US1500477A - Dry battery - Google Patents

Dry battery Download PDF

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Publication number
US1500477A
US1500477A US578891A US57889122A US1500477A US 1500477 A US1500477 A US 1500477A US 578891 A US578891 A US 578891A US 57889122 A US57889122 A US 57889122A US 1500477 A US1500477 A US 1500477A
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Prior art keywords
container
carton
zinc
moisture
edge
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Expired - Lifetime
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US578891A
Inventor
Henry E Warncke
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FAIRFIELD BATTERY Co
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FAIRFIELD BATTERY Co
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Application filed by FAIRFIELD BATTERY Co filed Critical FAIRFIELD BATTERY Co
Priority to US578891A priority Critical patent/US1500477A/en
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/172—Arrangements of electric connectors penetrating the casing
    • H01M50/174—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells
    • H01M50/182—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for cells with a collector centrally disposed in the active mass, e.g. Leclanché cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • CONNECTICUT ASSIGNOR TO FAIRFI'ELD BAT- TERY COMPANY, OF SOUTH NORWALK, CONNECTICUT, A CORPORATION OF DELA- IJRY BATTERY.
  • I provide the dry cell with a waterproofed carton spaced from the sides of the usual zinc container to form an annular receptacle into which moisture and salts may pass from the cell when forced out by gas pressure, this carton being sealed at the top in such manner as to control and direct the leaking moisture into this annular receptacle.
  • the dry cell illustrated in the drawing comprises a zinc container 1 lined with a layer of pulp board 2 folded over at its top to envelop a galvanically active mixture 3 of carbonaceous material, manganesedioxide, chlorides and water.
  • a carbon rod 4 surmounted by a brass cap 5'centrallypositioned on a brass post 6.
  • This post is fixed the drilled upper end of the carbon rod and has an integral flange 7 on which the ca 5 rests, and is ,also provided with a threa ed nut 8 by which a wire can be readily connected to an external circuit.
  • This sealing compound may consist essentially of a mixture of rosin and a filler such as talc, poured in while in a hot molten conditions to form a relatively tight joint with the zinc container and with the sides of the carbon rod 4.
  • a filler such as talc
  • a dry cell constructed as above described can be slipped into a snugly fitting pasteboard carton and is serviceable for use either singly or when connected up in series with other cells. It has the disadvantage, however, that when subjected to heavy service with' resultant liberation 7 of gas beneath the layer 9 of sealing compouTid, leaks are likely to develop around the edge of the layer of sealing compound through which the gases will escape. This passage of gas is accompanied by a seepage of moisture and ultimately by a creepage of crystals through the leak. It often happens that these leaks develop at the joints between the sealing compound and the zinc, but they sometimes develop adjacent to the carbon rod.
  • the leakage of moisture and the resultant formation of crystalline deposits of chlorides give to the cell an unsightly appearance and is likely to result in corroded terminals.
  • the greatest disadvantage is that the active material leaking from the container will wet the pasteboard carton, thereby imparing its insulating qualities and offering easy opportunity for leakage of the rent. from the dry cell.
  • the dry cell is placed side by side with others electrically connected to it in series rela tion, the moist carton or'cartons will form an easy path for leakage from one dry cell to the next with resultant loss of electrical energy and ultimate destruction of one or both of the cells through the short circuit.
  • the .crystalline deposits of chloride are hydroscopic in character and keep the pasteboard cartons damp even after the orlginal moisture has been evaporated.
  • the dry cell instead of being (provided with a snugly fitting pasteboar carton, is provided with a carton 10 .having an internal diameter large enough to provide an annular space 11 between the carton and the zinc container.
  • the carton 1 s waterproofed as by treatment with an asphaltum compound or a petroleum compound and is of a height somewhat greater than that of zinc container 1. .
  • the negative binding post 11' If, as is common,
  • the sealed zinc container is lowered into the carton and centered therein and then a layer of sealing compound 13 is poured in to close the end of the carton and thus seal up the annular receptacle which envelops the zinc container.
  • This sealing compound may consist of rosin and an inert filler such .as tale, about in the proportions of half and half, and is so regulated as to composition and temperature of pouring that it does not run down appreciably into the end of the receptacle, but on the contrary has its lower level substantially flush with the top of the zinc container and its upper level substantially flush with the top edge of the carton.
  • the structure above described is rugged in character and adapted for relatively rough handling during transportation and while in use.
  • the waterproofed character of the structure renders it particularly suited for use in boats and where the moisture con-- ditions are severe.
  • the cells may be placed side by side in close contact without danger of the leakage of electricity from one to the other. In this connection there is advantage in having terminal 11 positioned within the periphery of the carton.
  • a dry cell the combination with a zinc container having active galvanic materials sealed therein, of a Waterproofed carton enveloping said container and spaced therefrom to form an annular receptacle extending up'to the top of the zinc container, whereby moisture may escape overthe edge of the zinc container into said receptacle, and sealing compound closing the end of said carton; substantially as described.
  • a dry ,cell the combination with a zinc container having active galvanic materials sealed therein, of a Waterproofed carton enveloping said container and having a height somewhat greater than said container, said carton being spaced from said container to form an annular receptacle extending up to the top of the zinc container, whereby moisture may escape over the edge of the zinc container into said receptacle, and sealingcompound in contact with and closing the end of said carton, said sealin compound being in contact with the top 0 said zinc container and the upper level of said sealing compound being in contact with the upper edge of said carton.
  • a dry cell the combination of a zinc container, a carbon rod and active galvanic materials in said container, a brass cap on said carbon rod, a layer of sealing compound closing the end of said container and forming a substantially watertight joint at said carbon rod, a waterproofed carton enveloping said container and extending above the top thereof, said carton being spaced from the sides of said container to form an annular receptacle, and a' layer of sealing compound, the upper level of which is substantially flush with the upper edge of said oarton and the lower level of which is substantially flush with the upper edge of said container, said compound closing the top of said annular receptacle, but without seriously interfering with the passage of moisture over the upper edge of said zinc container into said annular receptacle.
  • a dry cell the combination of a zinc container, a carbon rod and active galvanic materials therein, a brass cap on said carbon rod, a layer of sealing compound closing the end of said container and forming a substantially watertightjoint at said rod below the top thereof, a waterproofed carton enveloping said container and extending above the nular receptacle, said compound making a relatively long stepped joint with the sides and end of said rod and with the sides of said brass cap whereby moisture driven from said container by gas pressure will find easiest escape over the ed e of said zinc container and into said annu ar receptacle.
  • a dry cell comprising a zinc container having active galvanic materials sealed therein, and a carbon electrode surmounted by a metallic cap; and an outer casing enveloping said container and forming an annular receptacle extending to the top of the container, the top of said casing being sealed so as to form moisture proof joints around said carbon electrode and cap and around the edge of the said outer casing, whereby any moisture escaping from the dry cellis confined in said annular receptacle.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hybrid Cells (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Primary Cells (AREA)

Description

July 8, 1924. 1500,47?
H. E. WARNCKE DRY BATTERY Filed Aug. 1, 1922 IN VEN TOR W. A TTORNE Y .40 tightly in Patented July 8,1924.
UNITED STATES PATENT OFFICE.
HENRY E. WARNCKE, OF NORWALK,
WARE.
CONNECTICUT, ASSIGNOR TO FAIRFI'ELD BAT- TERY COMPANY, OF SOUTH NORWALK, CONNECTICUT, A CORPORATION OF DELA- IJRY BATTERY.
Application filed August 1, 1922. Serial No. 578,891.
To all whom it may concern:
Be it lmown that I, HENRY E. WARNCKE, a citizen of the United States, residing at Norwalk, in the county of F airfield, State of Connecticut, have invented certain new and useful Improvements in Dry Batteries; and I do hereby declare the following to be a full, clear, and exact description of the invention, such as will enable others skilled in the art to which it appertains to make and use the same.
It is an object of the present invention to interior of a dry cell and to protect the 16 cell from'the harmful effect of such leakage by directing the moisture into a compartment Where it can do no harm. To attain this object I provide the dry cell with a waterproofed carton spaced from the sides of the usual zinc container to form an annular receptacle into which moisture and salts may pass from the cell when forced out by gas pressure, this carton being sealed at the top in such manner as to control and direct the leaking moisture into this annular receptacle.
The details of the invention will become clear from the following description taken in conjunction with the accompanying draw- The dry cell illustrated in the drawing comprises a zinc container 1 lined with a layer of pulp board 2 folded over at its top to envelop a galvanically active mixture 3 of carbonaceous material, manganesedioxide, chlorides and water. At the center of this mixture is a carbon rod 4 surmounted by a brass cap 5'centrallypositioned on a brass post 6. This post is fixed the drilled upper end of the carbon rod and has an integral flange 7 on which the ca 5 rests, and is ,also provided with a threa ed nut 8 by which a wire can be readily connected to an external circuit.
Immediately above the inturned edge of the pulp board lining 2 and substantially flush with the up er edge of container 1 is a layer of sealing compound 9. This sealing compound may consist essentially of a mixture of rosin and a filler such as talc, poured in while in a hot molten conditions to form a relatively tight joint with the zinc container and with the sides of the carbon rod 4. Preferably the top level of control the leakage of moisture from the I said compound edge of the carbon rod.
A dry cell constructed as above described can be slipped into a snugly fitting pasteboard carton and is serviceable for use either singly or when connected up in series with other cells. It has the disadvantage, however, that when subjected to heavy service with' resultant liberation 7 of gas beneath the layer 9 of sealing compouTid, leaks are likely to develop around the edge of the layer of sealing compound through which the gases will escape. This passage of gas is accompanied by a seepage of moisture and ultimately by a creepage of crystals through the leak. It often happens that these leaks develop at the joints between the sealing compound and the zinc, but they sometimes develop adjacent to the carbon rod. In either instance the leakage of moisture and the resultant formation of crystalline deposits of chlorides give to the cell an unsightly appearance and is likely to result in corroded terminals. However, the greatest disadvantage is that the active material leaking from the container will wet the pasteboard carton, thereby imparing its insulating qualities and offering easy opportunity for leakage of the rent. from the dry cell. the dry cell is placed side by side with others electrically connected to it in series rela tion, the moist carton or'cartons will form an easy path for leakage from one dry cell to the next with resultant loss of electrical energy and ultimate destruction of one or both of the cells through the short circuit. The .crystalline deposits of chloride are hydroscopic in character and keep the pasteboard cartons damp even after the orlginal moisture has been evaporated.
In accordance with the present invention the foregoing disadvantages are overcome in simple and eflicient manner. The dry cell, instead of being (provided with a snugly fitting pasteboar carton, is provided with a carton 10 .having an internal diameter large enough to provide an annular space 11 between the carton and the zinc container. The carton 1s waterproofed as by treatment with an asphaltum compound or a petroleum compound and is of a height somewhat greater than that of zinc container 1. .The negative binding post 11' If, as is common,
is somewhat below the top electric curof the cell is of unusual length, as shown in the drawing, and has a threaded collar 12 resting on the upper edge of the carton but not projecting substantially beyond the periphery of the carton.
In the assembly of the structure, the sealed zinc container is lowered into the carton and centered therein and then a layer of sealing compound 13 is poured in to close the end of the carton and thus seal up the annular receptacle which envelops the zinc container. This sealing compound may consist of rosin and an inert filler such .as tale, about in the proportions of half and half, and is so regulated as to composition and temperature of pouring that it does not run down appreciably into the end of the receptacle, but on the contrary has its lower level substantially flush with the top of the zinc container and its upper level substantially flush with the top edge of the carton. The result is a very strong and stepped or ofiset joint at the inner edge of the layer 13 of sealing compound and a much weaker joint around the upper edge of the zinc container. Consequently when an excessive gas pressure is developed within the zinc container, as, for instance, when the battery is being very rapidly discharged, the gas will force itself upward, not around the carbon rod where the path is long and tortuous, but out over the edge of the zinc container and into the annular receptacle within the waterproofed carton. The seepage of moisture through a leak so developed or the creepage of salt through such a leak will do no harm, for the moisture and salt will be held within the waterproofed carton through which it "cannot pass. Further moisture is not gathered up by the salt from the atmosphere and the top of the dry cellremains clean and without signs of the leakage that has actually occurred.
The structure above described is rugged in character and adapted for relatively rough handling during transportation and while in use. The waterproofed character of the structure renders it particularly suited for use in boats and where the moisture con-- ditions are severe. The cells may be placed side by side in close contact without danger of the leakage of electricity from one to the other. In this connection there is advantage in having terminal 11 positioned within the periphery of the carton.
Changes in the details of the dry cell may be made without departin from the spirit of this invention, as define by the append d claims.
I claim:
1. In a dry cell, the combination with a zinc container having active galvanic materials sealed therein, of a Waterproofed carton enveloping said container and spaced therefrom to form an annular receptacle extending up'to the top of the zinc container, whereby moisture may escape overthe edge of the zinc container into said receptacle, and sealing compound closing the end of said carton; substantially as described.
2. In a dry ,cell, the combination with a zinc container having active galvanic materials sealed therein, of a Waterproofed carton enveloping said container and having a height somewhat greater than said container, said carton being spaced from said container to form an annular receptacle extending up to the top of the zinc container, whereby moisture may escape over the edge of the zinc container into said receptacle, and sealingcompound in contact with and closing the end of said carton, said sealin compound being in contact with the top 0 said zinc container and the upper level of said sealing compound being in contact with the upper edge of said carton.
3.- In a dry cell, the combination of a zinc container, a carbon rod and active galvanic materials therein, a layer of sealing compound closing the end of said container and forming a substantially watertight joint at said rod, a waterproofed carton enveloping said container and extending above the top thereof, said carton being spaced from the sides of said container to form an annular receptacle extending up to the top of the zinc container, whereby molsture may escape over the edge of the zinc container into said annular receptacle, and sealing compound in contact with the upper edge of said carton and closing the top of said annular receptacle; substantially as described.
4;. In a dry cell, the combination of a zinc container, a carbon rod and active galvanic materials in said container, a brass cap on said carbon rod, a layer of sealing compound closing the end of said container and forming a substantially watertight joint at said carbon rod, a waterproofed carton enveloping said container and extending above the top thereof, said carton being spaced from the sides of said container to form an annular receptacle, and a' layer of sealing compound, the upper level of which is substantially flush with the upper edge of said oarton and the lower level of which is substantially flush with the upper edge of said container, said compound closing the top of said annular receptacle, but without seriously interfering with the passage of moisture over the upper edge of said zinc container into said annular receptacle.
5. In a dry cell, the combination of a zinc container, a carbon rod and active galvanic materials therein, a brass cap on said carbon rod, a layer of sealing compound closing the end of said container and forming a substantially watertightjoint at said rod below the top thereof, a waterproofed carton enveloping said container and extending above the nular receptacle, said compound making a relatively long stepped joint with the sides and end of said rod and with the sides of said brass cap whereby moisture driven from said container by gas pressure will find easiest escape over the ed e of said zinc container and into said annu ar receptacle.
6. The combination of a dry cell compris ing a zinc container having active galvanic materials sealed therein, and a carbon electrode surmounted by a metallic cap; and an outer casing enveloping said container and forming an annular receptacle extending to the top of the container, the top of said casing being sealed so as to form moisture proof joints around said carbon electrode and cap and around the edge of the said outer casing, whereby any moisture escaping from the dry cellis confined in said annular receptacle. I
In testimony whereof I afiix my signature.
HENRY E. WARNCKE.
US578891A 1922-08-01 1922-08-01 Dry battery Expired - Lifetime US1500477A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2523405A (en) * 1948-04-16 1950-09-26 Mardis O Whithed Electrical connection for a heating cable and the method of making the same
US2580664A (en) * 1946-05-07 1952-01-01 Union Carbide & Carbon Corp Dry cell
US2740823A (en) * 1952-10-25 1956-04-03 Ray O Vac Co Primary battery
US2740822A (en) * 1952-10-25 1956-04-03 Carrol G Sexe Primary battery
US2809226A (en) * 1954-03-09 1957-10-08 Kanda Masakichi Dry cell

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2580664A (en) * 1946-05-07 1952-01-01 Union Carbide & Carbon Corp Dry cell
US2523405A (en) * 1948-04-16 1950-09-26 Mardis O Whithed Electrical connection for a heating cable and the method of making the same
US2740823A (en) * 1952-10-25 1956-04-03 Ray O Vac Co Primary battery
US2740822A (en) * 1952-10-25 1956-04-03 Carrol G Sexe Primary battery
US2809226A (en) * 1954-03-09 1957-10-08 Kanda Masakichi Dry cell

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