US1019588A - Electrolytic anode. - Google Patents
Electrolytic anode. Download PDFInfo
- Publication number
- US1019588A US1019588A US61417911A US1911614179A US1019588A US 1019588 A US1019588 A US 1019588A US 61417911 A US61417911 A US 61417911A US 1911614179 A US1911614179 A US 1911614179A US 1019588 A US1019588 A US 1019588A
- Authority
- US
- United States
- Prior art keywords
- anode
- rod
- sleeve
- washer
- boss
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009413 insulation Methods 0.000 description 8
- 238000007789 sealing Methods 0.000 description 8
- 239000000725 suspension Substances 0.000 description 8
- 239000004568 cement Substances 0.000 description 6
- 239000003792 electrolyte Substances 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 230000009471 action Effects 0.000 description 4
- 239000004020 conductor Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 229920001800 Shellac Polymers 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- HCTVWSOKIJULET-LQDWTQKMSA-M phenoxymethylpenicillin potassium Chemical compound [K+].N([C@H]1[C@H]2SC([C@@H](N2C1=O)C([O-])=O)(C)C)C(=O)COC1=CC=CC=C1 HCTVWSOKIJULET-LQDWTQKMSA-M 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000001364 upper extremity Anatomy 0.000 description 1
- -1 vulcanite Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/60—Constructional parts of cells
- C25B9/65—Means for supplying current; Electrode connections; Electric inter-cell connections
Definitions
- the submersible insulation can be readily HERBERT EDWARD REACH, OF BIRMINGHAM, ENGLAND.
- My invention has reference to anodes for use 1n electro-glat-ing and other electrolytic operations, an relates in particular to anodes of the type wherein the current-conducting suspension rod is insulated to prevent leakage of current and to protect the rod from corrosive action when the anode itself is completely immersed in the electrolyte.
- the object of my invention is to obviate the disadvantages above referred to, and to provide an improved form or construction of-anode and an improved insulation and sealing arrangement whereby the joints in and perfectly sealed Without the aid of cement and independently of the application and adjustment of the rod to the anode; and whereby it is also rendered possible for a screwed suspens on rod and its insulation devices to be used interchangeably and repeatedly with a succession of anodes without risk of current leakage and without risk of the said rod being weakened or its screw thread damaged by corrosion under electrolytic action.
- Figure 1 of the accompanying drawings represents, in perspective, an anode with its insulated suspender constructed in accordance with my invention.
- Fig. 2 is a view showing the arrangement in use, with the whole of the anode and the lower part of the suspension rod and its insulation submerged in the electrolyte.
- Fig. 3 represents the said anode and its suspension u on an enlarged scale, and in elevation.
- ig. 4 is a sectional elevation of Fig. 3.
- Fig. 5 is a plan of the same, and Fig. 6 is a plan and elevation of'the top part of the anode separately.
- the anode a is of the plate form usually employed in nickel plating and similar electrol tic operations, and is adapted to be suspen ed within the solution bath by means of the current-conducting rod b, which hangs from the positive conductor a, of the said bath, as shown in Fig. 2.
- the lower end of the rod has a screw thread at b, and is designed to be connected to the anode with a circular-sectioned boss or enlargement d, in the center of which, the tapped hole a is formed, so that the said hole is surrounded by a thickness of metal which preferably exceeds the thickness of theplate-like body of the anode, and which is adapted to protect the end b of the rod from corrosion when submerged, owing to the fact that the body-metal will be entirely,
- the said lug has a so a flat top d.
- the said rod is provided with a long sleeve or covering e, made of suitablytreated wood, vulcanite, glass or other rigid non-conducting material which is impervious to liquid, while between the base or foot of this sleeve and the attachment boss or enlargement d, on the anode, there is interposed a sealing washer f, made of fiber, rubher or other compressible substance, which surrounds the rod 7), immediately above the boss d.
- This washer which is of considerable diameter, is everywhere supported by the flatstopped surface of the enlargement on the anode, while the lower end of thesleeve e, where it bears on the washer, is also of considerable diameter or thickness, so
- e, and f are of sufficiently ample area to insure perfectly liquid-tight joints when compressed.
- the sleeve e also serves as the medium for transmitting mechanical pressure for compressing thewasher f, be-
- a nut g whichis screwed onto the wormed upper part b of the rod and bears directly against the upper end of the sleeve as repre- 60 sented, or the nut may be arranged to act indirectly on the sleeve through an intermediate washer or sleeve having a D-shaped or similar hole engaging on a correspondingly-shaped part of the rod, which prevents the compressible washer f, being damaged by twisting when the nut is tightened up.
- anode may be covered with some plastic insulating material which is also compressed when the mechanical pressure is applied.
- the outside of the boss d may also be covered or surfaced with a protective insulating material to delay the act-ion of the electrolyte on the part of the anode to which the rod is attached.
- two or more bosses such as d, may be provided, each of which is furnished with a suspension rod and a mechanically-sealed insulation as described.
- the said boss maybe of the elevated form shown in Figs. 7 and 8; or it may be formed with a circular recess d to receive and confine the sealing washer as in Figs. 9 and 10; or the top of the said boss may be provided, for the same purpose,
- the latter may be furnished, as shown in Fig.- 12, with a screwed stud 03 see also Fig. 10, while the rod has an enlarged end 6 and a female screwed socket b, which is engaged with the quietn attaching the rod to the anode.
- an electrolytic anode having an enlargement at the center of the upper edge thereof around a screw socket, a current conducting suspension rod having a lower screwthreaded end removably fitted in the socket of the anode and also provided with a hook at its upper end and screw-threads on the body thereof, a non-conducting rigid sleeve mounted over the sus ension rod, a nonconducting compressible washer interposed between the lower end of the sleeve and the central enlarged portion of the.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Description
H. E. BEACH. ELECTROLYTIC ANODB.
APPLICATION FILED MAR.13, 1911.
1,019,588. Patented Mar. 5, 1912.
1 3 SHEETS-SHEET 1. o
H. E. BEACH.
ELECTROLYTIC ANODE.
PPPPPPPPPPPPPPPPP AR.13,1911. 1,019,588. Patented Mar. 5, 1912.
s nnnnnnnnnn ET 3.
45 r the submersible insulation can be readily HERBERT EDWARD REACH, OF BIRMINGHAM, ENGLAND.
ELECTROLYTIC AN ODE.
Specification of Letters Patent.
Application filed March 18, 1911.
Patented Mar. 5, 1912.
Serial No. 614,179.
It; all whom it may concern:
. been used up it is necessary to Be it known that I, HERBERT EowARp *BE'AoH, a subject of the King of Great Britain, residing at Britannia Works, Hospital street, Birmingham, England, have invented certain new and useful Improvements Relating to Electrolytic Anodes, of which the following is a specification.
My invention has reference to anodes for use 1n electro-glat-ing and other electrolytic operations, an relates in particular to anodes of the type wherein the current-conducting suspension rod is insulated to prevent leakage of current and to protect the rod from corrosive action when the anode itself is completely immersed in the electrolyte. Hitherto such suspension rods have been sheathed with a non-conducting covering which, in order to exclude the solution when submerged, has to be sealed by applyin shellac or other cement to its lower end: th1s cement seal is, however a ractical disadvanta e, since care and skil has to be exercise in applying the cement in order to obtain a joint, while after an anode has rovide the rod with a resh insulation an to re-seal the joint with cement before the said rod can be applied and used again in connection with a resh anode. It has also been proposed to use a sheathed rod having a female thread at its lower end ada ted to screw onto a stud on the anode an to compress a washer which surrounds the said stud, but in this arrangement, also, the outer sheath has to be independent] sealed with cement and the compression 0 the washer can only be eifected by the undesirable method of rotating the rod itself when connecting the same to the anode.
The object of my invention is to obviate the disadvantages above referred to, and to provide an improved form or construction of-anode and an improved insulation and sealing arrangement whereby the joints in and perfectly sealed Without the aid of cement and independently of the application and adjustment of the rod to the anode; and whereby it is also rendered possible for a screwed suspens on rod and its insulation devices to be used interchangeably and repeatedly with a succession of anodes without risk of current leakage and without risk of the said rod being weakened or its screw thread damaged by corrosion under electrolytic action. This object is attained in accordance with my invention first, by the use in conjunction with a screwed conductor rod, of a rigid and impervious sleeve to insulate and protect the same, together with a sealing washer which is compressed (for the purpose of sealin the submersible joints) by pressure which is applied and maintained mechanically, and is transmitted through the said sleeve after the rod itself has been screwed and adjusted to the anode; and secondly, b forming or providing the top ofthe ano e with an attachment lu or boss whose sectional area considerab y exceeds the thickness of the body of the said anode and which not only assists in the effective sealing-of the insulation by affording a large seating for the washer and a rigid bearing to take the sealing pressure, but also provides an additional thickness of metal which surrounds the attached end of the rod and protects the same from electrolytic erosion, so that an anode may be left in a solution until the whole of the body thereof has been used up (thus avoiding waste of anode metal) without risk of the suspension rod being weakened or the screw thread thereof being damaged, with the result that the rod is preserved intact for subsequent interchangeable use with other anodes.
Figure 1 of the accompanying drawings represents, in perspective, an anode with its insulated suspender constructed in accordance with my invention. Fig. 2 is a view showing the arrangement in use, with the whole of the anode and the lower part of the suspension rod and its insulation submerged in the electrolyte. Fig. 3 represents the said anode and its suspension u on an enlarged scale, and in elevation. ig. 4 is a sectional elevation of Fig. 3. Fig. 5 is a plan of the same, and Fig. 6 is a plan and elevation of'the top part of the anode separately.
The same letters of reference indicate corresponding parts in the said Figs. 1 to 6.
The anode a is of the plate form usually employed in nickel plating and similar electrol tic operations, and is adapted to be suspen ed within the solution bath by means of the current-conducting rod b, which hangs from the positive conductor a, of the said bath, as shown in Fig. 2. The lower end of the rod has a screw thread at b, and is designed to be connected to the anode with a circular-sectioned boss or enlargement d, in the center of which, the tapped hole a is formed, so that the said hole is surrounded by a thickness of metal which preferably exceeds the thickness of theplate-like body of the anode, and which is adapted to protect the end b of the rod from corrosion when submerged, owing to the fact that the body-metal will be entirely,
used u before the electrolyte can penetrate the thlcker walls of the In and attack the screw. The said lug has a so a flat top d.
which, in the arrangement shown in Figs.
1 to 6, is flush with the top edge of the anode, and serves as a seating for the sealing washer as hereinafter described.
To protect the rod b, from electrolytic action and prevent current leakages from the submerged part thereof direct to the electrolyte, the said rod is provided with a long sleeve or covering e, made of suitablytreated wood, vulcanite, glass or other rigid non-conducting material which is impervious to liquid, while between the base or foot of this sleeve and the attachment boss or enlargement d, on the anode, there is interposed a sealing washer f, made of fiber, rubher or other compressible substance, which surrounds the rod 7), immediately above the boss d. This washer, which is of considerable diameter, is everywhere supported by the flatstopped surface of the enlargement on the anode, while the lower end of thesleeve e, where it bears on the washer, is also of considerable diameter or thickness, so
that. the contacting surfaces of the parts 03,
e, and f, are of sufficiently ample area to insure perfectly liquid-tight joints when compressed.
In addition to providing a protective in- 59 sulation for the rod, the sleeve e, also serves as the medium for transmitting mechanical pressure for compressing thewasher f, be-
tween the base of said sleeve and the boss on the anode after the attachment of the said rod; such pressure being applied and maintained, in the arrangement shown, by
a nut g, whichis screwed onto the wormed upper part b of the rod and bears directly against the upper end of the sleeve as repre- 60 sented, or the nut may be arranged to act indirectly on the sleeve through an intermediate washer or sleeve having a D-shaped or similar hole engaging on a correspondingly-shaped part of the rod, which prevents the compressible washer f, being damaged by twisting when the nut is tightened up. Thus when the nut g, is screwed down the rod after the various parts a, b, e, f, have been assembled, the consequeiit compression of the washer by pressure transmitted through the said'sleeve mechanically closes and seals the joint between the parts e, f, d, so that when the anode is suspended in the electrolyte, not only is perfect electric insulation obtained, but it' is impossible for the solution to penetrate the sealing washer and attack the parts of the rod surrounded by the sleeve, while the end of the said rod which is screwed into the anode is protected by the surrounding thickness of metal in the boss or enlargement. As a further precaution, the contacting surfaces of the sleeve,
washer, and anode may be covered with some plastic insulating material which is also compressed when the mechanical pressure is applied. The outside of the boss d, may also be covered or surfaced with a protective insulating material to delay the act-ion of the electrolyte on the part of the anode to which the rod is attached.
If necessary, in the caseof large anodes,
two or more bosses such as d, may be provided, each of which is furnished with a suspension rod and a mechanically-sealed insulation as described.
Instead of the fiat top of the boss d, being flush with the edge of the anode a, as in Figs. 1 to 6, the said boss maybe of the elevated form shown in Figs. 7 and 8; or it may be formed with a circular recess d to receive and confine the sealing washer as in Figs. 9 and 10; or the top of the said boss may be provided, for the same purpose,
with a ring or collar d as shown in Fig.
11, to, surround the washer.
Instead of the lower end of the rod being screwed into a tapped hole in the anode boss, the latter may be furnished, as shown in Fig.- 12, with a screwed stud 03 see also Fig. 10, while the rod has an enlarged end 6 and a female screwed socket b, which is engaged with the studin attaching the rod to the anode.
said sleeve e, relative to the enlargement on the rod when sea-ling pressure isapplied by the nut. 11-.
It is obvious that the improtgements herein described can be applied to anodesmade of In this case, the inside 'of the insulating sleeve-has a clearance 6 suflicient to admit of the movement of the any metal and of any form, size or pattern, A
as well as to plate anodes such as represented in the drawings.
Having described my invention, what I desire to claim and secure by Letters Patent is 1. In a device of the class specified, the
combination of an anode, a current conduct-i at its upper extremity and screw-threads on the body thereof, a non-conductmg rigid sleeve mounted over the suspension rod, a
washer of a compressible structure surrounding the rod and interposed between the lower end of the sleeve and the upper ed e of the anode, and a single nut engaging t e screw-threads on the body of the rod and adjustable to tightly bear on the upper end of the sleeve to institute a tight engagement between the lower end of the sleeve and the washer and a non-leakable joint between the said washer and the upper edge of the anode adjacent to the point of attachment of the rod for the latter.
2. In a device of the class specified, an electrolytic anode having an enlargement at the center of the upper edge thereof around a screw socket, a current conducting suspension rod having a lower screwthreaded end removably fitted in the socket of the anode and also provided with a hook at its upper end and screw-threads on the body thereof, a non-conducting rigid sleeve mounted over the sus ension rod, a nonconducting compressible washer interposed between the lower end of the sleeve and the central enlarged portion of the. anode, and a nut en aging, the screw-threads on the body of 51c rod and movable toward and adapted to clamp tightly against the upper end of the sleeve and set up a tight engagement between the lower end of the latter and the washer and the enlarged portion of the anode.
In testimony whereof I have hereunto set my hand in presence of two subscribing witnesses.
HERBERT EDWARD BEACH.
Witnesses:
ARTHUR SADLEB, ALFRED WARD.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US61417911A US1019588A (en) | 1911-03-13 | 1911-03-13 | Electrolytic anode. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US61417911A US1019588A (en) | 1911-03-13 | 1911-03-13 | Electrolytic anode. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1019588A true US1019588A (en) | 1912-03-05 |
Family
ID=3087886
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US61417911A Expired - Lifetime US1019588A (en) | 1911-03-13 | 1911-03-13 | Electrolytic anode. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1019588A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2594881A (en) * | 1949-12-28 | 1952-04-29 | Rochester Lead Works Inc | Electrode for chromium plating |
-
1911
- 1911-03-13 US US61417911A patent/US1019588A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2594881A (en) * | 1949-12-28 | 1952-04-29 | Rochester Lead Works Inc | Electrode for chromium plating |
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