US1944273A - Lubricating compound - Google Patents

Lubricating compound Download PDF

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Publication number
US1944273A
US1944273A US369006A US36900629A US1944273A US 1944273 A US1944273 A US 1944273A US 369006 A US369006 A US 369006A US 36900629 A US36900629 A US 36900629A US 1944273 A US1944273 A US 1944273A
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United States
Prior art keywords
lubricating
compound
wire
tallow
compounds
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US369006A
Inventor
Rutherford George Stanley
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AT&T Corp
Original Assignee
Western Electric Co Inc
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Publication date
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Priority to US369006A priority Critical patent/US1944273A/en
Application granted granted Critical
Publication of US1944273A publication Critical patent/US1944273A/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • C10M2201/042Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • C10M2207/404Fatty vegetable or animal oils obtained from genetically modified species
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12Polysaccharides, e.g. cellulose, biopolymers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/241Manufacturing joint-less pipes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/242Hot working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/243Cold working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/245Soft metals, e.g. aluminum
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/246Iron or steel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/247Stainless steel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01Emulsions, colloids, or micelles

Definitions

  • the invention relates to lubricating compounds and method of making such compounds, and.
  • Lubricating compounds for wire drawing machines particularly machines designed for drawing wire at high speed or metal processing machines in general, have in many instances consisted principally of a lubricant, such as tallow, lard oil, fish oil, or vegetable oils mixed with soap and water, the soap acting as a flotation agent for the tallow or oil.
  • a lubricant such as tallow, lard oil, fish oil, or vegetable oils mixed with soap and water
  • the soap acting as a flotation agent for the tallow or oil.
  • the soap acting as a flotation agent for the tallow or oil.
  • the soap acting as a flotation agent for the tallow or oil.
  • the soap acting as a flotation agent for the tallow or oil.
  • the soap acting as a flotation agent for the tallow or oil.
  • the soap acting as a flotation agent for the tallow or oil.
  • the tallow which acts as a lubricating medium forms a thin surface layer on the'wire being drawn and also
  • the object of the present invention is the provision of a lubricating compound which possesses extremely high lubricating properties and in which these lubricating properties may be developed in a relatively short period of time and retained for a considerable period of time.
  • one embodiment of the invention contemplates the use of a soluble alginate either alone or In combination llll with another medium as the flotation or suspending agent for the lubricant.
  • One lubricating compound which has proved very satisfactory for wire drawing consists of the following ingredients mixed in the proportions named by weight: Anhydrous sodium alginate, 1 part; water, 195 parts; tallow, 4 parts.
  • Anhydrous sodium alginate 1 part
  • water 195 parts
  • tallow 4 parts.
  • the sodium alginate is dissolved in 25 parts of water, the lubricant thenadded, and the whole mixture is boiled for one hour by direct injection of live steam. After allowing the mixture'to cool to approximately 150 F.
  • lubricating compounds with the alginates there may be used in place of the tallow or in combination therewith any of the well known lubricants, such as graphite, rapeseed oil, sperm oil, seal oil, lard oil, mineral oil, fish oil, cotton seed oil, etc.
  • lubricants such as graphite, rapeseed oil, sperm oil, seal oil, lard oil, mineral oil, fish oil, cotton seed oil, etc.
  • the lubricating compounds so obtained are very stable and effective for use in the drawing of wire, since the alginate emulsion acts in the nature of a vehicle to conduct and. deposit the lubricant onto the surface of the wire and the wire drawing apparatus where it will be of greatest service.
  • These alginic lubricating compounds have been found to give exceptionally good operating results since satisfactory lubricating prop erties are obtained immediately upon the compounds being put into'use. In addition to this. the compounds also effectively wash away deleterious foreigmmatter from the drawing dies and act as a cooling agent to prevent any considerable increase in temperature.
  • alginic compounds Another important advantage of these alginic compounds is the inherent characteristic they possess or having an unusually long, useful life in providing effective lubrication under continuous operating conditions. It is necessary, in some instances, with the ordinary lubricating comnoundsto make comparatively frequent additions of emulsions of lubricating agents since the compounds are unstable and the lubricants settle or separate out to thus decrease the lubricating efliciency.
  • the addition of the alginate promotes the emulsiflcation ,0! the lubricants with the carrying medium, which is usually water, whereby the minute globules of lubricants are finely dispersed and retained in suspension for long periodsof time.
  • the alginate in the compound materially facilitates the emulsiflcation and imparts a character of permanence to its lubricating life.
  • a wire drawing compound comprising substantially one part of soluble alginate, four parts of tallow, two parts of soap, and one hundred and. ninety-five parts of water.

Description

Patented Jan. 23, 1934 STATES 1,944,2'23 Lnnamar'mo ooMPonNn 71 oi-li No Drawing. Application June 6, 1929 Serial No. 369,0ll8
l il laiurn The invention relates to lubricating compounds and method of making such compounds, and.
more particularly to Wire drawing compounds and their method of manufacture.
Lubricating compounds for wire drawing machines, particularly machines designed for drawing wire at high speed or metal processing machines in general, have in many instances consisted principally of a lubricant, such as tallow, lard oil, fish oil, or vegetable oils mixed with soap and water, the soap acting as a flotation agent for the tallow or oil. Experience has proved the requirement of having the'tallow finely dispersed in the soap in very small particles. As is particularly true in the drawing of wire, the tallow which acts as a lubricating medium forms a thin surface layer on the'wire being drawn and also on the mouth and reducing aperture of the reducing die. If the tallow is not finely dispersed throughout the soap insufiicient and inadequate lubrication results, and consequently a wire of inaccurate size is produced and the dies either become badly worn or subject the wire to excessive tension frequently resulting in broken wire. When the tallow is not finely dispersed not only does improper lubrication result, but it collects at the mouth of the die and accumulates an excessive amount of copper dust from the wire being reduced. Due to this collection of copper dust extreme heating results and replacement of the dies or the restringing of the dies because of broken wire is necessary. It is also noted that when preparing a wire drawing compound consisting of water, tallow, and soap it is, in many instances, necessary to use the compound in the wire drawing machine for a considerable period before sumcient and adequate lubrication is achieved. Many theories as to'the reason for this condition have been advanced, but so far no definite conclusion as to the actual cause has been agreed to by wire drawing experts. In view of the facts as stated it is highly desirable to have a wire drawing compound in which the tallow or the lubricating medium is finely, readily, and quickly dispersed in the flotation agent.
The object of the present invention is the provision of a lubricating compound which possesses extremely high lubricating properties and in which these lubricating properties may be developed in a relatively short period of time and retained for a considerable period of time.
In accordance with this object, one embodiment of the invention contemplates the use of a soluble alginate either alone or In combination llll with another medium as the flotation or suspending agent for the lubricant.
Other objects and features of the invention will be apparent from the following detailed description of a wire drawing compound embodying the invention.
One lubricating compound which has proved very satisfactory for wire drawing consists of the following ingredients mixed in the proportions named by weight: Anhydrous sodium alginate, 1 part; water, 195 parts; tallow, 4 parts. In the preparation of this compound the sodium alginate is dissolved in 25 parts of water, the lubricant thenadded, and the whole mixture is boiled for one hour by direct injection of live steam. After allowing the mixture'to cool to approximately 150 F. it is then passed through a homogenizer or colloid mill at the rate of about 300 gallons per hour to obtain a fine dispersion of the fat particles, whereupon the mixture is gradually added to the remainder of the water which is forceably agitated by continuously pumping the entire compound through a return circulating system which in some cases may include the wire drawing machine.
Another formulae which gives very satisfactory results is as follows: Anhydrous sodium alginate, 1 part; water, '195 .parts; soap, 2 parts; tallow, 4 parts. In the preparation of this compound, the sodium alginate is dissolved in 25 parts of warm water, the soap is then added to the warm solution, the lubricant is next added, and the entire mixture boiled for one hour. The mixture is then passed through a colloid mill and the remainder of the water added and the compound thoroughly agitated as described for the aforementioned compound.
In preparing lubricating compounds with the alginates there may be used in place of the tallow or in combination therewith any of the well known lubricants, such as graphite, rapeseed oil, sperm oil, seal oil, lard oil, mineral oil, fish oil, cotton seed oil, etc.
The lubricating compounds so obtained are very stable and effective for use in the drawing of wire, since the alginate emulsion acts in the nature of a vehicle to conduct and. deposit the lubricant onto the surface of the wire and the wire drawing apparatus where it will be of greatest service. These alginic lubricating compounds have been found to give exceptionally good operating results since satisfactory lubricating prop erties are obtained immediately upon the compounds being put into'use. In addition to this. the compounds also effectively wash away deleterious foreigmmatter from the drawing dies and act as a cooling agent to prevent any considerable increase in temperature.
Another important advantage of these alginic compounds is the inherent characteristic they possess or having an unusually long, useful life in providing effective lubrication under continuous operating conditions. It is necessary, in some instances, with the ordinary lubricating comnoundsto make comparatively frequent additions of emulsions of lubricating agents since the compounds are unstable and the lubricants settle or separate out to thus decrease the lubricating efliciency. The addition of the alginate promotes the emulsiflcation ,0! the lubricants with the carrying medium, which is usually water, whereby the minute globules of lubricants are finely dispersed and retained in suspension for long periodsof time. Hence, the alginate in the compound materially facilitates the emulsiflcation and imparts a character of permanence to its lubricating life.
Lubricating compounds containing an alginate understood that the embodiments of the invention herein described are merely convenient and use ful forms of the invention, which are-capable at many other modifications without departing from the spirit and scope of the invention as defined by the appended claim.
What is claimed is:
. A wire drawing compound comprising substantially one part of soluble alginate, four parts of tallow, two parts of soap, and one hundred and. ninety-five parts of water.
GEORGE STANLEY RUTHERFORD.
US369006A 1929-06-06 1929-06-06 Lubricating compound Expired - Lifetime US1944273A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2692857A (en) * 1951-01-19 1954-10-26 Josef M Michel Noncorrosive graphite emulsions
US4052323A (en) * 1974-05-08 1977-10-04 Lonza, Ltd. High-temperature lubricant for the hot-working of metals
US5099667A (en) * 1989-06-16 1992-03-31 Lonza Ltd. System for suspending and applying solid lubricants to tools or work pieces
US5102468A (en) * 1987-09-29 1992-04-07 Lonza Ltd. Device for applying a descaling agent to the inner surface of a hollow billet
US5205488A (en) * 1990-03-26 1993-04-27 Lonza Ltd. Process and device for spraying a liquid intermittently, especially a lubricant suspension to be sprayed under high pressure

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2692857A (en) * 1951-01-19 1954-10-26 Josef M Michel Noncorrosive graphite emulsions
US4052323A (en) * 1974-05-08 1977-10-04 Lonza, Ltd. High-temperature lubricant for the hot-working of metals
US5102468A (en) * 1987-09-29 1992-04-07 Lonza Ltd. Device for applying a descaling agent to the inner surface of a hollow billet
US5099667A (en) * 1989-06-16 1992-03-31 Lonza Ltd. System for suspending and applying solid lubricants to tools or work pieces
US5205488A (en) * 1990-03-26 1993-04-27 Lonza Ltd. Process and device for spraying a liquid intermittently, especially a lubricant suspension to be sprayed under high pressure

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