US1584588A - Treating lubricating oils - Google Patents

Treating lubricating oils Download PDF

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Publication number
US1584588A
US1584588A US453738A US45373821A US1584588A US 1584588 A US1584588 A US 1584588A US 453738 A US453738 A US 453738A US 45373821 A US45373821 A US 45373821A US 1584588 A US1584588 A US 1584588A
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oil
lubricating oils
lubricating
mixture
treating
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US453738A
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Acheson Edward Goodrich
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/06Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
    • C10G21/12Organic compounds only
    • C10G21/16Oxygen-containing compounds

Definitions

  • Patented Ma 11, 1926 Patented Ma 11, 1926.
  • lubricating oils of mineral origin comprise a rather complex mixture of hydrocarbon components; and it has been regarded as altogether probable that the lubricating value of the oil inheres 1n certain of these components to the exclusion of others, or at least, that the several components of the mixture are of unequal lubricating value.
  • lubricating value of the oil inheres 1n certain of these components to the exclusion of others, or at least, that the several components of the mixture are of unequal lubricating value.
  • the undissolved fraction of the oil amounting in this specific case to about 80% of the original weight, will be found to be decidedly improved in lubricating value.
  • the dissolved fraction may readily be separated from the acetone-water mixture by distilling the latter, and the recovered acetone is available for use in a repetition of the process.
  • acetone I may use other compounds, and more especially other ketonic or alcoholic bodies having a similar selective solvent action upon the components of the mineral oil.
  • the character and proportions of the solvent may of course vary according to the specific oil subjected to treatment.
  • Processof treating mineral lubricating oils to enhance their lubricating value comprising treating the same with a. select ve solvent having the essential solvent properties of a mixture of acetone and water, separating the treated oil and recovering the solvent for re-use in .the process.
  • Process of treating mineral lubricating oils to enhance their lubricating value comprising agitating the oil with a mixture containing acetone and water, settling the mixture and separating the treated oil, and recovering the acetone from the solution for Y re-use in the process.
  • Process of treating mineral lubricating oils to enhance their lubricating value comprising agitating the oil with a. selective solvent for the components of lower lubricating value, settling the mixture and separating the treated oil, and recovering the solvent from the solution for re-use in the process.

Description

Patented Ma 11, 1926.
OFFICE- EDWARD GOODRICH ACHIESON, OF NEW YORK, N. Y.
TREATING LUBRICATING OILS.
No Drawing.
It is well known that lubricating oils of mineral origin comprise a rather complex mixture of hydrocarbon components; and it has been regarded as altogether probable that the lubricating value of the oil inheres 1n certain of these components to the exclusion of others, or at least, that the several components of the mixture are of unequal lubricating value. However, so far as I am aware, but little is actually known relative to this subject-matter.
I have found that it is possible so to treat mineral lubricating oils as materially to enhance their lubricating value; and my invention comprises a. process whereby this result is attained by treating the oils with certain solvents having a selective action thereon; My preferredsolvent for this pur-' pose is a mixture of acetone and water, but my invention is notlimited thereto, inasmuch as many other solvents or liquid mixtures may prove to be equivalent for the purposes of the invention. Without limiting the invention by reference to theoretical considerations, it may be assumed that the function of the solvent is to act selectively on the oil complex, removing therefrom components of lesser lubricating value, and thereby concentrating in the residual oil the components of higher lubricating value. Irrespective of the truth of this assumption, it has been amply demonstrated in practice that the actual resultof treatment in the manner described is to effect a material improvement in the lubricating quality of the oil.
One specific embodiment of my invention is as follows, it being understood that the invention is not restricted to the particular materials or the specific proportions mentioned therein:
To 100 pounds of a mineral lubricating oil having a viscosity of 210 at 100 F. as determined bythe Saybolt viscosimete-r, I add about 100pounds of a mixture in equal proportions of acetone and water. The mixture is then thoroughly shaken or agitated at or- Application filed March 19, 1921. Serial No. 453,738.
dinary temperature and is permitted to settle, after which the two layers are parted in any suitable manner.
The undissolved fraction of the oil, amounting in this specific case to about 80% of the original weight, will be found to be decidedly improved in lubricating value. The dissolved fraction may readily be separated from the acetone-water mixture by distilling the latter, and the recovered acetone is available for use in a repetition of the process.
Instead of acetone I may use other compounds, and more especially other ketonic or alcoholic bodies having a similar selective solvent action upon the components of the mineral oil. The character and proportions of the solvent may of course vary according to the specific oil subjected to treatment.
1. Processof treating mineral lubricating oils to enhance their lubricating value, comprising treating the same with a. select ve solvent having the essential solvent properties of a mixture of acetone and water, separating the treated oil and recovering the solvent for re-use in .the process.
2. Process of treating mineral lubricating oils to enhance their lubricating value, comprising agitating the oil with a mixture containing acetone and water, settling the mixture and separating the treated oil, and recovering the acetone from the solution for Y re-use in the process.
3. Process of treating mineral lubricating oils to enhance their lubricating value, comprising agitating the oil with a. selective solvent for the components of lower lubricating value, settling the mixture and separating the treated oil, and recovering the solvent from the solution for re-use in the process.
In testimony whereof, I afiix my signature. 1
EDWARD. e. ACHESON.
US453738A 1921-03-19 1921-03-19 Treating lubricating oils Expired - Lifetime US1584588A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4028226A (en) * 1975-11-12 1977-06-07 The Lubrizol Corporation Method of rerefining oil with recovery of useful organic additives
US4302325A (en) * 1980-10-28 1981-11-24 Delta Central Refining, Inc. Solvent extraction process for rerefining used lubricating oil
US4342645A (en) * 1980-10-28 1982-08-03 Delta Central Refining, Inc. Method of rerefining used lubricating oil
US4360420A (en) * 1980-10-28 1982-11-23 Delta Central Refining, Inc. Distillation and solvent extraction process for rerefining used lubricating oil
US4399025A (en) * 1980-10-28 1983-08-16 Delta Central Refining, Inc. Solvent extraction process for rerefining used lubricating oil
US4405448A (en) * 1982-03-31 1983-09-20 Googin John M Process for removing halogenated aliphatic and aromatic compounds from petroleum products
US4491515A (en) * 1981-03-23 1985-01-01 Monash University Treating used automotive lubricating oil to reduce the content of suspended particulate matter, including lead

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4028226A (en) * 1975-11-12 1977-06-07 The Lubrizol Corporation Method of rerefining oil with recovery of useful organic additives
US4302325A (en) * 1980-10-28 1981-11-24 Delta Central Refining, Inc. Solvent extraction process for rerefining used lubricating oil
US4342645A (en) * 1980-10-28 1982-08-03 Delta Central Refining, Inc. Method of rerefining used lubricating oil
US4360420A (en) * 1980-10-28 1982-11-23 Delta Central Refining, Inc. Distillation and solvent extraction process for rerefining used lubricating oil
US4399025A (en) * 1980-10-28 1983-08-16 Delta Central Refining, Inc. Solvent extraction process for rerefining used lubricating oil
US4491515A (en) * 1981-03-23 1985-01-01 Monash University Treating used automotive lubricating oil to reduce the content of suspended particulate matter, including lead
US4405448A (en) * 1982-03-31 1983-09-20 Googin John M Process for removing halogenated aliphatic and aromatic compounds from petroleum products

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