US1865470A - Electrolytic bright dip for iron and steel - Google Patents

Description

. knownpic a goodbright surfacetreated has Patented July 5, 1932 enonen '3. noenoom, or mew ,nawm, new JERSEY,

BRITAIN, CONNECTICUT, AN D ASSIGNORS T0 HANSON -VAN WINKLE-MUNNING COMPANY,

OF I ATAWAN, NEWJERSEY, A CORPORATION OF NEW JERSEY The tinuation of our prior U. S, application filed October 9, 1929, Serial No. 398,557.

This invention relates to the treatment of iron. and steel for the removal of rust, scale, and the like, and the obtaining of a clean bright surface. The removal of rust and scale from. such materials is ordinarily'attempted by the use of so-called pickles, either acting in a purely chemical manner or acting electrochemically. Various acids have been employed for such pickles, and in the case of electrochemicaltreatments for removal of scale and rust the article being in some cases been made the cathodeman-electrolytic circuit, and in others it has been made the anode. In-all processes heretofore known, the pickling has not produced' a clean: bright surface, andit is a particularsobject of'our present invention to provide abright dip electrolytic treatment which Ina be employed after any of the zlingtreatments in order to obtain Both inpickling and important to avoid in bright dipping it is undue amount of the etching or removing an metal itself, and for commercial reasons it is essential that the treatment should be completed in a short time, and furthermore should not result in the production of substantial quantities of objectionable fumes.

The method which forms the subject mat v ter of'the present invention has, in addition to its general object of providing a bright surface, the further objects of obtaining this result without removingan undue amount 'of the base metal or fumes, and without able amount of'time.

The invention from a description of a treatment, including theoriginal ickling for the removal of rust and scale an the subsequent treatment of the material in the electrolytic bright dip. It will be understood, however, that any suitable pickling or preliminary treatment may be employed, and that the'essential novelty of the process resides in the electrolytic bright dip method. Assuming, for-example, the preliminary requiring an objection present application is in part a conmethods. The effect peratures above 100 producing objectionable will be clearly understood where large work is being mnc'rnonrrro 331cm: M2 E03 mon mn STEEL .Ro Drawing. Application filed October 17, 1930, Serial No. 489,408, and in Canada October 9, 1930.

cleaning and pickling of the iron or steel by cathodic action in an acid bath, we may prowILLIs 3. KING, of

cuit. The temperature of the solution may,

for example, be from room temperature to 160 F. The treatment may continue for a period of from 1 to 6 minutes or longer, after which the article may be subjected, with or without previous rinsing, to the electrolytic bright dip, in which treatment the article is made the anode in an electrolytic circuit having a sulphuric acid electrol e of from 25 to 75% strength. A particu arly favorable strength of acid in this step is'between 40 and 50% H 30 We find that high current densities (80 to 200 amperes per square foot) and compare;- tively low temperatures (50-90 F.) are favorable'to the production of a good bright surface. With too low a current density or too highsa temperature, the surface will be clean but not bright, and will have more the appearance obtainable by ordinary pickling of higher temperatures can to a certain extent be counteracted by the use of higher current densities, and at tem- F. it is necessary to use per square foot of anode 200 amperes or more surface. It is more economical to keep the F. and preferably temperature below 80 between and F. A typicalexample of temperature and-current density in the case of 40 to 50% sulphuric-acid is a casein which 150 amperes per square foot are passed through the circuit at a temperature of F. With temperatures between 60 and 70 F. somewhat lower current densities may be employed. Artificial cooling is desirable treated, as otherwise the temperature may rise to a degree at which the work will become darkened.

Thereare some indicationsthat the production of the bright surface is due to the anodic formation of persulphuric acid, the maintenance ,of which is favored by the high current density and thelow temperature. At

any rate, face, even after it has been obtained, can be dulled and darkened by further anodic treatment at higher temperatures or lower current densities. The anode and cathode areas in both the initial pickling step and in the final electrolytic bright dip, may be equal, though the invention is not limited to this particular relation of anode and" cathode areas. In the electrolytic bright dip, the current density referred to is an initial current density which drops or decreases sharply at the beginning of polarization. Shortly after this sharp drop in current density the work becomes clean, but not bright, while the current still continues to decrease. A little later the work becomes bright, and the decrease in current ceases and the current remains steady at a greatlyreduced Value. The treatment may be completed in the space of 1 minutes, under the conditions assumed, but it may be continued beyond this point for several minutes without injury to the material which is being treated. It should be borne in mind that favorable results require higher current densities when higher temperatures are used in the electrolytic bright dip. It is also of particular importance where high current densities are employed, such as herein contemplated, that the contact resistance throughout the circuit be kept low, and that all contacts be positive or secure so as to avoid any unintentional fluctuation in the current density passing through the electrolyte.

After the electrolytic bright dip treatment, the work may be removed and washed or rinsed and dried. In the case of steel articles the surface obtained is particularly clean and bright, whereas articles of iron will ordi- 'narily have a somewhat less bright surface than obtainable in the case'of steel, although far superior to that heretofore obtained in the use of the known pickling methods. By

the treatment described, the undesirable hardening of the surface, which has been a common fault in pickling methods heretofore employed, is apparently entirely avoided.

Those skilled in the art may employ addition agents of known function and character, in order to modify the electrolyte to suit their own special requirements or preferences. Since the high state. of oxidation or the maintenance of persulphuric acid appears to be important in obtaining the desired result,

such addition agents may include oxidizing agents such as chromic acid, sodium perborate, hydrogen peroxide or nitrate salts such as ammonium nitrate.

We claim 1. The method of bright dipping iron and steel, from which scale has been preliminarily removed, which comprises maintaining the iron or steel as an anode in a sulphuric acid electrolyte of from 25 to 75% strength with it is significant that the bright sura current density of from 80 to 250 amperes per square foot of anode surface, and artificially cooling the electrolyte to maintain the temperature thereof between F. and 1 00 F I .2. The method of bright dipping iron and steel,which comprises passing an electric cmrent of from 80 to 250 amperes per square foot of anode surface through an electrolytic circuit in which the iron or steel article is the anode, in an electrolyte of sulphuric acid of from 25 to75% strength, and artificially cooling the electrolyte to maintain the temperature thereof below 100 F. i

3. The method of bright dipping iron and steel, which comprises passing an electric current of from-80 to 250amperes per square foot of anode surface through an electrolytic circuit in which the iron or steel article is the anode, in an electrolyte of sulphuric acid of from 25 to 75% strength, and artificially cooling the electrolyte to maintain the temperature thereof below 80 F.

4. The method of bright dipping iron and steel, which comprises passing an electric current of from 80 to 250 amperes per square foot of anode surface through an electrolytic circuit in which the-iron or steel article is the anode, in an electrolyte of sulphuric acid of from 25 to 75% strength, and artificially cooling the electrolyte to maintain the temperature thereof between F. and F.

5. The method of bright dipping iron and steel, which comprises maintaining the iron or steel as an anode in a sulphuric acid electrolyte of from 40 to 50% strength with a current density of from 80 to 250 amperes per square foot, and artificially cooling the electrolyte to maintain the temperature thereof between 60 F. and 70 F.

6. The method of bright dipping iron or steel articles, which comprises preliminarily removing the scale and then making the article the anode in a sulphuric acid electrohTte of from 40 to 50% strength with an initial current density of about 150 amperes per square foot of anode surface, and artificially cooling the electrolyte to maintain the temperature thereof in the neighborhood of 60 F.

to 70 F.

GEORGE B. HOGABOOM. WVILLIS R. KING.