US1739752A - Magnetic material and appliance - Google Patents

Magnetic material and appliance Download PDF

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Publication number
US1739752A
US1739752A US243008A US24300827A US1739752A US 1739752 A US1739752 A US 1739752A US 243008 A US243008 A US 243008A US 24300827 A US24300827 A US 24300827A US 1739752 A US1739752 A US 1739752A
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cobalt
iron
magnetic
alloys
magnetizing
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US243008A
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Gustaf W Elmen
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AT&T Corp
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Bell Telephone Laboratories Inc
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/10Ferrous alloys, e.g. steel alloys containing cobalt

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  • MAGNETIC MATERIAL AND APPLIANCE Filed Dec. 28. 1927 '4 Sheets-Sheet 4 lo'a'oa'o'lw f'o'e'oio'a o 9'0100 PERCENT COBALT HYSTERESIS 0 IO o's'o 4 0 5'0 60'70 50 530
  • This invention relates to magnetic alloys and has particular reference to magnetic alloys of high permeability.
  • compositions are heat treate A suitable heat treatment consists in maintaining the alloy at about 1100 C. for from two to three hours, followed by fairly slow cooling in the furnace.
  • the heat treatment is not extremel critical and may be varied considerably wlth satisfactory results.
  • the flux densit is considerably greater than that of Armco 113011 and also considerably greater than that of magnetic compositions corresponding to the formula CoFe
  • the flux densities herein given for compositions of approximately 50% iron and 50% cobalt are not much greater than those given in prior ublications relating to the alloy 001%, it as been found that the high values of flux density'published by others for the alloy CoFe do not apply to ordinary compure or almost pure iron.
  • the magnetic compositions just described are also useful for electromagnetic receivers.
  • the pole pieces alone may be made of ironcobalt compositions such as herein described.
  • the entire core structure may be made of the iron-cobalt magnetic composition.
  • the diaphragm also may advantageously be made of iron-cobalt alloys of high permeability having between 40 and 60% iron.
  • Such relays are commonly employed in dial or machine switching telephone systems.
  • Fig. 1 is a cross-section of a loud speaker diaphragm and its driving magnet
  • Fig. 2 is a detailed cross-section of a part of the magnet structure
  • Fig. 3 illustrates the coil which is to be attached to the diaphragm on an enlarged scale
  • Fig. 4 represents an electromagnetic receiver
  • Fig. 5 represents a permanent magnet receiver
  • Fig. 6 is a graph of flux density B against magnetizing force H of a number of ironcobalt alloys for flux densities from zero to 34 gauss, the percentage of cobalt being indicated on each curve;
  • Fig. 7 is an extension to H 69 of the curves of Fig. 6;
  • the diaphragm 10 is supported under tension by the frame 11.
  • the electrodynamic unit 12 is supported by the cross members of the frame.
  • the coil 13 of the electrodynamic unit is secured to the diaphragm to drive it.
  • the coil 13 is positioned between the annular pole faces 14 and 15 of the magnetic structure.
  • the polarizing winding 16 is positioned within and substantially fills the hollow magnetic structure.
  • the brass ring 23 serves to support the winding.
  • the main body 17 of the magnet structure may consist of any suitable magnetic material.
  • the pole pieces 14 and 15, more particularly illustrated in Fig. 2 are annular and are constructed of high permeability cobalt-iron allow having about 50% iron. The annular gap between the pole pieces is made very small.
  • the coil 13 is made of a thin ribbon conductor preferably of copper and of the order of .002 thick and .014" Wide, wound so that the plane of the ribbon is perpendicular to the axis of the coil.
  • the adjacent turns of the ribbon conductor are insulated from each other by bakelite. This is applied by dissolving the bakelite in acetone and then drying the coil after the conductor is applied.
  • the coil 13 with a part broken away is illustrated in Fig. 3 on a still more enlarged scale.
  • Fig. 4 represents an electromagnetic receiver in which the magnetic core 18 consists of a body of material having about 50% iron and 50% cobalt heat treated to have high permeability.
  • the winding 19 is applied in the usual manner.
  • the diaphragm 20 may also advantageously be constructed of a mag netic material of 50% iron and 50% cobalt.
  • the permanent magnet 21 may consist of any suitable magnetic material.
  • the core portions 22 to which the magnetizing windings are applied consist of high permeability cobalt-iron alloys attached to the permanent magnet in any suitable manner.
  • the diaphragm 20 may also advantageously be composed of an alloy similar to that of the cores 22.
  • Fig. 9 indicates a decided hysteresis minimum in the iron-cobalt series at 50% Fe-50% Co for a flux density of 5,000 gauss. On this curve a few points were calculated by means of Steinmetz formula, from hysteresis cycles taken at slightly greater flux densltles. The results are no doubt quite close to those which would be obtained by using the same maximum flux density in each instance.
  • a magnetic composition comprising between 40 and 60% cobalt and the balance iron having a permeability above that of Armco iron at a corresponding magnetizing force.
  • a magnetic composition comprising approximately 50% iron and approximately 50% cobalt ieat treated to have apermeability higher than that of Armco iron at a corresponding magnetizing force.
  • An electromagnetic apparatus such as a loud speaker, telephone receiver or heavy duty relay, having a magnetic circuit consisting in whole or part, and preferably in a part adjacent an air-gap, of a magnetic composition consisting of 40 to 60% cobalt and the balance iron.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Hard Magnetic Materials (AREA)
  • Soft Magnetic Materials (AREA)

Description

Dec. 17, 1929. e. w. ELMEN v MAGNETIC MATERIAL AND APPLIQNCE 4 Sheets-Sheet ALLO Filed Dec. 28. 1927 -50 'IoFE150\7-CO N Y E WM RE. w W m WWW a Dec. 17, 1929.
G. W. ELMEN MAGNETIC MATERIAL AND APPLIANCE Filed Dec. 28. 1927 4 Sheets-Sheet 2 smwhomwnu 6 x ssnve m g /NVEN7'OR Guam/- W ELMEN y ATTORNEY Dec. 17, 1929. 5. w. ELMEN 1,739,752
MAGNETIC MATERIAL AND APPLIANCE Filed Dec. 28, 1927 4 Sheets-Sheet 5 H IN 6AU5S ATTORNEY Dec. 17, 1929. G. w. ELMEN- 1,739,752
MAGNETIC MATERIAL AND APPLIANCE Filed Dec. 28. 1927 '4 Sheets-Sheet 4 lo'a'oa'o'lw f'o'e'oio'a o 9'0100 PERCENT COBALT HYSTERESIS 0 IO o's'o 4 0 5'0 60'70 50 530 |o PERCENT COBALT /NVEN TOR Gusmr fLME/V Patented Dec. 17, 1929 UNITED STATES PATENT OFFICE GUST-AI w. ELIE-N, OI LEONIA, NEW JERSEY, ASSIGNOB T BELL TELEPHONE LLIBOBA- 'ronms, INCORPORATED, OF NEW YORK, N. Y., A CORPORATION OF NEW YORK MAGNETIC sum. up nrrnmxcn Application Med December 28, 1927, Serial No. 8,008, and Greatlritain August 29, 1927.
This invention relates to magnetic alloys and has particular reference to magnetic alloys of high permeability.
A usual assumption is that among the magnetic alloys of iron and cobalt, those compositions having the approximate proportions of iron and cobalt represented by the chemical formula Fe co, have the highest permeabilities in the range of ma netizing forces commonly described as mo erate magnetizing forces, i. e., from 5 to 75 c. s. units. It has been found that alloys 0 iron and cobalt, having the proportions of iron and 50% cobalt, have a permeability extremely high in the range of magnetizing forces from 5 to 7 5 c. g. s. units. Such alloys also exhibit very high flux densities at saturation. Alloys having from 40% to iron and the rest cobalt exhibit similar properties.
In order to develop such (properties the compositions are heat treate A suitable heat treatment consists in maintaining the alloy at about 1100 C. for from two to three hours, followed by fairly slow cooling in the furnace. However, the heat treatment is not extremel critical and may be varied considerably wlth satisfactory results.
Magnetic compositions made from ordinary commercially pure iron and cobalt in the proportions of 50% iron and 50% cobalt heat treated at atmospheric pressure and in ordinary air have been prepared and found to have a flux density of about 17,400, 21,700, and 22,000 gauss at magnetizing forces of 10, 50 and 70 gauss respectively. Furthermore, at low magnetizing forces up to H=.7, such a composition is found to have a higher permeability than Armco iron. In the range of magnetizing forces above about 5 gauss, the flux densit is considerably greater than that of Armco 113011 and also considerably greater than that of magnetic compositions corresponding to the formula CoFe Although the flux densities herein given for compositions of approximately 50% iron and 50% cobalt are not much greater than those given in prior ublications relating to the alloy 001%,, it as been found that the high values of flux density'published by others for the alloy CoFe do not apply to ordinary compure or almost pure iron.
and ordinary methods ofheat treating the flux densities of com ositions of 50% iron and 50% cobalt have been found to be con siderably higher than those obtainable with composltions approximating the formula CoFe Tests also indicate that the maximum permeability, for an magnetizing force, of the iron-cobalt series has a peak at about 50% cobalt although, of course, this peak is lower than the maximum ermeability of he flux density B for H=50 also reaches an absolute maxi- -mum for the iron-cobalt series at about 50% iron. Careful measurements also indicate that the initial permeability of iron and cobalt allo s is high at about 45 to 50% cobalt. By care ul measurement, values of over 600 for the initial permeability, have been determined. An interesting fact also is that the hysteresis loss for B= 5000 reaches a minimum for the iron-cobalt series at about 50% non.
These discoveries meet with practical application in pole pieces for loud speaker magnets. In certain types of such apparatus it is desirable to produce very high flux densities across narrow gaps. By employing pole pieces conslsting of 50% iron and 50% cobalt flux densities of the order of 27,000 gauss at the pole faces. have been produced. These flux densities were produced by practically saturatin the material. At magnetizing forces be ow those required for saturation, however, the flux densities produced are exceedingly high.
The magnetic compositions just described are also useful for electromagnetic receivers. In receivers employing permanent magnets the pole pieces alone may be made of ironcobalt compositions such as herein described. When non-permanent electromagnets are employed the entire core structure may be made of the iron-cobalt magnetic composition. The diaphragm also may advantageously be made of iron-cobalt alloys of high permeability having between 40 and 60% iron.
These materials are of general utility in heavy duty relays, and similar apparatus,
particularly in cases where excessively high magnetizing forces are not desirable. Such relays for example, are commonly employed in dial or machine switching telephone systems.
The mode of application of high permeability cobalt-iron alloys to structures such as described above is indicated more definitely by reference to the accompanying drawings in which:
Fig. 1 is a cross-section of a loud speaker diaphragm and its driving magnet;
Fig. 2 is a detailed cross-section of a part of the magnet structure;
Fig. 3 illustrates the coil which is to be attached to the diaphragm on an enlarged scale;
Fig. 4 represents an electromagnetic receiver;
Fig. 5 represents a permanent magnet receiver; and
Fig. 6 is a graph of flux density B against magnetizing force H of a number of ironcobalt alloys for flux densities from zero to 34 gauss, the percentage of cobalt being indicated on each curve;
Fig. 7 is an extension to H 69 of the curves of Fig. 6;
Fig. 8 is a smooth curve drawn through various points determined by plotting flux densities B, for H=50, gauss of various iron-cobalt alloys; and
Fig. 9 is a similar smooth curve in which hysteresis losses in ergs per cu. cm. per cycle at a maximum induction of B=5000 are plotted for various iron-cobalt alloys.
Referring particularly to Fig. 1, the diaphragm 10 is supported under tension by the frame 11. The electrodynamic unit 12 is supported by the cross members of the frame. The coil 13 of the electrodynamic unit is secured to the diaphragm to drive it. The coil 13 is positioned between the annular pole faces 14 and 15 of the magnetic structure. The polarizing winding 16 is positioned within and substantially fills the hollow magnetic structure. The brass ring 23 serves to support the winding. The main body 17 of the magnet structure may consist of any suitable magnetic material. The pole pieces 14 and 15, more particularly illustrated in Fig. 2, are annular and are constructed of high permeability cobalt-iron allow having about 50% iron. The annular gap between the pole pieces is made very small. The coil 13 is made of a thin ribbon conductor preferably of copper and of the order of .002 thick and .014" Wide, wound so that the plane of the ribbon is perpendicular to the axis of the coil. The adjacent turns of the ribbon conductor are insulated from each other by bakelite. This is applied by dissolving the bakelite in acetone and then drying the coil after the conductor is applied.
The coil 13 with a part broken away is illustrated in Fig. 3 on a still more enlarged scale.
In such arrangements, flux densities of the order of 27,000 gauss have been observed at the pole faces. Such high flux densities exceed those which it has been found possible to produce in such apparatus with previously used magentic materials and hence increase the effectiveness of the loud speaker device. Flux densities of 22,000 are attained at a magnetizing force of 11 60. This latter represents a practical operating condition.
Fig. 4 represents an electromagnetic receiver in which the magnetic core 18 consists of a body of material having about 50% iron and 50% cobalt heat treated to have high permeability. The winding 19 is applied in the usual manner. The diaphragm 20 may also advantageously be constructed of a mag netic material of 50% iron and 50% cobalt.
In Fig. 5, which represents a receiver having a permanent magnet, the permanent magnet 21 may consist of any suitable magnetic material. The core portions 22 to which the magnetizing windings are applied consist of high permeability cobalt-iron alloys attached to the permanent magnet in any suitable manner. The diaphragm 20 may also advantageously be composed of an alloy similar to that of the cores 22.
The data given hereinafter is taken from tests on specimens all of which were given approximately theheat treatment mentioned in the early part of this specification although no unusual precautions were taken to make the treatments identical.
Figs. 6 and 7 are graphs based upon carefully compiled experimental data. It will be seen that an alloy of as nearly 50% iron- 50% cobalt as was practicable to prepare had a flux density above 34% cobalt over practically the entire range of magnetizing forces for which measurements are indicated. At H=10 the flux for the 50% composition is about 30% higher than for the 34% cobalt composition. At H=5.5 to above H=69 the 50% composition has a greater flux density than iron. The same statements apply for compositions in the immediate region of 50% cobalt. At 60% cobalt and 40% cobalt it will be seen that the superiority of the compositions with respect to both 34% (lo-66% Fe and pure iron is less marked'and applies to a lesser portion of the range of magnetizing forces. The magnetizing curve of 50% (lo-50% Fe remains above those of pure iron and 34% (lo-66% Fe until magnetizing forces of several hundred gauss are reached.
Fig. 8 serves to show graphically that the flux density for H=50 is decidedly greater for 50% (lo-50% Fe than for any other tested member of the iron-cobalt series from pure iron ,to almost pure cobalt.
Fig. 9 indicates a decided hysteresis minimum in the iron-cobalt series at 50% Fe-50% Co for a flux density of 5,000 gauss. On this curve a few points were calculated by means of Steinmetz formula, from hysteresis cycles taken at slightly greater flux densltles. The results are no doubt quite close to those which would be obtained by using the same maximum flux density in each instance.
The following figures on initial ermeabilities of the iron-cobalt series were etermined experimentally A decided peak at 50% cobalt is evident. This indicates that the material may be better than iron for technical applications involving the employment of magnetizing forces of very low value, i. e. in the neighborhood of H=O, for example, in continuous loading of signaling conductors.
\Vhat is claimed is:
1. A magnetic composition comprising between 40 and 60% cobalt and the balance iron having a permeability above that of Armco iron at a corresponding magnetizing force.
2. A magnetic composition comprising approximately 50% iron and approximately 50% cobalt ieat treated to have apermeability higher than that of Armco iron at a corresponding magnetizing force.
3. An electromagnetic apparatus such as a loud speaker, telephone receiver or heavy duty relay, having a magnetic circuit consisting in whole or part, and preferably in a part adjacent an air-gap, of a magnetic composition consisting of 40 to 60% cobalt and the balance iron.
In witness whereof, I hereunto subscribe my name this 21st day of December, 1927.
GUSTAF \V. ELMEN.
US243008A 1927-08-29 1927-12-28 Magnetic material and appliance Expired - Lifetime US1739752A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2576679A (en) * 1939-08-02 1951-11-27 Electro Chimie Metal Permanent magnet and method of manufacture thereof
US2790948A (en) * 1951-06-19 1957-04-30 Lear Inc Magnetic modulator systems
US3166408A (en) * 1961-11-16 1965-01-19 Westinghouse Electric Corp Magnetic alloys
US3390443A (en) * 1964-10-20 1968-07-02 Bell Telephone Labor Inc Magnetic material and devices utilizing same
US3422407A (en) * 1964-10-20 1969-01-14 Bell Telephone Labor Inc Devices utilizing a cobalt-vanadium-iron magnetic material which exhibits a composite hysteresis loop
US4170498A (en) * 1973-12-26 1979-10-09 Texas Instruments Incorporated Transducer
US4208254A (en) * 1976-09-22 1980-06-17 Satoshi Ichioka Method of plating an iron-cobalt alloy on a substrate
US20040164571A1 (en) * 2003-02-06 2004-08-26 Gianandrea Pedrazzini Gripping device capable to grip a vial or other containers without using mechanical fingers or other mechanical gripping devices
DE102018118207A1 (en) 2017-07-31 2019-01-31 Taiwan Powder Technologies Co., Ltd Samarium-containing soft magnetic alloys

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2576679A (en) * 1939-08-02 1951-11-27 Electro Chimie Metal Permanent magnet and method of manufacture thereof
US2790948A (en) * 1951-06-19 1957-04-30 Lear Inc Magnetic modulator systems
US3166408A (en) * 1961-11-16 1965-01-19 Westinghouse Electric Corp Magnetic alloys
US3390443A (en) * 1964-10-20 1968-07-02 Bell Telephone Labor Inc Magnetic material and devices utilizing same
US3422407A (en) * 1964-10-20 1969-01-14 Bell Telephone Labor Inc Devices utilizing a cobalt-vanadium-iron magnetic material which exhibits a composite hysteresis loop
US4170498A (en) * 1973-12-26 1979-10-09 Texas Instruments Incorporated Transducer
US4208254A (en) * 1976-09-22 1980-06-17 Satoshi Ichioka Method of plating an iron-cobalt alloy on a substrate
US20040164571A1 (en) * 2003-02-06 2004-08-26 Gianandrea Pedrazzini Gripping device capable to grip a vial or other containers without using mechanical fingers or other mechanical gripping devices
US7004523B2 (en) * 2003-02-06 2006-02-28 E. Viridis S.A. Gripping device capable to grip a vial or other containers without using mechanical fingers or other mechanical gripping devices
DE102018118207A1 (en) 2017-07-31 2019-01-31 Taiwan Powder Technologies Co., Ltd Samarium-containing soft magnetic alloys
US10982305B2 (en) 2017-07-31 2021-04-20 Taiwan Powder Technologies Co., Ltd. Samarium-containing soft magnetic alloys

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