US20090255672A1 - Apparatus and method for obtaining formation samples - Google Patents
Apparatus and method for obtaining formation samples Download PDFInfo
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- US20090255672A1 US20090255672A1 US12/103,486 US10348608A US2009255672A1 US 20090255672 A1 US20090255672 A1 US 20090255672A1 US 10348608 A US10348608 A US 10348608A US 2009255672 A1 US2009255672 A1 US 2009255672A1
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- fluid
- internal cavity
- downhole
- pressure
- opening
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B49/00—Testing the nature of borehole walls; Formation testing; Methods or apparatus for obtaining samples of soil or well fluids, specially adapted to earth drilling or wells
- E21B49/08—Obtaining fluid samples or testing fluids, in boreholes or wells
- E21B49/081—Obtaining fluid samples or testing fluids, in boreholes or wells with down-hole means for trapping a fluid sample
- E21B49/0815—Sampling valve actuated by tubing pressure changes
Definitions
- the present disclosure generally relates to apparatuses and methods for evaluating formations traversed by a well borehole and in particular to formation sampling and testing.
- Formation sampling and testing tools have been used in the oil and gas industry for collecting formation samples, for monitoring formation parameters such as pressure along a well borehole, and for predicting performance of reservoirs around the borehole.
- Such formation sampling and testing tools typically include an elastomer packer or pad that is pressed against a borehole wall portion to form an isolated zone from which formation samples are collected. Information that helps in determining the viability of the formation for producing hydrocarbons and in determining drilling operation parameters may then be acquired by evaluating the formation samples.
- Information about the subterranean formations traversed by the borehole may be obtained by any number of techniques.
- Techniques used to obtain formation information include obtaining one or more downhole fluid samples produced from the subterranean formations.
- Downhole fluids as used herein include any one or any combination of drilling fluids, return fluids, connate formation fluids, and formation fluids that may be contaminated by materials and fluids such as mud filtrates, drilling fluids and return fluids.
- Downhole fluid samples are often retrieved from the borehole and tested in a rig-site or remote laboratory to determine properties of the fluid samples, which properties are used to estimate formation properties. Modern fluid sampling also includes various downhole tests to estimate fluid properties while the fluid sample is downhole.
- Some formations produce hazardous fluids, and local governmental regulations may greatly control and restrict the amount of formation fluids that are introduced into the well borehole to reduce the risk of exposing the surface environment and personnel to these hazardous fluids. This is the case even when it is necessary to retrieve connate formation samples from formations that produce hazardous downhole fluids. It is difficult to retrieve connate formation samples from these hazardous fluid producing formations, because borehole fluids and filtrates often contaminate the formation samples.
- One obstacle is that cleanup processes used to remove borehole contaminants from a fluid sample to obtain a connate fluid sample substantially free of borehole contaminants usually results in ejecting large amounts of formation fluid into the borehole. Thus, the hazardous formation fluids are produced into the return fluid posing environmental threats and hazards to personnel at the surface.
- An apparatus for collecting a fluid from a subterranean formation includes a fluid sample container that has an elongated body.
- the elongated body includes an internal cavity, a first end having a first opening for receiving the downhole fluid into the internal cavity, a second end axially displaced from the first end, the second end having a second opening for expelling at least a portion of the downhole fluid from the internal cavity.
- a method for collecting a downhole fluid includes establishing fluid communication with a formation of interest and a fluid sample container having an elongated body, the elongated body including an internal cavity, a first end having a first opening, a second end axially displaced from the first end, the second end having a second opening. The method further includes receiving the downhole fluid into the internal cavity through the first opening and expelling at least a portion of the downhole fluid from the internal cavity through the second opening.
- FIG. 1 schematically illustrates a non-limiting example of a well logging system in a wireline arrangement according to several non-limiting embodiments of the disclosure
- FIG. 2 illustrates a non-limiting example of extendable probes useful in several embodiments of the disclosure
- FIG. 3 illustrates a non-limiting example of a straddle packer arrangement useful in several embodiments of the disclosure
- FIG. 4 illustrates a non-limiting example of a fluid sample container suitable for operation as a flush-through sample container
- FIG. 5 illustrates an exemplary fluid sample container including one or more devices for controlling pressure within the container during transport.
- FIG. 1 schematically illustrates a non-limiting example of a well logging system 100 in a wireline arrangement according to several non-limiting embodiments of the disclosure.
- the exemplary logging system 100 includes a downhole sub 102 shown disposed in a borehole 104 and supported by a wireline cable 106 .
- the exemplary downhole sub 102 may include one or more centralizers 108 , 110 for centralizing the downhole sub 102 in the borehole 104 .
- the cable 106 may be supported by a sheave wheel 112 disposed in a drilling rig 114 .
- the cable 106 may be wound on a drum 116 , shown here mounted on a truck 118 , for lowering or raising the downhole sub 102 in the borehole.
- the cable 106 may comprise a multi-strand cable having electrical conductors for carrying electrical signals and power from the surface to the downhole sub 102 and for transmitting information to and from the downhole sub 102 .
- the downhole sub 102 may send information to and receive information from the surface for processing and/or for executing commands.
- a surface transceiver 120 and a controller 122 may be located on the truck 118 or at any suitable surface location.
- the exemplary downhole sub 102 communicates with the surface controller 122 via the surface transceiver 120 and a downhole transceiver 124 .
- the exemplary wireline FIG. 1 operates as a carrier, but any carrier is considered within the scope of the disclosure.
- carrier as used herein means any device, device component, combination of devices, media and/or member that may be used to convey, house, support or otherwise facilitate the use of another device, device component, combination of devices, media and/or member.
- exemplary non-limiting carriers include drill strings of the coiled tube type, of the jointed pipe type and any combination or portion thereof.
- Other carrier examples include casing pipes, wirelines, wireline sondes, slickline sondes, downhole subs, BHA's, drill string inserts, modules, internal housings and substrate portions thereof.
- the downhole sub 102 includes a downhole evaluation tool 126
- the downhole evaluation tool 126 may include an assembly of several tool segments that are joined end-to-end by threaded sleeves or mutual compression unions 128 .
- An assembly of tool segments suitable for the present disclosure may include an arrangement as shown in FIG. 1 .
- the exemplary arrangement includes the transceiver 124 discussed above, and a downhole controller 130 is shown below the transceiver 124 .
- the downhole controller 130 may further include a processor and memory for processing information and for executing commands used for controlling aspects of the downhole sub 102 .
- a power unit 132 may be coupled below the controller 130 .
- the power unit 132 may include one or more of a hydraulic power unit, an electrical power unit and an electromechanical power unit.
- a formation sampling tool 134 is shown coupled to the downhole evaluation tool 126 below the power unit 132 .
- the exemplary formation sampling tool 134 shown in FIG. 1 includes a formation sampling member 136 and a sample expulsion member 138 .
- the formation sampling member 136 may be extendable as shown in this example or the formation sampling member 136 may be a tool portion having a port for receiving a formation sample.
- the sample expulsion member 138 may be extendable as shown in this example or the sample expulsion member 138 may be a tool portion having a port for expelling a formation sample from the tool.
- the exemplary formation sampling tool 134 may be configured for acquiring and/or extracting a formation core sample, a formation fluid sample, formation images, nuclear information, electromagnetic information, and/or other downhole samples.
- the formation sampling member may include an extendable probe having a sealing pad 200 for isolating a portion of the well borehole.
- the fluid expulsion member 138 may also include an extendable probe having a sealing pad 200 as depicted in FIG. 2 .
- Other exemplary arrangements may use straddle packers 300 as depicted in FIG. 3 for isolating borehole portions for the respective formation sampling member 136 and fluid expulsion member 138 . Combinations of extendable pad seals and straddle packers are also within the scope of the disclosure.
- a fluid pump 140 may be placed in fluid communication with the formation sampling member 136 included with the formation sampling tool 134 for collecting fluid samples.
- the fluid pump 140 may be a single pump or may include one pump for line purging and a smaller displacement pump for collecting samples and for quantitatively monitoring fluid received by the downhole evaluation tool via the formation sampling tool 134 .
- the fluid pump 140 may be a variable rate pump or a constant rate pump.
- One or more flush-through fluid sample containers 142 may be included below the fluid pump 140 and above the sample expulsion member 138 .
- the fluid sample containers 142 are individually or collectively detachable from the downhole evaluation tool formation sampling tool 134 . Further details of several exemplary flush-through fluid sample containers will be provided below with reference to FIGS. 4-5 .
- FIG. 4 illustrates a non-limiting example of a fluid sample container 400 suitable for operation as a flush-through sample container according to one or more embodiments described above and shown in FIG. 1 at reference numeral 142 .
- the exemplary fluid sample container 400 may be used in a wireline arrangement, in a while-drilling drilling arrangement, a slickline arrangement or by using any suitable carrier for conveying the fluid sample container 400 in a well borehole.
- the exemplary embodiment of FIG. 4 is shown detachably mounted in a downhole sub 102 .
- the exemplary fluid sample container 400 shown in FIG. 4 includes an elongated body 402 having an internal cavity 404 for receiving fluid samples 406 .
- the elongated body 402 portion of the exemplary fluid sample container 400 includes a first end 408 and a second end 410 axially displaced from the first end.
- the elongated body 402 has a first opening 412 in the first end for receiving the fluid 406 into the internal cavity 404 , and a second opening 414 in the second end 410 for expelling at least a portion of the fluid 406 from the internal cavity 404 .
- the fluid sample container 400 of this non-limiting embodiment includes a fluid flow control device 416 proximate the second end 410 of the body 402 and coupled to the downhole sub for controlling fluid expulsion from the internal cavity 404 .
- the fluid flow control device 416 shown may be a controlled valve or any suitable fluid flow control device that is controllable to control fluid expulsion from the second opening 414 during fluid sampling and may be operable to cease fluid expulsion when a predetermined parameter is met for the downhole fluid expelled from the fluid container 400 .
- Additional fluid control devices 416 are shown in the exemplary embodiment of FIG. 4 coupled to the downhole sub input flow line 420 and within the container 400 proximate the body first end 408 to control fluid flow to and within the first end.
- the first end fluid control devices may be substantially similar to the fluid control devices 416 proximate the second end 410 , but the fluid control devices 416 may be of different types without departing from the scope of the disclosure.
- the exemplary embodiment shown in FIG. 4 includes a flow line connector 418 connected to an input flow line 420 at the body first end 408 for allowing fluid flow into the internal cavity 404 .
- a similar flow line connector 418 and flow control device 416 are shown coupled to an output flow line 422 at the body second end 410 for allowing fluid expulsion from the internal cavity 404 .
- the input flow line 420 and the output flow line 422 in the example shown here are flow line portions of the downhole sub 102 that are in fluid communication with the internal cavity 404 of the formation sample container 400 .
- the fluid sample container 400 may be detachable from the downhole sub 102 using detachable flow line connectors 418 and one or more detachable mounting members 424 that couple the fluid sample container body 402 to the downhole sub 102 .
- the downhole sub 102 may include a pump 140 for conveying fluid through a fluid flow control device 416 , which may be a valve controllable downhole using command signals.
- the fluid flow control device 416 is in communication with the internal cavity 404 .
- the exemplary fluid sample container 400 may further include a check valve 426 as shown coupled to the input flow line connector 418 and a similar check valve 426 coupled to the output flow line connector 418 to help ensure fluid flows through the fluid sample container 400 in one direction during a downhole sample cleanup process.
- the non-limiting embodiment of FIG. 4 may further include a fluid evaluation module 428 .
- the fluid evaluation module 428 may be in fluid communication with the output flow line 422 for estimating fluid content of fluid expelled from the internal cavity 404 .
- the fluid evaluation module 428 may be in fluid communication with the input flow line 420 for estimating fluid content of fluid entering the internal cavity 404 .
- a fluid evaluation module 428 may be in fluid communication with both the input flow line 420 and the output flow line 422 for estimating fluid content of fluid entering and exiting the internal cavity 404 .
- the fluid evaluation module may be a single module as shown or may be implemented using two or more modules.
- the fluid evaluation module 428 may include any number of fluid measurement devices for estimating fluid characteristics of the fluid 406 entering or leaving the internal cavity 404 .
- the fluid evaluation module 428 may be arranged to estimate optical characteristics, electrical characteristics, physical characteristics and any combination of characteristics of the fluid 406 .
- some test devices may be in fluid contact with fluid flowing in the fluid evaluation module, some devices may be in optical communication, some devices may be in acoustic communication, some devices may be in physical contact with the fluid, and still others may be in pressure and/or thermal communication with the fluid.
- Optical characteristics may be estimated using a downhole fluorescence test device, a reflectometer, a spectrometer, or any combination thereof.
- Physical characteristics of the fluid may be estimated using a viscometer, a pressure sensor, a temperature sensor, fluid density transducer, or any combination thereof.
- Electrical characteristics of the fluid 406 may be estimated using resistivity measurement devices, capacitance and dielectric constant measurement devices, or combinations thereof. Other devices may be included with the fluid evaluation module 428 for estimating fluid chemical properties and compositional properties.
- Exemplary devices include, but are not limited to, a gas chromatograph, a pH test device, a salinity test device, a CO2 test device, an H2S test device, a device for determining wax and asphaltene components, a device for determining metal content, (mercury or other metal), a device for determining acidity of the fluid, or any combination thereof.
- the internal cavity 404 is defined by a smooth curvilinear surface 430 within the body 402 .
- the surface 430 may be selected based on the desired cavity volume, overall size of the body and on fluid flow characteristics.
- the internal cavity 404 has a substantially oval cross section along a longitudinal axis.
- the internal cavity 404 may be spherical with a substantially circular cross section.
- the internal cavity 404 may have a cylindrical center portion with flat end portions, hemispherical end portions, conical end portions, or any other end portion shape that provides relatively free fluid flow within the internal cavity 404 .
- a surface treatment that reduces fluid adhesion may be used to further reduce sticking and resistance in the fluid flow within the internal cavity 404 .
- Exemplary surface treatments include, but are not limited to, polishing, coatings, laminates, inserts and combinations thereof.
- an exemplary fluid sample container 500 may further include one or more devices for controlling pressure within the container 500 during transport.
- the non-limiting embodiment shown in FIG. 5 is coupled to a downhole sub 102 and includes a substantially cylindrical internal cavity 504 .
- Many of the items in FIG. 5 may be substantially similar to the like-numbered items describe above and shown in FIG. 4 .
- the following description will focus more on the additional features shown in FIG. 5 .
- the exemplary fluid sample container 500 includes an elongated body 502 having an internal cavity 504 for receiving fluid samples 506 .
- the elongated body 502 portion of the exemplary fluid sample container 500 includes a first end 508 and a second end 510 axially displaced from the first end.
- the elongated body 502 has a first opening 512 in the first end 508 for receiving the fluid into the internal cavity 504 from the formation sampling member 136 .
- a second opening 514 in the second end 510 may be used for expelling at least a portion of the fluid 506 from the internal cavity 504 through the fluid expulsion member 138 .
- the fluid sample container 500 of this non-limiting embodiment includes a pressure control device 516 for controlling pressure of the fluid sample 506 .
- the pressure control device 516 provides a flow path via a check valve 522 for fluid 506 flowing through the internal cavity 504 and allows for substantially unrestricted flow during the cleanup process and expulsion of fluid from the internal cavity 504 via the expulsion member 138 .
- the pressure control device 516 in one or more non-limiting embodiments includes a piston 526 that is movably disposed within the cavity 504 .
- One or more O-rings 518 provide a fluid and pressure seal between the piston 526 and cavity wall 530 .
- the check valve 522 is positioned within the piston 526 to provide a flow path through the piston 526 to the opening 514 in the second end 510 .
- the piston 526 is shown positioned toward the second end 510 with the sample 506 shown with an arrow to indicate the direction of flow through the container 500 .
- the check valve 522 prevents flow in the opposite direction. In this manner, the fluid flow through the internal cavity is substantially free flowing during sample cleanup.
- the pressure control device 516 may be actuated using a device controller 520 .
- the device controller 520 may be a pump substantially similar to the pump 140 described above and shown in FIG. 1 .
- the pump 140 may be used as the controller for the pressure control device 516 .
- a gas supply 524 is shown in communication with one end of the piston 526 and with the device controller 520 .
- the gas supply may include a pressurized inert gas such as nitrogen.
- the device controller may be used to add pressure to the gas supply and/or to urge gas toward the piston 526 .
- the piston When pressurized, the piston tends to move toward the first end 508 , thereby decreasing the volume in the cavity 504 and/or increasing the pressure within the cavity 504 when one or more of the inflow and outflow fluid control devices 416 are actuated to cease fluid flow.
- the fluid 506 may be maintained at a predetermined pressure once a fluid sample is collected in the internal cavity 504 .
- the fluid 506 may be maintained above its bubble point pressure for transport to the surface.
- a downhole sub 102 may be conveyed in a well borehole to a formation of interest. A portion of the borehole is isolated using straddle packers, a pad seal disposed on the end of an extendable probe or by using a combination of packers and extendable probe to create an isolated zone. Fluid communication is established between the formation of interest and the downhole sub by exposing a tool port to the isolated zone. In some embodiments, formation pressure may be sufficient to flow fluid from the formation into the tool. In one or more embodiments, a pump 140 or other flow controller may be used to urge fluid into the downhole sub.
- Fluid flow into the downhole sub may be maintained in a substantially continuous manner to perform a cleanup process for removing borehole contaminants from the downhole fluid entering the downhole sub.
- the sample cleanup process may include initially expelling fluid from the downhole sub while the pump or formation pressure urges fluid through the downhole sub.
- the fluid is monitored for content properties during the cleanup process to estimate a cleanliness level of the fluid flowing within the tool.
- fluid expulsion is accomplished by reinjecting the expelled fluid into the formation proximate the downhole sub to limit or prevent the fluid from entering the borehole annulus.
- the fluid is injected into the formation using an extendable expulsion member that is extended to establish fluid communication with the formation. The fluid expulsion may be halted when the fluid within the tool is estimated to be substantially free of contaminants.
- fluid samples may be contained within the tool using an internal fluid sample container 400 , 500 .
- the fluid cleanup process may include urging the fluid received in the tool through a first end of the fluid sample container and expelling the fluid from a second end of the fluid sample container. Once the estimations show that the fluid within the fluid sample container are substantially free of contaminants, the second container end flow path may be closed using a sub-carried valve 416 that is in fluid communication with the output flow line 422 .
- the pump 140 may be used to increase the pressure in the container internal cavity 404 , 504 to a desired pressure. Once the pressure within the internal cavity reaches the desired pressure, then the pump may be halted and a second sub-carried valve 416 that is in fluid communication with the input flow line 420 may be actuated to close the flow path into the internal cavity 404 , 504 . In this manner, the fluid sample 406 , 506 is sealed within a volume defined between the two sub-carried valves 416 .
- Pressure within the internal cavity may be controlled after sample collection and during transport using a pressure control device. Fluid may flow through the pressure control device during the cleanup process and a check valve may be used to allow fluid flow in only one direction through the pressure control device. An inert gas may be used to move a piston within the internal cavity to control pressure.
- the fluid sample container 400 , 500 may be transported to a surface location and removed from the downhole sub without losing fluid containment within the internal cavity 404 , 504 .
- Surface operations may include actuating the first end and second end fluid control devices 416 within the container body 402 , 502 to seal the respective first end and second end portions of the internal cavity 404 , 504 .
- the fluid sample container 400 , 500 may then be disconnected from the downhole sub 102 by disconnecting the detachable couplings 424 and the flow line connectors 418 .
- the sample container internal cavity 404 , 504 may be flushed of contaminants and/or connate fluids without leaving substantial residue within the internal cavity.
- the pump 140 may generate a fluid flow through the cavity.
- the cavity 404 , 504 includes a curvilinear wall 430 , 530 that reduces fluid sticking within the cavity.
- the wall 430 , 530 may further include a surface treatment that further reduces fluid resistance and may be used to reduce sample sticking along the wall 430 , 530 .
- Fluid initially urged into the downhole sub 102 may include one or more contaminants such as borehole fluid and filtrates.
- Undesirable fluid sample components such as the above-noted contaminants may be cleaned from the fluid entering the downhole evaluation tool 126 by pumping the fluid into the tool and then expelling the fluid through the sample expulsion member 138 until the fluid entering the tool is substantially free of the undesirable contaminants.
- pumping and expulsion is performed for a period of time without separate content monitoring with the period of time selected to establish substantially contaminant-free connate fluid flow in the tool.
- the fluid sample expulsion may be halted on or after completion of the time-based pumping.
- fluid flowing in the tool is monitored using a downhole tester to estimate fluid content in substantially real-time.
- the fluid sample expulsion may be halted on or after the content estimate establishes that the fluid flowing in the tool is substantially contaminant-free connate fluid.
- One or more operational embodiments address fluid expulsion where environmental regulations, safety concerns or other factors make it desirable to reduce or avoid introducing produced formation fluid to the well borehole.
- Fluid communication may be established between the sample expulsion member 138 and the formation proximate the sample expulsion member.
- fluid expelled from the tool may be directly injected into the formation with leakage into the well borehole being reduced to levels in compliance with the applicable regulations or to levels that mitigate the safety hazards or that otherwise meet the selected leakage standards set for the particular sampling operation.
- Formation fluid samples that are substantially free of contaminants may be brought to the surface for testing on-site or in a laboratory environment using the flush through sample container 142 .
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Abstract
An apparatus and method for collecting a fluid from a subterranean formation are disclosed. A fluid sample container has an elongated body. The elongated body includes an internal cavity, a first end having a first opening for receiving the downhole fluid into the internal cavity, a second end axially displaced from the first end, the second end having a second opening for expelling at least a portion of the downhole fluid from the internal cavity. Fluid collecting includes establishing fluid communication with a formation of interest and the fluid sample container receiving the downhole fluid into the internal cavity through the first opening and expelling at least a portion of the downhole fluid from the internal cavity through the second opening.
Description
- 1. Technical Field
- The present disclosure generally relates to apparatuses and methods for evaluating formations traversed by a well borehole and in particular to formation sampling and testing.
- 2. Background Information
- Formation sampling and testing tools have been used in the oil and gas industry for collecting formation samples, for monitoring formation parameters such as pressure along a well borehole, and for predicting performance of reservoirs around the borehole. Such formation sampling and testing tools typically include an elastomer packer or pad that is pressed against a borehole wall portion to form an isolated zone from which formation samples are collected. Information that helps in determining the viability of the formation for producing hydrocarbons and in determining drilling operation parameters may then be acquired by evaluating the formation samples.
- Information about the subterranean formations traversed by the borehole may be obtained by any number of techniques. Techniques used to obtain formation information include obtaining one or more downhole fluid samples produced from the subterranean formations. Downhole fluids, as used herein include any one or any combination of drilling fluids, return fluids, connate formation fluids, and formation fluids that may be contaminated by materials and fluids such as mud filtrates, drilling fluids and return fluids. Downhole fluid samples are often retrieved from the borehole and tested in a rig-site or remote laboratory to determine properties of the fluid samples, which properties are used to estimate formation properties. Modern fluid sampling also includes various downhole tests to estimate fluid properties while the fluid sample is downhole.
- Some formations produce hazardous fluids, and local governmental regulations may greatly control and restrict the amount of formation fluids that are introduced into the well borehole to reduce the risk of exposing the surface environment and personnel to these hazardous fluids. This is the case even when it is necessary to retrieve connate formation samples from formations that produce hazardous downhole fluids. It is difficult to retrieve connate formation samples from these hazardous fluid producing formations, because borehole fluids and filtrates often contaminate the formation samples. One obstacle is that cleanup processes used to remove borehole contaminants from a fluid sample to obtain a connate fluid sample substantially free of borehole contaminants usually results in ejecting large amounts of formation fluid into the borehole. Thus, the hazardous formation fluids are produced into the return fluid posing environmental threats and hazards to personnel at the surface.
- The following presents a general summary of several aspects of the disclosure in order to provide a basic understanding of at least some aspects of the disclosure. This summary is not an extensive overview of the disclosure. It is not intended to identify key or critical elements of the disclosure or to delineate the scope of the claims. The following summary merely presents some concepts of the disclosure in a general form as a prelude to the more detailed description that follows.
- An apparatus for collecting a fluid from a subterranean formation is disclosed that includes a fluid sample container that has an elongated body. The elongated body includes an internal cavity, a first end having a first opening for receiving the downhole fluid into the internal cavity, a second end axially displaced from the first end, the second end having a second opening for expelling at least a portion of the downhole fluid from the internal cavity.
- A method for collecting a downhole fluid includes establishing fluid communication with a formation of interest and a fluid sample container having an elongated body, the elongated body including an internal cavity, a first end having a first opening, a second end axially displaced from the first end, the second end having a second opening. The method further includes receiving the downhole fluid into the internal cavity through the first opening and expelling at least a portion of the downhole fluid from the internal cavity through the second opening.
- For detailed understanding of the present disclosure, references should be made to the following detailed description of the several embodiments, taken in conjunction with the accompanying drawings, in which like elements have been given like numerals and wherein:
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FIG. 1 schematically illustrates a non-limiting example of a well logging system in a wireline arrangement according to several non-limiting embodiments of the disclosure; -
FIG. 2 illustrates a non-limiting example of extendable probes useful in several embodiments of the disclosure; -
FIG. 3 illustrates a non-limiting example of a straddle packer arrangement useful in several embodiments of the disclosure; -
FIG. 4 illustrates a non-limiting example of a fluid sample container suitable for operation as a flush-through sample container; and -
FIG. 5 illustrates an exemplary fluid sample container including one or more devices for controlling pressure within the container during transport. -
FIG. 1 schematically illustrates a non-limiting example of a welllogging system 100 in a wireline arrangement according to several non-limiting embodiments of the disclosure. Theexemplary logging system 100 includes adownhole sub 102 shown disposed in aborehole 104 and supported by awireline cable 106. Theexemplary downhole sub 102 may include one or 108, 110 for centralizing themore centralizers downhole sub 102 in theborehole 104. Thecable 106 may be supported by asheave wheel 112 disposed in adrilling rig 114. Thecable 106 may be wound on adrum 116, shown here mounted on atruck 118, for lowering or raising thedownhole sub 102 in the borehole. Thecable 106 may comprise a multi-strand cable having electrical conductors for carrying electrical signals and power from the surface to thedownhole sub 102 and for transmitting information to and from thedownhole sub 102. Thedownhole sub 102 may send information to and receive information from the surface for processing and/or for executing commands. Asurface transceiver 120 and acontroller 122 may be located on thetruck 118 or at any suitable surface location. Theexemplary downhole sub 102 communicates with thesurface controller 122 via thesurface transceiver 120 and adownhole transceiver 124. - The exemplary wireline
FIG. 1 operates as a carrier, but any carrier is considered within the scope of the disclosure. The term “carrier” as used herein means any device, device component, combination of devices, media and/or member that may be used to convey, house, support or otherwise facilitate the use of another device, device component, combination of devices, media and/or member. Exemplary non-limiting carriers include drill strings of the coiled tube type, of the jointed pipe type and any combination or portion thereof. Other carrier examples include casing pipes, wirelines, wireline sondes, slickline sondes, downhole subs, BHA's, drill string inserts, modules, internal housings and substrate portions thereof. - In the non-limiting embodiment of
FIG. 1 , thedownhole sub 102 includes adownhole evaluation tool 126, and thedownhole evaluation tool 126 may include an assembly of several tool segments that are joined end-to-end by threaded sleeves ormutual compression unions 128. An assembly of tool segments suitable for the present disclosure may include an arrangement as shown inFIG. 1 . The exemplary arrangement includes thetransceiver 124 discussed above, and adownhole controller 130 is shown below thetransceiver 124. Thedownhole controller 130 may further include a processor and memory for processing information and for executing commands used for controlling aspects of thedownhole sub 102. Apower unit 132 may be coupled below thecontroller 130. Thepower unit 132 may include one or more of a hydraulic power unit, an electrical power unit and an electromechanical power unit. Aformation sampling tool 134 is shown coupled to thedownhole evaluation tool 126 below thepower unit 132. - The exemplary
formation sampling tool 134 shown inFIG. 1 includes aformation sampling member 136 and asample expulsion member 138. Theformation sampling member 136 may be extendable as shown in this example or theformation sampling member 136 may be a tool portion having a port for receiving a formation sample. Likewise, thesample expulsion member 138 may be extendable as shown in this example or thesample expulsion member 138 may be a tool portion having a port for expelling a formation sample from the tool. The exemplaryformation sampling tool 134 may be configured for acquiring and/or extracting a formation core sample, a formation fluid sample, formation images, nuclear information, electromagnetic information, and/or other downhole samples. - Referring to
FIGS. 1 , 2 and 3, several non-limiting embodiments may be configured with theformation sampling tool 134 operable as a fluid sampling tool. In these embodiments, the formation sampling member may include an extendable probe having asealing pad 200 for isolating a portion of the well borehole. Thefluid expulsion member 138 may also include an extendable probe having asealing pad 200 as depicted inFIG. 2 . Other exemplary arrangements may usestraddle packers 300 as depicted inFIG. 3 for isolating borehole portions for the respectiveformation sampling member 136 andfluid expulsion member 138. Combinations of extendable pad seals and straddle packers are also within the scope of the disclosure. Afluid pump 140 may be placed in fluid communication with theformation sampling member 136 included with theformation sampling tool 134 for collecting fluid samples. Thefluid pump 140 may be a single pump or may include one pump for line purging and a smaller displacement pump for collecting samples and for quantitatively monitoring fluid received by the downhole evaluation tool via theformation sampling tool 134. Thefluid pump 140 may be a variable rate pump or a constant rate pump. - One or more flush-through
fluid sample containers 142 may be included below thefluid pump 140 and above thesample expulsion member 138. In several examples, thefluid sample containers 142 are individually or collectively detachable from the downhole evaluation toolformation sampling tool 134. Further details of several exemplary flush-through fluid sample containers will be provided below with reference toFIGS. 4-5 . -
FIG. 4 illustrates a non-limiting example of afluid sample container 400 suitable for operation as a flush-through sample container according to one or more embodiments described above and shown inFIG. 1 atreference numeral 142. The exemplaryfluid sample container 400 may be used in a wireline arrangement, in a while-drilling drilling arrangement, a slickline arrangement or by using any suitable carrier for conveying thefluid sample container 400 in a well borehole. The exemplary embodiment ofFIG. 4 is shown detachably mounted in adownhole sub 102. - The exemplary
fluid sample container 400 shown inFIG. 4 includes anelongated body 402 having aninternal cavity 404 for receivingfluid samples 406. Theelongated body 402 portion of the exemplaryfluid sample container 400 includes afirst end 408 and asecond end 410 axially displaced from the first end. Theelongated body 402 has afirst opening 412 in the first end for receiving the fluid 406 into theinternal cavity 404, and asecond opening 414 in thesecond end 410 for expelling at least a portion of the fluid 406 from theinternal cavity 404. Thefluid sample container 400 of this non-limiting embodiment includes a fluidflow control device 416 proximate thesecond end 410 of thebody 402 and coupled to the downhole sub for controlling fluid expulsion from theinternal cavity 404. The fluidflow control device 416 shown may be a controlled valve or any suitable fluid flow control device that is controllable to control fluid expulsion from thesecond opening 414 during fluid sampling and may be operable to cease fluid expulsion when a predetermined parameter is met for the downhole fluid expelled from thefluid container 400. - Additional
fluid control devices 416 are shown in the exemplary embodiment ofFIG. 4 coupled to the downhole subinput flow line 420 and within thecontainer 400 proximate the bodyfirst end 408 to control fluid flow to and within the first end. The first end fluid control devices may be substantially similar to thefluid control devices 416 proximate thesecond end 410, but thefluid control devices 416 may be of different types without departing from the scope of the disclosure. - The exemplary embodiment shown in
FIG. 4 includes aflow line connector 418 connected to aninput flow line 420 at the bodyfirst end 408 for allowing fluid flow into theinternal cavity 404. A similarflow line connector 418 and flowcontrol device 416 are shown coupled to anoutput flow line 422 at the bodysecond end 410 for allowing fluid expulsion from theinternal cavity 404. Theinput flow line 420 and theoutput flow line 422 in the example shown here are flow line portions of thedownhole sub 102 that are in fluid communication with theinternal cavity 404 of theformation sample container 400. - The
fluid sample container 400 may be detachable from thedownhole sub 102 using detachableflow line connectors 418 and one or more detachable mountingmembers 424 that couple the fluidsample container body 402 to thedownhole sub 102. Thedownhole sub 102 may include apump 140 for conveying fluid through a fluidflow control device 416, which may be a valve controllable downhole using command signals. The fluidflow control device 416 is in communication with theinternal cavity 404. - The exemplary
fluid sample container 400 may further include acheck valve 426 as shown coupled to the inputflow line connector 418 and asimilar check valve 426 coupled to the outputflow line connector 418 to help ensure fluid flows through thefluid sample container 400 in one direction during a downhole sample cleanup process. - The non-limiting embodiment of
FIG. 4 may further include afluid evaluation module 428. In one or more embodiments, thefluid evaluation module 428 may be in fluid communication with theoutput flow line 422 for estimating fluid content of fluid expelled from theinternal cavity 404. In one or more embodiments, thefluid evaluation module 428 may be in fluid communication with theinput flow line 420 for estimating fluid content of fluid entering theinternal cavity 404. In one or more embodiments, afluid evaluation module 428 may be in fluid communication with both theinput flow line 420 and theoutput flow line 422 for estimating fluid content of fluid entering and exiting theinternal cavity 404. The fluid evaluation module may be a single module as shown or may be implemented using two or more modules. - The
fluid evaluation module 428 may include any number of fluid measurement devices for estimating fluid characteristics of the fluid 406 entering or leaving theinternal cavity 404. Thefluid evaluation module 428 may be arranged to estimate optical characteristics, electrical characteristics, physical characteristics and any combination of characteristics of thefluid 406. For example, some test devices may be in fluid contact with fluid flowing in the fluid evaluation module, some devices may be in optical communication, some devices may be in acoustic communication, some devices may be in physical contact with the fluid, and still others may be in pressure and/or thermal communication with the fluid. - Optical characteristics may be estimated using a downhole fluorescence test device, a reflectometer, a spectrometer, or any combination thereof. Physical characteristics of the fluid may be estimated using a viscometer, a pressure sensor, a temperature sensor, fluid density transducer, or any combination thereof. Electrical characteristics of the fluid 406 may be estimated using resistivity measurement devices, capacitance and dielectric constant measurement devices, or combinations thereof. Other devices may be included with the
fluid evaluation module 428 for estimating fluid chemical properties and compositional properties. Exemplary devices include, but are not limited to, a gas chromatograph, a pH test device, a salinity test device, a CO2 test device, an H2S test device, a device for determining wax and asphaltene components, a device for determining metal content, (mercury or other metal), a device for determining acidity of the fluid, or any combination thereof. - In one or more embodiments, the
internal cavity 404 is defined by a smoothcurvilinear surface 430 within thebody 402. Thesurface 430 may be selected based on the desired cavity volume, overall size of the body and on fluid flow characteristics. In the exemplary embodiment ofFIG. 4 , theinternal cavity 404 has a substantially oval cross section along a longitudinal axis. In one or more embodiments, theinternal cavity 404 may be spherical with a substantially circular cross section. In one or more embodiments, theinternal cavity 404 may have a cylindrical center portion with flat end portions, hemispherical end portions, conical end portions, or any other end portion shape that provides relatively free fluid flow within theinternal cavity 404. A surface treatment that reduces fluid adhesion may be used to further reduce sticking and resistance in the fluid flow within theinternal cavity 404. Exemplary surface treatments include, but are not limited to, polishing, coatings, laminates, inserts and combinations thereof. - Turning now to
FIG. 5 , an exemplaryfluid sample container 500 may further include one or more devices for controlling pressure within thecontainer 500 during transport. The non-limiting embodiment shown inFIG. 5 is coupled to adownhole sub 102 and includes a substantially cylindricalinternal cavity 504. Many of the items inFIG. 5 may be substantially similar to the like-numbered items describe above and shown inFIG. 4 . For brevity, the following description will focus more on the additional features shown inFIG. 5 . - The exemplary
fluid sample container 500 includes anelongated body 502 having aninternal cavity 504 for receivingfluid samples 506. Theelongated body 502 portion of the exemplaryfluid sample container 500 includes afirst end 508 and asecond end 510 axially displaced from the first end. Theelongated body 502 has afirst opening 512 in thefirst end 508 for receiving the fluid into theinternal cavity 504 from theformation sampling member 136. Asecond opening 514 in thesecond end 510 may be used for expelling at least a portion of the fluid 506 from theinternal cavity 504 through thefluid expulsion member 138. Thefluid sample container 500 of this non-limiting embodiment includes apressure control device 516 for controlling pressure of thefluid sample 506. Thepressure control device 516 provides a flow path via acheck valve 522 forfluid 506 flowing through theinternal cavity 504 and allows for substantially unrestricted flow during the cleanup process and expulsion of fluid from theinternal cavity 504 via theexpulsion member 138. Thepressure control device 516 in one or more non-limiting embodiments includes apiston 526 that is movably disposed within thecavity 504. One or more O-rings 518 provide a fluid and pressure seal between thepiston 526 andcavity wall 530. Thecheck valve 522 is positioned within thepiston 526 to provide a flow path through thepiston 526 to theopening 514 in thesecond end 510. - The
piston 526 is shown positioned toward thesecond end 510 with thesample 506 shown with an arrow to indicate the direction of flow through thecontainer 500. Thecheck valve 522 prevents flow in the opposite direction. In this manner, the fluid flow through the internal cavity is substantially free flowing during sample cleanup. - The
pressure control device 516 may be actuated using adevice controller 520. In one or more embodiments, thedevice controller 520 may be a pump substantially similar to thepump 140 described above and shown inFIG. 1 . In one or more embodiments, thepump 140 may be used as the controller for thepressure control device 516. Agas supply 524 is shown in communication with one end of thepiston 526 and with thedevice controller 520. In one or more embodiments, the gas supply may include a pressurized inert gas such as nitrogen. When actuated, the device controller may be used to add pressure to the gas supply and/or to urge gas toward thepiston 526. When pressurized, the piston tends to move toward thefirst end 508, thereby decreasing the volume in thecavity 504 and/or increasing the pressure within thecavity 504 when one or more of the inflow and outflowfluid control devices 416 are actuated to cease fluid flow. In this manner, the fluid 506 may be maintained at a predetermined pressure once a fluid sample is collected in theinternal cavity 504. For example, the fluid 506 may be maintained above its bubble point pressure for transport to the surface. - Several non-limiting operational embodiments for formation sampling will now be described with reference to
FIGS. 1 through 5 . In one or more embodiments adownhole sub 102 may be conveyed in a well borehole to a formation of interest. A portion of the borehole is isolated using straddle packers, a pad seal disposed on the end of an extendable probe or by using a combination of packers and extendable probe to create an isolated zone. Fluid communication is established between the formation of interest and the downhole sub by exposing a tool port to the isolated zone. In some embodiments, formation pressure may be sufficient to flow fluid from the formation into the tool. In one or more embodiments, apump 140 or other flow controller may be used to urge fluid into the downhole sub. - Fluid flow into the downhole sub may be maintained in a substantially continuous manner to perform a cleanup process for removing borehole contaminants from the downhole fluid entering the downhole sub. The sample cleanup process may include initially expelling fluid from the downhole sub while the pump or formation pressure urges fluid through the downhole sub. In one or more embodiments, the fluid is monitored for content properties during the cleanup process to estimate a cleanliness level of the fluid flowing within the tool. In one or more embodiments, fluid expulsion is accomplished by reinjecting the expelled fluid into the formation proximate the downhole sub to limit or prevent the fluid from entering the borehole annulus. In one or more embodiments, the fluid is injected into the formation using an extendable expulsion member that is extended to establish fluid communication with the formation. The fluid expulsion may be halted when the fluid within the tool is estimated to be substantially free of contaminants.
- In one or more embodiments, fluid samples may be contained within the tool using an internal
400, 500. In one or more embodiments, the fluid cleanup process may include urging the fluid received in the tool through a first end of the fluid sample container and expelling the fluid from a second end of the fluid sample container. Once the estimations show that the fluid within the fluid sample container are substantially free of contaminants, the second container end flow path may be closed using afluid sample container sub-carried valve 416 that is in fluid communication with theoutput flow line 422. - The
pump 140 may be used to increase the pressure in the container 404, 504 to a desired pressure. Once the pressure within the internal cavity reaches the desired pressure, then the pump may be halted and a secondinternal cavity sub-carried valve 416 that is in fluid communication with theinput flow line 420 may be actuated to close the flow path into the 404, 504. In this manner, theinternal cavity 406, 506 is sealed within a volume defined between the twofluid sample sub-carried valves 416. - Pressure within the internal cavity may be controlled after sample collection and during transport using a pressure control device. Fluid may flow through the pressure control device during the cleanup process and a check valve may be used to allow fluid flow in only one direction through the pressure control device. An inert gas may be used to move a piston within the internal cavity to control pressure.
- In one or more embodiments, the
400, 500 may be transported to a surface location and removed from the downhole sub without losing fluid containment within thefluid sample container 404, 504. Surface operations may include actuating the first end and second endinternal cavity fluid control devices 416 within the 402, 502 to seal the respective first end and second end portions of thecontainer body 404, 504. Theinternal cavity 400, 500 may then be disconnected from thefluid sample container downhole sub 102 by disconnecting thedetachable couplings 424 and theflow line connectors 418. - The sample container
404, 504 may be flushed of contaminants and/or connate fluids without leaving substantial residue within the internal cavity. Theinternal cavity pump 140 may generate a fluid flow through the cavity. In some embodiments, the 404, 504 includes acavity 430, 530 that reduces fluid sticking within the cavity. Thecurvilinear wall 430, 530 may further include a surface treatment that further reduces fluid resistance and may be used to reduce sample sticking along thewall 430, 530.wall - Fluid initially urged into the
downhole sub 102 may include one or more contaminants such as borehole fluid and filtrates. Undesirable fluid sample components such as the above-noted contaminants may be cleaned from the fluid entering thedownhole evaluation tool 126 by pumping the fluid into the tool and then expelling the fluid through thesample expulsion member 138 until the fluid entering the tool is substantially free of the undesirable contaminants. - In one or more embodiments, pumping and expulsion is performed for a period of time without separate content monitoring with the period of time selected to establish substantially contaminant-free connate fluid flow in the tool. The fluid sample expulsion may be halted on or after completion of the time-based pumping. In one or more embodiments, fluid flowing in the tool is monitored using a downhole tester to estimate fluid content in substantially real-time. The fluid sample expulsion may be halted on or after the content estimate establishes that the fluid flowing in the tool is substantially contaminant-free connate fluid.
- One or more operational embodiments address fluid expulsion where environmental regulations, safety concerns or other factors make it desirable to reduce or avoid introducing produced formation fluid to the well borehole. Fluid communication may be established between the
sample expulsion member 138 and the formation proximate the sample expulsion member. In this manner, fluid expelled from the tool may be directly injected into the formation with leakage into the well borehole being reduced to levels in compliance with the applicable regulations or to levels that mitigate the safety hazards or that otherwise meet the selected leakage standards set for the particular sampling operation. Formation fluid samples that are substantially free of contaminants may be brought to the surface for testing on-site or in a laboratory environment using the flush throughsample container 142. - The present disclosure is to be taken as illustrative rather than as limiting the scope or nature of the claims below. Numerous modifications and variations will become apparent to those skilled in the art after studying the disclosure, including use of equivalent functional and/or structural substitutes for elements described herein, use of equivalent functional couplings for couplings described herein, and/or use of equivalent functional actions for actions described herein. Such insubstantial variations are to be considered within the scope of the claims below.
Claims (26)
1. An apparatus for collecting a downhole fluid, the apparatus comprising:
a fluid sample container having an elongated body, the elongated body including an internal cavity, a first end having a first opening for receiving the downhole fluid into the internal cavity, a second end axially displaced from the first end, the second end having a second opening for expelling at least a portion of the downhole fluid from the internal cavity.
2. An apparatus according to claim 1 , wherein the internal cavity is defined in part by a wall having a curvilinear cross section profile for fluid sticking, fluid resistance or a combination thereof within the internal cavity.
3. An apparatus according to claim 2 , wherein the wall curvilinear cross section profile approximates at least a portion of one or more of a circle and an oval.
4. An apparatus according to claim 1 , wherein the internal cavity is defined in part by a wall having a surface treatment that reduces fluid sticking, fluid resistance or a combination thereof.
5. An apparatus according to claim 4 , wherein the surface treatment is selected from one or more of a coating, a polished surface and an insert.
6. An apparatus according to claim 1 further comprising a flow control device that is controllable to cease downhole fluid expulsion from the second opening when a predetermined parameter is met for the downhole fluid.
7. An apparatus according to claim 1 , further comprising a pressure control device for controlling fluid pressure within the internal cavity.
8. An apparatus according to claim 7 , wherein the pressure control device includes a pump for controlling pressure in the internal cavity.
9. An apparatus according to claim 7 , wherein the pressure control device includes a member disposed within the internal cavity for controlling pressure in the internal cavity.
10. An apparatus according to claim 9 , wherein the member includes a piston that moves in the internal cavity to control pressure in the internal cavity.
11. An apparatus according to claim 9 further comprising a check valve coupled to the pressure control device to allow fluid flow through a central opening of the pressure control device.
12. An apparatus according to claim 1 further comprising a fluid monitoring device for estimating a property of the downhole fluid.
13. An apparatus according to claim 12 , wherein the property of the downhole fluid includes a level of contamination.
14. A method for collecting a downhole fluid, the method comprising:
establishing fluid communication with a formation of interest and a fluid sample container having an elongated body, the elongated body including an internal cavity, a first end having a first opening, a second end axially displaced from the first end, the second end having a second opening;
receiving the downhole fluid into the internal cavity through the first opening; and
expelling at least a portion of the downhole fluid from the internal cavity through the second opening.
15. A method according to claim 14 further comprising reducing fluid perturbations within the internal cavity using a wall having a curvilinear cross section profile defining at least in part the internal cavity.
16. A method according to claim 15 , wherein the wall curvilinear cross section profile approximates at least a portion of one or more of a circle and an oval.
17. A method according to claim 14 , wherein reducing fluid perturbations includes using a wall having a surface treatment that reduces fluid sticking, fluid resistance or a combination thereof.
18. A method according to claim 17 , wherein the surface treatment is selected from one or more of a coating, a polished surface and an insert.
19. A method according to claim 14 further comprising ceasing the downhole fluid expulsion when a predetermined parameter is met for the downhole fluid using a flow control device that is controllable to cease downhole fluid expulsion from the second opening.
20. A method according to claim 14 further comprising controlling fluid pressure within the internal cavity using a pressure control device.
21. A method according to claim 20 , wherein controlling fluid pressure within the internal cavity includes using a pump as part of the pressure control device.
22. A method according to claim 20 , wherein controlling fluid pressure within the internal cavity includes controllably changing a volume within the internal cavity using a member disposed within the internal cavity.
23. A method according to claim 22 , wherein the member includes a piston and controllably changing a volume within the internal cavity includes moving the piston to control pressure within the internal cavity.
24. A method according to claim 22 further comprising, flowing the downhole fluid through a check valve in the member.
25. A method according to claim 14 further comprising estimating a property of the downhole fluid using a monitoring device.
26. A method according to claim 25 , wherein the property of the downhole fluid includes a level of contamination.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/103,486 US20090255672A1 (en) | 2008-04-15 | 2008-04-15 | Apparatus and method for obtaining formation samples |
| PCT/US2009/040377 WO2009129185A2 (en) | 2008-04-15 | 2009-04-13 | Apparatus and method for obtaining formation samples |
| BRPI0910628A BRPI0910628A2 (en) | 2008-04-15 | 2009-04-13 | apparatus and method for obtaining formation samples |
| GB1017960A GB2472530A (en) | 2008-04-15 | 2009-04-13 | Apparatus and method for obtaining formation samples |
| NO20101451A NO20101451A1 (en) | 2008-04-15 | 2010-10-26 | Apparatus and method for obtaining formation samples |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/103,486 US20090255672A1 (en) | 2008-04-15 | 2008-04-15 | Apparatus and method for obtaining formation samples |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20090255672A1 true US20090255672A1 (en) | 2009-10-15 |
Family
ID=41163030
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US12/103,486 Abandoned US20090255672A1 (en) | 2008-04-15 | 2008-04-15 | Apparatus and method for obtaining formation samples |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20090255672A1 (en) |
| BR (1) | BRPI0910628A2 (en) |
| GB (1) | GB2472530A (en) |
| NO (1) | NO20101451A1 (en) |
| WO (1) | WO2009129185A2 (en) |
Cited By (4)
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|---|---|---|---|---|
| CN102345456A (en) * | 2011-07-20 | 2012-02-08 | 铜陵中都矿山建设有限责任公司 | Deep water sampling and detecting device |
| US20120297903A1 (en) * | 2011-05-24 | 2012-11-29 | Halliburton Energy Services, Inc. | Regulation-compliant holding device for storing or transporting a non-compliant container |
| GB2495163A (en) * | 2011-09-30 | 2013-04-03 | Schlumberger Holdings | Compositional analysis of hydrocarbons |
| WO2019237095A2 (en) | 2018-06-09 | 2019-12-12 | Todd Coleman | Apparatus and methods for gas sampling containers |
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| GB2495163B (en) * | 2011-09-30 | 2014-01-15 | Schlumberger Holdings | Real-time compositional analysis of hydrocarbon based fluid samples |
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| WO2019237095A2 (en) | 2018-06-09 | 2019-12-12 | Todd Coleman | Apparatus and methods for gas sampling containers |
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| US11788937B2 (en) | 2018-06-09 | 2023-10-17 | Todd Coleman | Apparatus and methods for gas sampling containers |
Also Published As
| Publication number | Publication date |
|---|---|
| GB201017960D0 (en) | 2010-12-08 |
| NO20101451A1 (en) | 2010-12-29 |
| WO2009129185A3 (en) | 2010-02-18 |
| BRPI0910628A2 (en) | 2015-09-22 |
| GB2472530A (en) | 2011-02-09 |
| WO2009129185A2 (en) | 2009-10-22 |
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| AS | Assignment |
Owner name: BAKER HUGHES INCORPORATED, TEXAS Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SIMPSON, ANGUS J.;SHAMMAI, MICHAEL H.;REEL/FRAME:021216/0604;SIGNING DATES FROM 20080331 TO 20080415 |
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| STCB | Information on status: application discontinuation |
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