US20060222034A1 - 6 Khz and above gas discharge laser system - Google Patents
6 Khz and above gas discharge laser system Download PDFInfo
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- US20060222034A1 US20060222034A1 US11/095,976 US9597605A US2006222034A1 US 20060222034 A1 US20060222034 A1 US 20060222034A1 US 9597605 A US9597605 A US 9597605A US 2006222034 A1 US2006222034 A1 US 2006222034A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/02—Constructional details
- H01S3/03—Constructional details of gas laser discharge tubes
- H01S3/036—Means for obtaining or maintaining the desired gas pressure within the tube, e.g. by gettering, replenishing; Means for circulating the gas, e.g. for equalising the pressure within the tube
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F27/00—Details of transformers or inductances, in general
- H01F27/08—Cooling; Ventilating
- H01F27/22—Cooling by heat conduction through solid or powdered fillings
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F3/00—Cores, Yokes, or armatures
- H01F3/10—Composite arrangements of magnetic circuits
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F38/00—Adaptations of transformers or inductances for specific applications or functions
- H01F38/08—High-leakage transformers or inductances
- H01F38/10—Ballasts, e.g. for discharge lamps
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/02—Constructional details
- H01S3/04—Arrangements for thermal management
- H01S3/041—Arrangements for thermal management for gas lasers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F27/00—Details of transformers or inductances, in general
- H01F27/24—Magnetic cores
- H01F27/26—Fastening parts of the core together; Fastening or mounting the core on casing or support
- H01F27/266—Fastening or mounting the core on casing or support
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/02—Constructional details
- H01S3/04—Arrangements for thermal management
- H01S3/0404—Air- or gas cooling, e.g. by dry nitrogen
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/09—Processes or apparatus for excitation, e.g. pumping
- H01S3/097—Processes or apparatus for excitation, e.g. pumping by gas discharge of a gas laser
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/09—Processes or apparatus for excitation, e.g. pumping
- H01S3/097—Processes or apparatus for excitation, e.g. pumping by gas discharge of a gas laser
- H01S3/09702—Details of the driver electronics and electric discharge circuits
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/14—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range characterised by the material used as the active medium
- H01S3/22—Gases
- H01S3/223—Gases the active gas being polyatomic, i.e. containing two or more atoms
- H01S3/225—Gases the active gas being polyatomic, i.e. containing two or more atoms comprising an excimer or exciplex
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/23—Arrangements of two or more lasers not provided for in groups H01S3/02 - H01S3/22, e.g. tandem arrangements of separate active media
- H01S3/2308—Amplifier arrangements, e.g. MOPA
Definitions
- the present invention related to 6 KHz and above gas discharge laser systems, such as ArF, KrF, F 2 , XeCl and the like gas discharge lasers.
- Gas discharge lasers e.g., in a MOPA configuration, e.g., applicants' assignee's XLA-100 series laser systems, employing a master oscillator and power amplifier based ArF excimer gas discharge laser, e.g., for use in various applications, e.g., as a microlithography DUV light source have demonstrated performance and stability that were unattainable by the traditional single oscillator line-narrowed laser design.
- the MOPA design uses two discharge chambers.
- the master oscillator (MO) generates an extremely line-narrowed laser beam, e.g., at around 193 nm for an ArF laser, with a relatively small energy content, typically around 1 mJ.
- the power amplifier (PA) amplifies the laser pulse from the MO.
- the beam from the MO can, e.g., traverse the power amplifier's gain region, e.g., making one round trip, e.g., timed to amplify some portion of the output pulse of the MO by initiating and sustaining a discharge while that portion of the MO output pulse is traversing the PA within the lasing medium between the electrodes of the PA with lasing occurring almost exclusively at the line narrowed center wavelength of the MO output.
- the extremely narrow output spectrum of the XLA-100 enables scanners with an NA greater than 0.9. Higher average output power improves the wafer throughput of the scanner. In addition, extended lifetimes of discharge chambers help to control the operating cost. Variable energy and repetition rate capabilities provide scanners with a freedom to use the optimum laser operating modes for any processes, thus always ensuring the best results.
- MOPA system for certain applications, e.g., as a drive laser for a laser produced plasma (“LPP”) extreme ultraviolet (“EUV”), sometimes called soft x-ray or a low temperature polycrystalline silicon laser annealing apparatus, e.g., for the manufacture of thin film transistors, e.g., for flat panel display uses, demand, among other things, higher pulse repetition rates.
- LPP laser produced plasma
- EUV extreme ultraviolet
- soft x-ray sometimes called soft x-ray
- a low temperature polycrystalline silicon laser annealing apparatus e.g., for the manufacture of thin film transistors, e.g., for flat panel display uses, demand, among other things, higher pulse repetition rates.
- this may be, e.g., to produce plasma formations, e.g., from liquid droplet targets, at a sufficiently high rate to extract enough wattage from relatively low energy plasmas for, e.g., microlithography use, and in the latter to deliver high enough laser power to a relatively large workpiece (hundreds of cm on a side) for effective throughput of a laser annealing apparatus.
- Cooling electrical components e.g., in a solid state pulse power system, e.g., magnetic switch components is discussed in U.S. patent application Ser. No. No. 10/607,407, filed Jun. 25, 2003, entitled “Method and Apparatus for Cooling Magnetic Circuit Elements,” Attorney Docket No. 2003-0051-01, U.S. Pat. No. 5,448,580, entitled AIR AND WATER COOLED MODULATOR, issued to Birx, et. al. on Sep. 5, 1995, and U.S. Pat. No. 6,240,112, entitled HIGH PULSE RATE PULSE POWER SYSTEM WITH LIQUID COOLING, issued to Partlo, et al. on May 29, 2001 and U.S. Pat.
- a high pulse repetition rate gas discharge laser system pulse power system magnetic reactor may comprise a housing comprising a core containing compartment between an inner wall of the housing, an outer wall and a bottom wall of the housing; a cooling mechanism operative to withdraw heat from the at least one of the inner wall, outer wall and bottom of the housing; at least two magnetic cores contained within the core containing compartment; a cooling fin disposed between each of the at least two magnetic cores; and a thermal conductivity enhancement mechanism intermediate at least one of each respective cooling fin and each respective core and a respective one of the inner wall, the outer wall or the bottom wall, the thermal conductivity enhancement mechanism comprising a band comprising a plurality of torsion spring or leaf spring elements each in contact with the respective one of the cooling fin and/or core and the respective inner wall, outer wall or bottom wall between which it is intermediate.
- the thermal conductivity enhancement mechanism may comprise a band comprising a plurality of interconnected torsion or leaf spring elements or a combination of such torsion or leaf spring elements.
- the thermal conductivity enhancement mechanism band may comprise multiple contact points with distributed constriction resistance.
- the thermal conductivity enhancement mechanism may comprise a band comprising a plurality of interconnected torsion or leaf spring elements or a combination of such torsion or leaf spring elements contained within a dovetailed groove in the respective one of the inner wall, outer wall and bottom wall.
- the thermal conductivity enhancement mechanism comprises a MultilLam electrical contact strip.
- the magnetic reactor may comprise a housing comprising a core containing compartment between an inner wall of the housing, an outer wall and a bottom wall of the housing; a cooling mechanism operative to withdraw heat from the at least one of the inner wall, outer wall and bottom of the housing; at least one two magnetic cores contained within the core containing compartment each respective core being wound on a mandrel contained within the core containing compartment; a cooling fin disposed between each of the at least two magnetic cores; a thermal conductivity enhancement mechanism intermediate at least one of each respective cooling fin and each respective core and a respective one of the inner wall, the outer wall or the bottom wall, the thermal conductivity enhancement mechanism comprising a band comprising a plurality of torsion spring or leaf spring elements each in contact with the respective one of the cooling fin and/or core and the respective inner wall, outer wall or bottom wall between which it is intermediate.
- the mandrel comprising a material with better thermal conductivity than stainless steel, e.g., a beryllium copper alloy.
- the gas discharge laser system may comprise a master oscillator comprising: a chamber; a first pair of electrodes contained within the chamber defining a first discharge region between the first pair of electrodes; a second pair of electrodes contained within the chamber defining a second discharge region between the first pair of electrodes; a pulsed power system providing charging voltage in parallel to the first pair of electrodes at a pulse repetition rate and to the second pair of electrodes at the pulse repetition rate alternating between the first pair of electrodes and the second pair of electrodes; a first amplifier laser receiving seed laser pulses at the pulse repetition rate generated in the first discharge region; a second amplifier laser receiving seed laser pulses at the pulse repetition rate generated in the second discharge region.
- the system may comprise a rotary gas flow fan having a longitudinal axis generally in parallel with first discharge region and the second discharge region whereby the single fan provides sufficient gas movement to replenish the gas in the first discharge region and the second gas discharge region, respectively, between discharges between the respective first pair of electrodes and the second pair of electrodes.
- the system may comprise a first output laser light pulse beam axis defined by the first pair of electrodes and a second output laser light pulse beam axis defined by the second pair of electrodes; the first output laser light pulse beam not overlapping the second laser output light pulse beam longitudinally or traversely.
- the system may comprise high voltage pulse power system supplying at least one charging voltage to provide for an electrical discharge between the first pair of electrodes and for an electrical discharge between the second pair of electrodes in a tic-toc fashion and for timing the discharge in the first amplifier laser to the discharge between the first set of electrodes and timing the discharge in the second amplifier laser section to the discharge between the second pair of electrodes.
- the system may comprise a gas discharge chamber; a hot chamber output window heated by the operation of the gas discharge laser chamber; an output laser light pulse beam path enclosure downstream of the hot chamber window and comprising an ambient temperature window; a cooling mechanism cooling the beam path enclosure intermediate the output window and the ambient window, and may include an intermediate window intermediate the hot window and the ambient window, the intermediate window and the ambient window forming a cooled section of the beam enclosure, with the windows are at or near Brewster's angle and with a section of the beam path enclosure between the hot window and the intermediate window is purged.
- the cooled section of the beam path enclosure may be under a vacuum.
- the system may comprise a squirrel cage blower fan; a first cutoff member having a first side on the discharge side of the cutoff and a second side on the opposite side from the cutoff side; a vortex shifting pocket on the second side of the cutoff shaped to substantially prevent the formation of a vortex on the discharge side of the cutoff by causing the vortex to preferentially form within the vortex shifting pocket.
- a second cutoff member may form an opposing end of the vortex shifting pocket., and each of the first and second cutoff members may form a sharp edge.
- the vortex shifting pocket may be formed by only the trailing cutoff 642 , e.g., with the leading vortex shifting pocket cutoff 641 or substantially all thereof removed, leaving the opening 640 ′ illustrated schematically in FIG. 18 or be made with a relatively thinner leading edge and a plurality of openings through teh cutoff, as illustrated schematically in the plan view of FIG. 19 .
- FIG. 1 shows a perspective view of an illustrative saturable reactor magnetic switch housing according to aspects of an embodiment of the present invention
- FIG. 2 shows a cross sectional view of the switch as illustrated in FIG. 1 with internal components assembled according to aspects of an embodiment of the present invention
- FIG. 3 shows a perspective view of a saturable reactor magnetic switch housing top according to aspects of an embodiment of the present invention
- FIG. 4 shows an exploded view of the indicated portion of FIG. 2 ;
- FIGS. 5A and 5B show an illustrative embodiment of a thermal conductivity enhancement mechanism according to aspects of an embodiment of the present invention
- FIG. 6 shows a blown up and cross sectional view of the thermal conductivity enhancement mechanism of FIGS. 5A and 5B ;
- FIG. 7 shows schematically a plan view of an illustrative high repetition rate excimer laser system according to aspects of an embodiment of the present invention
- FIG. 8 shows schematically and partly in cross section an illustrative laser exit window arrangement according to aspects of an embodiment of the present invention
- FIGS. 9A-9C show respectively two side views and one end view of an illustrative preionizer ground rod according to aspects of an embodiment of the present invention.
- FIG. 10 shows an illustrative version of a discharge region of a gas discharge laser chamber according to aspects of an embodiment of the present invention
- FIG. 11 shows schematically and partly in cross section portions of the laser chamber illustrated in FIG. 7 ;
- FIG. 12 shows a cross-sectional view of an embodiment of a saturable magnetic switch according to aspects of an embodiment of the present invention
- FIG. 13 shows a perspective exploded view of a portion of a blower fan according to aspects of an embodiment of the present invention
- FIG. 14 shows a side view of the blower fan of FIG. 13 ;
- FIG. 15 shows a cross sectional view taken along lines 15 of FIG. 14 ;
- FIG. 16 shows illustrative details of a portion of the cross-sectional view of FIG. 15 ;
- FIG. 17 shows a more detailed view of a portion of the blower fan illustrated in FIG. 13 .
- FIG. 18 illustrates partly schematically and partly in cross-section an alternate to the embodiment of FIG. 10 according to aspects of an embodiment of the present invention.
- FIG. 19 illustrates partly schematically and partly in cross-section an alternate to the embodiment of FIG. 10 according to aspects of an embodiment of the present invention.
- reactor cooling such as shown for example in the above referenced co-pending application “Method and Apparatus for Cooling Magnetic Circuit Elements” is of assistance in dealing with such thermal control issues, however applicants propose certain improvements.
- a step in accomplishing better thermal control relates to the magnetic core assembly itself.
- the core is typically would from very thin ( ⁇ 0.5 mil) magnetic tape which can be insulated for electrical reasons, the thermal conductivity can, therefore, be relatively poor and especially in the radial direction.
- Air voids or at best areas filled with insulating fluid, e.g., oil, between each winding turn (the housing and mandrel system) can also reduce the thermal conductivity in the radial direction.
- insulating fluid e.g., oil
- Such cooling fins have been proposed to be manufactures in a variety of ways, e.g., as an integral part of the switch center mandrel (machined into the mandrel).
- the magnetic cores can then either be wound around the mandrel or wound on an additional mandrel and slid down over the switch center mandrel.
- the disadvantage of such an approach is that, e.g., the core materials often require high temperature annealing after winding and this is not always compatible with mandrel materials which possess low thermal conductivity (e.g., stainless steel alloys with materials such as Nanocrystalline alloys like FINEMET, manufactured by Metglas Inc. of Conway, S.C.
- the disadvantage is that there then exists a gap between the actual mandrel and the wound mandrel, which can be filled with air or insulating thermally conductive fluid like oil, in either case detracting from the thermal conductivity in the radial direction from the cores to the actual mandrel.
- the fins could be manufactures along with the cores as donut-shaped members and slid down over the center mandrel, assembled with fins interspersed between each set of two cores, and with thermal contact between the fins and the water cooled center mandrel accomplished, e.g., with an intentional interference fit, the use of shims between the cores and fins and the center mandrel wall or the use of other interface materials, e.g., multi-contact strips similar to the “finger stock” material used, e.g., for electrical contact connections.
- the magnetic switch assembly may comprise a magnetic switch housing 22 , which may include a housing inner wall 24 , having a housing inner wall 25 inner surface 26 and an outer surface 28 , together defining a magnetic core and a housing outer wall 21 , having a housing outer wall inner surface 23 , together defining a core compartment 29 having a bottom 30 .
- a plurality of dovetail grooves 40 each formed by a respective pair of dovetails 48 , which may be machined into the side of the housing inner wall 25 outer surface 28 , and may number four grooves 40 accommodating, e.g., four magnetic cores 53 , which may be comprised of a suitable material as explained in more detail below and may be wound onto a respective core mandrel 46 and inserted into the core compartment 29 .
- the cores 53 may be stacked in the core compartment 29 with, e.g., an insulator 52 , e.g., made of “Kapton MT,” a polyimide film possessing 3 ⁇ the normal thermal conductivity of standard “Kapton HN,” insulating the cores 53 from the housing 22 outer wall 21 and from the winding cooling fins 54 and from a top plate 55 .
- the cores 53 may be individually wound on each respective core mandrel 46 and each pair separated by a core winding cooling fin 54 , made, e.g., of a copper alloy or other material with high thermal conductivity.
- a high voltage bus may be formed the magnetic switch housing 22 top bus 55 formed by the top plate 55 of the housing 22 , which may be connected, e.g., to a source of high voltage, e.g., a capacitor bank, through another top plate 57 .
- the high voltage source may be formed by a capacitor or capacitor bank (not shown) electrically connected to the plate bus 57 that will pass on its charge when the magnetic switch 20 closes upon saturation of the cores 53 to a downstream portion of the circuit, e.g., a transformer (not shown), connected, e.g., to a transformer bus plate 58 .
- An insulator 56 which may be mineral filled Teflon, e.g., with mica as the mineral, e.g., made under the name “Fluorosint” by Quadrant Engineering Plastic Products of Reading, PA may isolate the high voltage plates 55 , 57 from the transformer plate 58 and together with the Kapton insulation between the top and the bottom of the cores 53 insulating the top core 53 from the plate 55 and the bottom core 53 from the core container bottom 30 along with the Kapton insulating the cores 53 from the housing outer wall 23 forming a current loop from the high voltage bus 57 through the saturable reactor top bus 55 down the housing inner wall 25 and up the housing outer wall 21 to the transformer bus 58 , e.g., for an inductive saturable magnetic reactor 20 upstream of the transformer (not shown), e.g., in a solid state switched pulsed power system (not shown) such as are used in laser systems of the gas discharge variety as sold by applicants' assignee for uses, e.g., in integrated circuit manufacturing
- the magnetic reactor switch 20 may have a thermal conductivity enhancement mechanism 60 .
- the thermal conductivity enhancement mechanism 60 may comprise a strip or band of mechanical connectors 42 or the type manufactured by Multicontact AG of Norway with offices in Santa Rosa, Calif., such as the louver contact shown in cross section about, e.g., a longitudinal axis of such a strip 60 , illustrated in FIG. 6 .
- the thermal conductivity enhancement mechanism 60 may include, e.g., as illustrated in FIG. 6 , spring-elements 62 , such as the louvered shaped spring elements 62 there illustrated having contact points 66 , 68 .
- the strip 62 may be installed within a respective one of the dovetailed grooves 40 such that, e.g., contact points 66 contact a respective one of the magnetic cores 53 or the magnetic core mandrel 46 and the contact points 68 contact the housing inner wall 25 outer surface 28 .
- the strips may also conveniently have machined onto them tabs 64 , which may assist in holding the strips within the respective groove 40 , e.g., by interacting with the respective dove tail 48 on either side of the groove 40 and also, e.g., assist in providing the spring loading holding the thermal conductivity enhancement mechanism 60 in place and contacting the respective surfaces for good thermal conductivity.
- thermal conductivity enhancement mechanism may comprise such a strip 60 without taps 64 or in a leaf spring configuration, both of which are also as sold by Multicontact AG, and as described in a Multicontact brochure entitled “The Multilam Principle,” available at multicontact.com, the disclosure of which is hereby incorporated by reference.
- the tabs may also be replaced with longitudinally extending lip (not shown) such a appear on some of the models LAO, LAOG (illustrated in FIGS. 5A and B and 6 ), LAIA, LAIB, LAII, LA-CU, LAIII, LAIV, LAV and LAVII of the connectors sold by Munticontact any of which may be suitable for the thermal conductivity enhancement mechanism 60 .
- magnetic core arrangement 80 may include a thicker winding mandrel 82 , e.g., of about 5 cm from inner diameter to outer diameter, comprising, e.g., a material such as Beryllium Copper alloy which has a thermal conductivity of 120-150 BTU/(sq ft-ft-hr-F), an improvement over stainless steel, and a pair of cores 84 , which may comprise FineMet wound on the respective mandrel 82 with the cores 84 separated by a fin 85 , e.g., a generally flat donut shaped copper fin, e.g., of about 0.065 inches in thickness.
- a thicker winding mandrel 82 e.g., of about 5 cm from inner diameter to outer diameter
- a material such as Beryllium Copper alloy which has a thermal conductivity of 120-150 BTU/(sq ft-ft-hr-F)
- a pair of cores 84 which may comprise FineMet wound on the
- the compartment 29 has a compartment inner diameter 86 and a compartment outer diameter 88 and the remaining space around the cores 84 may be filled with a fluid, e.g., an insulating and heat transmitting fluid 90 such as Brayco Micronic 889 fluid manufactured by Castro, which of course can be employed in the embodiment of FIGS. 1-4 .
- a fluid e.g., an insulating and heat transmitting fluid 90 such as Brayco Micronic 889 fluid manufactured by Castro, which of course can be employed in the embodiment of FIGS. 1-4 .
- the cores may be essentially surrounded by a water cooled boundary, formed by the housing inner wall outer surface 28 , the compartment bottom 30 and the housing outer wall inner surface 23 , and by the top plate 55 , with at least one and up to all of the housing inner wall 25 , outer wall 23 , top plate 55 and housing bottom wall 32 having formed in them cooling fluid channels (not shown) as is taught in the above referenced co-pending patent application.
- cooling fluid channels not shown
- the core compartment 29 may also be lined with, e.g., an insulator 92 , such as Kapton along the housing outer wall inner surface 23 and the housing bottom 30 and between the respective cores 84 and the fin 85 .
- a stainless steel band 94 may hold the respective cores 84 in place on the respective mandrel 82 .
- Another insulator layer such as Cirlex, manufactured by Fralock, a Division of Lockwood Industries and selected because it is a laminate of individual Kapton insulator sheets providing more voltage insulation that can be obtained with a single sheet of Kapton material, may insulate the top core 84 from the top plate 55 , as shown in FIGS. 1-4 .
- a thermal conductivity enhancement mechanism 60 may be interposed between the respective mandrels 82 and the housing inner wall 25 , such as an LAOG Multilam electrical connector as discussed above.
- the presently used PDA readout is too slow since a 6 KHz readout requirement for the presently used readout of 1024 pixels is longer than the 167 ⁇ sec cycle period at 6 KHz. Because a faster clock rate reduces the pixel integration time, there may not be enough sensitivity, which must be at least as good at the higher repetition rate or, e.g., the etalon fluence would be too high for satisfactory operating lifetime. It would also be desirable to have the ability to integrate multiple shots between read scans, which can be useful for optical integration. In addition sensor responsiveness in relation to dark current must be stable with respect to DUV photons.
- the three separate sections of the detector can then be clocked out in series with respect to each 512 pixels, but in parallel with each other.
- the third 512 pixel section could also be on a separate integrated circuit for coarse measurement.
- the analog signals can then be signal processed in the analog domain the same as presently on the controller board, e.g., amplification, AGC for dynamic range adjustment, etc.
- This can be done similarly to the current BDU BAM, e.g., as discussed in an above referenced co-pending Cymer patent application, which clocks out beam pointing in the horizontal and vertical in parallel, except that the two 512 sections on the single integrated circuit substrate can be centered at the focus of the beam from the etalon and will be close enough on the single substrate to not suffer from an inability to identify the center of the interference pattern and thus the desired interference fringe.
- the added advantage increased resolution is obtained since 1024 pixels, read out in parallel for each of two 512 pixel sections can be used for fine measurement vs. 610 in currently utilized wavemeters and the additional 512 used for the course measurement vs. 414 today.
- Current software can be used to track the fringe peaks across a scan window within the separate 512 for fringes on either side of the center as wavelength changes.
- PDA upgrades for 6 KHz must meet certain criteria, namely cost effectiveness, DUV responsiveness, etalon lifetime which is a function of DUV fluence, which can increase with pulse repetition rate at the same level of required pixel sensitivity, adequate SNR, which can decrease with decreasing DUV intensity per pixel, linearity, mentioned below, dynamic range, related to dark current, well depth and capacitance, DUV hardness, e.g., ⁇ X % delta R/ ⁇ 30 kJ/cm 2 , i.e., over 12 B shots, ease of implementation, readout speed and spatial resolution, i.e., pixel size and FPN.
- non-linearity issues these can depend upon the choice of detector or the combination of the detector and read out electronics. It can depend upon how much non-linearity can be tolerated and of what kind. Applicants propose to address these issues in the context of a 6 KHz system by using the time savings to slow pixel clocking and increase signal/noise ratio by reducing integration error(s).
- Shuffling around 2048 words of data takes a lot of time, however, but keeping the same magnification one can get better resolution with more pixels, such that 1024 ⁇ 4 without masking can be an advantage.
- Splitting the vertical can enable picking the right diameter without complicated discrimination problems.
- a drive laser for a laser produced plasma it may be desirable to produce, e.g., in a tic-toc mode seed laser pulses into, e.g., a plurality of, e.g., two amplifier lasers, e.g., in a master oscillator-power amplifier (“MOPA”) or master oscillator power oscillator (“MOPO”) configuration.
- MOPA master oscillator-power amplifier
- MOPO master oscillator power oscillator
- Gas discharge lasers e.g., excimer lasers may have certain advantages over solid state seed lasers, such as being diffraction limited and being easier to match with an amplifying laser section that is of the same type, e.g., ArF, KrF, XeCl, XeF or CO 2 an issue with employing such a system, however, is that it is proving difficult to provided effective operation of gas discharge seed lasers a 6 KHz much less well above that pulse repetition rate.
- Part of the problem in achieving such pulse repetition rates is the amount of power that must be provided to the chamber blower fan necessary to achieve arc free blower speed for the increase of pulse repetition rate from currently operating lasers systems at 4 KHz to 6 KHz, much less significantly above that pulse repetition rate.
- Higher blower motor speeds in addition can create acoustical problems within the chamber that can affect laser output light pulse beam pulse parameter quality and stability.
- RPMs blower motor rotational speed
- LPP laser produced plasma
- EUV extreme ultraviolet
- LTPS low temperature poly-silicon
- PA power amplifiers
- PO power oscillator
- FIG. 7 there is shown is schematic and partially block diagram form a plan view of a proposed pulsed gas laser oscillator 300 which may have two parallel outputs 302 , 304 (two channels) and may be configured to operate in at least a master oscillator 300 tic-toc mode.
- a gas discharge chamber 310 of the master oscillator 300 may have at least two sets of elongated electrodes 312 , 314 that may form two independent discharge volumes shifted, e.g., both in the in transversal and longitudinal directions in respect with an axis of laser cavity, in effect forming two cavities with two separate optical axes 316 , 318 , one of which may also form the aforementioned axis of the cavity 310 .
- each of the discharges can serve as an independent gain media for generating two independent laser beams 302 , 304 .
- the gas flow and thermal load requirements for the chamber can be satisfied with a gas movement blower fan 320 capable of only a 6 KHz operation arc free blower speed and other such fan performance requirements at the 6 KHz pulse repetition rate level.
- The-system however can allow for 12 KHz output, e.g., in a tic-toc regime.
- An HV pulse power module 330 which can easily be made with existing technology to run at a total of a 12 KHz rate of charging the charging capacitors, e.g., in two parallel solid state pulse power modules operating in parallel to supply a commutator (not shown) and compression head(not shown), as is known in the art, for each of the respective pairs of electrodes 312 , 314 , but has the same output power requirements as for a 6 kHz regular chamber for each of the respective charging capacitors.
- pulse power system may have a single charging capacitor being charged to the appropriate voltage at the rate of, e.g., 12 KHz, with the split in the pulse compression circuits (not shown) into parallel circuits either to form two parallel commutator sections each feeding a separate compression head or to form two parallel compression heads downstream of the transformer in the separate compression heads for each respective pair of electrodes 312 , 314 . It will also be understood that in the future if and when solid state switches become able to handle the voltages needed for gas discharge laser operation the transformer to step up the voltages passed by current switches may not be needed.
- the separate compression heads can be timed to run at, e.g., 6 KHz and alternately fired to generate the beams 316 and 318 at, e.g., 6 KHz and together at, e.g., 12 KHz output laser light pulse beam pulses from the oscillator amplifier 300 .
- the cavity of the master oscillator laser 300 can thus be formed by a single resonator elements 304 , 340 , which serves both channels 316 , 318 .
- the oscillator 300 includes a mode selector 340 (line narrowing unit) to allow it to operate on a single line or Rmax mirror to operate in multilane regime.
- a combination of an output telescope 350 and an aperture plate 352 with two apertures downstream of an output coupler 354 can allow for the generation of two identical, good quality beams, which can then be used to pump two amplifier laser sections, e.g., two power amplifiers 360 , 362 .
- Suitable maximum reflectivity mirrors 370 , 372 , 374 , and 376 made, e.g., of CaF 2 coated with high reflectivity coating for the appropriate wavelength to get the desired maximum reflectivity at the selected wavelength can be use to direct the outputs of the telescope 350 to the respective one of the amplifying laser section, e.g., PA 360 , 362 .
- an output laser light pulse beam path contained, e.g., in a laser system 380 having a chamber 412 producing an output laser light pulse beam 382 , traveling along a beam path 400 through a beam enclosure 402 , e.g., to downstream optics (not shown).
- the beam enclosure 402 may have a first window 404 , a second window 406 and a third window 408 , each of which may be at, e.g., Brewster's angle or near thereto for purposes of reducing reflective losses in the respective windows 404 , 406 , 408 .
- the laser beam 382 can travel through a relatively hot window 408 from the laser chamber 412 to the window 408 , through the window 406 to a cooled section of the beam enclosure 402 and then to the window 404 in a region of the beam enclosure that is operating at a relatively cool temperature, e.g., at about room temperature.
- the vacuum tube could be water cooled to reduce heat transfer from the chamber 412 to the ambient portion of the beam tube 402 . According to aspects of an embodiment of the present invention there is enabled the Reduction in the amount of beam disturbance due to thermal boundary layers in chamber windows for a laser operating at or about 6 KHz.
- another issue to be addressed in increasing gas discharge laser pulse repetition rate e.g., for ArF, KrF, XeCl or XeF laser systems is the large increase in temperature in a chamber with a pulse repetition rate of around 6 KHz as opposed to around 4 KHz and also fluctuations with changing duty cycle may cause higher peak transients than before until cooling systems, e.g., the currently used heat exchangers or, if necessary redesigned ones to handle more thermal load can bring the chamber temperature back to a normal operating range.
- the chamber then can go through thermal expansion and contraction cycles, and components that are attached to, e.g., two opposing walls in the chamber or even just inserted into recesses in one or both of such walls, which may lead to failure during a relatively very short lifetime as compared to the same operation over a relatively much longer lifetime at a pulse repetition rate of around 4 KHz of below.
- an longitudinally and axially compliant ground rod 270 that will tolerate significant differential thermal expansion (being made of a brass alloy, e.g., 26000 brass, half hard (H02) temper per ASTM B19 or B36, and still maintain it mechanical integrity and electrical contact.
- a brass alloy e.g., 26000 brass, half hard (H02) temper per ASTM B19 or B36
- This problem like all internal chamber issues, is also complicated by the small list of compatible materials allowed for the construction of chamber elements in a gas discharge laser containing fluorine of chlorine gas.
- the spring section(s) 284 can be totally within the cylindrical ceramic PI tube (not shown), or substantially so, with the ends of the spring(s) 284 firmly held in longitudinal and axial alignment and since the very ends 290 , 292 of the ground rod 270 will be clamped into the chamber upper chamber half (not shown), the PI tube (not shown) can be made to remain stationary and well supported and also, by absorbing the stress along the longitudinal axis due to differential thermal expansion and also given some axial flexibility due to the spring(s) 284 , will not tend to bow in the middle, thus catastrophically failing the ceramic preionizer tube (not shown).
- a preionizer tube ground rod 270 may comprise an elongated wide radius portion 272 , extending, e.g., for the length of a cathode shim, which can extend essentially along the length of the cathode, e.g., about 33 cm, and which creates with the ground rod 270 and the ceramic preionizer tube within which the ground rod 270 snuggly fits, a capacitor across which a voltage builds when the cathode is charged to the peaking voltage from a peaking capacitor (not shown), causing preionization to occur.
- each end of the ground rod 270 may be a narrowed portion 274 , 276 , which can serve, e.g., to insulate the ground rod from external voltage in those regions of the ground rod 270 , in order to, e.g., prevent preionization discharge in that region of the preionization tube (not shown).
- the narrowed portion 274 and the narrowed portion 276 may, respectively be, e.g., intermediate the ends of the elongated center portion 272 and a respective wide radius end portion 280 and wide radius end portion 278 .
- One or both of the wide radius end portion 280 and wide radius end portion 278 may have formed therein a spring coil portion 284 .
- Each respective end of the ground rod 270 may have formed therein a set screw protrusion 290 and a set screw protrusion 292 , which, with appropriate set screws (not shown), may be utilized to secure the ground rod 270 to the chamber upper half adjacent the cathode shim (not shown).
- One or more anti-twist arms 286 may be fit into a slot (not shown) in the preionizer tube (not shown) to prevent
- the machining of the spring is accomplished by plunging a standard flat bottom end mill radially into expanded radius end portion, e.g., 280 of the ground rod 270 , past its center, to such a depth which leaves the desired resulting spring 284 thickness.
- the diameter of the cutter is then equal to the gap between successive spring turns.
- the ground rod 270 can thus simultaneously be rotated and traversed axially to describe a helical cut 285 that then leaves behind the finished form of the spring 284 .
- the end mill diameter and traverse rate may be chosen to ensure the resulting form of the spring 284 will be, e.g., a helical spring-like structure as is illustrated in FIG. 9 .
- FIG. 10 according to aspects of an embodiment of the present invention applicants propose to modify aspects of the chamber 610 in order to better accommodate 6 KHz and above operation. Applicants propose to reduce or eliminate the impact of vortices created at high RPM, e.g., around 4000 RPM fan 634 operation and the cut down on acoustic reflections from near in structures to the discharge region of the chamber 610 between the cathode 612 and the anode 614 .
- the chamber as illustrated partly in cross section in FIG.
- anode support bar 620 holding the anode 614 in opposition to the cathode 612 with a plurality of current returns 616 , in electrical contact with the anode support bar 620 and the anode 614 .
- Also mounted on the anode support bar may be, e.g., an upstream fairing 622 and a downstream fairing 624 and a bottom piece 630 , each of which may, e.g., be made of an insulator, e.g., ceramic material.
- the bottom piece may be formed, e.g., with a vortex shifting pocket 632 that may serve, e.g., to shift a vortex that applicants have determined forms at the cutoff 640 where the bottom piece 630 terminates, e.g., in a relatively sharp or pointed longitudinally extending edge 641 in the vicinity of the fan 634 , from the discharge region side of the cutoff 640 to within the vortex shifting pocket 632 .
- the bottom piece 630 may also have another cutoff 642 at the opposite extent of the vortex shifting pocket 632 .
- the distance between the cutoff 640 and the cutoff 642 may be selected to be d, where 0.5r ⁇ d, 1.0r, with r equal to one half the outer diameter of the fan 634 .
- an alternative approach to forming the vortex shifting pocket may be to remove the portion of the bottom piece 630 forming the cutoff 640 and only leave the pocket 632 and the lower cutoff 642 , as illustrated by way of example in FIG. 10 .
- FIG. 10 Also illustrated by way of example in FIG. 10 are a pair of baffles, a multifaceted upstream baffle 640 and a multifaceted downstream baffle 642 , each having, e.g., facets that are of irregular size and shape laterally, as illustrated in FIG. 10 and also (not shown) of irregular size and shape in the longitudinal direction, extending, e.g., essentially the length of the cathode 612 .
- FIG. 18 illustrates partly schematically and partly in cross-section an alternate to the embodiment of FIG. 10 according to aspects of an embodiment of the present invention
- FIG. 19 illustrates partly schematically and partly in cross-section an alternate to the embodiment of FIG. 10 according to aspects of an embodiment of the present invention.
- the vortex shifting pocket 632 ′ may be formed by only the trailing cutoff 642 , e.g., with the leading vortex shifting pocket cutoff 641 or substantially all thereof removed, leaving the opening 640 ′ illustrated schematically in FIG. 18 or be made with a relatively thinner leading edge 656 and a plurality of openings 652 through the cutoff, as illustrated schematically in the plan view of FIG. 19 .
- the openings may be formed by a plurality of struts 650 , e.g., formed, e.g., of metal at the end of the anode support bar 620 , or alternatively may be formed, e.g., from an insulator, e.g., ceramic material, e.g., as an extension of the bottom piece 630 as illustrated in FIG. 10 or an extension of the upstream faring 622 as illustrated partly schematically in plan view in FIG. 19 .
- an insulator e.g., ceramic material
- the vortex may form at the fan 634 cutoff leading edge 565 thin boundary opening 640 and then be cause to transfer into the pocket 632 through the openings 652 , thus, e.g., removing the il effects of the vortex existing in any substantial form between the fan 634 and the upstream edge of the anode 614 .
- applicants have addressed the problem of providing arc free blower speed for a laser system operating at around 6 KHz or above without an undue increase in the power consumption of the blower motor(s) which scales linearly with length, i.e., number of blades and exponentially by about a cubed function with increase in blower fan revolutions per minute.
- the blower motor(s) which scales linearly with length, i.e., number of blades and exponentially by about a cubed function with increase in blower fan revolutions per minute.
- applicants believe there would be approximately a 50% cubed requirement for increase and even if less, such as a 50% squared, the increase in blower motor power required and therefore the increase in the size of the motor required is not an acceptable alternative.
- applicants have determined a solution to this problem lies in the use of a blower fan with blade modifications that enable higher blower gas movement capability with a much more modest increase in blower motor speed.
- the multiple nested fans would be fastened to the end hubs creating the complete assembly and avoiding, e.g., soldering or brazing the pieces together.
- a squirrel cage rotary fan 450 which may comprise a first outer portion 452 , comprising a plurality of sections 454 , e.g., 18 sections 454 , each separated by a section bulkhead 455 , and each incorporating a plurality of blades 456 , which as has been discussed in patents issued to applicants assignee can be arranged in a variety of ways, including alternating segmented generally helical shapes, having different numbers of blades in different sections and/or different blade cross sections and/or sizes in the same of in different sections, or the like, for the purposes, e.g., of randomizing the acoustic impact within the chamber due to operating the squirrel cage fan 450 .
- FIGS. 13-17 The specific embodiment of FIGS. 13-17 is known as a double chevron or double helical fan blade 456 arrangement in which the fan blades are arranged such that acoustic impacts, e.g., on the uniformity of the discharge in the discharge region between the laser electrodes as a result of the fan turning can be reduced.
- the fan 450 may also comprise a second inner portion 460 , also having sections 462 , which may correspond in size and number and position along the longitudinal axis of the squirrel cage rotary fan 450 as the sections 462 , such as the same 18 sections 462 , each separated by a section bulkhead 465 , and may comprise within each section 462 a plurality of blade extensions 464 .
- the blade extensions 464 may correspond to and form an extension toward the radial centerline axis of the squirrel cage fan 450 of the blades 456 in the outer portion 452 .
- the two portions may be machined according to the currently used technology, since the blade pockets machined out between blades, illustrated in more detail in FIG.
- each portion 452 , 460 remain within currently attainable dimensions, e.g., as to lengths and aspect ratios and with a degree of tolerance with currently available computer aided machine tools such that the seam 466 between the two when nested together, as seen in FIG. 16 , the inner portion 460 inside of the outer portion 452 barely visible to the naked eye and of little or no impact on performance as if the blade formed by the respective blade portions 456 , 464 were of a single machining construction.
- the outer diameter of the inner portion 460 may be machined to 3.871′′ ⁇ 0.001 and the inner diameter of the outer portion 452 may be machined to 3.875′′ ⁇ 0.001, leaving a difference of 0.004 ⁇ 0.002 between the two.
- the outer diameter of the end bulkheads 467 of the outer portion 460 and the section bulkheads 455 may be, e.g., 5.000′′ ⁇ 0.001, with the blades 456 at the outer end extending to within about 0.001 of this outer diameter.
- the inner diameter of the inner section 460 may be machined to 2.75. as can be seen in FIG. 16 , the blades 454 in the outer portion 452 may be cut to have an inner radius of 0.883′′ and an outer radius of 0.915′′ from a point along a respective one of 23 radians of 15.65° centered on a point along a concentric circle having a radius of 1.676 near the midpoint between the inner diameter and outer diameter of the inner portion 464 (not shown in FIG.
- next successive blade according to this illustrative embodiment being cut with the same inner and outer diameters from a point centered on the opposite side of the same radian.
- those same points may be used to cut the blade extensions 464 in the inner section 460 to the same inner surface radius and outer surface radius.
- the outer and inner portions 452 , 460 may be conveniently joined together at the end bulkheads 467 , 468 , e.g., with an end plate 458 and screws 459 .
- the screw holes 461 in the end plate 458 for the outer section 452 and 463 for the inner portion 460 may be machined to a tolerance to provide no more than a maximum of 0.003′′ mismatch between the adjacent blade faces 480 on the blade extensions 464 of the inner portion 460 , as illustrated in FIG. 17 , and those (not shown) on the blades 456 of the outer portion 452 .
- FIG. 17 also illustrates rounded portions 490 that may be formed, e.g., when a rounded point drill bit is used to formed the pockets 492 are cut out to machine the blades 464 .
- the blades 456 , 464 may be randomized in position from section 454 , 462 to section 454 , 462 starting, e.g., from the right as seen in FIG. 14 to the left from some arbitrary point identified as 0.00 20 according to, e.g., the displacements shown in Table 1.
- TABLE 1 RELATIVE SECTION ANGLE No. (DEGREES) 1 0.00 2 6.96 3 ⁇ 1.74 4 5.22 5 ⁇ 3.48 6 3.48 7 ⁇ 5.22 8 1.74 9 ⁇ 6.96 10 0.87 11 ⁇ 6.09 12 2.61 13 ⁇ 4.35 14 4.35 15 ⁇ 2.61 16 6.09 17 ⁇ 0.87 18 7.83
- a high pulse repetition rate (e.g., 6 KHz and above) gas discharge laser system pulse power system magnetic reactor which may comprise a housing comprising a core containing compartment between an inner wall of the housing, an outer wall and a bottom wall of the housing; a cooling mechanism operative to withdraw heat from the at least one of the inner wall, outer wall and bottom of the housing; at least two magnetic cores contained within the core containing compartment; a cooling fin disposed between each of the at least two magnetic cores; and a thermal conductivity enhancement mechanism intermediate at least one of each respective cooling fin and each respective core and a respective one of the inner wall, the outer wall or the bottom wall, the thermal conductivity enhancement mechanism comprising a band comprising a plurality of torsion spring or leaf spring elements each in contact with the respective one of the cooling fin and/or core and the respective inner wall, outer wall or bottom wall between which it is intermediate.
- the thermal conductivity enhancement mechanism may comprise a band comprising a plurality of interconnected torsion or leaf spring elements or a combination of such torsion or leaf spring elements.
- the thermal conductivity enhancement mechanism band may comprise multiple contact points with distributed constriction resistance.
- the thermal conductivity enhancement mechanism may comprise a band comprising a plurality of interconnected torsion or leaf spring elements or a combination of such torsion or leaf spring elements contained within a dovetailed groove in the respective one of the inner wall, outer wall and bottom wall.
- the thermal conductivity enhancement mechanism comprising a MultilLam electrical contact strip or the like strip or band used to make similar electrical contacts between, e.g., curved or rounded surfaces.
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Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
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US11/095,976 US20060222034A1 (en) | 2005-03-31 | 2005-03-31 | 6 Khz and above gas discharge laser system |
US11/224,861 US20060233214A1 (en) | 2005-03-31 | 2005-09-13 | Hybrid electrode support bar |
KR1020077022202A KR101332767B1 (ko) | 2005-03-31 | 2006-03-27 | 6 KHz 이상의 가스방전 레이저 시스템 |
PCT/US2006/011339 WO2006105119A2 (en) | 2005-03-31 | 2006-03-27 | 6 KHz AND ABOVE GAS DISCHARGE LASER SYSTEM |
EP06748829A EP1867015B1 (en) | 2005-03-31 | 2006-03-27 | 6 KHz AND ABOVE GAS DISCHARGE LASER SYSTEM |
JP2008504262A JP5349954B2 (ja) | 2005-03-31 | 2006-03-27 | 6KHz及びこれを超えるガス放電レーザシステム |
US13/352,127 US8855166B2 (en) | 2005-03-31 | 2012-01-17 | 6 KHz and above gas discharge laser system |
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US11/095,976 US20060222034A1 (en) | 2005-03-31 | 2005-03-31 | 6 Khz and above gas discharge laser system |
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US13/352,127 Expired - Fee Related US8855166B2 (en) | 2005-03-31 | 2012-01-17 | 6 KHz and above gas discharge laser system |
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US13/352,127 Expired - Fee Related US8855166B2 (en) | 2005-03-31 | 2012-01-17 | 6 KHz and above gas discharge laser system |
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US (3) | US20060222034A1 (ja) |
EP (1) | EP1867015B1 (ja) |
JP (1) | JP5349954B2 (ja) |
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Also Published As
Publication number | Publication date |
---|---|
JP5349954B2 (ja) | 2013-11-20 |
KR20070120511A (ko) | 2007-12-24 |
EP1867015B1 (en) | 2012-11-21 |
WO2006105119A3 (en) | 2008-10-16 |
US20060233214A1 (en) | 2006-10-19 |
EP1867015A2 (en) | 2007-12-19 |
EP1867015A4 (en) | 2010-11-03 |
US8855166B2 (en) | 2014-10-07 |
JP2008538162A (ja) | 2008-10-09 |
KR101332767B1 (ko) | 2013-11-25 |
WO2006105119A2 (en) | 2006-10-05 |
US20120120974A1 (en) | 2012-05-17 |
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