US20060038400A1 - Tapered ceramic GC fitting and assembly - Google Patents
Tapered ceramic GC fitting and assembly Download PDFInfo
- Publication number
- US20060038400A1 US20060038400A1 US11/254,902 US25490205A US2006038400A1 US 20060038400 A1 US20060038400 A1 US 20060038400A1 US 25490205 A US25490205 A US 25490205A US 2006038400 A1 US2006038400 A1 US 2006038400A1
- Authority
- US
- United States
- Prior art keywords
- ferrule
- tip
- tubing
- internal bore
- chromatographic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 11
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000004817 gas chromatography Methods 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 description 9
- 230000007246 mechanism Effects 0.000 description 6
- 238000004587 chromatography analysis Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 3
- 239000004642 Polyimide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 239000005350 fused silica glass Substances 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 239000003082 abrasive agent Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L37/00—Couplings of the quick-acting type
- F16L37/02—Couplings of the quick-acting type in which the connection is maintained only by friction of the parts being joined
- F16L37/04—Couplings of the quick-acting type in which the connection is maintained only by friction of the parts being joined with an elastic outer part pressing against an inner part by reason of its elasticity
- F16L37/05—Couplings of the quick-acting type in which the connection is maintained only by friction of the parts being joined with an elastic outer part pressing against an inner part by reason of its elasticity tightened by the pressure of a mechanical element
Definitions
- the present invention relates to fittings for gas chromatography tubing.
- capillary columns need to be joined to various devices, such as injectors, detectors, and other column or tubing ends.
- devices such as injectors, detectors, and other column or tubing ends.
- managing the volumes, flow rates, and geometries between devices has a critical effect on maintaining peak shape quality.
- a union connector assembly that provides zero or near zero dead volume for GC columns.
- tapered glass press fit union Another common zero dead volume union which provide acceptable chromatographic performance is the tapered glass press fit union. This type of union, however, has certain drawbacks as well. The reliability of the tapered glass press fit union is inconsistent with temperature range cycling. Additionally, the integrity of the connection around bends is limited. Finally, this type of connector is not reusable.
- Micro GC refers to a type of chromatography that is performed on an instrument that is smaller than a standard gas chromatograph. Typically in a Micro-GC, the column is coiled to 57 mm ID, and is positioned in an oven that is only 110 mm tall.
- the size of the connector assembly is a significant consideration in Micro GC. Previous connectors are too large or bulky to be practical for use in this size machine. There is a need for a zero or near zero dead volume connector assembly that is simple and reusable, There is a need for a connector assembly that is less bulky and more compact for smaller chromatographs, and one that provides a secure connection for straight or bent tubing.
- a ferrule for gas chromatography fittings comprising a body having a first end, a second end, and an internal bore extending length of the body; a tip integral with the body and protruding from the first end is disclosed.
- the tip has a flat surface through which the internal bore extends and wherein the flat surface of the tip is of smaller area than the first end and is perpendicular to the body outer diameter.
- FIG. 1 is a plan view of a ceramic ferrule of the present invention
- FIG. 2 is a sectional view of a ceramic ferrule of the present invention
- FIG. 3 is an enlarged view of the tip of a ceramic ferrule
- FIG. 4 is a sectional view of a connector assembly of one embodiment of the present invention connecting the ends of two chromatographic tubings;
- FIG. 5 is a sectional view of a connector assembly of one embodiment of the present invention connecting the end of a chromatography tubing to a planar device;
- FIG. 6 is a perspective view of a connector assembly of a second embodiment of the present invention connecting the ends of two sets of chromatographic tubings.
- FIGS. 1 and 2 illustrate the preferred embodiment of the ceramic ferrule of the invention.
- the ceramic ferrule 10 has a main body 12 .
- the main body is preferably cylindrical, but need not be.
- the ceramic ferrule 10 has two ends, a first end 15 and a second end 17 .
- the ferrule 10 is preferably formed from a ceramic material and most preferably from Zirconia. Other materials may also be used depending on the application. Factors to be considered when choosing ferule material include the chemical inertness of the material, the effect of temperature on the material, the ability of the material to be fabricated with the precision required of the ferrule, and the polish capability of the material. Examples of such materials without limitation include glass, fused silica, and some plastics.
- the tip 25 is integrally connected to the first end 15 and is preferably fabricated from the same molded material and in the same process as the body 15 of the ferrule.
- the preferred method of constructing the body 15 with the integrally connected tip 25 is by ceramic injection molding. Once cast, the tip 25 is ground to final shape.
- the tip has a flat surface or face 28 that is substantially parallel to the first end 15 and perpendicular to the body outer diameter. The diameter of the tip is preferable less than 0.7 mm.
- the face 28 is polished by flat lapping to produce a smooth, substantially flat surface. In some embodiments of the invention the face 28 will interface with a second face 28 from a second ferrule 10 .
- the final geometry and finish on the ferrule tip is produced by lapping.
- Lapping refers to a specific kind of machine for producing a smooth flat surface using a rotating plate charged with appropriate particles. It is a specific kind of polishing, though polishing usually involves fine abrasive materials bonded to some backing. Lapping is slow and time consuming, but produces the desired surface characteristics of flatness, perpendicularity, and optically smooth finish.
- the ferrule 10 has an internal bore 20 extending the entire length of the ferrule 10 , including the tip 25 and the face 28 .
- the bore 20 is cylindrical in shape and is preferably conical with the wider portion beginning at the second end 17 and narrowing as it progresses toward the first end 15 .
- the bore has an internal taper of about 2.5 degrees. When tapered in this manner, a stronger primary gas seal between the outside of the tubing and the surface of the internal bore 20 is more easily created. Additionally, when tapered at this angle the bore is able to accommodate a larger variety of sized tubings.
- Chromatographic tubing typically refers to chromatography columns, however, other types of tubing may be used such as stainless steel tubing. This invention is equally applicable to all types of chromatography tubing and any reference to a column or columns in this specification refers to all types of chromatographic tubing unless otherwise noted.
- Typical chromatographic tubing for Micro GC is coiled and has an internal diameter of 57 mm and fits in an oven that is 110 mm tall.
- a ferrule 10 with about a 2.5 degree taper will accommodate tubing within a range of 430 micron outer diameter down to 90 micron outer diameter.
- the dimensions of the ferrule and internal bore can be adjusted to fit a much broader range of tubing sizes.
- the precise dimensions of the bore 20 will depend on the outer diameter of the tubing being inserted. Additionally, it is preferred that the opening 22 at the second end 17 be flared out to assist in the ease of the insertion of the tubing. Additionally, the flared opening will assist in installation of backup adhesive and can provides train relief to ease the transition from the ferrule constraints to the coiled column.
- the preferred angle of the flare is about 30 degrees, but other angles may be used.
- a chromatographic tubing is inserted into the second end 17 of the ferrule 10 and pressed inwards until a friction fit is created.
- Fused silica chromatographic tubing is coated with polyimide to improve lifetime.
- the polyimide coating provides the primary seal.
- the outside surface of the tubing will slightly deform creating the primary gas tight seal between the outside of the tubing and the inside surface of the internal bore 20 of the ferrule.
- some form of adhesive is applied to the outside of the tubing creating a secondary seal and strain relief. This secondary seal provides mechanical stability to prevent disruption of the seal due to stress from vibration or pressure if the tubing is wound in a tight coil, as is often the case in a Micro-GC.
- the internal bore 20 extends the length of the ferrule 10 . As best illustrated in FIG. 3 , the internal bore exits through the face 28 of the tip 25 .
- the face 28 of the tip 25 is substantially perpendicular to the main body 12 of the ferule 10 . It is at this area, face 28 , that in some embodiments, two ferrules 10 will interface to create a gas tight seal.
- the connector assembly 40 consists of two ferrules 10 a and 10 b and a clamping mechanism generally indicated at 60 .
- the clamping mechanism 60 is designed and constructed to secure the two ferrules 10 a and 10 b in the position and apply the appropriate force. Generally the amount of force needed to create the seal is around 6 lbs.
- the design of the clamping mechanism 60 is less bulky and requires less space than previous unions making it more suitable for the small spaces of a Micro GC.
- the clamping mechanism 60 has a frame 65 which secures the ferrules 10 a and 10 b in place.
- the frame 65 has a fixed plate 68 at one end with a screw 69 for securing the fixed plate 68 in place.
- the fixed plate 68 has an aperture or slot for allowing the chromatographic tubing 50 b to be installed with the attached ferrule.
- a floating plate 72 is movably attached to the frame 65 to provide force to the second end 17 of the second ferrule 10 a.
- the floating plate 72 also has an aperture or slot for allowing the second chromatographic tubing 50 a to be threaded through and into the ferrule 10 a.
- the floating plate can be unloaded or disarmed for easy insertion of the two column/ferrule ends, and subsequently loaded to create the seal.
- the floating plate 72 is forced axially towards the frame by an axial spring 75 .
- the axial spring 75 is connected to the frame by a screw 77 that extends through the spring 75 and the floating plate 72 .
- By turning the screw 77 the amount of force being applied to the floating plate 72 can be adjusted, thereby adjusting the amount of force being applied to the ferrules 10 a and 10 b at the interface 30 .
- planar device refers to such typical chromatographic equipment as injectors, detectors and manifolds. It is not meant to be limited in its application, but simply refers to a connection that is other than a column to column union.
- the planar device is generally represented by 80 .
- the planar device has an entry aperture 85 through which gas (not shown) enters the device 80 .
- the connector assembly 40 in this configuration contains a ferrule 10 and a clamping mechanism 100 .
- the column or tubing is inserted into the internal bore 20 of the ferrule 10 via the second end 17 .
- the ferrule 10 preferably interfaces with the planar device 80 through the use of an elastomer 90 .
- the tip of ferrule 10 is preferably dimensioned to fit with a standard sized o-ring, such as a 2-001 sized o-ring.
- the elastomer may be cut or molded specifically to match the dimensions of the ferrule 10 and the dimensions of the planar device 80 .
- the connector assembly 40 has a clamping mechanism 100 for securing the ferrule 10 in place and is constructed to position the face 28 of the ferrule 10 in alignment with the aperture 85 of the planar device 80 .
- the connector assembly also functions to provide axial force in the direction of the face 28 to create a gas tight seal at the interface.
- FIG. 6 an alternate embodiment assembly for joining chromatographic tubing is disclosed.
- the assembly is designed to connect two different sets of two chromatographic tubings (not shown) in one assembly.
- Ceramic ferrules 15 a, 15 b, 15 c, and 15 d are secured within the frame 165 .
- ferrules 15 a and 15 b are secured in a face 28 a to face 28 b interface.
- ferrules 15 c and 15 d may also be secured in face 28 c to face 28 d interface.
- Ferrules 15 a and 15 b are secured within the frame 65 by anchor 125 b and ferrules 15 c and 15 d are secured within frame 65 with anchor 125 a.
- Ferrules 15 a and 15 c are held in stationary position by fixed plates 168 a and 168 b.
- Floating plates 172 a and 172 b provide axial force to ferrules 15 b and 15 d as a result of spring 175 .
- spring 175 provides axial force to floating plates 172 a and 172 b.
- a set of pliers 135 a and 135 b is movably connected to the frame 165 and floating plates 172 a and 172 b. As the spring pulls the pliers 135 a and 135 b together, the force is redirected and leveraged to the floating plates 172 a and 172 b.
- the floating and fixed plates have apertures for allowing ingress and egress of the chromatographic tubing to be connected.
Abstract
The present invention is a ferrule for gas chromatography fittings comprising a body having a first end, a second end, and an internal bore extending length of the body; a tip integral with the body and protruding from the first end is disclosed. The tip has a flat surface through which the internal bore extends and wherein the flat surface of the tip is of smaller area than the first end and is perpendicular to the body. In one embodiment the body of the ferrule is formed from Zirconia ceramic. A connector assembly for creating a gas seal between chromatographic tubing is also disclosed.
Description
- The present invention relates to fittings for gas chromatography tubing.
- In GC, capillary columns need to be joined to various devices, such as injectors, detectors, and other column or tubing ends. Particularly in capillary chromatography, managing the volumes, flow rates, and geometries between devices has a critical effect on maintaining peak shape quality. There is a need for a union connector assembly that provides zero or near zero dead volume for GC columns.
- Previous attempts to provide this type of union have produced connectors that are either too complex in terms of their operation, too large and bulky to be useful in smaller areas, or too unreliable in terms of their performance. Examples of such fitting are found in U.S. Pat. No. 5,540,464 and U.S. Pat. No. 5,288,113. The fittings disclosed in these references are especially unsuitable for use in the smaller ovens utilized in Micro Gas Chromatography (Micro GC).
- Another common zero dead volume union which provide acceptable chromatographic performance is the tapered glass press fit union. This type of union, however, has certain drawbacks as well. The reliability of the tapered glass press fit union is inconsistent with temperature range cycling. Additionally, the integrity of the connection around bends is limited. Finally, this type of connector is not reusable.
- The term Micro GC refers to a type of chromatography that is performed on an instrument that is smaller than a standard gas chromatograph. Typically in a Micro-GC, the column is coiled to 57 mm ID, and is positioned in an oven that is only 110 mm tall. The size of the connector assembly is a significant consideration in Micro GC. Previous connectors are too large or bulky to be practical for use in this size machine. There is a need for a zero or near zero dead volume connector assembly that is simple and reusable, There is a need for a connector assembly that is less bulky and more compact for smaller chromatographs, and one that provides a secure connection for straight or bent tubing.
- A ferrule for gas chromatography fittings comprising a body having a first end, a second end, and an internal bore extending length of the body; a tip integral with the body and protruding from the first end is disclosed. The tip has a flat surface through which the internal bore extends and wherein the flat surface of the tip is of smaller area than the first end and is perpendicular to the body outer diameter.
- The accompanying drawings are incorporated in and constitute a part of this specification and, together with the description, explain the advantages and principles of the invention. In the drawings,
-
FIG. 1 is a plan view of a ceramic ferrule of the present invention; -
FIG. 2 is a sectional view of a ceramic ferrule of the present invention; -
FIG. 3 is an enlarged view of the tip of a ceramic ferrule; -
FIG. 4 is a sectional view of a connector assembly of one embodiment of the present invention connecting the ends of two chromatographic tubings; -
FIG. 5 is a sectional view of a connector assembly of one embodiment of the present invention connecting the end of a chromatography tubing to a planar device; -
FIG. 6 is a perspective view of a connector assembly of a second embodiment of the present invention connecting the ends of two sets of chromatographic tubings. - Turning now to the drawings,
FIGS. 1 and 2 illustrate the preferred embodiment of the ceramic ferrule of the invention. Theceramic ferrule 10 has amain body 12. The main body is preferably cylindrical, but need not be. Theceramic ferrule 10 has two ends, afirst end 15 and asecond end 17. Theferrule 10 is preferably formed from a ceramic material and most preferably from Zirconia. Other materials may also be used depending on the application. Factors to be considered when choosing ferule material include the chemical inertness of the material, the effect of temperature on the material, the ability of the material to be fabricated with the precision required of the ferrule, and the polish capability of the material. Examples of such materials without limitation include glass, fused silica, and some plastics. - Protruding from the
first end 15 istip 25. Thetip 25 is integrally connected to thefirst end 15 and is preferably fabricated from the same molded material and in the same process as thebody 15 of the ferrule. The preferred method of constructing thebody 15 with the integrally connectedtip 25 is by ceramic injection molding. Once cast, thetip 25 is ground to final shape. The tip has a flat surface orface 28 that is substantially parallel to thefirst end 15 and perpendicular to the body outer diameter. The diameter of the tip is preferable less than 0.7 mm. Theface 28 is polished by flat lapping to produce a smooth, substantially flat surface. In some embodiments of the invention theface 28 will interface with asecond face 28 from asecond ferrule 10. In those instances a smoother surface is desired to more easily achieve a gas tight seal. In the preferred embodiment the final geometry and finish on the ferrule tip is produced by lapping. Lapping refers to a specific kind of machine for producing a smooth flat surface using a rotating plate charged with appropriate particles. It is a specific kind of polishing, though polishing usually involves fine abrasive materials bonded to some backing. Lapping is slow and time consuming, but produces the desired surface characteristics of flatness, perpendicularity, and optically smooth finish. - The
ferrule 10 has aninternal bore 20 extending the entire length of theferrule 10, including thetip 25 and theface 28. Thebore 20 is cylindrical in shape and is preferably conical with the wider portion beginning at thesecond end 17 and narrowing as it progresses toward thefirst end 15. Preferably, the bore has an internal taper of about 2.5 degrees. When tapered in this manner, a stronger primary gas seal between the outside of the tubing and the surface of theinternal bore 20 is more easily created. Additionally, when tapered at this angle the bore is able to accommodate a larger variety of sized tubings. - Chromatographic tubing typically refers to chromatography columns, however, other types of tubing may be used such as stainless steel tubing. This invention is equally applicable to all types of chromatography tubing and any reference to a column or columns in this specification refers to all types of chromatographic tubing unless otherwise noted. Typical chromatographic tubing for Micro GC is coiled and has an internal diameter of 57 mm and fits in an oven that is 110 mm tall. A
ferrule 10 with about a 2.5 degree taper will accommodate tubing within a range of 430 micron outer diameter down to 90 micron outer diameter. Of course, the dimensions of the ferrule and internal bore can be adjusted to fit a much broader range of tubing sizes. - As the
ferrule 10 will typically receive some form chromatographic tubing, the precise dimensions of thebore 20 will depend on the outer diameter of the tubing being inserted. Additionally, it is preferred that theopening 22 at thesecond end 17 be flared out to assist in the ease of the insertion of the tubing. Additionally, the flared opening will assist in installation of backup adhesive and can provides train relief to ease the transition from the ferrule constraints to the coiled column. The preferred angle of the flare is about 30 degrees, but other angles may be used. - In use, a chromatographic tubing is inserted into the
second end 17 of theferrule 10 and pressed inwards until a friction fit is created. Fused silica chromatographic tubing is coated with polyimide to improve lifetime. The polyimide coating provides the primary seal. The outside surface of the tubing will slightly deform creating the primary gas tight seal between the outside of the tubing and the inside surface of theinternal bore 20 of the ferrule. Typically, some form of adhesive is applied to the outside of the tubing creating a secondary seal and strain relief. This secondary seal provides mechanical stability to prevent disruption of the seal due to stress from vibration or pressure if the tubing is wound in a tight coil, as is often the case in a Micro-GC. - The
internal bore 20 extends the length of theferrule 10. As best illustrated inFIG. 3 , the internal bore exits through theface 28 of thetip 25. Theface 28 of thetip 25 is substantially perpendicular to themain body 12 of theferule 10. It is at this area, face 28, that in some embodiments, twoferrules 10 will interface to create a gas tight seal. - Referring to
FIG. 4 , the ends of twochromatographic tubings connector assembly 40 of the current invention. Theconnector assembly 40 consists of twoferrules ferrules face 28 a to face 28b interface 30 and applying enough force to create a gas tight seal. Theclamping mechanism 60 is designed and constructed to secure the twoferrules faces clamping mechanism 60 is less bulky and requires less space than previous unions making it more suitable for the small spaces of a Micro GC. - The
clamping mechanism 60 has aframe 65 which secures theferrules frame 65 has a fixedplate 68 at one end with ascrew 69 for securing the fixedplate 68 in place. The fixedplate 68 has an aperture or slot for allowing thechromatographic tubing 50 b to be installed with the attached ferrule. At the other end, a floatingplate 72 is movably attached to theframe 65 to provide force to thesecond end 17 of thesecond ferrule 10 a. The floatingplate 72 also has an aperture or slot for allowing thesecond chromatographic tubing 50 a to be threaded through and into theferrule 10 a. The floating plate can be unloaded or disarmed for easy insertion of the two column/ferrule ends, and subsequently loaded to create the seal. - The floating
plate 72 is forced axially towards the frame by anaxial spring 75. Theaxial spring 75 is connected to the frame by ascrew 77 that extends through thespring 75 and the floatingplate 72. By turning thescrew 77 the amount of force being applied to the floatingplate 72 can be adjusted, thereby adjusting the amount of force being applied to theferrules interface 30. - Referring now to
FIG. 5 , the end of a chromatographic tubing is connected to a planar device. The reference to a planar device refers to such typical chromatographic equipment as injectors, detectors and manifolds. It is not meant to be limited in its application, but simply refers to a connection that is other than a column to column union. - The planar device is generally represented by 80. The planar device has an
entry aperture 85 through which gas (not shown) enters thedevice 80. Theconnector assembly 40 in this configuration contains aferrule 10 and aclamping mechanism 100. As in the previous devices, the column or tubing is inserted into theinternal bore 20 of theferrule 10 via thesecond end 17. - The
ferrule 10 preferably interfaces with theplanar device 80 through the use of anelastomer 90. The tip offerrule 10 is preferably dimensioned to fit with a standard sized o-ring, such as a 2-001 sized o-ring. Alternatively the elastomer may be cut or molded specifically to match the dimensions of theferrule 10 and the dimensions of theplanar device 80. - The
connector assembly 40 has aclamping mechanism 100 for securing theferrule 10 in place and is constructed to position theface 28 of theferrule 10 in alignment with theaperture 85 of theplanar device 80. The connector assembly also functions to provide axial force in the direction of theface 28 to create a gas tight seal at the interface. - Referring now to
FIG. 6 , an alternate embodiment assembly for joining chromatographic tubing is disclosed. The assembly is designed to connect two different sets of two chromatographic tubings (not shown) in one assembly.Ceramic ferrules frame 165. As inFIG. 4 .ferrules face 28 a to face 28 b interface. Additionally,ferrules frame 65 byanchor 125 b andferrules frame 65 withanchor 125 a. - Once in place, force is applied to the ferrules by the use of a
spring 175. Ferrules 15 a and 15 c are held in stationary position by fixedplates 168 a and 168 b. Floatingplates ferrules spring 175. Although not positioned axially,spring 175 provides axial force to floatingplates pliers 135 a and 135 b is movably connected to theframe 165 and floatingplates pliers 135 a and 135 b together, the force is redirected and leveraged to the floatingplates - As in the assembly described in
FIG. 4 , the floating and fixed plates have apertures for allowing ingress and egress of the chromatographic tubing to be connected.
Claims (7)
1. A ferrule for gas chromatography fittings comprising:
a rigid body having a first end, a second end, and an internal bore extending the length of the body; and
a tip integral with the body and protruding from the first end, wherein the tip has a flat surface through which the internal bore extends and wherein the flat surface of the tip is of smaller area than the first end and is perpendicular to the body.
2. The ferrule of claim 1 wherein the body is formed from Zirconia ceramic.
3. The ferrule of claim 1 wherein the flat tip diameter is less than 0.7 mm.
4. The ferrule of claim 1 wherein the internal bore is tapered in the direction of the first end.
5. The ferrule of claim 3 wherein the internal bore is tapered in the amount of 2.5 degrees.
6. The ferrule of claim 5 wherein the internal bore is flared at the second end.
7.-20. (canceled)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US11/254,902 US20060038400A1 (en) | 2003-11-07 | 2005-10-20 | Tapered ceramic GC fitting and assembly |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US10/702,583 US6981720B2 (en) | 2003-11-07 | 2003-11-07 | Tapered ceramic GC fitting and assembly |
US11/254,902 US20060038400A1 (en) | 2003-11-07 | 2005-10-20 | Tapered ceramic GC fitting and assembly |
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US10/702,583 Continuation US6981720B2 (en) | 2003-11-07 | 2003-11-07 | Tapered ceramic GC fitting and assembly |
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US20060038400A1 true US20060038400A1 (en) | 2006-02-23 |
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US10/702,583 Expired - Fee Related US6981720B2 (en) | 2003-11-07 | 2003-11-07 | Tapered ceramic GC fitting and assembly |
US11/254,902 Abandoned US20060038400A1 (en) | 2003-11-07 | 2005-10-20 | Tapered ceramic GC fitting and assembly |
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US10/702,583 Expired - Fee Related US6981720B2 (en) | 2003-11-07 | 2003-11-07 | Tapered ceramic GC fitting and assembly |
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Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6981720B2 (en) * | 2003-11-07 | 2006-01-03 | Agilent Technologies, Inc. | Tapered ceramic GC fitting and assembly |
US20060222050A1 (en) * | 2005-03-31 | 2006-10-05 | Robertshaw Controls Company | Ceramic receptacle for temperature probes and the like |
US8448995B2 (en) * | 2008-04-17 | 2013-05-28 | Onset Pipe Products, Inc. | Apparatus and method for supporting a pipe coupling |
JP5521293B2 (en) * | 2008-09-09 | 2014-06-11 | 株式会社島津製作所 | Capillary column connector |
GB201001100D0 (en) * | 2010-01-22 | 2010-03-10 | Bio Pure Technology Ltd | Tube applicator |
US9791080B2 (en) | 2012-03-12 | 2017-10-17 | Idex Health & Science Llc | Microfluidic interconnect |
US10094494B2 (en) | 2015-06-26 | 2018-10-09 | Agilent Technologies, Inc. | Ferrule with features for softening ferrule crush and related methods |
USD805164S1 (en) | 2015-06-26 | 2017-12-12 | Agilent Technologies, Inc. | Ferrule |
CA3117700C (en) * | 2018-10-31 | 2024-02-20 | Bioatla, Inc. | Anti-ctla4 antibodies, antibody fragments, their immunoconjugates and uses thereof |
EP3911946A4 (en) * | 2019-01-14 | 2022-10-19 | Agilent Technologies, Inc. | Versatile tube-free jet for gc detector |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4679895A (en) * | 1984-08-31 | 1987-07-14 | Amp Incorporated | Adhesiveless optical fiber connector |
US5288113A (en) * | 1992-12-24 | 1994-02-22 | Restek Corporation | Connector for capillary tubes having a tapered inner bore |
US5540464A (en) * | 1994-10-04 | 1996-07-30 | J&W Scientific Incorporated | Capillary connector |
US5595406A (en) * | 1995-11-30 | 1997-01-21 | Hewlett-Packard Co. | Capillary tubing connector |
US5601785A (en) * | 1991-12-23 | 1997-02-11 | Microsensor Technology, Inc. | Connector for detachable column cartridge for gas chromatograph |
US20040021113A1 (en) * | 2000-11-24 | 2004-02-05 | Owe Salven | Rotary valve |
US6981720B2 (en) * | 2003-11-07 | 2006-01-03 | Agilent Technologies, Inc. | Tapered ceramic GC fitting and assembly |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4163722A (en) * | 1978-02-14 | 1979-08-07 | Renal Systems, Inc. | Universal dialyzer end cap |
US4529230A (en) * | 1982-02-26 | 1985-07-16 | Supelco, Inc. | Capillary tubing and small rod connector |
US4787656A (en) * | 1985-06-19 | 1988-11-29 | Hewlett-Packard Company | Capillary tubing coupler |
US4655917A (en) * | 1985-08-19 | 1987-04-07 | Rainin Instrument Co. | Modular liquid chromatography column apparatus |
US4991883A (en) * | 1989-09-25 | 1991-02-12 | Ruska Laboratories, Inc. | Connection apparatus |
US4969938A (en) * | 1990-01-03 | 1990-11-13 | The Perkin-Elmer Corporation | Fluid connector for microdevices |
US5310029A (en) * | 1992-10-19 | 1994-05-10 | Bundy Corporation | Brake tube coupling |
US5234235A (en) * | 1992-11-30 | 1993-08-10 | Ruska Laboratories, Inc. | Connection apparatus |
US5487569A (en) * | 1994-10-12 | 1996-01-30 | Restek Corporation | Connector for three or more capillary tubes |
US6102449A (en) * | 1998-10-29 | 2000-08-15 | Agilent Technologies, In. | Connector for capillary tubing |
US6709027B2 (en) * | 2001-02-23 | 2004-03-23 | Agilent Technologies, Inc. | Capillary column sealing technique |
-
2003
- 2003-11-07 US US10/702,583 patent/US6981720B2/en not_active Expired - Fee Related
-
2005
- 2005-10-20 US US11/254,902 patent/US20060038400A1/en not_active Abandoned
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4679895A (en) * | 1984-08-31 | 1987-07-14 | Amp Incorporated | Adhesiveless optical fiber connector |
US5601785A (en) * | 1991-12-23 | 1997-02-11 | Microsensor Technology, Inc. | Connector for detachable column cartridge for gas chromatograph |
US5288113A (en) * | 1992-12-24 | 1994-02-22 | Restek Corporation | Connector for capillary tubes having a tapered inner bore |
US5540464A (en) * | 1994-10-04 | 1996-07-30 | J&W Scientific Incorporated | Capillary connector |
US5595406A (en) * | 1995-11-30 | 1997-01-21 | Hewlett-Packard Co. | Capillary tubing connector |
US20040021113A1 (en) * | 2000-11-24 | 2004-02-05 | Owe Salven | Rotary valve |
US6981720B2 (en) * | 2003-11-07 | 2006-01-03 | Agilent Technologies, Inc. | Tapered ceramic GC fitting and assembly |
Also Published As
Publication number | Publication date |
---|---|
US20050099006A1 (en) | 2005-05-12 |
US6981720B2 (en) | 2006-01-03 |
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Legal Events
Date | Code | Title | Description |
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STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |