US1287878A - Sulfur-mining. - Google Patents

Sulfur-mining. Download PDF

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US1287878A
US1287878A US23148018A US23148018A US1287878A US 1287878 A US1287878 A US 1287878A US 23148018 A US23148018 A US 23148018A US 23148018 A US23148018 A US 23148018A US 1287878 A US1287878 A US 1287878A
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pipe
sulfur
mining
slidable
well
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Robert E Carmichael
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GEORGE HAMAN
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GEORGE HAMAN
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    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/285Melting minerals, e.g. sulfur

Definitions

  • sulfur mining in sulfur mining and more particularly to an apparatus for mining subterranean s'ulfur, whereby the sulfur is fused by a heated fluid forced down into the well to the vicinity of the sulfur deposit and when so fused the sulfur is forced to the surface of the ground through a return pipe.
  • the principal object of my invention is to provide an apparatus for the purpose described by means of which the heated fluid may be directed to, the desired point in the. sulfur strata. 1
  • Another object-is to construct an appara tus for sulfur mining which shall be of extreme simplicity and particularly eflicient and economical in operation.
  • This heated fluid percolates through the strata of thesulfur and the heated sulfur fuses and flows down into the lower end of the well. It there forms a layer beneath the water in the well and fills the lower end of the outlet pipe.
  • the pressure of the heated fluid which is pumped into the well causes the sulfur to rise in the outlet pipe to the surfaceof the ound where it is discharged It is assisted in this 'upward passage by a current of air forced down through asmall ,central pipe to the lower end of the outlet pipe from which point it bubbles up through the rising sulfur to the surface.
  • My apparatus is adapted to so direct the discharge of the heating fluid that. it' will avoid the crevices through which the water can escape laterally and-project it directly upon the sulfur at any desired point.
  • Figure l' is a longitudinal sideview partly in section of my invention.
  • Fig. 2 is a similar view showing a modified form of the same.
  • My improved apparatus consists of a system of concentric pipes to be introduced into the well after thesaid well has been drilled;
  • the upper part of the'well is usually reinforced and maintained inshape by the provision of a casing 1 inserted into the hole for some distance. This casing may be omitted, however, as will be seen.
  • a casing 1 inserted into the hole for some distance.
  • This casing may be omitted, however, as will be seen.
  • Within the outer casing is a system of pipes in connec tion with which my improvement appears.
  • the outer pipe 2 fits within a stufling box 6 at the upper endof thecasing 1, and has a lateral inlet pipe 13 connected thereto by means of a T joint 12.
  • Thepipe 2 also has a stuffing box 15, of any common construction, at its upper end maintaining a fluid tight joint with the next inner concentric 0n the side of the pipe 7 as will appear.
  • T 12 opposite from pipe 13 is a smaller pipe 14 to be provided with a relief-valve, not
  • the lower end ofthe pipe 2 is threaded into a compound coupling3 by means of which it is firmly attached to an anchoring pipe 4 which is extended downwardly into the bot- Y tom of the well hole for a distance suflicient to firmly anchor the system of pipes into.
  • the pipe 2 is perforated as shown at 5 for the complete depth ofthe sulfur stratum which is to be mined by means of my' apparatus.
  • the pipe 7 is slidable within the outer pipe 2 and telescopes within the stuffing box 15 and maintains a sliding fit with pipe 1? at the upper end.
  • the pipe 17 is extended upwardly for some distance sufficiently to allow a raising and lowering of the pipe 7 for a distance equal the full depth of the sulfur strata.
  • the pipe 17 next within the pipe 7 has at its upper end a T joint 18 provided with a laterally extended inlet pipe 19 for the purpose of supplying a further volume of heating fluid when the same is needed.
  • a stuffinr box 20 provides a close lit with the next interior pipe 21.
  • the pipe 17 extends downwardly into the well and is reduced in diameter by a reducing coupling or swage 22 at a point intermediate its length. This reduction in diameter is for the purpose of increasing the velocity of the heating fluid forced downwardly into the well.
  • the lower end of this pipe 17 is threaded exteriorly and is anchored in the compound coupling 3 previously described.
  • Tt has perforations 23 at its lower end for the inflow of the fused sulfur and at a short distance above the perforations a coupling 24 is used.
  • This coupling 24 has an inwardly pro ecting annular flange 25 which forms a contact with the pipe 21.
  • Above this annular flange 25 thepipe is further perforated at 26 to allow the outward passage of the heated fluid which is pumped down within the pipe 17.
  • the pipe 21 is of still smaller diameter and provides an outlet for the fused sulfur which fills the lower part of the well.
  • a T joint 27 having a lateral outlet pipe 28 for the fused material.
  • the pipe 21 is imperforate throughout its length and is reduced in diameter somewhat by an intermediate reducing coupling 29'and has toward its lower end, and at a point immediately above the inwardly projecting flange 25 of the next outer pipe, an exterior collar 30.
  • This collar is adapted under ordinary circumstances, to seat upon the flange 25 and maintain a tight closure between the two pipes.
  • water or other heated fluid pumped in through the inlet pipe 19 and within the pipe 17 will be prevented from further downward passage by the the closure maintained by the flange 25 and will pass outwardly through the perforations 26 to the-space within the slidable nea /ere pipe 7.
  • the heated fluidpumped in through either of the inlets 13 or 19 will find an. outlet within the slidable pipe. 7 and will pass downward around the lower end of this pipe and outwardly through the perforations 5 in the outer pipe 2 and come in contact with the sulfur to be fused.
  • this heated fluid may be directedv at any point within the sulfur strata
  • the pipe may be raised or lowered as desired.
  • This is done by any ordinary means, preferably by the usual block and tackle provided in connection with the ordinary mining derrick, A grappler or elevator at the end of the tackle is gripped about the upper end of the pipe 7 and the .aid pipe is thus adjusted vertically to any point desired.
  • the raising and lowering of the pipe will cause an outward flow of the heated fluid to occur at any point.
  • the sulfur thus fused flows downwardly into the well and through the lower perforations 5 in the outer pi e and perforations 23 in the inner pipe 1;.
  • This pipe 2 has the same con-- necting T 12, the lateral extending inlet pipe 13 and the opposite relief pipe 14 as described in connection with Fi 1.
  • the slidable pipe 7 is also quite similar to the one previously described. It is fitted within the T 12 of the pipe 2 through thestufiing box 15 and is slidable at its upper end u on the pipe 21 by means of a slidable stun 2 box 16 in an obvious manner.
  • the pipe in this embodiment is enlarged in diameter somewhat, at an intermediate point as at 33 and immediately below this enlargement it is provided with an outer series of packing rings 9 clamped in place on the outer periphery of this pipe by means of the two clamping rings 10 threaded upon the outer portions of the pipe as previously described.
  • the pipe 7 is perforated to allow the inward passage of the heated fluid pumped downwardly within the outer pipe 2 causing the same to be forced downwardly within the slidable pipe 7 so that itmay issue around the lower end of said pipe and through the perforations 5 to the sulfur.
  • the pipe 21 in'this modification is not perforated but extends well down toward serves to directthe heating fluid around its the bottom of the well and provides an outward passage for the sulfur which is forced upwardly therethrough by the pressure of the heating fluid.
  • the sulfur is assisted in its upward passage by means of a current of air forced downwardly through the inner pipe 31 as in the previous modification.
  • Fig. 2 very much simplifies the apparatus to be used in mining sulfur and is at the same time a very'eiflcient structure.
  • the heating water forced inwardly through the inlet 13 and down within the pipe 2 has for the'full length of its passage a wide space within which to pass, which will accommodate a large volume of water.
  • This water is stopped in its passage outside of the pipe. 7 and is forced through the perforations 11 into the space within the pipe 7 by means of the closure 9.
  • the pipe ⁇ 7 is, vertically adjustable asf-describedand lower endand outwardly at any desired point.
  • Thefused sulfur findsanleasy passage into the-lower part of the pipes and passes upwardly within the outlet p1pe21 been operated until all of the available $111.
  • a system of concentric pipes consisting of an outer pipe, perforated at the lower end to conduct a heated fluid into contact with the sulfur bed, an inner pipe for the sulfurv outlet, and an intermediate slidable pipe, imperforate toward the lower end andhaving toward its upper'end exterior packing rings thereon which close the passage between'the slidable pipe and the outer pipe and perforations in said slidable pipe above said closure.
  • anapparatus for sulfur mining the combination of an outer, perforated pipe anchored at its lower end, an inner imperforate pipe for the sulfur exit, an intermediate adjustable pipe to regulate the point of discharge ofheated fluid, and a sliding closure between the. outer pipe and the slid 3.
  • an apparatus for sulfur mining - an outer perforated pipe, an inner return pipe, and an intermediate longitudinally slidable pipe imperforate toward thelower end but perforate intermediate its ends and a closure on said slidable pipe contacting with the outer pipe and closing the passage outside said slidable pipe;
  • An apparatusfor discharging the heating fluid into a sulfur mine comprising an outer pipe perforated adjacent the sulfur bed, an inner adjustable pipe, means for in-- troducing the heating fluid into the space between the pipes and means on the ad ustable pipe to CllVfilt the heatlng fluid to the space Within said adjustable pipe and.
  • An apparatus for introducing the heating fluid into a'sulfur mine comprising an outer pipe to discharge said fluid into vi (31PM?) 1 ha) '0 the sulfur strata, an inner adjustable pipe,
  • an inner imperforate sulfur exit pipe an intermediate longitudinally adjustable pipe adapted to regulate the point of discharge of heated fluid through said outer perforate pipe, and a closure between said outer and intermediate pipes slidahle With said intermediate pipe.
  • an outer perforated discharge pipe, an inner sulfur outlet pipe, and an intermediate pipe adapted to be regulated to direct the discharge of heating fluid to any desired point, said pipe being perforated above the sulfur bed and a sliding closure for the space between the outer discharge pipe and the intermediate pipe belowtheperforations in said intermediate pipe.

Description

R. E. CARMICHAEL.
SULFUR MINING.
APPLICATION FILED APR. 29, 1918.
Patented Dec. 17, 1918.
l AIIIII llllllllllll j ROBERT E.EARMIEHAEL |NVENTOR H [a ATTORNEY p Y L I x ROBERT E. CARMIGHAEL, 9F DAMON, TEXAS, ASSIGNOR OF HAMMAN, OF HOUSTON, TEXAS.
ONE-HALF TO GEORGE sULFim-MI NING.
Specification of Letters Patent. P te ted Dee. 1'7, 1918.
Application filed April 29, 1918. Serial No. 231,480.
in sulfur mining and more particularly to an apparatus for mining subterranean s'ulfur, whereby the sulfur is fused by a heated fluid forced down into the well to the vicinity of the sulfur deposit and when so fused the sulfur is forced to the surface of the ground through a return pipe.
The principal object of my invention is to provide an apparatus for the purpose described by means of which the heated fluid may be directed to, the desired point in the. sulfur strata. 1
Another object-is to construct an appara tus for sulfur mining which shall be of extreme simplicity and particularly eflicient and economical in operation.
Other objects and advantages will more clearly appear in the description which fol-- lows and will be pointed out with more particularity in the claims. 7
In the usual method of mining sulfur it is customary to inject hot water through pipes from the surface down to the-sulfurdeposit.
This heated fluid percolates through the strata of thesulfur and the heated sulfur fuses and flows down into the lower end of the well. It there forms a layer beneath the water in the well and fills the lower end of the outlet pipe. The pressure of the heated fluid which is pumped into the well causes the sulfur to rise in the outlet pipe to the surfaceof the ound where it is discharged It is assisted in this 'upward passage by a current of air forced down through asmall ,central pipe to the lower end of the outlet pipe from which point it bubbles up through the rising sulfur to the surface. Upon pumping the heated fluid down to the sulfur beds, .it is frequently found that the heated fluid escapes outwardly-into crevices or caverns in the strata to such an extent that it is mostly wasted and the sulfur in close proximity to the return pipe is not heated sufiiciently to maintain it in .a fused condition causing it to congeal and stop up the well.
My apparatus is adapted to so direct the discharge of the heating fluid that. it' will avoid the crevices through which the water can escape laterally and-project it directly upon the sulfur at any desired point.
With particular reference to the drawing wherein like characters of reference are applied to like partsthroughout the several views, Figure l'is a longitudinal sideview partly in section of my invention. Fig. 2 is a similar view showing a modified form of the same.
My improved apparatus consists of a system of concentric pipes to be introduced into the well after thesaid well has been drilled;
- The upper part of the'well is usually reinforced and maintained inshape by the provision of a casing 1 inserted into the hole for some distance. This casing may be omitted, however, as will be seen. Within the outer casing is a system of pipes in connec tion with which my improvement appears. The outer pipe 2 fits within a stufling box 6 at the upper endof thecasing 1, and has a lateral inlet pipe 13 connected thereto by means of a T joint 12. Thepipe 2 also has a stuffing box 15, of any common construction, at its upper end maintaining a fluid tight joint with the next inner concentric 0n the side of the pipe 7 as will appear.
T 12 opposite from pipe 13 is a smaller pipe 14 to be provided with a relief-valve, not
shown, for the purpose of relieving any excess pressure which may occur in the well. The lower end ofthe pipe 2 is threaded into a compound coupling3 by means of which it is firmly attached to an anchoring pipe 4 which is extended downwardly into the bot- Y tom of the well hole for a distance suflicient to firmly anchor the system of pipes into.
position. The pipe 2 is perforated as shown at 5 for the complete depth ofthe sulfur stratum which is to be mined by means of my' apparatus. a
Within the plpe 2 is a smaller-pipe 7, imi perforate for the greater portion of its,
length and extending upwardly through the stufling box 15for some distance and has at its upper end a smiling box 16 which provides a tight fit about the next inner pipe 17. At a point somewhattoward the upper endof the pipe 7 is a coupling 8 of ordinary construction and above this coupling the pipe is threaded for a short distance to receive two interiorly threaded clamping rings 10 between which is provided a 'series of packing rings 9 adapted to maintain a tight sliding contact with the interior surface of pipe 2. Tmmediately above the closure provided by these packing rings 9 is a series of perforations 1i, sufficient in number. to allow the passage of sufficient heated fluid to heat the sulfur. The pipe 7 is slidable within the outer pipe 2 and telescopes within the stuffing box 15 and maintains a sliding fit with pipe 1? at the upper end. The pipe 17 is extended upwardly for some distance sufficiently to allow a raising and lowering of the pipe 7 for a distance equal the full depth of the sulfur strata.
The pipe 17 next within the pipe 7 has at its upper end a T joint 18 provided with a laterally extended inlet pipe 19 for the purpose of supplying a further volume of heating fluid when the same is needed. At the upper point of the pipe a stuffinr box 20 provides a close lit with the next interior pipe 21. The pipe 17 extends downwardly into the well and is reduced in diameter by a reducing coupling or swage 22 at a point intermediate its length. This reduction in diameter is for the purpose of increasing the velocity of the heating fluid forced downwardly into the well. The lower end of this pipe 17 is threaded exteriorly and is anchored in the compound coupling 3 previously described. Tt has perforations 23 at its lower end for the inflow of the fused sulfur and at a short distance above the perforations a coupling 24 is used. This coupling 24. has an inwardly pro ecting annular flange 25 which forms a contact with the pipe 21. Above this annular flange 25 thepipe is further perforated at 26 to allow the outward passage of the heated fluid which is pumped down within the pipe 17. The pipe 21 is of still smaller diameter and provides an outlet for the fused sulfur which fills the lower part of the well. At the upper end of the pipe 21 is a T joint 27 having a lateral outlet pipe 28 for the fused material. The pipe 21 is imperforate throughout its length and is reduced in diameter somewhat by an intermediate reducing coupling 29'and has toward its lower end, and at a point immediately above the inwardly projecting flange 25 of the next outer pipe, an exterior collar 30. This collar is adapted under ordinary circumstances, to seat upon the flange 25 and maintain a tight closure between the two pipes. Thus, it will be noted that water or other heated fluid pumped in through the inlet pipe 19 and within the pipe 17 will be prevented from further downward passage by the the closure maintained by the flange 25 and will pass outwardly through the perforations 26 to the-space within the slidable nea /ere pipe 7. Thus the heated fluidpumped in through either of the inlets 13 or 19 will find an. outlet within the slidable pipe. 7 and will pass downward around the lower end of this pipe and outwardly through the perforations 5 in the outer pipe 2 and come in contact with the sulfur to be fused.
order that this heated fluid may be directedv at any point within the sulfur strata the pipe may be raised or lowered as desired. This is done by any ordinary means, preferably by the usual block and tackle provided in connection with the ordinary mining derrick, A grappler or elevator at the end of the tackle is gripped about the upper end of the pipe 7 and the .aid pipe is thus adjusted vertically to any point desired. As the water always finds an outlet around the lower end of this adjustable pipe the raising and lowering of the pipe will cause an outward flow of the heated fluid to occur at any point. The sulfur thus fused flows downwardly into the well and through the lower perforations 5 in the outer pi e and perforations 23 in the inner pipe 1;.
The pressure of the downwardly flowing fluid upon the sulfur in the bottom of the well will cause it to pass upwardly within the pipe 21. toward the outlet at the upper end thereof. It is assisted in its upward passage by means of an interior column of air projected downwardly through the small pipe 31 which is connected at its upper end through a joint or elbow 32 with an air compressor not shown.' Air pumped downwardly through this inner pipe will bubble up from the lower end thereof through the upward current of fused sulfur and will assist in raising the same to the surface.
This apparatus just described is very similar to the apparatus previously'set forth in my application filed April 20th, 1918 Serial No. 229,859. It differs principally in the provisions of .the slidable closure 9 on the outer surface of the slidable pipb 7.
By means of this sliding closure between the two pipes the elevation of the.pipe 7 will not modify, in any manner. the closure maintained between the two pipes and will cause the full volume of water pumped inwardly within the pipe 2 to pass through the perforations 11 to the space within the pipe This apparatus may be materially simplified by omission of the pipe 17 and the outer casing 1 or by the omission merely of the pipe 17. This modification is disclosed in the embodiment shown in Fig. 2. The outer casing 1 is here dispensed with and it is contemplated that the outer pipe 2 shall fit closely within the well hole so that there will be no danger of an upward passage of the heating fluid toward the surface. This pipe 2 is perforated toward the lower end in the usual manner. When this device has 4 eaner/sv in Fig. 1. 'This pipe 2 has the same con-- necting T 12, the lateral extending inlet pipe 13 and the opposite relief pipe 14 as described in connection with Fi 1. The slidable pipe 7 is also quite similar to the one previously described. It is fitted within the T 12 of the pipe 2 through thestufiing box 15 and is slidable at its upper end u on the pipe 21 by means of a slidable stun 2 box 16 in an obvious manner. The pipe in this embodiment is enlarged in diameter somewhat, at an intermediate point as at 33 and immediately below this enlargement it is provided with an outer series of packing rings 9 clamped in place on the outer periphery of this pipe by means of the two clamping rings 10 threaded upon the outer portions of the pipe as previously described. At the point Where the enlargement occurs and immediately thereabove, the pipe 7 is perforated to allow the inward passage of the heated fluid pumped downwardly within the outer pipe 2 causing the same to be forced downwardly within the slidable pipe 7 so that itmay issue around the lower end of said pipe and through the perforations 5 to the sulfur.
The pipe 21 in'this modification is not perforated but extends well down toward serves to directthe heating fluid around its the bottom of the well and provides an outward passage for the sulfur which is forced upwardly therethrough by the pressure of the heating fluid. The sulfur is assisted in its upward passage by means of a current of air forced downwardly through the inner pipe 31 as in the previous modification.
It will be noted that the embodiment shown in Fig. 2 very much simplifies the apparatus to be used in mining sulfur and is at the same time a very'eiflcient structure. The heating water forced inwardly through the inlet 13 and down within the pipe 2 has for the'full length of its passage a wide space within which to pass, which will accommodate a large volume of water. This water is stopped in its passage outside of the pipe. 7 and is forced through the perforations 11 into the space within the pipe 7 by means of the closure 9. The pipe \7 is, vertically adjustable asf-describedand lower endand outwardly at any desired point. Thefused sulfur findsanleasy passage into the-lower part of the pipes and passes upwardly within the outlet p1pe21 been operated until all of the available $111.
"fur around this mine has been obtained, the :slidable pipe 7 is lowered to the very bottom of the well and the heating fluid is,
able pipe.
directed upon the lower part of the apparatus where .all ofthesulfur which may be congealed about the coupling 3 is again fused. When this fusion is accomplished" the pipe is rotated to unscrew the same from the main coupling 3 or 3 and withdrawn from the wellto be used again in a subse-.
quent operation.
It will thus be seen that I have provided a device for sulfur mining simple in struc ture, efficient and economical in operation Having thus described my invention what g 1 claim as new and desire to protect by Letters Patent is:
1. In an'apparatus forv sulfur mining, a system of concentric pipes consisting of an outer pipe, perforated at the lower end to conduct a heated fluid into contact with the sulfur bed, an inner pipe for the sulfurv outlet, and an intermediate slidable pipe, imperforate toward the lower end andhaving toward its upper'end exterior packing rings thereon which close the passage between'the slidable pipe and the outer pipe and perforations in said slidable pipe above said closure. I
1 2.1n anapparatus for sulfur mining the combination of an outer, perforated pipe anchored at its lower end, an inner imperforate pipe for the sulfur exit, an intermediate adjustable pipe to regulate the point of discharge ofheated fluid, and a sliding closure between the. outer pipe and the slid 3. in an apparatus for sulfur mining,- an outer perforated pipe, an inner return pipe, and an intermediate longitudinally slidable pipe imperforate toward thelower end but perforate intermediate its ends and a closure on said slidable pipe contacting with the outer pipe and closing the passage outside said slidable pipe;
4:. In an apparatus for sulfur mining, an
outer perforate pipe and an inner 'slidable pipe, smaller at its upper end and enlarged intermediate its length, packing rings outside said slidable pipe-adjacent said ene 6. In a system of concentric pipes for sul fur mining, an outer perforated pipe, an
inner longitudinally adjustable pipe, out- ,wardly projecting packing rings on said inner? pipe contacting with the outer pipe and perforations in-said inner pipe above said rings.
'larged portion and closing the passage between the two pipes, and perforations in V 7. In a systemof-concentric pipes forsulfur mining, an outer stationary pipe, an inner longitudinally adjustable pipe, the diameter of the lower part of said pipe being greater than its upper portion, a series of packing rings on its outer periphery, to close the passage between said pipes, and perforations above said closure.
8. in an apparatus for sulfur mining, an outer stationary inlet pipe for the heating fluid, an inner sulfur lift pipe and an intermediate adjust-able pipe; means to discharge the heating fluid into the space between the outer pipe and the slidable pipe and means on said sli dalole pipe to divert the heating fluid from the passage ithout said slidable pipe to the space Within the same for the purpose described. \1
9. An apparatusfor discharging the heating fluid into a sulfur mine comprising an outer pipe perforated adjacent the sulfur bed, an inner adjustable pipe, means for in-- troducing the heating fluid into the space between the pipes and means on the ad ustable pipe to CllVfilt the heatlng fluid to the space Within said adjustable pipe and.
around the lower end thereof.
10. An apparatus for introducing the heating fluid into a'sulfur mine comprising an outer pipe to discharge said fluid into vi (31PM?) 1 ha) '0 the sulfur strata, an inner adjustable pipe,
the combination or an outer perforated pipe,
an inner imperforate sulfur exit pipe, an intermediate longitudinally adjustable pipe adapted to regulate the point of discharge of heated fluid through said outer perforate pipe, and a closure between said outer and intermediate pipes slidahle With said intermediate pipe.
12. in an apparatus for sulfur mining, an outer perforated discharge pipe, an inner sulfur outlet pipe, and an intermediate pipe adapted to be regulated to direct the discharge of heating fluid to any desired point, said pipe being perforated above the sulfur bed and a sliding closure for the space between the outer discharge pipe and the intermediate pipe belowtheperforations in said intermediate pipe.
In testimony whereof, I hereunto afliX my signature this the 25 day of April, A. D.
CARMICHAEL.
US23148018A 1918-04-29 1918-04-29 Sulfur-mining. Expired - Lifetime US1287878A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3169576A (en) * 1959-07-01 1965-02-16 Freeport Sulphur Co Pipe line for conveying sulfur and other hot liquids

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3169576A (en) * 1959-07-01 1965-02-16 Freeport Sulphur Co Pipe line for conveying sulfur and other hot liquids

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