US20060183653A1 - Fragrance compositions that reduce or eliminate malodor, related methods and related cleaning compositions - Google Patents
Fragrance compositions that reduce or eliminate malodor, related methods and related cleaning compositions Download PDFInfo
- Publication number
- US20060183653A1 US20060183653A1 US11/353,661 US35366106A US2006183653A1 US 20060183653 A1 US20060183653 A1 US 20060183653A1 US 35366106 A US35366106 A US 35366106A US 2006183653 A1 US2006183653 A1 US 2006183653A1
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- United States
- Prior art keywords
- composition
- amount
- dimethyl
- surfactant
- cis
- Prior art date
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- Abandoned
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- 239000000203 mixture Substances 0.000 title claims abstract description 72
- 239000003205 fragrance Substances 0.000 title claims abstract description 45
- 238000004140 cleaning Methods 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 13
- CZCBTSFUTPZVKJ-UHFFFAOYSA-N rose oxide Chemical compound CC1CCOC(C=C(C)C)C1 CZCBTSFUTPZVKJ-UHFFFAOYSA-N 0.000 claims abstract description 34
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 claims abstract description 32
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229930007790 rose oxide Natural products 0.000 claims abstract description 17
- 229940098795 (3z)- 3-hexenyl acetate Drugs 0.000 claims abstract description 16
- NPFVOOAXDOBMCE-PLNGDYQASA-N cis-3-Hexenyl acetate Natural products CC\C=C/CCOC(C)=O NPFVOOAXDOBMCE-PLNGDYQASA-N 0.000 claims abstract description 16
- RRGOKSYVAZDNKR-ARJAWSKDSA-M cis-3-hexenylacetate Chemical compound CC\C=C/CCCC([O-])=O RRGOKSYVAZDNKR-ARJAWSKDSA-M 0.000 claims abstract description 16
- NPFVOOAXDOBMCE-UHFFFAOYSA-N trans-3-hexenyl acetate Natural products CCC=CCCOC(C)=O NPFVOOAXDOBMCE-UHFFFAOYSA-N 0.000 claims abstract description 16
- KWVISVAMQJWJSZ-VKROHFNGSA-N solasodine Chemical compound O([C@@H]1[C@@H]([C@]2(CC[C@@H]3[C@@]4(C)CC[C@H](O)CC4=CC[C@H]3[C@@H]2C1)C)[C@@H]1C)[C@]11CC[C@@H](C)CN1 KWVISVAMQJWJSZ-VKROHFNGSA-N 0.000 claims abstract description 15
- MZZRKEIUNOYYDF-UHFFFAOYSA-N 2,4-dimethylcyclohex-3-ene-1-carbaldehyde Chemical compound CC1C=C(C)CCC1C=O MZZRKEIUNOYYDF-UHFFFAOYSA-N 0.000 claims abstract description 13
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- 150000003505 terpenes Chemical class 0.000 claims description 6
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- FVUGZKDGWGKCFE-UHFFFAOYSA-N 1-(2,3,8,8-tetramethyl-1,3,4,5,6,7-hexahydronaphthalen-2-yl)ethanone Chemical compound CC1(C)CCCC2=C1CC(C(C)=O)(C)C(C)C2 FVUGZKDGWGKCFE-UHFFFAOYSA-N 0.000 claims description 5
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- HMKKIXGYKWDQSV-KAMYIIQDSA-N alpha-Amylcinnamaldehyde Chemical compound CCCCC\C(C=O)=C\C1=CC=CC=C1 HMKKIXGYKWDQSV-KAMYIIQDSA-N 0.000 claims description 5
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- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000003368 amide group Chemical group 0.000 claims description 2
- 239000002563 ionic surfactant Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims 1
- 240000004978 Rosa x damascena Species 0.000 abstract 1
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- 238000013019 agitation Methods 0.000 description 4
- 238000010411 cooking Methods 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
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- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 3
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- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
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- FINOAUDUYKVGDS-UHFFFAOYSA-N (2-tert-butylcyclohexyl) acetate Chemical compound CC(=O)OC1CCCCC1C(C)(C)C FINOAUDUYKVGDS-UHFFFAOYSA-N 0.000 description 2
- WSTQLNQRVZNEDV-CSKARUKUSA-N (e)-4-methyldec-3-en-5-ol Chemical compound CCCCCC(O)C(\C)=C\CC WSTQLNQRVZNEDV-CSKARUKUSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
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- 150000004996 alkyl benzenes Chemical class 0.000 description 1
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- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- PDEQKAVEYSOLJX-BKKZDLJQSA-N alpha-santalol Chemical compound C1C2[C@]3(C)C2C[C@H]1[C@@]3(C)CC/C=C(CO)/C PDEQKAVEYSOLJX-BKKZDLJQSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000001857 anti-mycotic effect Effects 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- MIZGSAALSYARKU-UHFFFAOYSA-N cashmeran Chemical compound CC1(C)C(C)C(C)(C)C2=C1C(=O)CCC2 MIZGSAALSYARKU-UHFFFAOYSA-N 0.000 description 1
- SVURIXNDRWRAFU-OGMFBOKVSA-N cedrol Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1[C@@](O)(C)CC2 SVURIXNDRWRAFU-OGMFBOKVSA-N 0.000 description 1
- 229940026455 cedrol Drugs 0.000 description 1
- PCROEXHGMUJCDB-UHFFFAOYSA-N cedrol Natural products CC1CCC2C(C)(C)C3CC(C)(O)CC12C3 PCROEXHGMUJCDB-UHFFFAOYSA-N 0.000 description 1
- AHZYNUWTBDLJHG-RHBQXOTJSA-N cedryl formate Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1[C@@](OC=O)(C)CC2 AHZYNUWTBDLJHG-RHBQXOTJSA-N 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- CCRCUPLGCSFEDV-UHFFFAOYSA-N cinnamic acid methyl ester Natural products COC(=O)C=CC1=CC=CC=C1 CCRCUPLGCSFEDV-UHFFFAOYSA-N 0.000 description 1
- BJIOGJUNALELMI-ARJAWSKDSA-N cis-isoeugenol Chemical compound COC1=CC(\C=C/C)=CC=C1O BJIOGJUNALELMI-ARJAWSKDSA-N 0.000 description 1
- 229930003633 citronellal Natural products 0.000 description 1
- 235000000983 citronellal Nutrition 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229940019836 cyclamen aldehyde Drugs 0.000 description 1
- NUQDJSMHGCTKNL-UHFFFAOYSA-N cyclohexyl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1CCCCC1 NUQDJSMHGCTKNL-UHFFFAOYSA-N 0.000 description 1
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 229940093468 ethylene brassylate Drugs 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- PHXATPHONSXBIL-JTQLQIEISA-N gamma-Undecalactone Natural products CCCCCCC[C@H]1CCC(=O)O1 PHXATPHONSXBIL-JTQLQIEISA-N 0.000 description 1
- 229940020436 gamma-undecalactone Drugs 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- 235000008216 herbs Nutrition 0.000 description 1
- XOYYHTTVCNEROD-UHFFFAOYSA-N hex-1-enyl 2-hydroxybenzoate Chemical compound CCCCC=COC(=O)C1=CC=CC=C1O XOYYHTTVCNEROD-UHFFFAOYSA-N 0.000 description 1
- QVRVMTNMZRDDGX-UHFFFAOYSA-N hexan-1-ol;phenol Chemical compound CCCCCCO.OC1=CC=CC=C1 QVRVMTNMZRDDGX-UHFFFAOYSA-N 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 1
- SVURIXNDRWRAFU-UHFFFAOYSA-N juniperanol Natural products C1C23C(C)CCC3C(C)(C)C1C(O)(C)CC2 SVURIXNDRWRAFU-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 230000033001 locomotion Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 description 1
- 229940061634 magnesium sulfate heptahydrate Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- BFBPISPWJZMWJN-UHFFFAOYSA-N methyl 2-[(7-hydroxy-3,7-dimethyloctylidene)amino]benzoate Chemical compound COC(=O)C1=CC=CC=C1N=CCC(C)CCCC(C)(C)O BFBPISPWJZMWJN-UHFFFAOYSA-N 0.000 description 1
- IPWBXORAIBJDDQ-UHFFFAOYSA-N methyl 2-hexyl-3-oxocyclopentane-1-carboxylate Chemical compound CCCCCCC1C(C(=O)OC)CCC1=O IPWBXORAIBJDDQ-UHFFFAOYSA-N 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- CCRCUPLGCSFEDV-BQYQJAHWSA-N methyl trans-cinnamate Chemical compound COC(=O)\C=C\C1=CC=CC=C1 CCRCUPLGCSFEDV-BQYQJAHWSA-N 0.000 description 1
- 229940067137 musk ketone Drugs 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- LQPLDXQVILYOOL-UHFFFAOYSA-I pentasodium;2-[bis[2-[bis(carboxylatomethyl)amino]ethyl]amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC(=O)[O-])CCN(CC([O-])=O)CC([O-])=O LQPLDXQVILYOOL-UHFFFAOYSA-I 0.000 description 1
- QKNZNUNCDJZTCH-UHFFFAOYSA-N pentyl benzoate Chemical compound CCCCCOC(=O)C1=CC=CC=C1 QKNZNUNCDJZTCH-UHFFFAOYSA-N 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940079842 sodium cumenesulfonate Drugs 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- BJIOGJUNALELMI-UHFFFAOYSA-N trans-isoeugenol Natural products COC1=CC(C=CC)=CC=C1O BJIOGJUNALELMI-UHFFFAOYSA-N 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 229940124543 ultraviolet light absorber Drugs 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N α-citronellol Chemical compound OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/188—Terpenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Definitions
- compositions are adapted for use in all types of cleaning products, including those used for manual dishwashing and those used for machine dishwashing.
- the invention includes a fragrance composition that contains at least four compounds selected from a decyl aldehydes, an allyl amyl glycolate, cis-3-hexenyl acetate, a rose oxide, a terpinolene, and 2,4-dimethyl-3-cyclohexene-1-carbaldehyde.
- the invention also includes a cleaning product that incorporates a surfactant and a fragrance composition comprising: a decyl aldehydes, allyl amyl glycolate, cis-3-hexenyl acetate, rose oxide, terpinolene, and 2,4-dimethyl-3-cyclohexene-1-carbaldehyde.
- food malodors include those caused by vegetables of the Family Alliaceae (e.g., garlics, chives, shallots, leeks, garden onion), cruciferous vegetables (broccoli, cauliflower), fish/seafood, cooked food, burned food, cooked oil, burned oil, cooking spices or herbs, overripe or spoiled vegetable matter, or grease.
- the compositions may be incorporated into cleaning products for use in the kitchen, dining rooms, or other spaces, sink and counter surfaces used in dishwashing or cleaning of food preparation areas, and porous or non-porous surfaces, including dishware and cooking implements, especially liquid dishwashing products, automatic dishwashing products, cleaning wipes, hard surface cleaners, trash cans, trash can liners and bags, cleaning implements (brooms, sponges, brushes, cloths, etc.).
- the fragrance compositions may also be included in materials that can be used to fabricate or coat article or surfaces that are used in food preparation or disposal, included paints, varnishes, polymer coatings, plastics, etc.
- cleaning compositions incorporating the methods of reducing malodor by application or agitation in water of the fragrance composition of the invention.
- Malodor-reducing fragrance compositions that may be used in a kitchen cleaning product according to this invention are made, for example, by combining at least four of the components: (i) decyl aldehyde (n-decanal), (ii) allyl amyl glycolate, (iii) cis-3-hexenyl acetate, (iv) a rose oxide, (v) terpinolene, and (vi) 2,4-dimethyl-3-cyclohexene-1-carbaldehyde. Preferably at least five or all of the components are combined.
- the components of the invention may be obtained from any source known or to be developed in the art. They may be prepared synthetically or they may be extracted from natural sources. For example, n-decanal or allyl amyl glycolate may be obtained from lemon grass, citronella, other plants of the Genus Cymbopogon or oil of citrus peels.
- the rose oxide used in the composition of the invention may be any known or to be developed in the art, and may include combinations of rose oxides. Suitable rose oxides may include (4R,2S)-( ⁇ )-cis-rose oxide, (4R,2S)-(+)-cis-rose oxide, (4R,2S)-(+)-trans-rose oxide, (4R,2S)-( ⁇ )-trans-rose oxide or combinations of these.
- the components of the invention may be in any substituted, unsubstituted in whole or in part and may be any isomers, enantiomers, or racemers of the listed compounds.
- these malodor reducing components are incorporated into a kitchen product, they are suitably present in an amount sufficient to ensure that the product, e.g. a kitchen cleaning product, for example a dishwashing liquid, counteracts kitchen malodors and the smells of residual foods to the desired level of efficiency.
- a kitchen cleaning product for example a dishwashing liquid
- the component present in the fragrance composition of the invention may be present in any amount and/or relative proportion; such amounts and proportions may vary depending on the end use for which product containing the fragrance compositor is intended. However, it may be preferred that the decyl aldehyde and/or allyl amyl glycolate are independently present in an amount of about 0.1 to about 8% by weight, more preferably about 0.5 to about 5%, or 0.3 to about 3% by weight of the composition.
- the cis-3-hexenyl acetate is present in an amount of up to about 5% by weight, preferably about 0.1% to about 3% by weight, more preferably up to about 1.5% by weight of the composition.
- the rose oxide(s) is present in an amount of up to about 2% by weight, preferably about up to 1% by weight, more preferably about 0.1% by weight to about 3% by weight of the composition.
- the terpinolene is present in the composition in an amount up to about 10% by weight, preferably about up to about 0.05% by weight to about 7% by weight of the composition.
- the 2,4-dimethyl-3-cyclohexene-1-carbaldehyde is present in the composition in an amount up to about 3% by weight, preferably about up to about 0.05% to about 2% by weight of the composition.
- the components of the fragrance composition are present in relative weight proportions as shown in Table I and/or Table II: TABLE I Component Proportion Decyl aldehydes About 2.5 Ally amyl glycolate About 1 Cis-3-hexenyl acetate About 1 Rose oxide About 0.5 Terpinolene About 2 2,4-dimethyll-3-cyclohexene-1-carbaldehyde About 3
- the fragrance compositions of the invention may contain additional ingredients as well, including additional fragrance compounds, excipients, carriers, or colorants.
- the fragrance composition may include (a) esters of salicylic acid such as hexyl salicylate, hexenyl salicylate, isoamyl salicylate, benzyl salicylate and cyclohexyl salicylate;
- additional ingredients are orange terpenes; acetates of alcohols having 6 to 12 carbon atoms, e.g., terpinyl acetate, isononyl acetate, hexyl acetate, 2-tert-butyl-cyclohexyl acetate, and p-tert-butyl-cyclohexyl acetate; unsaturated alcohols having ten carbon atoms, e.g., dihydromyrcenol and linalool; and citronellyl nitrile.
- acetates of alcohols having 6 to 12 carbon atoms e.g., terpinyl acetate, isononyl acetate, hexyl acetate, 2-tert-butyl-cyclohexyl acetate, and p-tert-butyl-cyclohexyl acetate
- unsaturated alcohols having ten carbon atoms e.g., dihydr
- the fragrance compositions of the invention contains minimal or reduced amounts of one or more of the following compounds: amyl cinnamic aldehyde, 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-g-2-benzopyran (HHCB), or 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone.
- HHCB 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-g-2-benzopyran
- 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone for example, in may be preferred that the composition contains independently:
- the fragrance composition is substantially free of one or more of these ingredients, or that the ratio of the fragrance composition components (i) to (iv) listed above to one or more of the compounds listed above is about 10 to 1.
- the fragrance composition of the invention may be incorporated into a cleaning product.
- cleaning product may take any form; it may be, for example, a dishwashing detergent (liquid, powder, gel, paste; manual or automatic), an all-purpose surface cleaners, and a wipe or pre-treated textile, sponge, broom, or other cleaning implements, detergents for cleaning pots and pans, hand soaps, laundry products and shampoos or other hair care products.
- Such products may contain the fragrance composition of the invention in any amount. However, it may be preferable that the fragrance composition is present in an amount of about 2 to about 50% by weight, more particularly about 4 to about 20% by weight, or about 3.5 to about 10% by weight and up to about 9.5% by weight.
- the cleaning product contains one or more surfactants. Any surfactant or mixture of surfactants may be used; types and mixture will vary depending on the intended use of the end product.
- the product may contain one or more ionic and/or non-ionic surfactants.
- the product may contain one or more surfactants selected from cationic surfactants, linear alkyl benzene sulfonate salts (preferably having 8 to 18 carbon atoms), sulfated alcohol ethoxylates, amine oxide surfactants and/or amphoteric surfactants.
- An embodiment that is a manual dishwashing liquid could include (i) at least two surfactants selected from cationic surfactants (e.g, quaternary ammonium surfactants,dialkyl dimethyl ammonium chloride), nonionic surfactants (alkylpolyglucosides or polyoxyethylenated alcohols), linear alkyl benzene sulfonate salts (e.g., sodium and/or magnesium salts), sulfated alcohol ethoxylates (C 8 -C 18 ethoxylated alkyl ether sulfate; the sodium salt and/or the ammonium salt), amine oxide surfactants (a C 12 /C 14 alkyl amido propyl dimethyl amine oxide), amphoteric surfactants (a trialkyl glycine surfactant, for example cocobetaine).
- cationic surfactants e.g, quaternary ammonium surfactants,dialkyl dimethyl ammonium chloride
- the invention includes cleaning products that are liquid dishwashing liquids of conventional formulations but which contain the fragrance composition of the invention.
- the formulations for a dishwashing liquid in accordance with the invention may, for example, be as described in U.S. Pat. No. 6,492,314, the contents of which are incorporated herein by reference.
- cleaning product may additionally include conventional ingredients, adjuvants such as various coloring agents and perfumes; ultraviolet light absorbers, salts such as sodium chloride or magnesium sulfate heptahydrate; hydrotropes such as sodium cumene sulfonate or preferably sodium xylene sulfonate; chelators or sequestering agents, e.g., EDTA, HEDTA, or preferably pentasodium DTPA; pH modifiers, e.g., sodium hydroxide or sulfuric acid; etc., preservatives, such as sodium formate, formalin, or 1,3-dimethylol-5,5-dimethyl-hydantoin (DMDM hydantoin), color stabilizers such as sodium bisulfite, and anti-mycotic or antibacterial agents, such as triclosan.
- DMDM hydantoin 1,3-dimethylol-5,5-dimethyl-hydantoin
- color stabilizers such as sodium bis
- the invention provides a dishwashing liquid comprising, by weight:
- the total of components of the dishwashing liquid other than water and fragrance (sometime referred to as the Active Ingredient or AI fraction) in the dishwashing liquids of the invention is about 25-40%, e.g., about 30 to 36%.
- the AI fraction is about 36% and the fragrance level is about 0.9%.
- the dishwashing liquid may be conveniently provided in a plastic squeeze bottle with a small orifice in the cap to permit the liquid to be dispensed.
- the optimal diameter of the orifice may vary depending on the viscosity and other properties of the dishwashing liquid, but is typically 3-5 mm, for example 3.4 or 4.2 mm.
- compositions and products of the invention may be readily prepared by conventional means using, e.g., simple mixing methods.
- the invention also includes methods off reducing and/or eliminating malodor in a cleaning or dishwashing implement by application of the fragrance composition or a cleaning product of the invention to the implement.
- the implement may include any used in the cleaning or washing of tools, devices, surfaces, or containers used in the preparation or disposal of food. For example, rags, sponges, trays, abrasive pads, scrubbies, poufs, wipes, brushes, trash receptacles or cans, liners for such receptacles, food storage containers, are included.
- the invention includes methods off reducing and/or eliminating malodor in a space by the agitation of the fragrance composition or a cleaning product of the invention in water.
- Spaces in which the invention can be used to eliminate or reduce malodor include any in which food is consumer, disposed of, stored, or prepared. Specifically, such places include kitchens, dining rooms, restaurants, trash storage rooms, and dishwashing rooms, refrigerators, freezers, storerooms, and trash dumpsters.
- agitation it is meant any activities that disrupt the water into which the composition has been placed, thereby resulting in the volatilization of some of the components in the compositions. Agitation includes dishwashing (manual or automatic), handwashing or machine washing of textiles, the motions carried out when washing one's hands, mopping or wiping of floors and surfaces, and spraying.
- a fragrance composition 1 is prepared by admixing the following ingredients: Composition 1 Ingredient % by weight Aldehyde C10 2.50 Allyl Amyl Glycolate 1.00 Cis-3-hexenyl acetate 1.00 Rose Oxide 0.50 Terpinolene 2.00 Zestover 3.00 Orange terpenes 40.00 Isononyl acetate 5.00 Dorisyl ® 1) 10.00 Terpinyl acetate 10.00 Dihydromyrcenol 15.00 Citronellyl nitrile 10.00 Total 100.00 1) p-tert-butyl-cyclohexyl acetate; available from Firmenich SA, Geneva, Switzerland
- a comparative fragrance A is prepared as follows: Fragrance A Ingredient % by weight Dipropylene glycol 10.00 Orange terpenes 40.00 Isononyl acetate 5.00 Dorisyl ® 1) 10.00 Terpinyl acetate 10.00 Dihydromyrcenol 15.00 Citronellyl nitrile 10.00 Total 100.00 1) p-tert-butyl-cyclohexyl acetate; origin: Firmenich SA, Geneva, Switzerland
- a dishwashing liquid for use in combination with the fragrance components of examples 1 is prepared by combining the following ingredients: Formula Ingredients % by weight NaLAS 3.71 MgLAS 11.16 NH4 AEOS-1.3EO 14.23 Amine Oxide 6.70 SXS 3.30 Sodium Bisulfite 0.10 Salt 0.22 Ethanol 5.25 Sequestering agent 0.28 Preservative 0.11 Fragrance Component of Ex. 1 or 2 0.60 Water and minors (color, pH BALANCE adjustment)
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Fats And Perfumes (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention relates to a fragrance composition for control of kitchen malodor, kitchen cleaning and deodorizing products comprising them, and methods for the reduction of malodor utilizing them, the fragrance composition containing at least four of the following components: a. Decyl aldehyde or decanal b. Allyl amyl glycolate c. Cis-3-hexenyl acetate d. Rose oxide e. Terpinolene f. 2,4-dimethyl-3-cyclohexene-1-carbaldehyde
Description
- This application claims priority to U.S. provisional patent application Ser. No. 60/653,004, filed Feb. 15, 2005, the contents of which are incorporated herein by reference.
- Those who cook or work in the kitchen often comment on the disagreeable odors of food and cooking grease that linger after the preparation and/or consumption of a meal, particular those meals that include fish, onions, garlic, leeks, or shellfish. Prior approaches to addressing this problem have included the use in dishwashing products of fragrances that develop blooming or intense odors. Such odors may serve to overpower the targeted malodor and therefore reduce the perception by the user of the malodor. For example, the prior art describes a number of so-called blooming ingredients and compositions able to provide a pleasant fragrance in an area surrounding the dishwashing machine during and after use.
- Often these prior art products have an overpowering fragrance that itself may linger too long in the kitchen. Therefore it is desirable to provide a more subtlety fragranced dishwashing detergent or liquid while still giving good control of kitchen odors. Preferably, such compositions are adapted for use in all types of cleaning products, including those used for manual dishwashing and those used for machine dishwashing.
- The invention includes a fragrance composition that contains at least four compounds selected from a decyl aldehydes, an allyl amyl glycolate, cis-3-hexenyl acetate, a rose oxide, a terpinolene, and 2,4-dimethyl-3-cyclohexene-1-carbaldehyde.
- The invention also includes a cleaning product that incorporates a surfactant and a fragrance composition comprising: a decyl aldehydes, allyl amyl glycolate, cis-3-hexenyl acetate, rose oxide, terpinolene, and 2,4-dimethyl-3-cyclohexene-1-carbaldehyde.
- Methods of reducing and/or eliminating kitchen malodor using these compositions and products are also provided.
- Described is an invention that includes fragrance and cleaning compositions that reduce or eliminate the perception of the presence of food malodors present in areas where food is prepared, stored, consumed and/or which adhere to the implements used in food preparation and the associated washing up processes. Such food malodors include those caused by vegetables of the Family Alliaceae (e.g., garlics, chives, shallots, leeks, garden onion), cruciferous vegetables (broccoli, cauliflower), fish/seafood, cooked food, burned food, cooked oil, burned oil, cooking spices or herbs, overripe or spoiled vegetable matter, or grease. The compositions may be incorporated into cleaning products for use in the kitchen, dining rooms, or other spaces, sink and counter surfaces used in dishwashing or cleaning of food preparation areas, and porous or non-porous surfaces, including dishware and cooking implements, especially liquid dishwashing products, automatic dishwashing products, cleaning wipes, hard surface cleaners, trash cans, trash can liners and bags, cleaning implements (brooms, sponges, brushes, cloths, etc.). The fragrance compositions may also be included in materials that can be used to fabricate or coat article or surfaces that are used in food preparation or disposal, included paints, varnishes, polymer coatings, plastics, etc. Also included in the invention are cleaning compositions incorporating the methods of reducing malodor by application or agitation in water of the fragrance composition of the invention.
- Malodor-reducing fragrance compositions that may be used in a kitchen cleaning product according to this invention are made, for example, by combining at least four of the components: (i) decyl aldehyde (n-decanal), (ii) allyl amyl glycolate, (iii) cis-3-hexenyl acetate, (iv) a rose oxide, (v) terpinolene, and (vi) 2,4-dimethyl-3-cyclohexene-1-carbaldehyde. Preferably at least five or all of the components are combined.
- The components of the invention may be obtained from any source known or to be developed in the art. They may be prepared synthetically or they may be extracted from natural sources. For example, n-decanal or allyl amyl glycolate may be obtained from lemon grass, citronella, other plants of the Genus Cymbopogon or oil of citrus peels. The rose oxide used in the composition of the invention may be any known or to be developed in the art, and may include combinations of rose oxides. Suitable rose oxides may include (4R,2S)-(−)-cis-rose oxide, (4R,2S)-(+)-cis-rose oxide, (4R,2S)-(+)-trans-rose oxide, (4R,2S)-(−)-trans-rose oxide or combinations of these.
- The components of the invention may be in any substituted, unsubstituted in whole or in part and may be any isomers, enantiomers, or racemers of the listed compounds.
- When these malodor reducing components are incorporated into a kitchen product, they are suitably present in an amount sufficient to ensure that the product, e.g. a kitchen cleaning product, for example a dishwashing liquid, counteracts kitchen malodors and the smells of residual foods to the desired level of efficiency.
- The component present in the fragrance composition of the invention may be present in any amount and/or relative proportion; such amounts and proportions may vary depending on the end use for which product containing the fragrance compositor is intended. However, it may be preferred that the decyl aldehyde and/or allyl amyl glycolate are independently present in an amount of about 0.1 to about 8% by weight, more preferably about 0.5 to about 5%, or 0.3 to about 3% by weight of the composition.
- It may be preferred that the cis-3-hexenyl acetate is present in an amount of up to about 5% by weight, preferably about 0.1% to about 3% by weight, more preferably up to about 1.5% by weight of the composition.
- It may be preferred that the rose oxide(s) is present in an amount of up to about 2% by weight, preferably about up to 1% by weight, more preferably about 0.1% by weight to about 3% by weight of the composition.
- It may be preferred that the terpinolene is present in the composition in an amount up to about 10% by weight, preferably about up to about 0.05% by weight to about 7% by weight of the composition.
- It may be preferred that the 2,4-dimethyl-3-cyclohexene-1-carbaldehyde is present in the composition in an amount up to about 3% by weight, preferably about up to about 0.05% to about 2% by weight of the composition.
- In some embodiments, it may be preferable that the components of the fragrance composition are present in relative weight proportions as shown in Table I and/or Table II:
TABLE I Component Proportion Decyl aldehydes About 2.5 Ally amyl glycolate About 1 Cis-3-hexenyl acetate About 1 Rose oxide About 0.5 Terpinolene About 2 2,4-dimethyll-3-cyclohexene-1-carbaldehyde About 3 -
TABLE II Component Proportion Decyl aldehydes About 0.5 Ally amyl glycolate About 1.5 Cis-3-hexenyl acetate About 0.1 Rose oxide About 0.1 Terpinolene About 1 2,4-dimethyll-3-cyclohexene-1-carbaldehyde About 0.5 - The fragrance compositions of the invention may contain additional ingredients as well, including additional fragrance compounds, excipients, carriers, or colorants. For example, the fragrance composition may include (a) esters of salicylic acid such as hexyl salicylate, hexenyl salicylate, isoamyl salicylate, benzyl salicylate and cyclohexyl salicylate;
-
- (b) esters of cinnamic acid such as amyl cinnamate, cinnamyl cinnamate and methyl cinnamate;
- (c) perfume esters such as allyl cyclohexane propionate, amyl benzoate, para-tertiarybutylcyclohexyl acetate, cedryl acetate, cedryl formate, dihydro-isojasmonate, ethylene brassylate, ethyl undecylenate, geranyl anthranilate, geranyl phenyl acetate, linalyl benzoate, benzyl acetate, linalyl acetate, vetiveryl acetate, terpinyl acetate; especially acetates of C6-12 alcohols, for example terpinyl acetate, isononyl acetate, hexyl acetate, 2-tert-butyl-cyclohexyl acetate, p-tert-butyl-cyclohexyl acetate;
- (d) aldehydes such as cyclamen aldehyde, lilial, benzaldehyde, citronellal, hydroxy-citronellal;
- (e) alcohols such as geraniol, linalool, nerol, phenyl ethyl alcohol, alpha terpineol, eugenol, isoeugenol, alpha-citronellol, dihydromyrcenol, aurantiol, cedrol, phenyl heptanol, phenol hexanol, alpha-santalol, undecavertol (4-methyl-3-decen-5-ol), benzyl alcohol; especially C10 unsaturated alcohol e.g., dihydromyrcenol and linalool;
- (f) ketones such as benzophenone, dodecalactone, gamma-n-methyl ionone, delta-undecalactone, gamma-undecalactone, laevo-carvone, beta-methylnaphthyl ketone;
- (g) nitromusk such as musk ketone, musk tibetine, musk indanone;
- (h) terpenes such as orange terpenes, limonene; and
- (i) nitriles such as citronellyl nitrile.
- In one embodiment, additional ingredients are orange terpenes; acetates of alcohols having 6 to 12 carbon atoms, e.g., terpinyl acetate, isononyl acetate, hexyl acetate, 2-tert-butyl-cyclohexyl acetate, and p-tert-butyl-cyclohexyl acetate; unsaturated alcohols having ten carbon atoms, e.g., dihydromyrcenol and linalool; and citronellyl nitrile.
- However, in some embodiments it may be preferred that the fragrance compositions of the invention contains minimal or reduced amounts of one or more of the following compounds: amyl cinnamic aldehyde, 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-g-2-benzopyran (HHCB), or 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone. For example, in may be preferred that the composition contains independently:
-
- amyl cinnamic aldehyde in an amount of less than about 15%, more preferably less than about 5% by weight, more preferably less than about 1% by weight of the total fragrance composition;
- HHCB in an amount of less than about 20%, more preferably less than about 5% by weight, more preferably less than about 1% by weight of the total fragrance composition;
- 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone in an amount of less than about 5%, more preferably less than about 2% by weight, more preferably less than about 0.5% by weight of the total fragrance composition.
- In some embodiments it may be preferred that the fragrance composition is substantially free of one or more of these ingredients, or that the ratio of the fragrance composition components (i) to (iv) listed above to one or more of the compounds listed above is about 10 to 1.
- The fragrance composition of the invention may be incorporated into a cleaning product. Such cleaning product may take any form; it may be, for example, a dishwashing detergent (liquid, powder, gel, paste; manual or automatic), an all-purpose surface cleaners, and a wipe or pre-treated textile, sponge, broom, or other cleaning implements, detergents for cleaning pots and pans, hand soaps, laundry products and shampoos or other hair care products.
- Such products may contain the fragrance composition of the invention in any amount. However, it may be preferable that the fragrance composition is present in an amount of about 2 to about 50% by weight, more particularly about 4 to about 20% by weight, or about 3.5 to about 10% by weight and up to about 9.5% by weight.
- In one embodiment, it is preferred that the cleaning product contains one or more surfactants. Any surfactant or mixture of surfactants may be used; types and mixture will vary depending on the intended use of the end product. For example, if the end product is a manual dish detergent, the product may contain one or more ionic and/or non-ionic surfactants. Alternatively, the product may contain one or more surfactants selected from cationic surfactants, linear alkyl benzene sulfonate salts (preferably having 8 to 18 carbon atoms), sulfated alcohol ethoxylates, amine oxide surfactants and/or amphoteric surfactants.
- An embodiment that is a manual dishwashing liquid could include (i) at least two surfactants selected from cationic surfactants (e.g, quaternary ammonium surfactants,dialkyl dimethyl ammonium chloride), nonionic surfactants (alkylpolyglucosides or polyoxyethylenated alcohols), linear alkyl benzene sulfonate salts (e.g., sodium and/or magnesium salts), sulfated alcohol ethoxylates (C8-C18 ethoxylated alkyl ether sulfate; the sodium salt and/or the ammonium salt), amine oxide surfactants (a C12/C14alkyl amido propyl dimethyl amine oxide), amphoteric surfactants (a trialkyl glycine surfactant, for example cocobetaine).
- In another embodiment, the invention includes cleaning products that are liquid dishwashing liquids of conventional formulations but which contain the fragrance composition of the invention. The formulations for a dishwashing liquid in accordance with the invention may, for example, be as described in U.S. Pat. No. 6,492,314, the contents of which are incorporated herein by reference.
- Regardless of the type of cleaning product, it may additionally include conventional ingredients, adjuvants such as various coloring agents and perfumes; ultraviolet light absorbers, salts such as sodium chloride or magnesium sulfate heptahydrate; hydrotropes such as sodium cumene sulfonate or preferably sodium xylene sulfonate; chelators or sequestering agents, e.g., EDTA, HEDTA, or preferably pentasodium DTPA; pH modifiers, e.g., sodium hydroxide or sulfuric acid; etc., preservatives, such as sodium formate, formalin, or 1,3-dimethylol-5,5-dimethyl-hydantoin (DMDM hydantoin), color stabilizers such as sodium bisulfite, and anti-mycotic or antibacterial agents, such as triclosan.
- For example, the invention provides a dishwashing liquid comprising, by weight:
- (i) about 5% to about 45% of combined magnesium and sodium salts of a C8-C18 linear alkyl sulfonate surfactant, where the sodium salt can vary between about 0% and about 20%, preferably between 3% and 15% and the magnesium salt can vary between about 0% and about 35%, preferably about 3% and about 15%;
- (ii) about 1% to about 10% of a C12/C14 alkyl amido propyl dimethyl amine oxide surfactant;
- (iii) 0.35% to 3 wt. % of a fragrance component comprising the malodor reducing fragrance of the invention;
- (iv) 5% to 35% of a C8-C18 ethoxylated alkyl ether sulfate;
- (v) 0% to 10% ethanol;
- (vi) 1% to 5% sodium xylene sulfonate;
- (vii) 0% to 1% pentasodium pentatate;
- (viii) 0% to 0.5% 1,3-dimethylol-5,5-dimethyl-hydantoin; and
- (ix) water.
- The total of components of the dishwashing liquid other than water and fragrance (sometime referred to as the Active Ingredient or AI fraction) in the dishwashing liquids of the invention is about 25-40%, e.g., about 30 to 36%. For example, in one preferred embodiment, the AI fraction is about 36% and the fragrance level is about 0.9%. The dishwashing liquid may be conveniently provided in a plastic squeeze bottle with a small orifice in the cap to permit the liquid to be dispensed. The optimal diameter of the orifice may vary depending on the viscosity and other properties of the dishwashing liquid, but is typically 3-5 mm, for example 3.4 or 4.2 mm.
- The compositions and products of the invention may be readily prepared by conventional means using, e.g., simple mixing methods.
- The invention also includes methods off reducing and/or eliminating malodor in a cleaning or dishwashing implement by application of the fragrance composition or a cleaning product of the invention to the implement. The implement may include any used in the cleaning or washing of tools, devices, surfaces, or containers used in the preparation or disposal of food. For example, rags, sponges, trays, abrasive pads, scrubbies, poufs, wipes, brushes, trash receptacles or cans, liners for such receptacles, food storage containers, are included.
- The invention includes methods off reducing and/or eliminating malodor in a space by the agitation of the fragrance composition or a cleaning product of the invention in water. Spaces in which the invention can be used to eliminate or reduce malodor include any in which food is consumer, disposed of, stored, or prepared. Specifically, such places include kitchens, dining rooms, restaurants, trash storage rooms, and dishwashing rooms, refrigerators, freezers, storerooms, and trash dumpsters. By agitation, it is meant any activities that disrupt the water into which the composition has been placed, thereby resulting in the volatilization of some of the components in the compositions. Agitation includes dishwashing (manual or automatic), handwashing or machine washing of textiles, the motions carried out when washing one's hands, mopping or wiping of floors and surfaces, and spraying.
- A fragrance composition 1 is prepared by admixing the following ingredients:
Composition 1 Ingredient % by weight Aldehyde C10 2.50 Allyl Amyl Glycolate 1.00 Cis-3-hexenyl acetate 1.00 Rose Oxide 0.50 Terpinolene 2.00 Zestover 3.00 Orange terpenes 40.00 Isononyl acetate 5.00 Dorisyl ®1) 10.00 Terpinyl acetate 10.00 Dihydromyrcenol 15.00 Citronellyl nitrile 10.00 Total 100.00
1)p-tert-butyl-cyclohexyl acetate; available from Firmenich SA, Geneva, Switzerland
- Likewise, a comparative fragrance A, is prepared as follows:
Fragrance A Ingredient % by weight Dipropylene glycol 10.00 Orange terpenes 40.00 Isononyl acetate 5.00 Dorisyl ®1) 10.00 Terpinyl acetate 10.00 Dihydromyrcenol 15.00 Citronellyl nitrile 10.00 Total 100.00
1)p-tert-butyl-cyclohexyl acetate; origin: Firmenich SA, Geneva, Switzerland
- Various samples of these two compositions are then incorporated in a dishwashing product having the composition of Example 2 hereof, in the concentration indicated below, and tested for their efficiency in reducing typical cooking and residual food malodors.
- A dishwashing liquid for use in combination with the fragrance components of examples 1 is prepared by combining the following ingredients:
Formula Ingredients % by weight NaLAS 3.71 MgLAS 11.16 NH4 AEOS-1.3EO 14.23 Amine Oxide 6.70 SXS 3.30 Sodium Bisulfite 0.10 Salt 0.22 Ethanol 5.25 Sequestering agent 0.28 Preservative 0.11 Fragrance Component of Ex. 1 or 2 0.60 Water and minors (color, pH BALANCE adjustment) - In the table above:
-
- NaLAS and Mg LAS refer to the sodium and magnesium salts resp. of linear C12-14 alkyl benzene sulfonates.
- NH4AEOS-1.3EO refers to C8-C18 alcohol ethoxylate compounds with an average of 1.3 ethoxy groups.
- Amine oxide refers to C12-14 alkylamido propyl dimethyl amine oxide.
- SXS refers to sodium xylene sulfonate.
Claims (23)
1. A fragrance composition comprising:
a. a decyl aldehyde;
b. an allyl amyl glycolate;
c. cis-3-hexenyl acetate;
d. a rose oxide;
e. a terpinolene; and
f. 2,4-dimethyl-3-cyclohexene-1-carbaldehyde.
2. The composition of claim 1 , further comprising one or more of:
a. an amyl cinnamic aldehyde in an amount of less than about 15%,
b. 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-g-2-benzopyran in an amount of less than about 20%,
c. 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone, in an amount of less than 5%.
3. The composition of claim 1 , wherein the decyl aldehyde is present in an amount of about 0.5 to about 5%.
4. The composition of claim 1 , wherein allyl amyl glycolate is present in an amount of about 0.5 to about 5%.
5. The composition of claim 1 , wherein the cis-3-hexenyl acetate is present in an amount of about 0.1 to about 3%.
6. The composition of claim 1 , wherein the rose oxide is present in an amount of about 0.01 to about 0.5%.
7. The composition of claim 1 , wherein the terpinolene is present in amount of about 0.05 to about 7%.
8. The composition of claim 1 , wherein the 2,4-dimethyl-3-cyclohexene-1-carbaldehyde is present in an amount of about 0.05 to about 2%.
9. The composition of claim 1 , wherein the composition comprises one or more of:
a. amyl cinnamic aldehyde in an amount of less than about 5%,
b. 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-g-2-benzopyran in an amount of less than about 5%, and
c. 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone in an amount of less than about 2%.
10. The composition of claim 1 , further comprising an ingredient selected from an orange terpene; an acetate of a C6-12 alcohol; a C10 unsaturated alcohol; and citronellyl nitrile.
11. A cleaning product comprising:
a. a surfactant and
b. a fragrance composition comprising: a decyl aldehydes, allyl amyl glycolate, cis-3-hexenyl acetate, rose oxide, terpinolene, and 2,4-dimethyl-3-cyclohexene-1-carbaldehyde.
12. The product of claim 11 , wherein surfactant is selected from a nonionic surfactant and a mixture of ionic surfactants and nonionic surfactants.
13. The product of claim 11 , wherein the composition is in a form selected from a liquid, a gel, a powder, and a solid.
14. The product of claim 11 , wherein the surfactant comprises at least one surfactant selected from the group consisting of a cationic surfactant, a nonionic surfactants, C8-C18 linear alkyl benzene sulfonate salt, sulfated alcohol ethoxylates, amine oxide surfactants and amphoteric surfactants.
15. The product of claim 12 comprising by weight:
a. about 5% to about 45% of salts of a C8-C18 linear alkyl sulfonate surfactant;
b. about 1% to about 10% of a C12/C14alkyl amido propyl dimethyl amine oxide surfactant;
c. about 5% to about 35% of a C8-C18 ethoxylated alkyl ether sulfate; and
d. a fragrance composition comprising: decyl aldehydes, allyl amyl glycolate, cis-3-hexenyl acetate, rose oxide, terpinolene, and 2,4-dimethyl-3-cyclohexene-1-carbaldehyde.
16. The product of claim 15 wherein the salt of a C8-C18 linear alkyl sulfonate surfactant is selected from a sodium salt, a magnesium salt, and mixtures thereof.
17. A product comprising:
a. up to about 10% of a C12/C14 alkyl amido propyl dimethyl amine oxide surfactant;
b. up to about 3% of a fragrance composition comprising decyl aldehydes, allyl amyl glycolate, cis-3-hexenyl acetate, rose oxide, terpinolene, and 2,4-dimethyl-3-cyclohexene-1-carbaldehyde;
c. about 5% to about 35% of a C8-C18 ethoxylated alkyl ether sulfate;
d. up to about 10% ethanol;
e. up to about 5% sodium xylene sulfonate;
f. up to about 1% pentasodium pentatate; and
g. up to about 0.5% 1,3-dimethylol-5,5-dimethyl-hydantoin.
18. A method of reducing food malodor in a dishwashing implement comprising applying to the implement a malodor-reducing amount of a dish washing liquid comprising at least four components selected from decyl aldehydes, allyl amyl glycolate, cis-3-hexenyl acetate, rose oxide, terpinolene, and 2,4-dimethyl-3-cyclohexene-1-carbaldehyde.
19. A method of reducing food malodor in a space comprising agitating a mixture of dish washing liquid and water in the space, wherein the fragrance composition comprises at least four components selected from decyl aldehydes, allyl amyl glycolate, cis-3-hexenyl acetate, rose oxide, terpinolene, and 2,4-dimethyl-3-cyclohexene-1-carbaldehyde.
20. The method of claim 19 , wherein the malodor is reduced by at least 55%.
21. The method of claim 19 , wherein the composition further comprises one or more of:
a. n amyl cinnamic aldehyde in an amount of less than about 15%,
b. 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-g-2-benzopyran in an amount of less than about 20%,
c. 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone, in an amount of less than 5%.
22. The method of claim 19 wherein the food malodor has a source selected from components of vegetables of the Family Alliaceae, garlics, chives, shallots, leeks, garden onion, fish, burned food and grease.
23. A dishwashing liquid comprising:
a surfactant and
a fragrance composition comprising at least four selected from: a decyl aldehydes, allyl amyl glycolate, cis-3-hexenyl acetate, rose oxide, terpinolene, and 2,4-dimethyl-3-cyclohexene-1-carbaldehyde.
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US12/553,165 US8404630B2 (en) | 2005-02-15 | 2009-09-03 | Fragrance compositions that reduce or eliminate malodor, related methods and related cleaning compositions |
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- 2006-02-14 CA CA2597885A patent/CA2597885C/en not_active Expired - Fee Related
- 2006-02-14 ES ES06735043T patent/ES2392177T3/en active Active
- 2006-02-14 HN HN2006006763A patent/HN2006006763A/en unknown
- 2006-02-14 PL PL06735043T patent/PL1853689T3/en unknown
- 2006-02-14 WO PCT/US2006/005190 patent/WO2006088878A1/en active Application Filing
- 2006-02-14 NZ NZ560474A patent/NZ560474A/en not_active IP Right Cessation
- 2006-02-14 AU AU2006214427A patent/AU2006214427B2/en not_active Ceased
- 2006-02-14 CA CA2682796A patent/CA2682796C/en not_active Expired - Fee Related
- 2006-02-14 PT PT06735043T patent/PT1853689E/en unknown
- 2006-02-14 EP EP06735043A patent/EP1853689B1/en not_active Revoked
- 2006-02-14 MX MX2007009697A patent/MX2007009697A/en active IP Right Grant
- 2006-02-14 US US11/353,661 patent/US20060183653A1/en not_active Abandoned
- 2006-02-14 DK DK06735043.9T patent/DK1853689T3/en active
- 2006-02-15 MY MYPI20060620A patent/MY148845A/en unknown
- 2006-02-15 UY UY29381A patent/UY29381A1/en not_active Application Discontinuation
-
2007
- 2007-08-12 IL IL185193A patent/IL185193A/en not_active IP Right Cessation
- 2007-09-14 NO NO20074694A patent/NO20074694L/en not_active Application Discontinuation
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2009
- 2009-09-03 US US12/553,165 patent/US8404630B2/en not_active Expired - Fee Related
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EP2380963A1 (en) * | 2010-04-23 | 2011-10-26 | The Procter & Gamble Company | Method of perfuming |
EP2380963B1 (en) | 2010-04-23 | 2015-12-23 | The Procter and Gamble Company | Method of perfuming |
US20210299167A1 (en) * | 2018-12-14 | 2021-09-30 | Ecolab Usa Inc. | Stable iodine-containing antimicrobial teat dip compositions |
Also Published As
Publication number | Publication date |
---|---|
PT1853689E (en) | 2012-10-15 |
AU2006214427A1 (en) | 2006-08-24 |
DK1853689T3 (en) | 2012-11-12 |
MY148845A (en) | 2013-06-14 |
MX2007009697A (en) | 2007-09-13 |
US8404630B2 (en) | 2013-03-26 |
NZ560474A (en) | 2011-03-31 |
EP1853689A1 (en) | 2007-11-14 |
EP1853689B1 (en) | 2012-08-01 |
PL1853689T3 (en) | 2012-12-31 |
CA2597885C (en) | 2012-01-10 |
CA2682796A1 (en) | 2006-08-24 |
HN2006006763A (en) | 2010-08-19 |
US20090325855A1 (en) | 2009-12-31 |
UY29381A1 (en) | 2006-08-31 |
IL185193A (en) | 2013-08-29 |
NO20074694L (en) | 2007-09-14 |
IL185193A0 (en) | 2008-01-06 |
ES2392177T3 (en) | 2012-12-05 |
CA2682796C (en) | 2012-12-18 |
CA2597885A1 (en) | 2006-08-24 |
WO2006088878A1 (en) | 2006-08-24 |
AU2006214427B2 (en) | 2010-04-29 |
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Owner name: COLGATE-PALMOLIVE COMPANY, NEW YORK Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:GAMBOGI, JOAN E.;BRAUCHLI, MARY C.;MARR, GARY J.;AND OTHERS;REEL/FRAME:017627/0501;SIGNING DATES FROM 20060213 TO 20060323 |
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