Classifications

• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
  • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
  • D21H17/03—Non-macromolecular organic compounds
  • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
  • D21H17/14—Carboxylic acids; Derivatives thereof
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
  • C08F8/00—Chemical modification by after-treatment
  • C08F8/42—Introducing metal atoms or metal-containing groups
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
  • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
  • D21H17/20—Macromolecular organic compounds
  • D21H17/33—Synthetic macromolecular compounds
  • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
  • D21H17/375—Poly(meth)acrylamide
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
  • D21H17/20—Macromolecular organic compounds
  • D21H17/33—Synthetic macromolecular compounds
  • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • D21H17/53—Polyethers; Polyesters
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
  • D21H17/20—Macromolecular organic compounds
  • D21H17/33—Synthetic macromolecular compounds
  • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • D21H17/59—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon

Definitions

• the cationic charge is attracted to the anionic charge of the cellulose fibers allowing for the material to be retained on the cellulose fibers.
• anionic materials are used, a cationic promoter is required to retain the chemical on the fibers.
• Another limitation associated with wet end addition is the limited availability of adequate bonding sites on the cellulose papermaking fibers to which the chemical additives can attach themselves. Under such circumstances, more than one chemical functionality competes for the limited available bonding sites, oftentimes resulting in the insufficient retention of one or both chemical additives on the cellulose fibers.
• a cellulose papermaking fiber primarily contains two types of functional groups, hydroxyl and carboxyl. At a typical papermaking pH of about 4 to about 9, a portion-of the carboxyl groups are ionized causing the cellulose papermaking fibers to possess a net anionic charge. These anionic sites on the cellulose fibers serve as the source of attachment for wet end chemical additives.
• the amount of carboxyl groups on the cellulose fibers is limited and depends on the nature of the pulp. In general bleached kraft pulps contain about 2 to about 4 milli equivalents of carboxyl per 100 grams of pulp while mechanical pulps may contain upwards of about 30 to about 40 milli equivalents of carboxyl groups per 100 grams of pulp.
• non-ionic chemical additives When added in the wet end, non-ionic chemical additives show poor retention to the cellulose papermaking fibers.
• An option to circumvent this issue is to covalently bond the molecule to the cellulose fibers in some way.
• a problem with covalent bonding to cellulose lies in the type of groups on the cellulose fibers that are available for reaction.
• the two chemically active groups on the cellulose fibers are hydroxyls and carboxyls.
• the carboxyl groups are generally too few in number and too low in reactivity to be useful.
• any reaction at the carboxyl group will reduce the number of available ionic bonding sites on the cellulose fibers hence limiting the ability to retain any charged wet end chemical additives that may need to be used.
• hydroxyl groups While plentiful, are problematic in that anything that can react with a hydroxyl group can also react with water.
• the amount of the hydroxyl groups on water available for reaction is magnitudes of order larger than the amount of the hydroxyl groups of the cellulose fibers available for reaction. Simple kinetics will therefore dictate a preference for reaction with water hydroxyl groups over the cellulose fiber hydroxyl groups.
• This problem can be overcome as exemplified with the sizing agents ASA (alkyl succinic anhydride) and AKD (alkyl ketene dimer).
• ASA alkyl succinic anhydride
• AKD alkyl ketene dimer
• a paper or tissue product normally contains, among other things, a mixture of hardwood and softwood cellulose fibers, as well as a chemical additive to increase strength and a chemical additive to increase softness.
• both softness and strength additives are usually cationic in nature, binding to the anionic sites in the cellulose fibers.
• the number of anionic sites on the cellulose fibers control the number of cationic molecules that can attach to the cellulose fibers.
• Most Kraft pulps typically contain only about 2 to about 3 milli-equivalents of anionic sites per 100 grams of cellulose fiber. However, the number of anionic sites actually on the surface of the fibers available for reacting with the chemical additives may be significantly lower.
• Another problem with using positively charged paper modifying or debonder chemical additives is that these chemical additives must compete with cationic strength chemical additives for the limited anionic bonding sites on the cellulose fibers. This competition may result in unpredictable retention of the paper modifying and strength chemical additives, thereby providing a tissue product having varying softness and strength traits.
• one of the chemical additives typically the paper modifying chemical additive, can be incorporated to the tissue sheet after the sheet formation step by spraying or coating the chemical additive onto the tissue sheet. The chemical additive so applied then reacts with the anionic bonding sites on the surface of the cellulose fibers located on the surface of the tissue sheet.
• this approach can require the installation of the application equipment as well as engineering controls required to minimize airborne chemical exposure.
• Another approach for treating paper or tissue products involves the covalent bonding of the chemical additives to the cellulose fibers.
• a problem with the covalent bonding of the chemical additives to the cellulose fibers resides in the type of groups available on the cellulose fibers that are available to react with the chemical additives.
• the two chemically active groups on the cellulose fibers are hydroxyl and carboxyl groups.
• the carboxyl groups are generally too few in number and too low in reactivity to be useful.
• the hydroxyl groups while more plentiful, are problematic in that a chemical additive that is capable of reacting with a hydroxyl group is also capable of reacting with water.
• the amount of process water available for reaction is magnitudes of order larger than the amount of hydroxyl groups available for reaction on the cellulose fibers.
• the majority of the known chemical additives will react with the process water rather than the hydroxyl groups available on the cellulose fibers.
• This problem can be reduced as demonstrated in the wet end application of sizing agents, such as ASA (alkyl succinic anhydride) and AKD (alkyl ketene dimer).
• ASA alkyl succinic anhydride
• AKD alkyl ketene dimer
• two or more chemical functionalities can be combined into a single molecule, such that the combined molecule imparts a unique product property to the final paper product that heretofore have been imparted through the use of two or more different molecules.
• the process used allows for chemical additives previously not capable of being retained in the wet end of the process to be retained via wet end addition.
• synthetic aldehyde functional polymers which are commonly used in the paper industry as temporary wet strength resins can be combined into a single molecule with functionalized aldehyde reactive paper modifying agents.
• the non-functionalized paper modifying agent equivalents are utilized in the paper industry as surface modifiers, release agents, antifoams, softeners, debonders and lubricants.
• the resulting molecule is a synthetic co-polymer having moieties capable of bonding to the cellulose fibers and paper modifying moieties which can provide several potential benefits, depending on the specific combination employed, including: strength aids that impart softness; softeners that do not reduce strength; wet strength with improved wet/dry strength ratio; surface feel modifiers with reduced linting and sloughing; strength aids with controlled absorbency; retention aids that soften; and, improved retention of the paper modifying agent when added as a wet end chemical additive.
• the synthetic aldehyde functional polymers as described herein, have a portion of their structure derived from the polymerization of ethylenically unsaturated compounds which contain pendant groups that can form hydrogen bonds, ionic bonds or covalent bonds with cellulose molecules in the cellulose fibers, thereby increasing interfiber bonding. At least a portion of said aldehyde functional polymer contains pendant aldehyde functionality. Such pendant aldehyde functionality may be present on the starting polymer or generated in-situ within the papermaking process.
• aldehyde functional polymer may include additional functional groups such as those found in materials such as polyacrylamide, polyvinyl alcohol, polyacrylic acid, polymaleic anhydride, polymaleic acid, polyitaconic acid, cationic polyacrylamides, anionic polyacrylamides, mixtures thereof, and the like.
• the synthetic aldehyde functional polymers as described herein may be water soluble, organic soluble or soluble in mixtures of water and water miscible organic compounds.
• the synthetic aldehyde functional polymers are water-soluble or water dispersible but this is not a necessity of the present invention.
• the salts of the above mentioned acidic polymers are included within the definition. Substances which can be combined with the acidic portion of the polymers to make the salts include the alkali metals such as Potassium and Sodium usually added to the synthetic aldehyde functional polymer in form of their hydroxides.
• the present invention resides in a synthetic co-polymer having moieties capable of bonding to the cellulose fibers and containing one or more moieties capable of modifying the paper sheet, said synthetic co-polymer having the following structure:
• Q 1 a monomer unit or a block or graft copolymer prepared from the polymerization of ethylenically unsaturated compounds, at least a portion of which contains a pendant group capable of forming hydrogen bonds with the cellulose fibers.
• the preferred pendant groups for hydrogen bonding are —CONH 2 , —COOH, —COO ⁇ M + , H, and mixtures of these groups.
• M+ may be any suitable counter ion including Na + , K + , Ca +2 , and the like;
• R 1 H and C 1-4 alkyl
• R 2 a hydrocarbon group containing a pendant aldehyde functionality. The hydrocarbon-maybe aromatic or aliphatic, saturated or unsaturated, linear or branched, and substituted or unsubstituted.
• R 2 may take the form of Z 4 -R 2′ -Z 3′ wherein Z 4 is any bridging radical whose purpose is to incorporate the aldehyde containing moiety into the polymer backbone; R 2′ is any hydrocarbon, aromatic or aliphatic, saturated or unsaturated, linear or branched, and substituted or unsubstituted; and, Z 3′ is the aldehyde functional group —CHO or —CH(OH) 2 .
• R 2 groups include but are not limited to: —CONHCHOHCHO and ——CONHCHOH(CH 2 ) 2 CHO;
• R 3 the aldehyde reactive paper modifying agent residue and may be an aliphatic hydrocarbon, a polysiloxane, an amphiphilic hydrocarbon, or a humectant.
• R 3 is an aliphatic compound, it will be a C 6 or higher aliphatic hydrocarbon, linear or branched, and substituted or unsubstituted;
• Z 2 the covalently bonded bridging radical formed by the reaction of an aldehyde functionality with a reactivity entity on the aldehyde reactive paper modifying agent
• Q 3 a monomer unit or a block or graft copolymer containing a charge functionality.
• charge functionality is preferably cationic but may be anionic or amphoteric.
• the present invention resides in a method of incorporating nonionic or poorly substantive materials into a paper sheet, such as a tissue sheet, comprising: (a) forming an aqueous suspension of cellulose papermaking fibers; (b) reacting, prior to web formation, a derivatized aldehyde reactive paper modifying agent and an aldehyde functional ionic polymer according to the following reaction:
• Q 1 a monomer unit or a block or graft copolymer prepared from the polymerization of ethylenically unsaturated compounds and containing a pendant group capable of forming hydrogen bonds with the cellulose fibers.
• the preferred pendant groups for hydrogen bonding are —CONH 2 , POOH, —COO ⁇ M + , —OH, and mixtures of these groups.
• M + may be any suitable counter ion including Na + , K + , Ca +2 , and the like;
• R 1 , R 1′ , R 1′′ are independently H and C 1-4 alkyl;
• R 2 a hydrocarbon group containing a pendant aldehyde functionality.
• the hydrocarbon may be aromatic or aliphatic, saturated or unsaturated, linear or branched, and substituted or unsubstituted.
• R 2 may take the form of Z 4 -R 2′ -Z 3′ wherein Z 4 is any bridging radical whose purpose is to incorporate the aldehyde containing moiety into the polymer backbone;
• R 2′ is any hydrocarbon, aromatic or aliphatic, saturated or unsaturated, linear or branched, and substituted or unsubstituted; and, Z 3′ is the aldehyde functional group —CHO or —CH(OH) 2 .
• suitable R 2 groups include but are not limited to: —CONHCHOHCHO and —CONHCHOH(CH 2 ) 2 CHO;
• R 3 the aldehyde reactive paper modifying agent residue and may be an aliphatic hydrocarbon, a polysiloxane, an amphiphilic hydrocarbon, or a humectant.
• R 3 is an aliphatic compound, it will be a C 6 or higher aliphatic hydrocarbon, linear or branched, and substituted or unsubstituted;
• Z 1 a reactive group capable of reacting with an aldehyde in an aqueous environment to form a covalent bond which is stable in the aqueous environment.
• the preferred groups include, but are not limited to, primary amines —NH 2 and secondary amines —NH—, amides —CONH 2 , thiols —SH, sulfinic acids —SO 2 OH, and sulfonamides —SO 2 NH 2 ;
• Z 2 the covalently bonded bridging radical formed by the reaction of the aldehyde functionality with Z 1 functional moiety
• Q 3 a monomer unit or a block or graft copolymer containing a charge functionality.
• Such charge functionality is preferably cationic but may be anionic or amphoteric.
• the present invention resides in a paper sheet, such as a tissue sheet, comprising a synthetic co-polymer derived from an aldehyde reactive paper modifying agent and an aldehyde functional ionic polymer, such synthetic co-polymer having hydrogen bonding capability and containing a paper modifying moiety, the synthetic co-polymer having the following structure:
• Q 1 a monomer unit or a block or graft copolymer prepared from the polymerization of ethylenically unsaturated compounds, a portion of which contains pendant group capable of forming hydrogen bonds with the cellulose fibers.
• the preferred pendant groups for hydrogen bonding are —CONH 2 , —COOH, —COO ⁇ M+, —OH, and mixtures of these groups.
• M + may be any suitable counter ion including Na + , K + , Ca +2 , and the like;
• R 1 , R 1′ , R 1′′ are independently H and C 1-4 alkyl
• R 2 a hydrocarbon group containing a pendant aldehyde functionality.
• the hydrocarbon may be aromatic or aliphatic, saturated or unsaturated, linear or branched, and substituted or unsubstituted.
• R 2 may take the form of Z 4 -R 2′ -Z 3′ wherein Z 4 is any bridging radical whose purpose is to incorporate the aldehyde containing moiety into the polymer backbone;
• R 2′ is any hydrocarbon, aromatic or aliphatic, saturated or unsaturated, linear or branched, and substituted or unsubstituted; and, Z 3′ is the aldehyde functional group —CHO or —CH(OH) 2 .
• R 2 groups include but are not limited to: —CONHCHOHCHO and —CONHCHOH(CH 2 ) 2 CHO;
• R 3 the aldehyde reactive paper modifying agent residue and may be an aliphatic hydrocarbon, a polysiloxane, an amphiphilic hydrocarbon, or a humectant.
• R 3 is an aliphatic compound, it will be a C 6 or higher aliphatic hydrocarbon, linear or branched, and substituted or unsubstituted;
• Z 2 the covalently bonded bridging radical formed by the reaction of the aldehyde functionality with Z 1 functional moiety
• Q 3 a monomer unit or a block or graft copolymer containing a charge functionality.
• charge functionality is preferably cationic but may be anionic or amphoteric.
• the cationic aldehyde functional polymer and the derivatized aldehyde reactive paper modifying agent may be reacted and applied to the cellulosic fiber substrate.
• the cationic aldehyde functional polymer and the derivatized aldehyde reactive paper modifying agent can be mixed directly together in a reaction vessel, allowed to react and then directly added to the pulp slurry.
• the cationic aldehyde functional polymer is added to the cellulose papermaking fibers and then the functionalized aldehyde reactive paper modifying agent is added to the papermaking slurry treated with the cationic aldehyde functional polymer.
• the functionalized paper modifying agent and the cationic aldehyde functional polymer then react on the surface of the cellulose fiber, the aldehyde functional polymer and the synthetic co-polymer being retained on the cellulose fibers via the cationic charge.
• the aldehyde functional polymer is added to the paper slurry of cellulose fibers; (2) a molar excess of the derivatized aldehyde reactive paper modifying agent is added to the paper slurry treated with aldehyde functional polymer; (3) the excess unreacted derivatized aldehyde reactive paper modifying agent is removed via belt press, filtration, or other technique; (4) the pulp is re-dispersed; and, (5) the cellulose fibers are then used to make the paper web via any of the methods known to those skilled in the art.
• the amount of the derivatized aldehyde reactive paper modifying agent that can be reacted with the aldehyde functional polymer is not overly critical to the present invention and is limited only by the equivalents of aldehyde and aldehyde reactive moieties present on the molecules. In general, from about 2% to about 100% of the available aldehyde groups will be reacted with the derivatized aldehyde reactive paper modifying agent, more specifically from about 5% to about 100%, and still more specifically from about 10% to about 100%.
• the resulting synthetic co-polymer still maintaining aldehyde functionality and therefore capable of providing wet strength to the paper or tissue web.
• the derivatized synthetic copolymer may be reacted with glyoxal or other suitable dialdehyde to provide a synthetic co-polymer having pendant aldehyde functionality and therefore capable of delivering wet strength to the paper or tissue web.
• the amount of the synthetic co-polymer added to the cellulose papermaking fibers can be from about 0.02 to about 4 weight percent, on a dry cellulose fiber basis, more specifically from about 0.05 to about 3 weight percent, and still more specifically from about 0.1 to about 2 weight percent.
• the modified vinyl synthetic co-polymer can be added to the cellulose fibers at any point in the process where the cellulose fibers are suspended in water.
• Suitable aldehyde functional polymers include the “glyoxylated” polyacrylamides, a class of charged polyacrylamides that has found widespread use in tissue and papermaking. Coscia, et al., U.S. Pat. No. 3,556,932 assigned to the American Cyanamid Company, describes the preparation and properties of glyoxylated polyacrylamides in detail. Examples of commercially available glyoxylated polyacrylamides are Parez 631 NC° manufactured and sold by Cytec, Inc. and Hercobond 1366® available from Hercules, Incorporated. These aldehyde functional polymers are ionic or nonionic water-soluble polyvinyl amides, having sufficient glyoxal substituents to be thermosetting.
• the amount of cationic component in the aldehyde functional polymers should be sufficient to render the aldehyde functional polymer substantive to the cellulose fibers in aqueous suspensions.
• the amount of cationic charge in these aldehyde functional polymers may vary. It may be less than about 10 mole percent or as high as about 50 mole percent. Indeed, many commercial versions are sold with a charge density of about 5 mole percent. Incorporation of the charge onto the aldehyde functional polymer backbone can be accomplished through any of the methods known in the art. However, one method is to incorporate a cationic vinyl monomer with the acrylamide or other vinyl monomers during the polymerization of the base aldehyde functional polymer.
• the specific monomer used to introduce the cationic charge onto the polyacrylamide is not overly critical and may be chosen from any such monomers known to be capable of incorporating a cationic charge into a polyacrylamide backbone.
• Dimethyldiallyl ammonium chloride is an especially preferred monomer for introducing the cationic charge.
• the cationic charge moiety may be absent from the aldehyde functional polymer backbone.
• the anionic versions of the aldehyde functional polymers may be easily prepared from the appropriate raw materials, these anionic aldehyde functional polymers capable of being deposited on the cellulose fibers with use of alum or various cationic retention aids.
• the minimum amount of pendant amide groups that need to be reacted with the glyoxal for the aldehyde functional polymer to be thermosetting is about two mole percent of the total number of available amide groups. It is usually preferred to have an even higher degree of reaction so as to promote greater wet strength development, although above a certain level additional glyoxal provides only minimal wet strength improvement.
• the optimal ratio of glyoxylated to non-glyoxylated acrylamide groups is estimated to be from about 10 to about 20 mole percent of the total number of amide reactive groups available on the parent aldehyde functional polymer. For the purposes of the present invention, higher levels of glyoxylation may be preferred.
• the reaction can be easily carried out in dilute solution by stirring the glyoxal with the polyacrylamide base polymer at temperatures of from about 25° C. to about 100° C. at a neutral or slightly alkaline pH. Generally, the reaction is run until a slight increase in viscosity is noted. The majority of the glyoxal reacts at only one of its functionalities yielding the desired aldehyde functional acrylamide. It should also be noted that the reaction is not limited to glyoxal but may be accomplished with any water-soluble dialdehyde including glutaraldehyde.
• the molecular weight of the acrylamide base aldehyde functional polymer is not overly critical to the ability to react with glyoxal, and, generally aldehyde functional polymers of molecular weight less than two million are adequately water soluble and dilutable so as not to not severely hinder reaction capability.
• lower molecular weight aldehyde functional polymers having a molecular weight less than about 250,000 are generally preferred due to their lower solution viscosity, and the ease at which they can be diluted in water.
• the molecular weight and the degree of glyoxylation of the aldehyde functional polymer can have an impact on level of wet strength development and ability to disperse readily in water.
• a structure for a typical cationic glyoxylated polyacrylamide is shown in the structure below.
• the synthetic co-polymer is retained on the cellulose fiber by means of the cationic quaternary amine group that is attracted to anionic sites on the cellulose fibers.
• the amide and aldehyde functionalities are reactive. From about 2 mole % to about 30 mole % of the entire glyoxylated PAM co-polymer exists as the active aldehyde group.
• the pendant amide groups on the synthetic co-polymer form hydrogen bonds with the cellulose fibers increasing the dry strength of the sheet.
• the aldehyde group can either cross-link with an amide group in another part of the synthetic co-polymer or react with a hydroxyl group on the cellulose fibers.
• the aldehyde links with the amide, a permanent covalent cross-link is formed which increases permanent wet strength. If the aldehyde forms a covalent hemi-acetal bond to the cellulose fibers, wet strength is also increased. However, this bond is not permanent and will break when immersed in water resulting in temporary instead of permanent wet strength. Hence, the glyoxylated polyacrylamides are normally used to increase dry strength and temporary wet strength, such as is desired for bath tissue.
• the glyoxylated polyacrylamides have many beneficial properties.
• the glyoxylated polyacrylamides increase both the wet and dry strength of the paper. Though slightly acidic conditions are preferred, the glyoxylated polyacrylamides thermoset or “cure” at pHs in the range of from about 4 to about 8 and moderately elevated temperatures that are common to most papermaking systems. Since the glyoxylated polyacrylamide can be cured over a broad pH range including neutral pH, precise control of pH is not required in the papermaking system. The polymers develop the large majority of their wet and dry strength while passing through the drying section of the paper process with sheet temperatures as low as 70° F. to 90° F. being adequate.
• glyoxylated polyacrylamides possess what is referred to as “temporary wet strength”. A portion of the wet strength developed within the paper web is lost when soaked in water for a moderate period of time. This feature allows use of these materials in products, such as bath tissue, where water break-up is a required product attribute. In addition, all of the wet strength can be lost rapidly under alkaline conditions. This makes these materials very amenable to broke repulping operations not requiring additional chemical additives or processes which add to overall paper manufacturing costs.
• repulpable wet strength resins can be prepared from a polycarboxylic acid or ester, a polyamine and a dialdehyde, and an epichlorohydrin.
• the resulting imine functional groups provide easier repulp characteristics relative to typical azetidinium crosslinks.
• water soluble polyols in conjunction with glyoxylated PAMs as Yankee dryer adhesive coatings.
• a known method for imparting synergistic strength to paper is through the use of a aminopolyamide epichlorohydrin resin and a glyoxylated PAM resin in conjunction with or without a high charge density cationic polymer.
• the aldehyde group is a common carbonyl group that is rather reactive and used for many chemical syntheses.
• the aldehyde group can be easily oxidized to a carboxylic acid with a strong acid or reduced to an acetal with alcohols.
• the aldehydes can react with various forms of nitrogen (amines, cyanohydrins, amides, etc.) to form carbon-nitrogen bonds that are stable even in the presence of water. Amines, because of their non-bonding pair of electrons, are quite nucleophilic. Aldehydes and amines will react rapidly with each other even in aqueous environments.
• An imine, aminal, or hemi-aminal can be formed from the reaction of an aldehyde and a primary amine. Secondary amines will also react with aliphatic aldehydes but not aromatic aldehydes. This reaction is not limited to nitrogen containing compounds.
• Functional groups which can react with aldehydes in aqueous systems at near neutral pH to form covalent bonds include primary amines (—NH 2 ), secondary amines (—NHR 2 ), thiols (—SH), amides (—CONH 2 ), sulfonamides (—OSO 2 NH 2 ), and sulfinic acids (—SO 2 OH).
• Amines are particularly attractive for reaction with aldehydes due to their ease of preparation and ready availability. As discussed above, aldehydes and amines will react readily with each other, even in aqueous environments. An imine, aminal, or hemi-aminal can be formed from the reaction of an aldehyde and a primary amine (shown below). Secondary amines will also react with aliphatic aldehydes but not aromatic aldehydes. Secondary amines can not form imines with aldehydes but can form enamines.
• the amine functional groups are more nucleophillic in character. Therefore the amine functional groups will react faster and preferentially to the hydroxyl functional groups on the cellulose fiber and the process water. This affinity exhibited by the amine functional groups can be utilized in the reaction between an aldehyde functional polymer such as a glyoxylated polyacrylamide and the added amine.
• an aldehyde functional polymer such as a glyoxylated polyacrylamide
• the aldehyde functional polymer and amine or other functionalized aldehyde reactive paper modifying agent are mixed, the amine or other aldehyde reactive functional group reacts with the active site of aldehyde functional polymer, namely the aldehyde functional group site.
• the aldehyde functional group site is effectively destroyed, but the dry strength and product modifying traits provided by the reactants, the PAM aldehyde and the functionalized aldehyde reactive paper modifying agent, are maintained.
• the degree of wet strength loss will be dependent on the number of aldehyde groups reacted with amine functional compound. It is not necessary that all the aldehyde groups react with the amine or other functionalized aldehyde reactive paper-modifying agent. In fact, there are benefits to only reacting a portion of the said aldehyde groups.
• the unreacted aldehyde groups are available for bonding to the cellulose fibers or to pendant amide groups thereby increasing the wet or temporary wet strength of the tissue web.
• the paper modifying moieties of the present invention can be grouped into three basic categories: 1) aliphatic hydrocarbons; 2) polysiloxanes; and, 3) amphiphilic hydrocarbons including polyhydroxy and polyether derivatives and humectants.
• a traditional method of softening tissue is to add a quaternary ammonium compound containing a long chain, C 12 or higher, aliphatic hydrocarbon to the fibers in the wet end of the process.
• the long chain aliphatic hydrocarbons reduce fiber to fiber bonding and the resultant loss in tensile strength causes improved softness. It is also known to add these materials topically to a sheet so as to improve surface feel.
• the aliphatic hydrocarbons are derived from oleic or stearic acid.
• the functional derivatives of these compounds, including the amines, amides, thiols, and sulfinic acids are well known and commercially available.
• An example of a commercially available amine functional aldehyde reactive paper modifying agent suited for the present invention are the so called amido amines containing unreacted secondary amine groups. These materials are generally synthesized by the reaction of a compound containing a primary and a secondary amine with an acid or acid derivative of a long chain aliphatic hydrocarbon. The higher reactivity of the primary amine relative to the secondary amine allows for selective amidization of the primary amine. The reactions below are two known examples of such reactions.
• R C 6 or higher linear or branched, substituted or unsubstituted, saturated or unsaturated hydrocarbon.
• these materials will be delivered as aqueous emulsions or as solutions in appropriate polar protic or polar aprotic solvents such as propylene glycol, polyethylene glycol, isopropanol, acetone, and the like.
• the reaction with the glyoxylated polyacrylamide can be carried out directly by adding the amido amine solution to the aqueous solution of aldehyde functional polymer.
• suitable commercially available amido amines are those sold under the trade name Reactopaque® 100, 102 and 115 manufactured by Sequa Chemical Company, Chester, S.C., which are sold as aqueous emulsions.
• R 1 and R 2 are integers>0.
• R 1 and R 2 is a functional group capable of reacting with the aldehyde functionality in an aqueous environment.
• Suitable R 1 and R 2 groups include but are not limited to primary amines —NH 2 and secondary amines —NH—, amides —CONH 2 , thiols —SH, sulfinic acids —O 2 OH, and sulfonamides —SO 2 NH 2 .
• R 3 to R 10 moieties may be independently any organofunctional group including C 1 or higher alkyl groups, ethers, polyethers, polyesters, amines, imines, amides, or other functional groups including the alkyl and alkenyl analogues of such groups and including blends of such groups.
• a particularly useful moiety is a polyether functional group having the generic formula:
• R 12 —(R 13 O) a —(R 14 O) b —R 5 wherein R 12 , R 13 , and R 14 are independently C 1-4 alkyl groups, linear or branched; R 15 can be H or a C 1-30 alkyl group; and, “a” and “b” are integers of from about 1 to about 100, more specifically from about 5 to about 30.
• x and y are integers>0.
• the mole ratio of x to (x+y) can be from about 0.005 percent to about 25 percent.
• the R 1 -R 9 moieties may be independently any organofunctional group including C 1 or higher alkyl groups, ethers, polyethers, polyesters, amines, imines, amides, or other functional groups including the alkyl and alkenyl analogues of such groups.
• a particularly useful moiety is a polyether functional group having the generic formula: —R 12 —(R 13 —O) a —(R 14 O) b —R 15 , wherein R 12 , R 13 , and R 14 are independently C 1-4 alkyl groups, linear or branched; R 15 can be H or a C 1-30 alkyl group; and, “a” and “b” are integers of from about 1 to about 100, more specifically from about 5 to about 30.
• the R 10 moiety can include any group capable of reacting with aldehyde groups in an aqueous environment to form covalent bonds.
• the preferred groups include but are not limited to primary amine, secondary amine, thiol, and unsubstituted amides.
• the silicone polymers will normally be delivered as aqueous dispersions or emulsions, including microemulsions, stabilized by suitable surfactant systems that may confer a charge to the emulsion micelles.
• suitable surfactant systems that may confer a charge to the emulsion micelles.
• Nonionic, cationic, and anionic systems may be employed as long as the charge of the surfactant used to stabilize the emulsion does not prevent deposition of the synthetic co-polymer onto the surface of the cellulose fibers or interfere with the reaction between the two polymers.
• Plasticization in cellulose structures primarily through use of humectants including the polyethylene oxide and polypropylene oxide polymers as well as their lower molecular weight homologues such as propylene glycol, glycerin, glycerol, and polyethylene glycols of low molecular weights has been described in the literature. The majority of these materials are either low molecular weight polyhydroxy compounds or polyethers and derivatives. They are nonionic, and have no charge. The hydrophilic end often contains a polyether (polyoxyethylene) or one or more hydroxyl groups.
• the applications of such treatments include coating a tissue sheet with a carboxylic acid derivative and a water-soluble humectant polyether blend to create a virucidal tissue product. It is also known to spray or coat the sheet with non-cationic low molecular weight polyethers and glycols, to increase softness in combination with another “binder” to counteract the decreased strength of the treated tissue product. It is also known to apply a polyhydroxy compound and an oil to a tissue sheet just after the tissue sheet has been dried on a Yankee or drum dryer but before the creping step is completed to increase the softness of the tissue sheet. A starch or synthetic resin may also be applied as to increase strength to the treated tissue sheet.
• humectant polyether or glycol additives in the wet-end has been limited to use of these materials as co-solvents for various cationic softening compositions. These materials aid in the deposition of the softening agent on the cellulose fibers but do not play a direct role in affecting the properties of the tissue sheet. The absence of charge on these additives prevents the additives from binding or otherwise bonding to the cellulose fibers. In fact, it is well known that the addition of such additives in the wet-end of the paper or tissue making process is discouraged because of the resulting low retention, and therefore poor softening benefits, of these additives.
• Low molecular weight polyhydroxy compounds containing functional groups capable of reacting with aldehydes are well known commercially available materials.
• suitable materials include but are not limited to 2-(2-aminoethoxy)ethanol, 3-amino-1,2-propanediol, tris(hydroxymethyl) aminomethane, diethanol amine, 1-amino-1-deoxy-D-sorbitol (glucamine), 2-aminoethyl hydrogen sulfate, 2-amino-2-ethyl-1,3-propanediol, 2-amino-1 phenyl-1,3-propanediol, 2-amino-1,3-propanediol, 3-amino-1-propanol, ethanolamine, 3-amino-2-hydroxy propionic acid, 1-amino-2,3,4-trihydroxybutane, 4-amino-2-hydroxybutyric acid, aspartic acid, 2-amino-2-methyl-1,3-propaned
• amino and mercapto functional polyethers are well known compositions that may be prepared by the reductive amination of polyalkyleneoxy alcohols using hydrogen and ammonia in the presence of a catalyst. This reductive amination of polyols is described in U.S. Pat. Nos. 3,128,311; 3,152,998; 3,236,895; 3,347,926; 3,654,370; 4,014,933; 4,153,581; and, 4,766,245.
• the molecular weight of the polyalkyleneoxy amine material, when employed is preferably in the range of from about 100 to about 4,000.
• amine containing polymers having carbon-oxygen backbone linkages and their uses are described in U.S. Pat. Nos. 3,436,359; 3,155,728; and, 4,521,490.
• suitable commercially available polyalkyleneoxy amines are materials sold under the trade name Jeffamine® manufactured by Huntsman Chemical Corporation.
• Additional derivatives of the polyethers are known including the thiols. They can be obtained via different means including reaction of the corresponding polyoxyalkylene glycol with thionyl chloride to give the corresponding chloro derivative, followed by reaction with thiourea and hydrolysis of the product to give the desired thiol derivative. Examples of the synthesis of thiol derivatives via this process can be found in U.S. Pat. No. 5,143,999. Reactions of alcohols to give thiols is described in a variety of texts such as Organic Synthesis, Collective Volume 4, pp. 401-403, 1963. Dithiols and mono thiols can be obtained via the reaction depending on the nature of the starting polyether.
• the starting polyoxyalkylene derivatives can be a polyethylene, polypropylene, polybutylene, or other appropriate polyether derivative as well as copolymers having mixtures of the various polyether components. Such copolymers can be block or random.
• the molar and weight ratios of the various functional groups on the aldehyde functional polymer will largely depend on the specific application of the material and is not a critical aspect of the present invention.
• the portion of the aldehyde functional polymer [Q 1 ] capable of forming hydrogen bonds can constitute from about 0 to about 80 mole percent of the total polymer, more specifically from about 5 to about 75 mole percent of the total polymer, and still more specifically from about 10 to about 70 mole percent of the total polymer.
• the portion of the aldehyde functional polymer containing aldehyde groups can constitute from about 2 to about 80 mole percent of the total polymer, more specifically from about 5 to about 70 mole percent, and still more specifically from about 10 to about 60 mole percent of the total polymer.
• the charge containing portion [Q 3 ] of the aldehyde functional polymer may be comprised of monomer units constituting from 0 to about 80 mole percent of the total monomer units in the polymer, more specifically from 0 to about 30 mole percent, and still more specifically from about 2 to about 20 mole percent.
• the molecular weight of the aldehyde functional polymers of the present invention will largely depend on the specific application of the material and is not overly critical to the present invention.
• the weight average molecular weight range can be from about 500 to about 5,000,000, more specifically from about 1,000 to about 2,000,000, and still more specifically from about 2,000 to about 1,000,000.
• these aldehyde functional polymers are added for dry strength, it is important that the molecular weight of the aldehyde functional polymer be low enough so as to not bridge between particles and cause flocculation, and yet high enough so as to retard migration of the aldehyde functional polymer into the pores of the cellulose fibers.
• These materials can have weight average molecular weights in the range of from about 2,000 to about 2,000,000, more specifically from about 5,000 to about 1,500,000, and still more specifically from about 10,000 to about 1,000,000.
• the molecular weight of the product synthetic co-polymer will depend upon the molecular weight of the aldehyde reactive paper modifying agent, the degree to which the aldehyde groups are reacted and the molecular weight of the starting aldehyde functional polymer.
• the weight average molecular weight range can be from about 750 to about 6,000,000, more specifically from about 2,000 to about 4,000,000, and still more specifically from about 5,000 to about 3,000,000.
• these synthetic co-polymers are added for dry strength, it is important that the molecular weight of the synthetic co-polymer be low enough so as to not bridge between particles and cause flocculation, and yet high enough so as to retard migration of the synthetic co-polymer into the pores of the cellulose fibers.
• These materials can have weight average molecular weights in the range of from about 3,000 to about 3,000,000, more specifically from about 5,000 to about 2,000,000 and still more specifically from about 20,000 to about 1,500,000.
• the amount of derivatized aldehyde reactive paper modifying agent that can be reacted with the aldehyde functional polymer is not overly critical to the present invention and is limited only by the equivalents of aldehyde and amine groups. In general, from about 2 to about 100% of the available aldehyde groups will be reacted with the derivatized paper modifying agent, more specifically from about 5% to about 100%, and still more specifically from about 10% to about 100%. In some cases it is advantageous to only react a portion of the aldehyde groups with the derivatized aldehyde reactive paper modifying agent, the resulting synthetic co-polymer still maintaining aldehyde functionality and therefore capable of providing wet strength to the paper or tissue web.
• the derivatized aldehyde functional polymer may be reacted with glyoxal or other suitable dialdehyde to give a synthetic co-polymer having pendant aldehyde functionality and therefore capable of delivering wet strength to the paper or tissue web.
• the pH of the reaction mixture can be anticipated to have an impact on the extent and rate of reaction. Addition of hydrogen ion to the carbonyl group is known to facilitate nucleophilic addition to carbonyl compounds. On the other hand, if amines are used as the aldehyde reactive species, the nucleophilicity of the amine will be reduced by protonation of the basic amine group. Hence, it is desirable to select an adequate pH condition to promote the protonation of the carbonyl yet minimizing protonation of the basic amine.
• a pH of from about 3 to about 11 is adequate for the reaction. In another embodiment, a pH of from about 4 to about 10 is adequate for the reaction. In another embodiment, a pH of from about 5 to about 9 is adequate for the reaction.
• Heat may also be applied to help drive the reaction, however, where glyoxylated polyacrylamides are used it is important to choose a temperature sufficiently low so as to minimize reaction of the pendant amide groups with the aldehyde groups. Extensive crosslinking can lead to gel formation and insolubility reducing the effectiveness of the polymer.
• the basis weight and bone dry basis weight of the specimens was determined using a modified TAPPI T402 procedure. As is basis weight samples are conditioned at 23° C. ⁇ 1° C. and 50% ⁇ 2% relative humidity for a minimum of 4 hours. After conditioning, the handsheet specimen stack is cut to 7.5′′ ⁇ 7.5′′ sample size. The number of handsheets in the stack (represented as X) may vary but should contain a minimum of 5 handsheets. The specimen stack is then weighed to the nearest 0.001 gram on a tared analytical balance and the stack weight (represented as W) recorded. The basis weight in grams per square meter is then calculated using the following equation:
• the bone-dry basis weight is obtained by weighing a sample can and sample can lid the nearest 0.001 grams (this weight is represented as A).
• the sample stack is placed into the can and left uncovered.
• the uncovered sample can and stack along with sample can lid is placed in a 105° C. ⁇ 2° C. oven for a period of 1 hour ⁇ 5 minutes for sample stacks weighing less than 10 grams and at least 8 hours for sample stacks weighing 10 grams or greater.
• the sample can lid is placed on the sample can and the can removed from the oven.
• the sample cans are allowed to cool to approximately ambient temperature but no more than 10 minutes.
• the sample can, sample can lid, and specimen are then weighed to the nearest 0.001 gram (this weight is represented as C).
• the bone-dry basis weight in g/m 2 is calculated using the following equation:
• Bone Dry BW ( g/m 2 ) [( C ⁇ A )/ X] ⁇ 27.56
• Breaking length ( km ) [Peak Load in g/in ⁇ 0.039937] ⁇ Actual basis wt. in g/m 2
• the peak load tensile is defined as the maximum load, in grams, achieved before the specimen fails. It is expressed as grams-force per inch of sample width. All testing is done under laboratory conditions of 23.0+/ ⁇ 1.0° C., 50.0+/ ⁇ 2.0% relative humidity, and after the sheet has equilibrated to the testing conditions for a period of not less than four hours. The testing is done on a tensile testing machine maintaining a constant rate of elongation, and the width of each specimen tested was 1 inch. The specimen were cut into strips having a 1 ⁇ 0.4 inch width using a precision cutter. The “jaw span” or the distance between the jaws, sometimes referred to as gauge length, is 5.0 inches.
• the crosshead speed is 0.5 inches per minute (12.5 mm/min.)
• a load cell or full scale load is chosen so that all peak load results fall between about 20 and about 80 percent of the full scale load.
• Suitable tensile testing machines include those such as the Sintech QAD IMAP integrated testing system. This data system records at least 20 load and elongation points per second.
• distilled water is poured into a container to a depth of approximately 1 ⁇ 2 to 3 ⁇ 4 of an inch.
• An open loop was formed by holding each end of a test specimen and carefully lowering the specimen until the lowermost curve of the loop touches the surface of the water without allowing the inner side of the loop to come together.
• the lowermost point of the curve on the handsheet is contacted with the surface of the distilled water in such a way that the wetted area on the inside of the loop extends at least 1 inch and not more than 1.5 inches lengthwise on the specimen and is uniform across the width of the specimen. Care was taken to not wet each specimen more than once or allow the opposite sides of the loop to touch each other or the sides of the container.
• test specimen Excess water was removed from the test specimen by lightly touching the wetted area to a blotter. Each specimen was blotted only once. Each specimen is then immediately inserted into the tensile tester so that the jaws are clamped to the dry area of the test specimen with the wet area approximately midway between the span. The test specimen are tested under the same instrument conditions and using same calculations as for Dry Tensile Strength measurements.
• Polydimethyl siloxane content on cellulose fiber substrates was determined using the following procedure. A sample containing dimethyl siloxane is placed in a headspace vial, boron trifluoride reagent is added, and the vial sealed. After reacting for fifteen minutes at 100° C. the resulting Diflourodimethyl siloxane in the headspace of the vial is measured by gas chromatography with an FID detector.
• the gas chromatograph was equipped with a Hewlett-Packard headspace autosampler, HP-7964 and set up at the following conditions: Bath Temperature: 100° C. Loop Temperature: 110° C. Transfer Line Temperature: 120° C. GC Cycle Time: 25 minutes Vial Equilibrium Time: 15 minutes Pressurize Time: 0.2 minutes Loop Fill Time: 0.2 minutes Loop Equil. Time: 0.05 minutes Inject Time: 1.0 minute Vial Shake: 1 (Low)
• Carrier gas Helium
• Chromatography Conditions 50° C. for 4 minutes with a ramp of 10° C./minute to 150° C. Hold at final temperature for 5 minutes.
• a stock solution containing approximately 5000 ⁇ g/ml polydimethyl siloxane was prepared in the following manner. Approximately 1.25 grams of the Polydimethylsiloxane emulsion is weighed to the nearest 0.1 mg into a 250-ml volumetric flask. The actual weight (represented as X) is recorded. Distilled water is added and the flask swirled to dissolve/disperse the emulsion. When dissolved/dispersed the solution is diluted to volume with water and mixed. The ppm of the polysiloxane emulsion (represented as Y) is calculated from the following equation:
• the Calibration Standards are made to bracket the target concentration by adding 0 (blank), 50, 100, 250, and 500 ⁇ L of the Stock Solution (the volume in uL V c is recorded) to successive 20 mL headspace vials containing 0.1 ⁇ 0.001 grams of an untreated control tissue.
• the solvent is evaporated by placing the headspace vials in an oven at a temperature ranging between about 60° C. to about 70° C. for 15 minutes.
• the ⁇ g of emulsion (represented as Z) for each calibration standard is calculated from the following equation:
• the sealed vials are placed in the headspace autosampler and analyzed using the conditions described previously, injecting 1 mL of the headspace gas from each sample and standard.
• a calibration curve of ⁇ g emulsion versus analyte peak area is prepared.
• the analyte peak area of the sample is then compared to the calibration curve and amount of polydimethylsiloxane emulsion (represented as (A)) in ⁇ g on the tissue determined.
• the amount of the polydimethylsiloxane (represented as (D)) in percent by weight on the tissue sample is computed using the following equation and the weight % polysiloxane (represented as (F)) in the emulsion:
• Example 1 The same procedure as that of Example 1 was followed except that 0.66 grams of tris(hydroxymethyl)aminomethane was used as the amine compound and was added over a period of 57 minutes to the glyoxylated PAM.
• Example 4 illustrates the use of a polyhydroxy secondary amine. The same procedure as that of Example 1 was followed except that 0.56 grams of diethanol amine was used as the amine compound and was added over a period of 50 minutes to the glyoxylated PAM.
• Example 2 The same procedure as that of Example 1 was followed except that 3.28 grams of a commercially available amino functional polyether, Jeffamine M-600 from Hunstman Chemical was used as the amine. The amine was added to the stirred solution of glyoxylated polyacrylamide over a 90 minute period of time. A slightly hazy solution was obtained.
• a commercially available amino functional polyether Jeffamine M-600 from Hunstman Chemical
• Example 5 The same procedure as that of Example 5 was followed except that 5.48 grams of a commercially available amino functional polyether, Jeffamine M-1003 also named XTJ-506, molecular weight around 1,000 from Huntsman Chemical was used as the amine. The amine was added to the stirred solution of glyoxylated polyacrylamide over a 61 minute period of time. A slightly hazy solution was obtained.
• a commercially available amino functional polyether Jeffamine M-1003 also named XTJ-506, molecular weight around 1,000 from Huntsman Chemical was used as the amine.
• the amine was added to the stirred solution of glyoxylated polyacrylamide over a 61 minute period of time. A slightly hazy solution was obtained.
• Example 5 The same procedure as that of Example 5 was followed except that 11.34 grams of a commercially available amino functional polyether, Jeffamine M-2070, from Hunstman Chemical was used as the amine. The amine was added to the stirred solution of glyoxylated polyacrylamide over a 145 minute period of time. A hazy solution was obtained.
• a commercially available amino functional polyether Jeffamine M-2070, from Hunstman Chemical
• Examples 8-16 illustrate preparation of handsheets with the chemicals of Examples 1-7.
• the method for handsheet preparation was as follows:
• Table 1 and 2 give dry tensile strength and wet tensile strength data for the handsheets made with the various co-polymers and also shows the change in dry tensile strength relative to the control sample made with Parez® 631 NC.
• Example 9 all handsheets show equivalent to slightly higher dry tensile strength than the control made with Parez®631 NC and significantly higher dry tensile strength than Example 16 made with no chemical.
• Example 11 all show a marked decrease in wet strength relative to the glyoxylated polyacrylamide control. This would be an expected result were the aldehyde group to have reacted with the amine.
• Example 2 Destruction of the glyoxal group leads to a loss in wet strength, yet the pendant amide groups are available for increasing dry strength.
• the behavior seen in Example 2 can be explained due to the precipitation of the co-polymer. Precipitation of the co-polymer would lead to poor retention and a behavior similar to the control with no chemical should be noted.
• humectant materials into a paper sheet such as a tissue sheet would be decreased stiffness.
• a key element to softness in tissue products is the stiffness of the sheet.
• An inverse correlation exists between softness and stiffness.
• a direct linear correlation exists between tensile strength of a sheet and its bending stiffness.
• Kawabata bending stiffness provides a good analytical tool for measuring the stiffness of a paper sheet.
• Kawabata Pure Bending
• Kawabata S., “The Standardization and Analysis of Hand Evaluation”, The Textile Machinery Society of Japan, July 1980, 2nd Ed., Osaka, Japan.
• the sample specimen is mounted through a moving front chuck and then through a fixed rear chuck spaced 1 cm apart.
• the sample is installed so that the test direction is at right angles to chucks. Where MD and CD directions are tested the MD direction is tested first.
• the sample must be straight, flat and even, with no puckers or air pockets taking care not to allow the sample to protrude through the back chuck.
• the fixed end of the specimen is on a rod which is also supported by wires at both ends.
• the bending moment induced by the bending deformation is detected by a torque meter and the curvature is detected by measuring the rotation angle of the crank.
• a torque sensitivity of 2 ⁇ 1 and a full scale momentum of 20 gf/cm is used for tissue and handsheet analysis.
• the slope of the curve of bending moment vs. curvature is the bending stiffness (represented as B) per unit width given in units of gf-cm/cm. Where gf-cm is grams force centimeters, with one Newton-meter of force being equivalent to 9.807 ⁇ 10 ⁇ 5 gf-cm.
• the standard sample width is 20 cm, however, any sample width may be used provided a size factor is used to convert results to a 20 cm value.
• a sample width of 18.0 cm was used with a size factor of 1.1.
• Size Factor 20 ⁇ sample width in centimeters
• the pure bending stiffness results obtained from the handsheets of Examples 816 are shown in Table 3. Graphically the results are shown in Table 5.
• the slope is defined as the difference between the bending stiffness of the sample and the bending stiffness of the untreated cellulosic sheet divided by the difference between the breaking length of the sample sheet and the breaking length of the untreated cellulosic sheet.
• a lower slope is preferred and indicates a less stiff sheet at a given tensile strength.
• M-2070 Example 15
• all handsheets made with the polymers of the present invention exhibit lower stiffness at a given tensile strength than when only an unmodified glyoxylated polyacrylamide is used.
• Examples 17-20 demonstrate the use of a glyoxylated polyacrylamide in conjunction with an amino functional polysiloxane to enhance the retention of the polysiloxane material. It should be noted from these examples that even small levels of the glyoxylated polymer can significantly enhance the retention of the aldehyde reactive paper-modifying agent. In this case the amino functional polysiloxane was delivered in the form of a cationic microemulsion.
• a single ply, two-layered, uncreped through air dried tissue basesheet was made generally in accordance with U.S. Pat. No. 5,607,551 issued Mar. 4, 1997 to Farrington et al. entitled “Soft Tissue”, which is herein incorporated by reference. More specifically, 65 pounds (oven dry basis) of eucalyptus hardwood Kraft fiber were dispersed in a pulper for 25 minutes at a consistency of 3% before being transferred to a machine chest and diluted to a consistency of 1%. 40 pounds (oven dry basis) of northern softwood kraft fiber were dispersed in a pulper for 25 minutes at a consistency of 3 percent before being transferred to a second machine chest and diluted to 1% consistency.
• each stock Prior to forming each stock was further diluted to approximately 0.1 percent consistency and transferred to a 2-layer headbox in such a manner as to provide a layered sheet comprising 65% Eucalyptus and 35% NSWK.
• the formed web was non-compressively dewatered and rush transferred to a transfer fabric traveling at a speed about 25 percent slower than the forming fabric.
• the web was then transferred to a throughdrying fabric, dried and calendered.
• the total basis weight of the resulting sheet was 18.5 pounds per 2880 ft 2 .
• the amount of polysiloxane in the total basesheet was found to be 0.18% corresponding to a retention of 38%.
• a single ply, two-layered, uncreped throughdried tissue basesheet was made generally in accordance with U.S. Pat. No. 5,607,551 issued Mar. 4, 1997 to Farrington et al. entitled “Soft Tissue”, which is herein incorporated by reference. More specifically, 65 pounds (oven dry basis) of eucalyptus hardwood Kraft fiber were dispersed in a pulper for 25 minutes at a consistency of 3% before being transferred to a machine chest and diluted to a consistency of 1%. 40 pounds (oven dry basis) of northern softwood kraft fiber were dispersed in a pulper for 25 minutes at a consistency of 3 percent before being transferred to a second machine chest and diluted to 1% consistency.
• the formed web was non-compressively dewatered and rush transferred to a transfer fabric traveling at a speed about 25 percent slower than the forming fabric.
• the web was then transferred to a throughdrying fabric, dried and calendered.
• the total basis weight of the resulting sheet was 18.5 pounds per 2880 ft 2 .
• the amount of polysiloxane in the total basesheet was found to be 0.30% corresponding to a retention of 62%.
• a single ply, two-layered, uncreped throughdried tissue basesheet was made generally in accordance with U.S. Pat. No. 5,607,551 issued Mar. 4, 1997 to Farrington et al. entitled “Soft Tissue”, which is herein incorporated by reference. More specifically, 65 pounds (oven dry basis) of eucalyptus hardwood Kraft fiber was dispersed in a pulper for 25 minutes at a consistency of 3% before being transferred to a machine chest and diluted to a consistency of 1%. 40 pounds (oven dry basis) of northern softwood kraft fiber were dispersed in a pulper for 25 minutes at a consistency of 3 percent before being transferred to a second machine chest and diluted to 1% consistency.
• each stock Prior to forming each stock was further diluted to approximately 0.1 percent consistency and transferred to a 2-layer headbox in such a manner as to provide a layered sheet comprising 65% Eucalyptus and 35% NSWK.
• the formed web was non-compressively dewatered and rush transferred to a transfer fabric traveling at a speed about 25 percent slower than the forming fabric.
• the web was then transferred to a throughdrying fabric, dried and calendered.
• the total basis weight of the resulting sheet was 18.5 pounds per 2880 ft 2 .
• the amount of polysiloxane in the total basesheet was found to be 0.16% corresponding to a retention of 16%.
• a single ply, two-layered, uncreped throughdried tissue basesheet was made generally in accordance with U.S. Pat. No. 5,607,551 issued Mar. 4, 1997 to Farrington et al. entitled “Soft Tissue”, which is herein incorporated by reference. More specifically, 65 pounds (oven dry basis) of eucalyptus hardwood Kraft fiber was dispersed in a pulper for 25 minutes at a consistency of 3% before being transferred to a machine chest and diluted to a consistency of 1%. 40 pounds (oven dry basis) of northern softwood kraft fiber were dispersed in a pulper for 25 minutes at a consistency of 3 percent before being transferred to a second machine chest and diluted to 1% consistency.
• the formed web was non-compressively dewatered and rush transferred to a transfer fabric traveling at a speed about 25 percent slower than the forming fabric.
• the web was then transferred to a throughdrying fabric, dried and calendered.
• the total basis weight of the resulting sheet was 18.5 pounds per 2880 ft 2 .
• the amount of polysiloxane in the total basesheet was found to be 0.39% corresponding to a retention of 40%.

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