US20090191392A1 - Thin film for waste packing cassettes - Google Patents

Thin film for waste packing cassettes Download PDF

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US20090191392A1
US20090191392A1 US12322347 US32234709A US2009191392A1 US 20090191392 A1 US20090191392 A1 US 20090191392A1 US 12322347 US12322347 US 12322347 US 32234709 A US32234709 A US 32234709A US 2009191392 A1 US2009191392 A1 US 2009191392A1
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film
layer
used
multilayer film
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US12322347
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Dimitris Gkinosatis
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Flexopack Sa Plastics Industry
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Flexopack Sa Plastics Industry
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a general shape other than plane
    • B32B1/08Tubular products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/34Layered products comprising a layer of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form ; Layered products having particular features of form
    • B32B3/02Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form ; Layered products having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers, i.e. products comprising layers having different physical properties and products characterised by the interconnection of layers
    • B32B7/02Layered products characterised by the relation between layers, i.e. products comprising layers having different physical properties and products characterised by the interconnection of layers in respect of physical properties, e.g. hardness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers, i.e. products comprising layers having different physical properties and products characterised by the interconnection of layers
    • B32B7/04Layered products characterised by the relation between layers, i.e. products comprising layers having different physical properties and products characterised by the interconnection of layers characterised by the connection of layers
    • B32B7/12Layered products characterised by the relation between layers, i.e. products comprising layers having different physical properties and products characterised by the interconnection of layers characterised by the connection of layers using an adhesive, i.e. any interposed material having adhesive or bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/70Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00Resin or rubber layer containing a blend of at least two different polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54Yield strength; Tensile strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/72Density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • B32B2307/7242Non-permeable
    • B32B2307/7244Oxygen barrier
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • B32B2307/7242Non-permeable
    • B32B2307/7248Odour barrier
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/732Dimensional properties
    • B32B2307/734Dimensional stability
    • B32B2307/736Shrinkable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2553/00Packaging equipment or accessories not otherwise provided for
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2565/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D2565/38Packaging materials of special type or form
    • B65D2565/381Details of packaging materials of special type or form
    • B65D2565/387Materials used as gas barriers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/24992Density or compression of components

Abstract

The present invention refers to a polymeric film comprising odor barrier material and being able to pack malodorous waste. This is achieved by a multilayer film which comprises ethylene alpha olefin copolymer with a density less than 0.950 g/cm3 in at least one layer.

Description

    CROSS REFERENCE TO RELATED APPLICATIONS
  • This application claims the benefit of European patent application No. 08150769.1, filed Jan. 29, 2008, the entire disclosure of which is herein incorporated by reference.
  • FIELD OF THE INVENTION
  • The present invention refers to a polymeric film comprising odor barrier material and being able to pack malodorous waste.
  • BACKGROUND OF THE INVENTION
  • A lot of waste products produce smells that are annoying to the environment. Examples are decayed food, kid nappies and cat litter.
  • In the prior art there are many films that could be used for protection from malodors. As well known in the art, the use of materials like EVOH, PVDC, polyacrylonitrile is recommended in order to not allow malodors escape from the container (eg bag or other configuration) and create an unpleasant atmosphere.
  • There are also a lot of known configurations of packing a certain length of film (eg 20 meters) in a compressed form (eg in a cassette). Examples of the representative cassettes are shown in U.S. Pat. No. 4,934,529 or U.S. Pat. No. 3,356,192.
  • Generally the cassette comprises a tubular core, casing wall and cassette bottom. The film is pulled through the area between the lid of the cassette and the casing wall. The flexible tubing is dispensed from the cassette. After the malodorous item is thrown into the bag the core is rotated and the flexible tube is twisted so that it closes as hermetically as possible the waste/environment area.
  • To dispose the next diaper the user pushes the next portion of film. The previous hermetically closed diaper is pushed downwards and the new diaper is packed in a new configuration. All these different packs are stored in a bin which is periodically emptied.
  • Separation of one pack to the other can be done by various means. A rotary knife is preferred.
  • Film Characteristics
  • In the prior art a lot of possible film configurations either monolayer or multilayer have been proposed. The basic characteristics a film should have in order to be used in the particular case are
      • 1. Barrier to odours
      • 2. To have the proper deadfold properties (non resilient) so that is compressed efficiently in the cassette.
      • 3. To have sufficient mechanical properties (eg tensile strength at break, elongation).
  • We have surprisingly found that all these features can be achieved with a very lightweight multilayer film with grammage less than 19 grs/square meter. This is extremely beneficial for the environment as multilayer films are extremely difficult to be produced with so small weight per surface.
  • SUMMARY OF THE INVENTION
  • The invention is directed to a multilayer film with a weight of less than 19 g/m2 used in malodorous item packaging, where the film comprises ethylene alpha olefin copolymer with a density less than 0.950 g/cm3 in at least one of the outer or inner layers.
  • In a preferred embodiment, the film has the following configuration:
      • 1. More than 3 layers in total.
      • 2. Two layers comprising ethylene alpha olefin copolymer with density less than 0.950.
      • 3. An oxygen barrier layer.
    DEFINITIONS
  • In this application the following definitions are used:
  • The term “film” refers to a flat or tubular flexible structure of thermoplastic material.
  • The term “heat shrinkable” refers to a film that shrinks at least 10% in at least one of the longitudinal and transverse directions when heated at 90° C. for 4 seconds. The shrinkability is measured in water according to ASTM 2732. For temperatures like 100° C. or more, glycerine is used as a reference liquid.
  • The term “total heat shrinkability” refers to the sum of heat shrinkability at the MD direction and heat shrinkability at the TD direction. In all cases, ASTM 2732 is used for measurement of shrinkabilities.
  • The term “multilayer” refers to a film comprising 3 or more layers.
  • The phrase “longitudinal direction” or “machine direction” herein abbreviated “MD” refers to a direction along the length of the film.
  • The phrase “outer layer” refers to the film layer which comes in immediate contact with the outside environment (atmosphere).
  • The phrase “inner layer” refers to the film layer that comes in direct contact with the product packed. This is also called “sealing layer” as this layer must be hermetically sealed in order to protect the product from ingress of air.
  • As used herein, the term “homopolymer” refers to a polymer resulting from polymerization of a single monomer.
  • As used herein, the term “copolymer” refers to a polymer resulting from polymerization of at least two different polymers.
  • As used herein, the term “polymer” includes both above types.
  • As used herein the term “polyethylene” identifies polymers consisting essentially of the ethylene repeating unit. The ones that have a density more than 0.940 are called high density polyethylene (HDPE), the ones that are have less than 0.940 are low density polyethylene (LDPE).
  • As used herein the phrase “ethylene alpha olefin copolymer” refers to polymers like linear low density polyethylene (LLDPE), medium density polyethylene (MDPE), very low density polyethylene (VLDPE), ultra low density polyethylene (ULDPE), metallocene catalysed polymers and polyethylene plastomers and elastomers.
  • As used herein the term “homogeneous ethylene alpha olefin copolymers” refer to ethylene alpha olefin copolymers having a molecular weight distribution less than 2.7 as measured by GPC. Typical examples of these polymers are AFFINITY from DOW or Exact from Exxon.
  • As used herein the phrase “styrene polymers” refers to styrene homopolymer such as polystyrene and to styrene copolymers such as styrene-butadiene copolymers, styrene-butadiene-styrene copolymers, styrene-isoprene-styrene copolymers, styrene-ethylene-butadiene-styrene copolymers, ethylene-styrene copolymers and the like.
  • As used herein the phrase “ethylene methacrylate copolymers” refers to copolymers of ethylene and methacrylate monomer. The monomer content is less than 40%.
  • As used herein the phrase “ethylene vinyl acetate copolymer” or EVA refer to copolymers of ethylene and vinyl acetate.
  • As used herein, the term EVOH refers to saponified products of ethylene vinyl ester copolymers. The ethylene content is typically in the range of 25 to 50%.
  • As used herein the term PVDC refers to a vinylidene chloride copolymer wherein a major amount of the copolymer comprises vinylidene chloride and a minor amount of the copolymer comprises one or more monomers such as vinyl chloride and/or alkyl acrylates and methacrylates.
  • As used herein the term “polyamide” refers to homopolymers and copolymers. Polyamide 6, polyamide 66, polyamide 12, polyamide 6/66, polyamide 6/12, polyamide elastomers, MXD polyamides and other copolymers are specifically useful for the invention.
  • As used herein the term “polyester” refers to polymers comprising terephthalate units. Examples of polyesters are PET (polyethylene terephthalate), PBT(polybutylene terephthalate), polyester elastomer (block copolymer comprising ester or ether units), PTT and other similar polymers.
  • As used herein, the term “ionomer” comprises the copolymers of ethylene and methacrylic or acrylic acid being metal neutralized. An example of such material is Surlyn from Dupont.
  • As used herein the term “substantially non resilient material” refers to materials or material compounds comprising at least 40% per weight inorganics like calcium carbonate, titanium dioxide, wollastonite, mica, glass fibers, dolomite and the like. The rest percentage per weight can be polyethylene, polypropylene, styrene polymer or other thermoplastic material.
  • All measurement methods mentioned herein are readily available for the skilled person. For example, they can be obtained from the American National Standards Institute at: www.webstore.ansi.org
  • DETAILED DESCRIPTION OF THE INVENTION
  • According to a first aspect the present invention is directed to a multilayer film with weight less than 19 g/m2 used in malodorous item packaging, where the film comprises ethylene alpha olefin copolymer with a density less than 0.950 g/cm3 in at least one layer.
  • The multilayer film of the present invention preferably comprises two layers comprising ethylene alpha olefin copolymer with a density less than 0.950 g/cm3 in both layers.
  • In a further preferred embodiment, the film has the construction:
  • Outer Layer/Intermediate Layer/Barrier Layer/Intermediate Layer/inner layer,
    where both, outer and inner layer, comprise ethylene alpha olefin copolymer. It is noted that for the purposes of the present invention, the term “inner layer” is to be regarded as an additional outer layer of the multilayer film, which is in direct contact with the item to be packaged (i.e. an outer layer of the film which is located on the inside after a packaging process, not exposed to the environment).
  • According to a further embodiment, the present invention is of the same configuration where both inner and outer layer comprise a “substantially non resilient material” (SNR).
  • In a preferred version of the invention, the SNR material is at least 10 percent, preferably at least 20, preferably at least 30 percent of at least one of outer and inner layers.
  • Preferably, the film comprises an oxygen barrier layer. In a preferred version of the invention this barrier material in the barrier layer is polyamide. Polyamide 6, polyamide 6/66 and MXD nylon are especially preferred.
  • In the intermediate layers, typical adhesive resins like maleic anhydrite modified polyolefins may be used. Typical examples are BYNEL from Dupont and OREVAC from Arkema.
  • Additives well known in the art may be used in one or more layers of the present invention. Slip additives, antiblock additives, antifog, polymer processing aids may be used if pertinent. Antimicrobial additives may also be used in one or more of the layers to inhibit the microbe formation. Preferably the antimicrobial is put on the side where the waste is in direct vicinity.
  • The object of the invention is to produce the film of the above structure with a weight less than 19 grams per square meter. Preferably the weight is lower than 18 grams per square meter or even lower. Even more preferably, the weight is lower than 17 or 16 grams per square meter.
  • In order to increase the mechanical properties the film may be crosslinked with one of the following methods.
  • E-beam radiation, gamma radiation, moisture crosslinking using silane grafting compounds, peroxide crosslinking.
  • The film may be in tubular form or sealed at the edges or single sheet configuration.
  • Centrefold configuration is also possible.
  • The preferred production method for the film is the how blown film method, which is well known in the art. Other methods like extrusion through flat cast die is also possible.
  • EXAMPLES
  • A 5 layer film is produced in a commercial hot blown film line with the following recipe
  • Inner layer, 80% EA01+15% SNR1+5% ADDITIVES
  • Adjacent layer 100% ADH 1
  • Barrier layer PA1
  • Adjacent layer 100% ADH1
  • Outer layer same as inner layer
  • See table 1
  • The thickness of the structure is 6/1.5/1.5/1.5/6 starting from the inner and going to the outer layer.
  • TABLE 1
    Density
    Type Description g/cm3
    EAO1 Ethylene 0.92
    octene
    copolymer
    SNR1 Calcium 1.6
    carbonate
    compound
    AD1 LLDPE mod. 0.92
    Adhesive tie
    PA1 Polyamide 6 1.128
    PA2 MXD based
    polyamide
  • Example 2
  • A 5 layer film is produced in a hot blown film commercial line with the following recipe
  • Inner layer, 80% EAO1+15% SNR1+5% ADDITIVES
  • Adjacent layer 100% ADH 1
  • Barrier layer 80% PA1+20% PA2
  • Adjacent layer 100% ADH1
  • Outer layer same as inner layer
  • See table 1
  • The thickness of the structure is 6/1.5/1.5/1.5/6 starting from the inner and going to the outer layer.
  • See table 1
  • Tests
      • 1. Tensile strength and elongation test is done according to ASTM D 882.
      • 2. Odour test is done in the following way.
    Test 1
  • Tensile strength and elongation is measured as per ASTM D882.
  • MD stands for machine direction, whereas TD stands for transverse direction.
  • TENSILE ELONGATION TENSILE ELONGATION
    EXAMPLE STRENGTH(MD) (MD) STRENGTH(TD) (TD)
    1 20 150 15 380
    2 25 120 19 370
  • Odour Testing
  • 10 soiled diapers are put in a film of the present invention and also in a commercially sold film. The commercially sold film is believed to be monolayer.
  • The packs are put in PVDC comprising bags, so the odour cannot escape during the time of the evaluation.
  • The bags are opened 3 days after the soiling of the diapers and smell was evaluated by a 5 member panel.
  • The packs made from examples 1 and 2 were found substantially less smelly than the commercially sold ones.

Claims (8)

  1. 1. A multilayer film with weight less than 19 μm2 used in malodorous item packaging,
    where the film comprises ethylene alpha olefin copolymer with a density less than 0.950 g/cm3 in at least one layer.
  2. 2. The multilayer film of claim 1 where the film comprises two layers comprising ethylene alpha olefin copolymer with density less than 0.950 g/cm3 in both layers.
  3. 3. The multilayer film of claim 1 which comprises an oxygen barrier layer.
  4. 4. The multilayer film of claim 3, where the oxygen barrier layer comprises polyamide.
  5. 5. The multilayer film of claim 1, where the film is produced by the hot blown film method.
  6. 6. The multilayer film of claim 1, where the film comprises a substantially non resilient material.
  7. 7. The multilayer film of claim 1 where the grammage of the film is less than 17 g/m2.
  8. 8. The multilayer film of claim 7, where the grammage of the film is less than 16 g/m2.
US12322347 2008-01-29 2009-01-29 Thin film for waste packing cassettes Pending US20090191392A1 (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070082150A1 (en) * 2005-09-30 2007-04-12 Dimitrios Ginossatis Stack sealable heat shrinkable film
US20080003332A1 (en) * 2006-05-12 2008-01-03 Dimitrios Ginossatis Multilayer heat shrinkable cook-in film
US20080274314A1 (en) * 2007-04-26 2008-11-06 Dimitris Gkinosatis Stack sealable heat shrinkable film
US20080274328A1 (en) * 2007-04-26 2008-11-06 Dimitris Gkinosatis Thermoforming films
US20090176117A1 (en) * 2008-01-03 2009-07-09 Dimitris Gkinosatis Thermoforming films
US20090263599A1 (en) * 2008-04-21 2009-10-22 Dimitris Gkinosatis Stack sealable heat shrinkable film
US20100141003A1 (en) * 2008-12-09 2010-06-10 Combs John A Chair lift
US20110159263A1 (en) * 2009-12-02 2011-06-30 Dimitris Gkinosatis Thin film for waste packaging cassettes
US20120279181A1 (en) * 2011-05-03 2012-11-08 Dimitris Gkinosatis Waste packing system and film
US20130209797A1 (en) * 2012-02-08 2013-08-15 Flexopack S.A. Thin film for waste packing cassettes
US20150210454A1 (en) * 2008-01-29 2015-07-30 Flexopack S.A. Thin film for waste packing cassettes
US9365687B2 (en) 2008-01-02 2016-06-14 Flexopack S.A. Plastics Industry PVDC formulation and heat shrinkable film
US9440788B2 (en) 2011-06-16 2016-09-13 Flexopack S.A. Waste packing system and method of use
US9789669B2 (en) 2013-06-14 2017-10-17 Flexopack S.A. Heat shrinkable film

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US8129006B2 (en) 2005-09-30 2012-03-06 Flexopack S.A. Stack sealable heat shrinkable film
US20070082150A1 (en) * 2005-09-30 2007-04-12 Dimitrios Ginossatis Stack sealable heat shrinkable film
US20080003332A1 (en) * 2006-05-12 2008-01-03 Dimitrios Ginossatis Multilayer heat shrinkable cook-in film
US8697211B2 (en) 2007-04-26 2014-04-15 Flexopack S.A. Plastics Industry Stack sealable heat shrinkable film
US20080274314A1 (en) * 2007-04-26 2008-11-06 Dimitris Gkinosatis Stack sealable heat shrinkable film
US20080274328A1 (en) * 2007-04-26 2008-11-06 Dimitris Gkinosatis Thermoforming films
US9365687B2 (en) 2008-01-02 2016-06-14 Flexopack S.A. Plastics Industry PVDC formulation and heat shrinkable film
US20090176117A1 (en) * 2008-01-03 2009-07-09 Dimitris Gkinosatis Thermoforming films
US20150210454A1 (en) * 2008-01-29 2015-07-30 Flexopack S.A. Thin film for waste packing cassettes
US20090263599A1 (en) * 2008-04-21 2009-10-22 Dimitris Gkinosatis Stack sealable heat shrinkable film
US20100141003A1 (en) * 2008-12-09 2010-06-10 Combs John A Chair lift
US20110159263A1 (en) * 2009-12-02 2011-06-30 Dimitris Gkinosatis Thin film for waste packaging cassettes
US20120279181A1 (en) * 2011-05-03 2012-11-08 Dimitris Gkinosatis Waste packing system and film
US9290320B2 (en) * 2011-05-03 2016-03-22 Flexopack S.A. Plastics Industry Waste packing system and film
US20160236862A1 (en) * 2011-05-03 2016-08-18 Flexopack S.A. Waste packing system and film
US9440788B2 (en) 2011-06-16 2016-09-13 Flexopack S.A. Waste packing system and method of use
US20130209797A1 (en) * 2012-02-08 2013-08-15 Flexopack S.A. Thin film for waste packing cassettes
US9604430B2 (en) * 2012-02-08 2017-03-28 Flexopack S.A. Thin film for waste packing cassettes
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US20150210454A1 (en) 2015-07-30 application
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FI20090400U0 (en) application

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