M367088 八、新型說明： 【新型所屬之技術領域】 本創作涉及-種具物理發_膠材料的玩具，主要指一種採 用純氣態氣體娜_料齡形狀物體舰歸㈣製造之 玩具。 【先前技術】 舰技術乃是制物理發泡劑或化學發泡触熔融塑膠以 # 獲知發泡成型的方法。以發泡技術獲得的發泡材料具有輕量、緩 衝、斷熱、吸音、吸震等特性，與降低原料成本。 其中，化學發泡為採时解性化學發_航融塑膠混合製 ^ 造’此類發㈣卜紋固體粉末，並於加熱時分解放出氣體，而 - 使轉發泡，並減輕《。此類化學發泡劑多為有機的偶氮化合 物，如偶氮雙甲醯胺（Azodicarbonamide)、偶氮雙異丁晴 (Azobisisobutyro-nitrile 簡稱 AIBN )。例如： • Az〇dicarbonamide發泡劑在製造受熱過程中，會產生可能致癌 物質「鹽酸氨基脲semicarbazide (SEM)」；因而，此類化學發 泡劑與熔融塑膠混合製成之發泡塑膠，在類該化學發泡劑分解時 具有毒性殘留物存在發泡塑膠内，而造成人體接觸不安全情形， 且該殘留毒物具有不環保及汙染隱憂。 前述物理發泡劑可以是低沸點的有機化合物，如丁烷、戊 烷、石油醚、二氟二氯甲烷等；但該發泡劑有易燃性和毒物危險， 並有潛在空氣汙染問題，因而此種發泡劑技術使用受到限制。 M367088 此外為改善前述缺失，*有以無毒性的氣態惰性氣體作為物 理發泡劑的提出’並觀態_減體僅由加錢融塑膠方式不 易塑膠穩定混合，並產生發泡不均勾產品，因而前述以氣 悲惰性氣體作為物理發泡劑的方式並非可行。M367088 VIII. New description: [New technical field] This creation involves a kind of toy with physical hair_plastic material, which mainly refers to a toy made of pure gaseous gas Na_age age shape object ship (4). [Prior Art] The ship technology is a method of making a physical foaming agent or a chemical foaming touch molten plastic to obtain a foam molding. The foamed material obtained by the foaming technology has the characteristics of light weight, cushioning, heat insulation, sound absorption, shock absorption, etc., and reduces the cost of raw materials. Among them, chemical foaming is a time-consuming chemical reaction _ aero-plastic mixing system to make such a hair (four) wrinkle solid powder, and liberation of gas during heating, and - to make foaming, and reduce. Such chemical blowing agents are mostly organic azo compounds such as Azodicarbonamide and Azobisisobutyro-nitrile (abbreviated as AIBN). For example: • Az〇dicarbonamide foaming agent produces a possible carcinogen “semicarbazide hydrochloride (SEM)” during the manufacturing process; therefore, a foamed plastic made by mixing such a chemical foaming agent with molten plastic When the chemical foaming agent is decomposed, the toxic residue is present in the foamed plastic, which causes unsafe contact of the human body, and the residual poison has environmental protection and pollution concerns. The aforementioned physical blowing agent may be a low boiling organic compound such as butane, pentane, petroleum ether, difluoromethylene chloride, etc.; however, the blowing agent is flammable and toxic, and has potential air pollution problems. Thus the use of such blowing agent technology is limited. M367088 In addition, in order to improve the above-mentioned defects, * there is a non-toxic gaseous inert gas as a physical foaming agent's concept and the view body _ reduced body is only difficult to plastic stabilized by the addition of money and plastic, and produces uneven foaming products. Therefore, the aforementioned method of using a gas inert gas as a physical foaming agent is not feasible.
為了改善氣態的惰性氣體作為物理發泡劑不易獲得質量均 勻的發泡產品，有料提出靖臨界趙狀_惰性氣體作為物 理發泡劑的發泡方法，然而#由奴壓力、溫度產生超臨界惰性 氣體將造成製造成本增加情形，且為了該發泡產品有均勻的氣孔 與良好外觀而無_，常需額外使躲加劑，或化學發泡劑。 故而’ 述的單純物理發鋪制至射出發泡成型時，仍 存在許多技綱題未解決，所靴學發關運駐射出發 仍不得不被繼續採用。 ^ 此外因雜產品中多少有些許額外的添加物，而使塑料產 品無法有效回收再利用。 1習知如“子、板型、益智玩具、面具、玩偶、玩具手搶、塑 膠組合玩具·4玩具f制轉材質·製造崎低生產成 本^而^完全_料或添加少許添加物成型，造成用料成 本較向成品較重情形。 、為了獲得發泡材料具有的優良特性，與產品的外觀平整，以 及為了使發泡產品具有良好的表科觀而無絲，前述的物理發 泡劑的發泡方法’常f額外使 , w a化予發泡劑。此種狀 況對人脰縣泡產品接觸時，仍會 6 M367088 此外，發泡材料若是僅使用單純的物理發泡劑以獲得發泡成 型，也有助於環境保護的需要。 彖疋有種而求’僅使用單純的物理發泡劑而無額外添加 劑，使獲得的發泡歸簡，不含額相添加劑，簡免因添加 劑而產生殘留的安全隱憂，與避免造成環境汙染之問題；因而， 可以充分_發泡轉之伽，提升玩具產品實用功效。 【新型内容】 1乍之目的在採用純、氣體形成發泡劑與炼融塑膠混 合製造之發泡塑膠形成玩具，並可具質輕、減少塑料成本功效。 /創作具物理發_膠材制玩具，具㈣、氣態氣體， 其^態氣體可為氣態空氣或純氣態情性氣體，而該惰性氣體可 以疋氮孔、—氧化碳、…等’並該氣態氣體與塑料混合形成發 泡塑膠材料，而且該發泡塑膠材料具外層、内層，並該内層由 外層包覆’並外層為塑料、内層為塑料包覆氣泡，使得該發泡 塑膠材料可減少塑料用#，並可由内層之氣泡具質輕功效，又 該發泡塑騎料不_化學發泡劑，可確保域留有毒物質， 可避免人體接觸時危害人體，並可回收再利用，可具環保功效。 ，本創作之塑料可為PP聚丙稀、PE聚乙烯、ABS，並該發泡塑 膠材料的發泡比例氣態氣體為塑料之20%〜40%。 【實施方式】 请參閱第-圖’本創作具物理發泡塑膠材料的玩具，並可 製造如公仔、模型、益智玩具、面具、玩偶、玩具手搶、塑膠 M367088 組合玩具…等，並具塑料、氣態氣體，其氣態氣體可為氣態空 氣或純氣態惰性氣體，而該惰性氣體可以是氮氣、二氧化碳、... 等’並該氣態氣體與塑料混合形成發泡塑膠材料，而且該發泡 塑膠材料具外層11、内層12，並該内層12由外層11包覆，並外 層11為塑料、内層12為塑料包覆氣泡121，而該塑料可為pp聚丙 烯、PE聚乙烯、ABS，並該發泡塑膠材料的發泡比例氣態氣體為 塑料之20%〜40%，並使玩具可兼具質輕、減少塑料用量、環 • 保及具足夠強度功效，且因氣體本身膨脹使產品表面平整，可 避免射出保壓時表面不平整情況，並減少内應力，又可減少產 品在運送或使用中因溫度變化產生變形情況。 . 本創作製造前述玩具之發泡塑膠材料可採用創作人申請之 纟灣第_ 18655號、巾國公開細而Q77嶋號細氣態氣體 作發泡劑與溶融塑膠混合之物理塑膠發泡，並該案中將設定量 之氣態氣體與溶融塑膠混合後再藉由另一加壓方式使塑料與氣 • 態氣體可均勻混合，並可射出成型本創作具發泡塑膠材料的玩 具，使得可製造設定比概合物理發泡塑膠材料製造玩具，且 . 缝泡瓣㈣完全賴_解舰劑，可雜錢留毒性 物質，可避免人體接觸時危害人體，並可回收再糊，可具環 保功效，而本創作當然亦可由其他機具製造由氣態氣體作為發 泡劑之物理發泡塑膠玩具。 賴作成品因具奴比例之氣態氣體，因而可減低玩具重 量，Μ述實施形態係作為一例示，並非本創作限制，本創作可 M367088 而且本創作可在本創作 依需求採用其他塑料或其他發泡比例， 類似之範圍内改變及修正。 【圖式簡單說明】 【主要 第—圖係本創作之物理發泡塑膠材料 疋件符號說明】 11外層 構剖視示意圖。 12内層 121氣泡In order to improve the gaseous inert gas as a physical foaming agent, it is difficult to obtain a foamed product of uniform quality. It is proposed to use a foaming method as a physical foaming agent, but a supercritical inertia is generated by slave pressure and temperature. The gas will cause an increase in manufacturing cost, and for the foamed product to have uniform pores and good appearance without the need for additional additives, or chemical blowing agents. Therefore, there are still many technical problems that have not been solved in the simple physical development of injection molding, and the training of the boots has to be continued. ^ In addition, plastic products cannot be effectively recycled and reused due to some extra additives in the miscellaneous products. 1 I know such as "child, plate type, educational toys, masks, dolls, toy hand grabs, plastic combination toys, 4 toys, f-turning materials, manufacturing low-cost production costs ^ and ^ completely _ material or add a little additive molding , resulting in the material cost is heavier than the finished product. In order to obtain the excellent characteristics of the foamed material, the appearance of the product is flat, and in order to make the foamed product have a good view of the watch without silk, the aforementioned physical foaming The foaming method of the agent is often used to make a foaming agent. This condition will still be 6 M367088 when it is contacted with the people of the county. In addition, the foaming material uses only a simple physical foaming agent to obtain Foam molding also contributes to the need for environmental protection. 彖疋 There is a kind of demand for 'only use a simple physical foaming agent without additional additives, so that the obtained foam is reduced, no phase additive, no additives The problem of residual safety is avoided, and the problem of environmental pollution is avoided. Therefore, it is possible to fully enhance the practical effect of the toy product. [New content] The purpose of the 1乍 is to adopt a pure, gaseous shape. The foaming plastic made by mixing foaming agent and smelting plastic forms a toy, and can be light in weight and reduce the cost of plastic. / Create a physical hair _ rubber toy, with (4), gaseous gas, the gas can be a gaseous air or a pure gas atmosphere gas, and the inert gas may be a nitrogen gas hole, a carbon oxide, etc. and the gaseous gas is mixed with a plastic to form a foamed plastic material, and the foamed plastic material has an outer layer and an inner layer, and The inner layer is covered by the outer layer and the outer layer is made of plastic, and the inner layer is covered with plastic bubbles, so that the foamed plastic material can reduce the plastic use#, and the inner layer of the bubble can be light and light, and the foamed plastic riding material is not _ The chemical foaming agent can ensure the toxic substances in the domain, avoid harm to the human body when the human body comes into contact, and can be recycled and reused, which can be environmentally friendly. The plastics of this creation can be PP polypropylene, PE polyethylene, ABS, and The foaming ratio of the foamed plastic material is 20% to 40% of the plastic gas. [Embodiment] Please refer to the figure - the toy of the physical foam plastic material, and can be manufactured such as dolls, models, and benefits. Wisdom toys, masks, dolls, toy grabs, plastic M367088 combination toys, etc., and plastic, gaseous gas, the gaseous gas can be gaseous air or pure gaseous inert gas, and the inert gas can be nitrogen, carbon dioxide, ... And the gaseous gas is mixed with the plastic to form a foamed plastic material, and the foamed plastic material has an outer layer 11, an inner layer 12, and the inner layer 12 is covered by the outer layer 11, and the outer layer 11 is plastic, and the inner layer 12 is a plastic package. The bubble 121 is covered, and the plastic may be pp polypropylene, PE polyethylene, ABS, and the foaming proportion of the foamed plastic material is 20% to 40% of the plastic gas, and the toy can be both light and light. The amount of plastic, the ring and the protection have sufficient strength, and the surface of the product is flattened due to the expansion of the gas itself, which avoids the unevenness of the surface when the pressure is applied, reduces the internal stress, and reduces the temperature change during transportation or use. Deformation occurs. The foam plastic material of the above-mentioned toy can be foamed by the creator of the Tsuen Wan No. _ 18655, the towel of the country and the Q77 nickname of the fine gaseous gas as the foaming agent and the molten plastic. In this case, a set amount of gaseous gas is mixed with the molten plastic, and then the plastic and the gas can be uniformly mixed by another pressurization method, and the toy of the foamed plastic material can be injection molded, so that the manufacture can be made. Set the ratio of physical foam plastic materials to make toys, and. The foaming flaps (4) are completely dependent on the _ solution, can be mixed with toxic substances, can avoid human body contact when harming the human body, and can be recycled and paste, can be environmentally friendly However, this creation can of course also manufacture physical foam plastic toys made of gaseous gas as a foaming agent from other machines. Because the finished product is a gas with a slave ratio, it can reduce the weight of the toy. The description of the implementation is an example. It is not a limitation of this creation. This creation can be M367088 and this creation can use other plastics or other hairs according to the requirements. Bubble ratio, similar to the range of changes and corrections. [Simple description of the diagram] [Mainly - the picture is the physical foam plastic material of this creation. The symbol description of the element] 11 The outer structure is a schematic view. 12 inner layer 121 bubbles