TWI699238B - Deodorizing aerosol product - Google Patents
Deodorizing aerosol product Download PDFInfo
- Publication number
- TWI699238B TWI699238B TW107121440A TW107121440A TWI699238B TW I699238 B TWI699238 B TW I699238B TW 107121440 A TW107121440 A TW 107121440A TW 107121440 A TW107121440 A TW 107121440A TW I699238 B TWI699238 B TW I699238B
- Authority
- TW
- Taiwan
- Prior art keywords
- aerosol
- stock solution
- deodorization
- injection
- deodorizing
- Prior art date
Links
- 239000000443 aerosol Substances 0.000 title claims abstract description 199
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 91
- 239000002245 particle Substances 0.000 claims abstract description 118
- 239000011550 stock solution Substances 0.000 claims abstract description 89
- 238000004332 deodorization Methods 0.000 claims abstract description 72
- 238000012545 processing Methods 0.000 claims abstract description 61
- 238000002347 injection Methods 0.000 claims abstract description 59
- 239000007924 injection Substances 0.000 claims abstract description 59
- 239000003380 propellant Substances 0.000 claims abstract description 24
- 239000003960 organic solvent Substances 0.000 claims abstract description 15
- 239000007921 spray Substances 0.000 claims description 45
- 238000005507 spraying Methods 0.000 claims description 36
- 239000003205 fragrance Substances 0.000 claims description 35
- 239000000853 adhesive Substances 0.000 claims description 23
- 230000001070 adhesive effect Effects 0.000 claims description 23
- 239000004615 ingredient Substances 0.000 claims description 18
- 238000009826 distribution Methods 0.000 claims description 14
- -1 fatty acid esters Chemical class 0.000 claims description 8
- 150000001298 alcohols Chemical class 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 239000001707 (E,7R,11R)-3,7,11,15-tetramethylhexadec-2-en-1-ol Substances 0.000 claims description 4
- BLUHKGOSFDHHGX-UHFFFAOYSA-N Phytol Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C=CO BLUHKGOSFDHHGX-UHFFFAOYSA-N 0.000 claims description 4
- HNZBNQYXWOLKBA-UHFFFAOYSA-N Tetrahydrofarnesol Natural products CC(C)CCCC(C)CCCC(C)=CCO HNZBNQYXWOLKBA-UHFFFAOYSA-N 0.000 claims description 4
- BOTWFXYSPFMFNR-OALUTQOASA-N all-rac-phytol Natural products CC(C)CCC[C@H](C)CCC[C@H](C)CCCC(C)=CCO BOTWFXYSPFMFNR-OALUTQOASA-N 0.000 claims description 4
- BOTWFXYSPFMFNR-PYDDKJGSSA-N phytol Chemical compound CC(C)CCC[C@@H](C)CCC[C@@H](C)CCC\C(C)=C\CO BOTWFXYSPFMFNR-PYDDKJGSSA-N 0.000 claims description 4
- 239000000419 plant extract Substances 0.000 claims description 3
- 238000003825 pressing Methods 0.000 abstract description 5
- 235000019645 odor Nutrition 0.000 description 32
- 238000009792 diffusion process Methods 0.000 description 22
- 239000002781 deodorant agent Substances 0.000 description 19
- 239000007789 gas Substances 0.000 description 18
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 14
- 239000003814 drug Substances 0.000 description 14
- 229940079593 drug Drugs 0.000 description 14
- 238000004458 analytical method Methods 0.000 description 13
- 238000004088 simulation Methods 0.000 description 13
- 239000000126 substance Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 230000001464 adherent effect Effects 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 238000005259 measurement Methods 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 229910021529 ammonia Inorganic materials 0.000 description 7
- 238000004364 calculation method Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 230000001186 cumulative effect Effects 0.000 description 7
- 210000003608 fece Anatomy 0.000 description 7
- 210000002700 urine Anatomy 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000003915 liquefied petroleum gas Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 241000207199 Citrus Species 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 235000020971 citrus fruits Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 230000006399 behavior Effects 0.000 description 3
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 229940121375 antifungal agent Drugs 0.000 description 2
- 239000003429 antifungal agent Substances 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000002550 fecal effect Effects 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 description 1
- HMKKIXGYKWDQSV-SDNWHVSQSA-N 2-Pentyl-3-phenyl-2-propenal Chemical compound CCCCC\C(C=O)=C/C1=CC=CC=C1 HMKKIXGYKWDQSV-SDNWHVSQSA-N 0.000 description 1
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- MQVRGDZCYDEQML-UHFFFAOYSA-N Astragalin Natural products C1=CC(OC)=CC=C1C1=C(OC2C(C(O)C(O)C(CO)O2)O)C(=O)C2=C(O)C=C(O)C=C2O1 MQVRGDZCYDEQML-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 240000007108 Fuchsia magellanica Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- 235000011201 Ginkgo Nutrition 0.000 description 1
- 244000194101 Ginkgo biloba Species 0.000 description 1
- 235000008100 Ginkgo biloba Nutrition 0.000 description 1
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 235000019502 Orange oil Nutrition 0.000 description 1
- YPWHZCPMOQGCDQ-UHFFFAOYSA-N Populnin Natural products OC1C(O)C(O)C(CO)OC1OC1=CC(O)=C2C(=O)C(O)=C(C=3C=CC(O)=CC=3)OC2=C1 YPWHZCPMOQGCDQ-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- ZKEKDTIKFVCKMW-UHFFFAOYSA-N Trifolin Natural products OCC1OC(Oc2cc(O)ccc2C3=CC(=O)c4c(O)cc(O)cc4O3)C(O)C(O)C1O ZKEKDTIKFVCKMW-UHFFFAOYSA-N 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- TUFYVOCKVJOUIR-UHFFFAOYSA-N alpha-Thujaplicin Natural products CC(C)C=1C=CC=CC(=O)C=1O TUFYVOCKVJOUIR-UHFFFAOYSA-N 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- RBEXNLBQFJBXOY-UHFFFAOYSA-N benzaldehyde cumene Chemical compound C(C)(C)C1=CC=CC=C1.C(C1=CC=CC=C1)=O RBEXNLBQFJBXOY-UHFFFAOYSA-N 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- DHAZIUXMHRHVMP-UHFFFAOYSA-N butyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCC DHAZIUXMHRHVMP-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 239000010632 citronella oil Substances 0.000 description 1
- 239000001279 citrus aurantifolia swingle expressed oil Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000010639 cypress oil Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000013872 defecation Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000010642 eucalyptus oil Substances 0.000 description 1
- 229940044949 eucalyptus oil Drugs 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- 239000010651 grapefruit oil Substances 0.000 description 1
- 235000009569 green tea Nutrition 0.000 description 1
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940075495 isopropyl palmitate Drugs 0.000 description 1
- 239000010656 jasmine oil Substances 0.000 description 1
- JPUKWEQWGBDDQB-DTGCRPNFSA-N kaempferol 3-O-beta-D-galactoside Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1OC1=C(C=2C=CC(O)=CC=2)OC2=CC(O)=CC(O)=C2C1=O JPUKWEQWGBDDQB-DTGCRPNFSA-N 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 238000007561 laser diffraction method Methods 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- 239000007968 orange flavor Substances 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000000790 scattering method Methods 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 229930007845 β-thujaplicin Natural products 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/012—Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B9/00—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour
- B05B9/03—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material
- B05B9/04—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material with pressurised or compressible container; with pump
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/10—Apparatus features
- A61L2209/13—Dispensing or storing means for active compounds
- A61L2209/134—Distributing means, e.g. baffles, valves, manifolds, nozzles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Zoology (AREA)
- Botany (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Nozzles (AREA)
- Fats And Perfumes (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
本發明係提供一種消臭用氣溶膠，其係在廁所等之處理空間可發揮即效性、及持續性優異的消臭效果。 The present invention provides an aerosol for deodorization, which can exhibit immediate and excellent deodorizing effects in treatment spaces such as toilets.
本發明之消臭用氣溶膠係具備封入含有消臭成分與有機溶劑的氣溶膠原液及噴射劑而成之設置有定量噴射閥的耐壓容器，與設有噴射口連接於定量噴射閥的噴射按鈕；以按下1次噴射按鈕時之噴射容量成為0.1~0.4mL，且在噴射距離20cm的噴射力為以在25℃成為0.3~10.0g‧f之方式調整，以按下1次前述噴射按鈕而將耐壓容器內之氣溶膠原液噴射至2.5~3.5m3之處理空間時，經噴射的氣溶膠原液之50容量%以上為在60分鐘以內形成附著於處理空間內之露出部的附著性粒子之方式而構成。 The aerosol for deodorization of the present invention is provided with a pressure-resistant container equipped with a quantitative injection valve in which an aerosol stock solution containing a deodorizing component and an organic solvent and a propellant are enclosed, and a jet with an injection port connected to the quantitative injection valve Button; the injection volume when the injection button is pressed once becomes 0.1~0.4mL, and the injection force at the injection distance of 20cm is adjusted to become 0.3~10.0g‧f at 25℃, and the aforementioned injection is pressed once When the aerosol stock solution in the pressure-resistant container is sprayed into the processing space of 2.5~3.5m 3 by pressing the button, 50% or more of the sprayed aerosol stock solution will be attached to the exposed part of the processing space within 60 minutes The way of sex particles.
Description
本發明係關於消臭效果之即效性及持續性優異的消臭用氣溶膠。 The present invention relates to an aerosol for deodorization with excellent immediate effect and durability of the deodorizing effect.
作為用以消臭廁所空間之惡臭之製品，市售有已調配消臭成分的消臭劑。作為廁所空間用之消臭劑係已知靜置於室內而使消臭成分揮發而到持續的消臭效果的靜置型、或藉由噴霧而將消臭成分噴霧於室內的噴霧型等之各式各樣者，但其中尤其是排便後消臭臭氣的用途、或在外出目的地將臭氣強的廁所進行消臭的用途等，作為適於要求即效性的用途者，已知消臭用氣溶膠。 As a product used to deodorize the odor in the toilet space, deodorants that have been formulated with deodorizing ingredients are commercially available. As a deodorant for toilet spaces, there are known static types that are placed in a room to volatilize deodorizing ingredients to achieve a continuous deodorizing effect, or a spray type that sprays deodorizing ingredients into the room by spraying. There are various types, but among them, the use of deodorizing odor after defecation, or the use of deodorizing odorous toilets at the destination of going out, etc., are known as those suitable for applications requiring immediate effect. Smelly use aerosol.
於專利文獻1係開示使充分量之芳香劑之藥劑粒子迅速地擴散至處理空間，將滯留於氣中的惡臭藉由芳香劑之香味而遮蔽(masking)而得到消臭效果，同時於消臭後使芳香劑之香味很快地消失的消臭用氣溶膠。 In Patent Document 1, it is disclosed that a sufficient amount of fragrance particles can be rapidly diffused into the treatment space, and the malodor residing in the air can be masked by the fragrance of the fragrance to obtain a deodorizing effect. A deodorant aerosol that makes the fragrance of the fragrance disappear quickly.
[專利文獻1] 國際公開第2017/073478號 [Patent Document 1] International Publication No. 2017/073478
然而，如專利文獻1之方式，使藥劑粒子迅速地擴散至處理空間，之後使芳香劑之香味很快地消失的手法係對於繼續產生的惡臭係無法充分地帶來消臭效果，結果上消臭會變得不完全。只是說，一般住宅等之廁所係因為是2.5~3.5m3左右之狹小的空間，所以增加放出至處理空間的藥劑粒子之量之情事係會使在處理空間內的使用者強烈地感到藥劑粒子之芳香，特別是會擔心對不喜歡強烈的芳香的消費者會抱有不愉快感。 However, as in Patent Document 1, the method of rapidly dispersing the drug particles into the processing space and then quickly disappearing the fragrance of the fragrance does not have a sufficient deodorizing effect on the malodors that continue to be generated. Will become incomplete. It’s just that, because the toilets in general residences are in a narrow space of about 2.5~3.5m 3 , increasing the amount of drug particles released into the processing space will make users in the processing space feel strongly about the drug particles In particular, I am worried that consumers who do not like strong fragrances will feel unpleasant.
本發明係鑑於上述問題點所為者，其目的為提供一種消臭用氣溶膠，其係在廁所等之處理空間可發揮即效性、及持續性優異的消臭效果。 The present invention was made in view of the above-mentioned problems, and its object is to provide an aerosol for deodorization that can exhibit instantaneous and durable deodorizing effects in treatment spaces such as toilets.
用以解決上述課題之有關本發明的消臭用氣溶膠之特徵構成係一種消臭用氣溶膠，其係具備，封入含有消臭成分與有機溶劑的氣溶膠原液及噴射劑而成之設置有定量噴射閥的耐壓容器，與設有噴射口連接於前述定量噴射閥的噴射按鈕， 按下1次前述噴射按鈕時之噴射容量成為0.1~0.4mL，且在噴射距離20cm的噴射力為以在25℃成為0.3~10.0g‧f之方式調整， 按下1次前述噴射按鈕而將前述耐壓容器內之前述氣溶膠原液噴射至2.5~3.5m3 之處理空間時，經噴射的前述氣溶膠原液之50容量%以上為在60分鐘以內形成附著於前述處理空間內之露出部的附著性粒子之方式而構成。The characteristic structure of the deodorizing aerosol of the present invention to solve the above-mentioned problems is a deodorizing aerosol, which is provided with an aerosol stock solution containing a deodorizing component and an organic solvent and a propellant. The pressure-resistant container of the quantitative injection valve, and the injection button with the injection port connected to the aforementioned quantitative injection valve, the injection volume when the aforementioned injection button is pressed once becomes 0.1~0.4mL, and the injection force at an injection distance of 20cm is Adjust to 0.3~10.0g‧f at 25℃. When the aerosol stock solution in the pressure-resistant container is sprayed into the processing space of 2.5~3.5m 3 by pressing the spray button once, the sprayed gas The 50% by volume or more of the sol undiluted solution is configured to form adhesive particles attached to the exposed part in the processing space within 60 minutes.
在廁所之惡臭係不僅滯留於處理空間之氣中，來自飛散附著於壁面、地面等的尿等之惡臭源而繼續地產生。本發明者等係認為提昇對於由附著於壁面等的惡臭源產生的惡臭的消臭效果，是有關於對於在廁所之惡臭的消臭效果之提昇。因此，在關於本發明的消臭用氣溶膠係已被噴射於處理空間的氣溶膠原液之50容量%以上，設為形成附著性粒子者。所謂附著性粒子係由消臭用氣溶膠，將氣溶膠原液噴射於之2.5~3.5m3 之處理空間時所形成的噴射粒子之中，在噴射後60分鐘以內附著於處理空間內之露出部(例如，存在於廁所空間內的地面或壁面、便器等之構造物之表面等)的粒子。因此，可有效地消臭來自附著於露出部的惡臭源所產生的惡臭、以及滯留於處理空間之氣中的惡臭雙方，可使整個處理空間之消臭效果提昇。又，即使附著性粒子以外之噴射粒子(將此稱為「浮游性粒子」。)為遍及整個處理空間而擴散，處理空間中之氣溶膠原液之濃度係僅附著性粒子之份被降低。因此，在處理空間內的使用者吸入氣溶膠原液之粒子的量成為極微量，可抑制由氣溶膠原液本身所感覺到的過度的芳香。又，關於本發明的消臭用氣溶膠係按下1次噴射按鈕時之噴射容量成為0.1~0.4mL，且在噴射距離20cm的噴射力為以在25℃成為0.3~10.0g‧f之方式調整。以如此之方式調整噴射容量及噴射力，可形成合適的尺寸之附著性粒子，可顯現在廁所等之處理空間之優異的消臭效果。The odor in the toilet is not only retained in the air in the processing space, but also continuously generated from the source of odor such as urine that is scattered on the wall and the floor. The inventors of the present invention believe that the improvement of the deodorizing effect for malodors generated by malodor sources attached to the wall surface is related to the improvement of the deodorizing effect for malodors in toilets. Therefore, in the aerosol system for deodorization of the present invention, 50% or more of the volume of the aerosol stock solution sprayed into the processing space is regarded as the one that forms adhesive particles. The so-called adhering particles are sprayed particles formed when the aerosol for deodorization is sprayed into the treatment space of 2.5~3.5m 3 and adhere to the exposed part of the treatment space within 60 minutes after spraying. (For example, particles that exist on the floor or wall in the toilet space, the surface of structures such as toilets, etc.). Therefore, it is possible to effectively deodorize both the malodor generated from the malodor source attached to the exposed portion and the malodor remaining in the air in the processing space, and the deodorizing effect of the entire processing space can be improved. In addition, even if spray particles other than adherent particles (referred to as "floating particles") spread over the entire processing space, the concentration of the aerosol stock solution in the processing space is reduced only by the adherent particles. Therefore, the amount of particles of the aerosol stock solution inhaled by the user in the treatment space becomes extremely small, and it is possible to suppress the excessive fragrance felt by the aerosol stock solution itself. In addition, the deodorizing aerosol system of the present invention has a spray volume of 0.1 to 0.4 mL when the spray button is pressed once, and the spray force at a spray distance of 20 cm is such that it becomes 0.3 to 10.0 g‧f at 25°C Adjustment. By adjusting the spray capacity and spray force in this way, adhesive particles of suitable size can be formed, and an excellent deodorizing effect can be exhibited in treatment spaces such as toilets.
在關於本發明的消臭用氣溶膠中， 按下前述噴射按鈕而噴射前述耐壓容器內之前述氣溶膠原液時所形成的噴射粒子，其係在25℃、噴射距離15cm的體積累積分布之90%粒徑為40~60μm為理想。In the aerosol for deodorization of the present invention, the sprayed particles formed when the spray button is pressed to spray the aerosol stock solution in the pressure-resistant container are the cumulative distribution of the volume at 25°C and the spray distance of 15 cm The 90% particle size is ideally 40~60μm.
藉由將噴射粒子之粒徑調整至上述之最佳的範圍，噴射粒子之一部分成為附著性粒子，其餘部分成為浮游性粒子。因此，藉由本構成之消臭用氣溶膠，則飄盪在處理空間之氣中的惡臭、與附著於露出部的惡臭源所產生的惡臭，均可被消臭。By adjusting the particle size of the sprayed particles to the above-mentioned optimum range, a part of the sprayed particles becomes adhesive particles, and the remaining part becomes floating particles. Therefore, with the deodorizing aerosol of the present structure, both the malodors floating in the air in the treatment space and the malodors generated by the malodor source attached to the exposed part can be deodorized.
在關於本發明的消臭用氣溶膠中， 被封入前述耐壓容器的前述氣溶膠原液(a)與前述噴射劑(b)之容量比率（a/b）係10/90～50/50為理想。In the deodorizing aerosol of the present invention, the volume ratio (a/b) of the aerosol stock solution (a) and the propellant (b) enclosed in the pressure container is 10/90-50/50. ideal.
藉由本構成之消臭用氣溶膠，則在氣溶膠原液(a)與噴射劑(b)之容量比率（a/b）為上述之範圍的情況，藉由被噴射的氣溶膠原液而形成的附著性粒子與浮游性粒子之平衡成為最佳。藉由此，附著性粒子係可確實地到達處理空間內之露出部，又，浮游性粒子係可以不因過度的芳香而給予不愉快感之量，浮游於處理空間。如此，附著性粒子及浮游性粒子為各自以最佳的狀態存在，可分擔各自之角色而最大限度發揮消臭成分之效果。With the deodorizing aerosol of this structure, when the volume ratio (a/b) of the aerosol stock solution (a) to the propellant (b) is in the above range, it is formed by the sprayed aerosol stock solution The balance between adherent particles and floating particles is optimal. By this, the adhering particle system can reliably reach the exposed part in the processing space, and the floating particle system can float in the processing space without giving an unpleasant feeling due to excessive fragrance. In this way, the adhesive particles and the floating particles exist in their respective optimal states, and can share their roles to maximize the effect of the deodorizing ingredients.
在關於本發明的消臭用氣溶膠中， 前述有機溶劑係由高級脂肪酸酯及醇類所構成的群中選擇的至少1種為理想。In the aerosol for deodorization of the present invention, at least one selected from the group consisting of higher fatty acid esters and alcohols is preferred as the aforementioned organic solvent.
藉由本構成之消臭用氣溶膠，則作為有機溶劑，以使用高級脂肪酸酯或醇類，可使各成分之效果有效率地發揮。又，在已噴射氣溶膠原液的情況，可使附著性粒子及浮游性粒子平衡佳地形成，成為消臭效果安定者。With the deodorizing aerosol of this structure, higher fatty acid esters or alcohols are used as organic solvents, so that the effects of each component can be efficiently exhibited. In addition, when the aerosol stock solution has been sprayed, the adhering particles and the floating particles can be formed in a balanced manner, and the deodorizing effect can be stabilized.
在關於本發明的消臭用氣溶膠中， 前述消臭成分係包含植物萃取物及調和(harmonized)香料為理想。In the aerosol for deodorization related to the present invention, it is desirable that "the aforementioned deodorizing component system contains a plant extract and a harmonized fragrance."
藉由本構成之消臭用氣溶膠，則在廁所的糞尿臭等之惡臭被調和(harmonized)香料調和，可得到使惡臭被辨識為好的香味的感覺上的消臭之效果。With the deodorizing aerosol of the present composition, the odors such as feces and urine odors in the toilet are harmonized with harmonized fragrances, and a sensory deodorizing effect that makes the odors recognized as a good fragrance can be obtained.
在關於本發明的消臭用氣溶膠中， 前述噴射口係具有0.2~1.0mm之噴口徑為理想。In the aerosol for deodorization related to the present invention, it is desirable that the aforementioned injection port system has a nozzle diameter of 0.2 to 1.0 mm.
藉由本構成之消臭用氣溶膠，則在噴口徑為上述之範圍的情況，藉由被噴射的氣溶膠原液而形成的附著性粒子與浮游性粒子之平衡成為最佳。According to the deodorizing aerosol of this structure, when the nozzle diameter is in the above-mentioned range, the balance between the adherent particles and the floating particles formed by the sprayed aerosol stock solution becomes optimal.
在關於本發明的消臭用氣溶膠中， 前述氣溶膠原液係進而含有葉醇及/或葉醛為理想。In the aerosol for deodorization according to the present invention, it is preferable that the aerosol stock solution system further contains phytol and/or phyllaldehyde.
藉由本構成之消臭用氣溶膠，則以使可期待降低疲勞‧壓力等之放鬆效果的葉醇或葉醛含有於氣溶膠原液，可將由消臭用氣溶膠噴射氣溶膠原液的處理空間設為更愉快的空間。With the deodorizing aerosol of this structure, the phytol or phyllaldehyde, which can be expected to reduce fatigue, stress and other relaxation effects, is contained in the aerosol stock solution, and the processing space for spraying the aerosol stock solution by the deodorizing aerosol can be installed For a more pleasant space.
在關於本發明的消臭用氣溶膠中， 已噴射的前述氣溶膠原液係至120秒後擴散至前述整個處理空間為理想。In the aerosol for deodorization of the present invention, it is desirable that the sprayed aerosol stock solution spreads to the entire processing space after 120 seconds.
藉由本構成之消臭用氣溶膠，則因為已噴射的氣溶膠原液於120秒以內遍布整個處理空間而擴散，所以即使對於人之通常之利用廁所時間內滯留於天花板附近的惡臭、及滯留於地面附近的惡臭，均可發揮即效性優異的消臭效果。With the deodorizing aerosol of this structure, the sprayed aerosol stock solution spreads over the entire processing space within 120 seconds. Therefore, even for humans, the odor and odor staying near the ceiling during normal use of the toilet All the odors near the ground can exhibit an excellent deodorizing effect immediately.
在關於本發明的消臭用氣溶膠中，前述氣溶膠原液之空氣中濃度係由噴射開始至120秒後，在前述處理空間之95%以上中，成為0.0007ppm以上為理想。In the aerosol for deodorization of the present invention, the concentration in the air of the aerosol stock solution is preferably 0.0007 ppm or more in 95% or more of the processing space from the start of spraying to 120 seconds.
藉由本構成之消臭用氣溶膠，則氣溶膠原液之空氣中濃度為由噴射開始至120秒後，在處理空間之95%以上中，成為0.0007ppm以上，所以可從處理空間之天花板附近至地面附近，分布均勻地形成附著性粒子。With the deodorizing aerosol of this structure, the concentration of the aerosol stock solution in the air is 0.0007 ppm or more in 95% or more of the processing space from the start of spraying to 120 seconds, so it can be from near the ceiling of the processing space to Adhesive particles are evenly distributed near the ground.
在關於本發明的消臭用氣溶膠中， 作為前述處理空間係廁所為理想。Among the aerosols for deodorization related to the present invention, is ideal as the toilet for the treatment space.
藉由本構成之消臭用氣溶膠，則以附著性粒子附著於廁所之壁面、地面、便器等之露出部，對於正附著於露出部的惡臭源所產生的惡臭，可得到持續性的消臭效果。With the deodorizing aerosol of this structure, adherent particles are attached to the exposed part of the toilet wall, floor, toilet, etc., and the odor generated by the odor source attached to the exposed part can be continuously deodorized. effect.
本發明之消臭用氣溶膠係具備封入含有消臭成分與有機溶劑的氣溶膠原液及噴射劑而成之設置有定量噴射閥的耐壓容器，與設有噴射口連接於定量噴射閥的噴射按鈕 ; 按下噴射按鈕而噴射耐壓容器內之氣溶膠原液時，可將經噴射的氣溶膠原液之50容量%以上，作為附著性粒子而形成。所謂附著性粒子係由消臭用氣溶膠，將氣溶膠原液噴射於之2.5~3.5m3 之處理空間時所形成的噴射粒子之中，在噴射後60分鐘以內附著於處理空間內之露出部的噴射粒子。以下，關於本發明的消臭用氣溶膠進行說明。但是，本發明並無被限定於以下所說明的實施形態或記載於圖面的構成之意圖。The aerosol for deodorization of the present invention is provided with a pressure-resistant container equipped with a quantitative injection valve in which an aerosol stock solution containing a deodorizing component and an organic solvent and a propellant are enclosed, and a jet with an injection port connected to the quantitative injection valve Button; When the spray button is pressed to spray the aerosol stock solution in the pressure container, more than 50% of the sprayed aerosol stock solution can be formed as adhesive particles. The so-called adhering particles are sprayed particles formed when the aerosol for deodorization is sprayed into the treatment space of 2.5~3.5m 3 and adhere to the exposed part of the treatment space within 60 minutes after spraying. Of jet particles. Hereinafter, the aerosol for deodorization of the present invention will be described. However, the present invention is not intended to be limited to the embodiments described below or the configuration described in the drawings.
＜氣溶膠原液＞ [消臭成分] 氣溶膠原液之一個主成分的消臭成分係包含植物性消臭成分及調和(harmonized)香料為理想。植物性消臭成分係與呈現惡臭的臭氣物質反應而將惡臭消臭，所謂的具有化學性的消臭效果。作為如此的植物性消臭成分，可合適地選擇金鐘花、銀杏、無花果等之萃取物。此等之植物性消臭成分係單獨或混合狀態之任一均可使用。特別是，於植物性消臭成分係使用與酸性氣體及鹼性氣體任一者均進行反應而中和者為理想。或者是，亦可混合中和酸性氣體的植物性消臭成分、與中和鹼性氣體的植物性消臭成分而使用。<Aerosol stock solution> [Deodorant ingredient] It is desirable that the deodorant ingredient, which is one of the main components of the aerosol stock solution, contains a plant-based deodorant ingredient and a harmonized fragrance. The plant-derived deodorant component reacts with the malodorous substance to deodorize the malodor, and it has a so-called chemical deodorizing effect. As such a botanical deodorant ingredient, extracts of fuchsia, ginkgo, fig, etc. can be suitably selected. These botanical deodorant ingredients can be used alone or in a mixed state. In particular, it is preferable to use a plant-derived deodorant component that reacts with both acid gas and alkaline gas and neutralizes it. Alternatively, a plant-based deodorizing component that neutralizes acid gas and a plant-based deodorizing component that neutralizes alkaline gas may be mixed and used.
調和(harmonized)香料係意圖將糞尿臭等之惡臭作為香味構成要素之一而吸收而轉換為好的香味(香氣)而調香的香料。因此，調和(harmonized)香料係具有在作為香味之構成要素之一的惡臭存在的環境嗅聞，對人而言認識為好的香味之感覺上的消臭效果。以下，藉由感覺上的消臭效果，將降低因惡臭所致的不愉快感，表現為惡臭被調和。Harmonized fragrances are fragrances that are intended to absorb foul smell such as feces and urine as one of the fragrance components and convert them into a good fragrance (aroma) to be scented. Therefore, the harmonized fragrance system has a deodorizing effect in the sense of smell in the environment where the malodor as one of the constituent elements of the fragrance exists, and is recognized as a good fragrance by humans. In the following, the sensory deodorizing effect will reduce the unpleasant feeling caused by the foul odor, and the foul odor will be reconciled.
[有機溶劑] 氣溶膠原液之另一個主成分的有機溶劑係使用可溶解上述之消臭成分而調製氣溶膠原液，又，將已調製的氣溶膠原液噴射於處理空間時，可形成最合適的粒子者。作為有機溶劑係高級脂肪酸酯及醇類為理想。作為高級脂肪酸酯係碳數之總數為16~20者為理想，例如可舉出肉荳蔻酸異丙酯、肉荳蔻酸丁酯、月桂酸己酯、棕櫚酸異丙酯等。在此等之中，肉荳蔻酸異丙酯為特別合適。作為醇類係碳原子數2~3之低級醇為理想，例如可舉出乙醇、異丙醇、丙醇。在此等之中，乙醇為特別合適。於有機溶媒係例如亦可混合n-烷烴、及異烷烴等之烴系溶劑、或碳數3~6之二醇醚類、及酮系溶劑等。[Organic Solvent] The other main component of the aerosol stock solution is an organic solvent that can dissolve the above-mentioned deodorizing components to prepare the aerosol stock solution. In addition, when the prepared aerosol stock solution is sprayed into the processing space, the most suitable Particle person. It is ideal as organic solvent-based higher fatty acid esters and alcohols. It is preferable that the total number of carbon numbers of the higher fatty acid ester is 16-20, and examples thereof include isopropyl myristate, butyl myristate, hexyl laurate, isopropyl palmitate, and the like. Among these, isopropyl myristate is particularly suitable. The alcohols are preferably lower alcohols having 2 to 3 carbon atoms, and examples include ethanol, isopropanol, and propanol. Among these, ethanol is particularly suitable. In the organic solvent system, for example, hydrocarbon solvents such as n-alkanes and isoalkanes, or glycol ethers with 3 to 6 carbon atoms, and ketone solvents, etc. may be mixed.
[其他成分] 本發明之消臭用氣溶膠係除了上述成分以外，亦可將芳香劑、以黴類或菌類等作為對象的防黴劑、抗菌劑、殺菌劑、安定劑、防帶電劑、消泡劑、賦形劑等適宜地調配於氣溶膠原液。例如，以氣溶膠原液含有芳香劑，可藉由芳香劑之香氣而遮蔽飄盪在處理空間的惡臭。作為芳香劑係可舉出橙油、檸檬油、薰衣草油、薄荷油、尤加利油、香茅油、萊姆油、柚子油、茉莉油、檜油、綠茶精油、檸檬烯、α-蒎烯、沉香醇、香葉醇、苯乙醇、戊基肉桂醛、異丙基苯甲醛、苄基乙酸酯等之芳香成分、調配被稱為「綠色之香味」的葉醇(cis-3-hexenol)或葉醛之香料成分等。藉由芳香劑之調配而將氣溶膠原液設為柑橘、玫瑰及薰衣草等之香調，可滿足消費者之嗜好性。又，藉由調配可期待降低疲勞‧壓力等之放鬆效果的葉醇，將消臭用氣溶膠噴射於廁所時，可將廁所設為較愉快的空間。作為防黴劑、抗菌劑及殺菌劑係可舉出檜醇、2-巰基苯并噻唑、2-（4-噻唑基）苯并咪唑、5-氯-2-甲基-4-異噻唑啉-3-酮、三葉豆苷(trifolin)、3-甲基-4-異丙基苯酚、鄰苯基苯酚等。[Other components] The aerosol system for deodorization of the present invention, in addition to the above-mentioned components, may also contain fragrances, antifungal agents, antibacterial agents, bactericides, stabilizers, antistatic agents, etc. that target molds or fungi. Defoamers, excipients, etc. are suitably formulated in the aerosol stock solution. For example, if the aerosol stock solution contains fragrance, the fragrance of the fragrance can mask the bad smell floating in the processing space. Examples of the fragrance system include orange oil, lemon oil, lavender oil, peppermint oil, eucalyptus oil, citronella oil, lime oil, grapefruit oil, jasmine oil, cypress oil, green tea essential oil, limonene, α-pinene , Linalool, geraniol, phenethyl alcohol, amylcinnamaldehyde, cumene benzaldehyde, benzyl acetate and other aromatic ingredients, the blending is called ``green fragrance'' (cis-3-hexenol) ) Or the fragrance ingredients of folic aldehyde. Through the blending of fragrances, the original aerosol solution can be made into the fragrance of citrus, rose and lavender, which can satisfy consumers' preferences. In addition, by mixing phytol, which is expected to reduce fatigue and stress, and spraying deodorant aerosol in the toilet, the toilet can be set as a more pleasant space. Examples of antifungal agents, antibacterial agents, and bactericide systems include hinokitiol, 2-mercaptobenzothiazole, 2-(4-thiazolyl)benzimidazole, 5-chloro-2-methyl-4-isothiazoline -3-one, trifolin, 3-methyl-4-isopropylphenol, o-phenylphenol, etc.
＜噴射劑＞ 作為在本發明之消臭用氣溶膠所使用的噴射劑係可舉出液化石油氣(LPG)、二甲基醚(DME)、氮氣氣體、碳酸氣體、一氧化二氮、壓縮空氣等。上述之噴射劑係可單獨或以混合狀態使用，但將LPG作為主成分者為容易使用。<Propellant> As the propellant used in the deodorizing aerosol of the present invention, liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas, nitrous oxide, compressed Air etc. The above-mentioned propellant can be used alone or in a mixed state, but it is easy to use LPG as the main component.
本發明之消臭用氣溶膠係氣溶膠原液(a)與噴射劑(b)之容量比率(a/b)，以成為10/90～50/50之方式調整。藉由調整至如此的範圍，則可將經噴射的氣溶膠原液之至少一部分作為附著性粒子而形成。藉由此，附著性粒子係可確實地到達處理空間內之露出部，又，浮游性粒子係可以不因過度的芳香而給予不愉快感之量，浮游於處理空間。又，在形成附著性粒子與浮游性粒子之雙方的情況係兩者之平衡成為最佳。如此，附著性粒子及浮游性粒子係各自以最佳的狀態存在，可分擔各自之角色而最大限度發揮消臭效果。若將容量比率(a/b)變為小於10/90，亦即，若將封入耐壓容器內的噴射劑(b)之比例變大，則因為被噴射的氣溶膠原液被超過必要地微細化，所以附著性粒子減少。藉由此，因為附著於處理空間內之露出部的附著性粒子不足，所以無法將來自附著於露出部的惡臭源繼續地產生的惡臭充分地消臭，有消臭效果之持續性不足的情況。另一方面，若將容量比率(a/b)變為大於50/50，亦即，若將封入耐壓容器內的噴射劑(b)之比例變小，則因為難以將被噴射的氣溶膠原液形成作為具有最佳的範圍之粒徑的附著性粒子、及浮游性粒子，所以一噴射氣溶膠原液就立刻沈降。因此，在處理空間浮游的浮游性粒子為在數量上不足，變得難以將惡臭迅速地消臭。The volume ratio (a/b) of the aerosol-based aerosol stock solution for deodorization of the present invention (a) and propellant (b) is adjusted so as to be 10/90-50/50. By adjusting to such a range, at least a part of the sprayed aerosol stock solution can be formed as adhesive particles. By this, the adhering particle system can reliably reach the exposed part in the processing space, and the floating particle system can float in the processing space without giving an unpleasant feeling due to excessive fragrance. In addition, in the case of forming both adhesive particles and floating particles, the balance between the two is optimal. In this way, the adhering particles and the floating particles exist in their optimal states, and can share their roles to maximize the deodorizing effect. If the volume ratio (a/b) is reduced to less than 10/90, that is, if the ratio of the propellant (b) enclosed in the pressure-resistant container is increased, the aerosol stock solution to be sprayed is finer than necessary As a result, the adhesive particles are reduced. As a result, since the adherent particles attached to the exposed portion in the processing space are insufficient, the malodor continuously generated from the malodor source attached to the exposed portion cannot be sufficiently deodorized, and the persistence of the deodorizing effect may be insufficient. . On the other hand, if the volume ratio (a/b) is greater than 50/50, that is, if the ratio of the propellant (b) enclosed in the pressure vessel is reduced, it is difficult to remove the sprayed aerosol The stock solution is formed into adhesive particles and floating particles having a particle size in the optimal range, so the stock solution of aerosol immediately settles as soon as it is sprayed. Therefore, the floating particles floating in the treatment space are insufficient in number, and it becomes difficult to quickly deodorize malodors.
＜消臭用氣溶膠＞ 如上述之方式，選擇消臭成分、有機溶劑、噴射劑、其他按照必要而調配的成分，以將此等封入耐壓容器，完成氣溶膠製品。此氣溶膠製品係本發明之消臭用氣溶膠，噴射氣溶膠原液於處理空間者。氣溶膠原液係主要是由消臭成分和有機溶劑所構成者，嚴格來說係與噴射劑為不同者，但氣溶膠原液係與噴射劑同時被放出至耐壓容器之外部，所以在以下之說明係有將包含氣溶膠原液及噴射劑的氣溶膠內容物作為「氣溶膠原液」而操作的情況。<Aerosol for deodorization> As described above, select deodorant ingredients, organic solvents, propellants, and other ingredients that are blended as necessary to seal them in a pressure-resistant container to complete the aerosol product. This aerosol product is the aerosol for deodorization of the present invention, which sprays the aerosol stock solution into the treatment space. The aerosol stock solution system is mainly composed of deodorizing ingredients and organic solvents. Strictly speaking, it is different from the propellant. However, the aerosol stock solution system and the propellant are discharged to the outside of the pressure vessel at the same time, so the following It is explained that there is a case where an aerosol content containing an aerosol stock solution and a propellant is handled as an "aerosol stock solution".
以下，關於有關本發明的消臭用氣溶膠所具備的噴射閥進行說明。關於本發明的消臭用氣溶膠係主要是由耐壓容器(氣溶膠容器)、定量噴射閥、及噴射按鈕所構成。於定量噴射閥係被連接用以噴射氣溶膠原液之作動部的噴射按鈕，於噴射按鈕係設置由氣溶膠容器向外部(處理空間)噴出的噴射口。Hereinafter, the injection valve included in the deodorizing aerosol of the present invention will be described. The aerosol system for deodorization concerning the present invention is mainly composed of a pressure-resistant container (aerosol container), a quantitative injection valve, and an injection button. The quantitative injection valve is connected to the injection button of the actuator for injecting the aerosol stock solution, and the injection button is provided with an injection port for ejecting from the aerosol container to the outside (processing space).
在已按下1次消臭用氣溶膠之噴射按鈕的情況，藉由噴射劑之壓力而定量噴射閥作動，耐壓容器內之氣溶膠原液上昇至噴射口，被噴射於處理空間。此時之氣溶膠原液之噴射容量係被調整至0.1～0.4mL，較理想為0.2～0.4mL。如為如此的範圍，則氣溶膠原液之至少一部分作為附著性粒子而形成。又，在形成附著性粒子、及浮游性粒子之雙方的情況，係各自在處理空間以可發揮最佳的消臭效果之方式而平衡佳地形成。如噴射容量為未達0.1mL，則因為噴射容量過少，所以附著性粒子無法充分地附著於處理空間內之露出部，變得難以將來自正附著於露出部的惡臭源持續地產生的惡臭進行消臭。又，因為浮游性粒子亦變少，所以在處理空間飄盪於氣中的惡臭的消臭亦成為不充分。另一方面，若噴射容量超過0.4mL，則因為於處理空間超過必要地放出氣溶膠原液，所以有對不喜歡強烈的芳香的消費者帶來不愉快感的疑慮，又，因為氣溶膠原液之使用量亦變得過大，所以在經濟上亦為不利。When the aerosol injection button for deodorization has been pressed once, the quantitative injection valve is actuated by the pressure of the propellant, and the aerosol stock solution in the pressure-resistant container rises to the injection port and is injected into the processing space. At this time, the spray volume of the aerosol stock solution is adjusted to 0.1～0.4mL, preferably 0.2～0.4mL. If it is in such a range, at least a part of the aerosol stock solution is formed as adhesive particles. In addition, in the case of forming both the adhesive particles and the floating particles, they are formed in a well-balanced manner in the processing space so as to exert the best deodorizing effect. If the ejection volume is less than 0.1 mL, the ejection volume is too small, so the adherent particles cannot sufficiently adhere to the exposed part in the processing space, and it becomes difficult to remove the odor that is continuously generated from the odor source attached to the exposed part. Deodorize. In addition, since the floating particles are also reduced, the deodorization of malodors floating in the air in the treatment space is also insufficient. On the other hand, if the ejection volume exceeds 0.4 mL, the aerosol stock solution is released more than necessary in the processing space, so there is a concern that consumers who do not like strong aromas will feel unpleasant, and because of the use of the aerosol stock solution The amount has also become too large, so it is economically disadvantageous.
消臭用氣溶膠，係以在從噴射口之距離為20cm之處所的噴射力為在25℃，成為0.3~10.0g‧f之方式進行調整。如為如此的範圍，則藉由1次之噴射，可使由氣溶膠原液所形成的附著性粒子平滑地到達處理空間內之露出部，可使消臭成分之效果迅速地發揮。更進一步，噴射口之噴口徑係設定為0.2~1.0mm為理想。如為此之範圍，則可合適地調整上述之粒徑、及噴射力，經噴射於處理空間的氣溶膠原液之至少一部分為最佳地形成作為附著性粒子，可由正附著於露出部的惡臭源繼續地產生的惡臭進行消臭。The aerosol for deodorization is adjusted so that the spray force at a distance of 20cm from the spray port becomes 0.3~10.0g‧f at 25℃. In such a range, the adhesive particles formed by the aerosol stock solution can smoothly reach the exposed part in the processing space by one injection, and the effect of the deodorant component can be quickly exhibited. Furthermore, it is ideal to set the nozzle diameter of the nozzle to 0.2~1.0mm. Within this range, the above-mentioned particle size and spraying force can be adjusted appropriately, and at least a part of the aerosol stock solution sprayed into the processing space is optimally formed as adhesive particles, and the offensive smell adhering to the exposed part The malodor generated continuously by the source is deodorized.
由消臭用氣溶膠噴射的噴射粒子之粒徑係被調整在25℃、噴射距離15cm的累積體積分布之90%粒徑為40~60μm為理想。如為如此的範圍，則氣溶膠原液為經噴射於2.5~3.5m3 之處理空間時，將被噴射的氣溶膠原液之50容量%以上，可作為附著性粒子形成，充分的量之附著性粒子可迅速地移動、附著至處理空間內之露出部。因此，可將來自正附著於露出部的惡臭源繼續地產生的惡臭，藉由附著性粒子之消臭成分而消臭。若噴射粒子之粒徑在25℃、噴射距離15cm的累積體積分布之90%粒徑未達40μm，則因為粒徑過小，所以很多粒子成為難以到達露出部，不形成充分的量之附著性粒子。結果，變為難以將來自正附著於露出部的惡臭源繼續地產生的惡臭，有效地消臭。另一方面，若粒徑超過60μm，則因為粒徑過大，所以變得難以控制附著性粒子之行為，變得難以合適地附著於露出部。The particle size of the sprayed particles sprayed by the aerosol for deodorization is preferably adjusted at 25°C, and the cumulative volume distribution of the spraying distance of 15 cm has a 90% particle size of 40-60 μm. If it is in this range, when the aerosol stock solution is sprayed into a processing space of 2.5~3.5m 3 , 50% or more of the sprayed aerosol stock solution can be formed as adhesive particles and sufficient adhesion The particles can move quickly and adhere to the exposed part in the processing space. Therefore, the malodor that is continuously generated from the malodor source adhering to the exposed portion can be deodorized by the deodorizing component of the adherent particles. If the particle size of the sprayed particles is 25°C and the 90% particle size of the cumulative volume distribution at a spray distance of 15cm is less than 40μm, the particle size is too small, so many particles will hardly reach the exposed part, and a sufficient amount of adhesive particles will not be formed . As a result, it becomes difficult to effectively deodorize the malodor that is continuously generated from the malodor source adhering to the exposed portion. On the other hand, if the particle size exceeds 60 μm, the particle size is too large, and it becomes difficult to control the behavior of the adhesive particles, and it becomes difficult to properly adhere to the exposed portion.
進而，噴射粒子之粒徑係在25℃、噴射距離15cm的累積體積分布之10%粒徑為被調整為5μm以下，50%粒徑被調整為20~40μm為較理想。具有如此的累積體積分布的噴射粒子係粒徑之分布寬度為寬。此結果，由消臭用氣溶膠，將氣溶膠原液噴射1次到處理空間，則形成具有較大的粒徑的附著性粒子、與具有較小的粒徑的浮游性粒子。Furthermore, the particle size of the sprayed particles is adjusted to be 5μm or less for 10% particle size of the cumulative volume distribution at 25°C and a spraying distance of 15cm, and it is desirable that the 50% particle size is adjusted to 20-40μm. The particle size distribution width of the sprayed particle system having such a cumulative volume distribution is wide. As a result, by spraying the aerosol stock solution once into the treatment space from the deodorizing aerosol, adhesive particles having a larger particle diameter and floating particles having a smaller particle diameter are formed.
浮游性粒子係因為形成作為小於附著性粒子的粒徑，所以在氣溶膠原液被噴射於處理空間時，可迅速地擴散，且浮游於處理空間。因此，可將在處理空間中滯留於氣中的惡臭，藉由浮游性粒子之消臭成分而消臭。如此，以被噴射的氣溶膠原液之中一部分形成浮游性粒子之方式，藉由將粒徑調整為如上述般的最佳的範圍，浮游性粒子變為顯現與附著性粒子不同的行為，可與附著性粒子一起有效地將惡臭消臭。Since the floating particles are formed to have a smaller particle size than the adhesive particles, when the aerosol stock solution is sprayed into the processing space, it can quickly diffuse and float in the processing space. Therefore, it is possible to deodorize the foul odor remaining in the air in the processing space by the deodorizing component of the floating particles. In this way, a part of the sprayed aerosol stock solution forms floating particles, and by adjusting the particle size to the optimum range as described above, the floating particles exhibit a behavior different from that of the adhesive particles. Together with the adhesive particles, it effectively deodorizes bad odors.
＜擴散模擬＞ 第1圖係將關於本發明的消臭用氣溶膠噴射於3m3 之處理空間時之擴散模擬之說明圖。關於利用於第1圖之擴散模擬的藥劑濃度之解析手法，於以下說明。<Diffusion simulation> Figure 1 is an explanatory diagram of the diffusion simulation when the aerosol for deodorization of the present invention is sprayed into a 3 m 3 processing space. The analysis method of the drug concentration used in the diffusion simulation of Figure 1 will be described below.
當解析藥劑濃度時，將隨著時間之進行而藥劑(氣溶膠原液)擴散的狀況，作為解析結果輸出。最初，藉由氣流算出手段，到將風速、溫度等之空間分布成為穩定狀態才進行解析，接著，由氣溶膠製品使藥劑產生，使用已解析的風速分布等，藉由濃度算出手段，將藥劑濃度之空間分布藉由穩定解析而預測。又，將濃度分布之因時間所致的變化，藉由瞬態解析而預測。When analyzing the concentration of the drug, the diffusion of the drug (aerosol stock solution) over time is output as the analysis result. Initially, analysis is performed by airflow calculation means until the spatial distribution of wind speed, temperature, etc. becomes a stable state. Next, the aerosol product generates the drug, and the analyzed wind speed distribution is used to calculate the concentration of the drug. The spatial distribution of the concentration is predicted by stable analysis. In addition, the time-induced changes in the concentration distribution are predicted by transient analysis.
氣流算出手段係在模擬空間，藉由將3維之平流擴散方程式藉由有限差分法而離散化而在數值上求解，求出氣流之速度及氣流之方向(風速、風向)‧空氣之溫度(以下有稱為「氣流狀態」之情事)的手段。氣流算出手段係關於根據將氣流之速度及方向、以及壓力之各運動要素設為變數的納維-斯托克斯方程式(Navier–Stokes equations)的k-ε紊流模式(由動量之輸送方程式(1)、紊流能量之輸送方程式(2)、及紊流消散率之輸送方程式(3)所構成)、熱量之輸送方程式(4)、及由連續之式](5)~(8)所構成的前述平流擴散方程式，在各微小分割區域之相鄰的格子點間，使用在每個微小時間藉由有限差分法所得的數值解析而重複進行計算，在前述各格子點間之風速、風向、氣溫及風壓成為特定之平衡狀態的情況，以可用該值而決定作為前述各格子點之預測風速資料、預測風向資料、及預測氣溫資料之方式構成。 [動量之輸送方程式]The airflow calculation method is in the simulation space. The 3D advection diffusion equation is discretized by the finite difference method and solved numerically. The airflow velocity and the airflow direction (wind speed, direction) ‧ air temperature ( Hereinafter, there is a means called "air flow state". The air flow calculation method is based on the k-ε turbulence model of the Navier-Stokes equations (Navier-Stokes equations) that set the velocity and direction of the air flow, and the motion elements of the pressure as variables (from the momentum transport equation) (1), turbulence energy transport equation (2), and turbulent dissipation rate transport equation (3)), heat transport equation (4), and continuous equation) (5) ~ (8) The aforesaid advection diffusion equation is repeatedly calculated between adjacent grid points of each minute division area using numerical analysis obtained by the finite difference method at each minute time. The wind speed between the aforementioned grid points, When the wind direction, temperature, and wind pressure become a specific equilibrium state, the value can be used to determine the predicted wind speed data, predicted wind direction data, and predicted temperature data of the aforementioned grid points. [Momentum transport equation]
【數1】
【數2】
【數3】
【數4】
【數5】
濃度算出手段係在模擬空間，關於設為對象的藥劑，藉由將3維之濃度擴散支配方程式藉由有限差分法而離散化而在數值上求解，求出濃度分布的手段。亦即，濃度算出手段係在已算出的微小分割區域的各格子點之氣流狀態(預測風速資料、預測風向資料、及預測氣溫資料)、以及擴散物質之產生量設為給定時，關於由藥劑(擴散物質)之輸送方程式(9)所構成的濃度擴散支配方程式，在各微小分割區域之相鄰的格子點間，使用在每個微小時間藉由有限差分法所得的數值解析而重複進行計算，在前述各格子點間之藥劑濃度成為平衡狀態的情況，以用該值而決定作為前述各格子點之預測藥劑濃度資料之定態解之方式構成。更進一步，在重複進行計算的過程，藉由將微小時間之累積值、和在該時間的各微小分割區域之藥劑濃度，藉由每個事先已決定的特定時間進行記錄，亦可決定預測藥劑濃度資料之非定態解。又，藉由將擴散物質之產生量設為無因次量，將預測藥劑濃度資料，並非作為絕對值而是亦可作為對應擴散物質之產生量的相對值而進行預測。 [擴散物質之輸送方程式]The concentration calculation means is in the simulation space. Regarding the target drug, the three-dimensional concentration diffusion formula formula is discretized by the finite difference method and solved numerically to obtain the concentration distribution. That is, the concentration calculation method is based on the calculated airflow state (predicted wind speed data, predicted wind direction data, and predicted temperature data) at each grid point of the calculated micro-segmented area, and the amount of diffused material generated is set at a given time. The formula of concentration diffusion branch formed by the transport equation (9) of (diffusible substance), between the adjacent grid points of each small divided area, uses the numerical analysis obtained by the finite difference method at each minute time to repeat the calculation When the drug concentration between the grid points is in equilibrium, the value is used to determine the steady-state solution as the predicted drug concentration data for each grid point. Furthermore, in the process of repeating the calculation, by recording the cumulative value of the minute time and the drug concentration in each minute divided area at that time, by recording each specific time determined in advance, the predicted drug can also be determined Unsteady state solution of concentration data. In addition, by setting the amount of diffusion material generated as a dimensionless amount, the predicted drug concentration data can be predicted not as an absolute value but as a relative value corresponding to the amount of diffusion material generated. [Conveying equation of diffusion material]
【數6】
解析對象係如第1(a)圖所示，設定於約3m3
之處理空間(寬78cm×深169cm×天花板高230cm)配置使用者2、及噴射口1a朝向斜上方的消臭用氣溶膠1的解析形狀。將此解析形狀及處理空間分割為解析格子。The analysis target is as shown in Fig. 1(a), which is set in a processing space of approximately 3m 3 (width 78cm×depth 169cm×ceiling height 230cm) to dispose the
解析條件係設定為風速0m/秒，室內外之發熱‧溫度之影響係無視。藉由消臭用氣溶膠1之噴射口1a，將每1次之噴射容量設定為0.2mL、將在從噴射口至20cm之距離之噴射力在25℃設定為2.9 g‧f，噴射氣溶膠原液，實施已擴散的氣溶膠原液之空氣中濃度之空間分布之解析。The analysis conditions are set to wind speed of 0m/s, and the influence of heat and temperature indoors and outdoors is ignored. With the
第1(b)圖係由消臭用氣溶膠1將氣溶膠原液噴射1次於處理空間後，顯現10秒後、30秒後、60秒後、120秒後及170秒後之氣溶膠原液之空氣中濃度(ppm)的擴散模擬之結果影像。在第1(b)圖係在各影像於氣溶膠原液之空氣中濃度為0.0007ppm的區域附上符號A。藉由上述之解析，如第1(b)圖所示之方式，噴射後，氣溶膠原液係迅速地擴散，從噴射於60秒後係從處理空間之天花板面到達至地面，得到從噴射至120秒後係擴散進行至整個處理空間的結果。在此所謂「擴散至整個處理空間」係以第1(b)圖之120秒後之影像所示之方式，在處理空間之95%以上之容量中氣溶膠原液之空氣中濃度成為0.0007ppm以上的狀態。順帶一提，因為人之通常之廁所利用時間為5~15分左右，所以向廁所空間全體之氣溶膠原液之擴散時間如為120秒，則於廁所利用時間內可充分地進行消臭。更進一步，由噴射至170秒後係擴散至整個處理空間之氣溶膠原液之濃度成為一樣。因此，噴射後經過充分的時間，附著性粒子就結束向處理空間內之壁面、地面及天花板面之全部之表面之附著，維持已附著的狀態。於是，依上述，將來自正附著於露出部的惡臭源繼續地產生的惡臭，藉由消臭成分而消臭。Figure 1(b) shows the aerosol stock solution after spraying the aerosol stock solution once into the treatment space by the aerosol for deodorization 1 after 10 seconds, 30 seconds, 60 seconds, 120 seconds, and 170 seconds. The result image of the diffusion simulation of the air concentration (ppm). In Figure 1(b), the symbol A is attached to the area where the concentration of each image in the air of the aerosol stock solution is 0.0007 ppm. According to the above analysis, as shown in Figure 1(b), after spraying, the aerosol stock solution diffuses rapidly. After 60 seconds of spraying, it reaches from the ceiling surface of the processing space to the ground. After 120 seconds, it is the result of diffusion to the entire processing space. The so-called "diffusion to the entire processing space" here is shown in the image 120 seconds later in Figure 1(b), where the concentration of the aerosol stock solution in the air becomes 0.0007 ppm or more in the volume of more than 95% of the processing space. status. By the way, since the normal toilet use time of a person is about 5~15 minutes, if the diffusion time of the aerosol stock solution to the entire toilet space is 120 seconds, the deodorant can be fully deodorized during the toilet use time. Furthermore, the concentration of the aerosol stock solution diffused to the entire processing space becomes the same after being sprayed for 170 seconds. Therefore, after sufficient time has elapsed after spraying, the adhesion of the adherent particles to all surfaces of the wall, floor, and ceiling surfaces in the processing space is completed, and the adhered state is maintained. Then, according to the above, the malodor continuously generated from the malodor source adhering to the exposed portion is deodorized by the deodorizing component.
另一方面，浮游性粒子係消臭成分為徐徐地揮發，將處理空間之滯留於氣中的惡臭進行消臭。特別是在廁所之惡臭係有因氨等所致的尿臭、及因硫化氫、甲基硫醇等所致的糞臭，氨係較空氣輕，容易滯留於天花板附近，硫化氫、甲基硫醇係比空氣重而容易滯留於地面附近。但是，如第1(b)圖所示之方式，從消臭用氣溶膠1經噴射的氣溶膠原液係從噴射至120秒後遍布整個處理空間而擴散，所以滯留於天花板附近的惡臭、及滯留於地面附近的惡臭，均可藉由浮游性粒子而消臭。尚，氨為鹼性氣體，硫化氫及甲基硫醇為酸性氣體。氣溶膠原液為含有均可與鹼性氣體及酸性氣體反應而中和的消臭成分，任何種類之臭氣物質均可藉由化學性的消臭而消臭。作為上述之消臭成分，理想為使用可與鹼性氣體反應而中和的植物性消臭成分及可與酸性氣體反應而中和的植物性消臭成分之混合物、或均可與鹼性氣體及酸性氣體之反應而中和的植物性消臭成分。On the other hand, the floating particle-based deodorizing component evaporates slowly, and deodorizes the malodor remaining in the air in the processing space. In particular, the odor of toilets includes urine odor caused by ammonia, and fecal odor caused by hydrogen sulfide and methyl mercaptan. Ammonia is lighter than air and tends to stay near the ceiling. Mercaptans are heavier than air and tend to stay near the ground. However, as shown in Fig. 1(b), the aerosol stock solution sprayed from the deodorizing aerosol 1 spreads over the entire processing space after 120 seconds from spraying, so the odor staying near the ceiling, and The foul odor staying near the ground can be deodorized by floating particles. Still, ammonia is an alkaline gas, hydrogen sulfide and methyl mercaptan are acid gases. The aerosol stock solution contains deodorizing components that can react with alkaline gas and acid gas to neutralize. Any kind of odorous substance can be deodorized by chemical deodorization. As the above-mentioned deodorizing component, it is desirable to use a mixture of a vegetable deodorizing component that can react with alkaline gas to neutralize and a vegetable deodorizing component that can react with acid gas to neutralize, or both can be used with alkaline gas A plant-based deodorizing ingredient neutralized by the reaction of acid gas.
如此，關於本發明的消臭用氣溶膠係因為是由經噴射的氣溶膠原液形成的粒子為行為不同的2種之粒子，所以各自之粒子為以最佳的狀態存在，可分擔各自之角色而最大限度發揮消臭效果。因此，藉由附著性粒子及浮游性粒子，對於在處理空間滯留於氣中的惡臭、及由正附著於處理空間內之露出部的惡臭源產生的臭氣之任一者，均可發揮優異的消臭效果。In this way, regarding the aerosol system for deodorization of the present invention, because the particles formed from the sprayed aerosol stock solution are two kinds of particles with different behaviors, the respective particles exist in the best state and can share their roles. And maximize the deodorizing effect. Therefore, the adhering particles and the floating particles are excellent for both the malodor that stays in the air in the processing space and the odor generated by the malodor source that is attached to the exposed part of the processing space. The deodorizing effect.
尚，作為解析條件，在較對於第1圖所示的擴散模擬而言，將噴射容量及噴射力設定為較小的情況，例如在將每1次之噴射容量設定為0.1mL、在從噴射口在20cm之距離之噴射力在25℃設定為0.4 g‧f的模式係與第1圖所示的擴散模擬相同，可得到氣溶膠原液迅速地擴散至整個處理空間的擴散模擬之結果。在較對於第1圖所示的擴散模擬而言，將噴射容量及噴射力設定為較大的情況，例如在將每1次之噴射容量設定為0.4mL、在從噴射口在20cm之距離之噴射力在25℃設定為7.0 g‧f的模式係與第1圖所示的擴散模擬相同，可得到氣溶膠原液迅速地擴散至整個處理空間的擴散模擬之結果。As an analysis condition, when the injection volume and injection force are set to be smaller than the diffusion simulation shown in Fig. 1, for example, when the injection volume per shot is set to 0.1 mL, the The injection force at a distance of 20 cm from the mouth is set to 0.4 g‧f at 25°C. The model is the same as the diffusion simulation shown in Figure 1. The results of the diffusion simulation in which the aerosol stock solution rapidly diffuses into the entire processing space can be obtained. In the case where the injection volume and injection force are set to be larger than the diffusion simulation shown in Figure 1, for example, when the injection volume per shot is set to 0.4 mL, when the distance from the injection port is 20 cm The injection force is set to 7.0 g·f at 25°C. The model is the same as the diffusion simulation shown in Figure 1. The result of the diffusion simulation in which the aerosol stock solution rapidly diffuses throughout the processing space can be obtained.
如以上之方式，由關於本發明的消臭用氣溶膠噴射1次氣溶膠原液至2.5~3.5m3 之處理空間，可得到即效性及持續性優異的消臭效果。2.5~3.5m3 之空間係大略相當於一般住宅之廁所空間(寬80～85cm×深度140～180cm×天花板高230cm)之大小。因而，如為關於本發明的消臭用氣溶膠，則在一般住宅之廁所等，可迅速地將惡臭消臭，可使該消臭效果長時間地持續。又，從關於本發明的消臭用氣溶膠被噴射至處理空間的氣溶膠原液而形成的粒子之中一部分，作為浮游性粒子形成。因此，正擴散於處理空間的氣溶膠原液(浮游性粒子)之濃度係附著性粒子之份降低，處理空間之濃度係成為低者。因而，來自浮游性粒子之芳香被降低，可抑制對於不喜歡強烈的芳香的消費者帶來不愉快感之情事。 [實施例]In the above manner, the aerosol stock solution for deodorization of the present invention is sprayed once to a treatment space of 2.5 to 3.5 m 3 to obtain a deodorizing effect with excellent immediate effect and durability. The space of 2.5~3.5m 3 is roughly equivalent to the size of the toilet space of a general residence (width 80~85cm×depth 140~180cm×ceiling height 230cm). Therefore, in the case of the aerosol for deodorization of the present invention, it is possible to quickly deodorize bad odors in toilets in general houses, and the deodorizing effect can be continued for a long time. In addition, part of the particles formed from the aerosol stock solution sprayed into the treatment space of the aerosol for deodorization according to the present invention is formed as floating particles. Therefore, the concentration of the aerosol stock solution (floating particles) being diffused in the processing space is reduced in proportion to the adherent particles, and the concentration in the processing space is lower. Therefore, the fragrance from the floating particles is reduced, and it is possible to suppress unpleasant feelings for consumers who do not like strong fragrances. [Example]
＜噴射力、粒徑之測定＞ 準備已具備本發明之特徵構成的消臭用氣溶膠(實施例1~3)，測定噴射力。更進一步，關於實施例1之消臭用氣溶膠，測定噴射粒子之粒徑。消臭用氣溶膠之氣溶膠原液係作為消臭成分，將植物萃取物1.35g(10w/v%)以及調和(harmonized)香料0.4g(3w/v%)、以及，作為有機溶劑將乙醇(無水)作為殘留物(平衡)混合，調製為全量13.5mL。<Measurement of ejection power and particle size> The aerosol for deodorization (Examples 1 to 3) having the characteristic structure of the present invention was prepared, and the ejection power was measured. Furthermore, regarding the aerosol for deodorization of Example 1, the particle size of the sprayed particles was measured. The aerosol stock solution of the aerosol for deodorization is used as the deodorizing ingredient. The plant extract is 1.35g (10w/v%) and the harmonized fragrance 0.4g (3w/v%), and as an organic solvent, ethanol ( Anhydrous) was mixed as a residue (equilibrium) to prepare a total volume of 13.5 mL.
藉由將氣溶膠原液13.5mL，與噴射劑(LPG氣體作為主劑)31.5mL一起以內壓0.46MPa填充於附定量噴射閥(0.2mL/push)之氣溶膠罐，製作氣溶膠原液(a)與噴射劑(b)之容量比率(a/b)成為30/70的全量45mL之消臭用氣溶膠，將此設為實施例1。Prepare aerosol stock solution by filling 13.5mL of aerosol stock solution and 31.5mL of propellant (LPG gas as the main agent) at an internal pressure of 0.46MPa in an aerosol can with a quantitative injection valve (0.2mL/push) (a) The volume ratio (a/b) to the propellant (b) was 30/70, the total volume of 45 mL of aerosol for deodorization, and this was set as Example 1.
藉由將氣溶膠原液13.5mL，與噴射劑(LPG氣體作為主劑)31.5mL一起以內壓0.35MPa填充於附定量噴射閥(0.1mL/push)之氣溶膠罐，製作氣溶膠原液(a)與噴射劑(b)之容量比率(a/b)成為30/70的全量45mL之消臭用氣溶膠，將此設為實施例2。Prepare aerosol stock solution by filling 13.5mL of aerosol stock solution and 31.5mL of propellant (LPG gas as the main agent) at an internal pressure of 0.35MPa in an aerosol can with a quantitative injection valve (0.1mL/push) (a) The volume ratio (a/b) of the propellant (b) was 30/70, and the total volume of 45 mL of aerosol for deodorization was set as Example 2.
藉由將氣溶膠原液13.5mL，與噴射劑(LPG氣體作為主劑)31.5mL一起以內壓0.50MPa填充於附定量噴射閥(0.4mL/push)之氣溶膠罐，製作氣溶膠原液(a)與噴射劑(b)之容量比率(a/b)成為30/70的全量45mL之消臭用氣溶膠，將此設為實施例3。Prepare aerosol stock solution by filling 13.5mL of aerosol stock solution and 31.5mL of propellant (LPG gas as main agent) at an internal pressure of 0.50MPa in an aerosol can with a quantitative injection valve (0.4mL/push) (a) The volume ratio (a/b) of the propellant (b) was 30/70, and the total volume of 45 mL aerosol for deodorization was set as Example 3.
噴射力之測定係按下1次實施例1之消臭用氣溶膠之噴射按鈕，從噴射口在5cm、10cm及20cm之距離，對於TENSILON(測定裝置)之測定面噴射而實施。測定之結果，在從噴射口在5cm之距離之噴射力係在25℃為3.2g‧f，在從噴射口10cm之距離之噴射力係在25℃為3.2g‧f，在從噴射口在20cm之距離之噴射力係在25℃為2.9g‧f。The spray force was measured by pressing the spray button of the deodorizing aerosol of Example 1 once, and spraying it on the measurement surface of the TENSILON (measurement device) at a distance of 5 cm, 10 cm, and 20 cm from the spray port. As a result of the measurement, the ejection force at a distance of 5 cm from the ejection port is 3.2g‧f at 25°C, and the ejection force at a distance of 10 cm from the ejection port is 3.2g‧f at 25°C. The spray force at a distance of 20cm is 2.9g‧f at 25℃.
實施例2及3之消臭用氣溶膠之噴射力之測定係將各自之噴射按鈕按下1次，在從噴射口在20cm之距離，對於TENSILON(測定裝置)之測定面噴射而實施。測定之結果，從實施例2之消臭用氣溶膠之噴射口在20cm之距離之噴射力係在25℃為0.4g‧f。從實施例3之消臭用氣溶膠之噴射口在20cm之距離之噴射力係在25℃為7.0 g‧f。The measurement of the spray force of the aerosol for deodorization in Examples 2 and 3 was performed by pressing the respective spray button once, and spraying it on the measurement surface of the TENSILON (measuring device) at a distance of 20 cm from the spray port. As a result of the measurement, the spray force at a distance of 20 cm from the spray port of the aerosol for deodorization of Example 2 at 25°C was 0.4 g·f. The spray force from the spray port of the aerosol for deodorization in Example 3 at a distance of 20 cm is 7.0 g‧f at 25°C.
粒徑之測定係將實施例1之消臭用氣溶膠之噴射按鈕按下1次，藉由雷射繞射‧散射法，在從噴射口15cm之距離實施。測定之結果，在累積體積分布之10%粒徑(Dv10)為2.5μm、50%粒徑（Dv50）為33.2μm、90%粒徑（Dv90）為53.4μm。The measurement of particle size was performed by pressing the spray button of the aerosol for deodorization of Example 1 once, by the laser diffraction and scattering method, at a distance of 15 cm from the spray port. As a result of the measurement, the 10% particle size (Dv10) of the cumulative volume distribution is 2.5μm, the 50% particle size (Dv50) is 33.2μm, and the 90% particle size (Dv90) is 53.4μm.
＜消臭效力試驗＞ 關於本發明之消臭用氣溶膠，為了確認消臭效果，所以準備與實施例1同樣地製作的消臭用氣溶膠(實施例4及5)，實施藉由嗅覺測定法所致的消臭效力試驗。又，為了比較，準備與本發明係成分不同的消臭用氣溶膠(比較例1)，實施同樣之消臭效力試驗。<Deodorizing Effect Test> In order to confirm the deodorizing effect of the deodorizing aerosol of the present invention, a deodorizing aerosol prepared in the same manner as in Example 1 (Examples 4 and 5) was prepared and implemented by olfactory measurement Deodorization effect test caused by law. In addition, for comparison, an aerosol for deodorization (Comparative Example 1) with a different component from the system of the present invention was prepared, and the same deodorization efficacy test was performed.
除了於氣溶膠原液調配微量之柑橘香料作為芳香劑以外係以與實施例1之消臭用氣溶膠相同原材料及製法製作消臭用氣溶膠，將此作為實施例4。除了於氣溶膠原液調配微量之柳橙香料作為芳香劑以外係以與實施例1之消臭用氣溶膠相同原材料及製法製作消臭用氣溶膠，將此作為實施例5。Except that a small amount of citrus flavor was prepared as an aromatic agent in the aerosol stock solution, a deodorizing aerosol was produced using the same raw materials and manufacturing method as the deodorizing aerosol of Example 1, and this was referred to as Example 4. The aerosol for deodorization was made by using the same raw materials and manufacturing method as the aerosol for deodorization of Example 1 except that a small amount of orange flavor was blended into the aerosol stock solution as an aromatic agent. This was referred to as Example 5.
於比較例1係使用調配脂肪酸鹽作為消臭成分、四級銨鹽作為殺菌成分、乙醇作為有機溶劑的先前市售之消臭用氣溶膠。In Comparative Example 1, a previously commercially available aerosol for deodorization in which a fatty acid salt is formulated as a deodorizing component, a quaternary ammonium salt is used as a sterilizing component, and ethanol is used as an organic solvent.
在消臭效力試驗係在3m3 之處理空間，散布呈現糞尿模擬臭的特定量之臭氣物質。之後，在處理空間噴射1次消臭用氣溶膠，於噴射之後(0分後)、5分後、10分後、20分後、30分後及60分後，將處理空間內之臭氣，感官試驗員藉由9階之愉快‧不愉快度表示法而評估。但是，比較例1之消臭用氣溶膠係因為是未設置定量噴射閥的氣溶膠製品，所以替代1次之定量噴射之實施，而按照比較例1之用法而實施1秒鐘之連續噴射。噴射量係在噴射前後計量消臭用氣溶膠，由該重量差求出。In the deodorizing effect test system, a specific amount of odorous substances showing a simulated odor of excrement and urine was dispersed in a 3m 3 treatment space. After that, spray the deodorizing aerosol once in the treatment space, and after spraying (after 0 minutes), 5 minutes, 10 minutes, 20 minutes, 30 minutes, and 60 minutes, the odor in the treatment space , The sensory tester evaluated by the 9-level pleasantness and unpleasantness notation. However, the aerosol for deodorization of Comparative Example 1 is an aerosol product without a quantitative injection valve. Therefore, instead of performing one-time quantitative injection, the method of Comparative Example 1 is used for continuous injection for 1 second. The amount of injection is measured by measuring the aerosol for deodorization before and after injection, and is calculated from the difference in weight.
9階之愉快‧不愉快度表示法之評估基準係依據芳香消臭脫臭劑協議會之效力試驗方法，設為「+4：極端愉快」、「+3：非常愉快」、「+2：愉快」、「+1：略愉快」、「0：無愉快亦無不愉快」、「-1：略不愉快」、「-2：不愉快」、「-3：非常不愉快」、「-4：極端不愉快」。散布臭氣物質後，未以消臭用氣溶膠處理之情況之評估為 -3。將實施例4、5及比較例1的消臭效力試驗之結果(愉快‧不愉快度)表示於表1。The 9-level pleasure and unpleasant degree representation method is based on the effectiveness test method of the Aroma Deodorant Deodorant Council, which is set to "+4: extremely pleasant", "+3: very pleasant", "+2: pleasant ", "+1: slightly pleasant", "0: neither pleasant nor unpleasant", "-1: slightly unpleasant", "-2: unpleasant", "-3: very unpleasant", "-4: extremely unpleasant" . After dispersing odorous substances, the evaluation of the situation where the deodorizing aerosol is not treated is -3. Table 1 shows the results of the deodorizing effect test of Examples 4, 5 and Comparative Example 1 (pleasure and unpleasantness).
消臭效力試驗之結果，實施例4及5均在全試驗期間，無低於「+1：略愉快」之評估。具體而言，實施例4之消臭用氣溶膠係從噴射0分後、5分後及10分後之各時點，確認到柑橘之芳香。從噴射20分以後係變得無芳香，但糞尿模擬臭係被調和(harmonize)。實施例5之消臭用氣溶膠係從噴射至5分後，確認到柑橘之芳香。從噴射10分以後係芳香徐徐地減少，但糞尿模擬臭係被調和(harmonize)。As a result of the deodorizing effect test, in both Examples 4 and 5, during the entire test period, there was no evaluation lower than "+1: slightly pleasant". Specifically, in the aerosol system for deodorization of Example 4, the aroma of citrus was confirmed at each time point after 0 minutes, 5 minutes, and 10 minutes after spraying. After 20 minutes of spraying, the system becomes non-scented, but the simulated odor of feces and urine is harmonized. After spraying the aerosol system for deodorization of Example 5 to 5 minutes, the aroma of citrus was confirmed. After 10 minutes of spraying, the aroma gradually decreases, but the fecal and urine simulated odor is harmonized.
另一方面，比較例1之消臭用氣溶膠係從噴射0分後，確認糞尿擬似臭，從噴射5分後，糞尿模擬臭消失。但是，於噴射10分後，糞尿模擬臭再次產生，之後，從噴射60分以後，糞尿模擬臭逐漸變得更強。On the other hand, in the aerosol system for deodorization of Comparative Example 1, the pseudo-odor of feces was confirmed after 0 minutes of spraying, and the pseudo-odor of feces disappeared after 5 minutes of spraying. However, 10 minutes after spraying, the simulated feces odor reproduced, and after 60 minutes of spraying, the simulated odor of feces gradually became stronger.
如此，本發明品的實施例4及5之消臭用氣溶膠係相較於市售品的比較例1，在即效性、持續性之任一面均顯現優異的消臭效果。In this way, the deodorizing aerosol systems of Examples 4 and 5 of the product of the present invention exhibited an excellent deodorizing effect on both the immediate effect and the durability compared to the commercial product of Comparative Example 1.
＜化學性的消臭效力試驗＞ 關於實施例1及4之消臭用氣溶膠，實施藉由機器測定法所致的化學性的消臭效力試驗。試驗方法係依據芳香消臭脫臭劑協議會之消臭效力試驗法，於10L塑膠容器注入惡臭成分(氨)，充滿後，噴射1次消臭用氣溶膠。將容器內之氨濃度，於消臭用氣溶膠噴射前、噴射1小時後、及噴射10小時後，使用氣體檢測管而測定，以下述之式算出噴射1小時後、及噴射10小時後之各自之衰減率。 衰減率(%) = 100-｛噴射後氨濃度（ppm）/噴射前氨濃度（ppm）｝×100 將在實施例1及4的化學性的消臭效力試驗之結果(衰減率)表示於表2。<Chemical deodorization efficacy test> Regarding the aerosols for deodorization of Examples 1 and 4, a chemical deodorization efficacy test by a machine measurement method was performed. The test method is based on the deodorizing efficacy test method of the Aromatic Deodorant Deodorant Association. A 10L plastic container is filled with malodorous ingredients (ammonia), and after it is full, aerosol for deodorizing is sprayed once. The ammonia concentration in the container was measured using a gas detection tube before spraying, 1 hour after spraying, and 10 hours after spraying for aerosol for deodorization, and calculated using the following formula to calculate the value of 1 hour after spraying and 10 hours after spraying The respective decay rate. Attenuation rate (%) = 100-{Ammonia concentration after injection (ppm)/Ammonia concentration before injection (ppm)}×100 The results (decay rate) of the chemical deodorizing efficacy test in Examples 1 and 4 are shown in Table 2.
化學性的消臭效力試驗之結果，實施例1及4之任一者，噴射1小時後之衰減率均為60%以上，噴射10小時後之衰減率係進而上昇而為87%。以如此之方式，實施例1及4之消臭用氣溶膠係顯現從噴射直至10小時的持續性的消臭效果。 [產業上之可利用性]As a result of the chemical deodorizing effect test, in either of Examples 1 and 4, the attenuation rate after 1 hour of spraying was 60% or more, and the attenuation rate after spraying for 10 hours further increased to 87%. In this way, the deodorizing aerosols of Examples 1 and 4 exhibited a continuous deodorizing effect from spraying to 10 hours. [Industrial availability]
本發明之消臭用氣溶膠係用以將處理空間之惡臭消臭所使用者，作為廁所用之消臭劑可合適地利用，且亦可用在客廳、臥室、玄關、廚房、浴室等之生活空間的消臭用途。The aerosol for deodorization of the present invention is used to deodorize the odor in the processing space. It can be suitably used as a deodorant for toilets, and can also be used in living rooms, bedrooms, entrances, kitchens, bathrooms, etc. Deodorizing use of space.
1‧‧‧消臭用氣溶膠1a‧‧‧噴射口2‧‧‧使用者1‧‧‧Aerosol for
[第1圖] 第1圖係將關於本發明的消臭用氣溶膠噴射於3m3 之處理空間時之擴散模擬之說明圖。[Figure 1] Figure 1 is an explanatory diagram of the diffusion simulation when the aerosol for deodorization of the present invention is sprayed into a 3m 3 processing space.
Claims (10)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017122574 | 2017-06-22 | ||
| JP2017-122574 | 2017-06-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201904659A TW201904659A (en) | 2019-02-01 |
| TWI699238B true TWI699238B (en) | 2020-07-21 |
Family
ID=64737023
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW107121440A TWI699238B (en) | 2017-06-22 | 2018-06-22 | Deodorizing aerosol product |
Country Status (6)
| Country | Link |
|---|---|
| JP (3) | JP6472937B1 (en) |
| KR (2) | KR102318445B1 (en) |
| CN (3) | CN118022033A (en) |
| SG (1) | SG11201912845RA (en) |
| TW (1) | TWI699238B (en) |
| WO (1) | WO2018235844A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7268965B2 (en) * | 2018-06-05 | 2023-05-08 | アース製薬株式会社 | Quantitative injection type aerosol product and deodorizing method |
| JP7304736B2 (en) * | 2019-05-13 | 2023-07-07 | シャープ株式会社 | Aerosol composition and aerosol spray can filled with the same |
| JP7237784B2 (en) * | 2019-09-18 | 2023-03-13 | シャープ株式会社 | Aerosol spray can filled with aerosol composition |
| WO2021182433A1 (en) * | 2020-03-13 | 2021-09-16 | 大日本除蟲菊株式会社 | Fixed-amount spray aerosol product for controlling specific hazardous things, and method for controlling specific hazardous things using same |
| JP7404163B2 (en) * | 2020-06-15 | 2023-12-25 | シャープ株式会社 | Photocatalyst spray and deodorizing method |
| WO2024009881A1 (en) * | 2022-07-05 | 2024-01-11 | 大日本除蟲菊株式会社 | Indoor pest control water-based aerosol product, indoor pest control method, and use method for indoor pest control water-based aerosol product |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1242816C (en) * | 2001-06-25 | 2006-02-22 | 大日本除虫菊株式会社 | Deodorization, degerming fragrance sol agent |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4614402B2 (en) * | 2000-07-06 | 2011-01-19 | フマキラー株式会社 | Spray treatment method for all-injection aerosol |
| JP2002167577A (en) * | 2000-11-30 | 2002-06-11 | Daizo:Kk | Aerosol composition for spraying |
| JP3753997B2 (en) * | 2002-02-19 | 2006-03-08 | ライオン株式会社 | Aroma and deodorant for toilet |
| JP5241905B2 (en) * | 2005-04-27 | 2013-07-17 | 大日本除蟲菊株式会社 | Deodorant formulated with an efficacy enhancer for organic deodorant ingredients |
| GB0522287D0 (en) * | 2005-11-01 | 2005-12-07 | Reckitt Benckiser Uk Ltd | Method and compositions |
| CN101530625A (en) * | 2009-04-26 | 2009-09-16 | 白东江 | Deodorizing antistaling agent |
| JP5546834B2 (en) | 2009-11-19 | 2014-07-09 | 株式会社ダイゾー | Aerosol product and method for injecting aerosol composition filled in the aerosol product |
| JPWO2013018805A1 (en) * | 2011-08-01 | 2015-03-05 | 山本香料株式会社 | Fragrance for suppressing fecal odor, microencapsulated fragrance using the same, fiber product with fecal odor suppressing function, pellet for suppressing fecal odor, microencapsulated fragrance spray, and spray for suppressing fecal odor |
| WO2015133318A1 (en) | 2014-03-04 | 2015-09-11 | 大日本除蟲菊株式会社 | Aerosol for mosquito control and mosquito control method |
| JP6829207B2 (en) * | 2015-10-27 | 2021-02-10 | アース製薬株式会社 | Aerosol type air freshener |
-
2018
- 2018-06-20 CN CN202410180349.1A patent/CN118022033A/en active Pending
- 2018-06-20 WO PCT/JP2018/023377 patent/WO2018235844A1/en active Application Filing
- 2018-06-20 CN CN201880034503.7A patent/CN110709109A/en active Pending
- 2018-06-20 CN CN202010179237.6A patent/CN111317850A/en active Pending
- 2018-06-20 KR KR1020197034790A patent/KR102318445B1/en active IP Right Grant
- 2018-06-20 KR KR1020217034230A patent/KR102411559B1/en active IP Right Grant
- 2018-06-20 JP JP2018534900A patent/JP6472937B1/en active Active
- 2018-06-20 SG SG11201912845RA patent/SG11201912845RA/en unknown
- 2018-06-22 TW TW107121440A patent/TWI699238B/en active
-
2019
- 2019-01-23 JP JP2019008922A patent/JP6813605B2/en active Active
-
2020
- 2020-12-17 JP JP2020208998A patent/JP7043151B2/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1242816C (en) * | 2001-06-25 | 2006-02-22 | 大日本除虫菊株式会社 | Deodorization, degerming fragrance sol agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111317850A (en) | 2020-06-23 |
| JP2021053429A (en) | 2021-04-08 |
| KR102318445B1 (en) | 2021-10-27 |
| CN118022033A (en) | 2024-05-14 |
| CN110709109A (en) | 2020-01-17 |
| TW201904659A (en) | 2019-02-01 |
| JP6472937B1 (en) | 2019-02-20 |
| JP6813605B2 (en) | 2021-01-13 |
| SG11201912845RA (en) | 2020-01-30 |
| KR20190138693A (en) | 2019-12-13 |
| JP2019103820A (en) | 2019-06-27 |
| JPWO2018235844A1 (en) | 2019-06-27 |
| KR20210130273A (en) | 2021-10-29 |
| JP7043151B2 (en) | 2022-03-29 |
| KR102411559B1 (en) | 2022-06-22 |
| WO2018235844A1 (en) | 2018-12-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI699238B (en) | Deodorizing aerosol product | |
| JP2010158587A (en) | Method for freshening air | |
| JP2006514860A (en) | How to clean the air | |
| JP2011529992A (en) | Fragrance composition containing functional fragrance ingredients | |
| KR102005027B1 (en) | Essential oil containing substance and its fabrication method for long lasting fragrance | |
| JP6829207B2 (en) | Aerosol type air freshener | |
| JP2022171748A (en) | Fixed-quantity ejection type aerosol product and deodorizing method | |
| JP2012040417A (en) | Enhancing agent for effectiveness of organic deodorant component and deodorizer blended with the same | |
| JP5394629B2 (en) | Deodorizing and fragrance for spraying, production method thereof, and spraying deodorizing and fragrance | |
| JP4896538B2 (en) | Potency enhancer for organic deodorant ingredients. | |
| JP7305335B2 (en) | Accumulator spray composition and spray formulation using the same | |
| US2228993A (en) | Deodorant | |
| KR200203590Y1 (en) | Panel for furniture | |
| RU2085216C1 (en) | Air freshener (versions) | |
| JP5988538B2 (en) | Chemical solution for spraying and chemical spraying device | |
| JP4469097B2 (en) | Deodorant for toilet | |
| JPH06205823A (en) | Fragrant agent and method for adjusting odor | |
| JPH06205822A (en) | Fragrant agent and method or adjusting odor | |
| JP2003339837A (en) | Deodorizer and its composition | |
| JPH06125802A (en) | Insole for shoes | |
| JPH0611299B2 (en) | Spray type deodorant composition | |
| JPH0611298B2 (en) | Deodorant composition | |
| HRP20100169A2 (en) | Fragant granules for suction cleaners |