US20060101808A1 - Engine self-diagnosis system - Google Patents
Engine self-diagnosis system Download PDFInfo
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- US20060101808A1 US20060101808A1 US11/271,988 US27198805A US2006101808A1 US 20060101808 A1 US20060101808 A1 US 20060101808A1 US 27198805 A US27198805 A US 27198805A US 2006101808 A1 US2006101808 A1 US 2006101808A1
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- catalyst
- temperature
- diagnosis system
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- sensor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0814—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N11/00—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity
- F01N11/002—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity the diagnostic devices measuring or estimating temperature or pressure in, or downstream of the exhaust apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N11/00—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity
- F01N11/002—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity the diagnostic devices measuring or estimating temperature or pressure in, or downstream of the exhaust apparatus
- F01N11/005—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity the diagnostic devices measuring or estimating temperature or pressure in, or downstream of the exhaust apparatus the temperature or pressure being estimated, e.g. by means of a theoretical model
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N11/00—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity
- F01N11/007—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity the diagnostic devices measuring oxygen or air concentration downstream of the exhaust apparatus
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0828—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
- F01N3/0835—Hydrocarbons
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2550/00—Monitoring or diagnosing the deterioration of exhaust systems
- F01N2550/02—Catalytic activity of catalytic converters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2550/00—Monitoring or diagnosing the deterioration of exhaust systems
- F01N2550/03—Monitoring or diagnosing the deterioration of exhaust systems of sorbing activity of adsorbents or absorbents
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2560/00—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
- F01N2560/02—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
- F01N2570/12—Hydrocarbons
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/03—Adding substances to exhaust gases the substance being hydrocarbons, e.g. engine fuel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/13—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/40—Engine management systems
Definitions
- the present invention relates to an engine self-diagnosis system, and more particularly to an engine self-diagnosis system capable of performing diagnosis of an exhaust cleaning catalyst, which is provided in an exhaust passage, at a low cost and high accuracy.
- a catalyst for cleaning specific components in engine exhaust is important.
- a catalyst exhibits the exhaust cleaning function at temperatures not lower than a predetermined value.
- a shift into the state where the exhaust cleaning rate is not lower than a predetermined value is called catalyst light-off (or catalyst activation).
- the catalyst diagnosis has hitherto been made on the cleaning capacity after the catalyst light-off.
- Patent Document 1 JP-A-2003-176714 proposes a system for detecting the exhaust component concentration corresponding to both the engine run status and the catalyst operating status by an exhaust component sensor, e.g., an HC sensor, disposed downstream of the catalyst, and the diagnosing, e.g., the light-off performance of the catalyst in accordance with the detected value.
- an exhaust component sensor e.g., an HC sensor
- Patent Document 2 JP-A-5-248227 proposes a diagnosis system including an O 2 sensor downstream of a catalyst and a sensor for detecting the catalyst temperature. Then, when the catalyst performance is diagnosed in accordance with the O 2 sensor downstream of the catalyst, a reference value for use in diagnosis of the catalyst performance is changed in accordance with the detected catalyst temperature.
- any of those proposed diagnosis systems requires an additional new sensor, such as the exhaust component sensor and the temperature sensor, and increases the system cost.
- Patent Document 3 JP-A-2001-3173405 proposes a system for detecting the timing at which the oxygen storage capacity of a catalyst is activated, based on the correlation between output signals of O 2 sensors disposed upstream and downstream of the catalyst, and diagnosing the light-off performance of the catalyst in accordance with the detected timing.
- Such a diagnosis system requires the O 2 sensor downstream of the catalyst to be activated before the catalyst light-off.
- the sensor downstream of the catalyst is generally heated up after the water in the catalyst has been sufficiently evaporated.
- an improvement of the O 2 sensor downstream of the catalyst is required in order to activate that sensor before the catalyst light-off as in the above-mentioned diagnosis system.
- Patent Document 4 JP-A-9-158713 proposes a system in which, in consideration of that the O 2 sensor (or the A/F sensor) downstream of the catalyst is not sufficiently activated during the catalyst light-off, a diagnosis determination value is changed depending on the temperature of the O 2 sensor downstream of the catalyst.
- an object of the present invention is to provide an engine self-diagnosis system capable of performing diagnosis of the light-off performance of a catalyst at a low cost and high accuracy.
- the present invention provides an engine self-diagnosis system comprising a unit for directly or indirectly detecting performance A of an exhaust cleaning catalyst when temperature of the catalyst or temperature of exhaust gas flowing into the catalyst is within a predetermined temperature range; and a unit for, based on the detected catalyst performance A, estimating performance B of the catalyst which is resulted, when the temperature of the catalyst is outside the predetermined temperature range.
- diagnosis (detection) of the catalyst performance after light-off of the catalyst is carried out, and based on the result of the performance diagnosis, the catalyst performance before or during the light-off is estimated for diagnosis.
- static (steady-state) performance of a catalyst after the light-off is decided dominantly depending on the specific surface area (dispersibility) of a precious metal used in the catalyst.
- the light-off performance of the catalyst is also decided dominantly depending on the specific surface area of the precious metal. Accordingly, by detecting the catalyst performance after the light-off, the catalyst performance before or during the light-off can be indirectly estimated (see FIGS. 1 and 17 ).
- the catalyst has at least three-way performance.
- the catalyst is an HC adsorbing combustion catalyst that adsorbs HC when the catalyst temperature is within a predetermined temperature range, desorbs the adsorbed HC when the catalyst temperature exceeds the predetermined temperature range, and cleans the adsorbed and desorbed HC.
- the catalyst is a lean NOx catalyst.
- the diagnosis principle employed in the first form is also applicable.
- the system further comprises a unit for directly or indirectly detecting the temperature of the catalyst; a unit for directly or indirectly detecting the catalyst performance A when the catalyst temperature detected by the detecting unit is within a temperature range in which an exhaust cleaning rate is not smaller than a predetermined value; and a unit for, based on the detected catalyst performance A, estimating the catalyst performance B resulted when the catalyst temperature detected by the detecting unit is within a temperature range in which the exhaust cleaning rate is smaller than the predetermined value (see FIG. 2 ).
- the temperature ranges after and before the light-off are defined respectively depending on that the exhaust cleaning rate is not smaller than or is smaller than the predetermined value.
- the catalyst performance B is a catalyst temperature T 0 at which the exhaust cleaning rate is not smaller than the predetermined value (see FIG. 3 ).
- the catalyst performance B estimated from the directly detected catalyst performance after the light-off is specifically defined as the light-off temperature.
- the system further comprises catalyst deterioration determining unit for determining that the catalyst has deteriorated, when the catalyst temperature T 0 at which the exhaust cleaning rate is not smaller than the predetermined value exceeds a predetermined temperature (see FIG. 4 ).
- the estimated light-off temperature exceeds the predetermined temperature, a time from the engine startup to the catalyst light-off is prolonged and particular components (HC, CO and NOx) in exhaust are increased. In such a condition, therefore, it is determined that the catalyst has deteriorated.
- the catalyst is an HC adsorbing combustion catalyst
- the catalyst deterioration determining unit determines that the HC adsorbing combustion catalyst has deteriorated, when the catalyst temperature T 0 at which the exhaust cleaning rate is not smaller than the predetermined value exceeds a predetermined temperature (see FIG. 4 ).
- the function of the HC adsorbing combustion catalyst is mainly divided into HC adsorbing performance and adsorbed-HC cleaning capacity.
- the adsorbed-HC cleaning capacity developed by a precious metal as a primary component generally deteriorates in a shorter term.
- deterioration diagnosis of the HC adsorbing combustion catalyst is realized by diagnosing the light-off performance in the adsorbed-HC cleaning capacity of the HC adsorbing combustion catalyst.
- the catalyst is a lean NOx catalyst
- the catalyst deterioration determining unit determines that the lean NOx catalyst has deteriorated, when the catalyst temperature T 0 at which the exhaust cleaning rate is not smaller than the predetermined value exceeds a predetermined temperature (see FIG. 4 ).
- this ninth form is based on the fact that the light-off performance in the NOx storage capacity of the lean NOx catalyst also depends on the precious metal in the catalyst.
- the catalyst performance A is exhaust cleaning capacity (see FIG. 5 ).
- the performance detected after the catalyst temperature exceeds the predetermined temperature is defined as the exhaust cleaning capacity of the catalyst.
- the catalyst performance A is oxygen storage capacity (see FIG. 6 ).
- the performance detected after the catalyst temperature exceeds the predetermined temperature is defined as the oxygen storage capacity of the catalyst.
- the oxygen storage capacity (OSC) of a catalyst is decided depending on both the specific surface area (dispersibility) of a precious metal used in the catalyst and the content of an auxiliary catalyst such as ceria (or zirconia). Because the content of the auxiliary catalyst is hardly changed from the initial value, the OSC is substantially decided by sintering (cohesion) of the precious metal. Accordingly, the light-off performance (catalyst characteristic B) of the catalyst is estimated in terms of a sintering degree of the precious metal by diagnosing the OSC.
- the catalyst performance A is given as exhaust cleaning capacity
- the catalyst performance B is given as the catalyst temperature T 0 at which the exhaust cleaning rate is not smaller than the predetermined value (see FIG. 7 ).
- the performance detected after the catalyst temperature exceeds the predetermined temperature is defined as the exhaust cleaning capacity of the catalyst
- the catalyst performance B estimated from the exhaust cleaning capacity after the light-off is specifically defined as the light-off temperature.
- the catalyst performance A is given as oxygen storage capacity
- the catalyst performance B is given as the catalyst temperature T 0 at which the exhaust cleaning rate is not smaller than the predetermined value or the oxygen storage capacity is not smaller than a predetermined value (see FIG. 8 ).
- the performance detected after the catalyst temperature exceeds the predetermined temperature is defined as the oxygen storage capacity of the catalyst
- the catalyst performance B estimated from the oxygen storage capacity after the light-off is specifically defined as the light-off temperature
- the system further comprises an exhaust component detecting unit disposed downstream of the catalyst (see FIG. 9 ).
- exhaust components downstream of the catalyst are directly detected by the exhaust component detecting unit, and the exhaust cleaning rate after the light-off is detected based on the detected exhaust components. Then, the light-off performance is estimated based on the detected cleaning capacity.
- the system further comprises an O 2 sensor or an A/F sensor downstream of the catalyst (see FIG. 10 ).
- the A/F ratio downstream of the catalyst is directly detected by the O 2 sensor or the A/F sensor, and the exhaust cleaning capacity after the light-off is detected based on the detected A/F ratio. Then, the light-off performance is estimated based on the detected cleaning capacity.
- the system further comprises a unit for detecting oxygen storage capacity of the catalyst based on an output signal from the O 2 sensor or the A/F sensor (see FIG. 11 ).
- the A/F ratio downstream of the catalyst is directly detected by the O 2 sensor or the A/F sensor, and the oxygen storage capacity of the catalyst after the light-off is detected based on the detected A/F ratio. Then, the light-off performance is estimated based on the detected oxygen storage capacity.
- the system further comprises a unit for oscillating an O 2 concentration or an air/fuel ratio upstream of the catalyst at a predetermined frequency; a unit for computing a component at the predetermined frequency of the output signal from the O 2 sensor or the A/F sensor; and a unit for detecting oxygen storage capacity of the catalyst based on the computed component at the predetermined frequency (see FIG. 12 ).
- the oscillation of the O 2 concentration or the air/fuel ratio downstream of the catalyst exhibits behaviors differing from those upstream of the catalyst due to the oxygen storage capacity of the catalyst if the catalyst (oxygen storage capacity) is in the light-off state.
- the oxygen storage capacity is detected by executing frequency analysis of the oscillation of the O 2 concentration or the air/fuel ratio downstream of the catalyst, and the light-off performance is estimated based on the detected oxygen storage capacity.
- the system further comprises a unit for changing an O 2 concentration or an air/fuel ratio upstream of the catalyst by a predetermined value; a response delay time computing unit for computing a response delay time from a time at which the O 2 concentration or the air/fuel ratio upstream of the catalyst is changed by a predetermined value to a time at which an output signal from the O 2 sensor downstream of the catalyst is changed by a predetermined value; and a unit for detecting oxygen storage capacity of the catalyst based on the computed response delay time ( FIG. 13 ).
- the response delay time until the O 2 concentration or the air/fuel ratio downstream of the catalyst is changed depends on the oxygen storage capacity of the catalyst if the catalyst (oxygen storage capacity) is in the light-off state. Based on that finding, in the eighteenth form, the oxygen storage capacity is detected by determining the response delay time until the O 2 concentration or the air/fuel ratio downstream of the catalyst is changed, and the light-off performance is estimated based on the detected oxygen storage capacity.
- the system further comprises a unit for raising temperature of the catalyst; a catalyst temperature estimating unit; an O 2 sensor, an A/F sensor, or an exhaust sensor disposed downstream of the catalyst; a unit for directly detecting, based on an output signal from the O 2 sensor, the A/F sensor, or the exhaust sensor, whether the exhaust cleaning rate of the catalyst is not smaller than a predetermined value and the catalyst is in the light-off state; and an abnormality determining unit for determining the catalyst temperature raising unit to be abnormal, when the unit for directly detecting the catalyst light-off does not detect that the catalyst is in the light-off state, in spite of the catalyst temperature estimated by the catalyst temperature estimating unit reaching an estimated light-off temperature representing the catalyst performance B (see FIG. 14 ).
- the nineteenth form is intended to distinctly detect whether the light-off performance of the catalyst has deteriorated or the unit for activating the catalyst in a shorter time (i.e., the catalyst temperature raising unit) has deteriorated.
- the catalyst temperature raising unit determines whether the light-off performance of the catalyst has deteriorated or the unit for activating the catalyst in a shorter time (i.e., the catalyst temperature raising unit) has deteriorated.
- the catalyst temperature raising unit is determined to be abnormal.
- the system further comprises a unit for indicating the catalyst performance A and/or B or information related to the catalyst performance A and/or B.
- the system further comprises a unit for modifying an engine control parameter based on the catalyst performance A and/or B (see FIG. 15 ).
- the engine control parameter is modified based on the catalyst performance determined as described above, to thereby further reduce particular components (HC, CO and NOx) in engine exhaust.
- the system further comprises a unit for modifying a control parameter for the catalyst temperature raising unit based on the catalyst performance B represented by a catalyst temperature T 0 at which an exhaust cleaning rate is not smaller than the predetermined value (see FIG. 16 ).
- a control parameter for engine startup is modified based on the catalyst light-off performance estimated as described above.
- control parameter for the catalyst temperature raising unit is a retard amount of ignition timing and/or a period during which the ignition timing is retarded (see FIG. 16 ).
- the retard amount of ignition timing and/or the period during which the ignition timing is retarded is modified based on the catalyst light-off performance estimated as described above, to thereby activate the catalyst in a shorter time.
- the present invention also provides an automobile equipped with the engine self-diagnosis system constituted as described above.
- FIG. 1 is a block diagram showing first through fourth forms of an engine self-diagnosis system according to the present invention
- FIG. 2 is a block diagram showing a fifth form of the engine self-diagnosis system according to the present invention.
- FIG. 3 is a block diagram showing a sixth form of the engine self-diagnosis system according to the present invention.
- FIG. 4 is a block diagram showing seventh to ninth forms of the engine self-diagnosis system according to the present invention.
- FIG. 5 is a block diagram showing a tenth form of the engine self-diagnosis system according to the present invention.
- FIG. 6 is a block diagram showing an eleventh form of the engine self-diagnosis system according to the present invention.
- FIG. 7 is a block diagram showing a twelfth form of the engine self-diagnosis system according to the present invention.
- FIG. 8 is a block diagram showing a thirteenth form of the engine self-diagnosis system according to the present invention.
- FIG. 9 is a block diagram showing a fourteenth form of the engine self-diagnosis system according to the present invention.
- FIG. 10 is a block diagram showing a fifteenth form of the engine self-diagnosis system according to the present invention.
- FIG. 11 is a block diagram showing a sixteenth form of the engine self-diagnosis system according to the present invention.
- FIG. 12 is a block diagram showing a seventeenth form of the engine self-diagnosis system according to the present invention.
- FIG. 13 is a block diagram showing an eighteenth form of the engine self-diagnosis system according to the present invention.
- FIG. 14 is a block diagram showing a nineteenth form of the engine self-diagnosis system according to the present invention.
- FIG. 15 is a block diagram showing a twenty-first form of the engine self-diagnosis system according to the present invention.
- FIG. 16 is a block diagram showing twenty-second and—third forms of the engine self-diagnosis system according to the present invention.
- FIG. 17 is a graph showing the relationship between the catalyst temperature and the OSC index for explaining the diagnosis principle in the present invention.
- FIG. 18 is a schematic view showing an engine self-diagnosis system according to a first embodiment of the present invention, along with an engine to which the self-diagnosis system is applied;
- FIG. 19 is a block diagram showing the internal configuration of a control unit in the first embodiment of the present invention.
- FIG. 20 is a block diagram showing a control system in the first embodiment
- FIG. 21 is a block diagram for explaining a basic fuel injection amount computing unit in the first embodiment
- FIG. 22 is a block diagram for explaining a deterioration diagnosis permission determining unit in the first embodiment
- FIG. 23 is a block diagram for explaining an air/fuel ratio modification term computing unit in the first embodiment
- FIG. 24 is a block diagram for explaining a target air/fuel ratio computing unit in the first embodiment
- FIG. 25 is a block diagram for explaining a unit for detecting the oxygen storage capacity after the light-off in the first embodiment
- FIG. 26 is a block diagram for explaining a frequency component computing unit in the first embodiment
- FIG. 27 is a block diagram for explaining an oxygen storage capacity computing unit in the first embodiment
- FIG. 28 is a block diagram for explaining a light-off temperature estimating unit in the first embodiment
- FIG. 29 is a block diagram showing a control system in a second embodiment
- FIG. 30 is a block diagram for explaining a target air/fuel ratio computing unit in the second embodiment
- FIG. 31 is a block diagram for explaining a unit for detecting the oxygen storage capacity after the light-off in the second embodiment
- FIG. 32 is a block diagram for explaining a response delay time computing unit in the second embodiment
- FIG. 33 is a block diagram for explaining an oxygen storage capacity computing unit in the second embodiment
- FIG. 34 is a block diagram showing a control system in a third embodiment
- FIG. 35 is a block diagram for explaining a light-off temperature estimating unit in the third embodiment.
- FIG. 36 is a block diagram showing a control system in a fourth embodiment
- FIG. 37 is a block diagram for explaining a deterioration diagnosis permission determining unit in the fourth embodiment.
- FIG. 38 is a block diagram for explaining a light-off temperature estimating unit in the fourth embodiment.
- FIG. 39 is a block diagram for explaining an ignition timing setting unit in the fourth embodiment.
- FIG. 18 is a schematic view showing an engine self-diagnosis system according to a first embodiment of the present invention, along with one example of a vehicle-loaded engine to which the self-diagnosis system is applied.
- An engine 10 shown in FIG. 18 is a multi-cylinder engine having four cylinders, for example, and comprises cylinders 12 and pistons 15 slidably inserted in the cylinders 12 numbered # 1 , # 2 , # 3 and # 4 .
- a combustion chamber 17 is defined above the piston 15 .
- An ignition plug 35 is disposed to face the combustion chamber 17 .
- Air supplied for combustion of fuel is taken in from an air cleaner 21 disposed at a start end of an intake passage 20 and enters a collector 56 through an airflow sensor 24 and an electronically-controlled throttle valve 25 . Then, the intake air is introduced from the collector 56 to the combustion chamber 17 of each cylinder numbered # 1 , # 2 , # 3 or # 4 through an intake valve 28 that is disposed at a downstream end of the intake passage 20 (i.e., at an intake port). Further, a fuel injection valve 30 is disposed at the downstream end of the intake passage 20 .
- a gas mixture of the air introduced to the combustion chamber 17 and fuel injected from the fuel injection valve 30 is ignited by the ignition plug 35 and is burnt for explosion.
- Combustion waste gas (exhaust gas) is discharged through an exhaust valve 48 from the combustion chamber 17 to each individual passage portion 40 A forming an upstream part of an exhaust passage 40 .
- the exhaust gas flows from the individual passage portion 40 A into a three-way catalyst 50 , which is disposed in the exhaust passage 40 , through an exhaust collecting portion 40 B. After cleaning by the three-way catalyst 50 , the exhaust gas is discharged to the exterior.
- An O 2 sensor 51 is disposed in the exhaust passage 40 downstream of the three-way catalyst 50
- an A/F (air/fuel ratio) sensor 52 is disposed in the exhaust passage 40 upstream of the three-way catalyst 50 at a position near the exhaust collecting portion 40 B.
- the A/F sensor 52 has a linear output characteristic for the concentration of oxygen contained in the exhaust gas. Because the relationship between the concentration of oxygen in the exhaust gas and the air/fuel ratio is substantially linear, the air/fuel ratio in the exhaust collecting portion 40 B can be determined based on a signal from the A/F sensor 52 for detecting the oxygen concentration. Also, based on a signal from the O 2 sensor 51 , it is possible to detect the oxygen concentration downstream of the three-way catalyst 50 , or whether the exhaust gas is rich or lean with respect to the stoichiometric air/fuel ratio.
- a part of the exhaust gas discharged from the combustion chamber 17 to the exhaust passage 40 is introduced to the intake passage 20 through an EGR passage 41 , as required, for circulation to the combustion chamber 17 of each cylinder through a branched passage portion of the intake passage 20 .
- An EGR valve 42 for adjusting the EGR rate is disposed in the EGR passage 41 .
- a self-diagnosis system 1 of this embodiment comprises a control unit 100 with a microcomputer incorporated therein for executing various kinds of control of the engine 10 .
- the control unit 100 basically comprises, as shown in FIG. 19 , a CPU 101 , an input circuit 102 , input/output ports 103 , a RAM 104 , a ROM 105 , etc.
- the control unit 100 is supplied with, as input signals, a signal detected by the airflow sensor 24 and corresponding to the intake air amount, a signal detected by a throttle sensor 34 and corresponding to the opening degree of the throttle valve 25 , a signal detected by a crank angle sensor 37 and indicating the rotation (engine rotation speed)/phase of a crankshaft 18 , a signal detected by the O 2 sensor 51 disposed in the exhaust passage 40 downstream of the three-way catalyst 50 and corresponding to the oxygen concentration in the exhaust gas, a signal detected by the A/F sensor 52 disposed in the exhaust collecting portion 40 B of the exhaust passage 40 upstream of the three-way catalyst 50 and corresponding to the oxygen concentration (air/fuel ratio), a signal detected by a water temperature sensor 19 disposed in the cylinder 12 and corresponding to the temperature of the engine cooling water, a signal detected by an accelerator sensor 36 and corresponding to the amount of depression of an accelerator pedal 39 (which represents a torque demanded by a driver), and a signal detected by a vehicle speed sensor 29 and corresponding to the vehicle
- control unit 100 when the signals outputted from the various sensors, such as the A/F sensor 52 , the O 2 sensor 51 , the throttle sensor 34 , the airflow sensor 24 , the crank angle sensor 37 , the water temperature sensor 16 and the accelerator sensor 36 , are inputted, those signals are subjected to signal processing, e.g., removal of noise, in the input circuit 102 and then sent to the input/output ports 103 . Respective values at the input ports are stored in the RAM 104 and are subjected to arithmetic/logical operations in the CPU 101 . A control program describing the contents of the arithmetic/logical operations is written in the ROM 105 beforehand. Values computed in accordance with the control program and representing strokes of various actuators to be operated are stored in the RAM 104 and are sent to the output ports 103 .
- the various sensors such as the A/F sensor 52 , the O 2 sensor 51 , the throttle sensor 34 , the airflow sensor 24 , the crank angle sensor 37 , the water temperature sensor 16
- a signal for operating the ignition plug 35 is set as an on/off signal such that it is turned on when a current is supplied to a primary coil in an ignition output circuit 116 and turned off when a current is not supplied to the primary coil.
- the ignition timing is defined as a time at which the signal is shifted from the on- to off-state.
- the signal for operating the ignition plug 35 which has been set at the output port 103 , is amplified by an ignition output circuit 116 to a level of energy sufficient for ignition and is then supplied to the ignition plug 35 .
- a signal for driving the fuel injection valve 30 i.e., an air/fuel ratio control signal
- the driving signal is amplified by a fuel injection valve driving circuit 117 to a level of energy sufficient for opening the fuel injection valve 30 and is then supplied to the fuel injection valve 30 .
- a driving signal for realizing the target opening degree of the electronically-controlled throttle valve 25 is sent to the electronically-controlled throttle valve 25 through an electronically-controlled throttle valve driving circuit 118 .
- the control unit 100 computes the air/fuel ratio upstream of the three-way catalyst 50 based on the signal from the A/F sensor 52 , and also computes, based on the signal from the O 2 sensor 51 , the oxygen concentration downstream of the three-way catalyst 50 , or whether the exhaust gas is rich or lean with respect to the stoichiometric air/fuel ratio. Further, by using the outputs of both the sensors 51 , 52 , the control unit 100 executes feedback control for sequentially modifying the fuel injection amount or the intake air amount so that the cleaning efficiency of the three-way catalyst 50 is optimized.
- FIG. 20 is a functional block diagram showing a control system in the first embodiment.
- the control unit 100 comprises a basic fuel injection amount computing unit 110 , an air/fuel ratio modification term computing unit 120 , a deterioration diagnosis permission determining unit 130 , a catalyst characteristic A (after-light-off oxygen storage capacity) detecting unit 140 , and a catalyst characteristic B (light-off temperature) estimating unit 150 .
- a catalyst characteristic A after-light-off oxygen storage capacity
- B light-off temperature
- the control unit 100 computes a fuel injection amount Ti for each of the cylinders # 1 -# 4 based on a basic fuel injection amount Tp and an air/fuel ratio modification term Lalpha so that air/fuel ratios of all the cylinders are held at the stoichiometric air/fuel ratio. Then, when deterioration diagnosis is permitted, the control unit 100 oscillates the target air/fuel ratio at a predetermined frequency and estimates the after-light-off oxygen storage capacity (catalyst performance A) of the three-way catalyst 50 in accordance with predetermined frequency components of respective output signals from the A/F sensor 52 and the O 2 sensor 51 . Then, based on the detection result, the control unit 100 estimates the light-off temperature.
- This computing unit 110 computes, based on the engine intake air amount, the fuel injection amount for realizing the target torque and the target air/fuel ratio at the same time under arbitrary operating conditions. Specifically, a basic fuel injection amount Tp is computed as shown in FIG. 21 .
- K is a constant having a value for making adjustment such that the stoichiometric air/fuel ratio is always realized with respect to the intake air amount.
- Cyl represents the number of engine cylinders.
- This permission determining unit 130 determines whether the deterioration diagnosis of the three-way catalyst 50 is permitted.
- Twn is the engine cooling water temperature
- Ne is the engine rotation speed
- Qa is the intake air amount
- ⁇ Ne is the change rate of the engine rotation speed
- ⁇ Qa is the change rate of the intake air amount
- Tcat is the estimated catalyst temperature.
- ⁇ Ne and ⁇ Qa can be each given as the difference between a value computed in the preceding job and a value computed in the current job.
- the catalyst temperature depends on the temperature of the exhaust gas flowing into the catalyst and the temperature of the exhaust gas depends on the intake air amount Qa (fuel injection amount), etc.
- the catalyst temperature can be estimated based on Twn, Qa, an integrated value of Qa, etc. Further details are omitted here for the reason that various methods have already been proposed and are described in many books, papers, etc.
- Tcatdag is preferably set to a temperature at which the three-way catalyst 50 is in the light-off state at a sufficient level.
- This computing unit 120 executes F/B (feedback) control based on the air/fuel ratio detected by the A/F sensor 52 so that the air/fuel ratio at an inlet of the three-way catalyst 50 is held at the target air/fuel ratio under arbitrary operating conditions.
- F/B feedback
- an air/fuel ratio modification term Lalpha is computed with PI control from a deviation Dltabf between a target air/fuel ratio Tabf set by a target air/fuel ratio computing unit 121 and an air/fuel ratio Rabf detected by the A/F sensor.
- the air/fuel ratio modification term Lalpha is multiplied by the basic fuel injection amount Tp.
- Tabf 0 is a value corresponding to the stoichiometric air/fuel ratio
- Tabf 1 R is a value shifted from the stoichiometric air/fuel ratio toward the rich side by a predetermined value
- Tabf 1 L is a value shifted from the stoichiometric air/fuel ratio toward the lean side by a predetermined value.
- the values of Tabf 1 R(L) and fa are preferably decided based on experiments from the viewpoints of diagnosis accuracy and exhaust performance (emission characteristics).
- This detecting unit 140 detects the oxygen storage capacity after the light-off. Specifically, this detection is executed as shown in FIG. 25 .
- This detecting unit 140 comprises a frequency component computing unit 141 for computing respective frequency components of an output Rabf of the A/F sensor 52 and an output RVO 2 of the O 2 sensor 51 , and an oxygen storage capacity computing unit 142 for computing the oxygen storage capacity of the three-way catalyst 50 based on the computed frequency components.
- the frequency component computing unit 141 and the oxygen storage capacity computing unit 142 will be described below.
- This computing unit 141 computes respective frequency components of the output Rabf of the A/F sensor 52 and the output RVO 2 of the O 2 sensor 51 . Specifically, as shown in FIG. 26 , powers (Power 1 and Power 2 ) and phases (Phase 1 and Phase 2 ) at the frequency fa [Hz] are computed from both signals Rabf and RVO 2 with processes using DFT (Discrete Fourier Transform).
- DFT Discrete Fourier Transform
- This computing unit 142 computes the oxygen storage capacity of the three-way catalyst 50 .
- an after-light-off performance deterioration index Ind 13 det 0 is obtained by referring to a map with (Phase 2 -Phase 1 ) and (Power 2 /Power 1 ) being parameters.
- the map used in obtaining Ind 13 det 0 is preferably decided based on experiments from the relationship between the oxygen storage capacity of the three-way catalyst 50 and the exhaust performance.
- This computing unit 150 computes (estimates) the light-off temperature of the three-way catalyst 50 .
- a (estimated) light-off temperature T 0 is obtained, for example, by using a map with the after-light-off performance deterioration index Ind_det 0 being a parameter.
- the map used in obtaining T 0 is preferably decided based on experiment results shown in FIG. 17 , by way of example, from the relationship between a deterioration amount of the oxygen storage capacity after the light-off and a change (rise) amount of the light-off temperature.
- T 0 may be estimated using, e.g., a catalyst model.
- the predetermined value C representing the deterioration limit (in light-off performance) of the three-way catalyst 50 is decided depending on the target exhaust performance (diagnosis performance).
- the target air/fuel ratio is oscillated at the predetermined frequency, and the after-light-off oxygen storage capacity (catalyst performance A) of the three-way catalyst 50 is detected in accordance with the predetermined frequency components of the output signals from the A/F sensor 52 and the O 2 sensor 51 .
- the light-off temperature (catalyst performance B) is then estimated based on the detection result. Therefore, the light-off performance of the catalyst can be diagnosed at a low cost and high accuracy without requiring addition or improvement of a sensor, etc.
- FIG. 29 is a functional block diagram showing a control system in a second embodiment.
- a control unit 100 similar to that in the first embodiment comprises a basic fuel injection amount computing unit 110 , an air/fuel ratio modification term computing unit 120 including a target air/fuel ratio computing unit 221 , a deterioration diagnosis permission determining unit 130 , (the units 110 and 130 being the same as those in the first embodiment), a catalyst characteristic A (after-light-off oxygen storage capacity) detecting unit 240 , and a catalyst characteristic B (light-off temperature) estimating unit 250 .
- a catalyst characteristic A after-light-off oxygen storage capacity
- B catalyst characteristic B
- control unit 100 computes a fuel injection amount Ti per cylinder based on a basic fuel injection amount Tp and an air/fuel ratio modification term Lalpha so that air/fuel ratios of all the cylinders are held at the stoichiometric air/fuel ratio. While that process is the same as that in the first embodiment, this second embodiment differs in the following point.
- the air/fuel ratio is shifted from the stoichiometric air/fuel ratio by a predetermined value for a predetermined time, and the after-light-off oxygen storage capacity (catalyst performance A) of the three-way catalyst 50 is detected in accordance with a response delay time between respective output signals from the A/F sensor 52 and the O 2 sensor 51 . Then, based on the detection result, the control unit 100 estimates the light-off temperature (catalyst characteristic B).
- the units 221 , 240 and 250 executing processing in a different manner from that in the first embodiment will be described in more detail below.
- This response delay time depends on the oxygen storage (release) performance of the three-way catalyst 50 .
- Tabf 0 is a value corresponding to the stoichiometric air/fuel ratio
- Tabf 1 is a value shifted from the stoichiometric air/fuel ratio toward the lean side by a predetermined value.
- the value of Tabf 1 is preferably decided based on experiments from the viewpoints of diagnosis accuracy and exhaust performance.
- This detecting unit 240 detects the oxygen storage capacity after the light-off. Specifically, as shown in FIG. 31 , this detecting unit 240 comprises a response delay time computing unit 241 for computing the response delay time from an output Rabf of the A/F sensor 52 to an output RVO 2 of the O 2 sensor 51 , and an oxygen storage capacity computing unit 242 for computing the oxygen storage capacity of the three-way catalyst 50 based on the computed response delay time.
- the response delay time computing unit 241 and the oxygen storage capacity computing unit 242 will be described in more detail below.
- This computing unit 241 computes the response delay time from the output Rabf of the A/F sensor 52 to the output RVO 2 of the O 2 sensor 51 .
- a response delay time T_det is given as a period from a time at which Rabf ⁇ Tabf 1 —K_Tabf 1 is met to a time at which RVO 2 ⁇ KRVO 2 is met.
- This computing unit 242 computes the oxygen storage capacity of the three-way catalyst 50 .
- an after-light-off performance deterioration index Ind_det 0 is obtained by referring to a map with the response delay time T_det and the intake air amount Qa being parameters.
- the map used in obtaining Ind_det 0 is preferably decided based on experiments from the relationship between the oxygen storage capacity of the three-way catalyst 50 and the exhaust performance.
- Ind_det_NG representing the deterioration limit is decided depending on the target exhaust performance (diagnosis performance).
- This estimating unit 250 is substantially the same as the estimating unit 150 in the first embodiment, and therefore a detailed description thereof is omitted here.
- FIG. 34 is a functional block diagram showing a control system in a third embodiment.
- a control unit 100 similar to that in the first and second embodiments comprises a basic fuel injection amount computing unit 110 , an air/fuel ratio modification term computing unit 120 , a deterioration diagnosis permission determining unit 130 , (these three units being the same as those in the first embodiment), a catalyst characteristic A (after-light-off exhaust cleaning capacity) detecting unit 340 , and a catalyst characteristic B (light-off temperature) estimating unit 350 .
- a NOx sensor 53 is disposed downstream of the three-way catalyst 50 instead of the O 2 sensor. An output signal from the NOx sensor 53 is also supplied to the control unit 100 .
- the control unit 100 computes a fuel injection amount Ti per cylinder based on a basic fuel injection amount Tp and an air/fuel ratio modification term Lalpha so that air/fuel ratios of all the cylinders are held at the stoichiometric air/fuel ratio. While that process is the same as that in the first embodiment, this third embodiment differs in the following point.
- the target air/fuel ratio is oscillated at a predetermined frequency, and the after-light-off exhaust cleaning capacity (catalyst performance A) of the three-way catalyst 50 is detected in accordance with an output signals of the NOx sensor 53 at that time. Then, based on the detection result, the control unit 100 estimates the light-off temperature (catalyst characteristic B).
- the units 340 and 350 executing processing in a different manner from that in the first and second embodiments will be described in more detail below.
- This detecting unit 340 detects the exhaust cleaning capacity after the light-off. Specifically, the detection is executed as shown in FIG. 35 .
- An after-light-off performance deterioration index Ind_det 0 is obtained by referring to a map with an output value RNOx of the NOx sensor 53 and an intake air amount Qa being parameters.
- the map used in obtaining Ind_det 0 is preferably decided based on experiments from the NOx cleaning capacity of the three-way catalyst 50 .
- Ind_det 0 Ind_det_NG
- Ind_det_NG representing the deterioration limit is decided depending on the target exhaust performance (diagnosis performance).
- This estimating unit 350 is substantially the same as the estimating units in the first and second embodiments, and therefore a detailed description thereof is omitted here.
- FIG. 36 is a functional block diagram showing a control system in a fourth embodiment.
- a control unit 100 similar to that in the first through third embodiments comprises a basic fuel injection amount computing unit 110 , an air/fuel ratio modification term computing unit 120 , a deterioration diagnosis permission determining unit 430 , a catalyst characteristic A (after-light-off oxygen storage capacity) detecting unit 440 , a catalyst characteristic B (light-off temperature) estimating unit 450 , and an ignition timing setting unit 160 for, based on the estimated light-off temperature, setting a retard amount of ignition timing at the startup and a period during which the ignition timing is retarded.
- a control unit 100 similar to that in the first through third embodiments comprises a basic fuel injection amount computing unit 110 , an air/fuel ratio modification term computing unit 120 , a deterioration diagnosis permission determining unit 430 , a catalyst characteristic A (after-light-off oxygen storage capacity) detecting unit 440 , a catalyst characteristic B (light-off temperature) estimating unit 450
- the deterioration diagnosis permission determining unit 430 and the catalyst characteristic B (light-off temperature) estimating unit 450 are constituted respectively as shown in FIGS. 37 and 38 .
- the ignition timing setting unit 160 which is not disposed in the above-described embodiments, is constituted as follows.
- This setting unit 160 sets the ignition timing. Specifically, the setting is executed as shown in FIG. 39 .
- Basic ignition timing ADVO is decided based on Tp (basic fuel injection amount) and Ne (engine rotation speed).
- Tp basic fuel injection amount
- Ne engine rotation speed
- the present invention is not limited to the three-way catalyst so long as a catalyst has the three-way performance, and the present invention is also applicable to the cases using an HC adsorbing combustion catalyst, a lean NOx catalyst, etc.
- the present invention can be advantageously applied to the case using the HC adsorbing combustion catalyst because the light-off temperature is a very important factor in deciding the performance of that catalyst.
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- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Exhaust Gas After Treatment (AREA)
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- Electrical Control Of Air Or Fuel Supplied To Internal-Combustion Engine (AREA)
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Abstract
An engine self-diagnosis system capable of performing diagnosis of the light-off performance of a catalyst at a low cost and high accuracy without requiring addition or improvement of a sensor, etc. The engine self-diagnosis system comprises a unit for directly or indirectly detecting performance A of an exhaust cleaning catalyst when temperature of the catalyst is within a predetermined temperature range, and a unit for, based on the detected catalyst performance A, estimating performance B of the catalyst, which is resulted when the temperature of the catalyst is outside the predetermined temperature range.
Description
- 1. Field of the Invention
- The present invention relates to an engine self-diagnosis system, and more particularly to an engine self-diagnosis system capable of performing diagnosis of an exhaust cleaning catalyst, which is provided in an exhaust passage, at a low cost and high accuracy.
- 2. Description of the Related Art
- Recently, higher accuracy in diagnosis of various devices related to the engine exhaust performance has been demanded with severer control applied to self-diagnosis of automobile engines in North America, Europe, Japan, etc. In particular, the diagnosis accuracy of a catalyst for cleaning specific components (HC, CO and NOx) in engine exhaust is important. Generally, a catalyst exhibits the exhaust cleaning function at temperatures not lower than a predetermined value. A shift into the state where the exhaust cleaning rate is not lower than a predetermined value is called catalyst light-off (or catalyst activation). The catalyst diagnosis has hitherto been made on the cleaning capacity after the catalyst light-off. On the other hand, with a recent increase in performance of a catalyst and catalyst control, the amount of the specific components in engine exhaust has been dominantly occupied by the amount exhausted during a period from the engine startup to the catalyst light-off. For that reason, it is important to diagnose the light-off performance of the catalyst.
- As one example of a system for diagnosing the catalyst performance, Patent Document 1 (JP-A-2003-176714) proposes a system for detecting the exhaust component concentration corresponding to both the engine run status and the catalyst operating status by an exhaust component sensor, e.g., an HC sensor, disposed downstream of the catalyst, and the diagnosing, e.g., the light-off performance of the catalyst in accordance with the detected value.
- Also, Patent Document 2 (JP-A-5-248227) proposes a diagnosis system including an O2 sensor downstream of a catalyst and a sensor for detecting the catalyst temperature. Then, when the catalyst performance is diagnosed in accordance with the O2 sensor downstream of the catalyst, a reference value for use in diagnosis of the catalyst performance is changed in accordance with the detected catalyst temperature.
- However, any of those proposed diagnosis systems requires an additional new sensor, such as the exhaust component sensor and the temperature sensor, and increases the system cost.
- Meanwhile, Patent Document 3 (JP-A-2001-317345) proposes a system for detecting the timing at which the oxygen storage capacity of a catalyst is activated, based on the correlation between output signals of O2 sensors disposed upstream and downstream of the catalyst, and diagnosing the light-off performance of the catalyst in accordance with the detected timing.
- Such a diagnosis system requires the O2 sensor downstream of the catalyst to be activated before the catalyst light-off. In practice, however, to avoid the sensor from causing a trouble, e.g., cracking due to the presence of water in the catalyst, the sensor downstream of the catalyst is generally heated up after the water in the catalyst has been sufficiently evaporated. Hence, an improvement of the O2 sensor downstream of the catalyst is required in order to activate that sensor before the catalyst light-off as in the above-mentioned diagnosis system.
- Further, Patent Document 4 (JP-A-9-158713) proposes a system in which, in consideration of that the O2 sensor (or the A/F sensor) downstream of the catalyst is not sufficiently activated during the catalyst light-off, a diagnosis determination value is changed depending on the temperature of the O2 sensor downstream of the catalyst.
- However, such a diagnosis system also requires the O2 sensor downstream of the catalyst to be activated to some extent at the timing of the catalyst light-off, and accompanies a risk of sensor cracking as in the diagnosis system proposed by
Patent Document 3. Moreover, there is a fear that diagnosis accuracy lowers because the diagnosis is performed during activation of the sensor downstream of the catalyst. - All of the above-mentioned diagnosis systems have still another problem that, because light-off characteristics are directly detected, it is difficult to distinctively confirm whether the light-off performance of the catalyst, i.e., the catalyst itself, has deteriorated or the performance of means for raising the temperature of the catalyst has reduced.
- In view of the above-described problems in the related art, an object of the present invention is to provide an engine self-diagnosis system capable of performing diagnosis of the light-off performance of a catalyst at a low cost and high accuracy.
- To achieve the above object, the present invention provides an engine self-diagnosis system comprising a unit for directly or indirectly detecting performance A of an exhaust cleaning catalyst when temperature of the catalyst or temperature of exhaust gas flowing into the catalyst is within a predetermined temperature range; and a unit for, based on the detected catalyst performance A, estimating performance B of the catalyst which is resulted, when the temperature of the catalyst is outside the predetermined temperature range.
- In a first form of the present invention embodying the above features, diagnosis (detection) of the catalyst performance after light-off of the catalyst is carried out, and based on the result of the performance diagnosis, the catalyst performance before or during the light-off is estimated for diagnosis. In general, static (steady-state) performance of a catalyst after the light-off is decided dominantly depending on the specific surface area (dispersibility) of a precious metal used in the catalyst. On the other hand, the light-off performance of the catalyst is also decided dominantly depending on the specific surface area of the precious metal. Accordingly, by detecting the catalyst performance after the light-off, the catalyst performance before or during the light-off can be indirectly estimated (see
FIGS. 1 and 17 ). - In a second form of the engine self-diagnosis system according to the present invention, the catalyst has at least three-way performance.
- In a third form of the engine self-diagnosis system according to the present invention, the catalyst is an HC adsorbing combustion catalyst that adsorbs HC when the catalyst temperature is within a predetermined temperature range, desorbs the adsorbed HC when the catalyst temperature exceeds the predetermined temperature range, and cleans the adsorbed and desorbed HC.
- In a fourth form of the engine self-diagnosis system according to the present invention, the catalyst is a lean NOx catalyst.
- Thus, because the catalysts used in the second, third and fourth forms are all ones using precious metals, the diagnosis principle employed in the first form is also applicable.
- In a fifth form of the engine self-diagnosis system according to the present invention, the system further comprises a unit for directly or indirectly detecting the temperature of the catalyst; a unit for directly or indirectly detecting the catalyst performance A when the catalyst temperature detected by the detecting unit is within a temperature range in which an exhaust cleaning rate is not smaller than a predetermined value; and a unit for, based on the detected catalyst performance A, estimating the catalyst performance B resulted when the catalyst temperature detected by the detecting unit is within a temperature range in which the exhaust cleaning rate is smaller than the predetermined value (see
FIG. 2 ). - Thus, in the fifth form, the temperature ranges after and before the light-off are defined respectively depending on that the exhaust cleaning rate is not smaller than or is smaller than the predetermined value.
- In a sixth form of the engine self-diagnosis system according to the present invention, the catalyst performance B is a catalyst temperature T0 at which the exhaust cleaning rate is not smaller than the predetermined value (see
FIG. 3 ). - Thus, in the sixth form, the catalyst performance B estimated from the directly detected catalyst performance after the light-off is specifically defined as the light-off temperature.
- In a seventh form of the engine self-diagnosis system according to the present invention, the system further comprises catalyst deterioration determining unit for determining that the catalyst has deteriorated, when the catalyst temperature T0 at which the exhaust cleaning rate is not smaller than the predetermined value exceeds a predetermined temperature (see
FIG. 4 ). - Thus, in the seventh form, when the estimated light-off temperature exceeds the predetermined temperature, a time from the engine startup to the catalyst light-off is prolonged and particular components (HC, CO and NOx) in exhaust are increased. In such a condition, therefore, it is determined that the catalyst has deteriorated.
- In an eighth form of the engine self-diagnosis system according to the present invention, the catalyst is an HC adsorbing combustion catalyst, and the catalyst deterioration determining unit determines that the HC adsorbing combustion catalyst has deteriorated, when the catalyst temperature T0 at which the exhaust cleaning rate is not smaller than the predetermined value exceeds a predetermined temperature (see
FIG. 4 ). - The function of the HC adsorbing combustion catalyst is mainly divided into HC adsorbing performance and adsorbed-HC cleaning capacity. However, the adsorbed-HC cleaning capacity developed by a precious metal as a primary component generally deteriorates in a shorter term. Hence, deterioration diagnosis of the HC adsorbing combustion catalyst is realized by diagnosing the light-off performance in the adsorbed-HC cleaning capacity of the HC adsorbing combustion catalyst.
- In a ninth form of the engine self-diagnosis system according to the present invention, the catalyst is a lean NOx catalyst, and the catalyst deterioration determining unit determines that the lean NOx catalyst has deteriorated, when the catalyst temperature T0 at which the exhaust cleaning rate is not smaller than the predetermined value exceeds a predetermined temperature (see
FIG. 4 ). - Thus, this ninth form is based on the fact that the light-off performance in the NOx storage capacity of the lean NOx catalyst also depends on the precious metal in the catalyst.
- In a tenth form of the engine self-diagnosis system according to the present invention, the catalyst performance A is exhaust cleaning capacity (see
FIG. 5 ). - Thus, in the tenth form, the performance detected after the catalyst temperature exceeds the predetermined temperature (i.e., after the light-off) is defined as the exhaust cleaning capacity of the catalyst.
- In an eleventh form of the engine self-diagnosis system according to the present invention, the catalyst performance A is oxygen storage capacity (see
FIG. 6 ). - Thus, in the eleventh form, the performance detected after the catalyst temperature exceeds the predetermined temperature (i.e., after the light-off) is defined as the oxygen storage capacity of the catalyst. The oxygen storage capacity (OSC) of a catalyst is decided depending on both the specific surface area (dispersibility) of a precious metal used in the catalyst and the content of an auxiliary catalyst such as ceria (or zirconia). Because the content of the auxiliary catalyst is hardly changed from the initial value, the OSC is substantially decided by sintering (cohesion) of the precious metal. Accordingly, the light-off performance (catalyst characteristic B) of the catalyst is estimated in terms of a sintering degree of the precious metal by diagnosing the OSC.
- In a twelfth form of the engine self-diagnosis system according to the present invention, the catalyst performance A is given as exhaust cleaning capacity, and the catalyst performance B is given as the catalyst temperature T0 at which the exhaust cleaning rate is not smaller than the predetermined value (see
FIG. 7 ). - Thus, in the twelfth form, the performance detected after the catalyst temperature exceeds the predetermined temperature (i.e., after the light-off) is defined as the exhaust cleaning capacity of the catalyst, and the catalyst performance B estimated from the exhaust cleaning capacity after the light-off is specifically defined as the light-off temperature.
- In a thirteenth form of the engine self-diagnosis system according to the present invention, the catalyst performance A is given as oxygen storage capacity, and the catalyst performance B is given as the catalyst temperature T0 at which the exhaust cleaning rate is not smaller than the predetermined value or the oxygen storage capacity is not smaller than a predetermined value (see
FIG. 8 ). - Thus, in the thirteenth form, the performance detected after the catalyst temperature exceeds the predetermined temperature (i.e., after the light-off) is defined as the oxygen storage capacity of the catalyst, and the catalyst performance B estimated from the oxygen storage capacity after the light-off is specifically defined as the light-off temperature.
- In a fourteenth form of the engine self-diagnosis system according to the present invention, the system further comprises an exhaust component detecting unit disposed downstream of the catalyst (see
FIG. 9 ). - Thus, in the fourteenth form, exhaust components downstream of the catalyst are directly detected by the exhaust component detecting unit, and the exhaust cleaning rate after the light-off is detected based on the detected exhaust components. Then, the light-off performance is estimated based on the detected cleaning capacity.
- In a fifteenth form of the engine self-diagnosis system according to the present invention, the system further comprises an O2 sensor or an A/F sensor downstream of the catalyst (see
FIG. 10 ). - Thus, in the fifteenth form, the A/F ratio downstream of the catalyst is directly detected by the O2 sensor or the A/F sensor, and the exhaust cleaning capacity after the light-off is detected based on the detected A/F ratio. Then, the light-off performance is estimated based on the detected cleaning capacity.
- In a sixteenth form of the engine self-diagnosis system according to the present invention, the system further comprises a unit for detecting oxygen storage capacity of the catalyst based on an output signal from the O2 sensor or the A/F sensor (see
FIG. 11 ). - Thus, in the sixteenth form, the A/F ratio downstream of the catalyst is directly detected by the O2 sensor or the A/F sensor, and the oxygen storage capacity of the catalyst after the light-off is detected based on the detected A/F ratio. Then, the light-off performance is estimated based on the detected oxygen storage capacity.
- In a seventeenth form of the engine self-diagnosis system according to the present invention, the system further comprises a unit for oscillating an O2 concentration or an air/fuel ratio upstream of the catalyst at a predetermined frequency; a unit for computing a component at the predetermined frequency of the output signal from the O2 sensor or the A/F sensor; and a unit for detecting oxygen storage capacity of the catalyst based on the computed component at the predetermined frequency (see
FIG. 12 ). - When the O2 concentration or the air/fuel ratio upstream of the catalyst is oscillated at the predetermined frequency, the oscillation of the O2 concentration or the air/fuel ratio downstream of the catalyst exhibits behaviors differing from those upstream of the catalyst due to the oxygen storage capacity of the catalyst if the catalyst (oxygen storage capacity) is in the light-off state. Based on that finding, in the seventeenth form, the oxygen storage capacity is detected by executing frequency analysis of the oscillation of the O2 concentration or the air/fuel ratio downstream of the catalyst, and the light-off performance is estimated based on the detected oxygen storage capacity.
- In an eighteenth form of the engine self-diagnosis system according to the present invention, the system further comprises a unit for changing an O2 concentration or an air/fuel ratio upstream of the catalyst by a predetermined value; a response delay time computing unit for computing a response delay time from a time at which the O2 concentration or the air/fuel ratio upstream of the catalyst is changed by a predetermined value to a time at which an output signal from the O2 sensor downstream of the catalyst is changed by a predetermined value; and a unit for detecting oxygen storage capacity of the catalyst based on the computed response delay time (
FIG. 13 ). - When the O2 concentration or the air/fuel ratio upstream of the catalyst is changed by the predetermined value, the response delay time until the O2 concentration or the air/fuel ratio downstream of the catalyst is changed depends on the oxygen storage capacity of the catalyst if the catalyst (oxygen storage capacity) is in the light-off state. Based on that finding, in the eighteenth form, the oxygen storage capacity is detected by determining the response delay time until the O2 concentration or the air/fuel ratio downstream of the catalyst is changed, and the light-off performance is estimated based on the detected oxygen storage capacity.
- In a nineteenth form of the engine self-diagnosis system according to the present invention, the system further comprises a unit for raising temperature of the catalyst; a catalyst temperature estimating unit; an O2 sensor, an A/F sensor, or an exhaust sensor disposed downstream of the catalyst; a unit for directly detecting, based on an output signal from the O2 sensor, the A/F sensor, or the exhaust sensor, whether the exhaust cleaning rate of the catalyst is not smaller than a predetermined value and the catalyst is in the light-off state; and an abnormality determining unit for determining the catalyst temperature raising unit to be abnormal, when the unit for directly detecting the catalyst light-off does not detect that the catalyst is in the light-off state, in spite of the catalyst temperature estimated by the catalyst temperature estimating unit reaching an estimated light-off temperature representing the catalyst performance B (see
FIG. 14 ). - Thus, the nineteenth form is intended to distinctly detect whether the light-off performance of the catalyst has deteriorated or the unit for activating the catalyst in a shorter time (i.e., the catalyst temperature raising unit) has deteriorated. Specifically, when the estimated catalyst temperature (not actual temperature) reaches the estimated light-off temperature, the catalyst should have been (normally) brought into the light-off state. Taking into account that point, whether the catalyst is in the light-off state or not is detected by using, e.g., the O2 sensor, the A/F sensor, or the exhaust sensor. If the detection result shows that the catalyst is not in the light-off state, this is determined as indicating that the catalyst temperature does not reach the light-off temperature. Then, the catalyst temperature raising unit is determined to be abnormal.
- In a twentieth form of the engine self-diagnosis system according to the present invention, the system further comprises a unit for indicating the catalyst performance A and/or B or information related to the catalyst performance A and/or B.
- In a twenty-first form of the engine self-diagnosis system according to the present invention, the system further comprises a unit for modifying an engine control parameter based on the catalyst performance A and/or B (see
FIG. 15 ). - Thus, the engine control parameter is modified based on the catalyst performance determined as described above, to thereby further reduce particular components (HC, CO and NOx) in engine exhaust.
- In a twenty-second form of the engine self-diagnosis system according to the present invention, the system further comprises a unit for modifying a control parameter for the catalyst temperature raising unit based on the catalyst performance B represented by a catalyst temperature T0 at which an exhaust cleaning rate is not smaller than the predetermined value (see
FIG. 16 ). - Thus, in the twenty-second form, for example, a control parameter for engine startup is modified based on the catalyst light-off performance estimated as described above.
- In a twenty-third form of the engine self-diagnosis system according to the present invention, the control parameter for the catalyst temperature raising unit is a retard amount of ignition timing and/or a period during which the ignition timing is retarded (see
FIG. 16 ). - Thus, in the twenty-third form, for example, the retard amount of ignition timing and/or the period during which the ignition timing is retarded is modified based on the catalyst light-off performance estimated as described above, to thereby activate the catalyst in a shorter time.
- In addition, the present invention also provides an automobile equipped with the engine self-diagnosis system constituted as described above.
- With the engine self-diagnosis system according to the present invention, the catalyst performance A after the light-off of the catalyst is detected for diagnosis, and the catalyst performance before or during the light-off (i.e., the catalyst performance B) is estimated based on the result of the detection and diagnosis. Therefore, the light-off performance of the catalyst can be diagnosed at a low cost and high accuracy without requiring addition or improvement of a sensor, etc.
-
FIG. 1 is a block diagram showing first through fourth forms of an engine self-diagnosis system according to the present invention; -
FIG. 2 is a block diagram showing a fifth form of the engine self-diagnosis system according to the present invention; -
FIG. 3 is a block diagram showing a sixth form of the engine self-diagnosis system according to the present invention; -
FIG. 4 is a block diagram showing seventh to ninth forms of the engine self-diagnosis system according to the present invention; -
FIG. 5 is a block diagram showing a tenth form of the engine self-diagnosis system according to the present invention; -
FIG. 6 is a block diagram showing an eleventh form of the engine self-diagnosis system according to the present invention; -
FIG. 7 is a block diagram showing a twelfth form of the engine self-diagnosis system according to the present invention; -
FIG. 8 is a block diagram showing a thirteenth form of the engine self-diagnosis system according to the present invention; -
FIG. 9 is a block diagram showing a fourteenth form of the engine self-diagnosis system according to the present invention; -
FIG. 10 is a block diagram showing a fifteenth form of the engine self-diagnosis system according to the present invention; -
FIG. 11 is a block diagram showing a sixteenth form of the engine self-diagnosis system according to the present invention; -
FIG. 12 is a block diagram showing a seventeenth form of the engine self-diagnosis system according to the present invention; -
FIG. 13 is a block diagram showing an eighteenth form of the engine self-diagnosis system according to the present invention; -
FIG. 14 is a block diagram showing a nineteenth form of the engine self-diagnosis system according to the present invention; -
FIG. 15 is a block diagram showing a twenty-first form of the engine self-diagnosis system according to the present invention; -
FIG. 16 is a block diagram showing twenty-second and—third forms of the engine self-diagnosis system according to the present invention; -
FIG. 17 is a graph showing the relationship between the catalyst temperature and the OSC index for explaining the diagnosis principle in the present invention; -
FIG. 18 is a schematic view showing an engine self-diagnosis system according to a first embodiment of the present invention, along with an engine to which the self-diagnosis system is applied; -
FIG. 19 is a block diagram showing the internal configuration of a control unit in the first embodiment of the present invention; -
FIG. 20 is a block diagram showing a control system in the first embodiment; -
FIG. 21 is a block diagram for explaining a basic fuel injection amount computing unit in the first embodiment; -
FIG. 22 is a block diagram for explaining a deterioration diagnosis permission determining unit in the first embodiment; -
FIG. 23 is a block diagram for explaining an air/fuel ratio modification term computing unit in the first embodiment; -
FIG. 24 is a block diagram for explaining a target air/fuel ratio computing unit in the first embodiment; -
FIG. 25 is a block diagram for explaining a unit for detecting the oxygen storage capacity after the light-off in the first embodiment; -
FIG. 26 is a block diagram for explaining a frequency component computing unit in the first embodiment; -
FIG. 27 is a block diagram for explaining an oxygen storage capacity computing unit in the first embodiment; -
FIG. 28 is a block diagram for explaining a light-off temperature estimating unit in the first embodiment; -
FIG. 29 is a block diagram showing a control system in a second embodiment; -
FIG. 30 is a block diagram for explaining a target air/fuel ratio computing unit in the second embodiment; -
FIG. 31 is a block diagram for explaining a unit for detecting the oxygen storage capacity after the light-off in the second embodiment; -
FIG. 32 is a block diagram for explaining a response delay time computing unit in the second embodiment; -
FIG. 33 is a block diagram for explaining an oxygen storage capacity computing unit in the second embodiment; -
FIG. 34 is a block diagram showing a control system in a third embodiment; -
FIG. 35 is a block diagram for explaining a light-off temperature estimating unit in the third embodiment; -
FIG. 36 is a block diagram showing a control system in a fourth embodiment; -
FIG. 37 is a block diagram for explaining a deterioration diagnosis permission determining unit in the fourth embodiment; -
FIG. 38 is a block diagram for explaining a light-off temperature estimating unit in the fourth embodiment; and -
FIG. 39 is a block diagram for explaining an ignition timing setting unit in the fourth embodiment. - Embodiments of the present invention will be described below with reference to the drawings.
-
FIG. 18 is a schematic view showing an engine self-diagnosis system according to a first embodiment of the present invention, along with one example of a vehicle-loaded engine to which the self-diagnosis system is applied. - An
engine 10 shown inFIG. 18 is a multi-cylinder engine having four cylinders, for example, and comprisescylinders 12 andpistons 15 slidably inserted in thecylinders 12 numbered #1, #2, #3 and #4. Acombustion chamber 17 is defined above thepiston 15. An ignition plug 35 is disposed to face thecombustion chamber 17. - Air supplied for combustion of fuel is taken in from an air cleaner 21 disposed at a start end of an
intake passage 20 and enters acollector 56 through anairflow sensor 24 and an electronically-controlledthrottle valve 25. Then, the intake air is introduced from thecollector 56 to thecombustion chamber 17 of each cylinder numbered #1, #2, #3 or #4 through anintake valve 28 that is disposed at a downstream end of the intake passage 20 (i.e., at an intake port). Further, afuel injection valve 30 is disposed at the downstream end of theintake passage 20. - A gas mixture of the air introduced to the
combustion chamber 17 and fuel injected from thefuel injection valve 30 is ignited by theignition plug 35 and is burnt for explosion. Combustion waste gas (exhaust gas) is discharged through anexhaust valve 48 from thecombustion chamber 17 to eachindividual passage portion 40A forming an upstream part of anexhaust passage 40. Then, the exhaust gas flows from theindividual passage portion 40A into a three-way catalyst 50, which is disposed in theexhaust passage 40, through anexhaust collecting portion 40B. After cleaning by the three-way catalyst 50, the exhaust gas is discharged to the exterior. - An O2 sensor 51 is disposed in the
exhaust passage 40 downstream of the three-way catalyst 50, and an A/F (air/fuel ratio)sensor 52 is disposed in theexhaust passage 40 upstream of the three-way catalyst 50 at a position near theexhaust collecting portion 40B. - The A/
F sensor 52 has a linear output characteristic for the concentration of oxygen contained in the exhaust gas. Because the relationship between the concentration of oxygen in the exhaust gas and the air/fuel ratio is substantially linear, the air/fuel ratio in theexhaust collecting portion 40B can be determined based on a signal from the A/F sensor 52 for detecting the oxygen concentration. Also, based on a signal from the O2 sensor 51, it is possible to detect the oxygen concentration downstream of the three-way catalyst 50, or whether the exhaust gas is rich or lean with respect to the stoichiometric air/fuel ratio. - Further, a part of the exhaust gas discharged from the
combustion chamber 17 to theexhaust passage 40 is introduced to theintake passage 20 through anEGR passage 41, as required, for circulation to thecombustion chamber 17 of each cylinder through a branched passage portion of theintake passage 20. AnEGR valve 42 for adjusting the EGR rate is disposed in theEGR passage 41. - A self-
diagnosis system 1 of this embodiment comprises acontrol unit 100 with a microcomputer incorporated therein for executing various kinds of control of theengine 10. - The
control unit 100 basically comprises, as shown inFIG. 19 , aCPU 101, aninput circuit 102, input/output ports 103, aRAM 104, aROM 105, etc. - The
control unit 100 is supplied with, as input signals, a signal detected by theairflow sensor 24 and corresponding to the intake air amount, a signal detected by athrottle sensor 34 and corresponding to the opening degree of thethrottle valve 25, a signal detected by acrank angle sensor 37 and indicating the rotation (engine rotation speed)/phase of acrankshaft 18, a signal detected by the O2 sensor 51 disposed in theexhaust passage 40 downstream of the three-way catalyst 50 and corresponding to the oxygen concentration in the exhaust gas, a signal detected by the A/F sensor 52 disposed in theexhaust collecting portion 40B of theexhaust passage 40 upstream of the three-way catalyst 50 and corresponding to the oxygen concentration (air/fuel ratio), a signal detected by awater temperature sensor 19 disposed in thecylinder 12 and corresponding to the temperature of the engine cooling water, a signal detected by anaccelerator sensor 36 and corresponding to the amount of depression of an accelerator pedal 39 (which represents a torque demanded by a driver), and a signal detected by avehicle speed sensor 29 and corresponding to the vehicle speed of an automobile in which theengine 10 is mounted. - In the
control unit 100, when the signals outputted from the various sensors, such as the A/F sensor 52, the O2 sensor 51, thethrottle sensor 34, theairflow sensor 24, thecrank angle sensor 37, the water temperature sensor 16 and theaccelerator sensor 36, are inputted, those signals are subjected to signal processing, e.g., removal of noise, in theinput circuit 102 and then sent to the input/output ports 103. Respective values at the input ports are stored in theRAM 104 and are subjected to arithmetic/logical operations in theCPU 101. A control program describing the contents of the arithmetic/logical operations is written in theROM 105 beforehand. Values computed in accordance with the control program and representing strokes of various actuators to be operated are stored in theRAM 104 and are sent to theoutput ports 103. - A signal for operating the
ignition plug 35 is set as an on/off signal such that it is turned on when a current is supplied to a primary coil in anignition output circuit 116 and turned off when a current is not supplied to the primary coil. The ignition timing is defined as a time at which the signal is shifted from the on- to off-state. The signal for operating theignition plug 35, which has been set at theoutput port 103, is amplified by anignition output circuit 116 to a level of energy sufficient for ignition and is then supplied to theignition plug 35. Also, a signal for driving the fuel injection valve 30 (i.e., an air/fuel ratio control signal) is set as an on/off signal such that it is turned on when thefuel injection valve 30 is opened and turned off when it is closed. The driving signal is amplified by a fuel injectionvalve driving circuit 117 to a level of energy sufficient for opening thefuel injection valve 30 and is then supplied to thefuel injection valve 30. A driving signal for realizing the target opening degree of the electronically-controlledthrottle valve 25 is sent to the electronically-controlledthrottle valve 25 through an electronically-controlled throttlevalve driving circuit 118. - The
control unit 100 computes the air/fuel ratio upstream of the three-way catalyst 50 based on the signal from the A/F sensor 52, and also computes, based on the signal from the O2 sensor 51, the oxygen concentration downstream of the three-way catalyst 50, or whether the exhaust gas is rich or lean with respect to the stoichiometric air/fuel ratio. Further, by using the outputs of both thesensors control unit 100 executes feedback control for sequentially modifying the fuel injection amount or the intake air amount so that the cleaning efficiency of the three-way catalyst 50 is optimized. - Performance diagnosis of the three-
way catalyst 50 executed by thecontrol unit 100 will be described in more detail below. -
FIG. 20 is a functional block diagram showing a control system in the first embodiment. As shown in the functional block diagram, thecontrol unit 100 comprises a basic fuel injectionamount computing unit 110, an air/fuel ratio modificationterm computing unit 120, a deterioration diagnosispermission determining unit 130, a catalyst characteristic A (after-light-off oxygen storage capacity) detectingunit 140, and a catalyst characteristic B (light-off temperature)estimating unit 150. - In an ordinary mode, the
control unit 100 computes a fuel injection amount Ti for each of the cylinders #1-#4 based on a basic fuel injection amount Tp and an air/fuel ratio modification term Lalpha so that air/fuel ratios of all the cylinders are held at the stoichiometric air/fuel ratio. Then, when deterioration diagnosis is permitted, thecontrol unit 100 oscillates the target air/fuel ratio at a predetermined frequency and estimates the after-light-off oxygen storage capacity (catalyst performance A) of the three-way catalyst 50 in accordance with predetermined frequency components of respective output signals from the A/F sensor 52 and the O2 sensor 51. Then, based on the detection result, thecontrol unit 100 estimates the light-off temperature. - Each of the processing units will be described in more detail below.
- <Basic Fuel Injection Amount Computing Unit 110 (
FIG. 21 )> - This
computing unit 110 computes, based on the engine intake air amount, the fuel injection amount for realizing the target torque and the target air/fuel ratio at the same time under arbitrary operating conditions. Specifically, a basic fuel injection amount Tp is computed as shown inFIG. 21 . InFIG. 21 , K is a constant having a value for making adjustment such that the stoichiometric air/fuel ratio is always realized with respect to the intake air amount. Also, Cyl represents the number of engine cylinders. - <Deterioration Diagnosis Permission Determining Unit 130 (
FIG. 22 )> - This
permission determining unit 130 determines whether the deterioration diagnosis of the three-way catalyst 50 is permitted. - Specifically, as shown in
FIG. 22 , when Twn≧Twndag, NedagH≧Ne≧NedagL, QadagH≧Qa≧QadagL, ΔNe≦DNedag, ΔQa≦Dqadag, and Tcat≧Tcatdag are all satisfied, a deterioration diagnosis permission flag Fpdag=1 is set to permit the deterioration diagnosis. Otherwise, Fpdag=0 is set to inhibit the deterioration diagnosis. - In
FIG. 22 , Twn is the engine cooling water temperature, Ne is the engine rotation speed, Qa is the intake air amount, ΔNe is the change rate of the engine rotation speed, ΔQa is the change rate of the intake air amount, and Tcat is the estimated catalyst temperature. - ΔNe and ΔQa can be each given as the difference between a value computed in the preceding job and a value computed in the current job. Also, because the catalyst temperature depends on the temperature of the exhaust gas flowing into the catalyst and the temperature of the exhaust gas depends on the intake air amount Qa (fuel injection amount), etc., the catalyst temperature can be estimated based on Twn, Qa, an integrated value of Qa, etc. Further details are omitted here for the reason that various methods have already been proposed and are described in many books, papers, etc. Tcatdag is preferably set to a temperature at which the three-
way catalyst 50 is in the light-off state at a sufficient level. - <Air/Fuel Ratio Modification Term Computing Unit 120 (
FIG. 23 )> - This
computing unit 120 executes F/B (feedback) control based on the air/fuel ratio detected by the A/F sensor 52 so that the air/fuel ratio at an inlet of the three-way catalyst 50 is held at the target air/fuel ratio under arbitrary operating conditions. Specifically, as shown inFIG. 23 , an air/fuel ratio modification term Lalpha is computed with PI control from a deviation Dltabf between a target air/fuel ratio Tabf set by a target air/fuelratio computing unit 121 and an air/fuel ratio Rabf detected by the A/F sensor. The air/fuel ratio modification term Lalpha is multiplied by the basic fuel injection amount Tp. - <Target Air/Fuel Ratio Computing Unit 121 (Frequency Response) (
FIG. 24 )> - This
computing unit 121 computes the target air/fuel ratio in a frequency response manner. Specifically, this computation is executed as shown inFIG. 24 . When Fpdag=1 holds, a target air/fuel ratio Tabf1L and a target air/fuel ratio Tab0 are switched over at a frequency fa [Hz]. Otherwise, an ordinary target air/fuel ratio Tabf0 is set. In this embodiment, Tabf0 is a value corresponding to the stoichiometric air/fuel ratio, Tabf1R is a value shifted from the stoichiometric air/fuel ratio toward the rich side by a predetermined value, and Tabf1L is a value shifted from the stoichiometric air/fuel ratio toward the lean side by a predetermined value. The values of Tabf1R(L) and fa are preferably decided based on experiments from the viewpoints of diagnosis accuracy and exhaust performance (emission characteristics). - <After-Light-Off Oxygen Storage capacity Detecting Unit 140 (Frequency Response) (
FIG. 25 )> - This detecting
unit 140 detects the oxygen storage capacity after the light-off. Specifically, this detection is executed as shown inFIG. 25 . This detectingunit 140 comprises a frequencycomponent computing unit 141 for computing respective frequency components of an output Rabf of the A/F sensor 52 and an output RVO2 of the O2 sensor 51, and an oxygen storagecapacity computing unit 142 for computing the oxygen storage capacity of the three-way catalyst 50 based on the computed frequency components. - The frequency
component computing unit 141 and the oxygen storagecapacity computing unit 142 will be described below. - <Frequency Component Computing Unit 141 (
FIG. 26 )> - This
computing unit 141 computes respective frequency components of the output Rabf of the A/F sensor 52 and the output RVO2 of the O2 sensor 51. Specifically, as shown inFIG. 26 , powers (Power1 and Power2) and phases (Phase1 and Phase2) at the frequency fa [Hz] are computed from both signals Rabf and RVO2 with processes using DFT (Discrete Fourier Transform). - <Oxygen Storage capacity Computing Unit 142 (
FIG. 27 )> - This
computing unit 142 computes the oxygen storage capacity of the three-way catalyst 50. Specifically, as shown inFIG. 27 , an after-light-off performance deterioration index Ind13det0 is obtained by referring to a map with (Phase2-Phase1) and (Power2/Power1) being parameters. The map used in obtaining Ind13det0 is preferably decided based on experiments from the relationship between the oxygen storage capacity of the three-way catalyst 50 and the exhaust performance. Also, in the state of (Phase2-Phase1)≧(predetermined value A) and (Power2/Power1)≧(predetermined value B), this is determined as indicating that the oxygen storage capacity (catalyst performance) has deteriorated to a limit, whereupon an after-light-off performance deterioration flag Fdet0=1 is set. Note that the predetermined value A and the predetermined value B representing the deterioration limit are decided depending on the target exhaust performance (diagnosis performance). - <Light-Off Temperature Estimating Unit 150 (
FIG. 28 )> - This
computing unit 150 computes (estimates) the light-off temperature of the three-way catalyst 50. Specifically, as shown inFIG. 28 , a (estimated) light-off temperature T0 is obtained, for example, by using a map with the after-light-off performance deterioration index Ind_det0 being a parameter. The map used in obtaining T0 is preferably decided based on experiment results shown inFIG. 17 , by way of example, from the relationship between a deterioration amount of the oxygen storage capacity after the light-off and a change (rise) amount of the light-off temperature. As an alternative, T0 may be estimated using, e.g., a catalyst model. Also, in the state of T0≧(predetermined value C) or the after-light-off performance deterioration flag Fdet0=1, this is determined as indicating that the three-way catalyst 50 has exceeded its performance limit, whereupon a deterioration indicator lamp illuminating flag Fdet=1 is set, for example, to illuminate adeterioration indicator lamp 27 for providing an indication to the exterior. Note that the predetermined value C representing the deterioration limit (in light-off performance) of the three-way catalyst 50 is decided depending on the target exhaust performance (diagnosis performance). - As understood from the above description, with the self-
diagnosis system 10 of this embodiment, the target air/fuel ratio is oscillated at the predetermined frequency, and the after-light-off oxygen storage capacity (catalyst performance A) of the three-way catalyst 50 is detected in accordance with the predetermined frequency components of the output signals from the A/F sensor 52 and the O2 sensor 51. The light-off temperature (catalyst performance B) is then estimated based on the detection result. Therefore, the light-off performance of the catalyst can be diagnosed at a low cost and high accuracy without requiring addition or improvement of a sensor, etc. -
FIG. 29 is a functional block diagram showing a control system in a second embodiment. As shown in the functional block diagram, acontrol unit 100 similar to that in the first embodiment comprises a basic fuel injectionamount computing unit 110, an air/fuel ratio modificationterm computing unit 120 including a target air/fuelratio computing unit 221, a deterioration diagnosispermission determining unit 130, (theunits unit 240, and a catalyst characteristic B (light-off temperature)estimating unit 250. - In an ordinary mode, the
control unit 100 computes a fuel injection amount Ti per cylinder based on a basic fuel injection amount Tp and an air/fuel ratio modification term Lalpha so that air/fuel ratios of all the cylinders are held at the stoichiometric air/fuel ratio. While that process is the same as that in the first embodiment, this second embodiment differs in the following point. When the deterioration diagnosis is permitted, the air/fuel ratio is shifted from the stoichiometric air/fuel ratio by a predetermined value for a predetermined time, and the after-light-off oxygen storage capacity (catalyst performance A) of the three-way catalyst 50 is detected in accordance with a response delay time between respective output signals from the A/F sensor 52 and the O2 sensor 51. Then, based on the detection result, thecontrol unit 100 estimates the light-off temperature (catalyst characteristic B). - The
units - <Target Air/Fuel Ratio Computing Unit 221 (step response) (
FIG. 30 )> - This
computing unit 221 is substituted for the target air/fuel ratio computing unit 121 (seeFIG. 24 ) included in the air/fuel ratio modification term computing unit 120 (seeFIG. 23 ) in the first embodiment. Specifically, the target air/fuelratio computing unit 221 executes the processing shown inFIG. 30 . When Fpdag=1 holds, the target air/fuel ratio is set to a diagnosis-mode target air/fuel ratio Tabf1. Otherwise, an ordinary target air/fuel ratio Tabf0 is set. More specifically, a response delay time occurs from a time at which the output of the A/F sensor 52 has reached a level corresponding to Tabf1 to a time at which the output of the O2 sensor 51 has reached a level corresponding to Tabf1. This response delay time depends on the oxygen storage (release) performance of the three-way catalyst 50. In this embodiment, Tabf0 is a value corresponding to the stoichiometric air/fuel ratio, and Tabf1 is a value shifted from the stoichiometric air/fuel ratio toward the lean side by a predetermined value. The value of Tabf1 is preferably decided based on experiments from the viewpoints of diagnosis accuracy and exhaust performance. - <After-Light-Off Oxygen Storage capacity Detecting Unit 240 (Step Response) (
FIG. 31 )> - This detecting
unit 240 detects the oxygen storage capacity after the light-off. Specifically, as shown inFIG. 31 , this detectingunit 240 comprises a response delaytime computing unit 241 for computing the response delay time from an output Rabf of the A/F sensor 52 to an output RVO2 of the O2 sensor 51, and an oxygen storagecapacity computing unit 242 for computing the oxygen storage capacity of the three-way catalyst 50 based on the computed response delay time. - The response delay
time computing unit 241 and the oxygen storagecapacity computing unit 242 will be described in more detail below. - <Response Delay Time Computing Unit 241 (
FIG. 32 )> - This
computing unit 241 computes the response delay time from the output Rabf of the A/F sensor 52 to the output RVO2 of the O2 sensor 51. Specifically, as shown inFIG. 32 , when Fpdag=1 holds and the target air/fuelratio computing unit 221 sets the diagnosis-mode target air/fuel ratio Tabf1, a response delay time T_det is given as a period from a time at which Rabf≧Tabf1—K_Tabf1 is met to a time at which RVO2≦KRVO2 is met. - <Oxygen Storage capacity Computing Unit 242 (
FIG. 33 )> - This
computing unit 242 computes the oxygen storage capacity of the three-way catalyst 50. Specifically, as shown inFIG. 33 , an after-light-off performance deterioration index Ind_det0 is obtained by referring to a map with the response delay time T_det and the intake air amount Qa being parameters. The map used in obtaining Ind_det0 is preferably decided based on experiments from the relationship between the oxygen storage capacity of the three-way catalyst 50 and the exhaust performance. Also, in the state of Ind_det0≧Ind_det_NG, this is determined as indicating that the oxygen storage capacity (catalyst performance) has deteriorated to a limit, whereupon an after-light-off performance deterioration flag Fdet0=1 is set. Note that Ind_det_NG representing the deterioration limit is decided depending on the target exhaust performance (diagnosis performance). - <Light-Off
Temperature Estimating Unit 250> - This
estimating unit 250 is substantially the same as theestimating unit 150 in the first embodiment, and therefore a detailed description thereof is omitted here. -
FIG. 34 is a functional block diagram showing a control system in a third embodiment. As shown in the functional block diagram, acontrol unit 100 similar to that in the first and second embodiments comprises a basic fuel injectionamount computing unit 110, an air/fuel ratio modificationterm computing unit 120, a deterioration diagnosispermission determining unit 130, (these three units being the same as those in the first embodiment), a catalyst characteristic A (after-light-off exhaust cleaning capacity) detectingunit 340, and a catalyst characteristic B (light-off temperature)estimating unit 350. In this third embodiment, a NOx sensor 53 is disposed downstream of the three-way catalyst 50 instead of the O2 sensor. An output signal from the NOx sensor 53 is also supplied to thecontrol unit 100. - In an ordinary mode, the
control unit 100 computes a fuel injection amount Ti per cylinder based on a basic fuel injection amount Tp and an air/fuel ratio modification term Lalpha so that air/fuel ratios of all the cylinders are held at the stoichiometric air/fuel ratio. While that process is the same as that in the first embodiment, this third embodiment differs in the following point. When the deterioration diagnosis is permitted, the target air/fuel ratio is oscillated at a predetermined frequency, and the after-light-off exhaust cleaning capacity (catalyst performance A) of the three-way catalyst 50 is detected in accordance with an output signals of the NOx sensor 53 at that time. Then, based on the detection result, thecontrol unit 100 estimates the light-off temperature (catalyst characteristic B). - The
units - <After-Light-Off Exhaust Cleaning Capacity Detecting Unit 340 (
FIG. 35 )> - This detecting
unit 340 detects the exhaust cleaning capacity after the light-off. Specifically, the detection is executed as shown inFIG. 35 . An after-light-off performance deterioration index Ind_det0 is obtained by referring to a map with an output value RNOx of the NOx sensor 53 and an intake air amount Qa being parameters. The map used in obtaining Ind_det0 is preferably decided based on experiments from the NOx cleaning capacity of the three-way catalyst 50. Also, in the state of Ind_det0≧Ind_det_NG, this is determined as indicating that the exhaust cleaning capacity (catalyst performance) has deteriorated to a limit, whereupon an after-light-off performance deterioration flag Fdet0=1 is set. Note that Ind_det_NG representing the deterioration limit is decided depending on the target exhaust performance (diagnosis performance). - <Light-Off Temperature Estimating Unit 350 (
FIG. 34 )> - This
estimating unit 350 is substantially the same as the estimating units in the first and second embodiments, and therefore a detailed description thereof is omitted here. - While this third embodiment employs the NOx sensor, similar processing to that described above can also be executed by using, for example, an HC sensor or a CO sensor.
-
FIG. 36 is a functional block diagram showing a control system in a fourth embodiment. As shown in the functional block diagram, acontrol unit 100 similar to that in the first through third embodiments comprises a basic fuel injectionamount computing unit 110, an air/fuel ratio modificationterm computing unit 120, a deterioration diagnosispermission determining unit 430, a catalyst characteristic A (after-light-off oxygen storage capacity) detectingunit 440, a catalyst characteristic B (light-off temperature)estimating unit 450, and an ignitiontiming setting unit 160 for, based on the estimated light-off temperature, setting a retard amount of ignition timing at the startup and a period during which the ignition timing is retarded. In this fourth embodiment, the deterioration diagnosispermission determining unit 430 and the catalyst characteristic B (light-off temperature)estimating unit 450 are constituted respectively as shown inFIGS. 37 and 38 . The ignitiontiming setting unit 160, which is not disposed in the above-described embodiments, is constituted as follows. - <Ignition Timing Setting Unit 160 (
FIG. 39 )> - This
setting unit 160 sets the ignition timing. Specifically, the setting is executed as shown inFIG. 39 . Basic ignition timing ADVO is decided based on Tp (basic fuel injection amount) and Ne (engine rotation speed). When the estimated catalyst temperature does not reach the light-off temperature, i.e., in the state of Tcat≦T0, a value obtained by referring to a map with the light-off temperature T0 being a parameter is set as a retard amount ADVRTD of the ignition timing. Then, a value obtained by subtracting the retard amount ADVRTD of the ignition timing from the basic ignition timing ADVO is set as ignition timing ADV. - While the embodiments have been described above in connection with the case using the three-way catalyst, the present invention is not limited to the three-way catalyst so long as a catalyst has the three-way performance, and the present invention is also applicable to the cases using an HC adsorbing combustion catalyst, a lean NOx catalyst, etc. In particular, the present invention can be advantageously applied to the case using the HC adsorbing combustion catalyst because the light-off temperature is a very important factor in deciding the performance of that catalyst.
Claims (24)
1. An engine self-diagnosis system comprising:
means for directly or indirectly detecting performance A of an exhaust cleaning catalyst when temperature of said catalyst or temperature of exhaust gas flowing into said catalyst is within a predetermined temperature range; and
means for, based on the detected catalyst performance A, estimating performance B of said catalyst which is resulted, when the temperature of said catalyst is outside the predetermined temperature range.
2. The engine self-diagnosis system according to claim 1 , wherein said catalyst has at least three-way performance.
3. The engine self-diagnosis system according to claim 1 , wherein said catalyst is an HC adsorbing combustion catalyst that adsorbs HC when the catalyst temperature is within a predetermined temperature range, desorbs the adsorbed HC when the catalyst temperature exceeds the predetermined temperature range, and cleans the adsorbed and desorbed HC.
4. The engine self-diagnosis system according to claim 1 , wherein said catalyst is a lean NOx catalyst.
5. The engine self-diagnosis system according to Claim 1 , further comprising:
means for directly or indirectly detecting the temperature of said catalyst;
means for directly or indirectly detecting the catalyst performance A when the catalyst temperature detected by said detecting means is within a temperature range in which an exhaust cleaning rate is not smaller than a predetermined value; and
means for, based on the detected catalyst performance A, estimating the catalyst performance B resulted when the catalyst temperature detected by said detecting means is within a temperature range in which the exhaust cleaning rate is smaller than the predetermined value.
6. The engine self-diagnosis system according to claim 1 , wherein the catalyst performance B is a catalyst temperature T0 at which the exhaust cleaning rate is not smaller than the predetermined value.
7. The engine self-diagnosis system according to claim 6 , further comprising catalyst deterioration determining means for determining that said catalyst has deteriorated, when the catalyst temperature T0 at which the exhaust cleaning rate is not smaller than the predetermined value exceeds a predetermined temperature.
8. The engine self-diagnosis system according to claim 7 , wherein said catalyst is an HC adsorbing combustion catalyst, and said catalyst deterioration determining means determines that said HC adsorbing combustion catalyst has deteriorated, when the catalyst temperature T0 at which the exhaust cleaning rate is not smaller than the predetermined value exceeds a predetermined temperature.
9. The engine self-diagnosis system according to claim 7 , wherein said catalyst is a lean NOx catalyst, and said catalyst deterioration determining means determines that said lean NOx catalyst has deteriorated, when the catalyst temperature T0 at which the exhaust cleaning rate is not smaller than the predetermined value exceeds a predetermined temperature.
10. The engine self-diagnosis system according to claim 1 , wherein the catalyst performance A is exhaust cleaning capacity.
11. The engine self-diagnosis system according to claim 1 , wherein the catalyst performance A is oxygen storage capacity.
12. The engine self-diagnosis system according to claim 1 , wherein the catalyst performance A is given as exhaust cleaning capacity, and the catalyst performance B is given as the catalyst temperature T0 at which the exhaust cleaning rate is not smaller than the predetermined value.
13. The engine self-diagnosis system according to claim 1 , wherein the catalyst performance A is given as oxygen storage capacity, and the catalyst performance B is given as the catalyst temperature T0 at which the exhaust cleaning rate is not smaller than the predetermined value or the oxygen storage capacity is not smaller than a predetermined value.
14. The engine self-diagnosis system according to claim 1 , further comprising exhaust component detecting means disposed downstream of said catalyst.
15. The engine self-diagnosis system according to claim 1 , further comprising an O2 sensor or an A/F sensor downstream of said catalyst.
16. The engine self-diagnosis system according to claim 15 , further comprising means for detecting oxygen storage capacity of said catalyst based on an output signal from said O2 sensor or said A/F sensor.
17. The engine self-diagnosis system according to claim 15 , further comprising:
means for oscillating an O2 concentration or an air/fuel ratio upstream of said catalyst at a predetermined frequency;
means for computing a component at the predetermined frequency of the output signal from said O2 sensor or said A/F sensor; and
means for detecting oxygen storage capacity of said catalyst based on the computed component at the predetermined frequency.
18. The engine self-diagnosis system according to claim 15 , further comprising:
means for changing an O2 concentration or an air/fuel ratio upstream of said catalyst by a predetermined value;
response delay time computing means for computing a response delay time from a time at which the O2 concentration or the air/fuel ratio upstream of said catalyst is changed by a predetermined value to a time at which an output signal from said O2 sensor downstream of said catalyst is changed by a predetermined value; and
means for detecting oxygen storage capacity of said catalyst based on the computed response delay time.
19. The engine self-diagnosis system according to claim 1 , further comprising:
means for raising temperature of said catalyst;
catalyst temperature estimating means;
an O2 sensor, an A/F sensor, or an exhaust sensor disposed downstream of said catalyst;
means for directly detecting, based on an output signal from said O2 sensor, said A/F sensor, or said exhaust sensor, whether the exhaust cleaning rate of said catalyst is not smaller than a predetermined value and said catalyst is in a light-off state; and
abnormality determining means for determining said catalyst temperature raising means to be abnormal, when said means for directly detecting catalyst light-off does not detect that said catalyst is in the light-off state, in spite of the catalyst temperature estimated by said catalyst temperature estimating means reaching an estimated light-off temperature representing the catalyst performance B.
20. The engine self-diagnosis system according to claim 1 , further comprising means for indicating the catalyst performance A and/or B or information related to the catalyst performance A and/or B.
21. The engine self-diagnosis system according to claim 1 , further comprising means for modifying an engine control parameter based on the catalyst performance A and/or B.
22. The engine self-diagnosis system according to claim 21 , further comprising means for modifying a control parameter for said catalyst temperature raising means based on the catalyst performance B represented by a catalyst temperature T0 at which an exhaust cleaning rate is not smaller than the predetermined value.
23. The engine self-diagnosis system according to claim 21 , wherein the control parameter for said catalyst temperature raising means is a retard amount of ignition timing and/or a period during which the ignition timing is retarded.
24. An automobile equipped with the engine self-diagnosis system according to any one of claims 1 to 23 .
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2004330119A JP4253294B2 (en) | 2004-11-15 | 2004-11-15 | Engine self-diagnosis device |
JP2004-330119 | 2004-11-15 |
Publications (1)
Publication Number | Publication Date |
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US20060101808A1 true US20060101808A1 (en) | 2006-05-18 |
Family
ID=35781212
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US11/271,988 Abandoned US20060101808A1 (en) | 2004-11-15 | 2005-11-14 | Engine self-diagnosis system |
Country Status (5)
Country | Link |
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US (1) | US20060101808A1 (en) |
EP (1) | EP1657415B1 (en) |
JP (1) | JP4253294B2 (en) |
CN (2) | CN100404810C (en) |
DE (1) | DE602005022029D1 (en) |
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US11828210B2 (en) | 2020-08-20 | 2023-11-28 | Denso International America, Inc. | Diagnostic systems and methods of vehicles using olfaction |
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Also Published As
Publication number | Publication date |
---|---|
JP4253294B2 (en) | 2009-04-08 |
EP1657415A3 (en) | 2008-08-20 |
CN100404810C (en) | 2008-07-23 |
EP1657415B1 (en) | 2010-06-30 |
JP2006138276A (en) | 2006-06-01 |
CN101311507A (en) | 2008-11-26 |
CN1776204A (en) | 2006-05-24 |
DE602005022029D1 (en) | 2010-08-12 |
EP1657415A2 (en) | 2006-05-17 |
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