US1310450A - Process of electrodepositing magnesium - Google Patents
Process of electrodepositing magnesium Download PDFInfo
- Publication number
- US1310450A US1310450A US1310450DA US1310450A US 1310450 A US1310450 A US 1310450A US 1310450D A US1310450D A US 1310450DA US 1310450 A US1310450 A US 1310450A
- Authority
- US
- United States
- Prior art keywords
- magnesium
- bath
- electrodepositing
- molten
- oxid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title description 56
- 229910052749 magnesium Inorganic materials 0.000 title description 56
- 239000011777 magnesium Substances 0.000 title description 56
- 238000000034 method Methods 0.000 title description 14
- 229940091250 Magnesium supplements Drugs 0.000 description 54
- 235000001055 magnesium Nutrition 0.000 description 54
- 230000005484 gravity Effects 0.000 description 22
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 20
- 229910052751 metal Inorganic materials 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- 239000003792 electrolyte Substances 0.000 description 10
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- ZLNQQNXFFQJAID-UHFFFAOYSA-L Magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 6
- ORUIBWPALBXDOA-UHFFFAOYSA-L Magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 6
- 239000001095 magnesium carbonate Substances 0.000 description 6
- 239000011776 magnesium carbonate Substances 0.000 description 6
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 6
- OYLGJCQECKOTOL-UHFFFAOYSA-L Barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 description 4
- 229910001018 Cast iron Inorganic materials 0.000 description 4
- 229910052788 barium Inorganic materials 0.000 description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium(0) Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000005868 electrolysis reaction Methods 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 241000331231 Amorphocerini gen. n. 1 DAD-2008 Species 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- -1 magnesium fluor Chemical compound 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/04—Electrolytic production, recovery or refining of metals by electrolysis of melts of magnesium
Definitions
- the electrolyte which I use is preferably of the general nature set forth in my prior Patent No. 880,489; that is to say, it comprises magnesium fiuorid, a fluorid of a metal or metals electropositive to magnesium, as sodium or potassium, and one or more salts acting to increase the specific gravity of the bath and to reduce its melting-point, barium fluorid being preferred.
- the density of the bath is an important consideration, for reasons.
- the electrolysis may be carried out in apparatus of the type illustrated in United States Letters Patent No. 864,928, patented September 3, 1907 to George 0. Seward and Franz von Kugelgen, said apparatus comprising essentially a cast-iron container having means for cooling the base, one or more carbon anodes dipping or depending into. the.
- anodes are prefera'bly located somewhatabove but out of vertical alinement with the cathode or cathodes.
- a layer of magnesia or magnesium carbonate of considerable depth is-maintained upon the surface of the bath, intowhich ithas but little tendency to sink by reason of the high specific gravity of the electrolyte.
- This layer serves not only to retain the heat, but also serves as a primary source or raw material for the production of magnesium, the magnesium oxid either dissolving progressively in the bath and undergoing electrolysis therein, or uniting with fluorin libthe magnesium fluor id content of the bath.
- magnesium carbonate In case magnesium carbonate is used it is I eventually converted into magnesium oxid by calcination in situ. Either magnesium oxid or magnesium carbonate is effective to protect the anodes, which are otherwise subject to rapid attack at or near the surface of the bath.
- the current conditions are so maintained as to keep a central pool or body of the electrolyte in a molten condition, and to deposit metallic magnesium at' the cathode at a temperature materially above its melting-point.
- a bath temperature of about 900 to 1000 C. is found satisfactory in practice.
- the amount of current required to maintain this condition will depend of course upon the size of the apparatus, the radiation therefrom, and many other factors,'but in general a current density approximating 400 amperes per square foot of cathode surface has been found suitable.
- a representative bath may comprise by weight Magnesium fiuorid 55 parts Sodium fiuorid 5 parts Barium fluorid 40 parts
- a bath'so constituted will have a specific gravity of about 4.10, this figure referring to a determination made upon cooled (solidified) samples.
- the specific gravity at the operating temperature will of course be somewhat lower but should be sufficient to accomplish certain definite purposes as mentioned below.
- the specific gravity of the bath should be sufficiently high to cause the magnesium deposited upon the cathode to flow freely and rapidly to the surface; and also to prevent the magnesium oxid, which is present in great excess of the proportion which is soluble in the bath, from sinking too rapidly or in excessive propor tions to the bottom, where it would overlie the cathode or portions .thereof.
- the bath should carry suspended and distributed therethrougha suflicient quantity of magnesium oxid to prevent evolution of fluorin at the anodes and to insure prompt and substantially quantitative regeneration of the bath.
- the specific gravity of the bath determined as above, should preferably be at least 3.5, and in practice usually approximates or even somewhat exceeds 4.
- a process of electrodepositing magnesium which consists in passing an electric current through a molten bath including magnesium fluorid, said bath carrying magnesium oxid in substantial excess of the proportion soluble therein, and having a specific gravity approximating 4.0.
- a process of electrodepositing magnesium which consists in passing an electric current through a molten bath including fiuorid of magnesium, sodium and barium, said bath carrying magnesium oxid in substantial excess of the proportion soluble therein, and having a specific gravity approximating 41.0.
- a rocess of electrodepositing magnesium, w ich consists in passing an electric current through a molten bath including magnesium fluorid, said bath carrying magnesium oxid in substantial excess of the pro portion soluble therein and being of sufiicient density to prevent rapid subsidence of the undissolved portions, and withdrawing mag nesium in the molten state from the upper portion of the bath.
- a process of electrodepositing magne sium which consists in passing an electric current through a molten bath including magnesium fiuorid, said bath carrying magnesium oxid in substantial excess of the proportion soluble therein and having a specific gravity in excess of 3.0, and withdrawing magnesium in the molten state from the upper portion of the bath;
- a rocess of electrodepositing magnesium which consists in passing an electric current through a. molten bath including magnesium fluorid, said bath carrying mag nesium oxid in substantial excess of theproportion soluble therein and having a specific gravity approximating 4.0, and withdrawing magnesium in the molten state from the upper portion of the bath.
- a process of electrodepositing magnesium which consists in passing an electric current through a molten bath including fiuorids of magnesium, sodium and barium, said bath carrying magnesium oxid in substantial excess of the proportion soluble therein and having a specific gravity ap- GEORGE O. SEWARD.
Description
UNITED STATES PATENT onmcn.
GEORGE O. SEWARD, -01E NIAGARA FALLS, NEW YORK, ASSIGNOR TO AMERIOAN MAGNESIUM CORPORATION, OF NIAGARA FALLS, NEW YORK, A CORPORATION OF To all whom it may concern:
Be it known that-I, GEORGE O. SEWARD, a citizen of the United States, residing at Niagara Falls, in the county of Niagara and State of New York, have invented certain 880,489, patented February 25, 1908, m
Franz von Kugel en and George 0. Seward there is described and claimed an electrolytic process of producing magnesium or alloys thereof, according to which magne-- sium oxid is added to a molten bath containing magnesium fiuorid and a fluorid of a metal or metals electropositive to magnesium. My present invention relates to operations of the above general character,
modified in such manner as to secure improved elficiency of operation and an increased yield of metal.
The electrolyte which I use is preferably of the general nature set forth in my prior Patent No. 880,489; that is to say, it comprises magnesium fiuorid, a fluorid of a metal or metals electropositive to magnesium, as sodium or potassium, and one or more salts acting to increase the specific gravity of the bath and to reduce its melting-point, barium fluorid being preferred.
Inthe present case the density of the bath is an important consideration, for reasons.
hereinafter explained.
The electrolysis may be carried out in apparatus of the type illustrated in United States Letters Patent No. 864,928, patented September 3, 1907 to George 0. Seward and Franz von Kugelgen, said apparatus comprising essentially a cast-iron container having means for cooling the base, one or more carbon anodes dipping or depending into. the.
I bath, and a cathode or cathodes, usually of cast iron, projecting upwardly through the base into the molten electrolyte and terminating in an edge or point in order to facilitate the upward flow and detachment of the molten magnesium. The bath-solidifies to a greater or lesser extent adjacent the cooled portions of the container, a central pool or Specification of Letters Ifate'nt. l atenteol July 22, 1919.. Application filed November 19, 1917. Serial No. 202,821.
NEW YORK. PROCESS OF ELECTRODEPOSITING MAGNESIUM.
No Drawing.
portion remaining fluid under the operating conditions.
In this construction the anodes are prefera'bly located somewhatabove but out of vertical alinement with the cathode or cathodes. Directly above the latter I provide means, forexample a cooling coil as shown in the above-mentioned patent, for chilling the surface of the bath to a degree sufficient to form a local crust of solidified electrolyte, sufficient to shield the floating magnesium from the atmosphere but easily broken through when the metal is to be removed. It is found in practice that in operating in this manner the floating molten metal. may be ladled or otherwise removed from the highly heated bath Without material loss by burning. Other suitable forms of collecting device may be used instead of that above described. r
In practising the present invention, a layer of magnesia or magnesium carbonate of considerable depth is-maintained upon the surface of the bath, intowhich ithas but little tendency to sink by reason of the high specific gravity of the electrolyte. This layer serves not only to retain the heat, but also serves as a primary source or raw material for the production of magnesium, the magnesium oxid either dissolving progressively in the bath and undergoing electrolysis therein, or uniting with fluorin libthe magnesium fluor id content of the bath.
In case magnesium carbonate is used it is I eventually converted into magnesium oxid by calcination in situ. Either magnesium oxid or magnesium carbonate is effective to protect the anodes, which are otherwise subject to rapid attack at or near the surface of the bath.
In the operation of the cell the current conditions are so maintained as to keep a central pool or body of the electrolyte in a molten condition, and to deposit metallic magnesium at' the cathode at a temperature materially above its melting-point. A bath temperature of about 900 to 1000 C. is found satisfactory in practice. The amount of current required to maintain this condition will depend of course upon the size of the apparatus, the radiation therefrom, and many other factors,'but in general a current density approximating 400 amperes per square foot of cathode surface has been found suitable.
A representative bath may comprise by weight Magnesium fiuorid 55 parts Sodium fiuorid 5 parts Barium fluorid 40 parts A bath'so constituted will have a specific gravity of about 4.10, this figure referring to a determination made upon cooled (solidified) samples. The specific gravity at the operating temperature will of course be somewhat lower but should be sufficient to accomplish certain definite purposes as mentioned below.
It is important that the specific gravity of the bath should be sufficiently high to cause the magnesium deposited upon the cathode to flow freely and rapidly to the surface; and also to prevent the magnesium oxid, which is present in great excess of the proportion which is soluble in the bath, from sinking too rapidly or in excessive propor tions to the bottom, where it would overlie the cathode or portions .thereof. At the same time, it is .desirable that the bath should carry suspended and distributed therethrougha suflicient quantity of magnesium oxid to prevent evolution of fluorin at the anodes and to insure prompt and substantially quantitative regeneration of the bath. F or these purposes the specific gravity of the bath, determined as above, should preferably be at least 3.5, and in practice usually approximates or even somewhat exceeds 4.
I claim 1. A process of electrodepositing magnesium, which consists in passing an electric current through a molten bath including magnesium fluorid, said bath carrying magnesium oxid in substantial excess of the proportion soluble therein, and having a specific gravity approximating 4.0.
2. A process of electrodepositing magnesium, which consists in passing an electric current through a molten bath including fiuorid of magnesium, sodium and barium, said bath carrying magnesium oxid in substantial excess of the proportion soluble therein, and having a specific gravity approximating 41.0.
3. A rocess of electrodepositing magnesium, w ich consists in passing an electric current through a molten bath including magnesium fluorid, said bath carrying magnesium oxid in substantial excess of the pro portion soluble therein and being of sufiicient density to prevent rapid subsidence of the undissolved portions, and withdrawing mag nesium in the molten state from the upper portion of the bath.
4:. A process of electrodepositing magne sium, which consists in passing an electric current through a molten bath including magnesium fiuorid, said bath carrying magnesium oxid in substantial excess of the proportion soluble therein and having a specific gravity in excess of 3.0, and withdrawing magnesium in the molten state from the upper portion of the bath;
5. A rocess of electrodepositing magnesium, which consists in passing an electric current through a. molten bath including magnesium fluorid, said bath carrying mag nesium oxid in substantial excess of theproportion soluble therein and having a specific gravity approximating 4.0, and withdrawing magnesium in the molten state from the upper portion of the bath.
6. A process of electrodepositing magnesium, which consists in passing an electric current through a molten bath including fiuorids of magnesium, sodium and barium, said bath carrying magnesium oxid in substantial excess of the proportion soluble therein and having a specific gravity ap- GEORGE O. SEWARD.
Publications (1)
Publication Number | Publication Date |
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US1310450A true US1310450A (en) | 1919-07-22 |
Family
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US1310450D Expired - Lifetime US1310450A (en) | Process of electrodepositing magnesium |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3055734A (en) * | 1956-10-05 | 1962-09-25 | Edmund S Pomykala | Process for separating sea salts |
-
0
- US US1310450D patent/US1310450A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3055734A (en) * | 1956-10-05 | 1962-09-25 | Edmund S Pomykala | Process for separating sea salts |
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