US1718012A - Artificial board and its manufacture - Google Patents
Artificial board and its manufacture Download PDFInfo
- Publication number
- US1718012A US1718012A US222938A US22293827A US1718012A US 1718012 A US1718012 A US 1718012A US 222938 A US222938 A US 222938A US 22293827 A US22293827 A US 22293827A US 1718012 A US1718012 A US 1718012A
- Authority
- US
- United States
- Prior art keywords
- binder
- board
- water
- plant
- natural
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title description 4
- 239000011230 binding agent Substances 0.000 description 55
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 46
- 239000000463 material Substances 0.000 description 35
- 241000196324 Embryophyta Species 0.000 description 34
- 238000000034 method Methods 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 10
- 238000010411 cooking Methods 0.000 description 10
- 229920006395 saturated elastomer Polymers 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000003153 chemical reaction reagent Substances 0.000 description 8
- 239000007859 condensation product Substances 0.000 description 6
- 230000002940 repellent Effects 0.000 description 6
- 239000005871 repellent Substances 0.000 description 6
- 240000008042 Zea mays Species 0.000 description 5
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 5
- 235000005822 corn Nutrition 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000012745 toughening agent Substances 0.000 description 5
- 150000002989 phenols Chemical class 0.000 description 4
- 229920001131 Pulp (paper) Polymers 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 235000017060 Arachis glabrata Nutrition 0.000 description 2
- 244000105624 Arachis hypogaea Species 0.000 description 2
- 235000010777 Arachis hypogaea Nutrition 0.000 description 2
- 235000018262 Arachis monticola Nutrition 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 240000000111 Saccharum officinarum Species 0.000 description 2
- 235000007201 Saccharum officinarum Nutrition 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 235000020232 peanut Nutrition 0.000 description 2
- 239000011295 pitch Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000010902 straw Substances 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- 241000609240 Ambelania acida Species 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 240000001398 Typha domingensis Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229960000443 hydrochloric acid Drugs 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011276 wood tar Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21J—FIBREBOARD; MANUFACTURE OF ARTICLES FROM CELLULOSIC FIBROUS SUSPENSIONS OR FROM PAPIER-MACHE
- D21J1/00—Fibreboard
- D21J1/08—Impregnated or coated fibreboard
Definitions
- the present invention relates to artificial board and its manufacture, and more especially to an insulating board made of matted cellulose plant fibres having air spaces so as to serve as an ellicient heat insulator.
- the board is made from the fibres of plants which contain a natural binding material which may be converted into a waterproof binder by suitable reagents, as hereinafter described.
- This application is directed particularly to the toughening of such binder by the addltion of some tough water-resisting substance, such as a pitch, which makes the board tougher and less brittle.
- the present invention is in the nature of a modification of an improvement on artificial board and its manufacture as developed by Clarence C. Vogt and covered by an application filed by him of even date herewith, Serial No, 222,937. In order to explain the present invention, it will be first necessaryto outline the Vogt process. Certain plantnaterials of the character hereinafter described contain a natural binding material which may be made the basis of a waterproof binder of the completed board.
- plant materials of this character are cooked with Water to partially dissolve the natural binder of the plant fibres and the material 1s mechanically disintegrated so as to produce a fibrous mass which is saturated with the water solution containing the natural binder.
- This mass is treated with a suitable reagent, such, for example, as a phenolic compound, which will convert the water soluble natural blnder into a water insoluble binder, and the mass is formed into board form and so treated, as by baking, to set the binder and form the completed board product.
- the binding material is allowed to remain with the fibres to serve as the basis of the waterproof binder of the completed board.
- the binder thus formed serves to unite the fibres into a stiff structurally strong board but with a considerable number of minute spaces between the fibres in which air is entrapped and held so that the board is particularly useful as a heat insulating building material.
- Plant materials other than the wood of usual trees have been found satisfactory as a basis. For example, corn stalks, corn cobs, straw, sugar cane bagasse, oat hulls, peanut Application filed September 29, 1927. Serial No. 222,938.
- shells cat tails, salt hay, peat moss and the like, may be used.
- Matcrials such as wood pulp made from ordinary pulp making trees do not contain such binder er which cements together the plant fibres.
- This binder after the cooking treatment with water, may be converted into a water insoluble or diflicultly soluble binder by a treatment with a suitable chemical reagent, such, for example, as a phenol, which forms upon suitable treatment, such as heating, a resinlike condensation product.
- a suitable chemical reagent such as a phenol
- any part of the plant may be used so long as it contains the fibrous cellulose material and the natural binder.
- the corn stalks including the leaves, as harvested from the cornfields, may be used.
- the material is first preferably cut up into convenient size for handling and is cooked with water, in the form of either hot water or steam (water vapor). Therefore, when we speak of cooking or treating with water, we intend to include water either in the liquid state or in the vapor state (steam).
- This cooking treatmeant is preferably carried out in an autoclave under pressure at a temperature between 140 and 180 centigrade for half an hour to an hour, either using water which is heated in the autoclave or admitting steam under pressure into the autoclave.
- the water either in the form of hot water or steam at these temperatures dissolves or partially dissolves and decomposes the pentosans and other organic compounds which serve as the natural binder of the cellulose fibres in the plant.
- This treatment does not decompose or weaken the cellulose fibres, as is the case where chemiruls are used to remove the binder as has been the usual commercial practice in preparing tibrcs for. making boards of this type.
- This cooking treatment softens the material so that the fibres are readily separated by suitable mechanical means, as for example, by
- binding material has adhesive qualities, as may be demonstrated by separating the water solution and boiling it down to a syrup-like consistency.
- the binding material is readily soluble in water and would not in its form as roduced by the cooking operation be satis actory where a waterproof binder is desired, as in an insulating board.
- the fibrous mass saturated with the water solution containing the natural binding material of the plant is treated with a suitable reagent to render the binding material waterinsoluble.
- a suitable reagent for this purpose Vogt prefers to use a phenolic compound containing the characteristic phenolic OH group, together with a suitable condensing agent, such as hydro chloric acid, ammonium chloride or the like,
- reagents are preferably added to the mass before it is formed into board form, although our process is not to be limited to any particular sequence of such steps unless so specifically stated.
- the phenolic body and the condensing agent are thoroughly mixed with the fibrous mass or pulp, which is then made into board form by the usual insulating board making machinery. This operation mats the fibres together to form the fibre board.
- the excess solution may be drained ofi' from the pulp during the board making operation, although it is preferable to allow as much as possible of the solution containing the natural binder to remain in the board.
- the board thus formed is baked to drive oil the water and convert the natural binder into a water insoluble binder.
- the natural binder Under the action of heat and the condensing agent, the natural binder combines with the phenolic compound used to form a resin-like water insoluble con- 'dcnsat ion product, which serves to bind to-.
- the Vogtprocess is modified by the addition to the mixture containin the solution of the natural binder, phenolic body and condensing agent, of some tou h insoluble substance, preferably a pitch-1i e material such as stearin pitch, petroleum pitch, Wax tailings. asphalt.
- coal tar, wood tar, or similar materials which does not interfere with the formation of the resinous binder but does improve its toughness. These materials may be added either with the addition of the phenolic compound before or after. Materials such as those specified do not interfere with the condensing reaction which takes place be tween the natural binding material or the phenol. They also tend to improve the water repelling properties of the board, as well as toughening the board makingit less stiff and )rittle.
- fillers may be used.
- organic fillers such as wood pulp, paper pulp which do not contain the natural binder, or materials such as sugar cane residue, peanut hulls, corn cobs, and the like, which-may contain a natural binder but which have not been cooked to render such binder available, or even inorganic materials, such as mineral Wool, asbestos, or the like, may be added in various percentages, do pending upon the amount of binder yielded by the plant material being used in excess of that necessary to bind it own fibres in the completed board.
- a fire retarding board may be rendered resist-ant to fire by treatment with ammonium sulphate or ammonium phosphate or other well known fire preventing agents. fere with the process of manufacture as herein outlined.
- This treatment does not interof steps, but may be otherwise embodied and prises cooking the plant material and mechanicall separating the fibres so as to produce a fibrous mass saturated with a water solution containing a natural binder of the plant fibres, adding to the mass a phenolic body toegther with a water insoluble toughenin agent and forming it into board form, and baking the board to form a water repellent phenolic condensation product from the natural binder.
- the process of making board from plants of the character described, wh ch comprises forming from the plant material a d sintegrated fibrous pulpy mass saturated with a water solution containing the natural binder of the plant, and adding to the mass a reagent which converts the natural binder of the plant into a water repellent binder for the board together with a pitch-like water insoluble agent which toughens the binder.
- An artificial board containing matted fibres cemented together with a phenolic condensation product of the natural binder of the plant material employed, and containing a water insoluble toughening agent.
Description
Patented June l8, 1929.
UNITED STATES PATENT OFFICE.
CLARENCE c. VOGT AND'ERNEST J. Pmrnn. or HADDONFIELD, NEW JERSEY, As SIGNORB T0 anmszmono coax COMPANY, or PITTSBURGH, PENNSYLVANIA, A
CORPORATION OF PENNSYLVANIA.
ARTIFICIAL BOARD AND ITS MANUFACTUBIE.
llo Drawing.
The present invention relates to artificial board and its manufacture, and more especially to an insulating board made of matted cellulose plant fibres having air spaces so as to serve as an ellicient heat insulator. The board is made from the fibres of plants which contain a natural binding material which may be converted into a waterproof binder by suitable reagents, as hereinafter described. This application is directed particularly to the toughening of such binder by the addltion of some tough water-resisting substance, such as a pitch, which makes the board tougher and less brittle.
The present invention is in the nature of a modification of an improvement on artificial board and its manufacture as developed by Clarence C. Vogt and covered by an application filed by him of even date herewith, Serial No, 222,937. In order to explain the present invention, it will be first necessaryto outline the Vogt process. Certain plantnaterials of the character hereinafter described contain a natural binding material which may be made the basis of a waterproof binder of the completed board.
According to the Vogt process, plant materials of this character are cooked with Water to partially dissolve the natural binder of the plant fibres and the material 1s mechanically disintegrated so as to produce a fibrous mass which is saturated with the water solution containing the natural binder. This mass is treated with a suitable reagent, such, for example, as a phenolic compound, which will convert the water soluble natural blnder into a water insoluble binder, and the mass is formed into board form and so treated, as by baking, to set the binder and form the completed board product. The binding material is allowed to remain with the fibres to serve as the basis of the waterproof binder of the completed board. The binder thus formed serves to unite the fibres into a stiff structurally strong board but with a considerable number of minute spaces between the fibres in which air is entrapped and held so that the board is particularly useful as a heat insulating building material.
Plant materials other than the wood of usual trees have been found satisfactory as a basis. For example, corn stalks, corn cobs, straw, sugar cane bagasse, oat hulls, peanut Application filed September 29, 1927. Serial No. 222,938.
shells, cat tails, salt hay, peat moss and the like, may be used. These materials, and particularly materials such as corn stalks and straw, contain a natural binder which may be partially dissolved or decomposed by cooking with water, either hot water or steam,
and which serves as the basis for the waterproof binder of the completed board. Matcrials such as wood pulp made from ordinary pulp making trees do not contain such binder er which cements together the plant fibres.
This binder, after the cooking treatment with water, may be converted into a water insoluble or diflicultly soluble binder by a treatment with a suitable chemical reagent, such, for example, as a phenol, which forms upon suitable treatment, such as heating, a resinlike condensation product.
According to the preferred Vogt process, any part of the plant may be used so long as it contains the fibrous cellulose material and the natural binder. For example, the corn stalks, including the leaves, as harvested from the cornfields, may be used. The material is first preferably cut up into convenient size for handling and is cooked with water, in the form of either hot water or steam (water vapor). Therefore, when we speak of cooking or treating with water, we intend to include water either in the liquid state or in the vapor state (steam). This cooking treatmeant is preferably carried out in an autoclave under pressure at a temperature between 140 and 180 centigrade for half an hour to an hour, either using water which is heated in the autoclave or admitting steam under pressure into the autoclave. The water either in the form of hot water or steam at these temperatures dissolves or partially dissolves and decomposes the pentosans and other organic compounds which serve as the natural binder of the cellulose fibres in the plant. This treatment does not decompose or weaken the cellulose fibres, as is the case where chemiruls are used to remove the binder as has been the usual commercial practice in preparing tibrcs for. making boards of this type. This cooking treatment softens the material so that the fibres are readily separated by suitable mechanical means, as for example, by
rolling or beating in a beater, grinding in a rod mill, treating in a Jordan engine, or the like; Such treatment reduces the material into a fibrous mass, which is saturated with the water solution containing the natural plant binder. The solution is allowed to remain in the mass, so that the fibres are kept in contact and are saturated with the solution containing the natural plant binder. The natural binding material may be either dissolved in water without chemical change or may be partially decomposed by the cooking operation. The actual chemical formulae and constitution of the substance as they exist in the water solution are notknown since they apparently consists of many complex compounds.
These materials have adhesive qualities, as may be demonstrated by separating the water solution and boiling it down to a syrup-like consistency. The binding material, however, is readily soluble in water and would not in its form as roduced by the cooking operation be satis actory where a waterproof binder is desired, as in an insulating board.
The fibrous mass saturated with the water solution containing the natural binding material of the plant, is treated with a suitable reagent to render the binding material waterinsoluble. For this purpose Vogt prefers to use a phenolic compound containing the characteristic phenolic OH group, together with a suitable condensing agent, such as hydro chloric acid, ammonium chloride or the like,
which will react with the natural binding material to form an insoluble resinous condensation product when subjected to heat.
These reagents are preferably added to the mass before it is formed into board form, although our process is not to be limited to any particular sequence of such steps unless so specifically stated. In the preferred process, the phenolic body and the condensing agent are thoroughly mixed with the fibrous mass or pulp, which is then made into board form by the usual insulating board making machinery. This operation mats the fibres together to form the fibre board. The excess solution may be drained ofi' from the pulp during the board making operation, although it is preferable to allow as much as possible of the solution containing the natural binder to remain in the board.
The board thus formed is baked to drive oil the water and convert the natural binder into a water insoluble binder. Under the action of heat and the condensing agent, the natural binder combines with the phenolic compound used to form a resin-like water insoluble con- 'dcnsat ion product, which serves to bind to-.
may he carried out in ovens or other suitable devices, but care should be taken not to overheat the material during baking so as to Weaken or char the fibres or the binder. It has been found safe to heat up to about 160 centi grade, although a somewhat lower temperature at longertimes is referable. The board as thus produced by t to Vogt process, while a good board, possesses the disadvantage of being somewhat brittle. According to our improvement, the Vogtprocess is modified by the addition to the mixture containin the solution of the natural binder, phenolic body and condensing agent, of some tou h insoluble substance, preferably a pitch-1i e material such as stearin pitch, petroleum pitch, Wax tailings. asphalt. coal tar, wood tar, or similar materials, which does not interfere with the formation of the resinous binder but does improve its toughness. These materials may be added either with the addition of the phenolic compound before or after. Materials such as those specified do not interfere with the condensing reaction which takes place be tween the natural binding material or the phenol. They also tend to improve the water repelling properties of the board, as well as toughening the board makingit less stiff and )rittle.
In making the board, fillers may be used.
For example, organic fillers such as wood pulp, paper pulp which do not contain the natural binder, or materials such as sugar cane residue, peanut hulls, corn cobs, and the like, which-may contain a natural binder but which have not been cooked to render such binder available, or even inorganic materials, such as mineral Wool, asbestos, or the like, may be added in various percentages, do pending upon the amount of binder yielded by the plant material being used in excess of that necessary to bind it own fibres in the completed board. When such filling material is added, it is mixed with the pulp-like mass containing the plant fibres and saturating solution, so that the fibres of the filler become also saturated with the natural binder obtained from the plant, and upon condensation of the hinder the whole mass is bound together.
If a fire retarding board is desired, it may be rendered resist-ant to fire by treatment with ammonium sulphate or ammonium phosphate or other well known fire preventing agents. fere with the process of manufacture as herein outlined.
While we have specifically described the preferred embodiment of our invention, it is to be understood that the invention is not limited to the described details or sequence This treatment does not interof steps, but may be otherwise embodied and prises cooking the plant material and mechanicall separating the fibres so as to produce a fibrous mass saturated with a water solution containing a natural binder of the plant fibres, adding to the mass a phenolic body toegther with a water insoluble toughenin agent and forming it into board form, and baking the board to form a water repellent phenolic condensation product from the natural binder.
2. The process of making board from plants of the character described, which comprises cooking the plant material and mechanically separating the fibres so as to produce a fibrous mass saturated with a water solution containing the natural binder of the plant fibres, adding to the mass a phenolic body, a condensing agent and a water insoluble toughening agent and forming it into board form, and baking the board to form a water insoluble condensation product binder containing a toughened water insoluble phenolic condensation product binder from the water soluble natural binder.
3. The process of making board from plants of the character described, which comprises cooking the plant material and mechanicall separating the fibres so as to produce a fi rous mass saturated with a water 1 solution containing the natural binder of the plant fibres, and treating the mass so formed with a reagent which converts the natural plant binder into a water repellent binder, and also adding to the mass a pitchlike water insoluble material which serves as a toughening agent for the binder.
4. The process of making board from plants of the character described, which cor n prises forming from the plant material a disintegrated fibrous pulpy mass saturated with a water solution containing the natural binder of the plant, and adding to the mass a reagent which converts the natural binder of the plant into a water repellent binder for the board together with an agent which toughens the binder.
5. The process of making board from plants of the character described, wh ch comprises forming from the plant material a d sintegrated fibrous pulpy mass saturated with a water solution containing the natural binder of the plant, and adding to the mass a reagent which converts the natural binder of the plant into a water repellent binder for the board together with a pitch-like water insoluble agent which toughens the binder.
6. An artificial board containing fibres cemented together with a water repellent binder formed from the natural binder of the fibrous plant material employed and containing a toughening agent.
7 An artificial board containing fibres cemented together with a water repellent binder formed from the natural binder of the fibrous plant material employed and containing a pitch-like water insoluble toughening agent.
8. An artificial board containing matted fibres cemented together with a phenolic condensation product of the natural binder of the plant material employed, and containing a water insoluble toughening agent.
In testimony whereof we have hereunto set our hands.
CLARENCE o. voo'r. ERNEST J. PIEPER.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US222938A US1718012A (en) | 1927-09-29 | 1927-09-29 | Artificial board and its manufacture |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US222938A US1718012A (en) | 1927-09-29 | 1927-09-29 | Artificial board and its manufacture |
Publications (1)
Publication Number | Publication Date |
---|---|
US1718012A true US1718012A (en) | 1929-06-18 |
Family
ID=22834345
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US222938A Expired - Lifetime US1718012A (en) | 1927-09-29 | 1927-09-29 | Artificial board and its manufacture |
Country Status (1)
Country | Link |
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US (1) | US1718012A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2574785A (en) * | 1951-11-13 | Ingredient of adhesives and a | ||
US3892706A (en) * | 1969-02-06 | 1975-07-01 | Jetzer Eng Ag | Method of processing refuse for conversion into shaped bodies |
US4665993A (en) * | 1985-06-12 | 1987-05-19 | Balassa Leslie L | Hydrated fibrous mats |
-
1927
- 1927-09-29 US US222938A patent/US1718012A/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2574785A (en) * | 1951-11-13 | Ingredient of adhesives and a | ||
US3892706A (en) * | 1969-02-06 | 1975-07-01 | Jetzer Eng Ag | Method of processing refuse for conversion into shaped bodies |
US4665993A (en) * | 1985-06-12 | 1987-05-19 | Balassa Leslie L | Hydrated fibrous mats |
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