US20040065056A1 - Patch for flexible container - Google Patents
Patch for flexible container Download PDFInfo
- Publication number
- US20040065056A1 US20040065056A1 US10/065,317 US6531702A US2004065056A1 US 20040065056 A1 US20040065056 A1 US 20040065056A1 US 6531702 A US6531702 A US 6531702A US 2004065056 A1 US2004065056 A1 US 2004065056A1
- Authority
- US
- United States
- Prior art keywords
- layer
- patch
- container
- back wall
- container system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000463 material Substances 0.000 claims abstract description 29
- 230000009969 flowable effect Effects 0.000 claims abstract description 7
- 239000010410 layer Substances 0.000 claims description 141
- 239000012528 membrane Substances 0.000 claims description 38
- -1 polyethylene Polymers 0.000 claims description 25
- 239000004698 Polyethylene Substances 0.000 claims description 23
- 229920000573 polyethylene Polymers 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 19
- 239000000853 adhesive Substances 0.000 claims description 14
- 230000001070 adhesive effect Effects 0.000 claims description 14
- 239000004952 Polyamide Substances 0.000 claims description 13
- 229920002647 polyamide Polymers 0.000 claims description 13
- 229920000728 polyester Polymers 0.000 claims description 11
- 238000001125 extrusion Methods 0.000 claims description 8
- 239000011324 bead Substances 0.000 claims description 7
- 239000002356 single layer Substances 0.000 claims description 7
- 229920001684 low density polyethylene Polymers 0.000 claims description 5
- 239000004702 low-density polyethylene Substances 0.000 claims description 5
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 238000007789 sealing Methods 0.000 description 9
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- 241001122767 Theaceae Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 235000013351 cheese Nutrition 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 235000008504 concentrate Nutrition 0.000 description 2
- 235000013365 dairy product Nutrition 0.000 description 2
- 235000015203 fruit juice Nutrition 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 235000011962 puddings Nutrition 0.000 description 2
- 235000015067 sauces Nutrition 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000003032 molecular docking Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
- B65D75/52—Details
- B65D75/58—Opening or contents-removing devices added or incorporated during package manufacture
- B65D75/5861—Spouts
- B65D75/5872—Non-integral spouts
- B65D75/5877—Non-integral spouts connected to a planar surface of the package wall
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B61/00—Auxiliary devices, not otherwise provided for, for operating on sheets, blanks, webs, binding material, containers or packages
- B65B61/18—Auxiliary devices, not otherwise provided for, for operating on sheets, blanks, webs, binding material, containers or packages for making package-opening or unpacking elements
- B65B61/186—Auxiliary devices, not otherwise provided for, for operating on sheets, blanks, webs, binding material, containers or packages for making package-opening or unpacking elements by applying or incorporating rigid fittings, e.g. discharge spouts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B61/00—Auxiliary devices, not otherwise provided for, for operating on sheets, blanks, webs, binding material, containers or packages
- B65B61/20—Auxiliary devices, not otherwise provided for, for operating on sheets, blanks, webs, binding material, containers or packages for adding cards, coupons or other inserts to package contents
- B65B61/202—Auxiliary devices, not otherwise provided for, for operating on sheets, blanks, webs, binding material, containers or packages for adding cards, coupons or other inserts to package contents for attaching articles to the outside of a container
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D33/00—Details of, or accessories for, sacks or bags
- B65D33/02—Local reinforcements or stiffening inserts, e.g. wires, strings, strips or frames
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B55/00—Preserving, protecting or purifying packages or package contents in association with packaging
- B65B55/02—Sterilising, e.g. of complete packages
- B65B55/022—Sterilising, e.g. of complete packages of flexible containers having a filling and dispensing spout, e.g. containers of the "bag-in-box"-type
Definitions
- This invention relates to filling flexible containers, and particularly to aseptically filling such containers.
- Flexible polymeric containers are well known for storing and dispensing wine, dairy products, enteral feeding solutions, fruit juices, tea and coffee concentrates, puddings, cheese sauces, and many other flowable materials, including those that must be filled aseptically. These generally include low acid materials.
- Flexible polymeric containers typically have walls made of polymeric films with either a monolayer or multiple layer structure. The particular polymers constituting the container film layers vary depending on the type of material to be placed in the container. The film layers may also include an oxygen barrier material layer to prevent contact between such materials and oxygen or other gas sensitive contents.
- the walls of the containers may be metallized, or coated with a metallic layer such as aluminum to prevent incursion of oxygen or other gases. A separate metallized enclosure may also encase the polymeric container.
- the flexible polymeric containers have inlets and/or spouts for filling and dispensing the container contents.
- the containers are also often placed within a box.
- the spout extends through an opening in the box to dispense the contents.
- Such packaging systems are commonly referred to as “bag-in-box.”
- the present invention provides a container system for flowable materials including a front wall having an inner surface and an outer surface, and a back wall having an inner surface and an outer surface. There is an opening in the front wall.
- the invention further provides a patch attached to the back wall of the container opposite and in substantial registration with the opening.
- the present invention provides a multilayer film patch.
- the film patch includes a first layer of polyester or polyamide, and a second layer of polyethylene.
- the present invention provides a multilayer film patch including a metallized inner layer or an inner layer of polyamide, a first outer layer, a second outer layer.
- the present invention provides a method of filling a flexible container including the steps of providing a flexible container, the container having a front wall, the front wall having an inner surface and an outer surface.
- the front wall has an opening.
- the container also has a back wall.
- the back wall includes an inner surface and an outer surface.
- the method also includes providing a fitment assembly accommodated in the opening in the front wall.
- the fitment assembly has a flange attaching the fitment assembly to the front wall.
- the flange includes a heat sealable membrane attached to the flange.
- the method further includes attaching a patch to a portion of the outer surface of the container back wall, bringing at least part of the inner surface of the portion of the container back wall to which the patch is attached into contact with the heat sealable membrane. Additionally, the method includes applying heat to the patch while the inner surface of the back wall is in contact with the heat sealable membrane to seal the membrane to the flange.
- the method of the present invention provides attaching the patch to the inner surface of the container back wall, and bringing at least part of the patch into contact with the heat sealable membrane.
- the method also provides applying heat to the container back wall while the patch is in contact with the heat sealable membrane to seal the membrane to the flange.
- Yet another embodiment of the present invention provides a method of filling a flexible container including the steps of providing a flexible container, the container having a front wall.
- the front wall has an inner surface and an outer surface, and an opening.
- the container also has a back wall with at least a first layer and a second layer.
- the method also includes providing a fitment assembly accommodated in the opening in the front wall.
- the fitment assembly includes a flange attaching the fitment assembly to the front wall.
- the flange also has a heat sealable membrane attached to the flange.
- the method further includes positioning a patch between the first layer and second layer of the container back wall, and bringing at least part of the back wall into contact with the heat sealable membrane. Lastly, the method includes applying heat to the container back wall while the first layer of the back wall is in contact with the heat sealable membrane to seal the membrane to the flange.
- the present invention protects and strengthens the back wall of the container to prevent compromising the integrity of the back wall through the application of heat to heat seal the flange. Additional features and advantages of the present invention are described in, and will be apparent from, the following Detailed Description of the Invention and the figures.
- FIG. 1 is a schematic side view of a container system of an embodiment of the present invention prior to filling.
- FIG. 2 is a second schematic side view of a container system of an embodiment of the present invention after filling.
- FIG. 3 is a schematic side view of a fitment assembly used in an embodiment of the present invention.
- FIG. 4 is a schematic bottom view of a fitment assembly used in an embodiment of the present invention.
- FIG. 5 is a schematic side view of an embodiment of the patch of the present invention.
- FIG. 6 is a schematic side view of another embodiment of the patch of the present invention.
- FIG. 7 is a schematic side view of a further embodiment of the patch of the present invention.
- FIG. 1 shows a container system 10 including an embodiment of the present invention.
- the container system 10 includes a fitment assembly 12 , a flexible container 14 , and a patch 16 .
- FIG. 1 shows the container system 10 prior to filling the flexible container 14 .
- the flexible container 14 has a front wall 18 and a back wall 20 .
- the front wall 18 has an inner surface 22 and an outer surface 24 .
- the back wall 20 has an inner surface 26 and an outer surface 28 .
- the front wall 18 and back wall 20 of the flexible container 14 are sealed along their periphery 30 .
- the flexible container 14 can be formed by placing the front wall 18 and back wall 20 into registration and sealing the front wall 18 and back wall 20 together along their periphery 30 to form a liquid tight chamber 31 . Any suitable means to attach the front wall 18 and back wall 20 may be used, but they are preferably heat sealed. It is also contemplated that the flexible container 14 can be fabricated using a blown tube extrusion process where longitudinal ends of the tube are sealed to form the liquid tight chamber.
- the front wall 18 and back wall 20 may be of any suitable material depending on the contents to be stored in the flexible container 14 .
- the front wall 18 and back wall 20 are formed from a polymeric material such as polyethylene, polyvinyl chloride (PVC), polyolefins, polyamides, polyesters, ethylene vinyl acetate (EVA) to name but a few.
- the front wall 18 and back wall 20 can be monolayer structures or multiple layer structures. The multiple layer structures can be formed by coextrusion, extrusion, lamination, extrusion lamination, or other processes well known in the art.
- the front wall 18 and back wall 20 are made of a single layer of polyethylene.
- the front wall 18 and back wall 20 are made of two laminated layers of polyethylene.
- the front wall 18 has an opening 32 generally centrally disposed on the front wall 18 that accommodates the fitment assembly 12 .
- the opening 32 may be suitably located anywhere within the front wall 18 .
- FIG. 3 shows a side view of the fitment assembly 12 in an embodiment of the present invention.
- the fitment assembly 12 has spout 34 , and a base 38 defining a passageway 36 (FIG. 4).
- the base 38 is flat and generally rectangular shaped, but may be of any suitable shape such as circular.
- the base 38 has a front surface 46 and a back surface 48 .
- the base 38 is attached to the inner surface 22 of the front wall 18 at the front surface 46 .
- Preferably attached to the back surface 48 of the base 38 is a heat sealable membrane 50 .
- the heat sealable membrane 50 has a sealing surface 52 and an other surface 54 .
- the heat sealable membrane 50 can be a monolayer or multiple layer structure.
- the heat sealable membrane 50 is preferably rectangular in shape and initially attached to the back surface 48 of the flange 38 by heat sealing the heat sealing surface 52 to the back surface 48 of the base 38 at points 56 and 58 .
- the heat sealable membrane 50 preferably covers enough of the back surface 48 of the base 38 to overlie the passageway 36 . Edges 60 and 62 of the heat sealable membrane 50 are not initially attached to the back surface 48 to permit the flexible container 14 to be moved away from the base when impacted by a flowable material filled through the fitment assembly 12 .
- the spout 34 has a generally circular cross-sectional shape, but may be of any suitable shape such polygonal or oval.
- the spout 34 is generally centrally disposed on the base, and preferably extends in a perpendicular direction from the base 38 .
- Disposed and spaced along the length of the spout 34 are a first flange 42 and a second flange 44 .
- the first flange 42 is located at a second end 45 of the spout 34 opposite the base 38 .
- the second flange 44 is located at a suitable position between the base 38 and the first flange 42 .
- the first flange 42 and second flange 44 extend around the circumference of the spout 34 , and are integral with the spout 34 .
- the first flange 42 is preferably wider than the second flange 44 .
- the first and second flanges 42 and 44 may accommodate docking to filling equipment, or a fluid access device such as a dispenser accommodated in the passageway 36 .
- a third circumferential flange 47 is integral with the base 38 .
- a rupturable seal 64 Attached to the first flange 42 is a rupturable seal 64 .
- the rupturable seal 64 conforms to the shape of the spout 34 to cover the entire second end 45 and overlie the passageway 36 .
- the rupturable seal 64 is pierced when the flexible container 14 is filled.
- the rupturable seal 64 is made of any suitable material, but is preferably made of the same materials as the heat sealable membrane 50 , and can be a monolayer or a multiple layer structure.
- the spout 34 , base 38 , and first and second flanges 42 and 44 are made of any suitable material, but are preferably made of rigid polymeric materials and more preferably are selected from polypropylenes, high density polyethylenes, polyamides, polycarbonates, polyesters, polyester ethers, polyester elastomers, polystyrenes, acrylonitrile butadiene styrene block copolymers (ABS), polyethylene terephthalate or other rigid polymeric material that can be heat sealed to front wall 18 of the flexible container 14 .
- polypropylenes high density polyethylenes
- polyamides polycarbonates
- polyesters polyester ethers
- polyester elastomers polystyrenes
- ABS acrylonitrile butadiene styrene block copolymers
- ABS acrylonitrile butadiene styrene block copolymers
- Suitable materials for the heat sealable membrane 50 include polyolefins, ethylene vinyl acetate copolymers, PVC, polyamides, polyesters, or any other polymeric material that is adhesively compatible with the base 38 and is capable of being heat sealed thereto.
- the heat sealable membrane 50 is a two-layer film structure having a first layer made of a suitable material for sealing to the back surface 48 of the base 38 , and a second layer that does not readily seal to inner surface 26 of the back wall 20 of the flexible container 14 .
- the patch 16 is preferably attached to the back wall 20 of the flexible container 14 .
- the patch 16 is preferably generally rectangular, but may be any suitable shape.
- the patch 16 is attached to the outer surface 28 of the back wall 20 (FIGS. 1 and 2).
- the patch 16 is positioned on the outer surface 28 such that it is opposite and in substantial registration with the opening 32 and the base 38 of the fitment assembly 12 .
- the patch 16 is also preferably of a surface area less than the surface area of the back wall 20 .
- the patch 16 is preferably a two-layered polymeric film structure.
- the patch 16 includes a first layer 66 of a polyamide, preferably nylon.
- the first layer 66 is of polyester.
- the first layer 66 is metallized.
- the patch 16 also includes a second layer 68 of a polyethylene.
- the second layer 68 is preferably made of a homopolymer of polyethylene, and preferably low density polyethylene.
- the second layer 68 also is preferably approximately 0.0005 inches thick and is extrusion coated onto the first layer 66 .
- the patch 16 includes an additional metallized layer 73 attached to the first layer 66 opposite the second layer 68 (FIG. 5).
- the metallized layer 73 acts to dissipate heat from the heat sealer 78 .
- the metallized layer preferably includes aluminum.
- the second layer 68 has an inner surface 70 and an outer surface 72 .
- the inner surface 70 contacts the first layer 66 .
- the outer surface 72 of the second layer 68 has at least one, but preferably a pair of adhesive beads 74 .
- the adhesive beads 74 attach the patch 16 to a portion 76 of the outer surface 28 of the back wall 20 .
- the adhesive beads 74 can be made of any suitable adhesive.
- the adhesive need not be in the form of beads, but may be a ring of adhesive, or an adhesive layer covering part of or the entire outer surface 72 .
- the adhesive may be applied in any suitable way to keep the patch 16 in place during the process described below.
- the flexible container 14 is filled with contents (not shown) through the passageway 36 .
- a separate dispenser (not shown) may cooperate with the passageway 36 to dispense the contents of the flexible container 14 .
- the contents may also be dispensed through the passageway 36 .
- the contents can include any suitable substance, including wine, dairy products, enteral feeding solutions, fruit juices, tea and coffee concentrates, puddings, cheese sauces, low acid materials and many other flowable materials that can be contained in and dispensed from a flexible container and must be filled aseptically.
- FIG. 2 shows the fitment assembly 12 , flexible container 14 , and patch 16 after the flexible container 14 has been filled, and when it is being resealed.
- a heat sealer 78 is brought into contact with the patch 16 .
- the heat sealer 78 is advanced until the inner surface 26 of the back wall 20 is brought into contact with the heat sealable membrane 50 . Heat transferred from the heat sealer 78 causes the heat sealable membrane 50 to adhere to the back surface 48 of the base 38 , thus resealing the passageway 36 of the flexible container 14 to retain the contents.
- the heat sealer 78 operates at approximately 180° C. to 200° C., and is of any suitable type well known in the art.
- the patch 16 protects the back wall 20 from direct heat from the heat sealer 78 by absorbing heat that would otherwise have been directly absorbed by the back wall 20 of the flexible container 14 , thereby insulating the back wall 20 from the heat sealer 78 . This prevents compromising the integrity of the back wall 20 at the point where the heat sealer 78 meets the back wall 20 .
- the patch 16 also adds mechanical strength to the area of the flexible container 14 that contacts the heat sealer 78 .
- the patch 16 preferably has at least the same surface area as the heat sealer 78 .
- the second layer 68 of the patch 16 and the back wall 20 melt, thereby sealing the second layer 68 and the back wall 20 together
- the melting temperature of polyester is 250° C.
- the melting temperature of polyethylene is 105° C.
- the first layer 66 acts to hold together the back wall 20 and second layer 68 .
- the second layer 68 also acts as a material reservoir, replacing any material squeezed from the back wall 20 to maintain structural integrity.
- the first layer 66 is preferably of a material that has a higher melting temperature than the second layer 68 .
- the patch 16 is located within the flexible container 14 , attached to the inner surface 26 of the back wall 20 .
- FIG. 6 shows the beads 74 of adhesive attaching the patch 16 to the inner surface 26 of the back wall 20 such that it is opposite and in substantial registration with the opening 32 and flange 38 of the fitment assembly 12 .
- the patch 16 includes a first layer 80 and a second layer 82 .
- the first layer 80 and second layer 82 preferably made of the same materials as the first layer 66 and second layer 68 of the embodiment described above.
- the heat sealer 78 directly contacts the outer surface 28 of the back wall 20 of the flexible container 14 .
- the second layer 82 of the patch 16 acts a reservoir of material to replace any material squeezed out from pressure provided by the heat sealer 78 .
- the first layer 80 maintains structural integrity of the patch 16 .
- the patch 16 is located between the inner surface 26 and outer surface 28 of the back wall 20 .
- the back wall 20 is preferably made of at least a two layered structure having a first layer 20 a and second layer 20 b .
- the first layer 20 a and second layer 20 b of the back wall 20 are both made of polyethylene.
- the patch 16 is located between the two layers 20 a and 20 b , in a position such that it is opposite and in substantial registration with the opening 32 and flange 38 of the fitment assembly 12 .
- the patch 16 of FIG. 7 includes an inner layer 86 surrounded by a first outer layer 84 and a second outer layer 88 .
- the inner layer 86 is metallized similar to metallized layer 73 described above, and the first outer layer 84 and second outer layer 88 are both of polyethylene.
- the inner layer 86 is of a polyamide such as nylon, and the first and second outer layers 84 and 88 are of polyethylene.
- the heat sealer 78 directly contacts the outer layer 20 b of the back wall 20 .
- the first and second outer layers 84 and 88 are preferably of polyethylene, and act as a reservoir for materials squeezed out during melting by pressure from the heat sealer 78 .
Abstract
The present invention provides a container system for flowable materials including a front wall having an inner surface and an outer surface, and a back wall having an inner surface and an outer surface. There is an opening in the front wall. The present invention further provides a patch attached to the back wall of the container, the patch opposite and in substantial registration with the opening.
Description
- This invention relates to filling flexible containers, and particularly to aseptically filling such containers. Flexible polymeric containers are well known for storing and dispensing wine, dairy products, enteral feeding solutions, fruit juices, tea and coffee concentrates, puddings, cheese sauces, and many other flowable materials, including those that must be filled aseptically. These generally include low acid materials. Flexible polymeric containers typically have walls made of polymeric films with either a monolayer or multiple layer structure. The particular polymers constituting the container film layers vary depending on the type of material to be placed in the container. The film layers may also include an oxygen barrier material layer to prevent contact between such materials and oxygen or other gas sensitive contents. The walls of the containers may be metallized, or coated with a metallic layer such as aluminum to prevent incursion of oxygen or other gases. A separate metallized enclosure may also encase the polymeric container.
- The flexible polymeric containers have inlets and/or spouts for filling and dispensing the container contents. The containers are also often placed within a box. The spout extends through an opening in the box to dispense the contents. Such packaging systems are commonly referred to as “bag-in-box.”
- Filling equipment used to aseptically fill flexible containers is well known in the art. Prior art examples include U.S. Pat. No. 4,519,184, to Brunswick; U.S. Pat. No. 4,942,716 to Anderson; and U.S. Pat. No. 4,805,378 to Anderson. In particular, U.S. Pat. No. 4,805,378 (the '378 patent), incorporated by reference as though made a part hereof, discloses a method and system for aseptically filling flexible containers. The '378 patent discloses a system and method in which the container inlet is covered by a rupturable closure. The rupturable closure is broken to fill the container. The inlet has a heat sealable flap located opposite the rupturable closure. After filling, the inlet is closed by heat sealing the flap to the interior of the inlet.
- It has been found that the '378 patent method and apparatus works well with containers having an outer metallized layer or separate metallized enclosure. The metallized layer or enclosure dissipates heat created by the heat sealing. However, heat applied directly to polymeric containers lacking the metallized layer or enclosure does not dissipate, and unacceptably compromises the integrity of the container by weakening it in the area where the heat is applied.
- In one embodiment, the present invention provides a container system for flowable materials including a front wall having an inner surface and an outer surface, and a back wall having an inner surface and an outer surface. There is an opening in the front wall. The invention further provides a patch attached to the back wall of the container opposite and in substantial registration with the opening.
- In another embodiment, the present invention provides a multilayer film patch. The film patch includes a first layer of polyester or polyamide, and a second layer of polyethylene. In a further embodiment, the present invention provides a multilayer film patch including a metallized inner layer or an inner layer of polyamide, a first outer layer, a second outer layer.
- In a still further embodiment, the present invention provides a method of filling a flexible container including the steps of providing a flexible container, the container having a front wall, the front wall having an inner surface and an outer surface. The front wall has an opening. The container also has a back wall. The back wall includes an inner surface and an outer surface. The method also includes providing a fitment assembly accommodated in the opening in the front wall. The fitment assembly has a flange attaching the fitment assembly to the front wall. The flange includes a heat sealable membrane attached to the flange.
- The method further includes attaching a patch to a portion of the outer surface of the container back wall, bringing at least part of the inner surface of the portion of the container back wall to which the patch is attached into contact with the heat sealable membrane. Additionally, the method includes applying heat to the patch while the inner surface of the back wall is in contact with the heat sealable membrane to seal the membrane to the flange.
- Alternatively, the method of the present invention provides attaching the patch to the inner surface of the container back wall, and bringing at least part of the patch into contact with the heat sealable membrane. The method also provides applying heat to the container back wall while the patch is in contact with the heat sealable membrane to seal the membrane to the flange.
- Yet another embodiment of the present invention provides a method of filling a flexible container including the steps of providing a flexible container, the container having a front wall. The front wall has an inner surface and an outer surface, and an opening. The container also has a back wall with at least a first layer and a second layer. The method also includes providing a fitment assembly accommodated in the opening in the front wall. The fitment assembly includes a flange attaching the fitment assembly to the front wall. The flange also has a heat sealable membrane attached to the flange.
- The method further includes positioning a patch between the first layer and second layer of the container back wall, and bringing at least part of the back wall into contact with the heat sealable membrane. Lastly, the method includes applying heat to the container back wall while the first layer of the back wall is in contact with the heat sealable membrane to seal the membrane to the flange.
- The present invention protects and strengthens the back wall of the container to prevent compromising the integrity of the back wall through the application of heat to heat seal the flange. Additional features and advantages of the present invention are described in, and will be apparent from, the following Detailed Description of the Invention and the figures.
- FIG. 1 is a schematic side view of a container system of an embodiment of the present invention prior to filling.
- FIG. 2 is a second schematic side view of a container system of an embodiment of the present invention after filling.
- FIG. 3 is a schematic side view of a fitment assembly used in an embodiment of the present invention.
- FIG. 4 is a schematic bottom view of a fitment assembly used in an embodiment of the present invention.
- FIG. 5 is a schematic side view of an embodiment of the patch of the present invention.
- FIG. 6 is a schematic side view of another embodiment of the patch of the present invention.
- FIG. 7 is a schematic side view of a further embodiment of the patch of the present invention.
- FIG. 1 shows a
container system 10 including an embodiment of the present invention. Thecontainer system 10 includes afitment assembly 12, aflexible container 14, and apatch 16. FIG. 1 shows thecontainer system 10 prior to filling theflexible container 14. - The
flexible container 14 has afront wall 18 and aback wall 20. Thefront wall 18 has aninner surface 22 and anouter surface 24. Theback wall 20 has aninner surface 26 and anouter surface 28. Thefront wall 18 andback wall 20 of theflexible container 14 are sealed along theirperiphery 30. Theflexible container 14 can be formed by placing thefront wall 18 andback wall 20 into registration and sealing thefront wall 18 andback wall 20 together along theirperiphery 30 to form a liquidtight chamber 31. Any suitable means to attach thefront wall 18 andback wall 20 may be used, but they are preferably heat sealed. It is also contemplated that theflexible container 14 can be fabricated using a blown tube extrusion process where longitudinal ends of the tube are sealed to form the liquid tight chamber. - The
front wall 18 andback wall 20 may be of any suitable material depending on the contents to be stored in theflexible container 14. Preferably, thefront wall 18 andback wall 20 are formed from a polymeric material such as polyethylene, polyvinyl chloride (PVC), polyolefins, polyamides, polyesters, ethylene vinyl acetate (EVA) to name but a few. Thefront wall 18 andback wall 20 can be monolayer structures or multiple layer structures. The multiple layer structures can be formed by coextrusion, extrusion, lamination, extrusion lamination, or other processes well known in the art. In a preferred embodiment, thefront wall 18 andback wall 20 are made of a single layer of polyethylene. In another embodiment, thefront wall 18 andback wall 20 are made of two laminated layers of polyethylene. Thefront wall 18 has anopening 32 generally centrally disposed on thefront wall 18 that accommodates thefitment assembly 12. Theopening 32, however, may be suitably located anywhere within thefront wall 18. - FIG. 3 shows a side view of the
fitment assembly 12 in an embodiment of the present invention. Thefitment assembly 12 has spout 34, and a base 38 defining a passageway 36 (FIG. 4). In a preferred form of the invention, thebase 38 is flat and generally rectangular shaped, but may be of any suitable shape such as circular. Thebase 38 has afront surface 46 and aback surface 48. Thebase 38 is attached to theinner surface 22 of thefront wall 18 at thefront surface 46. Preferably attached to theback surface 48 of thebase 38 is aheat sealable membrane 50. Theheat sealable membrane 50 has a sealingsurface 52 and another surface 54. Theheat sealable membrane 50 can be a monolayer or multiple layer structure. Theheat sealable membrane 50 is preferably rectangular in shape and initially attached to theback surface 48 of theflange 38 by heat sealing theheat sealing surface 52 to theback surface 48 of the base 38 atpoints heat sealable membrane 50 preferably covers enough of theback surface 48 of the base 38 to overlie thepassageway 36.Edges heat sealable membrane 50 are not initially attached to theback surface 48 to permit theflexible container 14 to be moved away from the base when impacted by a flowable material filled through thefitment assembly 12. - The
spout 34 has a generally circular cross-sectional shape, but may be of any suitable shape such polygonal or oval. Thespout 34 is generally centrally disposed on the base, and preferably extends in a perpendicular direction from thebase 38. Disposed and spaced along the length of thespout 34 are afirst flange 42 and asecond flange 44. Thefirst flange 42 is located at asecond end 45 of thespout 34 opposite thebase 38. Thesecond flange 44 is located at a suitable position between the base 38 and thefirst flange 42. Thefirst flange 42 andsecond flange 44 extend around the circumference of thespout 34, and are integral with thespout 34. Thefirst flange 42 is preferably wider than thesecond flange 44. The first andsecond flanges passageway 36. A thirdcircumferential flange 47 is integral with thebase 38. - Attached to the
first flange 42 is arupturable seal 64. Therupturable seal 64 conforms to the shape of thespout 34 to cover the entiresecond end 45 and overlie thepassageway 36. Therupturable seal 64 is pierced when theflexible container 14 is filled. Therupturable seal 64 is made of any suitable material, but is preferably made of the same materials as theheat sealable membrane 50, and can be a monolayer or a multiple layer structure. After theflexible container 14 is filled, a cap (not shown) is placed over thesecond end 45 of thespout 34 to sealpassageway 36. - The
spout 34,base 38, and first andsecond flanges front wall 18 of theflexible container 14. Suitable materials for theheat sealable membrane 50 include polyolefins, ethylene vinyl acetate copolymers, PVC, polyamides, polyesters, or any other polymeric material that is adhesively compatible with thebase 38 and is capable of being heat sealed thereto. In one preferred form of the invention, theheat sealable membrane 50 is a two-layer film structure having a first layer made of a suitable material for sealing to theback surface 48 of thebase 38, and a second layer that does not readily seal toinner surface 26 of theback wall 20 of theflexible container 14. - The
patch 16 is preferably attached to theback wall 20 of theflexible container 14. Thepatch 16 is preferably generally rectangular, but may be any suitable shape. In one preferred embodiment, thepatch 16 is attached to theouter surface 28 of the back wall 20 (FIGS. 1 and 2). Thepatch 16 is positioned on theouter surface 28 such that it is opposite and in substantial registration with theopening 32 and thebase 38 of thefitment assembly 12. Thepatch 16 is also preferably of a surface area less than the surface area of theback wall 20. - The
patch 16 is preferably a two-layered polymeric film structure. In a preferred form of the invention, thepatch 16 includes afirst layer 66 of a polyamide, preferably nylon. In another preferred embodiment, thefirst layer 66 is of polyester. In another embodiment, thefirst layer 66 is metallized. - The
patch 16 also includes asecond layer 68 of a polyethylene. Thesecond layer 68 is preferably made of a homopolymer of polyethylene, and preferably low density polyethylene. Thesecond layer 68 also is preferably approximately 0.0005 inches thick and is extrusion coated onto thefirst layer 66. In another embodiment, thepatch 16 includes anadditional metallized layer 73 attached to thefirst layer 66 opposite the second layer 68 (FIG. 5). The metallizedlayer 73 acts to dissipate heat from theheat sealer 78. The metallized layer preferably includes aluminum. - The
second layer 68 has aninner surface 70 and anouter surface 72. Theinner surface 70 contacts thefirst layer 66. Theouter surface 72 of thesecond layer 68 has at least one, but preferably a pair ofadhesive beads 74. Theadhesive beads 74 attach thepatch 16 to aportion 76 of theouter surface 28 of theback wall 20. Theadhesive beads 74 can be made of any suitable adhesive. The adhesive need not be in the form of beads, but may be a ring of adhesive, or an adhesive layer covering part of or the entireouter surface 72. The adhesive may be applied in any suitable way to keep thepatch 16 in place during the process described below. - In operation, the
flexible container 14 is filled with contents (not shown) through thepassageway 36. A separate dispenser (not shown) may cooperate with thepassageway 36 to dispense the contents of theflexible container 14. The contents may also be dispensed through thepassageway 36. The contents can include any suitable substance, including wine, dairy products, enteral feeding solutions, fruit juices, tea and coffee concentrates, puddings, cheese sauces, low acid materials and many other flowable materials that can be contained in and dispensed from a flexible container and must be filled aseptically. - To fill the
flexible container 14, therupturable seal 64 is punctured, and the contents fill theflexible container 14 through thepassageway 36. FIG. 2 shows thefitment assembly 12,flexible container 14, andpatch 16 after theflexible container 14 has been filled, and when it is being resealed. After filling, aheat sealer 78 is brought into contact with thepatch 16. Theheat sealer 78 is advanced until theinner surface 26 of theback wall 20 is brought into contact with theheat sealable membrane 50. Heat transferred from theheat sealer 78 causes theheat sealable membrane 50 to adhere to theback surface 48 of thebase 38, thus resealing thepassageway 36 of theflexible container 14 to retain the contents. Theheat sealer 78 operates at approximately 180° C. to 200° C., and is of any suitable type well known in the art. Thepatch 16 protects theback wall 20 from direct heat from theheat sealer 78 by absorbing heat that would otherwise have been directly absorbed by theback wall 20 of theflexible container 14, thereby insulating theback wall 20 from theheat sealer 78. This prevents compromising the integrity of theback wall 20 at the point where theheat sealer 78 meets theback wall 20. - The
patch 16 also adds mechanical strength to the area of theflexible container 14 that contacts theheat sealer 78. Thepatch 16 preferably has at least the same surface area as theheat sealer 78. During heat sealing, thesecond layer 68 of thepatch 16 and theback wall 20 melt, thereby sealing thesecond layer 68 and theback wall 20 together The melting temperature of polyester is 250° C. The melting temperature of polyethylene is 105° C. Thefirst layer 66 acts to hold together theback wall 20 andsecond layer 68. Thesecond layer 68 also acts as a material reservoir, replacing any material squeezed from theback wall 20 to maintain structural integrity. Thefirst layer 66 is preferably of a material that has a higher melting temperature than thesecond layer 68. - In another embodiment, the
patch 16 is located within theflexible container 14, attached to theinner surface 26 of theback wall 20. FIG. 6 shows thebeads 74 of adhesive attaching thepatch 16 to theinner surface 26 of theback wall 20 such that it is opposite and in substantial registration with theopening 32 andflange 38 of thefitment assembly 12. In this embodiment, thepatch 16 includes afirst layer 80 and asecond layer 82. Thefirst layer 80 andsecond layer 82 preferably made of the same materials as thefirst layer 66 andsecond layer 68 of the embodiment described above. In this embodiment, theheat sealer 78 directly contacts theouter surface 28 of theback wall 20 of theflexible container 14. As in the above embodiment, thesecond layer 82 of thepatch 16 acts a reservoir of material to replace any material squeezed out from pressure provided by theheat sealer 78. Thefirst layer 80 maintains structural integrity of thepatch 16. - In a further embodiment shown in FIG. 7, the
patch 16 is located between theinner surface 26 andouter surface 28 of theback wall 20. In this embodiment, theback wall 20 is preferably made of at least a two layered structure having afirst layer 20 a and second layer 20 b. In a preferred embodiment, thefirst layer 20 a and second layer 20 b of theback wall 20 are both made of polyethylene. Thepatch 16 is located between the twolayers 20 a and 20 b, in a position such that it is opposite and in substantial registration with theopening 32 andflange 38 of thefitment assembly 12. - The
patch 16 of FIG. 7 includes aninner layer 86 surrounded by a firstouter layer 84 and a secondouter layer 88. In a preferred embodiment, theinner layer 86 is metallized similar to metallizedlayer 73 described above, and the firstouter layer 84 and secondouter layer 88 are both of polyethylene. In another preferred embodiment, theinner layer 86 is of a polyamide such as nylon, and the first and secondouter layers heat sealer 78 directly contacts the outer layer 20 b of theback wall 20. The first and secondouter layers heat sealer 78. - It should be understood that various changes and modifications to the presently preferred embodiments described herein will be apparent to those skilled in the art. Such changes and modifications can be made without departing from the spirit and scope of the present invention and without diminishing its intended advantages. It is therefore intended that such changes and modifications be covered by the appended claims.
Claims (55)
1. A container system for flowable materials comprising:
a front wall having an inner surface and an outer surface;
a back wall having an inner surface and an outer surface;
an opening in the front wall; and
a patch attached to the back wall of the container, the patch opposite and in substantial registration with the opening.
2. The container system of claim 1 wherein the patch is attached to the inner surface of the back wall.
3. The container system of claim 1 wherein the patch is attached to the outer surface of the back wall.
4. The container system of claim 1 further comprising a fitment assembly accommodated in the opening in the front wall, the fitment assembly having a flange attaching the fitment assembly to the front wall.
5. The container system of claim 4 further comprising a heat sealable membrane attached to the flange.
6. The container system of claim 5 wherein the heat sealable membrane is a monolayer structure or a multiple layer structure.
7. The container system of claim 6 wherein the heat sealable membrane is a two layer structure.
8. The container system of claim 7 wherein the heat sealable membrane includes a first heat sealable film layer and a second non-heat sealable film layer.
9. The container system of claim 8 wherein the first heat sealable film layer is selected from the group of polyolefins, ethylene vinyl acetate copolymers, PVC, polyamides, and polyesters.
10. The container system of claim 8 wherein the second non-heat sealable film layer is selected from the group of polyolefins, ethylene vinyl acetate copolymers, PVC, polyamides, and polyesters.
11. The container system of claim 1 wherein the patch is a monolayer structure or a multiple layer structure.
12. The container system of claim 11 wherein the patch is a two layer structure.
13. The container system of claim 12 wherein the patch includes a first layer of polyamide, and a second layer.
14. The container system of claim 13 wherein the second layer is polyethylene.
15. The container system of claim 11 wherein the patch is a three layer structure.
16. The container system of claim 15 wherein the patch includes a first layer, a second layer, and a third metallized layer attached to the first layer opposite the second layer.
17. The container system of claim 15 wherein the patch includes an inner layer, a first outer layer, and a second outer layer.
18. The container system of claim 17 wherein the inner layer is metallized.
19. The container system of claim 17 wherein the inner layer is a polyamide.
20. The container system of claim 17 wherein the first outer layer is polyethylene.
21. The container system of claim 17 wherein the second outer layer is polyethylene.
22. The container system of claim 14 wherein the second layer is low density polyethylene.
23. The container system of claim 14 wherein the second layer is approximately 0.0005 inches thick.
24. The container system of claim 13 wherein the second layer is extrusion coated onto the first layer.
25. The container system of claim 12 wherein the patch includes a first layer of polyester, and a second layer.
26. The container system of claim 25 wherein the second layer is polyethylene.
27. The container system of claim 26 wherein the second layer is low density polyethylene.
28. The container system of claim 26 wherein the second layer is approximately 0.0005 inches thick.
29. The container system of claim 25 wherein the second layer is extrusion coated onto the first layer.
30. A multilayer film patch, the patch comprising:
a first layer of polyamide; and
a second layer of polyethylene.
31. The patch of claim 30 wherein the second layer is extrusion coated onto the first layer.
32. The patch of claim 30 wherein the second layer is approximately 0.0005 inches thick.
33. The patch of claim 30 wherein the second layer is a low density polyethylene.
34. The patch of claim 30 wherein the second layer of polyethylene has an outer surface, and further comprising adhesive on the outer surface of the second layer.
35. The patch of claim 34 wherein the adhesive includes at least one bead of adhesive on the outer surface of the second layer.
36. The patch of claim 30 further comprising a third layer attached to the first layer.
37. The patch of claim 36 wherein the third layer is metallized.
38. A multilayer film patch, the patch comprising:
a first layer of polyester; and
a second layer of polyethylene.
39. The patch of claim 38 wherein the second layer of polyethylene has an outer surface, and further comprising adhesive on the outer surface of the second layer.
40. The patch of claim 39 wherein the adhesive includes at least one bead of adhesive on the outer surface of the second layer.
41. The patch of claim 38 wherein the second layer is extrusion coated onto the first layer.
42. The patch of claim 38 wherein the second layer is approximately 0.0005 inches thick.
43. The patch of claim 38 wherein the second layer is a low density polyethylene.
44. A multilayer film patch, the film patch comprising:
an inner metallized layer;
a first outer layer; and
a second outer layer.
45. The patch of claim 44 wherein the first outer layer is polyethylene.
46. The patch of claim 44 wherein the second outer layer is polyethylene.
47. A multilayer film patch, the film patch comprising:
an inner layer of polyamide;
a first outer layer; and
a second outer layer.
48. The patch of claim 47 wherein the first outer layer is polyethylene.
49. The patch of claim 47 wherein the second outer layer is polyethylene.
50. A method of filling a flexible container comprising the steps of:
providing a flexible container, the container having a front wall, the front wall having an inner surface and an outer surface, the front wall also having an opening, the container also having a back wall, the back wall having an inner surface and an outer surface;
providing a fitment assembly accommodated in the opening in the front wall, the fitment assembly having a flange attaching the fitment assembly to the front wall, the flange also having a heat sealable membrane attached to the flange;
attaching a patch to the outer surface of the container back wall;
bringing at least part of the inner surface of the portion of the container back wall to which the patch is attached into contact with the heat sealable membrane; and
applying heat to the patch while the inner surface of the back wall is in contact with the heat sealable membrane to seal the membrane to the flange.
51. A method of filling a flexible container comprising the steps of:
providing a flexible container, the container having a front wall, the front wall having an inner surface and an outer surface, the front wall also having an opening, the container also having a back wall, the back wall having an inner surface and an outer surface;
providing a fitment assembly accommodated in the opening in the front wall, the fitment assembly having a flange attaching the fitment assembly to the front wall, the flange also having a heat sealable membrane attached to the flange;
attaching a patch to the inner surface of the container back wall;
bringing at least part of the patch into contact with the heat sealable membrane; and
applying heat to the container back wall while the patch is in contact with the heat sealable membrane to seal the membrane to the flange.
52. A method of filling a flexible container comprising the steps of:
providing a flexible container, the container having a front wall, the front wall having an inner surface and an outer surface, the front wall also having an opening, the container also having a back wall, the back wall having at least a first layer and a second layer;
providing a fitment assembly accommodated in the opening in the front wall, the fitment assembly having a flange attaching the fitment assembly to the front wall, the flange also having a heat sealable membrane attached to the flange;
positioning a patch between the first layer and second layer of the container back wall;
bringing at least part of the back wall into contact with the heat sealable membrane; and
applying heat to the container back wall while the first layer of the back wall is in contact with the heat sealable membrane to seal the membrane to the flange.
53. A container for a flowable materials comprising:
a front wall having an inner surface and an outer surface;
a back wall having an inner surface and an outer surface;
an opening in the front wall; and
the back wall including a patch opposite the opening.
54. The container of claim 53 wherein the patch is located between the inner and outer surface of the back wall.
55. The container of claim 54 wherein the back wall includes a first layer and a second layer, and the patch is located between first layer and the second layer.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/065,317 US20040065056A1 (en) | 2002-10-02 | 2002-10-02 | Patch for flexible container |
PCT/US2002/031407 WO2004031041A1 (en) | 2002-10-02 | 2002-10-03 | Patch for flexible container |
AU2002330198A AU2002330198A1 (en) | 2002-10-02 | 2002-10-03 | Patch for flexible container |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/065,317 US20040065056A1 (en) | 2002-10-02 | 2002-10-02 | Patch for flexible container |
Publications (1)
Publication Number | Publication Date |
---|---|
US20040065056A1 true US20040065056A1 (en) | 2004-04-08 |
Family
ID=32041304
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/065,317 Abandoned US20040065056A1 (en) | 2002-10-02 | 2002-10-02 | Patch for flexible container |
Country Status (3)
Country | Link |
---|---|
US (1) | US20040065056A1 (en) |
AU (1) | AU2002330198A1 (en) |
WO (1) | WO2004031041A1 (en) |
Cited By (7)
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---|---|---|---|---|
US20070127854A1 (en) * | 2005-12-05 | 2007-06-07 | Smith Mark A | Form fill and seal container |
US20130269827A1 (en) * | 2012-04-10 | 2013-10-17 | John Sheridan Thomas, JR. | Two compartment syringe accessible package and method of using and making the same |
US20140246455A1 (en) * | 2009-09-14 | 2014-09-04 | Pouch Pac Innovations, Llc | Pouch with a tube spout fitment |
EP2581323A4 (en) * | 2010-06-11 | 2015-08-19 | Jeong Sik Han | Pack |
JP2018533527A (en) * | 2015-10-30 | 2018-11-15 | ダウ グローバル テクノロジーズ エルエルシー | Port with diaphragm and ethylene / alpha-olefin multiblock copolymer |
US10526190B2 (en) | 2015-04-17 | 2020-01-07 | Ds Smith Plastics Limited | Multilayer film used with flexible packaging |
WO2022150614A3 (en) * | 2021-01-07 | 2022-08-25 | Trade Secret Chocolates | Methods and apparatus for preserving flavor in food products and shelf-stable food products |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20160122104A1 (en) * | 2014-11-03 | 2016-05-05 | Scholle Corporation | Spout assembly having a barrier film for a flexible bag and a flexible bag having a spout assembly having a barrier film |
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Also Published As
Publication number | Publication date |
---|---|
AU2002330198A1 (en) | 2004-04-23 |
WO2004031041A1 (en) | 2004-04-15 |
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Owner name: DS SMITH (UK) LIMITED, ENGLAND Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:WILFORD, MICHAEL;RUTTER, CHRIS;SMITH, MARK A.;REEL/FRAME:014258/0279;SIGNING DATES FROM 20021209 TO 20021213 |
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