US1795473A - Method of treating magnesium - Google Patents

Method of treating magnesium Download PDF

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Publication number
US1795473A
US1795473A US147618A US14761826A US1795473A US 1795473 A US1795473 A US 1795473A US 147618 A US147618 A US 147618A US 14761826 A US14761826 A US 14761826A US 1795473 A US1795473 A US 1795473A
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Prior art keywords
magnesium
articles
treating magnesium
treating
action
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Expired - Lifetime
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US147618A
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Edward C Burdick
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Dow Chemical Co
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Dow Chemical Co
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Priority to US147618A priority Critical patent/US1795473A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • C23C22/57Treatment of magnesium or alloys based thereon

Definitions

  • the articles to be treated, castings or other shaped articles, and-of the pure metal or magnesium alloys substantially free from copper and cadmium, are subjected to the action of material capable of removing surface traces of such impurities present, and
  • a method of treating magnesium arti cles which comprises subjecting the article to the action of ten to thirty per cent. sulphuric acid, and then washing.
  • a method of treating magnesium articles which comprises dipping the article in a bath of one part of 96% sulphuric acid and three parts of water, then washing the article in hot water, and drying.

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Description

40 particularly being desirable Patented Mar. 10, 1931 UNITED STATES PATENT OFFICE;
EDWARD C. BURDICK, OF MIDLAND, MICHIGAN, ASSIGNOB TO THE DOW CHEMICAL COMPANY, OF MIDLAND, MICHIGAN, A CORPORATION OF MICHIGAN v METHOD OF TREATING MAGNESIUM No Drawing.
Metallic magnesium and its alloys in exposure to the air under ordinary conditions ecomes quickly covered with a deepening tarnish of dark color which detracts fromon the surface in suflicient amount to act in I the presence of moisture, and apparently also direct a catalytic oxidative process; and the present invention provides a treatment preventing such action and making possible a bright lustrous surface resistance against detrimental change.
To the accomplishment of the foregoing and related ends, the invention, then, consists of the features hereinafter fully described, and particularly pointed out in the 2 claims, the following description setting forth in detail but one of the various ways in which the principle of the invention may be used.
The articles to be treated, castings or other shaped articles, and-of the pure metal or magnesium alloys substantially free from copper and cadmium, are subjected to the action of material capable of removing surface traces of such impurities present, and
for this an agent of acid character is em ployed. I prefer sulphuric acid, although other acids, as nitric, hydrochloric, or even in some instances acid salts, as acid sodium sulphate, may be used less desirably. The
articles are thoroughly exposed to the treating agent,for instance by dipping. For sulphuric acid a strength of ten to thirty per cent. is em loyed; a proportion of one part of 96% su phuric to three arts of water 'f r alloys. The magnesium articles are then well washed in water, which should best be hot in order to promote the subsequent drying. The articles so treated present a smooth lustrous surface not subject to further action in average conditions in the air. v
, Other modes of applying the principle of the invention may be employed, change being made as regards the details disclosed,
provided the steps stated by any of the 1501- Application filed November 10, 1926. Serial No. 147,618.
lowing claims or the equivalent of such be employed. 7
I therefore particularly point out and distinctly claim as my invention:
1. A method of treating magnesium arti cles, which comprises subjecting the article to the action of ten to thirty per cent. sulphuric acid, and then washing.
2. A method of treating magnesium articles, which comprises dipping the article in a bath of one part of 96% sulphuric acid and three parts of water, then washing the article in hot water, and drying.
Signed by me this 2 day of November,
EDWARD C. BURDICK.
US147618A 1926-11-10 1926-11-10 Method of treating magnesium Expired - Lifetime US1795473A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2418955A (en) * 1943-05-25 1947-04-15 Aluminum Co Of America Process of removing foreign matter from magnesium surfaces
US2638424A (en) * 1946-02-09 1953-05-12 American Electro Metal Corp Method of processing metal powders
US3087841A (en) * 1958-11-03 1963-04-30 Dow Chemical Co Method of treating magnesium metal article prior to spotwelding
KR20180041208A (en) * 2015-08-20 2018-04-23 후지 라이트 메탈 가부시키가이샤 Alloy member usable in living body and method for manufacturing the same

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2418955A (en) * 1943-05-25 1947-04-15 Aluminum Co Of America Process of removing foreign matter from magnesium surfaces
US2638424A (en) * 1946-02-09 1953-05-12 American Electro Metal Corp Method of processing metal powders
US3087841A (en) * 1958-11-03 1963-04-30 Dow Chemical Co Method of treating magnesium metal article prior to spotwelding
KR20180041208A (en) * 2015-08-20 2018-04-23 후지 라이트 메탈 가부시키가이샤 Alloy member usable in living body and method for manufacturing the same
EP3342901A4 (en) * 2015-08-20 2019-04-17 Fuji Light Metal Co., Ltd. Alloy member usable in organisms and production method therefor
KR102170607B1 (en) 2015-08-20 2020-10-27 후지 라이트 메탈 가부시키가이샤 Alloy member usable in living body and manufacturing method thereof
US10842911B2 (en) 2015-08-20 2020-11-24 Fuji Light Metal Co., Ltd. Alloy member usable in organisms and production method therefor

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