US1877915A - Process for pumping vapors under high vacuum - Google Patents

Process for pumping vapors under high vacuum Download PDF

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Publication number
US1877915A
US1877915A US296006A US29600628A US1877915A US 1877915 A US1877915 A US 1877915A US 296006 A US296006 A US 296006A US 29600628 A US29600628 A US 29600628A US 1877915 A US1877915 A US 1877915A
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gas
vapors
pump
under high
high vacuum
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US296006A
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Warren K Lewis
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Standard Oil Development Co
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Standard Oil Development Co
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G5/00Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
    • C10G5/06Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas by cooling or compressing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S264/00Plastic and nonmetallic article shaping or treating: processes
    • Y10S264/78Processes of molding using vacuum

Definitions

  • the drawing is a semi-diagrammatic view in sectional elevation of an apparatus ar' ranged for the extraction of oil vapors from gas or oil wells operated under high vacua.
  • the present method finds a ready and valuable appli- 20 cation for the same purpose, namely for obtaining an increased yield of'natural gas and naphtha from gas wells, although my present method is of great value in other processes.
  • numeral 1 denotes the casinghead of a gas or oil well which is being operated at a high vacuum, for example, 28.5 to 29 inches of mercury below atmospheric pressure or higher. It will be understood that operation at such high vacua has not been heretofore practical.
  • a pipe 2 conducts the vaporous mixture from the Well to a vacuum pump 3 which may be of v10 to storage (not shown).
  • a pipe 4 is shown connected to pipe 2 for introduction of inert gas.
  • the drawing shows only the compression cylinder which is provided with valve chest 3a.
  • the compressed mixture is discharged through a pipe 7 to cooler 8 and thence to separator drum 9 from which the condensate is 'removed by line
  • the uncondensed gas is removed by line 11 to a suitable apparatus or removing the remaining gasoline or low boiling liquid hydrocarbons from the gas.
  • the extraction system is shown generally at 12 and may be a compression and coollng process, an absorption'process, an adsorption process or, indeed, any known method for removing'the normally liquid constituents from the gas.
  • the extracted gasoline is removed by line 13 to storage (not shown) and the ducted back by pipe 4 or recirculation through thecompressor. Gas may be bled from the system for fuel or for other uses by line 14.
  • the vaporous mixture is removed from the well under high vacuum, for example 1/;, inch of mercury absolute pressure or less, and is fed to the vacuum pump ⁇ together with a regulated quantity of non-condensible gas, such as nitrogen, CO2 or hydrocarbon gas.
  • non-condensible gas such as nitrogen, CO2 or hydrocarbon gas.
  • Inert gases are preferred-to air, although the latter could be used.
  • the Volume of gas is from 10 to 100% of the volume of the vapor and the amount may be regulated so that substantially no condensation occurs within the pump, although the cylinders are as may be concooled according to the present practice.
  • a pump which is capable of reducing the pressure in a closed air filled vessel to 0.7 inches of mercury absolute pressure, is tested pumping air at approximately 1.0 inch of mercury pressure and the volumetric efficiency was found to be 8.8%.
  • the same pump is then tested pumping toluene vapor substantially free of air or inert gas under the same pressure and it is found to have an efficiency of 1.75%. That is to say, the pump handles about five times as much air as toluene under the same pressure conditions.
  • the method of compressing through a vacuum pump vapors which condense on adiabatic compression which comprises actuating the vacuum pump adiabatically to draw the vapors from a body thereof in' a confined stream under less than atmospheric pressure, adding to the confined stream on the intake side of the pump gas which does not condense on adiabatic compression whereby condensation is lessened at pressures greater than the pressure in the intake, and delivering the mixture from the pump under said increased pressure.
  • the method of compressin through a vacuum pump vapors which con ense an adiabatic compression which comprises actuating the vacuum pump adiabatically to draw the vapors ⁇ in a confined stream from a body thereof under less than atmospheric pressure, adding to the confined stream on the intake side of the pump at least 10 percent by v olume of gas which does not condense on adiabatic compression to lessen condensation at atmospheric pressure, and delivering the mixture from the pumping operation under at' least atmospheric pressure.
  • the method of increasing the flow of vapors from a well which comprises mecha-nically drawing vapors from the well under vless than atmospheric pressure by an adiabatically operated vacuum pump, adding to the vapors gas which does not condense on adiabatic compression to lessen condensation at pressures greater' than the pressures on the intake of the pump, and discharging the mixture from the pump under said increased pressure.
  • the method of increasing the flow of vapors from a Well which comprises mechanically drawing vapors from the Well under less than atmospheric pressure by an adiabatically operated vacuum pump, adding to the vapors gas which does not condense on adiabatic compression to prevent condensation at atmospheric pressure, and discharging the mixture from the pumping operation under at least atmospheric pressure.

Description

Sept. ZO, 1932. w. K. L Ewls PROCESS FOR PUMPING VAPORS UNDER HIGH VACUUM Filed July 28, 1928 NUYWOK QR nSnNQ bbb @imm UZNU Patented Sept. 20, 129.."2
UNITED STATES PATENT OFFICE WARREN K. LEWIS, OF NEWTON, MASSACHUSETTS, ASSIGNOR TO STANDARD OIL DEVELOPMENT COMPANY, A CORPORATION 0F DELAWARE PROCESS FOR PUMPING VAPORS UNDER HIGH VACUUM Application med my as, 1928. semi No. 296,006.
10 drawing which illustrates the invention.
The drawing is a semi-diagrammatic view in sectional elevation of an apparatus ar' ranged for the extraction of oil vapors from gas or oil wells operated under high vacua.
15 In my copending applications Serial Nos.
296,007 and 296,008, filed July 28, 1928, methods for obtaining high vacua in oil wells, gas wells and the like were disclosed. The present method finds a ready and valuable appli- 20 cation for the same purpose, namely for obtaining an increased yield of'natural gas and naphtha from gas wells, although my present method is of great value in other processes.
I have observed that certain vapors unlike steam do not, on adiabatic compression, become superheated, but on the contrary condense and the vapor of normally liquid hydrocarbons, such as pentane, hexane, benzene, toluene and the like are of this nature. It is needless to say that cooling of the pump cylinders increases the condensation. I have further observed that vacuum pumps when pumping such vapors, particularly at high vacua, operate with avolumetric eihciency greatly below that obtained when operating on non-condensible gases under the same pressure. My present method greatly increases the capacity of any given pump and makes it possible to obtain higher'vacua than are now commercially realized.
Referring to the drawing, numeral 1 denotes the casinghead of a gas or oil well which is being operated at a high vacuum, for example, 28.5 to 29 inches of mercury below atmospheric pressure or higher. It will be understood that operation at such high vacua has not been heretofore practical. A pipe 2 conducts the vaporous mixture from the Well to a vacuum pump 3 which may be of v10 to storage (not shown).
one or more stages, although a single stage unit is shown on the drawing for simplicity. A pipe 4 is shown connected to pipe 2 for introduction of inert gas. The drawing shows only the compression cylinder which is provided with valve chest 3a. The compressed mixture is discharged through a pipe 7 to cooler 8 and thence to separator drum 9 from which the condensate is 'removed by line The uncondensed gas is removed by line 11 to a suitable apparatus or removing the remaining gasoline or low boiling liquid hydrocarbons from the gas. The extraction system is shown generally at 12 and may be a compression and coollng process, an absorption'process, an adsorption process or, indeed, any known method for removing'the normally liquid constituents from the gas. The extracted gasoline is removed by line 13 to storage (not shown) and the ducted back by pipe 4 or recirculation through thecompressor. Gas may be bled from the system for fuel or for other uses by line 14.
In the operation of my process the vaporous mixture is removed from the well under high vacuum, for example 1/;, inch of mercury absolute pressure or less, and is fed to the vacuum pump `together with a regulated quantity of non-condensible gas, such as nitrogen, CO2 or hydrocarbon gas. Inert gases are preferred-to air, although the latter could be used. Ordinarily the Volume of gas is from 10 to 100% of the volume of the vapor and the amount may be regulated so that substantially no condensation occurs within the pump, although the cylinders are as may be concooled according to the present practice. Ad-
for each case.
As an example of my process, a pump, which is capable of reducing the pressure in a closed air filled vessel to 0.7 inches of mercury absolute pressure, is tested pumping air at approximately 1.0 inch of mercury pressure and the volumetric efficiency was found to be 8.8%. The same pump is then tested pumping toluene vapor substantially free of air or inert gas under the same pressure and it is found to have an efficiency of 1.75%. That is to say, the pump handles about five times as much air as toluene under the same pressure conditions. When air is admixed with the toluene vapor in a proportion of .4 volumes of air per volume of toluene vapor, the efficiency rises to 7.65%, and if the efficiency is based on the vapor alone, neglecting the volume of air, the value is found to be 5.4%; or in other words, the volume of toluene vapor handled is increased about threefold by the addition of the air.
Although my specification has particularly described the process in relation to the removal of gas and oil vapor from wells, it will be understood that my invention finds application wherever it is desirable to pump vapors which, unlike steam, do not superheat on adiabatic compression or such compression as occurs in compression pumps cooled in any suitable manner.
My invention is not to be limited by any theory of the operation of the process, nor by any example which may have been given merely by way of illustration, but only by the following claims in which l Wish to claim all novelty inherent in the invention.
I claim:
1. The method of compressing through a vacuum pump vapors which condense on adiabatic compression, which comprises actuating the vacuum pump adiabatically to draw the vapors from a body thereof in' a confined stream under less than atmospheric pressure, adding to the confined stream on the intake side of the pump gas which does not condense on adiabatic compression whereby condensation is lessened at pressures greater than the pressure in the intake, and delivering the mixture from the pump under said increased pressure.
2. The method of compressin through a vacuum pump vapors which con ense an adiabatic compression, which comprises actuating the vacuum pump adiabatically to draw the vapors `in a confined stream from a body thereof under less than atmospheric pressure, adding to the confined stream on the intake side of the pump at least 10 percent by v olume of gas which does not condense on adiabatic compression to lessen condensation at atmospheric pressure, and delivering the mixture from the pumping operation under at' least atmospheric pressure.
4. The method of increasing the flow of vapors from a well, which comprises mecha-nically drawing vapors from the well under vless than atmospheric pressure by an adiabatically operated vacuum pump, adding to the vapors gas which does not condense on adiabatic compression to lessen condensation at pressures greater' than the pressures on the intake of the pump, and discharging the mixture from the pump under said increased pressure.
5. The method of increasing the flow of vapors from a Well which comprises mechanically drawing vapors from the Well under less than atmospheric pressure by an adiabatically operated vacuum pump, adding to the vapors gas which does not condense on adiabatic compression to prevent condensation at atmospheric pressure, and discharging the mixture from the pumping operation under at least atmospheric pressure.
WARREN K. LEWIS.
US296006A 1928-07-28 1928-07-28 Process for pumping vapors under high vacuum Expired - Lifetime US1877915A (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4369839A (en) * 1981-08-17 1983-01-25 F & P Production Co., Inc. Casing vacuum system
US4593760A (en) * 1984-01-04 1986-06-10 The Upjohn Company Removal of volatile contaminants from the vadose zone of contaminated ground
US4660639A (en) * 1984-01-04 1987-04-28 The Upjohn Company Removal of volatile contaminants from the vadose zone of contaminated ground
USRE33102E (en) * 1984-01-04 1989-10-31 The Upjohn Company Removal of volatile contaminants from the vadose zone of contaminated ground
US5554290A (en) * 1995-04-11 1996-09-10 Geraghty & Miller, Inc. Insitu anaerobic reactive zone for insitu metals precipitation and to achieve microbial de-nitrification
US5575589A (en) * 1995-04-11 1996-11-19 Geraghty & Miller, Inc. Apparatus and method for removing volatile contaminants from phreatic water
US5588490A (en) * 1995-05-31 1996-12-31 Geraghty & Miller, Inc. Method and system to achieve two dimensional air sparging
US5664911A (en) * 1991-05-03 1997-09-09 Iit Research Institute Method and apparatus for in situ decontamination of a site contaminated with a volatile material
US6007274A (en) * 1997-05-19 1999-12-28 Arcadis Geraghty & Miller In-well air stripping, oxidation, and adsorption
US6116816A (en) * 1998-08-26 2000-09-12 Arcadis Geraghty & Miller, Inc. In situ reactive gate for groundwater remediation
US6143177A (en) * 1995-04-11 2000-11-07 Arcadis Geraghty & Miller, Inc. Engineered in situ anaerobic reactive zones
US20060290197A1 (en) * 2005-06-10 2006-12-28 See Jackie R Oil extraction system and method
US20080164020A1 (en) * 2007-01-04 2008-07-10 Rock Well Petroleum, Inc. Method of collecting crude oil and crude oil collection header apparatus
US20080169104A1 (en) * 2007-01-11 2008-07-17 Rock Well Petroleum, Inc. Method of collecting crude oil and crude oil collection header apparatus
US20080314640A1 (en) * 2007-06-20 2008-12-25 Greg Vandersnick Hydrocarbon recovery drill string apparatus, subterranean hydrocarbon recovery drilling methods, and subterranean hydrocarbon recovery methods
US20090183872A1 (en) * 2008-01-23 2009-07-23 Trent Robert H Methods Of Recovering Hydrocarbons From Oil Shale And Sub-Surface Oil Shale Recovery Arrangements For Recovering Hydrocarbons From Oil Shale

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4369839A (en) * 1981-08-17 1983-01-25 F & P Production Co., Inc. Casing vacuum system
US4593760A (en) * 1984-01-04 1986-06-10 The Upjohn Company Removal of volatile contaminants from the vadose zone of contaminated ground
US4660639A (en) * 1984-01-04 1987-04-28 The Upjohn Company Removal of volatile contaminants from the vadose zone of contaminated ground
USRE33102E (en) * 1984-01-04 1989-10-31 The Upjohn Company Removal of volatile contaminants from the vadose zone of contaminated ground
US5664911A (en) * 1991-05-03 1997-09-09 Iit Research Institute Method and apparatus for in situ decontamination of a site contaminated with a volatile material
US6143177A (en) * 1995-04-11 2000-11-07 Arcadis Geraghty & Miller, Inc. Engineered in situ anaerobic reactive zones
US5554290A (en) * 1995-04-11 1996-09-10 Geraghty & Miller, Inc. Insitu anaerobic reactive zone for insitu metals precipitation and to achieve microbial de-nitrification
US5575589A (en) * 1995-04-11 1996-11-19 Geraghty & Miller, Inc. Apparatus and method for removing volatile contaminants from phreatic water
US6632364B1 (en) 1995-04-11 2003-10-14 Arcadis G & M Engineered in situ anaerobic reactive zones
US6322700B1 (en) 1995-04-11 2001-11-27 Arcadis Geraghty & Miller Engineered in situ anaerobic reactive zones
US5588490A (en) * 1995-05-31 1996-12-31 Geraghty & Miller, Inc. Method and system to achieve two dimensional air sparging
US6283674B1 (en) 1997-05-19 2001-09-04 Arcadis Geraghty & Miller In-well air stripping, oxidation, and adsorption
US6102623A (en) * 1997-05-19 2000-08-15 Arcadis Geraghty & Miller, Inc. In-well air stripping, oxidation, and adsorption
US6007274A (en) * 1997-05-19 1999-12-28 Arcadis Geraghty & Miller In-well air stripping, oxidation, and adsorption
US6254310B1 (en) 1997-05-19 2001-07-03 Arcadis Geraghty & Miller, Inc. In-well air stripping and adsorption
US6280118B1 (en) 1998-08-26 2001-08-28 Arcadis Geraghty & Miller, Inc. In situ reactive gate
US6116816A (en) * 1998-08-26 2000-09-12 Arcadis Geraghty & Miller, Inc. In situ reactive gate for groundwater remediation
US20060290197A1 (en) * 2005-06-10 2006-12-28 See Jackie R Oil extraction system and method
US7568527B2 (en) 2007-01-04 2009-08-04 Rock Well Petroleum, Inc. Method of collecting crude oil and crude oil collection header apparatus
US20080164020A1 (en) * 2007-01-04 2008-07-10 Rock Well Petroleum, Inc. Method of collecting crude oil and crude oil collection header apparatus
US20080169104A1 (en) * 2007-01-11 2008-07-17 Rock Well Petroleum, Inc. Method of collecting crude oil and crude oil collection header apparatus
US7543649B2 (en) 2007-01-11 2009-06-09 Rock Well Petroleum Inc. Method of collecting crude oil and crude oil collection header apparatus
US20080314640A1 (en) * 2007-06-20 2008-12-25 Greg Vandersnick Hydrocarbon recovery drill string apparatus, subterranean hydrocarbon recovery drilling methods, and subterranean hydrocarbon recovery methods
US7823662B2 (en) 2007-06-20 2010-11-02 New Era Petroleum, Llc. Hydrocarbon recovery drill string apparatus, subterranean hydrocarbon recovery drilling methods, and subterranean hydrocarbon recovery methods
US8307918B2 (en) 2007-06-20 2012-11-13 New Era Petroleum, Llc Hydrocarbon recovery drill string apparatus, subterranean hydrocarbon recovery drilling methods, and subterranean hydrocarbon recovery methods
US8474551B2 (en) 2007-06-20 2013-07-02 Nep Ip, Llc Hydrocarbon recovery drill string apparatus, subterranean hydrocarbon recovery drilling methods, and subterranean hydrocarbon recovery methods
US8534382B2 (en) 2007-06-20 2013-09-17 Nep Ip, Llc Hydrocarbon recovery drill string apparatus, subterranean hydrocarbon recovery drilling methods, and subterranean hydrocarbon recovery methods
US20090183872A1 (en) * 2008-01-23 2009-07-23 Trent Robert H Methods Of Recovering Hydrocarbons From Oil Shale And Sub-Surface Oil Shale Recovery Arrangements For Recovering Hydrocarbons From Oil Shale
US7832483B2 (en) 2008-01-23 2010-11-16 New Era Petroleum, Llc. Methods of recovering hydrocarbons from oil shale and sub-surface oil shale recovery arrangements for recovering hydrocarbons from oil shale

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