US1673301A - Process of dyeing cellulose-acetate silk - Google Patents

Process of dyeing cellulose-acetate silk Download PDF

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Publication number
US1673301A
US1673301A US206123A US20612327A US1673301A US 1673301 A US1673301 A US 1673301A US 206123 A US206123 A US 206123A US 20612327 A US20612327 A US 20612327A US 1673301 A US1673301 A US 1673301A
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United States
Prior art keywords
acetate silk
dyeing cellulose
silk
dyeing
acetate
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US206123A
Inventor
Reddelien Gustav
Matzdorf Georg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Grasselli Dyestuff Corp
Original Assignee
Grasselli Dyestuff Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Grasselli Dyestuff Corp filed Critical Grasselli Dyestuff Corp
Application granted granted Critical
Publication of US1673301A publication Critical patent/US1673301A/en
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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34Material containing ester groups
    • D06P3/40Cellulose acetate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92Synthetic fiber dyeing
    • Y10S8/921Cellulose ester or ether

Definitions

  • This invention relates to processes of dye-' ing artificial silk, and particularly to dyeing artificialsilk containing cellulose acetate.
  • Dyestuffs of this kind are obtained by coupling any aromatic diazo compound with an N -dihydroxydialkyl-derivative of an aromatic amine.
  • the dyeings are remarkable for their clearness and fastness to washing, water and 0 light. They also have good level dyeing properties, producing dyeings of uniform depth and strength of coloring, which have not hitherto been observed in the known suspension dyestuffs for acetate silk.

Description

Patented June 12, 1928.
UNITED STATES PATENT OFFICE.
GUSTAV BEDDELIEN AND GEORG MATZDORF, OF LEIIPZIG, GERMANY, ASSIGNORS, BY MESNE ASSIGNMENTS, 10 GRASSELLI DYESTUFF CORPORATION, OF NEW YORK,
N. Y., .A. CORPORATION or DELAWARE.
PROCESS OF DYEING CELLULOSE-ACETATE SILK.
No Drawing. Application filed July 15, 1927, Serial No. 206,123, and in Germany July 24, 1926.
This invention relates to processes of dye-' ing artificial silk, and particularly to dyeing artificialsilk containing cellulose acetate.
We have found that artificial silk contain- 5 ing cellulose acetate may be dyed by treating the same with a suspension of an azo-dyestuff of the general formula alkyl-OH R-N=NRN alkylOH wherein R and R represent aromatic radicles of the benzene series.
Dyestuffs of this kind are obtained by coupling any aromatic diazo compound with an N -dihydroxydialkyl-derivative of an aromatic amine. y
The dyeings are remarkable for their clearness and fastness to washing, water and 0 light. They also have good level dyeing properties, producing dyeings of uniform depth and strength of coloring, which have not hitherto been observed in the known suspension dyestuffs for acetate silk.
For example, 100 parts by weight of acetate silk are dyed for 30-45 minutes at 6070 C. with addition of soap in a suspension of 7.5 parts of l-nitraniline-azo-dihydroxydiethylaniline in water and then washed for a short time. There is thus obtained a clear yellowish red.
dihydroxydietllylaniline wherein R and R represent aromatic radicles of the benzene series.
2. Process of dyeing cellulose acetate silk which comprises treating the same with an aqueous suspension of the azo dyestuff having most probably the general formula CHzCH:OH
-- \CH:CH2OH In testimonywhereof, we affix our signatures.
DR. GUSTAV REDDELIEN. GEORG MATZDORF.
US206123A 1926-07-24 1927-07-15 Process of dyeing cellulose-acetate silk Expired - Lifetime US1673301A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1673301X 1926-07-24

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US1673301A true US1673301A (en) 1928-06-12

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US206123A Expired - Lifetime US1673301A (en) 1926-07-24 1927-07-15 Process of dyeing cellulose-acetate silk

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2615013A (en) * 1950-07-21 1952-10-21 Eastman Kodak Co 2,4-bis(methylsulfonyl)-benzeneazo-n-fluoroalkyl-n-hydroxyalkylaniline compounds
US2618631A (en) * 1949-05-27 1952-11-18 Eastman Kodak Co 4-nitro-2-trifluoromethyl-benzene-azo-n-hydroxyethyl-aniline dye compounds
US2638403A (en) * 1949-01-20 1953-05-12 Yorkshire Dyeware And Chemical Dyeing of nylon with sulfonamide azo dyes

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2638403A (en) * 1949-01-20 1953-05-12 Yorkshire Dyeware And Chemical Dyeing of nylon with sulfonamide azo dyes
US2618631A (en) * 1949-05-27 1952-11-18 Eastman Kodak Co 4-nitro-2-trifluoromethyl-benzene-azo-n-hydroxyethyl-aniline dye compounds
US2615013A (en) * 1950-07-21 1952-10-21 Eastman Kodak Co 2,4-bis(methylsulfonyl)-benzeneazo-n-fluoroalkyl-n-hydroxyalkylaniline compounds

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