US12230553B2 - Semiconductor structure, manufacturing method of semiconductor structure and stacked structure - Google Patents
Semiconductor structure, manufacturing method of semiconductor structure and stacked structure Download PDFInfo
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- US12230553B2 US12230553B2 US17/647,458 US202217647458A US12230553B2 US 12230553 B2 US12230553 B2 US 12230553B2 US 202217647458 A US202217647458 A US 202217647458A US 12230553 B2 US12230553 B2 US 12230553B2
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/48—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor
- H01L23/481—Internal lead connections, e.g. via connections, feedthrough structures
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- H10W20/20—
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76898—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics formed through a semiconductor substrate
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- H10W20/023—
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- H10W20/0242—
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- H10W20/0261—
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- H10W20/0265—
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- H10W20/072—
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- H10W20/2134—
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- H10W20/46—
Definitions
- the present disclosure relates to the technical field of integrated circuits (ICs), and in particular to a semiconductor structure, a manufacturing method of the semiconductor structure and a stacked structure.
- ICs integrated circuits
- TSV Through silicon via
- TSV structures typically include metal conductive structures.
- the conductive structures are typically annealed after being formed so as to make their size more uniform. However, annealing will cause thermal expansion of the conductive structures. As a result, structures surrounding the conductive structures, for example, the semiconductor substrate and the dielectric layer thereon, may be prone to interface cracks due to thermal stress, thereby affecting the performance of the structures surrounding the conductive structures.
- Some embodiments of the present disclosure provide a semiconductor structure, a manufacturing method of the semiconductor structure and a stacked structure.
- a semiconductor structure includes:
- a base including a substrate and a dielectric layer, where the substrate includes a front surface and a back surface that are opposite to each other; the dielectric layer is formed on the front surface; the base is provided with a via hole; and the via hole penetrates the substrate from the back surface of the substrate and extends to the dielectric layer;
- the conductive structure includes a first conductive layer and a second conductive layer connected to each other; the first conductive layer is close to a bottom of the via hole, and the second conductive layer is close to a top of the via hole; and a diameter of the first conductive layer is less than that of the second conductive layer.
- a manufacturing method of a semiconductor structure includes:
- the base includes a substrate and a dielectric layer;
- the substrate includes a front surface and a back surface that are opposite to each other;
- the dielectric layer is formed on the front surface;
- the base is provided with a via hole; and the via hole penetrates the substrate from the back surface of the substrate and extends to the dielectric layer;
- the conductive structure includes a first conductive layer and a second conductive layer connected to each other; the first conductive layer is close to a bottom of the via hole, and the second conductive layer is close to a top of the via hole; and a diameter of the first conductive layer is less than that of the second conductive layer.
- a stacked structure is formed by processing the above-mentioned semiconductor structure.
- FIG. 1 is a view illustrating a semiconductor structure according to an embodiment of the present disclosure.
- FIG. 2 is a flowchart of a manufacturing method of the semiconductor structure according to an embodiment of the present disclosure.
- FIG. 3 is a view illustrating a structure obtained by implementing step S 100 of the manufacturing method of the semiconductor structure shown in FIG. 1 .
- FIG. 4 is a view illustrating a structure obtained by implementing step S 200 of the manufacturing method of the semiconductor structure shown in FIG. 1 .
- FIG. 5 is a view illustrating a structure obtained by implementing step S 300 of the manufacturing method of the semiconductor structure shown in FIG. 1 .
- FIG. 6 is a view illustrating a structure obtained by implementing step S 400 of the manufacturing method of the semiconductor structure shown in FIG. 1 .
- FIG. 7 is a view illustrating a structure obtained by implementing step S 500 of the manufacturing method of the semiconductor structure shown in FIG. 1 .
- FIG. 8 is a view illustrating a structure obtained by implementing step S 600 of the manufacturing method of the semiconductor structure shown in FIG. 1 .
- FIG. 9 is a view illustrating a structure obtained by implementing step S 700 of the manufacturing method of the semiconductor structure shown in FIG. 1 .
- FIG. 10 is a view illustrating a structure obtained by implementing step S 800 of the manufacturing method of the semiconductor structure shown in FIG. 1 .
- FIG. 11 is a view illustrating a structure obtained by implementing step S 900 of the manufacturing method of the semiconductor structure shown in FIG. 1 .
- an embodiment of the present disclosure provides a semiconductor structure.
- the semiconductor structure includes a base 100 , an insulating layer 200 and a conductive structure 320 .
- the base 100 includes a substrate 110 and a dielectric layer 120 .
- the substrate 110 includes a front surface 110 a and a back surface 110 b that are opposite to each other.
- the dielectric layer 120 is formed on the front surface 110 a .
- the base 100 is provided with a via hole 100 a .
- the via hole 100 a penetrates the substrate 110 from the back surface 110 b of the substrate 100 and extends to the dielectric layer 120 .
- the insulating layer 200 is located on an inner wall surface of the via hole 100 a .
- the conductive structure 320 includes a first conductive layer 321 and a second conductive layer 322 connected to each other.
- the first conductive layer 321 is close to a bottom of the via hole 100 a
- the second conductive layer 322 is close to a top of the via hole 100 a
- a diameter of the first conductive layer 321 is less than that of the second conductive layer 322 .
- the diameter of the first conductive layer 321 corresponding to a semiconductor device formed between the substrate 110 and the dielectric layer 120 is small. Therefore, the expansion stress of the first conductive layer 321 on the substrate 110 and the dielectric layer 120 in this corresponding part is small, thereby reducing the thermal stress of the conductive structure 320 on the surrounding device.
- the semiconductor structure further includes a barrier layer 310 .
- the barrier layer 310 is located on a surface of the insulating layer 200 , and there is a gap 100 b between the barrier layer 310 and the first conductive layer 321 .
- the gap 100 b may be filled with air or other heat insulating medium.
- the barrier layer 310 is a film layer that effectively inhibits the thermal expansion stress of the conductive structure 320 .
- the barrier layer 310 may be made of tantalum (Ta), tantalum nitride (TaN), etc., and may have a thickness of 0.05-0.1 ⁇ m.
- the barrier layer 310 can effectively reduce the thermal expansion coefficient of the conductive structure 320 when the conductive structure 320 is thermally expanded.
- the gap 100 b isolates the first conductive layer 321 from the barrier layer 310 , thereby effectively blocking the thermal expansion stress of the first conductive layer, so as to better protect the surrounding device.
- the first conductive layer 321 and the barrier layer 310 are spaced apart, and the second conductive layer 322 is connected to the barrier layer 310 .
- the first conductive layer 321 may be made of a metal conductive material such as copper (Cu).
- the first conductive layer may include a first seed layer and a first conductive portion. The first seed layer is formed on a surface of the barrier layer 310 , and the first conductive portion is formed on a surface of the first seed layer.
- the semiconductor structure further includes an isolation layer 330 .
- the isolation layer 330 is located at the bottom of the via hole 100 a and between the barrier layer 310 and the first conductive layer 321 .
- the barrier layer 310 , the isolation layer 330 , the first conductive layer 321 and the second conductive layer 322 together enclose the gap 100 b filled with air.
- the second conductive layer 322 includes a second seed layer 3221 and a second conductive portion 3222 .
- the second seed layer 3221 surrounds the second conductive portion 3222 .
- a sidewall of the second seed layer 3221 is in contact with the barrier layer 310 , and the bottom of the second seed layer 3221 is in contact with the first conductive layer 321 .
- An embodiment further provides a stacked structure.
- the stacked structure is formed by processing the above-mentioned semiconductor structure.
- the above-mentioned semiconductor structure is processed through a process such as etching or planarization, such that the conductive structure 320 in the dielectric layer 120 is exposed (not shown).
- a process such as etching or planarization
- the conductive structure 320 in the via hole 100 a can be conductively connected to achieve signal transmission.
- an embodiment provides a manufacturing method of a semiconductor structure.
- the manufacturing method includes:
- Step S 1 Provide a base, where the base includes a substrate and a dielectric layer;
- the substrate includes a front surface and a back surface that are opposite to each other;
- the dielectric layer is formed on the front surface;
- the base is provided with a via hole;
- the via hole penetrates the substrate from the back surface of the substrate and extends to the dielectric layer.
- Step S 2 Form an insulating layer on an inner wall surface of the via hole.
- Step S 3 Form a conductive structure on a surface of the insulating layer, where the conductive structure includes a first conductive layer and a second conductive layer connected to each other; the first conductive layer is close to a bottom of the via hole, and the second conductive layer is close to a top of the via hole; and a diameter of the first conductive layer is less than that of the second conductive layer.
- Step S 100 Provide a base 100 .
- the base 100 includes a substrate 110 and a dielectric layer 120 .
- the substrate 110 has a front surface 110 a and a back surface 110 b that are opposite to each other.
- the dielectric layer 120 is formed on the front surface 110 a.
- the substrate 110 may include, but is not limited to, a silicon substrate.
- a shallow trench isolation structure 400 may be formed on a side of the substrate 110 close to the dielectric layer 120 .
- the shallow trench isolation structure 400 isolates the substrate 110 into multiple active regions. The active regions are used to form various semiconductor devices.
- the dielectric layer 120 may include, but is not limited to, a dielectric layer made of an oxide (such as silicon dioxide).
- a via structure and a metal layer electrically connecting the active regions may be formed in the dielectric layer 120 , so as to draw out signals of the semiconductor devices to the outside or provide an external signal for the semiconductor devices.
- Step S 200 Form a via hole 100 a in the base 100 .
- the base 100 shown in FIG. 3 may be etched from the back surface 110 b of the substrate 110 by dry etching, thereby forming the base 100 with the via hole 100 a .
- the via hole 100 a penetrates the substrate 110 from the back surface 110 b of the substrate 110 and extends to the dielectric layer 120 .
- the depth of the via hole 100 a may be 20-150 ⁇ m, and the depth that the via hole extends into the dielectric layer 120 may be 0.5-1 ⁇ m.
- the diameter of the via hole 100 a may be 3-50 ⁇ m.
- the depth-to-width ratio (that is, the ratio of the depth to the diameter) of the via hole 100 a may be 0.4-50.
- the via hole 100 a is used to form a conductive structure therein.
- the corresponding via holes 100 a of the chips are aligned, such that the conductive structures in the via holes 100 a are electrically connected, thereby realizing interconnection between the chips.
- the back surface 110 b of the substrate 110 is far away from the semiconductor devices formed in the active regions and circuit structures connecting the semiconductor devices. Therefore, in this embodiment, when the via hole 100 a is formed, damage to the semiconductor devices formed in the active regions and the related circuit structures is effectively prevented.
- Step S 300 Form an insulating layer 200 on an inner wall surface of the via hole 100 a.
- the insulating layer 200 is used to achieve electrical isolation between the conductive structure and the substrate 110 .
- the insulating layer 200 may be made of silicon dioxide, etc.
- the materials of the insulating layer 200 and the dielectric layer 120 may be the same or different.
- a silicon dioxide film layer may be deposited as the insulating layer 200 on an inner wall of the via hole 100 a through chemical vapor deposition (CVD) based on silane (SiH 4 ) or tetraethyl orthosilicate (TEOS).
- the thickness of the silicon dioxide film layer may be 0.2-2 ⁇ m.
- Step S 400 Form a barrier layer 310 on a surface of the insulating layer 200 .
- the barrier layer 310 may be made of tantalum (Ta), tantalum nitride (TaN), etc., and may have a thickness of 0.05-0.1 ⁇ m.
- Step S 500 Form a primary isolation layer 331 on a surface of the barrier layer 310 , where the primary isolation layer 331 includes a sidewall portion 3311 .
- the primary isolation layer 331 is made of an insulating material.
- the primary isolation layer 331 may be made of silicon dioxide.
- a 0.2-2 ⁇ m thick silicon dioxide film layer may be deposited as the primary isolation layer 331 on the inner wall of the via hole 100 a through CVD based on silane (SiH 4 ) or tetraethyl orthosilicate (TEOS).
- Step S 600 Form a primary conductive layer 3211 on a surface of the primary isolation layer 331 .
- a first primary seed layer may be formed on the surface of the barrier layer 310 , and then a first primary conductive layer may be formed on a surface of the first primary seed layer.
- the first primary conductive layer and the first primary seed layer define the primary conductive layer 3211 .
- the primary conductive layer 3211 may be made of copper (Cu).
- a copper seed layer may be formed on the surface of the barrier layer 310 as the first primary seed layer through physical vapor deposition (PVD). Then, copper (Cu) is electroplated on a surface of the first primary seed layer to form the first primary conductive layer.
- the primary conductive layer 3211 grown on the surface of the barrier layer 310 may not fill the via hole 100 a .
- the filling thickness of a central part of the primary conductive layer 3211 may be 20-70% of the depth of the via hole 100 a.
- Step S 700 Remove a part of the primary conductive layer 3211 to expose a part of the sidewall portion 3311 , such that the remaining primary conductive layer 3211 defines a first conductive layer 321 .
- a part of the primary conductive layer 3211 covering the sidewall portion 3311 may be removed by a mixed acid solution (for example, a mixed solution of H 2 SO 4 /H 2 O 2 ), so as to expose a part of the sidewall portion 3311 of the primary isolation layer 331 and form the first conductive layer 321 .
- a mixed acid solution for example, a mixed solution of H 2 SO 4 /H 2 O 2
- the first primary seed layer forms a first seed layer
- the first primary conductive layer forms a first conductive portion.
- the first seed layer and the first conductive portion define the first conductive layer 321 .
- Step S 800 Remove a part of the sidewall portion 3311 to form the gap 100 b between the barrier layer 310 and the first conductive layer 321 , where the remaining primary isolation layer 331 defines an isolation layer 330 .
- the sidewall portion 3311 of the primary isolation layer 331 may be etched by hydrofluoric acid or dry etching to form the gap 100 b between the barrier layer 310 and the first conductive layer 321 .
- a distance H 1 between a surface of the isolation layer 330 formed by the remaining primary isolation layer 331 and an opening of the via hole 100 a is greater than a distance H 2 between a surface of the first conductive layer 321 and the opening of the via hole 100 a . That is, after this part of the primary isolation layer 331 is removed, an upper surface of the isolation layer 330 formed by the remaining primary isolation layer 331 is lower than that of the first conductive layer 321 .
- the isolation layer 330 by forming the isolation layer 330 , the first conductive layer 321 and the barrier layer 310 are spaced apart easily and effectively.
- the isolation layer 330 may not be formed.
- the first conductive layer 321 and the barrier layer 310 may be spaced apart by other means, which is not limited herein.
- Step S 900 Form a second seed layer 3221 on the surface of the barrier layer 310 and the surface of the first conductive layer 321 , where the second seed layer 3221 closes the gap 100 b , thereby forming the gap 100 b on two sides of the first conductive layer 321 .
- the second seed layer 3221 may be formed through PVD, etc.
- the second seed layer 3221 facilitates the subsequent formation of a second conductive portion 3222 and closes the gap 100 b.
- Step S 1000 Form the second conductive portion 3222 on a surface of the second seed layer 3221 , where the second conductive portion 3222 and the second seed layer 3221 define a second conductive layer 322 .
- the second conductive portion 3222 may be formed through electroplating, etc.
- the first conductive layer 321 and the second conductive layer 322 of the conductive structure 320 may also be formed simultaneously through a single process.
- the materials of the first conductive layer 321 and the second conductive layer 322 are the same. For example, they are both made of copper (Cu). In this way, the first conductive layer 321 is in good contact with the second conductive layer 322 , thereby reducing the contact resistance of the conductive layers and effectively reducing the impedance of the conductive structure 320 .
- the materials of the first conductive layer 321 and the second conductive layer 322 may also be different.
- the semiconductor structure is not limited to being formed by the manufacturing method in the above embodiments.
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Abstract
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Claims (14)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110357894.XA CN115172325B (en) | 2021-04-01 | 2021-04-01 | Semiconductor structure and its formation method, stacked structure |
| CN202110357894.X | 2021-04-01 | ||
| PCT/CN2021/112066 WO2022205733A1 (en) | 2021-04-01 | 2021-08-11 | Semiconductor structure and manufacturing method therefor, and stacking structure |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CN2021/112066 Continuation WO2022205733A1 (en) | 2021-04-01 | 2021-08-11 | Semiconductor structure and manufacturing method therefor, and stacking structure |
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| US20220319958A1 US20220319958A1 (en) | 2022-10-06 |
| US12230553B2 true US12230553B2 (en) | 2025-02-18 |
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| CN113675140B (en) * | 2021-08-20 | 2024-05-17 | 武汉新芯集成电路制造有限公司 | Semiconductor device and method for manufacturing the same |
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| CN101355069A (en) | 2007-05-18 | 2009-01-28 | 三星电子株式会社 | Semiconductor package with through-hole silicon and related manufacturing method |
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| US20220319958A1 (en) | 2022-10-06 |
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