US20050196592A1 - Three-dimensional textile composite structure and manufacture and use thereof - Google Patents

Three-dimensional textile composite structure and manufacture and use thereof Download PDF

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Publication number
US20050196592A1
US20050196592A1 US10/791,280 US79128004A US2005196592A1 US 20050196592 A1 US20050196592 A1 US 20050196592A1 US 79128004 A US79128004 A US 79128004A US 2005196592 A1 US2005196592 A1 US 2005196592A1
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United States
Prior art keywords
energy
thermoplastic matrix
woven textile
matrix material
base
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Abandoned
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US10/791,280
Inventor
Xiaoming Tao
Tongxi Yu
Peggie Lam
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Hong Kong University of Science and Technology HKUST
Hong Kong Polytechnic University HKPU
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Hong Kong University of Science and Technology HKUST
Hong Kong Polytechnic University HKPU
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Priority to US10/791,280 priority Critical patent/US20050196592A1/en
Assigned to HONG KONG UNIVERSITY OF SCIENCE & TECHNOLOGY, THE, HONG KONG POLYTECHNIC UNIVERSITY, THE reassignment HONG KONG UNIVERSITY OF SCIENCE & TECHNOLOGY, THE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: LAM, PEGGIE SIN-WAN, TAO, XIAOMING, YU, TONGXI
Publication of US20050196592A1 publication Critical patent/US20050196592A1/en
Abandoned legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R21/00—Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
    • B60R21/02—Occupant safety arrangements or fittings, e.g. crash pads
    • B60R21/04—Padded linings for the vehicle interior ; Energy absorbing structures associated with padded or non-padded linings
    • A—HUMAN NECESSITIES
    • A42—HEADWEAR
    • A42B—HATS; HEAD COVERINGS
    • A42B3/00—Helmets; Helmet covers ; Other protective head coverings
    • A42B3/04—Parts, details or accessories of helmets
    • A42B3/10—Linings
    • A42B3/12—Cushioning devices
    • A42B3/124—Cushioning devices with at least one corrugated or ribbed layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/02—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board the layer being formed of fibres, chips, or particles, e.g. MDF, HDF, OSB, chipboard, particle board, hardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/10—Next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/28—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022—Non-woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60N—SEATS SPECIALLY ADAPTED FOR VEHICLES; VEHICLE PASSENGER ACCOMMODATION NOT OTHERWISE PROVIDED FOR
    • B60N2/00—Seats specially adapted for vehicles; Arrangement or mounting of seats in vehicles
    • B60N2/58—Seat coverings
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • A41D13/015—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches with shock-absorbing means
    • A41D13/0156—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches with shock-absorbing means having projecting patterns
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B32B2260/023—Two or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/56—Damping, energy absorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2571/00—Protective equipment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/003—Interior finishings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R21/00—Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
    • B60R21/02—Occupant safety arrangements or fittings, e.g. crash pads
    • B60R21/04—Padded linings for the vehicle interior ; Energy absorbing structures associated with padded or non-padded linings
    • B60R21/0428—Padded linings for the vehicle interior ; Energy absorbing structures associated with padded or non-padded linings associated with the side doors or panels, e.g. displaced towards the occupants in case of a side collision
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1362—Textile, fabric, cloth, or pile containing [e.g., web, net, woven, knitted, mesh, nonwoven, matted, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628—Nonplanar uniform thickness material
    • Y10T428/24669—Aligned or parallel nonplanarities
    • Y10T428/24678—Waffle-form

Definitions

  • the present invention relates to three-dimensional textile composite structures with energy-absorbing capacities under multiple impacts, and to the manufacture and use thereof.
  • Three-dimensional textile composite structures have been widely used for energy absorbing purposes.
  • U.S. Pat. No. 6,536,052 issued to Xiaoming Tao et al. on Mar. 25, 2003 and entitled “Safety Helmets with Cellular Textile Composite Structure as Energy Absorber,” discloses a porous textile composite structure with high energy-absorbing capacities.
  • Preferred embodiments of '052 suggest spraying and then curing thermoset resins onto knitted fabrics for achieving the desired textile composite structures.
  • the knitted textile composite structure according to the preferred embodiments as disclosed In '052 may exhibit unsatisfactory energy-absorbing performance.
  • the three-dimensional knitted textile composite structure may collapse at the first impact and therefore lose a substantial part of its energy-absorbing capacities.
  • thermoset resin onto the fabrics is time consuming. It may take several days for the resin to cure at ambient temperatures.
  • a three-dimensional textile composite structure with energy-absorbing capacities under multiple impacts includes a base, and at least one progressively collapsible projection extending from the base for absorbing energies under the multiple impacts.
  • the projection includes a non-woven textile material supported in a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after the first impact of the multiple impacts.
  • a process for manufacturing a textile composite structure capable of retaining energy-absorption capacity at least after the first impact of multiple impacts includes the steps of:
  • an energy-absorbing door includes:
  • a safety headgear includes:
  • a body protective gear includes:
  • a protective package includes:
  • a seat cushion includes:
  • FIG. 1A is a perspective diagram of a sheet-like textile composite structure according to an exemplary embodiment of the present invention
  • FIG. 1B Is top plan view of the textile composite structure of FIG. 1A ;
  • FIG. 1C is a cross sectional view of the textile composite structure of FIG. 1A ;
  • FIG. 1D is a cross sectional view of the textile composite structure of FIG. 1A , illustrating deformation of the textile composite structure under an impact;
  • FIG. 2 is a diagram illustrating a process of making the textile composite structure of FIG. 1 according to an exemplary embodiment of the present invention
  • FIG. 3A is a cross-sectional view illustrating a vehicle door in which the textile composite structure of FIG. 1 can be used;
  • FIG. 3B is a perspective view of an energy absorbing structure, which is part of the vehicle door of FIG. 3A ;
  • FIG. 4 is a cross-sectional view illustrating a helmet in which the textile composite structure of FIG. 1 can be used.
  • FIG. 1 illustrates an exemplary three-dimensional sheet-like textile composite structure 100 with energy-absorbing capacities under multiple impacts.
  • the textile composite structure 100 has a generally planar base 103 and a plurality of projections 105 extending from the base 103 .
  • each projection 105 has a grid-domed shape with a conical sidewall 107 and a generally flat top 109 .
  • each projection 105 defines a space (not shown) where the sidewall 107 and/or the top 109 may collapse under impacts.
  • FIGS. 1B and 1C are respective top plan view and cross sectional view of the textile composite structure of FIG. 1A .
  • the textile composite structure 100 includes a textile and a matrix material. More specifically, in the exemplary embodiment, the textile structure 100 is made from non-woven fabric materials impregnated with thermoplastic matrix materials.
  • Materials for producing the non-woven fabric may vary.
  • Examples of the individual yarns in the non-woven fabrics may include strands of fiberglass, carbon, ceramics, and aromatic fibers.
  • a variety of yarns can be used including flat continuous filament yarns, textured or non-textured filament yarns and staple yarns. A mixture of these materials may be used in a single yarn if desired.
  • fibers with good mechanical properties for energy absorption and processing are used such as high-density polyethylene, polyester, nylon, and so on.
  • the yarn can be straight or textured including crimped or deformed yarns. Textured yarns may be preferred for the large deformation needed through formation and for better matrix penetration.
  • Methods for producing the non-woven fabric may also vary. Firstly the orientation of the fiber web prepared for production of the non-woven fabric can be in parallel, cross-layered, unidirectional or random. Furthermore, various bonding methods such as chemical bonding, thermal bonding, or mechanical bonding can be used to integrate the fibers in the non-woven fabric.
  • the exemplary embodiment uses at least a mechanical bonding method such as needle-punching to create the non-woven fabric of the exemplary embodiment.
  • the non-woven fabric thus produced in the exemplary embodiment is made from staple fibers with a random orientation and a low level of anisotropy in mechanical properties. It is also preferred that the non-woven fabric is resilient and has a bulk form so that the fabric is deformable to form the complex shape and contain sufficient fiber volume fraction in the fabricated composite.
  • thermoplastic matrix materials include low density polyethylene, polypropylene, polyester, polyamide, polystymene, polyetheretherketone, polyphenlenesulfide, and so on.
  • the thermoplastic matrix material in the exemplary embodiment may be one of the listed materials or a combination of several materials. In either case, in the exemplary embodiment, the thermoplastic matrix material has a lower melting temperature than the non-woven textile material.
  • the exemplary sheet-like textile composite structure 100 with projections made from non-woven fabric impregnated with thermoplastic matrix materials as described above exhibits high energy-absorbing capacities at least after the first impact of the multiple impacts.
  • FIG. 1D it is observed that once a repeated impact force hits the tops 109 of the projections 105 , rings 111 are progressively formed along the side walls 107 when the projections 105 are deformed under the impacts. Therefore, the tops 109 remain intact under the multiple impacts, and the textile composite structure 100 retains high energy-absorbing capacities at least after the first impact of the multiple impacts.
  • such a textile composite structure 100 can be produced through a relatively fast and clean process as discussed in details below.
  • FIG. 2 illustrate an exemplary process of producing a textile composite structure with the capacity of retaining energy-absorption capacity at least after the first impact of the multiple impacts.
  • a laminate 201 of a layer of non-woven fabric and a layer of thermoplastic matrix material is provided.
  • the non-woven layer and the thermoplastic matrix layer are made from the materials and methods according to the above illustrative descriptions accompanying FIGS. 1A-1C .
  • the non-woven fabric has a melting temperature at least approximately 30 degrees Celsius higher than the melting temperature of the thermoplastic matrix material.
  • the laminate 201 is then heated by a heater 203 in a closed mold cavity (not shown) to a processing temperature higher than the melting temperature of the thermoplastic matrix material but lower than the melting temperature of the non-woven fabric.
  • the processing temperature is at least approximately 10 degrees Celsius higher than the melting temperature of the thermoplastic matrix material and at least approximately 10 degrees Celsius lower than the melting temperature of the non-woven fabric.
  • Pressure is also applied to the laminate 201 to force the melted thermoplastic matrix materials to impregnate the fibers of the non-woven fabric in a relatively short period.
  • the processing temperature, pressure applied and the processing time in the step above are well controlled in the exemplary embodiment to avoid polymer degradation.
  • both the polymeric non-woven fabric and thermoplastic matrix are exposed to an elevated temperature.
  • the processing temperature is controlled such that the fabric and the matrix are not exposed to an extremely high processing temperature so as to avoid unnecessary thermal degradation, which may lead to reduction of the molecular weight of the polymers and thus deteriorate its mechanical behaviors.
  • the processing temperature is controlled to avoid non-woven fabric yellowing, which may happen when the non-woven fabric is processed at very high temperature and/or long exposure time.
  • the applied pressure is also monitored and may be varied at different stages of process to release the air inside the compression mold so as to avoid forming voids therein and to reduce the oxidation.
  • the laminated 201 is heated to a second processing temperature above the glass transition temperature of the non-woven fabric but below its melting temperature.
  • the laminate is thermally softened and partially deformed with the grid-dome-shaped projections 105 temporarily extending from the generally planar bases 103 .
  • the partially deformed laminate is fed to a heated mold 209 with grid-dome-shaped projections thereon for permanent molding.
  • a three-dimensional sheet-like textile structure 100 according to an exemplary embodiment of the present Invention is produced, with a generally planar base and a plurality of projections extending from the base.
  • the impregnation of the matrix material with the non-woven fabric is achieved within a relatively short period as compared to conventional processes since the heat and press are applied within the closed mold cavity. Furthermore, such a process is proved to be a relatively clean process In that the impregnation of the matrix material with the non-woven fabric is achieved within a closed cavity.
  • FIG. 3A a cross-sectional view of a typical vehicle door 200 is shown and includes an outer panel 301 and an inner panel 303 , which are spaced apart to define a vehicle door structure carrying a window regulator mechanism, door latch, and other components of a vehicle door.
  • the inner and outer panels define a window opening 305 .
  • a door trim panel 307 is formed of a suitable material such as pressed hardboard or plastic and is covered with a suitable decorative material such as vinyl, leather, cloth, carpeting or the like.
  • the door trim panel 307 is attached to the door inner panel 303 .
  • An arm rest structure 309 is also mounted on the door inner panel 303 .
  • An energy absorbing structure 311 is also interposed between the door trim panel 308 and the door inner panel 303 in the region above the arm rest 0 . 309 and below the window opening 305 .
  • FIG. 3B shows a perspective view of the energy absorbing structure 311 .
  • Energy absorbing structure 311 may include a pair of three-dimensional textile panels 313 , 315 with an interface sheet 317 interposed therebetween.
  • Each textile panel 313 , 315 is made from non-woven fabric materials impregnated with thermoplastic matrix materials according to the exemplary embodiments of the present invention as described above and has a generally planar base 319 with a plurality of projections 317 extending therefrom.
  • the vehicle door 300 with such energy absorbing structure 311 may exhibit high energy absorbing capabilities under multiple impacts.
  • FIG. 4 illustrates a head gear or a helmet 400 , for example a bicycle helmet or a safety helmet, having a relatively hard outer shell 401 with an inner liner 403 made of the exemplary textile composite structure embodiment of the present invention, i.e., a three-dimensional textile structure being made from non-woven fabric materials impregnated with thermoplastic matrix materials and having a generally planar base with a plurality of projections extending therefrom.
  • the inner liner has an arcuate shape for fitting the outer shell 401 .
  • the exemplary textile composite structure 100 may also have other applications such as body protective gear, protective packaging, mattresses, seat cushions, etc. All of these may generally have an outer shell, soft, semi-rigid or rigid, and an energy-absorbing liner within the outer shell including at least an energy-absorbing sheet of textile composite according to the exemplary embodiment of the present invention, i.e., a three-dimensional textile composite structure being made from non-woven fabric materials impregnated with thermoplastic matrix materials and having a generally planar base with a plurality of projections extending therefrom.

Abstract

A three-dimensional cellular textile composite structure with energy-absorbing capacities under multiple impacts is provided. The cellular textile composite structure includes a base, and at least one progressively collapsible projection extending from the base for absorbing energies under the multiple impacts. The projection includes a non-woven textile material supported in a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after the first impact of the multiple impacts.

Description

    BACKGROUND
  • 1. Field of the Invention
  • The present invention relates to three-dimensional textile composite structures with energy-absorbing capacities under multiple impacts, and to the manufacture and use thereof.
  • 2. Background of the Invention
  • Three-dimensional textile composite structures have been widely used for energy absorbing purposes. For example, U.S. Pat. No. 6,536,052, issued to Xiaoming Tao et al. on Mar. 25, 2003 and entitled “Safety Helmets with Cellular Textile Composite Structure as Energy Absorber,” discloses a porous textile composite structure with high energy-absorbing capacities. Preferred embodiments of '052 suggest spraying and then curing thermoset resins onto knitted fabrics for achieving the desired textile composite structures.
  • However, disadvantages exist with such knitted textile composite structure according to the preferred embodiments as disclosed in '052.
  • Firstly, it is observed that under multiple impacts, the knitted textile composite structure according to the preferred embodiments as disclosed In '052 may exhibit unsatisfactory energy-absorbing performance. In particular, the three-dimensional knitted textile composite structure may collapse at the first impact and therefore lose a substantial part of its energy-absorbing capacities.
  • Furthermore, it is also observed the process of spraying and curing thermoset resin onto the fabrics is time consuming. It may take several days for the resin to cure at ambient temperatures.
    • OBJECT OF THE INVENTION
  • Therefore, it is an object of the present invention to provide a textile composite structure with energy-absorbing capacities under multiple impacts, preferably such a structure being made by a faster and more convenient process as compared to '052, or at least provide the public with a useful choice.
    • SUMMARY OF THE INVENTION
  • According to an aspect of present invention, a three-dimensional textile composite structure with energy-absorbing capacities under multiple impacts includes a base, and at least one progressively collapsible projection extending from the base for absorbing energies under the multiple impacts. The projection includes a non-woven textile material supported in a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after the first impact of the multiple impacts.
  • According to a second aspect of the present invention, a process for manufacturing a textile composite structure capable of retaining energy-absorption capacity at least after the first impact of multiple impacts includes the steps of:
      • providing a layer of non-woven textile material;
      • laminating a layer of thermoplastic matrix material with the non-woven textile layer, the thermoplastic matrix material melting at a lower temperature than the non-woven textile;
      • heating the laminate to a processing temperature higher than the melting temperature of the thermoplastic matrix material but lower than the melting temperature of the non-woven textile material;
      • applying pressure to the heated laminate for impregnating the non-woven textile material with the melted thermoplastic matrix material; and
      • molding the non-woven textile material impregnated with the thermoplastic matrix material to a desired shape with a base and a plurality of progressively collapsible projections extending from the base.
  • According to a third aspect of the present invention, an energy-absorbing door includes:
      • inner and outer panels joined together in spaced apart relation; and
      • an energy absorbing structure provided on the inner panel including at least an energy-absorbing sheet of textile composite having a base and a plurality of projections extending from the base,
      • wherein each projection includes a non-woven textile material supported in a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after an initial impact.
  • According to a fourth aspect of the present invention, a safety headgear includes:
      • an outer shell; and
      • an energy-absorbing liner within said outer shell including at least an energy-absorbing sheet of textile composite having a base and a plurality of projections extending from the base,
      • wherein each projection includes a non-woven textile material supported in a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after an initial impact.
  • According to a fifth aspect of the present invention, a body protective gear includes:
      • an outer shell; and
      • an energy-absorbing liner within the outer shell including at least an energy-absorbing sheet of textile composite having a base and a plurality of projections extending from the base,
      • wherein each projection includes a non-woven textile material supported in a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after an initial impact.
  • According to a sixth aspect of the present invention, a protective package includes:
      • an outer shell; and
      • an energy-absorbing liner within the outer shell including at least an energy-absorbing sheet of textile composite having a base and a plurality of projections extending from the base,
      • wherein each projection includes a non-woven textile material supported in a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after an initial impact.
  • According to another aspect of the present invention, a seat cushion includes:
      • an outer shell; and
      • an energy-absorbing liner within the outer shell including at least an energy-absorbing sheet of textile composite having a base and a plurality of projections extending from the base,
      • wherein each projection includes a non-woven textile material supported In a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after an initial impact.
  • Other aspects and advantages of the invention will become apparent from the following detailed description, taken in conjunction with the accompanying drawings, which description illustrates by way of example the principles of the invention.
    • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1A is a perspective diagram of a sheet-like textile composite structure according to an exemplary embodiment of the present invention;
  • FIG. 1B Is top plan view of the textile composite structure of FIG. 1A;
  • FIG. 1C is a cross sectional view of the textile composite structure of FIG. 1A;
  • FIG. 1D is a cross sectional view of the textile composite structure of FIG. 1A, illustrating deformation of the textile composite structure under an impact;
  • FIG. 2 is a diagram illustrating a process of making the textile composite structure of FIG. 1 according to an exemplary embodiment of the present invention;
  • FIG. 3A is a cross-sectional view illustrating a vehicle door in which the textile composite structure of FIG. 1 can be used;
  • FIG. 3B is a perspective view of an energy absorbing structure, which is part of the vehicle door of FIG. 3A; and
  • FIG. 4 is a cross-sectional view illustrating a helmet in which the textile composite structure of FIG. 1 can be used.
    • DETAILED DESCRIPTION
  • FIG. 1 illustrates an exemplary three-dimensional sheet-like textile composite structure 100 with energy-absorbing capacities under multiple impacts. The textile composite structure 100 has a generally planar base 103 and a plurality of projections 105 extending from the base 103. In the exemplary embodiment, each projection 105 has a grid-domed shape with a conical sidewall 107 and a generally flat top 109. Furthermore, each projection 105 defines a space (not shown) where the sidewall 107 and/or the top 109 may collapse under impacts. FIGS. 1B and 1C are respective top plan view and cross sectional view of the textile composite structure of FIG. 1A.
  • The textile composite structure 100, at least the projections 105, includes a textile and a matrix material. More specifically, in the exemplary embodiment, the textile structure 100 is made from non-woven fabric materials impregnated with thermoplastic matrix materials.
  • Materials for producing the non-woven fabric may vary. Examples of the individual yarns in the non-woven fabrics may include strands of fiberglass, carbon, ceramics, and aromatic fibers. A variety of yarns can be used including flat continuous filament yarns, textured or non-textured filament yarns and staple yarns. A mixture of these materials may be used in a single yarn if desired. Preferably, fibers with good mechanical properties for energy absorption and processing are used such as high-density polyethylene, polyester, nylon, and so on. The yarn can be straight or textured including crimped or deformed yarns. Textured yarns may be preferred for the large deformation needed through formation and for better matrix penetration.
  • Methods for producing the non-woven fabric may also vary. Firstly the orientation of the fiber web prepared for production of the non-woven fabric can be in parallel, cross-layered, unidirectional or random. Furthermore, various bonding methods such as chemical bonding, thermal bonding, or mechanical bonding can be used to integrate the fibers in the non-woven fabric. The exemplary embodiment uses at least a mechanical bonding method such as needle-punching to create the non-woven fabric of the exemplary embodiment.
  • Preferably, the non-woven fabric thus produced in the exemplary embodiment is made from staple fibers with a random orientation and a low level of anisotropy in mechanical properties. It is also preferred that the non-woven fabric is resilient and has a bulk form so that the fabric is deformable to form the complex shape and contain sufficient fiber volume fraction in the fabricated composite.
  • On the other hand, examples of the thermoplastic matrix materials include low density polyethylene, polypropylene, polyester, polyamide, polystymene, polyetheretherketone, polyphenlenesulfide, and so on. The thermoplastic matrix material in the exemplary embodiment may be one of the listed materials or a combination of several materials. In either case, in the exemplary embodiment, the thermoplastic matrix material has a lower melting temperature than the non-woven textile material.
  • The exemplary sheet-like textile composite structure 100 with projections made from non-woven fabric impregnated with thermoplastic matrix materials as described above exhibits high energy-absorbing capacities at least after the first impact of the multiple impacts. As illustrated in FIG. 1D, it is observed that once a repeated impact force hits the tops 109 of the projections 105, rings 111 are progressively formed along the side walls 107 when the projections 105 are deformed under the impacts. Therefore, the tops 109 remain intact under the multiple impacts, and the textile composite structure 100 retains high energy-absorbing capacities at least after the first impact of the multiple impacts.
  • Furthermore, such a textile composite structure 100 can be produced through a relatively fast and clean process as discussed in details below.
  • FIG. 2 illustrate an exemplary process of producing a textile composite structure with the capacity of retaining energy-absorption capacity at least after the first impact of the multiple impacts.
  • Firstly, a laminate 201 of a layer of non-woven fabric and a layer of thermoplastic matrix material is provided. The non-woven layer and the thermoplastic matrix layer are made from the materials and methods according to the above illustrative descriptions accompanying FIGS. 1A-1C. Furthermore, in the exemplary embodiment, the non-woven fabric has a melting temperature at least approximately 30 degrees Celsius higher than the melting temperature of the thermoplastic matrix material.
  • The laminate 201 is then heated by a heater 203 in a closed mold cavity (not shown) to a processing temperature higher than the melting temperature of the thermoplastic matrix material but lower than the melting temperature of the non-woven fabric. Preferably, the processing temperature is at least approximately 10 degrees Celsius higher than the melting temperature of the thermoplastic matrix material and at least approximately 10 degrees Celsius lower than the melting temperature of the non-woven fabric. Pressure is also applied to the laminate 201 to force the melted thermoplastic matrix materials to impregnate the fibers of the non-woven fabric in a relatively short period.
  • The processing temperature, pressure applied and the processing time in the step above are well controlled in the exemplary embodiment to avoid polymer degradation. During processing, both the polymeric non-woven fabric and thermoplastic matrix are exposed to an elevated temperature. The processing temperature is controlled such that the fabric and the matrix are not exposed to an extremely high processing temperature so as to avoid unnecessary thermal degradation, which may lead to reduction of the molecular weight of the polymers and thus deteriorate its mechanical behaviors. Furthermore, the processing temperature is controlled to avoid non-woven fabric yellowing, which may happen when the non-woven fabric is processed at very high temperature and/or long exposure time. The applied pressure is also monitored and may be varied at different stages of process to release the air inside the compression mold so as to avoid forming voids therein and to reduce the oxidation.
  • After that, as the laminate 201 is fed by a pair of drive rollers 205 through a pair of heated rollers 207, the laminated 201 is heated to a second processing temperature above the glass transition temperature of the non-woven fabric but below its melting temperature. Thereby, the laminate is thermally softened and partially deformed with the grid-dome-shaped projections 105 temporarily extending from the generally planar bases 103. Subsequently, the partially deformed laminate is fed to a heated mold 209 with grid-dome-shaped projections thereon for permanent molding. After the molding and de-molding, a three-dimensional sheet-like textile structure 100 according to an exemplary embodiment of the present Invention is produced, with a generally planar base and a plurality of projections extending from the base.
  • In the exemplary process described thereabove, the impregnation of the matrix material with the non-woven fabric is achieved within a relatively short period as compared to conventional processes since the heat and press are applied within the closed mold cavity. Furthermore, such a process is proved to be a relatively clean process In that the impregnation of the matrix material with the non-woven fabric is achieved within a closed cavity.
  • The exemplary textile structure 100 described above may have different applications. For example, in FIG. 3A, a cross-sectional view of a typical vehicle door 200 is shown and includes an outer panel 301 and an inner panel 303, which are spaced apart to define a vehicle door structure carrying a window regulator mechanism, door latch, and other components of a vehicle door. The inner and outer panels define a window opening 305.
  • A door trim panel 307 is formed of a suitable material such as pressed hardboard or plastic and is covered with a suitable decorative material such as vinyl, leather, cloth, carpeting or the like. The door trim panel 307 is attached to the door inner panel 303. An arm rest structure 309 is also mounted on the door inner panel 303.
  • An energy absorbing structure 311 is also interposed between the door trim panel 308 and the door inner panel 303 in the region above the arm rest 0.309 and below the window opening 305.
  • FIG. 3B shows a perspective view of the energy absorbing structure 311. Energy absorbing structure 311 may include a pair of three- dimensional textile panels 313, 315 with an interface sheet 317 interposed therebetween. Each textile panel 313, 315 is made from non-woven fabric materials impregnated with thermoplastic matrix materials according to the exemplary embodiments of the present invention as described above and has a generally planar base 319 with a plurality of projections 317 extending therefrom.
  • The vehicle door 300 with such energy absorbing structure 311 may exhibit high energy absorbing capabilities under multiple impacts.
  • FIG. 4 illustrates a head gear or a helmet 400, for example a bicycle helmet or a safety helmet, having a relatively hard outer shell 401 with an inner liner 403 made of the exemplary textile composite structure embodiment of the present invention, i.e., a three-dimensional textile structure being made from non-woven fabric materials impregnated with thermoplastic matrix materials and having a generally planar base with a plurality of projections extending therefrom. It is noted that the inner liner has an arcuate shape for fitting the outer shell 401.
  • It is understood that the exemplary textile composite structure 100 may also have other applications such as body protective gear, protective packaging, mattresses, seat cushions, etc. All of these may generally have an outer shell, soft, semi-rigid or rigid, and an energy-absorbing liner within the outer shell including at least an energy-absorbing sheet of textile composite according to the exemplary embodiment of the present invention, i.e., a three-dimensional textile composite structure being made from non-woven fabric materials impregnated with thermoplastic matrix materials and having a generally planar base with a plurality of projections extending therefrom.

Claims (17)

1. A three-dimensional textile composite structure with energy-absorbing capacities under multiple impacts, comprising:
a base, and
at least one progressively collapsible projection extending from the base for absorbing energies under the multiple Impacts,
wherein the projection includes a non-woven textile material supported in a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after the first impact of the multiple impacts.
2. The structure of claim 1, wherein the projection has a grid-domed shape.
3. The structure of claim 1, wherein the non-woven textile material is made from staple fibers with a random orientation.
4. The structure of claim 3, wherein the staple fibers have a low level of anisotropy in mechanical properties.
5. The structure of claim 1, wherein the thermoplastic matrix material has a melting temperature lower than the no-woven textile material.
6. The structure of claim 1, wherein the non-woven textile material is impregnated with the thermoplastic matrix material by the following steps:
laminating a layer of the thermoplastic matrix material with a layer of the non-woven textile material;
heating the laminate to a processing temperature higher than the melting temperature of the thermoplastic matrix material but lower than the melting temperature of the non-woven textile material; and
applying pressure to the heated laminate for impregnating the non-woven textile material with the melted thermoplastic matrix material.
7. A process for manufacturing a textile composite structure capable of retaining energy-absorption capacity at least after the first impact of multiple impacts, comprising:
providing a layer of non-woven textile material;
laminating a layer of thermoplastic matrix material with the non-woven textile layer, the thermoplastic matrix material melting at a lower temperature than the non-woven textile;
heating the laminate to a processing temperature higher than the melting temperature of the thermoplastic matrix material but lower than the melting temperature of the non-woven textile material;
applying pressure to the heated laminate for impregnating the non-woven textile material with the melted thermoplastic matrix material; and
molding the non-woven textile material impregnated with the thermoplastic matrix material to a desired shape with a base and a plurality of progressively collapsible projections extending from the base.
8. The process of claim 7, wherein the heating step includes raising the processing temperature to at least five degrees higher than the melting temperature of the thermoplastic matrix material.
9. The process of claim 7, wherein the projections have a grid-domed shape.
10. The process of claim 7, wherein the non-woven textile material is made from staple fibers with a random orientation
11. The process of claim 10, wherein the staple fibers have a low level of anisotropy in mechanical properties.
12. The process of claim 7, further comprising:
obtaining the non-woven textile layer by processing a layer of fabrics using a process selected from needle-punching, water jet penetration, melting binding, adhesive bonding, melt-blowing and bonding by adhesive fibers.
13. An energy-absorbing door, comprising:
inner and outer panels joined together in spaced apart relation; and
an energy absorbing structure provided on the inner panel including at least an energy-absorbing sheet of textile composite having a base and a plurality of projections extending from the base,
wherein each projection includes a non-woven textile material supported in a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after an initial Impact.
14. A safety headwear, comprising:
an outer shell; and
an energy-absorbing liner within said outer shell including at least an energy-absorbing sheet of textile composite having a base and a plurality of projections extending from the base,
wherein each projection Includes a non-woven textile material supported in a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after an initial impact.
15. A body protective gear, comprising:
an outer surface; and
an energy-absorbing liner within the outer surface including at least an energy-absorbing sheet of textile composite having a base and a
wherein each projection includes a non-woven textile material supported in a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after an initial Impact.
16. A protective package, comprising
an outer shell; and
an energy-absorbing liner within the outer shell including at least an energy-absorbing sheet of textile composite having a base and a plurality of projections extending from the base,
wherein each projection includes a non-woven textile material supported in a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after an initial impact.
17. A seat cushion, comprising
an outer shell; and
an energy-absorbing liner within said outer shell including at least an energy-absorbing sheet of textile composite having a base and a plurality of projections extending from the base,
wherein each projection includes a non-woven textile material supported in a thermoplastic matrix material such that the projection is capable of retaining energy-absorption capacity at least after an initial impact.
US10/791,280 2004-03-03 2004-03-03 Three-dimensional textile composite structure and manufacture and use thereof Abandoned US20050196592A1 (en)

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US9516910B2 (en) 2011-07-01 2016-12-13 Intellectual Property Holdings, Llc Helmet impact liner system
CN106696288A (en) * 2012-07-18 2017-05-24 三菱丽阳株式会社 Fiber reinforced composite material structure, composite material molded body using the same, and manufacturing method therefor
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IT202100006620A1 (en) * 2021-03-19 2022-09-19 Tibi Optima Sagl BODY IMPACT PROTECTIVE DEVICE

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US20180132557A1 (en) * 2015-05-19 2018-05-17 Maurício Paranhos Torres Improvements to Skull Protection Cell
US11419381B2 (en) * 2015-05-19 2022-08-23 Maurício Paranhos Torres Cranial protection cell
US10736371B2 (en) 2016-10-01 2020-08-11 Choon Kee Lee Mechanical-waves attenuating protective headgear
US10433610B2 (en) * 2017-11-16 2019-10-08 Choon Kee Lee Mechanical-waves attenuating protective headgear
US10561189B2 (en) 2017-12-06 2020-02-18 Choon Kee Lee Protective headgear
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