the engagement takes the form of at least one and even more preferably a plurality of pointed teeth 46 , which are provided in parallel rows 48 , each row having multiple teeth.
  • the teeth 46 are preferably all about the same length and are provided in a length sufficient to securely engage the core 32 .
  • the teeth 46 are approximately 1 inch (2.5 cm) long and are stamped from the second portion 44 and bent into an approximate perpendicular orientation thereto. However, other dimensions, fabrication techniques are contemplated depending on the application.
  • transition portion 50 is provided which axially displaces or offsets the first and second portions, which are also preferably parallel to each other.
  • the transition portion 50 is integral with the first and second portions 40 , 44 , being stamped from a single piece of 14 Gauge galvanized or stainless steel or material with similar strength and corrosion-resistant properties.
  • the present cast architectural element 10 further includes a layer or sheet of mesh 52 disposed upon the core and the second clip portions 44 of each of the clips 36 . It will be seen that the mesh 52 is disposed below the inner corner 28 ( FIG. 1 ). It is preferred that the mesh 52 is 2.5 ounce per square foot (0.763 kg/m 2 )galvanized expanded metal lath or the like. The weight and material of the mesh 52 may vary to suit the application.
  • a main function of the mesh 52 is to provide a matrix for supporting a layer of settable filler 54 , which is disposed upon the mesh in the rear opening 26 .
  • the filler 54 is preferably a settable, workable material that can be troweled upon the layer of mesh 52 , and most preferably is cement-based stucco.
  • the filler 54 is applied in a sufficient amount and consistency to become flush with an exterior surface 56 of the rear walls 20 . It is important for achieving the desired properties of the present cast architectural element 10 that the filler 54 be applied so that peripheral edges 58 engage the angled inner edges 24 of the rear walls 20 ( FIG. 1 ).
  • the filler 54 upon setting, the filler 54 will bond with the shell 12 , will be supported by the mesh 52 , and will encapsulate the clips 36 as well as the core 32 .
  • the set filler 54 will be retained in position in the element 10 by virtue of the angled edges 24 .
  • FIG. 8 the manner of securing the present cast architectural elements 10 to a building exterior, interior or other substrate 60 is shown.
  • Fasteners (not shown) engage the eyelets 42 and the building substrate 60 .
  • a layer of chemical adhesive 62 is placed behind the element 10 to enhance the action of the fastener, and also to facilitate leveling the element against the substrate 60 .
  • a sealant 64 is placed between adjacent elements 10 to prevent water entry and to simulate mortar used in conventional ornamental stone applications.
  • the present cast architectural building element provides a lightweight replacement for conventional ornamental stone blocks.
  • it is relatively easy to positively attach to a building surface using conventional fasteners as well as chemical adhesive.
  • the clip is secured within, and becomes an integral part of the element.

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Finishing Walls (AREA)
  • Roof Covering Using Slabs Or Stiff Sheets (AREA)

Abstract

A clip is provided for use in securing a cast architectural element to a substrate, wherein the element has a stone shell having front, end, side and rear walls defining an internal cavity, the rear walls defining a rear opening, a core disposed in the internal cavity, a layer of mesh disposed upon the core, and a settable filler layer disposed upon the mesh in the rear opening, such that upon setting, the filler retains the clip in position. The clip includes a first clip portion with an eyelet, a second clip portion with at least one core engaging tooth, and a transition portion between the first and second clip portions which axially displaces the first and second portions, which are parallel to each other.

Description

    RELATED APPLICATION
  • This is a divisional of application Ser. No. 12/113,605, filed May 1, 2008, and Applicants claim priority under 35 USC §120 from the above-identified parent application.
  • BACKGROUND OF THE INVENTION
  • The present invention generally relates to cast architectural elements, and more specifically to such elements used as simulated stone blocks for replacing more expensive and heavy solid ornamental stone on building exteriors and interiors.
  • For reasons of esthetics, lower maintenance and/or fire retardant properties, stone exteriors are preferred. However, due to the relatively high cost of the stone, particularly blocks of granite, marble or even limestone, as well as the technical challenge of handling and securing stone blocks to building substrates, there has been a demand for architectural elements made of simulated or artificial stone. Also, with the current interest in preserving resources, the use of solid stone blocks requires significantly more fuel for transportation due to vehicle weight restrictions. In many cases, cast architectural elements have a facing of relatively expensive pure or composite stone, with backings of less expensive, and typically relatively lighter weight materials.
  • One such product is a foam core architectural element that is coated to resemble stone and is sold under the trademark ELEGANT STONE™ by L&W Supply of Chicago, Illinois (www.lwsupply.com). As is well known in the art, such products include an exterior surface of ornamental stone, such as limestone, marble, quartz, silica or the like in a cement matrix with aggregate in a castable formulation. Using a known foam casting technique, the element is produced so that the exterior shell is fused to an interior core of expanded polystyrene foam (EPS). The interior core is thus significantly lighter and easier to handle and install than conventional solid stone blocks. Also, this type of architectural element costs a fraction of solid stone.
  • Conventional cast architectural elements are secured to building exterior or interior substrates using adhesive and/or clamps which are fastened to the building substrate and grip the cast element in a peripheral groove. However, a drawback of such clips is that the installer needs to assemble them on site, and each clip requires multiple components which must be inventoried on site, and are easily misplaced during construction.
  • BRIEF SUMMARY OF THE INVENTION
  • The above-identified drawbacks of conventional cast architectural elements are met or exceeded by the present embedded clip attachment for a cast architectural element, which features the ability to install such elements on building exterior or interior substrates with fasteners as well as adhesive. With the present attachment, an attachment clip is embedded in the interior of the block, and is virtually impossible to pull out without destroying the block. In addition, the present attachment fully encases the foam core in stone or cement or settable matrix. A single integral clip has a portion for accommodating a fastener for securing the block to the building exterior or interior, and a second portion for engaging the foam core.
  • More specifically, a cast architectural element is provided, including a stone shell having front, end, side and rear walls defining an internal cavity, the rear walls defining a rear opening. A core is disposed in the internal cavity, and at least one attachment clip is provided having a first portion extending from the shell, and a second portion engaged in the core. A layer of mesh is disposed upon the core and the second clip portion, and a settable filler layer is disposed upon the mesh in the rear opening, such that upon setting, the filler retains the clip in position.
  • In another embodiment, a method of forming a cast architectural element is provided and includes the steps of providing a pre-cast element having a front, end, side and rear walls defining an internal cavity, the rear walls defining a rear opening, and forming edges of the rear walls to angle inwardly; providing a foam core disposed in the internal cavity; providing at least one attachment clip having a first portion extending from the shell, and a second portion with at least one tooth configured for insertion into the core, and placing the clips on said element so that the second portion engages the core; placing a layer of mesh upon the core and the second clip portion, so that edges of the mesh are beneath an inner corner of each edge; and applying a settable filler layer upon the mesh in the rear opening, such that upon setting, the filler retains the clip in position.
  • In yet another embodiment, a clip for use in securing a cast architectural element to a substrate is provided, wherein the element has a stone shell having front, end, side and rear walls defining an internal cavity, the rear walls defining a rear opening, a core is disposed in the internal cavity, a layer of mesh is disposed upon the core, and a settable filler layer is disposed upon the mesh in the rear opening, such that upon setting, the filler retains the clip in position. The clip includes a first clip portion with an eyelet, a second clip portion with at least one core engaging tooth, a transition portion between the first and second clip portions which axially displaces the first and second portions, which are parallel to each other.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a fragmentary top perspective view of the present block with embedded clip;
  • FIG. 2 is an exploded perspective view of the block of FIG. 1;
  • FIG. 3 is a partially exploded view of the block of FIG. 2;
  • FIG. 4 is a top perspective view of the present block partially assembled;
  • FIG. 5 is a top perspective view of the final assembly of the present block;
  • FIG. 6 is a top perspective of the block of FIG. 6 fully assembled;
  • FIG. 7 is a bottom perspective of a clip suitable for use with the present block; and
  • FIG. 8 is a fragmentary elevation of a wall having a plurality of the present blocks attached thereto.
  • DETAILED DESCRIPTION OF THE INVENTION
  • Referring now to FIGS. 1-4, a cast architectural element is generally designated 10 and is shown as an ornamental facade construction block; however other types of cast architectural elements are contemplated, including but not limited to trim pieces, moldings, baseboard moldings, mantles, wainscoting, window sills, window jams, columns, column bases, column caps, cornices, headboards, and the like. Included on the element 10 is a stone shell 12 having a front wall 14, a pair of side walls 16, a pair of end walls 18, and a pair of rear walls 20 defining an internal cavity 22 (shown hidden). The rear walls 20 each have a corresponding edge 24 spaced from each other to define a rear opening 26. It will be seen in FIG. 1 that the edges 24 are angled inwardly so that an inner corner 28 of each edge is closer to an adjacent one of the side walls 16 than an outer corner 30.
  • A core 32 is disposed in the internal cavity 22, and as is known in the art, the core is made of expanded polystyrene foam (EPS) which becomes fused to inner surfaces of the stone shell 12 through the casting process. The stone shell 12 is preferably made of a cement matrix with aggregate, as described above, and may be made of marble, quartz, limestone, silica or the like, as well as mixtures of the above. Prior to further assembly, approximately ⅜-⅝ inch (0.9525-1.588 cm) of the core 32 is removed from the rear edge 24, creating a recess 34 in the core (FIG. 2).
  • Referring now to FIGS. 2, 3 and 7, at least one and preferably a pair of attachment clips 36 are placed on a rear ledge 38 formed by the end walls 18. In total, each cast element 10 will preferably have four attachment clips 36, a pair at the upper edge and a pair at the lower edge. However, the number and placement of the clips 36 may vary to suit the application.
  • Each clip 36 has a first portion 40 resting on the ledge 38, extending from the shell 12 and defining at least one eyelet 42. A second portion 44 is engaged in the core 32. In the preferred embodiment, the engagement takes the form of at least one and even more preferably a plurality of pointed teeth 46, which are provided in parallel rows 48, each row having multiple teeth. It will be seen that the teeth 46 are preferably all about the same length and are provided in a length sufficient to securely engage the core 32. In the preferred embodiment, the teeth 46 are approximately 1 inch (2.5 cm) long and are stamped from the second portion 44 and bent into an approximate perpendicular orientation thereto. However, other dimensions, fabrication techniques are contemplated depending on the application.
  • Between the first and second portions 38, 42 a transition portion 50 is provided which axially displaces or offsets the first and second portions, which are also preferably parallel to each other. In the clip 36, which is preferably an integral unit, the transition portion 50 is integral with the first and second portions 40, 44, being stamped from a single piece of 14 Gauge galvanized or stainless steel or material with similar strength and corrosion-resistant properties.
  • The present cast architectural element 10 further includes a layer or sheet of mesh 52 disposed upon the core and the second clip portions 44 of each of the clips 36. It will be seen that the mesh 52 is disposed below the inner corner 28 (FIG. 1). It is preferred that the mesh 52 is 2.5 ounce per square foot (0.763 kg/m2)galvanized expanded metal lath or the like. The weight and material of the mesh 52 may vary to suit the application. A main function of the mesh 52 is to provide a matrix for supporting a layer of settable filler 54, which is disposed upon the mesh in the rear opening 26.
  • Referring now to FIGS. 1, 5 and 6, the filler 54 is preferably a settable, workable material that can be troweled upon the layer of mesh 52, and most preferably is cement-based stucco. The filler 54 is applied in a sufficient amount and consistency to become flush with an exterior surface 56 of the rear walls 20. It is important for achieving the desired properties of the present cast architectural element 10 that the filler 54 be applied so that peripheral edges 58 engage the angled inner edges 24 of the rear walls 20 (FIG. 1). Thus, upon setting, the filler 54 will bond with the shell 12, will be supported by the mesh 52, and will encapsulate the clips 36 as well as the core 32. Also, the set filler 54 will be retained in position in the element 10 by virtue of the angled edges 24.
  • Referring now to FIG. 8, the manner of securing the present cast architectural elements 10 to a building exterior, interior or other substrate 60 is shown. Fasteners (not shown) engage the eyelets 42 and the building substrate 60. In addition, a layer of chemical adhesive 62 is placed behind the element 10 to enhance the action of the fastener, and also to facilitate leveling the element against the substrate 60. Next, a sealant 64 is placed between adjacent elements 10 to prevent water entry and to simulate mortar used in conventional ornamental stone applications.
  • Thus, it will be seen that the present cast architectural building element provides a lightweight replacement for conventional ornamental stone blocks. In addition, it is relatively easy to positively attach to a building surface using conventional fasteners as well as chemical adhesive. By employing the present system for embedding the attachment clips, the clip is secured within, and becomes an integral part of the element.
  • While a particular embodiment of the embedded clip attachment for a cast architectural element has been described herein, it will be appreciated by those skilled in the art that changes and modifications may be made thereto without departing from the invention in its broader aspects and as set forth in the following claims.

Claims (4)

1. A clip for use in securing a cast architectural element to a substrate, wherein the element has a stone shell having front, end, side and rear walls defining an internal cavity, the rear walls defining a rear opening, a core disposed in the internal cavity, a layer of mesh disposed upon the core, and a settable filler layer disposed upon the mesh in the rear opening, such that upon setting, the filler retains said clip in position, said clip comprising:
a first clip portion with an eyelet;
a second clip portion with at least one core engaging tooth;
a transition portion between said first and second clip portions which axially displaces said first and second portions, which are parallel to each other.
2. The clip of claim 1 further including a plurality of said at least one tooth in a pair of transverse, parallel rows, individual teeth in said rows being laterally spaced from each other.
3. The clip of claim 2 wherein each said tooth is pointed.
4. The clip of claim 1 wherein said first, second and transition portions are integral with each other.
US12/956,610 2008-05-01 2010-11-30 Embedded clip attachment for cast architectural element Abandoned US20110067342A1 (en)

Priority Applications (1)

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US12/113,605 US8033069B2 (en) 2008-05-01 2008-05-01 Embedded clip attachment for cast architectural element
US12/956,610 US20110067342A1 (en) 2008-05-01 2010-11-30 Embedded clip attachment for cast architectural element

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CA (1) CA2719709A1 (en)
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CA2719709A1 (en) 2009-11-05
US20090272057A1 (en) 2009-11-05
WO2009134954A2 (en) 2009-11-05
MX2010011892A (en) 2010-11-30
US8033069B2 (en) 2011-10-11
WO2009134954A3 (en) 2010-02-18

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