US1898061A - Treatment of electrical sheet steels - Google Patents

Treatment of electrical sheet steels Download PDF

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US1898061A
US1898061A US395751A US39575129A US1898061A US 1898061 A US1898061 A US 1898061A US 395751 A US395751 A US 395751A US 39575129 A US39575129 A US 39575129A US 1898061 A US1898061 A US 1898061A
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rolls
steel
sheet
roll
metal
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US395751A
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Otho M Otte
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Allegheny Ludlum Corp
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Allegheny Steel Corp
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/12Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
    • C21D8/1216Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
    • C21D8/1222Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2201/00Treatment for obtaining particular effects
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/30Foil or other thin sheet-metal making or treating
    • Y10T29/301Method

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  • This invention relates to the treatment of electrical sheet steels and particularly to a method of finishing silicon steel sheets to reduce watt loss.
  • the present highest quality silicon alloy electrical steel checks around .70 to .75 watt loss per pound of metal while lower grades by the same test check around .80 to .88 watt loss.
  • Such steel is commonly classified as Grade A, Grade B and Grade C according to watt loss per pound and most mills turn out about 25% Grade A, 25% Grade B and 50% Grade C. Some more favored mills are able to produce 50% Grade A and 50% Grade B with the practical elimination of Grade C.
  • Grade B steel and even more so Grade C steel represents a loss and it would be highly desirable to eliminate both Grade B and Grade C and to raise the quality of Grade A.
  • Another object is to treat silicon steel sheets to a reducing step between rolls having different surface speeds.
  • a further object lies in suitably controlling the temperature of such reducing step.
  • FIG. 1 is a diagrammatical side view showing ordinary rolls in operation.
  • Figure 2 is a like view but shows the effect of increasing the speed of one of the rolls in accordance with one aspect of my invention;
  • Fig. 3 is a diagrammatical sectional view showing the effect of employing rolls of different diameters while at the same time maintaining them at a like speed of rotation in accordance with another aspect of my invention.
  • upper and lower rolls 1 and 2 form a path in which the metal shape 3 is reduced to form the shape 4. Since the speed ratio of both rolls in the illustration of Fig ure 1 is one to one (1: 1) and they are of like diameter, the orientation of crystals before rolling (see 3) is similar to the orientation after rolling (see 4). That is, when two rolls of the same diameter are driven at the same rotative speed, or when two rolls of different diameters are driven at rotative speeds which represent a function of the ratio between diameters, the metal shape 3 is, in general, only subjected to a strain.
  • strain it is meant that the metal is subjected to vertical pressure and mainly to the forces of compres- 7 sion. As a result, the orientation of crystals is changed very little, if any, by the roll pass (see numeral 4)
  • speed of one roll, 1' of Fig. 2. is given a ratio of say two to one (2: 1) to the other roll 2, one face or side of the metal while being rolled and compressed is, in addition, subjected to a stressing force.
  • the faster roll 1 tends to press one surface of the metal forward at a higher rate of speed than the slower roll 2, resulting in a multiplication of varied types of forces produced upon the shape being rolled.
  • the pressure of one roll, as influencing the crystalline structure of the metal being rolled, is advanced with respect to the pressure of the other roll.
  • the metal is not only reduced (see 4' and 4") but, is in addition, subjected to a tensile force makin an angle or (see Figure 2) or an angle [1 (see igure 3) with the axis of the metal .za:.
  • a tensile force makin an angle or (see Figure 2) or an angle [1 (see igure 3) with the axis of the metal .za:.
  • the greater the speed ratio, or the advanced push of one roll the greater will be the tensile force and the ofl-vertical displacement of the crystals of the metal.
  • Fig. 3 As is well known to the art, for many purposes, the layout represented by Fig. 3 is more eflicient than that shown in Fig. 2. For, the sharper and smaller the rolls, the greater is the horizontal component available for extending the bar or sheet in the direction of its length, and the smaller the proportion of power expended in extending the bar laterally to its length. Small rolls are, therefore, found to require less power to draw out a bar, doing so more quickly and causing less spreading in the operation than large rolls; this means there is more pressure per unit of surface if a small roll is applied. But questions of strength prevent full advantage being taken of this fact.
  • angles a and as seen in Figure 3, the angles ,8, are illustrative of such. In other words, they represent the angles formed between the normal axis H, of the metal being rolled and the axis of the orientation of crystalsor of metal flow.
  • the best electrical quality of silicon alloy steel is obtained in direct proportion as the aim structure is strained or so relatively located that the crystal is in position favorable to slip.
  • Such condition destroys the nal stress and the plasticity suflicient to weaken the crystal cleavage planes, allowing definite slip by definite, though minute, movement, all the while holding the displacement until frozen in the stressed relations.
  • Annealing partly or completely normalizes these strains depending upon the degree and uniformity of temperature and the duration of the annealing.
  • Certain premises are set up, on the basis of which, the present invention is unusually and unexpectedly eflicient.
  • Electrical steels must have definite orientation of grain structure as well as uniform strain after the anneal. The critical point between these two attributes, that is, the balance between them, determines the degree or amount of watt loss. In a fine grain steel, adjustment of grain and the beginning of stress is not detectable until elongation of approximately 8%. Extreme elongation of 50% or more produces a grain relatively unfavorable to stress or crystal slip and, therefore, many metals will harden by proportional elongation and the higher Brinell values result in part by the grain adjusting itself to positions unfavorable to further slip. At about elongation of the more ductile metals, rupture will occur and thus the maximum or limit of crystal slip is indicated.
  • a good silicon alloy is rolled, preferably in packs, to about one gauge heavy (#28 U. S. S.).
  • the alloy is reheated at approved temperatures, as per curve chart, say up to 1500 or 1600 F. and then given two passes on an Otte compound stressing mill with (balance screw and stress levers) the same side of the sheet always to the same side of the roll, the rolls being driven at different surface speeds or being of different diameters and with a counter-pressure at 45 to 65 to the line of metal flow.
  • the Otte stressing mill consists of two rolls either of different diameters driven at the same speed, or of the same diameters driven at different speeds, so as to give a different peripheral speed for each roll.
  • the sheets rolled in a mill of this kind receive a different amount of work by each roll, which would tend to stress the sheet. It has been found that by using a set up of this kind that the flow lines of the sheet have a different direction than when two rolls of the same diameter and driven at thesame speed are used. By proper regulation of the speed of the two rolls, or by proper regulation of the diameters the direction of these flow lines can be made to assume angles of 45 and 65 to the axis of the sheet. When such a condition in the mill is obtained it has been found that the pressure is exerted at these angles.
  • the action of the stressing mill by virtue of the different peripheral speeds of the two rolls, is a kneading action which breaks up the structure of the metal and introduces desirable stresses.
  • the next step is an immediate passing through straightening rolls, preferably with the sheet temperature about the point of recalescence, that is, around 800 to 900 F. Annealing atabout 1550 F. follows.
  • mills may be of two, three, and/or four roll high units and charts and temperature curves may be used or made for plainness and simplicity.
  • the process of treating electrical silicon alloy steels for reducing the watt loss which includes the steps of rolling the alloy to gauge, reheating to 1500 to 1600 F., passing through a roll pass and subjecting the steel to a stressing pressure for orienting the crystals at angles of 45 to 65 to the axes of the steel, straightening at 800 to 900 F., and annealing at about 1550 F.
  • a process of treating silicon steel to reduce its watt loss including'the steps of roll ing the steel to gauge, reheating it, stressing its opposite sides unequally, and thereafter straightening and annealing.
  • a process of treating silicon steel to reduce its watt loss including the steps of rolling the steel to gauge, reheating it to about 15001600 F., stressing it unequally on opposite sides, straightening it at about 800- 900 F., and annealing at about 1550 F.
  • a process of treating silicon steel to reduce its watt loss including the steps of rolling the steel to gauge, reheating it, passing it through a compound stressing mill to impart unequal stresses to opposite sides of the steel, straightening the so stressed steel and then annealing it.
  • a process of treating silicon steel to reduce its watt loss including the steps of rolling the steel to gauge, reheating it, assin it at least twice in the same relation t roug a compound stressing mill to impart unequal stresses to opposite sides of the steel, straightening the same and annealing it.

Description

Feb. 21, 1933. O M OTTE 1,898,061
TREATMENT OF ELECTRICAL SHEET STEELS Filed Sept. 27, 1929 HHHHPWiHHHIik-l INVENTOR an 727. am l%ww K ZWQPM A TTORNEYS Patented Feb. 21, 1933 UNITED STATES PATENT OFFICE OTHO M. OT'IE, OF TARENTUIMI, PENNSYLVANIA, ASSIGNOR TO ALLEGHENY STEEL COMPANY, A CORPORATION OF PENNSYLVANIA TREATMENT OF ELECTRICAL SHEET STEELS Application filed September 27, 1929. Serial No. 395,751.
This invention relates to the treatment of electrical sheet steels and particularly to a method of finishing silicon steel sheets to reduce watt loss.
Electrical sheet steels, as manufacturedby the various mills, have hitherto been of known relatively poor and unimproved quality and the industry has apparently had to make the best of the recognized unfavorable situation.
According to the Epstein test, the present highest quality silicon alloy electrical steel checks around .70 to .75 watt loss per pound of metal while lower grades by the same test check around .80 to .88 watt loss.
Such steel is commonly classified as Grade A, Grade B and Grade C according to watt loss per pound and most mills turn out about 25% Grade A, 25% Grade B and 50% Grade C. Some more favored mills are able to produce 50% Grade A and 50% Grade B with the practical elimination of Grade C.
It is realized that Grade B steel and even more so Grade C steel represents a loss and it would be highly desirable to eliminate both Grade B and Grade C and to raise the quality of Grade A.
It is, therefore, an object of my invention to eliminate Grades B and C as far as possible and to improve the quality of Grade A.
It is an object of my invention to produce a Supergrade A steel of reduced watt loss per pound with the practical elimination of Grades B and C.
Another object is to treat silicon steel sheets to a reducing step between rolls having different surface speeds.
A further object lies in suitably controlling the temperature of such reducing step.
Other and further objects will be pointed out hereinafter or will be apparent as the description proceeds.
For the purpose of illustratively explainin g certain features of my invention, a suitable drawing has been added. Figure 1 is a diagrammatical side view showing ordinary rolls in operation. Figure 2 is a like view but shows the effect of increasing the speed of one of the rolls in accordance with one aspect of my invention; and, Fig. 3 is a diagrammatical sectional view showing the effect of employing rolls of different diameters while at the same time maintaining them at a like speed of rotation in accordance with another aspect of my invention.
In the various figures somewhat similar elements will be given the same reference numerals, and be distinguished from the others by prime s'uffixes. In the figures, upper and lower rolls 1 and 2, respectively, form a path in which the metal shape 3 is reduced to form the shape 4. Since the speed ratio of both rolls in the illustration of Fig ure 1 is one to one (1: 1) and they are of like diameter, the orientation of crystals before rolling (see 3) is similar to the orientation after rolling (see 4). That is, when two rolls of the same diameter are driven at the same rotative speed, or when two rolls of different diameters are driven at rotative speeds which represent a function of the ratio between diameters, the metal shape 3 is, in general, only subjected to a strain. By strain it is meant that the metal is subjected to vertical pressure and mainly to the forces of compres- 7 sion. As a result, the orientation of crystals is changed very little, if any, by the roll pass (see numeral 4) On the other hand, if the speed of one roll, 1' of Fig. 2. is given a ratio of say two to one (2: 1) to the other roll 2, one face or side of the metal while being rolled and compressed is, in addition, subjected to a stressing force. In other words, the faster roll 1 tends to press one surface of the metal forward at a higher rate of speed than the slower roll 2, resulting in a multiplication of varied types of forces produced upon the shape being rolled. In using the term stressing I particularly wish to bring out subjecting the crystals of the metal to both tensile and compressive stresses and more particularly to the former and to the latter when so applied as to be conductive of the former. As a result, the rolling action upon the metal sheet, or the like, causes a slippage between the crystals after they have cooled down from the rolling heat and at the time they are allowed to freeze into position.
The same effect may be accomplished, as
seen in Figure 3, by providing rolls of different diameters, say of a ratio of three to one (3:1). This effect is obtained if the axial speed of both rolls 1'{ and 2" is maintained at the same value. Of course, if the roll diameters of Fig. 3 had the same ratio as the speed of the rolls of Fig. 2, the same angle representing the orientation of crystals would result.
Due to the s eed ratio maintained between the surface 0 one roll and the surface of another, the pressure of one roll, as influencing the crystalline structure of the metal being rolled, is advanced with respect to the pressure of the other roll. As a result, the metal is not only reduced (see 4' and 4") but, is in addition, subjected to a tensile force makin an angle or (see Figure 2) or an angle [1 (see igure 3) with the axis of the metal .za:. Of course, the greater the speed ratio, or the advanced push of one roll, the greater will be the tensile force and the ofl-vertical displacement of the crystals of the metal.
As is well known to the art, for many purposes, the layout represented by Fig. 3 is more eflicient than that shown in Fig. 2. For, the sharper and smaller the rolls, the greater is the horizontal component available for extending the bar or sheet in the direction of its length, and the smaller the proportion of power expended in extending the bar laterally to its length. Small rolls are, therefore, found to require less power to draw out a bar, doing so more quickly and causing less spreading in the operation than large rolls; this means there is more pressure per unit of surface if a small roll is applied. But questions of strength prevent full advantage being taken of this fact.
I have more or less arbitrarily selected the angular range of from 45 to as representative of advantageous angles of metal flow. As seen in Figure 2, the angles a, and as seen in Figure 3, the angles ,8, are illustrative of such. In other words, they represent the angles formed between the normal axis H, of the metal being rolled and the axis of the orientation of crystalsor of metal flow. Although I have found this range very effective, yet I do not wish to limit my application to such, since it has been employed merely for the purpose of explanation; other suitable angles may also be effective.
Present practice in manufacturing silicon alloy steels is one of indefinite control. This is clear from the fact that three different grades are obtained from heating, rolling and annealing under supposedly and apparently similar conditions. Like causes produce like results and variable products confirm variable control.
The best electrical quality of silicon alloy steel is obtained in direct proportion as the aim structure is strained or so relatively located that the crystal is in position favorable to slip. Such condition destroys the nal stress and the plasticity suflicient to weaken the crystal cleavage planes, allowing definite slip by definite, though minute, movement, all the while holding the displacement until frozen in the stressed relations. Annealing partly or completely normalizes these strains depending upon the degree and uniformity of temperature and the duration of the annealing.
Certain premises are set up, on the basis of which, the present invention is unusually and unexpectedly eflicient. Electrical steels must have definite orientation of grain structure as well as uniform strain after the anneal. The critical point between these two attributes, that is, the balance between them, determines the degree or amount of watt loss. In a fine grain steel, adjustment of grain and the beginning of stress is not detectable until elongation of approximately 8%. Extreme elongation of 50% or more produces a grain relatively unfavorable to stress or crystal slip and, therefore, many metals will harden by proportional elongation and the higher Brinell values result in part by the grain adjusting itself to positions unfavorable to further slip. At about elongation of the more ductile metals, rupture will occur and thus the maximum or limit of crystal slip is indicated.
According to the present invention, a good silicon alloy is rolled, preferably in packs, to about one gauge heavy (#28 U. S. S.). The alloy is reheated at approved temperatures, as per curve chart, say up to 1500 or 1600 F. and then given two passes on an Otte compound stressing mill with (balance screw and stress levers) the same side of the sheet always to the same side of the roll, the rolls being driven at different surface speeds or being of different diameters and with a counter-pressure at 45 to 65 to the line of metal flow. The Otte stressing mill consists of two rolls either of different diameters driven at the same speed, or of the same diameters driven at different speeds, so as to give a different peripheral speed for each roll. The sheets rolled in a mill of this kind receive a different amount of work by each roll, which would tend to stress the sheet. It has been found that by using a set up of this kind that the flow lines of the sheet have a different direction than when two rolls of the same diameter and driven at thesame speed are used. By proper regulation of the speed of the two rolls, or by proper regulation of the diameters the direction of these flow lines can be made to assume angles of 45 and 65 to the axis of the sheet. When such a condition in the mill is obtained it has been found that the pressure is exerted at these angles. The action of the stressing mill, by virtue of the different peripheral speeds of the two rolls, is a kneading action which breaks up the structure of the metal and introduces desirable stresses. The next step is an immediate passing through straightening rolls, preferably with the sheet temperature about the point of recalescence, that is, around 800 to 900 F. Annealing atabout 1550 F. follows.
The cost per ton to roll and anneal under the above process will not vary appreciablyv from the cost of manufacturing the low grades of electrical steels as made today.
The above is intended to be illustrative and not limitative and I may vary the details and application of the invention considerably without departing from its spirit and scope.
It is to be understood that the amount of normal pressure, secondary stress, the angle of counterpressure, area of metal stressed at normal pressure under rolls, temperature of rolling and annealing are all subject to variation as dictated or warranted by proper and good practice. The mills may be of two, three, and/or four roll high units and charts and temperature curves may be used or made for plainness and simplicity.
What I claim as new and desire to secure by Letters Patent is:
1. In a process of the character described, the steps of finishing silicon steel sheets at about the temperature of recalescence and subjecting the opposite sides of such sheets to rollers having unequal effective surface speeds.
2. In a process of the character described, the steps of heating a silicon steel sheet to a temperature not lower than the ordinary reheating temperature and in passing the reheated sheet between reducing rolls which cause, to opposite sides of the sheet, unequal forward slippage resulting in diiferential elongation in opposite sides of the sheet.
3. In a process of the character described, the step of stressing unequally the opposite sides of a sheet of silicon steel undergoing final mechanical reduction.
4. In a process of the character described, the step of simultaneously subjecting the o posite sides of a sheet of silicon steel to ro ls imparting unequal streses thereto during the final mechanical reduction of the sheet.
5. The process of treating electrical silicon alloy steels for reducing the watt loss which includes the steps of rolling the alloy to gauge, reheating to 1500 to 1600 F., passing through a roll pass and subjecting the steel to a stressing pressure for orienting the crystals at angles of 45 to 65 to the axes of the steel, straightening at 800 to 900 F., and annealing at about 1550 F.
6. A process of treating silicon steel to reduce its watt loss including'the steps of roll ing the steel to gauge, reheating it, stressing its opposite sides unequally, and thereafter straightening and annealing.
7. A process of treating silicon steel to reduce its watt loss including the steps of rolling the steel to gauge, reheating it to about 15001600 F., stressing it unequally on opposite sides, straightening it at about 800- 900 F., and annealing at about 1550 F.
8. A process of treating silicon steel to reduce its watt loss including the steps of rolling the steel to gauge, reheating it, passing it through a compound stressing mill to impart unequal stresses to opposite sides of the steel, straightening the so stressed steel and then annealing it.
9. A process of treating silicon steel to reduce its watt loss including the steps of rolling the steel to gauge, reheating it, assin it at least twice in the same relation t roug a compound stressing mill to impart unequal stresses to opposite sides of the steel, straightening the same and annealing it.
10. In a process of the character described, the steps of finishing silicon steel sheets at about the temperature of recalescence and subjecting such sheets to such mechanical working that the metal flow at the surface of one side of each sheet adjacent the line of greatest reduction is retarded with relation to the metal flow at the surface of the other side of the same sheet adjacent said line of greatest reduction.
11. The process of treating silicon steel comprising rolling it to gauge, reheating it subjecting it to the action of a compound stressing mill to impart a counterpressure of 45 to 65 to the line of metal flow, straightening at about the temperature of recalescence and annealing.
In testimony whereof, I have hereunto subscribed my name this 26th day of September, 1929.
OTHO M. OTTE.
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2968860A (en) * 1957-05-23 1961-01-24 Gen Electric Method of obtaining selective directional critical elongation in sheet magnetic material
US3099176A (en) * 1957-11-06 1963-07-30 Westinghouse Electric Corp Rolling silicon-iron
US3164496A (en) * 1956-09-20 1965-01-05 Gen Electric Magnetic material and method of fabrication
US3874954A (en) * 1970-05-11 1975-04-01 Mannesmann Ag Method of preparing iron silicon alloys with high silicon content for cold working requiring ductility
US4231818A (en) * 1972-03-30 1980-11-04 Allegheny Ludlum Industries, Inc. Methods of producing silicon steel strip
EP0019289A2 (en) * 1979-05-16 1980-11-26 Nippon Steel Corporation Process for producing grain-oriented silicon steel strip
DE3116419A1 (en) * 1980-04-26 1982-01-28 Nippon Steel Corp., Tokyo METHOD FOR PRODUCING A CORNORIENTED, ELECTROMAGNETIC STEEL TAPE
FR2506783A1 (en) * 1981-05-30 1982-12-03 Nippon Steel Corp PROCESS FOR MANUFACTURING ORIENTED GRAIN SILICON STEEL SHEET OR SHEET HAVING EXCELLENT MAGNETIC PROPERTIES
US5408856A (en) * 1992-11-17 1995-04-25 Allegheny Ludlum Corporation Apparatus for domain refining electrical steels by local mechanical deformation with multiple scribing rolls
WO2009094794A1 (en) * 2008-01-31 2009-08-06 Anton Walliser One-cylinder thrust roll method, device therefor and products manufactured therewith
US20120251379A1 (en) * 2011-03-28 2012-10-04 Jeong Hyo-Tae Asymmetric rolling apparatus, asymmetric rolling method and rolled materials fabricated by using the same
US20130017118A1 (en) * 2010-03-18 2013-01-17 Gangnung-Wonju National University Industry Academy Cooperation Group Asymmetric rolling device, asymmetric rolling method and rolled material manufactured using same

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3164496A (en) * 1956-09-20 1965-01-05 Gen Electric Magnetic material and method of fabrication
US2968860A (en) * 1957-05-23 1961-01-24 Gen Electric Method of obtaining selective directional critical elongation in sheet magnetic material
US3099176A (en) * 1957-11-06 1963-07-30 Westinghouse Electric Corp Rolling silicon-iron
US3874954A (en) * 1970-05-11 1975-04-01 Mannesmann Ag Method of preparing iron silicon alloys with high silicon content for cold working requiring ductility
US4231818A (en) * 1972-03-30 1980-11-04 Allegheny Ludlum Industries, Inc. Methods of producing silicon steel strip
EP0019289A2 (en) * 1979-05-16 1980-11-26 Nippon Steel Corporation Process for producing grain-oriented silicon steel strip
US4339287A (en) * 1979-05-16 1982-07-13 Nippon Steel Corporation Process for producing grain-oriented silicon steel strip
EP0019289B1 (en) * 1979-05-16 1985-04-10 Nippon Steel Corporation Process for producing grain-oriented silicon steel strip
DE3116419A1 (en) * 1980-04-26 1982-01-28 Nippon Steel Corp., Tokyo METHOD FOR PRODUCING A CORNORIENTED, ELECTROMAGNETIC STEEL TAPE
FR2506783A1 (en) * 1981-05-30 1982-12-03 Nippon Steel Corp PROCESS FOR MANUFACTURING ORIENTED GRAIN SILICON STEEL SHEET OR SHEET HAVING EXCELLENT MAGNETIC PROPERTIES
US5408856A (en) * 1992-11-17 1995-04-25 Allegheny Ludlum Corporation Apparatus for domain refining electrical steels by local mechanical deformation with multiple scribing rolls
US5590559A (en) * 1992-11-17 1997-01-07 Allegheny Ludlum Corporation Method and apparatus for domain refining electrical steels by local mechanical deformation with multiple scribing rolls
WO2009094794A1 (en) * 2008-01-31 2009-08-06 Anton Walliser One-cylinder thrust roll method, device therefor and products manufactured therewith
CN101932393A (en) * 2008-01-31 2010-12-29 杜蒙特瑞士股份公司 One-cylinder thrust roll method, device therefor and products manufactured therewith
JP2011514438A (en) * 2008-01-31 2011-05-06 デュモント スイッツァランド アクチェンゲゼルシャフト Single cylinder type thrust rolling method, apparatus for the single cylinder type thrust rolling method, and products manufactured using the single cylinder type thrust rolling method
US20110172783A1 (en) * 2008-01-31 2011-07-14 Dumont Switzerland Ag One-cylinder thrust roll method, device therefor and products manufactured therewith
CN101932393B (en) * 2008-01-31 2013-04-24 杜蒙特瑞士股份公司 One-cylinder thrust roll method, device therefor and products manufactured therewith
US20130017118A1 (en) * 2010-03-18 2013-01-17 Gangnung-Wonju National University Industry Academy Cooperation Group Asymmetric rolling device, asymmetric rolling method and rolled material manufactured using same
US9421592B2 (en) * 2010-03-18 2016-08-23 Gangneung-Wonju National University Industry Academy Cooperation Group Asymmetric rolling device, asymmetric rolling method and rolled material manufactured using same
US20120251379A1 (en) * 2011-03-28 2012-10-04 Jeong Hyo-Tae Asymmetric rolling apparatus, asymmetric rolling method and rolled materials fabricated by using the same
US9126248B2 (en) * 2011-03-28 2015-09-08 Gangneung-Wonju National University Industry Academy Cooperation Group Asymmetric rolling apparatus, asymmetric rolling method and rolled materials fabricated by using the same

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