US20080028826A1 - Volatile organic compound monitoring - Google Patents
Volatile organic compound monitoring Download PDFInfo
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- US20080028826A1 US20080028826A1 US11/872,603 US87260307A US2008028826A1 US 20080028826 A1 US20080028826 A1 US 20080028826A1 US 87260307 A US87260307 A US 87260307A US 2008028826 A1 US2008028826 A1 US 2008028826A1
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- facility
- monitoring
- soil
- subsurface
- volatile organic
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/22—Devices for withdrawing samples in the gaseous state
- G01N1/2294—Sampling soil gases or the like
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
- G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
- G01N33/0036—Specially adapted to detect a particular component
- G01N33/0047—Specially adapted to detect a particular component for organic compounds
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/22—Devices for withdrawing samples in the gaseous state
- G01N1/24—Suction devices
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/24—Earth materials
Definitions
- This invention relates generally to environmental pollution monitoring and, more specifically, to a system, method and apparatus for monitoring subsurface levels of volatile organic compounds (VOCs).
- VOCs volatile organic compounds
- VOCs Numerous commercial and industrial businesses use VOCs in day-to-day operations. Many of these VOCs are dangerous to human health and the environment if released to soil and groundwater.
- the dry cleaner industry has historically used a variety of solvents in the cleaning process, including volatile organic solvents such as kerosene, Stoddard solvent, gasoline, propylene glycol ethers and carbon tetrachloride. More recently, the majority of dry cleaner operations use tetrachloroethene or perchloroethene (PCE) as a cleaning solvent.
- PCE perchloroethene
- This VOC is a known cancer-causing agent in animals and may cause cancer in humans. Almost 95% of dry cleaner facilities use PCE in their cleaning processes.
- PCE When released and allowed to seep into the ground even small quantities of PCE can contaminate large quantities of soil and groundwater at levels dangerous to human health and the environment. Government prescribed cleanup levels for PCE are as low as 0.05 milligrams per kilogram in soil and 5 micrograms per liter in groundwater. A release of one gallon of PCE can contaminate 100 million gallons of groundwater to twice the prescribed cleanup level, and result in cleanup liability of hundreds of thousands and potentially millions of dollars.
- This invention is directed to a system, method and apparatus for periodically monitoring the subsurface at facilities where VOCs are used, stored and treated/recycled for releases of VOCs to the environment.
- This invention will enable business owners and property owners who lease space to business owners to protect their investment by monitoring the business operations.
- This invention will also provide insurers a means of assessing if a property has been affected by a release and monitoring insured properties to identify if a release has occurred such that the impacts can be mitigated before the contamination spreads and dramatically increases the costs associated with cleanup.
- This invention involves the installation of one or more VOC monitoring systems at business operations where VOCs are used.
- a soil probe (or other VOC gas or vapor monitoring device) is placed so as to be in communication with the soil beneath the surface at a facility and used to withdraw samples of gas or vapor from the pore space within the soil.
- soil gas and soil vapor are used interchangeably.
- Samples of the soil gas are analyzed for the presence of VOCs. VOCs released in the soil evaporate and diffuse within the pore space in the soil matrix. Samples of the gas removed from soil in the area of a VOC release will contain detectible concentrations of the VOC. Under facilities where no releases have occurred in close proximity to the soil probe, concentrations of the VOC should not be present in the soil gas. Where a release has occurred and migrated to soil in proximity to the soil probe, evidence of this release will be found present in the soil gas.
- FIG. 1 is an illustration of the preferred embodiment of the system of the present invention
- FIG. 2 is a flowchart showing the preferred VOC monitoring methodology of the present invention
- FIGS. 3, 3B , 3 C and 3 D are component views of the preferred embodiment of the soil probe of the present invention.
- FIG. 3A is a partially exploded view of a monitoring port cap, monitoring port and swedge fitting of the preferred embodiment of the soil probe of the present invention
- FIG. 4 is an illustration of an aspect of the installation of the preferred soil probe of the present invention utilizing an install tool
- FIG. 4A is an illustration of the bottom configuration of the install tool shown in FIG. 4 ;
- FIG. 5 is a further illustration of an aspect of the installation of the preferred soil probe of the present invention utilizing an install tool
- FIG. 6 is an illustration of an aspect of the installation of the preferred soil probe of the present invention utilizing a cap tool
- FIG. 6A is an illustration of the bottom configuration of the cap tool shown in FIG. 6 ;
- FIG. 6B is an illustration of an aspect of the installation of the preferred soil probe of the present invention wherein the cap tool is used to install a monitoring port cap;
- FIG. 7 is an illustration of an aspect of the VOC monitoring process utilizing a preferred sampling adaptor
- FIG. 8 is a flow chart showing the preferred VOC installation methodology of the present invention.
- FIG. 9 is a flow chart showing the preferred VOC monitoring methodology of the present invention.
- the present invention is directed to a system, method and apparatus for monitoring subsurface levels of chemicals of concern or, in the preferred context of the present invention, volatile organic compounds (VOCs).
- the preferred system 10 includes a soil probe 20 (or other VOC gas or vapor monitoring device) that is inserted through a surface penetration 150 in a facility surface 160 , such as an interior building floor slab or an exterior facility surface such as parking lot, a sidewalk or concrete slab, to create access to the soil beneath the facility surface, referred to as the facility subsurface 170 .
- VOCs at the facility are prevented from seeping into the facility subsurface 170 through the surface penetration 150 by the installed soil probe 20 fixed in place, preferably by use of a VOC resistant epoxy sealant 180 or similar chemically resistant sealant between the soil probe and the facility surface.
- the facility is evaluated to determine the applicability of the VOC monitoring technology of the present invention. This step preferably involves an evaluation of the historical uses of the location, the chemical composition of VOCs that potentially may be released and the physical construction of the facility.
- decision block 310 if the technology is determined not to be applicable, the logic proceeds to block 320 , where other VOC monitoring technologies may be considered. If at decision block 310 the technology is determine to be applicable, the logic proceeds to block 330 .
- the preferred location for the VOC monitor is selected.
- the present invention is preferably used at facility locations where VOCs are used, stored, or treated/recycled in commercial and industrial processes. This is preferably based on factors such as (1) the proximity to where VOCs are stored, used, treated, recycled, or disposed and releases are possible, and (2) the location where VOC release to the subsurface is made possible by facility structures, such as near construction joints, piping and storage containers.
- the VOCs of interest are selected to facilitate proper sampling and testing. This step preferably involves determining what chemicals have been used at the facility and may have been released into the subsurface. The order of blocks 330 and 340 may be altered, or the steps performed simultaneously.
- one or more VOC monitoring ports of the present invention are installed according the procedure described below with reference to FIG. 8 .
- a soil gas sample is collected for analysis. This is preferably accomplished according to the procedure described below with reference to FIG. 9 , and may be the initial assessment or part of an ongoing periodic or incidental monitoring program.
- the soil gas sample is analyzed for selected VOCs of interest, either using field or laboratory methods.
- decision block 380 a determination is made whether significant concentrations of VOCs are present. If significant concentrations of VOCs are present, the logic proceeds to block 390 , where an investigation is commenced to determine whether a release of VOCs occurred and, if so, the nature of the release and preferred remedy.
- significant concentrations may be predetermined or determined during analysis, and may be based on a variety of factors, but preferably is characterized in part depending on the particular history of the property being evaluated and subsurface conditions such as soil type and presence of groundwater. For example, significant concentrations could include any concentration of VOCs in cases where previous monitoring found no concentrations to exist. Alternatively, significant concentrations could include only increases in concentrations of VOCs in cases where previous monitoring found low background levels to exist.
- the preferred embodiment of the soil probe 20 is better understood with reference to FIGS. 1, 3 and 3 A- 3 D.
- the preferred soil probe 20 consists of a monitoring port 30 , a swedge fitting 60 , an installation tool 70 , a monitoring port cap 80 , a cap tool 90 and a sampling adaptor 100 , described in greater detail below.
- the monitoring port 30 is a substantially hollow, generally tubular-shaped member comprised of a head or mounting plate 32 , a threaded neck 44 , an extension tube 46 , a thread adaptor 48 and an end filter 50 .
- the mounting plate 32 is preferably larger in diameter than the tubular body of the probe in order to cover the surface opening of the surface penetration 150 .
- the mounting plate 32 has a top side 34 and bottom side 36 .
- the mounting plate 32 includes a threaded locking aperture 38 used to receive the installation tool 70 , the monitoring port cap 80 or the sampling adaptor 100 .
- the locking aperture 38 tapers from flush with the top 34 of the mounting plate to an interior locking groove 40 and then to a threaded interior 42 .
- a one-way valve (not shown) may be installed in the interior of the threaded neck 44 to prevent VOCs or other contaminants from the facility atmosphere from passing through the monitoring port 30 into the subsurface 170 during operation of the system of the present invention.
- the threaded neck 44 extends away from the bottom 36 of the mounting plate 32 .
- the extension tube 46 extends from the end of the threaded neck 44 remote from the mounting plate 32 .
- the extension tube may be of varying length depending on the penetration depth required for the probe, which in turn varies depending on the type of soil beneath the facility, the proximity to potential leaks or spills and the surface construction details.
- the length of the probe may be such that it does not extend beneath the bottom of the facility surface 160 , for example, the bottom of a building floor slab.
- the sample of soil gas is drawn from the pocket created between the facility surface 160 and the subsurface 170 by the surface penetration 150 .
- the thread adaptor 48 transitions between the end of the extension tube 46 remote from the threaded neck 44 and the end filter 50 .
- the end filter 50 may be a screen, other porous material filter or simply holes in the soil probe designed to allow the passage of soil gas while restricting the passage of soil particles into the soil probe.
- the diameter of the probe is preferably less than one inch (2.45 cm), but may be larger in certain applications where a larger probe is desirable for engineering reasons.
- the swedge fitting 60 has an interior nut 62 with threads corresponding to the threaded neck 44 of the monitoring port 30 . As the threaded neck 44 is threaded through the swedge fitting, the sides 64 of the swedge fitting are forced outward to engage material adjacent the swedge fitting, thereby securing the swedge fitting in place.
- the install tool 70 has a locking end 72 corresponding in size and shape to the locking aperture 40 of the mounting plate 32 and a tightening end 74 preferably of a standard socket size and shape. The unique correspondence between the interior locking groove 40 of the mounting plate 32 and the locking end 72 of the install tool 70 in the preferred embodiment discourages inadvertent or unauthorized removal of the monitoring port.
- the monitoring port cap 80 has a threaded first end 82 that corresponds to the threaded interior 42 of the locking aperture 38 of the mounting plate 32 and a cap head second end 84 that includes turning recesses 86 preferably formed therein.
- the monitoring port cap 80 preferably includes a plurality of o-rings 88 designed to created a substantially airtight seal between the monitoring port cap 80 and the interior of the locking aperture 38 of the monitoring port 30 when the monitoring port cap is interfaced within the monitoring port.
- the monitoring port cap 80 may be attached to the monitoring port 30 by means other than corresponding threads, for example, snap or friction fit.
- the monitoring port cap may be unitary with the monitoring port, for example, as a retractable piece providing access to the monitoring port 30 .
- the cap tool 90 has a connection end 92 having turning pins 94 corresponding in size and shape to the turning recesses 86 of the monitoring port cap 80 and a tightening end 96 preferably of a standard socket size and shape.
- the unique corresponding pin-recess configuration between the cap tool 90 and the monitoring port cap 80 in the preferred embodiment discourages inadvertent or unauthorized removal of the monitoring port cap.
- the sampling adaptor 100 is a hollow, generally tubular-shaped member having a threaded first end 102 that corresponds to the threaded interior 42 of the locking aperture 38 of the mounting plate 32 .
- the sampling adaptor 100 preferably includes a plurality of o-rings 104 designed to created a substantially liquid and airtight seal between the sampling adaptor 100 and the interior of the locking aperture 38 of the mounting plate 32 when the sampling adaptor 100 is interfaced within the monitoring port 30 .
- the sampling adaptor 100 has a second end 106 designed to interface with a sampling pump (represented as 190 in FIG. 1 ) into which soil gas samples are withdrawn from the facility subsurface 170 .
- the sampling adaptor includes a shutoff valve 108 that opens and closes the tubular interior path between the first end 102 and the second end 106 .
- the soil probe may take various forms without departing from the scope of the present invention.
- the soil probe may consist of a hollow tube with a closed end, manufactured with small diameter holes or slots along its length for the intake of gases from the subsurface 170 .
- the holes can vary in size and spacing depending on the soil being penetrated for sampling and monitoring.
- This embodiment effectively merges the monitoring port 30 and sampling adaptor 100 components into a single, monolithic member or monitoring station.
- the resulting monitoring station would preferably have a first monitoring end through which soil gas samples could be drawn and a second sampling end adaptable to a sampling pump or other device designed to withdraw and capture a soil gas sample.
- Yet other embodiments, for example incorporating the use of one or more screens rather than holes or slots along a hollow tube, may also be used.
- FIGS. 1 , 3 - 6 and 8 A preferred method for installing the preferred soil probe 20 of the present invention is described with reference to FIGS. 1 , 3 - 6 and 8 .
- a small diameter surface penetration 150 is made in the facility surface 160 to allow installation of the soil probe. This may be accomplished by drilling or other means.
- a VOC resistant epoxy sealant 180 or similar chemically resistant sealant is placed around the surface penetration 150 on the facility surface 160 .
- the monitoring port 30 is inserted through the surface penetration 150 so as to be in communication with the facility subsurface 170 beneath the facility surface 160 . In the preferred embodiment, this is accomplished by threading the threaded neck 44 of the mounting plate 32 through the threads of the interior nut 62 of the swedge fitting 60 . The mounting plate 32 is pressed securely via the VOC resistant epoxy sealant 180 to the facility surface 160 as it is threaded into the swedge fitting within the surface penetration.
- the monitoring port 30 is tightened within the swedge fitting 60 to firmly lodge the monitoring port in place within the surface penetration 150 . As better described with reference to FIGS.
- the locking end 72 of the install tool 70 is inserted into the locking aperture 40 of the mounting plate 32 .
- the tightening end 74 is twisted, thereby further threading the threaded neck 44 along the threads of the interior nut 62 of the swedge fitting 60 .
- the sides 64 of the swedge fitting are forced outward to engage material adjacent the swedge fitting, in this case the facility surface 160 , for example, within the surface penetration of a building floor slab, thereby securing the swedge fitting and monitoring port in place within the surface penetration.
- Alternative fittings or other securing methods may be used to secure the monitoring port in place within the surface penetration.
- locking clamps, tightening bolts or expanding fittings may be used instead of a swedge fitting.
- sealants, glues or filling material may be placed between the monitoring port and the facility surface to secure the monitoring port in place within the surface penetration.
- the bottom side 36 of the mounting plate 32 is sealed to the facility surface 160 using the VOC resistant epoxy sealant 180 to preferably eliminate leakage of VOCs or other contaminants from the facility into the subsurface 170 beneath the facility surface 160 via the surface penetration 150 and to seal in soil gas that may contain VOCs or other contaminants.
- VOCs volatile organic compound
- stored, treated/recycled there will be measurable concentrations of VOCs in the air. It is necessary to seal out these VOCs from being drawn into the soil beneath the slab during or between sampling events.
- the monitoring port cap 80 is inserted into the monitoring port 30 . More specifically, the threaded first end 82 of the monitoring port cap 80 is threaded along the threaded interior 42 of the locking aperture 38 of the mounting plate 32 . This is preferably accomplished using the cap tool 90 . As shown with reference to FIGS. 6, 6A and 6 B, the turning pins 94 of the cap tool 90 are aligned with and inserted into the corresponding turning recesses 86 of the monitoring port cap 80 and the cap tool (or other tightening means) is used to thread the threaded first end 82 of the monitoring port cap along the threaded interior 42 of the mounting plate 32 . A substantially liquid or airtight seal is preferably created between the monitoring port cap 80 and the monitoring port 30 by virtue of the plurality of o-rings 88 (see FIGS. 3 and 3 A).
- Alternative embodiments of the soil probe 20 can be installed using any of a variety of methods, for example, through vibratory insertion or manual force in a retrofit application or forming the soil probe into the facility surface at the time of construction.
- the top of an alternative soil probe is terminated along the top of the facility surface at an access port, which is a port sealed in the surface penetration and designed to prevent any possible leakage of released VOCs or other contaminants.
- the access cover, door, hatch, or other means of opening the monitoring port is also sealed between uses to prevent any possible leakage through the monitoring port by use of o-rings, sealants or other means.
- the soil probe that penetrates the subsurface is installed with a manual valve or quick-connect self-sealing valve to prevent possible chemical leakage through the sampling port as well as to seal in soil gas that may contain VOCs or other contaminants.
- FIGS. 1, 7 and 9 A preferred method for collecting soil vapor samples using the preferred soil probe 20 of the present invention is described with reference to FIGS. 1, 7 and 9 .
- the monitoring cap 80 is removed from the monitoring port 30 using the cap tool 90 .
- the sampling adaptor 100 is inserted into the threaded locking aperture 38 of the monitoring port 30 . This is accomplished by screwing the threaded first end 102 of the sampling adaptor along the threaded interior 42 of the locking aperture 38 of the mounting plate 32 .
- the removal of the monitoring cap 80 and the insertion of the sampling adaptor 100 preferably occurs very quickly to minimize the potential exchange of undesirable materials or contaminants, such as gases, liquids or other particles, between the facility and the facility subsurface 170 , particularly in the event that a one-way valve is not present in the interior of the threaded neck 44 to prevent undesirable materials from the facility passing through the monitoring port 30 into the subsurface 170 during operation of the system of the present invention.
- the sampling adaptor is preferably inserted with the shutoff valve 108 closed.
- a sampling pump 190 is attached to the second end 106 of the sampling adaptor 100 .
- a determination is made whether to purge the soil gas prior to withdrawing a sample for testing. It is frequently desirable to purge the soil probe 20 and subsurface 170 of possible atmospheric contaminants prior to withdrawing a sample for testing purposes. If the determination is made at decision block 606 to purge the soil gas, the logic proceeds to block 608 .
- the sampling pump 190 is initiated, the shutoff valve 108 is opened, a sample of the subsurface soil gas is withdrawn using the sampling pump, the shutoff valve 108 is closed, and the captured purge sample is released in a predetermined manner so as to avoid further possible soil gas contamination.
- the logic then proceeds to block 610 . If the determination is made at decision block 606 not to purge the soil gas, for example if a purge process has already occurred, the logic proceeds directly to block 610 .
- the sampling pump 190 is initiated, the shutoff valve 108 is opened, a sample of the subsurface soil gas is withdrawn using the sampling pump and the shutoff valve 108 is closed. The resultant captured sample is subsequently tested.
- the top of the soil probe is designed to facilitate connection to a sampling device that withdraws vapors and gas from the soil beneath the facility surface.
- a hand pump or other sampling device can be used to withdraw air from the soil probe.
- Soil gas VOC content is preferably measured in the field by using a hand pump connected to a variety of commercial calorimetric detector tubes or field instruments designed to measure VOC concentrations. Soil gas samples can also be collected in containers for later laboratory analysis and precise quantification of VOC concentration.
- the subsurface 170 soil gas is preferably sampled on a routine basis, but sampling may also occur on an incidental basis as desired.
- Routine monitoring annually or semi-annually, is preferably established to determine if a release of VOC to the subsurface has occurred during the period.
- sampling events can take place in anticipation of property sale, renewal of insurance, or following a release incident to assess potential migration to the subsurface soil.
Abstract
A system, method and apparatus for monitoring the subsurface at facilities for the presence of volatile organic compounds (VOCs). A surface penetration is made in a facility surface providing access to the subsurface soil beneath the facility. A soil probe is placed in communication with the soil beneath the facility surface and used to withdraw samples of soil gas from the pore space within the soil. The soil probe includes a monitoring port configured to seal the surface penetration and minimize the movement of undesirable materials between the facility and the subsurface via the monitoring port. The soil probe has an end filter in communication with the subsurface under the facility. The monitoring port is coupled to a sampling pump used to withdraw the soil gas sample. Soil gas samples are periodically obtained and analyzed for the presence of VOCs.
Description
- This application is a continuation of U.S. patent application Ser. No. 10/800,458, filed Mar. 15, 2004, which claims priority from U.S. Provisional Application Ser. No. 60/454,922, filed Mar. 13, 2003, both of which are hereby incorporated by reference.
- This invention relates generally to environmental pollution monitoring and, more specifically, to a system, method and apparatus for monitoring subsurface levels of volatile organic compounds (VOCs).
- Numerous commercial and industrial businesses use VOCs in day-to-day operations. Many of these VOCs are dangerous to human health and the environment if released to soil and groundwater. For example, the dry cleaner industry has historically used a variety of solvents in the cleaning process, including volatile organic solvents such as kerosene, Stoddard solvent, gasoline, propylene glycol ethers and carbon tetrachloride. More recently, the majority of dry cleaner operations use tetrachloroethene or perchloroethene (PCE) as a cleaning solvent. This VOC is a known cancer-causing agent in animals and may cause cancer in humans. Almost 95% of dry cleaner facilities use PCE in their cleaning processes.
- When released and allowed to seep into the ground even small quantities of PCE can contaminate large quantities of soil and groundwater at levels dangerous to human health and the environment. Government prescribed cleanup levels for PCE are as low as 0.05 milligrams per kilogram in soil and 5 micrograms per liter in groundwater. A release of one gallon of PCE can contaminate 100 million gallons of groundwater to twice the prescribed cleanup level, and result in cleanup liability of hundreds of thousands and potentially millions of dollars.
- Given the liabilities associated with contamination cleanup, the insurance industry has been reticent to insure real estate against environmental risks where dry cleaner operations are ongoing or have previously occupied space on the property. Property owners are unable to sell properties or can only sell at reduced prices because of the risk associated with owning properties previously occupied by dry cleaner operations. Other businesses that use, store or treat or recycle VOCs, such as metal plating and fabrication plants, are affected similarly.
- Currently there is no practical system or method to periodically monitor, in an efficient and cost effective manner, the subsurface at business facilities where VOCs are used. Typically, subsurface investigations occur only when an audit, insurance review or property sale takes place, or when a large release is documented. These investigations generally involve installing soil borings and groundwater monitoring wells to determine if a release has affected the soil and/or groundwater. By the time an investigation is performed the damage is done and the problem could have been spread by groundwater flow to contaminate millions of gallons of groundwater and migrated beyond property boundaries. In addition, subsurface investigations involving soil borings and monitoring wells are expensive, with costs ranging to hundreds of thousands of dollars. Environmental professionals are required to design these investigations, manage boring and well installation, interpret data, and report results.
- Thus, there is a need for an inexpensive system, method and apparatus to monitor facilities where VOCs are used to determine if a release has occurred. The monitoring will determine if problems already exist or will catch future releases in a timely manner to facilitate mitigation before the cost of cleanup escalates.
- This invention is directed to a system, method and apparatus for periodically monitoring the subsurface at facilities where VOCs are used, stored and treated/recycled for releases of VOCs to the environment. This invention will enable business owners and property owners who lease space to business owners to protect their investment by monitoring the business operations. This invention will also provide insurers a means of assessing if a property has been affected by a release and monitoring insured properties to identify if a release has occurred such that the impacts can be mitigated before the contamination spreads and dramatically increases the costs associated with cleanup.
- This invention involves the installation of one or more VOC monitoring systems at business operations where VOCs are used. A soil probe (or other VOC gas or vapor monitoring device) is placed so as to be in communication with the soil beneath the surface at a facility and used to withdraw samples of gas or vapor from the pore space within the soil. As used herein, the term soil gas and soil vapor are used interchangeably. Samples of the soil gas are analyzed for the presence of VOCs. VOCs released in the soil evaporate and diffuse within the pore space in the soil matrix. Samples of the gas removed from soil in the area of a VOC release will contain detectible concentrations of the VOC. Under facilities where no releases have occurred in close proximity to the soil probe, concentrations of the VOC should not be present in the soil gas. Where a release has occurred and migrated to soil in proximity to the soil probe, evidence of this release will be found present in the soil gas.
- Implementing a protocol of periodic soil gas sampling at the facility is a cost-effective way to document whether ongoing operations have introduced VOCs into the soil matrix and groundwater, if present. Property owners and insurers benefit by knowing that year-to-year no releases to the subsurface have occurred. Property buyers benefit by knowing that the property is not being negatively impacted by ongoing operations. Business owners and insurers benefit by knowing that ongoing operations are not causing impacts to the property that would incur expensive liabilities.
- The preferred and alternative embodiments of the present invention are described in detail below with reference to the following drawings.
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FIG. 1 is an illustration of the preferred embodiment of the system of the present invention; -
FIG. 2 is a flowchart showing the preferred VOC monitoring methodology of the present invention; -
FIGS. 3, 3B , 3C and 3D are component views of the preferred embodiment of the soil probe of the present invention; -
FIG. 3A is a partially exploded view of a monitoring port cap, monitoring port and swedge fitting of the preferred embodiment of the soil probe of the present invention; -
FIG. 4 is an illustration of an aspect of the installation of the preferred soil probe of the present invention utilizing an install tool; -
FIG. 4A is an illustration of the bottom configuration of the install tool shown inFIG. 4 ; -
FIG. 5 is a further illustration of an aspect of the installation of the preferred soil probe of the present invention utilizing an install tool; -
FIG. 6 is an illustration of an aspect of the installation of the preferred soil probe of the present invention utilizing a cap tool; -
FIG. 6A is an illustration of the bottom configuration of the cap tool shown inFIG. 6 ; -
FIG. 6B is an illustration of an aspect of the installation of the preferred soil probe of the present invention wherein the cap tool is used to install a monitoring port cap; -
FIG. 7 is an illustration of an aspect of the VOC monitoring process utilizing a preferred sampling adaptor; -
FIG. 8 is a flow chart showing the preferred VOC installation methodology of the present invention; and -
FIG. 9 is a flow chart showing the preferred VOC monitoring methodology of the present invention. - The present invention is directed to a system, method and apparatus for monitoring subsurface levels of chemicals of concern or, in the preferred context of the present invention, volatile organic compounds (VOCs). With reference to
FIG. 1 , thepreferred system 10 includes a soil probe 20 (or other VOC gas or vapor monitoring device) that is inserted through asurface penetration 150 in afacility surface 160, such as an interior building floor slab or an exterior facility surface such as parking lot, a sidewalk or concrete slab, to create access to the soil beneath the facility surface, referred to as thefacility subsurface 170. Possible VOCs at the facility are prevented from seeping into thefacility subsurface 170 through thesurface penetration 150 by the installedsoil probe 20 fixed in place, preferably by use of a VOC resistantepoxy sealant 180 or similar chemically resistant sealant between the soil probe and the facility surface. - The methodology of the preferred embodiment for a monitoring system is described with reference to
FIG. 2 . Atblock 300, the facility is evaluated to determine the applicability of the VOC monitoring technology of the present invention. This step preferably involves an evaluation of the historical uses of the location, the chemical composition of VOCs that potentially may be released and the physical construction of the facility. Atdecision block 310, if the technology is determined not to be applicable, the logic proceeds to block 320, where other VOC monitoring technologies may be considered. If atdecision block 310 the technology is determine to be applicable, the logic proceeds to block 330. - At
block 330, the preferred location for the VOC monitor is selected. The present invention is preferably used at facility locations where VOCs are used, stored, or treated/recycled in commercial and industrial processes. This is preferably based on factors such as (1) the proximity to where VOCs are stored, used, treated, recycled, or disposed and releases are possible, and (2) the location where VOC release to the subsurface is made possible by facility structures, such as near construction joints, piping and storage containers. Atblock 340, the VOCs of interest are selected to facilitate proper sampling and testing. This step preferably involves determining what chemicals have been used at the facility and may have been released into the subsurface. The order ofblocks block 350, one or more VOC monitoring ports of the present invention are installed according the procedure described below with reference toFIG. 8 . - At
block 360, a soil gas sample is collected for analysis. This is preferably accomplished according to the procedure described below with reference toFIG. 9 , and may be the initial assessment or part of an ongoing periodic or incidental monitoring program. Atblock 370, the soil gas sample is analyzed for selected VOCs of interest, either using field or laboratory methods. Atdecision block 380, a determination is made whether significant concentrations of VOCs are present. If significant concentrations of VOCs are present, the logic proceeds to block 390, where an investigation is commenced to determine whether a release of VOCs occurred and, if so, the nature of the release and preferred remedy. If no significant concentrations of VOCs are present, the logic proceeds to block 400, where data obtained during monitoring is processed, tabulated and maintained for future reference and continued evaluation. The definition of “significant concentrations” may be predetermined or determined during analysis, and may be based on a variety of factors, but preferably is characterized in part depending on the particular history of the property being evaluated and subsurface conditions such as soil type and presence of groundwater. For example, significant concentrations could include any concentration of VOCs in cases where previous monitoring found no concentrations to exist. Alternatively, significant concentrations could include only increases in concentrations of VOCs in cases where previous monitoring found low background levels to exist. - The preferred embodiment of the
soil probe 20 is better understood with reference toFIGS. 1, 3 and 3A-3D. Thepreferred soil probe 20 consists of amonitoring port 30, a swedge fitting 60, aninstallation tool 70, amonitoring port cap 80, acap tool 90 and asampling adaptor 100, described in greater detail below. - The
monitoring port 30 is a substantially hollow, generally tubular-shaped member comprised of a head or mountingplate 32, a threadedneck 44, anextension tube 46, athread adaptor 48 and anend filter 50. The mountingplate 32 is preferably larger in diameter than the tubular body of the probe in order to cover the surface opening of thesurface penetration 150. The mountingplate 32 has atop side 34 andbottom side 36. As described with reference toFIG. 3A , the mountingplate 32 includes a threadedlocking aperture 38 used to receive theinstallation tool 70, themonitoring port cap 80 or thesampling adaptor 100. The lockingaperture 38 tapers from flush with the top 34 of the mounting plate to aninterior locking groove 40 and then to a threadedinterior 42. In an alternative embodiment, a one-way valve (not shown) may be installed in the interior of the threadedneck 44 to prevent VOCs or other contaminants from the facility atmosphere from passing through themonitoring port 30 into thesubsurface 170 during operation of the system of the present invention. - The threaded
neck 44 extends away from the bottom 36 of the mountingplate 32. Theextension tube 46 extends from the end of the threadedneck 44 remote from the mountingplate 32. The extension tube may be of varying length depending on the penetration depth required for the probe, which in turn varies depending on the type of soil beneath the facility, the proximity to potential leaks or spills and the surface construction details. In an alternative embodiment, the length of the probe may be such that it does not extend beneath the bottom of thefacility surface 160, for example, the bottom of a building floor slab. In this embodiment, the sample of soil gas is drawn from the pocket created between thefacility surface 160 and thesubsurface 170 by thesurface penetration 150. - The
thread adaptor 48 transitions between the end of theextension tube 46 remote from the threadedneck 44 and theend filter 50. Theend filter 50 may be a screen, other porous material filter or simply holes in the soil probe designed to allow the passage of soil gas while restricting the passage of soil particles into the soil probe. The diameter of the probe is preferably less than one inch (2.45 cm), but may be larger in certain applications where a larger probe is desirable for engineering reasons. - The
swedge fitting 60 has aninterior nut 62 with threads corresponding to the threadedneck 44 of themonitoring port 30. As the threadedneck 44 is threaded through the swedge fitting, thesides 64 of the swedge fitting are forced outward to engage material adjacent the swedge fitting, thereby securing the swedge fitting in place. The installtool 70 has a lockingend 72 corresponding in size and shape to the lockingaperture 40 of the mountingplate 32 and a tighteningend 74 preferably of a standard socket size and shape. The unique correspondence between theinterior locking groove 40 of the mountingplate 32 and the lockingend 72 of the installtool 70 in the preferred embodiment discourages inadvertent or unauthorized removal of the monitoring port. - The preferred embodiment, the
monitoring port cap 80 has a threadedfirst end 82 that corresponds to the threadedinterior 42 of the lockingaperture 38 of the mountingplate 32 and a cap headsecond end 84 that includes turningrecesses 86 preferably formed therein. Themonitoring port cap 80 preferably includes a plurality of o-rings 88 designed to created a substantially airtight seal between the monitoringport cap 80 and the interior of the lockingaperture 38 of themonitoring port 30 when the monitoring port cap is interfaced within the monitoring port. In alternative embodiments, themonitoring port cap 80 may be attached to themonitoring port 30 by means other than corresponding threads, for example, snap or friction fit. In yet an alternative embodiment, the monitoring port cap may be unitary with the monitoring port, for example, as a retractable piece providing access to themonitoring port 30. Thecap tool 90 has aconnection end 92 having turning pins 94 corresponding in size and shape to the turning recesses 86 of themonitoring port cap 80 and a tighteningend 96 preferably of a standard socket size and shape. The unique corresponding pin-recess configuration between thecap tool 90 and themonitoring port cap 80 in the preferred embodiment discourages inadvertent or unauthorized removal of the monitoring port cap. - The
sampling adaptor 100 is a hollow, generally tubular-shaped member having a threadedfirst end 102 that corresponds to the threadedinterior 42 of the lockingaperture 38 of the mountingplate 32. Thesampling adaptor 100 preferably includes a plurality of o-rings 104 designed to created a substantially liquid and airtight seal between thesampling adaptor 100 and the interior of the lockingaperture 38 of the mountingplate 32 when thesampling adaptor 100 is interfaced within themonitoring port 30. Thesampling adaptor 100 has asecond end 106 designed to interface with a sampling pump (represented as 190 inFIG. 1 ) into which soil gas samples are withdrawn from thefacility subsurface 170. The sampling adaptor includes ashutoff valve 108 that opens and closes the tubular interior path between thefirst end 102 and thesecond end 106. - Other VOC monitoring devices, for example, electronic detectors, could be used to perform the function of the
soil probe 20. In addition, the soil probe may take various forms without departing from the scope of the present invention. For example, the soil probe may consist of a hollow tube with a closed end, manufactured with small diameter holes or slots along its length for the intake of gases from thesubsurface 170. The holes can vary in size and spacing depending on the soil being penetrated for sampling and monitoring. This embodiment effectively merges themonitoring port 30 andsampling adaptor 100 components into a single, monolithic member or monitoring station. The resulting monitoring station would preferably have a first monitoring end through which soil gas samples could be drawn and a second sampling end adaptable to a sampling pump or other device designed to withdraw and capture a soil gas sample. Yet other embodiments, for example incorporating the use of one or more screens rather than holes or slots along a hollow tube, may also be used. - A preferred method for installing the
preferred soil probe 20 of the present invention is described with reference to FIGS. 1, 3-6 and 8. With reference to the flow chart shown inFIG. 8 , atblock 500, a smalldiameter surface penetration 150 is made in thefacility surface 160 to allow installation of the soil probe. This may be accomplished by drilling or other means. Atblock 502, a VOC resistantepoxy sealant 180 or similar chemically resistant sealant is placed around thesurface penetration 150 on thefacility surface 160. - At
block 504, themonitoring port 30 is inserted through thesurface penetration 150 so as to be in communication with thefacility subsurface 170 beneath thefacility surface 160. In the preferred embodiment, this is accomplished by threading the threadedneck 44 of the mountingplate 32 through the threads of theinterior nut 62 of theswedge fitting 60. The mountingplate 32 is pressed securely via the VOC resistantepoxy sealant 180 to thefacility surface 160 as it is threaded into the swedge fitting within the surface penetration. Atblock 506, themonitoring port 30 is tightened within the swedge fitting 60 to firmly lodge the monitoring port in place within thesurface penetration 150. As better described with reference toFIGS. 4, 4A and 5, the lockingend 72 of the installtool 70 is inserted into the lockingaperture 40 of the mountingplate 32. Using a socket wrench or other tightening means, the tighteningend 74 is twisted, thereby further threading the threadedneck 44 along the threads of theinterior nut 62 of theswedge fitting 60. As the threadedneck 44 is threaded through the swedge fitting, thesides 64 of the swedge fitting are forced outward to engage material adjacent the swedge fitting, in this case thefacility surface 160, for example, within the surface penetration of a building floor slab, thereby securing the swedge fitting and monitoring port in place within the surface penetration. Alternative fittings or other securing methods may be used to secure the monitoring port in place within the surface penetration. For example, locking clamps, tightening bolts or expanding fittings may be used instead of a swedge fitting. In addition, sealants, glues or filling material may be placed between the monitoring port and the facility surface to secure the monitoring port in place within the surface penetration. - As described above, the
bottom side 36 of the mountingplate 32 is sealed to thefacility surface 160 using the VOC resistantepoxy sealant 180 to preferably eliminate leakage of VOCs or other contaminants from the facility into thesubsurface 170 beneath thefacility surface 160 via thesurface penetration 150 and to seal in soil gas that may contain VOCs or other contaminants. In addition, in facilities where VOCs are used, stored, treated/recycled there will be measurable concentrations of VOCs in the air. It is necessary to seal out these VOCs from being drawn into the soil beneath the slab during or between sampling events. - At
block 508, themonitoring port cap 80 is inserted into themonitoring port 30. More specifically, the threadedfirst end 82 of themonitoring port cap 80 is threaded along the threadedinterior 42 of the lockingaperture 38 of the mountingplate 32. This is preferably accomplished using thecap tool 90. As shown with reference toFIGS. 6, 6A and 6B, the turning pins 94 of thecap tool 90 are aligned with and inserted into the corresponding turning recesses 86 of themonitoring port cap 80 and the cap tool (or other tightening means) is used to thread the threadedfirst end 82 of the monitoring port cap along the threadedinterior 42 of the mountingplate 32. A substantially liquid or airtight seal is preferably created between the monitoringport cap 80 and themonitoring port 30 by virtue of the plurality of o-rings 88 (seeFIGS. 3 and 3 A). - Alternative embodiments of the
soil probe 20 can be installed using any of a variety of methods, for example, through vibratory insertion or manual force in a retrofit application or forming the soil probe into the facility surface at the time of construction. The top of an alternative soil probe is terminated along the top of the facility surface at an access port, which is a port sealed in the surface penetration and designed to prevent any possible leakage of released VOCs or other contaminants. The access cover, door, hatch, or other means of opening the monitoring port is also sealed between uses to prevent any possible leakage through the monitoring port by use of o-rings, sealants or other means. As described above, in the preferred embodiment, the soil probe that penetrates the subsurface is installed with a manual valve or quick-connect self-sealing valve to prevent possible chemical leakage through the sampling port as well as to seal in soil gas that may contain VOCs or other contaminants. - A preferred method for collecting soil vapor samples using the preferred
soil probe 20 of the present invention is described with reference toFIGS. 1, 7 and 9. With reference to the flow chart shown inFIG. 9 , at block 600, themonitoring cap 80 is removed from themonitoring port 30 using thecap tool 90. Atblock 602, thesampling adaptor 100 is inserted into the threaded lockingaperture 38 of themonitoring port 30. This is accomplished by screwing the threadedfirst end 102 of the sampling adaptor along the threadedinterior 42 of the lockingaperture 38 of the mountingplate 32. The removal of themonitoring cap 80 and the insertion of thesampling adaptor 100 preferably occurs very quickly to minimize the potential exchange of undesirable materials or contaminants, such as gases, liquids or other particles, between the facility and thefacility subsurface 170, particularly in the event that a one-way valve is not present in the interior of the threadedneck 44 to prevent undesirable materials from the facility passing through themonitoring port 30 into thesubsurface 170 during operation of the system of the present invention. For the same reason, namely, to prevent the unintended exchange of undesirable materials between the facility and thefacility subsurface 170, the sampling adaptor is preferably inserted with theshutoff valve 108 closed. - At
block 604, asampling pump 190 is attached to thesecond end 106 of thesampling adaptor 100. Atdecision block 606, a determination is made whether to purge the soil gas prior to withdrawing a sample for testing. It is frequently desirable to purge thesoil probe 20 andsubsurface 170 of possible atmospheric contaminants prior to withdrawing a sample for testing purposes. If the determination is made atdecision block 606 to purge the soil gas, the logic proceeds to block 608. Atblock 608, thesampling pump 190 is initiated, theshutoff valve 108 is opened, a sample of the subsurface soil gas is withdrawn using the sampling pump, theshutoff valve 108 is closed, and the captured purge sample is released in a predetermined manner so as to avoid further possible soil gas contamination. The logic then proceeds to block 610. If the determination is made atdecision block 606 not to purge the soil gas, for example if a purge process has already occurred, the logic proceeds directly to block 610. Atblock 610, thesampling pump 190 is initiated, theshutoff valve 108 is opened, a sample of the subsurface soil gas is withdrawn using the sampling pump and theshutoff valve 108 is closed. The resultant captured sample is subsequently tested. - As explained above, the top of the soil probe is designed to facilitate connection to a sampling device that withdraws vapors and gas from the soil beneath the facility surface. For example, a hand pump or other sampling device can be used to withdraw air from the soil probe. Soil gas VOC content is preferably measured in the field by using a hand pump connected to a variety of commercial calorimetric detector tubes or field instruments designed to measure VOC concentrations. Soil gas samples can also be collected in containers for later laboratory analysis and precise quantification of VOC concentration.
- The
subsurface 170 soil gas is preferably sampled on a routine basis, but sampling may also occur on an incidental basis as desired. Routine monitoring, annually or semi-annually, is preferably established to determine if a release of VOC to the subsurface has occurred during the period. In addition, sampling events can take place in anticipation of property sale, renewal of insurance, or following a release incident to assess potential migration to the subsurface soil. - While the preferred embodiment of the invention has been illustrated and described, as noted above, many changes can be made without departing from the spirit and scope of the invention. For example, the precise components used in the
preferred soil probe 20 may be modified in accordance with the overall function of the soil probe to safely withdraw soil gas samples. As discussed above, various types of sampling pumps may be used. The exact sequence of many of the steps in the installation and sampling methods may be altered and steps merged. For example, applying the VOCresistant sealant 180 inblock 502 ofFIG. 8 may occur concurrent with insertion of themonitoring port 20 inblock 504. Accordingly, the scope of the invention is not limited by the disclosure of the preferred embodiment. Instead, the invention should be determined entirely by reference to the claims that follow.
Claims (12)
1. A method for monitoring the subsurface under a facility for volatile organic compounds, comprising:
evaluating a facility for applicability of subsurface monitoring of volatile organic compounds;
if subsurface monitoring of volatile organic compounds is appropriate at the facility, determining the location at which to monitor subsurface volatile organic compounds at the facility;
installing a volatile organic compound monitoring station at the determined location at the facility, which installation includes positioning the monitoring station within a surface penetration such that the monitoring station engages a wall of the surface penetration;
collecting soil vapor samples using the volatile organic compound monitoring station; and
analyzing the collected soil vapor sample for the presence of volatile organic compounds.
2. The method of claim 1 , wherein determining the location at which to monitor subsurface volatile organic compounds at the facility is based on at least one of the proximity to where volatile organic compounds are found at the facility or the location where volatile organic compound release to the subsurface under the facility is made possible by the facility structure.
3. The method of claim 1 , further comprising if volatile organic compounds are present in the collected soil vapor sample, investigating the subsurface under the facility to determine if significant quantities of volatile organic compounds are present.
4. The method of claim 1 , further comprising if volatile organic compounds are not present in the collected soil vapor sample, maintaining data related to the collected soil vapor sample.
5. A method for installing a volatile organic compound monitoring station for sampling soil gas in the subsurface under a facility, comprising:
creating a surface penetration at a facility;
inserting a monitoring station having at least one securing member into the surface penetration such that the at least one securing member engages a wall of the surface penetration to position the monitoring station in the surface penetration, the monitoring station comprising a mounting plate and a generally tubular member extending substantially perpendicularly from the mounting plate; and
forming a seal between the monitoring station and the facility surface, wherein forming a seal between the monitoring station and the facility surface comprises applying a sealant to the facility surface substantially around the surface penetration to facilitate creation of the seal between the monitoring station and the facility surface and positioning the mounting plate on the seal having the generally tubular member extending into the penetration.
6. The method of claim 5 , wherein forming a seal between the monitoring station and the facility surface further comprises applying a sealant to the facility surface substantially around the surface penetration to facilitate creation of the seal between the monitoring station and the facility surface.
7. The method of claim 5 , wherein the monitoring station has a hollow, generally tubular shape and further comprising closing the monitoring station by inserting a monitoring station cap into the hollow, generally tubular-shaped monitoring station.
8. A soil probe for monitoring the subsurface under a facility surface for volatile organic compounds, comprising:
a monitoring port having an end filter in communication with the subsurface under the facility surface and at least one securing member engaging the subsurface under the facility surface so that the end filter of the monitoring port extends into the subsurface under the facility surface;
a monitoring port cap configured to close the monitoring port to minimize the movement of undesirable materials between the facility and the subsurface via the monitoring port; and
a sampling adaptor configured to interface with the monitoring port and a sampling pump to allow the withdrawal of a soil gas sample from the subsurface under the facility surface.
9. The soil probe of claim 8 , wherein:
the monitoring port is a substantially hollow, generally tubular-shaped member having a threaded interior; and
the monitoring port cap has a threaded exterior corresponding to and configured to interface with the threaded interior of the monitoring port.
10. The soil probe of claim 8 , wherein:
the monitoring port has a locking aperture; and
further comprising a locking tool for use in the installation of the monitoring port, the locking tool having an end corresponding in size and shape to the locking aperture of the monitoring port.
11. The soil probe of claim 8 , wherein:
the monitoring port cap has turning recesses formed therein; and
further comprising a cap tool for use in the installation of the monitoring port cap, the cap tool having turning pins corresponding in size and shape to the turning recesses of the monitoring port cap.
12. The soil probe of claim 8 , wherein the monitoring port cap has at least one sealing means designed to create a substantially liquid and airtight seal between the monitoring port cap and the monitoring port when the monitoring port cap is used to close the monitoring port.
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