US171753A - Improvement in treating leather - Google Patents
Improvement in treating leather Download PDFInfo
- Publication number
- US171753A US171753A US171753DA US171753A US 171753 A US171753 A US 171753A US 171753D A US171753D A US 171753DA US 171753 A US171753 A US 171753A
- Authority
- US
- United States
- Prior art keywords
- skins
- leather
- hides
- gelatine
- tanning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000010985 leather Substances 0.000 title description 19
- 239000001828 Gelatine Substances 0.000 description 15
- 229920000159 gelatin Polymers 0.000 description 15
- 235000019322 gelatine Nutrition 0.000 description 15
- 238000000034 method Methods 0.000 description 12
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 5
- 239000001263 FEMA 3042 Substances 0.000 description 5
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 5
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 5
- 229940033123 tannic acid Drugs 0.000 description 5
- 235000015523 tannic acid Nutrition 0.000 description 5
- 229920002258 tannic acid Polymers 0.000 description 5
- 241001465754 Metazoa Species 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000011148 porous material Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 1
- 241000208225 Rhus Species 0.000 description 1
- 235000014220 Rhus chinensis Nutrition 0.000 description 1
- 241000490025 Schefflera digitata Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 239000003212 astringent agent Substances 0.000 description 1
- 244000309466 calf Species 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000037336 dry skin Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000015250 liver sausages Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
Definitions
- leather is a combination of tannic acid, or any other substance which is capable of precipitating gelatine, with the gelatine of the tissues-of skins and hides of animals. I, therefore, first thoroughly tan the skins and hides in any of the ordinary ways now known and practiced. I then soak them, when dry or partially so, in a solution of gelatine, and retan them in any tanning-liquor which is capable of precipitating the same. This produces a new leathery compound in the pores of skins and hides, and unites it firmly to the already tanned tissues, by which means the whole body of the leather becomes greatly improved in thickness, firmness, strength, and durability.
- the skins of small animals such as deer-skins, goat-skins, sheep-skins, and calf-skins, are
- Sole-leather is also rendered heavier, thicker, and more durable by this method of tannage; besides, the thin and elastic parts of the skins and hides of all animals are capable of being thickened up into leather as solid and firm as the better portions of the same.
- Sheep-skins especially, may be made to possess a solidity, and smoothness, and firmness of surface so nearly approximating to calves skins as not to be easily distinguished from them.
- Skins and hides may first be tanned in alum and salt, or other astringents, and then filled with a solution of gelatine and retanned in the same tanning-liquors, or in those stronger and better. By this means the skins and hides are tanned quick, and the pores are opened to receive the gelatinous solution; then be made.
- the stronger bark liquors more readily saturate the same and precipitate the liquid gelatine soaked into them, and the new leathery compound is firmly and permanently united into one homogeneous body.
- My preference is to tan goat-skins, sheep-skins, and calfskins, in the first instance, with sumac, and then partially dry them, and soak them in gelatine, and retan them with oak-bark liquor at the common temperature, without the aid of any chemicals.
- the gelatine which I employ for this purpose I make from the ordinary sources of glue. I prefer to take, however, the legs, and pates, and trimmings of skins and hides, and boil them into a tolerably thick solution.
- This solution I keep liquid in a mauner not necessary to mention in this specification.
- the tanned or partially-tanned skins and hides When the tanned or partially-tanned skins and hides are immersed in it, it should be only milk-warm. It should be a thick solution, in order that the dry or partially dry skins and hides may soak up a considerable quantity. As soon as they are thoroughly saturated, they should be immediately put into a strong solution of tanning-liquor, at the common temperature, without chemicals, and thoroughly tanned in the usual way. Oakbark liquor in strong solution I greatly prefer for this purpose. If one treatment is not sufficient, a second or even a third saturation and tannage of the same skins and hides may It is possible in this way to make leather of any required thickness and strength.
- gelatine has been employed in the process of tanning raw skins and hides, but only concurrently with the said tanning process; but this use of gelatine I believe retards the tanning process, by coating the untanncd tissues with the same, and thus interposing a foreign body between the tannic acid and the gelatine of the said tissues. This prevents contact of the said acid and tissues, and hinders the tanning of the same; besides this, a great loss of tannic acid and gelatine results from this useof gelatine during the process of tanning raw skins and hides. This leathery compound, thus prematurely made, will not adhere to the untanned tissues and make firm leather. My process is contra-distinguished from this use of gelatine in this respect. I first tan in a thorough manner, and
- M Mr WWWWMW The refuse portions of skins and hides may thus be converted into good leather, and added to the already tanned parts.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Description
UNITED STATES PATENT OFFICE.
HENRY W. ADAMS, OF PHILADELPHIA, PENNSYLVANIA.
IMPROVEMENT IN; TREATING LEATHER.
v Specification forming part of Letters Patent No. 171,753., dated J auuary 4, 1876; application filed September 27, 1875).
To all whom it may concern:
Be it-known that I, HENRY W. ADAMS, of the city and county of Philadelphia, and State of Pennsylvania, have invented a new and useful Process of Treating Leather, which is fully set forth in the following specification; the object of which is to increase its weight, its firmness, and durability, with special reference to a lighter class of leather, but adapted to improve leather of all grades and weights. The object of my invention is to improve the quality of leather'by giving weight, firmness, toughness, and durability to skins and hides of animals by means of a new and improvedprocess of manufacturing and tanning the same.
Leather is a combination of tannic acid, or any other substance which is capable of precipitating gelatine, with the gelatine of the tissues-of skins and hides of animals. I, therefore, first thoroughly tan the skins and hides in any of the ordinary ways now known and practiced. I then soak them, when dry or partially so, in a solution of gelatine, and retan them in any tanning-liquor which is capable of precipitating the same. This produces a new leathery compound in the pores of skins and hides, and unites it firmly to the already tanned tissues, by which means the whole body of the leather becomes greatly improved in thickness, firmness, strength, and durability. The skins of small animals, such as deer-skins, goat-skins, sheep-skins, and calf-skins, are
thus rendered more valuable and suitable for new and important uses. Sole-leather is also rendered heavier, thicker, and more durable by this method of tannage; besides, the thin and elastic parts of the skins and hides of all animals are capable of being thickened up into leather as solid and firm as the better portions of the same. Sheep-skins, especially, may be made to possess a solidity, and smoothness, and firmness of surface so nearly approximating to calves skins as not to be easily distinguished from them.
Skins and hides may first be tanned in alum and salt, or other astringents, and then filled with a solution of gelatine and retanned in the same tanning-liquors, or in those stronger and better. By this means the skins and hides are tanned quick, and the pores are opened to receive the gelatinous solution; then be made.
the stronger bark liquors more readily saturate the same and precipitate the liquid gelatine soaked into them, and the new leathery compound is firmly and permanently united into one homogeneous body. My preference is to tan goat-skins, sheep-skins, and calfskins, in the first instance, with sumac, and then partially dry them, and soak them in gelatine, and retan them with oak-bark liquor at the common temperature, without the aid of any chemicals. The gelatine which I employ for this purpose I make from the ordinary sources of glue. I prefer to take, however, the legs, and pates, and trimmings of skins and hides, and boil them into a tolerably thick solution. This solution I keep liquid in a mauner not necessary to mention in this specification. When the tanned or partially-tanned skins and hides are immersed in it, it should be only milk-warm. It should be a thick solution, in order that the dry or partially dry skins and hides may soak up a considerable quantity. As soon as they are thoroughly saturated, they should be immediately put into a strong solution of tanning-liquor, at the common temperature, without chemicals, and thoroughly tanned in the usual way. Oakbark liquor in strong solution I greatly prefer for this purpose. If one treatment is not sufficient, a second or even a third saturation and tannage of the same skins and hides may It is possible in this way to make leather of any required thickness and strength.
I am aware that gelatine has been employed in the process of tanning raw skins and hides, but only concurrently with the said tanning process; but this use of gelatine I believe retards the tanning process, by coating the untanncd tissues with the same, and thus interposing a foreign body between the tannic acid and the gelatine of the said tissues. This prevents contact of the said acid and tissues, and hinders the tanning of the same; besides this, a great loss of tannic acid and gelatine results from this useof gelatine during the process of tanning raw skins and hides. This leathery compound, thus prematurely made, will not adhere to the untanned tissues and make firm leather. My process is contra-distinguished from this use of gelatine in this respect. I first tan in a thorough manner, and
by any of the known processes, my raw skins and hides. I then take these thoroughlytanned skins and hides, which now constitute marketable leather, and soak them fullof gelatine in a fluid condition, and, when "saturated and partially dried, immerse them in a bath of tannic acid, and thus fill the pores of the said leather with a leathery compound. which unites with the already tanned tissues, and produces one homogeneous body. This process may be repeated as many times as may be desirable, to give any degree of thickness, weight, firmness, and durability to the leather. Thin leather is thus rendered more impervious to water, and sheep-skins saturated with gelatine;mauufactured from the refuse of tougher and firmer skins and hides are greatly improved. I add great weight and value to sole-leatherin a short time by this process.
M Mr WWWWMW The refuse portions of skins and hides may thus be converted into good leather, and added to the already tanned parts. I can treat leather by my process which has been tannedbyoth" ers and put into the market for sale'.
Having thus explained the nature and operation of my invention, what I claim, and desire to secure by Letters Patent, is
The improved process of treating leather, consisting of siturating tanned skins and hides with a gelatinous solution, and then immersing them in a bath of tannic acid, all sub stantially as and forthe purpose set forth.
HELIRY W. ADAMS.
Witnesses: I
S. S. BRooKs, ROBERT WATKIN.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US171753A true US171753A (en) | 1876-01-04 |
Family
ID=2241160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US171753D Expired - Lifetime US171753A (en) | Improvement in treating leather |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US171753A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3945792A (en) * | 1969-07-09 | 1976-03-23 | Ciba-Geigy Corporation | Process for the filling of leather and compositions therefor |
-
0
- US US171753D patent/US171753A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3945792A (en) * | 1969-07-09 | 1976-03-23 | Ciba-Geigy Corporation | Process for the filling of leather and compositions therefor |
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