TWI648431B - Electrolysis device - Google Patents

Abstract

The electrolysis device of the invention is mainly composed of a supply mechanism, an electrolysis mechanism and a mixing mechanism, which can provide an aqueous solution, a cooling aqueous solution having a temperature lower than the aqueous solution, and a saline aqueous solution containing a salt, and the electrolysis mechanism can receive the cooling aqueous solution to supply the power supply component. The temperature is lowered, and the brine solution can be electrolyzed to form an oxidized composite gas. When the electrolysis mechanism performs electrolysis, the electrolysis mechanism transmits the electrolysis mechanism to maintain the electrolysis temperature of the brine solution in the electrolysis mechanism, and the mixing mechanism The aqueous solution is mixed with the oxidizing complex gas to form an oxidized complex type gaseous aqueous solution, whereby the present invention can provide an electrolytic device for mass-producing an oxidized complex type gaseous aqueous solution.

Description

Electrolytic device

The present invention relates to an electrolysis apparatus, and more particularly to an electrolysis apparatus capable of mass producing an oxidized complex type gaseous aqueous solution.

Since the oxidized complex gas itself has an unpaired free active electron, the oxidized complex gas aqueous solution has a strong oxidizing ability and can be used to oxidize proteins, peptides, DNA or RNA of bacteria, viruses, molds and the like. Since the use of gaseous oxidized complex gas does not provide users with convenient use, it is currently used in industries such as health care, food processing, environmental protection, industrial water, Xumu farming and sewage treatment. The oxidized complex gas is dissolved in water to form an oxidized composite gaseous aqueous solution, so that the user can conveniently use the oxidized composite aqueous solution for disinfection, sterilization, and deodorization.

However, in order to improve the aforementioned deficiency, a conventional electrolysis device is currently used to electrolyze brine to form an oxidized complex gas, and then the oxidized complex gas is dissolved in water to form an oxidized complex gas aqueous solution, but it is known When the electrolysis device performs electrolysis, the conventional electrolysis device only cools the power supply component and the electrolysis cell through a set of cooling mechanisms. When a electrolysis device is in the electrolysis time process, a group of cooling mechanisms cannot effectively reduce the power supply component and the electrolysis cell. The temperature of the person, even if the temperature of both the power supply unit and the electrolytic cell is too high, the conventional electrolysis device must be stopped, whereby the electrolysis device must be stopped after a certain period of operation to ensure the power supply. The temperature of both the module and the electrolytic cell should not be too high, which leads to an inability to effectively increase the yield of the oxidized composite gaseous aqueous solution produced by the conventional electrolytic device.

The main object of the present invention is that both the power supply component and the electrolytic cell can be cooled by a single cooling mechanism, so that the user can mass-produce the oxidized complex gaseous aqueous solution in a short time through the electrolysis device of the present invention, which is convenient for the user. Oxidation-based complex gaseous aqueous solution is used for sterilization, sterilization, and deodorization.

Another object of the present invention is to control whether an aqueous solution and an aqueous saline solution flow into the electrolytic cell, thereby reducing the number of tubes used between the supply mechanism and the electrolysis mechanism, so that the overall size of the electrolysis device can be effectively reduced.

Still another object of the present invention is to reduce the moisture entrained by the oxidized composite gas in the process of flowing the oxidized composite gas from the electrolysis mechanism to the mixing mechanism, so that the oxidized composite gas flowing to the mixing mechanism can be mixed. Less water vapor allows the mixing mechanism to produce an oxidized complex gaseous aqueous solution in a short period of time, thereby increasing production efficiency.

A further object of the present invention is to avoid wasting the oxidized complex gas, allowing the oxidizing complex gas to be sufficiently mixed with the aqueous solution to form an oxidized composite gaseous aqueous solution, and the mixing mechanism can produce a large amount of oxidized composite in a short time. Type of gaseous aqueous solution.

In order to achieve the foregoing object, the present invention relates to an electrolysis device which is mainly composed of a supply mechanism, an electrolysis mechanism and a mixing mechanism, the supply mechanism having a liquid supply assembly and a liquid supply assembly. An aqueous solution, the liquid supply assembly is respectively connected to a cooling assembly and a brine mixing assembly, such that the aqueous solution flows through the cooling assembly and the brine mixing assembly respectively to form a cooling aqueous solution having a lower temperature than the aqueous solution and a brine solution mixed with salt. .

In this embodiment, the liquid supply assembly has a fresh water storage tank connected to the cooling assembly and the electrolytic cell, and a reverse osmosis water storage tank simultaneously connected to the brine mixing assembly and the gas-liquid mixing assembly, and the aqueous solution has a clear water solution stored in the fresh water storage tank and a reverse osmosis water solution stored in the reverse osmosis water storage tank, and the clear water solution flows through a reverse osmosis water between the fresh water storage tank and the reverse osmosis water storage tank The above-mentioned reverse osmosis aqueous solution is formed by a manufacturer.

The electrolysis mechanism has a power supply assembly connected to the cooling assembly and an electrolytic cell connected to the power supply assembly. The power supply assembly is configured to receive the cooling aqueous solution for cooling, and provide a voltage for electrolysis of the electrolytic cell. The electrolytic cells are respectively connected to the liquid supply unit and the brine mixing unit, and are capable of selectively receiving the aqueous solution or the brine solution, and the electrolytic tank electrolyzes the aqueous salt solution to form an oxidized composite gas and is permeable to the aqueous solution. Cleaning is performed to form an electrolytic waste liquid, and the electrolytic cell is connected to an electrolytic cooling unit to maintain the electrolysis temperature of the aqueous salt water solution in the electrolytic cell.

Wherein, a switching component is disposed between the liquid supply component, the brine mixing component and the electrolytic cell, the switching component has a switching unit capable of simultaneously receiving the aqueous solution and the brine solution, and two outlet pipes connected to the switching unit. The switching unit can selectively flow the aqueous solution or the brine solution into one of the two outlet pipes, and one of the two outlet pipes is connected to an anode electrolysis space formed inside the electrolysis cell, and the other outlet pipe is connected. A cathode electrolysis space formed inside the electrolytic cell.

Further, when the brine solution flows into the anode electrolysis space through the switching unit, the brine solution flows first to a brine flow meter assembled to the switching unit, and then flows to the outlet pipe, so that the brine flow meter calculates the brine solution. The flow rate into the anode electrolysis space.

In this embodiment, the switching unit has an aqueous tube body for receiving the aqueous solution and a brine tube body for receiving the aqueous salt water solution, wherein the aqueous solution tube body and the brine tube body are respectively connected to the outlet pipe and passed through a shunt tube. Connected to each other, and the shunt tube is assembled with a shunt switch that allows the aqueous pipe body to selectively communicate with or not communicate with the brine pipe body, such that the diverter switch connects the aqueous pipe body to the brine pipe body, the aqueous solution or The aqueous brine solution can simultaneously flow into the aqueous solution body and the brine tube.

In addition, the aqueous solution tube body is respectively provided with an aqueous solution switching switch on both sides of the shunt tube, and one of the two aqueous solution switching switches can be used to inhibit the aqueous solution from flowing into the aqueous solution tube body, and the other aqueous solution switching switch can inhibit the aqueous solution from flowing into the aqueous solution tube. a water outlet pipe, wherein the brine pipe body is respectively provided with a brine switching switch on both sides of the branch pipe, wherein one of the brine switching switches can be used to inhibit the brine solution from flowing into the brine pipe body, and the other salt water switching switch is available. In order to inhibit the above aqueous brine solution from flowing into another outlet pipe.

In a preferred embodiment, the electrolytic waste liquid flows to a recovery tank, and a partition plate is disposed inside the recovery tank, so that the inside of the recovery tank is separated into a sediment for accommodating the electrolytic waste liquid through the partition plate. The space and a recovery space communicating with the precipitation space, wherein the electrolytic waste liquid is precipitated in the precipitation space to form an electrolytic waste at the bottom of the sedimentation space and a recovery aqueous solution capable of flowing to the recovery space.

Further, the recovery tank has a bottom plate disposed on the partition plate at a side of the partition plate, and a circumference of the bottom plate is formed on the other side of the partition plate to form a ring wall having a length larger than the partition plate. The height of the partition plate at a side away from the bottom plate is lower than a side of the ring wall away from the bottom plate, and when the liquid level of the recovered aqueous solution is higher than the partition plate, the recovered aqueous solution overflows to The above recycling space.

Finally, the mixing mechanism has a gas-liquid mixing assembly and a finished tank connected to the gas-liquid mixing assembly. The gas-liquid mixing assembly is simultaneously connected to the liquid supply assembly and the electrolytic tank, and can receive the aqueous solution and the oxidized composite gas. The gas-liquid mixing module can circulate the aqueous solution to mix the aqueous solution with the oxidizing complex gas to form an oxidized composite gaseous aqueous solution which is transferred to the finished tank.

Further, a condensing tube is disposed between the electrolytic cell and the gas-liquid mixing assembly, and the condensing tube forms an air inlet at an end close to the electrolytic cell, and a hole having a smaller diameter than the air inlet is formed at an end far from the air inlet. a gas port, a gap between the gas inlet and the gas outlet is formed such that the oxidized composite gas passes through the condensation passage, and the inner pore diameter of the condensation passage is smaller as it is closer to the gas outlet, so that the oxidized composite gas contacts at least A condensation surface forming the condensation passage allows the moisture of the oxidized composite gas to be condensed to form a water droplet which stays in the condensation passage.

In this embodiment, the gas-liquid mixing module has a reaction tank for accommodating the aqueous solution and a gas mixer for receiving the oxidized composite gas, and the aqueous solution located in the reaction tank is first connected to the reaction tank. a mixing tube flows into the gas mixer, so that the aqueous solution entrains the oxidized composite gas back to the reaction tank via a second mixing tube connected to the gas mixer, and the aqueous solution located in the reaction tank is converted into the oxidation A complex gaseous aqueous solution.

In a preferred embodiment, the reaction tank is assembled with a backup reaction tank connected to the liquid supply unit, such that the standby reaction tank can receive the aqueous solution, and the oxidized composite is formed when the oxidized composite gas flows into the reaction tank. a part of the type gas is mixed with the aqueous solution in the reaction tank to form the above-mentioned oxidized complex type gaseous aqueous solution, and the remaining oxidized complex type gas flows to the above-mentioned alternate reaction tank, and is located in the above-mentioned alternate reaction tank. The aqueous solution inside is mixed to form the above-described oxidized complex type gaseous aqueous solution.

Further, the first mixing tube assembly and the second mixing tube respectively assemble a controller, and the controller assembled to the first mixing tube controls whether the aqueous solution flows to the gas mixer and is assembled to the second mixing tube. The controller can control whether an aqueous solution containing the oxidized complex gas flows to the reaction tank, and when the aqueous solution can freely flow between the reaction tank and the gas mixer, the aqueous solution is assembled through the second The mixer motor of the mixing tube repeatedly flows into the gas mixer from the first mixing tube, and then flows from the second mixing tube to the reaction tank, so that the concentration of the oxidized complex gas of the oxidized composite gaseous aqueous solution can be increased. .

Further, the reaction tank is connected to the liquid supply unit via an inlet pipe, and is connected to the product tank via a product input pipe, and the inlet pipe and the finished product inlet pipe are respectively provided with the controller, and are assembled to the water inlet pipe. The controller can control whether the aqueous solution flows into the reaction tank, and the controller assembled in the finished input tube can control whether the oxidized composite gaseous aqueous solution flows to the finished tank, and further, the product tank and the inlet pipe are disposed between There is a finished water inlet pipe into which the aqueous solution flows, and the product inlet water pipe is assembled with an aqueous solution adjuster, and the aqueous solution adjuster can control whether the aqueous solution can flow into the finished product tank, thereby adjusting the oxidized composite gas state in the finished product tank. The oxidation system complex gas concentration of the aqueous solution.

Wherein, the finished product input pipe is connected to a finished product output pipe, and a feeding regulator capable of controlling whether the aqueous solution of the above-mentioned dioxide is flown into the finished product tank is assembled at an end remote from the controller, and the finished product output pipe is connected to a storage container. And assembling a discharge regulator capable of controlling whether the aqueous solution of the second oxidation solution flows into the storage tank, or a switching valve is disposed between the finished product input pipe and the finished product output pipe, and the switching valve can selectively connect the finished product input pipe or Blocked from the above finished output tube.

The invention is characterized in that the power supply component can be cooled by the cooling aqueous solution, and the electrolytic cell cools the brine solution in the electrolytic cell through the electrolytic cooling component, so that the power supply component and the electrolytic cell can be separately cooled by a cooling mechanism. The user can mass-produce the oxidized composite gaseous aqueous solution in a short time through an electrolysis device mainly composed of a supply mechanism, an electrolysis mechanism and a mixing mechanism, so that the user can conveniently use the oxidized composite gaseous aqueous solution for disinfection, Sterilization and deodorization.

In addition, the switching component is disposed between the liquid supply component, the brine mixing component and the electrolytic cell, so that the switching component can selectively flow one of the aqueous solution and the brine solution into the interior of the electrolytic cell, thereby between the supply mechanism and the electrolysis mechanism. The number of tubes used can be reduced, so that the overall size of the electrolyzer can be effectively reduced.

In addition, when the oxidized complex gas flows into the condensation passage of the condensing tube, the oxidized composite gas will become smaller and smaller, so that the oxidized composite gaseous aqueous solution contacts the condensed surface, thereby oxidizing the composite. The water gas contained in the gas can form water droplets staying in the condensation passage, so that the oxidized composite gas flowing to the mixing mechanism can be mixed with less moisture, so that the mixing mechanism can generate the oxidized composite gaseous aqueous solution in a short time. To improve production efficiency.

Further, the reaction tank and the standby reaction tank are assembled to each other such that the oxidized complex gas which is not mixed with the aqueous solution flows to the standby reaction tank, and is mixed with the aqueous solution located in the reaction tank to form an oxidized composite gas state. The aqueous solution can avoid wasting the oxidized composite gas, allowing the oxidized composite gas to be sufficiently mixed with the aqueous solution to form an oxidized composite gaseous aqueous solution, and the mixing mechanism can produce a large amount of oxidized complex gas in a short time. Aqueous solution.

In order to further clarify and understand the structure, the use and the features of the present invention, the preferred embodiment is described in detail with reference to the following drawings:

Referring to FIG. 1 , the electrolysis device 1 of the present invention is mainly composed of a supply mechanism 10 , an electrolysis mechanism 20 and a mixing mechanism 30 . The supply mechanism 10 has a liquid supply assembly 11 , a cooling assembly 12 , and a brine mixing assembly . 13 and a switching component 14, the liquid supply assembly 11 has a fresh water storage tank 111 and a reverse osmosis water storage tank 112, and can provide an aqueous solution. The fresh water storage tank 111 is provided with a clear water input pipe 111a and a first clear water output pipe 111b. a second clear water outlet pipe 111c and a third fresh water outlet pipe 111d, and the reverse osmosis water storage tank 112 is connected to the first fresh water inlet pipe 111a, and has a first inlet pipe 112a and a second inlet pipe 112b, wherein The aqueous solution contains a clear aqueous solution, and the aqueous clear water solution can flow into the fresh water storage tank 111 via the fresh water inlet pipe 111a, so that the fresh water storage tank 111 can store the aqueous clear water solution, and the aqueous clear water solution located in the clean water storage tank 111 can be separately separated. Flowing into the inside of the first, second, and third clean water output pipes 111b, 111c, and 111d, when the above-mentioned clean water solution flows into the first clean water output pipe In the interior of the 111b, the aqueous solution of the clear water flows through a reverse osmosis water generator 113 assembled in the first clean water outlet pipe 111b to form a reverse osmosis aqueous solution stored in the reverse osmosis water storage tank 112, so that the above aqueous solution and the reverse water Both of the permeated aqueous solutions constitute the above aqueous solution.

The cooling unit 12 has a cooling water storage tank 121 connected to the second fresh water outlet pipe 111c and a cold water outlet pipe 122 connected to the cooling water storage tank 121, and an assembly between the cooling water storage tank 121 and the fresh water storage tank 111 is provided. In the cooling maker 123 of the second fresh water outlet pipe 111c, when the fresh water solution flows into the second fresh water outlet pipe 111c, the clear water solution passes through the cooling maker 123 to form a cooling aqueous solution having a temperature lower than that of the fresh water solution. The cooling aqueous solution is stored in the inside of the cooling water storage tank 121.

As shown, the brine mixing assembly 13 has a brine storage tank 131 and a brine mixing tank 132 connected to the brine mixing tank 132 via a brine input pipe 131a and having a brine output pipe 131b, and brine. The mixing tank 132 is connected to the first inlet pipe 112a of the liquid supply assembly 11, so that the reverse osmosis aqueous solution flows into the brine mixing tank 132 via the first inlet pipe 112a, and the reverse osmosis aqueous solution and the one in the brine mixing tank 132 are inside. The salt is mixed to form an aqueous brine solution flowing into the brine outlet pipe 131b, and the brine storage tank 131 is allowed to store the aqueous salt water solution.

Referring to FIG. 1 and FIG. 2, the switching component 14 has a switching unit 141, a first outlet pipe 142, a second outlet pipe 143, and a brine flow meter 144. The switching unit 141 has a connection to the third clear water. The aqueous solution tube 141a of the output tube 111d and the saline tube body 141b connected to the brine output tube 131b enable the aqueous solution tube body 141a and the saline tube body 141b to receive the aqueous solution and the aqueous salt solution, respectively, wherein the aqueous solution tube body The 141a is connected to the first outlet pipe 142, and is connected to the brine pipe body 141b via a branch pipe 141c, and the brine pipe body 141b is connected to the second water outlet pipe 143.

As shown, the shunt tube 141c assembles a shunt switch 145 that allows the aqueous tube body 141a to be selectively or non-connected to the brine tube body 141b, and when the aqueous solution tube body 141a passes through the shunt switch 145 and is not connected to the brine tube. In the case of the body 141b, the aqueous solution of the fresh water flows into the first outlet pipe 142 via the aqueous pipe body 141a alone, and the brine solution flows into the second outlet pipe 143 by the separate brine pipe 141b, and conversely, when the aqueous pipe body 141a passes through the branching switch When the 145 is connected to the brine pipe body 141b, a part of the fresh water solution flows into the first water discharge pipe 142, and the remaining water solution can flow into the second water outlet pipe 143 via the branch pipe 141c, and a part of the brine solution can The second outlet pipe 143 flows into the second outlet pipe 143, and the remaining brine solution also flows into the first outlet pipe 142 via the branch pipe 141c.

In addition, the aqueous solution pipe body 141a assembles a first aqueous solution changeover switch 146 on the side away from the first outlet pipe 142 on the branch pipe 141c, and assembles a first outlet pipe on a side away from the first aqueous solution changeover switch 146. The second aqueous solution of the 142 switch 147, and the brine pipe 141b is assembled with a first brine switching switch 148 on the side away from the second outlet pipe 143, and is assembled close to the first side of the first brine switching switch 148. a second brine switching switch 149 of the second outlet pipe 143, wherein the first aqueous solution switching switch 146 can be used to control whether the aqueous solution of the clear water flows into the aqueous pipe body 141a, and the second aqueous solution switching switch 147 can be used to control whether the aqueous solution of the clear water flows into the first An outlet pipe 142, in addition, the first brine switching switch 148 can selectively inhibit the brine solution from flowing into the interior of the brine pipe 141b or let the brine solution flow into the interior of the brine pipe 141b, and the second brine switching switch 149 can Selectively inhibiting the aqueous salt water solution from flowing into the second outlet pipe 143 or allowing the brine solution to flow into the second The inside of the water pipe 143, whereby the shunt switch 145, the first and second aqueous solution changeover switches 146, 147 and the first and second brine changeover switches 148, 149 cooperate to allow the above-mentioned clean water aqueous solution to flow into the first and second outlet pipes simultaneously 142, 143 or one of the first and second outlet pipes 142, 143 can also be flowed into the first and second outlet pipes 142, 143 or into the first and second outlet pipes 142 at the same time. 143, one of them.

The brine flow meter 144 is connected to the brine pipe body 141b, wherein when the water distribution switch 145 and the second salt water switching switch 149 restrict the water solution from flowing into the brine pipe body 141b and the second water outlet pipe 143, the brine solution can only flow into the brine. The tube body 141b, at this time, the brine solution first flows into the brine flow meter 144, and then flows to the second outlet pipe 143, so that the brine flow meter 144 calculates the flow rate of the brine solution into the second outlet pipe 143.

Referring to FIG. 1 and FIG. 3 , the electrolysis mechanism 20 has a power supply component 21 , an electrolytic cell 22 , a recovery tank 23 , and an electrolytic cooling assembly 24 . The power supply assembly 21 is connected to the cold water output pipe 122 of the cooling assembly 12 . The power supply component 21 can receive the cooling aqueous solution, and the electrolytic cell 22 is electrically connected to the power supply component 21, and internally forms an anode electrolysis space 221 and a cathode electrolysis space 222, wherein the anode electrolysis space 221 is connected to the switching component. The second outlet pipe 143 of 14 is assembled with an anode discharge pipe 223 to communicate with the outside of the electrolytic cell 22, and the cathode electrolysis space 222 is connected to the first outlet pipe 142 of the switching assembly 14, and a cathode discharge pipe 224 is assembled and connected. Outside of the electrolytic cell 22, the switching assembly 14 is thereby located between the liquid supply assembly 11, the brine mixing assembly 13 and the electrolytic cell 22.

Referring to FIG. 4, the recovery tank 23 has a horizontally disposed bottom plate 231. The circumference of the bottom plate 231 extends upward to form a ring wall 232, so that the bottom plate 231 and the ring wall 232 together form a space inside the recovery tank 23. The space 233 is provided with a longitudinally disposed partitioning plate 234, so that the accommodating space 233 is divided into a sedimentation space 233a and a recovery space 233b having a smaller space than the sedimentation space 233a. As shown, the longitudinal length of the ring wall 232 is greater than the longitudinal length of the partition plate 234 such that the height of the partition plate 234 on the side away from the bottom plate 231 is lower than the side of the ring wall 232 away from the bottom plate 231, wherein the sedimentation space 233a is connected to the recovery space 233b, and the recovery space 233b is connected to a discharge container 235 via a recovery output pipe 233c, and the discharge container 235 is provided with a pH detector 235a and a neutralizer addition member 235b. The electrolytic cooling assembly 24 is shown connected to the electrolytic cell 22.

Referring to FIG. 2, FIG. 3 and FIG. 5, when the electrolysis device 1 performs the electrolysis operation, the brine solution passes through the switching unit 14 and simultaneously flows into the first and second outlet pipes 142 and 143, so that the brine solution can flow in. The anode electrolysis space 221 of the electrolysis cell 22 and the cathode electrolysis space 222 of the electrolysis cell 22, after the anode electrolysis space 221 and the cathode electrolysis space 222 are filled with the above brine solution, the power supply unit 21 supplies a voltage to the electrolysis cell 22, and the electrolysis cell 22 is allowed. The positive and negative electrodes generate a redox reaction, and the electrolytic cell 22 electrolyzes the aqueous brine solution to form an oxidized composite gas, and the oxidized composite gas flows into an electrolytic output connected between the electrolytic cell 22 and the mixing mechanism 30. The tube 225 allows the oxidizing complex gas to flow to the mixing mechanism 30. When the electrolytic cell 22 electrolyzes the aqueous salt solution, the power supply unit 21 generates heat due to the continuous supply of voltage, and the electrolytic cell 22 is continuously received. The voltage supplied by the power supply unit 21 causes the temperature of the aqueous brine solution to rise, however, The temperature of the power supply unit 21 and the brine solution is prevented from being too high, and the cooling aqueous solution located inside the cooling water storage tank 121 flows through the power supply unit 21 via the cold water outlet pipe 122 to allow the power supply unit 21 to cool down and electrolyze. The cooling unit 24 provides an electrolytically cooled aqueous solution to the electrolytic cell 22, so that the electrolytically cooled aqueous solution flows through the electrolytic cell 22 and flows back to the electrolytic cooling unit 24 to lower the temperature of the aqueous salt solution. In this embodiment, the above-mentioned oxidized composite The type gas is set to chlorine dioxide, hypochlorous acid or ozone.

Referring to FIG. 1 and FIG. 6 , a condensing tube 40 assembled to the electrolytic output tube 225 is disposed between the electrolysis mechanism 20 and the mixing mechanism 30 . The condensing tube 40 forms an air inlet port 41 at an end close to the electrolytic cell 22 , and An air outlet 42 having a smaller diameter than the air inlet 41 is formed at an end close to the mixing mechanism 30, and a condensation passage 43 located inside the condensation tube 40 and a condensation formed in the condensation passage 43 are formed between the air inlet 41 and the air outlet 42. The surface 44, as shown, the condensation passage 43 is composed of a plurality of tube portions 431 having different aperture sizes, and the plurality of tube portions 431 are arranged from the air inlet 41 to the air outlet 42 according to the aperture size, so that the closer to the air inlet 41 The larger the diameter of the tube portion 431, the smaller the diameter of the tube portion 431 closer to the gas outlet 42 is, and the condensation surface 44 is formed between the two tube portions 431, and the normal direction of the condensation surface 44 faces the gas inlet port 41. However, the condensation passage 43 is composed of a plurality of tube portions 431 for convenience of explanation, that is, the condensation passage 43 can be tapered from the inlet port 41 toward the outlet port 42, so that the condensation passage 43 assumes a tapered shape.

When the electrolytic cell 22 of the electrolysis mechanism 20 electrolyzes the aqueous salt water solution to form the oxidized composite gas, the oxidized composite gas contains a small amount of moisture, so that the oxidized composite gas is supplied to the gas inlet 41. When the condensing passage 43 flows to the gas outlet port 42, the oxidized composite gas is brought into contact with the condensing surface 44 by the internal pore diameter of the condensing passage 43 so that the oxidized composite gas is further caused. The entrained moisture can form a water droplet that stays in the condensation passage 43, so that the above-mentioned oxidized composite gas flowing to the mixing mechanism 30 can be entrained with less moisture.

Referring to FIG. 4 and FIG. 7 , when the electrolysis device 1 is cleaned, the aqueous solution of the clean water passes through the switching unit 14 and simultaneously flows into the first and second outlet pipes 142 and 143 so that the aqueous solution of the clean water can flow into the anode electrolysis space of the electrolytic cell 22 . 221 and the cathode electrolysis space 222 of the electrolytic cell 22, such that the aqueous solution of the clear water washes the anode and cathode electrolysis spaces 221, 222 to form an electrolysis waste liquid, wherein the electrolysis waste liquid located inside the anode electrolysis space 221 passes through the anode. The discharge pipe 223 flows into the sedimentation space 233a of the recovery tank 23, and similarly, the electrolytic waste liquid located in the cathode electrolysis space 222 flows into the sedimentation space 233a via the cathode discharge pipe 224.

When the above-mentioned electrolytic waste liquid is in the precipitation space 233a, the electrolytic waste liquid is precipitated in the sedimentation space 233a to form an electrolytic waste at the bottom of the sedimentation space 233a and a recovered aqueous solution inside the sedimentation space 233a, wherein When the liquid level of the recovered aqueous solution is higher than the partition plate 234, the recovered aqueous solution overflows to the recovery space 233b of the recovery tank 23, so that the recovered aqueous solution flows into the discharge container 235 via the recovery output pipe 233c, and at this time, the pH value is detected. The 235a detects the pH of the recovered aqueous solution, and the neutralizer addition member 235b adds an appropriate amount of the neutralizing agent according to the detected pH value, so that the pH of the recovered aqueous solution approaches neutrality.

Referring to FIG. 1 and FIG. 8, the mixing mechanism 30 has a gas-liquid mixing assembly 31 and a finished tank 32. The gas-liquid mixing assembly 31 has a reaction tank 311 connected to the second inlet pipe 112b and a connection to the electrolytic output pipe. a gas mixer 312 of 225, a first mixing tube 313 and a second mixing tube 314 are disposed between the reaction tank 311 and the gas mixer 312, so that the reaction tank 311 is connected to the gas via the first and second mixing tubes 313 and 314. The mixer 312, wherein the reaction tank 311 is connected to a standby reaction tank 315, and the backup reaction tank 315 is connected to the second inlet pipe 112b via a backup inlet pipe 315a, so that the backup reaction tank 315 can be connected to the liquid supply assembly 11. The reverse osmosis water storage tank 112, however, the reaction tank 311 is assembled with a spare reaction tank 315 for convenience of explanation, that is, the reaction tank 311 can simultaneously assemble a plurality of alternate reaction tanks 315, or a plurality of alternate reaction tanks 315 are connected to each other. Further, one of the alternate reaction tanks 315 is connected to the reaction tank 311.

As shown, the gas mixer 312 is provided with a mixing portion 312a connected to the electrolytic output tube 225. The mixing portion 312a exhibits a hollow state, and the inner diameter is smaller than the first and second mixing tubes 313, 314, and the mixing portion. One end 312a extends to form a first connecting portion 312b connected to the first mixing tube 313, and extends from an end away from the first connecting portion 312b to form a second connecting portion 312c connected to the second mixing tube 314, wherein The internal apertures of the two connecting portions 312b, 312c are tapered, and the first mixing tube 313 is assembled with a first controller 316. The first controller 316 can selectively present a first communication state and a first blocking state. And when the first controller 316 is in communication with the first communication state, the reaction tank 311 can communicate with the gas mixer 312 via the first mixing tube 313, and conversely, when the first controller 316 exhibits the first blocking state. At this time, the reaction tank 311 cannot communicate with the gas mixer 312 via the first mixing tube 313. Further, the second mixing tube 314 assembles a second controller 317, and the second controller 317 is identical to the first controller 316. Can present one a second communication state that is the same as the first communication state and a second isolation state that is the same as the first isolation state. When the second controller 317 assumes the second communication state, the reaction tank 311 can pass the second mixing. The tube 314 is in communication with the gas mixer 312. Conversely, when the second controller 317 assumes the second blocking state, the reaction tank 311 cannot communicate with the gas mixer 312 via the first mixing tube 313.

As shown, the finished tank 32 has a finished inlet pipe 321 connected to the second inlet pipe 112b so that the reverse osmosis aqueous solution can flow into the finished inlet pipe 321, and the finished inlet pipe 321 assembles an aqueous regulator 322 and transmits The aqueous solution regulator 322 controls whether the above-described reverse osmosis aqueous solution can flow into the finished water inlet pipe 321.

A finished product input pipe 323 is disposed between the finished product tank 32 and the reaction tank 311. The finished product input pipe 323 is assembled with a third controller 318 having the same function as the first controller 316 on a side close to the reaction tank 311. The second inlet pipe 112b also assembles a fourth controller 319 having the same function as the third controller 318 on the side close to the reaction tank 311, and the finished product input pipe 323 is connected to a finished output pipe 324, and a feed is assembled. The adjuster 325, and the finished output tube 324 is connected to a storage container 326, and an output adjuster 327 is assembled. In this embodiment, both the feed adjuster 325 and the discharge adjuster 327 have the same function as the aqueous solution regulator. 322.

Referring to FIG. 8 and FIG. 9 , when the mixing mechanism 30 is specifically applied, the first controller 316 and the second controller 317 respectively present the first communication state and the second communication state, so that the reaction channel 311 passes through the first The first and second mixing tubes 313 and 314 are in communication with the gas mixer 312. At this time, the fourth controller 319 allows the reverse osmosis aqueous solution to flow into the reaction tank 311, and the reverse osmosis aqueous solution simultaneously passes through the standby inlet pipe 315a. The inside of the standby reaction tank 315 is flowed into the reaction tank 311 and the spare reaction tank 315 to accommodate the reverse osmosis aqueous solution.

Subsequently, a mixer motor 33 assembled to the second mixing tube 314 is activated, and the mixer motor 33 continuously flows the above-mentioned reverse osmosis aqueous solution positioned inside the reaction tank 311 from the first mixing tube 313 into the gas mixer 312, and then Flowing back to the inside of the reaction tank 311 by the second mixing tube 314, wherein when the reverse osmosis aqueous solution flows into the mixing portion 312a of the gas mixer 312, since the internal diameter of the mixing portion 312a is smaller than that of the first and second mixing tubes 313, 314, the flow rate of the reverse osmosis aqueous solution is increased, and the oxidized composite gas flowing into the gas mixer 312 can be quickly brought into the reaction tank 311 by the reverse osmosis aqueous solution. When the type gas flows into the inside of the reaction tank 311, a part of the oxidized composite gas is mixed with the reverse osmosis aqueous solution in the reaction tank 311 to form an oxidized composite gaseous aqueous solution, and the remaining oxidized composite The type gas will flow into the alternate reaction tank 315 and be mixed with the above-mentioned reverse osmosis aqueous solution in the alternate reaction tank 315 to form the above oxidation. The composite gaseous aqueous solution, wherein the reverse osmosis aqueous solution is caused by the first mixing because the internal pore diameter of the mixing portion 312a is smaller than the first and second mixing tubes 313, 314, and further, in order to prevent the reverse osmosis aqueous solution from flowing into the gas mixer 312. The tube 313 is returned to the reaction tank 311, and a plurality of gas mixers 312 can be disposed between the first mixing tube 313 and the second mixing tube 314 to allow the reverse osmosis aqueous solution to be branched to the plurality of gas mixers 312. In the example, the oxidized complex type gaseous aqueous solution is a chlorine dioxide aqueous solution, a hypochlorous acid aqueous solution or an ozone aqueous solution.

When the oxidized complex type gaseous aqueous solution is formed in the inside of the reaction tank 311, the oxidized complex type gaseous aqueous solution has a low concentration of the oxidizing complex type gas, but the mixer motor 33 further adds the oxidized composite type gaseous aqueous solution. Flowing into the gas mixer 312 and flowing back to the reaction tank 311, more of the above-mentioned oxidized complex gas flows into the interior of the reaction tank 311, so that the concentration of the oxidized complex gas of the oxidized composite gaseous aqueous solution gradually increases. When the concentration of the oxidizing complex gas of the oxidized composite gaseous aqueous solution reaches a predetermined value, the mixer motor 33 is turned off, so that the oxidized composite gaseous aqueous solution can no longer flow into the gas through the first mixing tube 313. Mixer 312.

Next, the third controller 318 and the feed adjuster 325 are turned on, so that the oxidized composite gaseous aqueous solution can flow into the finished tank 32 via the finished product inlet pipe 323, wherein the oxidation of the oxidized composite gaseous aqueous solution is performed. When the complex gas is too concentrated, the aqueous solution regulator 322 is opened to allow the reverse osmosis aqueous solution to flow into the finished tank 32, so that the oxidized complex gas concentration of the oxidized composite gaseous aqueous solution located in the finished tank 32 can Lowering, finally, the feed adjuster 325 is closed, and the discharge adjuster 327 is opened, so that the above-mentioned oxidized composite gaseous aqueous solution located in the finished tank 32 flows into the storage container 326 via the finished product output pipe 324, however, when the above oxidation When the complex gaseous aqueous solution flows into the storage container 326, the oxidized composite gaseous aqueous solution through the feed adjuster 325 cannot flow to the reaction tank 311 via the product inlet pipe 323, and the through-feed adjuster 327 can pass through the finished product output pipe 324. The inflow storage container 326 is only for convenience of explanation, that is, as shown in FIG. 10, the finished product input pipe 323 and the finished product output pipe. A switching valve 34 is assembled between 324, and the switching valve 34 can selectively connect or block the finished input pipe 323 to the finished product output pipe 324, and then oxidize in the reaction tank 311 when the finished product input pipe 323 is in communication with the finished product output pipe 324. The complex gaseous aqueous solution can flow to the storage vessel 326.

The above embodiments are intended to be illustrative only, and are not intended to limit the scope of the present invention. It is included in the scope of the following patent application.

1‧‧‧Electrolytic device

10‧‧‧Supply agencies

11‧‧‧Liquid supply components

111‧‧‧Water storage tank

111a‧‧‧Clear water inlet pipe

111b‧‧‧First clear water outlet

111c‧‧‧Second clear water outlet

111d‧‧‧The third clear water output pipe

112‧‧‧ reverse osmosis water storage tank

112a‧‧‧First inlet pipe

112b‧‧‧Second inlet pipe

113‧‧‧ Reverse osmosis water maker

12‧‧‧ Cooling components

121‧‧‧Cooling water storage tank

122‧‧‧ cold water outlet pipe

123‧‧‧Cooling Maker

13‧‧‧Salt Mixing Components

131‧‧‧ brine storage tank

131a‧‧·Saline input tube

131b‧‧‧Salt output tube

132‧‧‧ brine mixing tank

14‧‧‧Switching components

141‧‧‧Switch unit

141a‧‧‧Aqueous pipe body

141b‧‧‧ saline body

141c‧‧ ‧ shunt tube

142‧‧‧First outlet pipe

143‧‧‧Second outlet

144‧‧‧Salt flowmeter

145‧‧‧Shunt switch

146‧‧‧First aqueous solution switch

147‧‧‧Second aqueous solution switch

148‧‧‧First brine switch

149‧‧‧Second brine switch

20‧‧‧Electrical institutions

21‧‧‧Power supply components

22‧‧‧electrolyzer

221‧‧‧Anode Electrolysis Space

222‧‧‧ Cathodic Electrolysis Space

223‧‧‧Anode discharge tube

224‧‧‧Cathode discharge tube

225‧‧‧Electrical output tube

23‧‧‧Recycling tank

231‧‧‧floor

232‧‧‧Circle

233‧‧‧ accommodating space

233a‧‧‧Precipitation space

233b‧‧‧Recycling space

233c‧‧‧Recycled output tube

234‧‧‧ partition board

235‧‧‧Draining container

235a‧‧‧PH value detector

235b‧‧‧ neutralizer additive

24‧‧‧Electrolysis cooling components

30‧‧‧Mixed institutions

31‧‧‧ gas-liquid mixing components

311‧‧‧Reaction tank

312‧‧‧ gas mixer

312a‧‧‧Mixed Department

312b‧‧‧First connection

312c‧‧‧Second connection

313‧‧‧First mixing tube

314‧‧‧Second mixing tube

315‧‧‧Replacement reaction tank

315a‧‧‧Spare inlet pipe

316‧‧‧First controller

317‧‧‧Second controller

318‧‧‧ Third controller

319‧‧‧fourth controller

32‧‧‧ finished product slot

321‧‧‧ finished water inlet pipe

322‧‧‧Aqueous solution regulator

323‧‧‧Finished input tube

324‧‧‧Finished output tube

325‧‧‧feed adjuster

326‧‧‧ storage container

327‧‧‧Discharge adjuster

33‧‧‧Mixer motor

34‧‧‧Switching valve

40‧‧‧Condensation tube

41‧‧‧ inlet

42‧‧‧ outlet

43‧‧‧Condensation channel

431‧‧‧ Department of Tube

44‧‧‧Condensing surface

1 is a schematic view of an electrolysis apparatus of the present invention; FIG. 2 is a schematic view of a switching assembly of the present invention; FIG. 3 is a schematic view of an electrolysis cell of the present invention; Figure 6 is a schematic view of a condensing tube; Figure 7 is a schematic view of a cleaning apparatus for performing a cleaning operation; Figure 8 is a schematic view of a gas mixer; Figure 9 is a schematic view of a concrete application of the mixing mechanism; and Figure 10 is a finished input tube and Schematic diagram of assembling a switching valve between the finished output tubes.

Claims (16)

An electrolysis device comprising: a supply mechanism having a liquid supply assembly and an aqueous solution provided by the liquid supply assembly, wherein the liquid supply assembly is coupled to a cooling assembly and a brine mixing assembly, respectively, such that the aqueous solution flows through the Cooling the assembly with the brine to form a cooling aqueous solution having a lower temperature than the aqueous solution and a brine aqueous solution mixed with the salt; an electrolysis mechanism having a power supply assembly connected to the cooling assembly and a power supply assembly connected thereto In the electrolytic cell, the power supply component is configured to receive the cooling aqueous solution for cooling, and provide a voltage for electrolysis of the electrolytic cell, wherein the electrolytic cell is respectively connected to the liquid supply component and the brine mixing component, and can selectively receive the aqueous solution or An aqueous brine solution, wherein the electrolytic cell electrolyzes the aqueous salt water solution to form an oxidized composite gas, and is capable of being washed through the aqueous solution to form an electrolytic waste liquid, and the electrolytic cell is connected to an electrolytic cooling component to maintain a mixing temperature of the brine solution in the electrolytic cell; and a mixing mechanism having a gas-liquid mixing component and a product tank connected to the gas-liquid mixing component, wherein the gas-liquid mixing component is simultaneously connected to the liquid supply component and the electrolytic cell And receiving the aqueous solution and the oxidizing complex gas, wherein the gas-liquid mixing module can circulate the aqueous solution, and mixing the aqueous solution with the oxidizing composite gas to form an oxidized composite gaseous aqueous solution which is sent to the finished tank. . The electrolysis device according to claim 1, wherein the liquid supply assembly has a fresh water storage tank connected to the cooling unit and the electrolytic tank, and a reverse osmosis simultaneously connected to the brine mixing unit and the gas-liquid mixing unit. a water storage tank, wherein the aqueous solution has a clear water solution stored in the fresh water storage tank and a reverse osmosis water solution stored in the reverse osmosis water storage tank, and the clear water solution flows through the fresh water storage tank and the reverse osmosis water. The reverse osmosis water generator is formed between the storage tanks to form the above-mentioned reverse osmosis aqueous solution. The electrolysis device according to claim 1, wherein a switching unit is disposed between the liquid supply unit, the brine mixing unit and the electrolytic cell, and the switching unit has a switching unit capable of receiving the aqueous solution and the brine solution; Two outlet pipes connected to the switching unit, the switching unit selectively selectively flowing the aqueous solution or the brine solution into one of the two outlet pipes, and one of the two outlet pipes is connected to an inside of the electrolytic cell. The anode electrolysis space, and the other of the outlet pipes is connected to a cathode electrolysis space formed inside the electrolysis cell. The electrolysis device according to claim 3, wherein, when the brine solution flows into the anode electrolysis space through the switching unit, the brine solution flows first to a salt water flow meter assembled to the switching unit, and then flows to the outlet. The water pipe causes the above-mentioned brine flow meter to calculate the flow rate of the aqueous salt water solution flowing into the anode electrolysis space. The electrolysis device according to claim 3, wherein the switching unit has an aqueous tube body for receiving the aqueous solution and a saline tube body for receiving the aqueous salt water solution, wherein the aqueous solution tube body and the saline tube body are respectively connected to the outlet tube. a water pipe connected to each other via a shunt pipe, wherein the shunt pipe is assembled with a shunt switch that allows the aqueous pipe body to selectively communicate or not communicate with the brine pipe body, so that the diverter switch connects the aqueous pipe body to the above In the case of a brine pipe, the aqueous solution or the brine solution can simultaneously flow into the aqueous pipe body and the brine pipe body. The electrolysis device according to claim 5, wherein the aqueous solution tube body is respectively provided with an aqueous solution switching switch on both sides of the shunt tube, and one of the two aqueous solution switching switches can be used to inhibit the aqueous solution from flowing into the aqueous solution tube body. Another aqueous solution switching switch can prevent the aqueous solution from flowing into one of the outlet pipes, and the brine pipe body is respectively provided with a brine switching switch on both sides of the dividing pipe, wherein one of the brine switching switches can be used to inhibit the flow of the brine solution into the above In the case of a brine pipe, another brine switching switch as described above can be used to inhibit the aqueous brine solution from flowing into the other outlet pipe. The electrolysis device according to claim 1, wherein the electrolysis waste liquid flows to a recovery tank, and a partition plate is disposed inside the recovery tank, so that the inside of the recovery tank is divided into a volume through the partition plate. a sedimentation space of the electrolysis waste liquid and a recovery space connected to the sedimentation space, wherein the electrolysis waste liquid precipitates in the precipitation space to form an electrolysis waste at the bottom of the sedimentation space and a energy flow to the recovery space The recovered aqueous solution. The electrolysis device according to claim 7, wherein the recovery tank forms a bottom plate on one side of the partition plate that is disposed on the partition plate, and the periphery of the bottom plate faces the other side of the partition plate Forming a ring wall having a length greater than the partition plate, such that a height of the partition plate at a side away from the bottom plate is lower than a side of the ring wall away from the bottom plate, and further, when the liquid level of the recovered aqueous solution is higher than the above When the separator is partitioned, the above-mentioned recovered aqueous solution overflows to the above-mentioned recovery space. The electrolysis device according to claim 1, wherein a condensing tube is disposed between the electrolytic cell and the gas-liquid mixing assembly, and the condensing tube forms an air inlet at an end close to the electrolytic cell, and is away from the inlet. One end of the gas port forms an air outlet having a smaller diameter than the air inlet, and a gap between the air inlet and the air outlet is formed to allow the oxidized composite gas to pass through the condensation passage, and the inner diameter of the condensation passage is closer to the air outlet. Small, the oxidized complex gas is brought into contact with at least one condensed surface forming the condensing passage, and the water gas entrained by the oxidized composite gas is condensed to form a water droplet which stays in the condensing passage. The electrolysis device according to claim 1, wherein the gas-liquid mixing module has a reaction tank for accommodating the aqueous solution and a gas mixer for receiving the oxidized composite gas, and the aqueous solution located in the reaction tank is passed through a a first mixing tube connected to the reaction tank flows into the gas mixer, so that the aqueous solution entrains the oxidized composite gas back to the reaction tank via a second mixing tube connected to the gas mixer, and is located above The aqueous solution of the reaction tank is converted into the above-mentioned oxidized complex type gaseous aqueous solution. The electrolysis device according to claim 10, wherein the reaction tank is equipped with a backup reaction tank connected to the liquid supply unit, so that the standby reaction tank can receive the aqueous solution, and the oxidized composite gas flows into the reaction. In the tank, a part of the oxidized composite gas is mixed with an aqueous solution in the reaction tank to form the oxidized composite gaseous aqueous solution, and the remaining oxidized complex gas flows to the standby reaction tank, and The aqueous solution in the above-mentioned alternate reaction tank is mixed to form the above-described oxidized complex type gaseous aqueous solution. The electrolysis device according to claim 10, wherein the first mixing tube assembly and the second mixing tube are respectively assembled with a controller, and the controller assembled to the first mixing tube controls whether the aqueous solution flows to the above a gas mixer, and the controller assembled in the second mixing tube controls whether an aqueous solution containing the oxidized complex gas flows to the reaction tank, and the aqueous solution is freely between the reaction tank and the gas mixer During the flow, the aqueous solution flows through the mixer motor assembled in the second mixing tube, and the first mixing tube flows into the gas mixer, and then flows from the second mixing tube to the reaction tank, so that the oxidation system is compounded. The concentration of the oxidizing complex gas of the gaseous aqueous solution can be increased. The electrolysis device according to claim 10, wherein the reaction tank is connected to the liquid supply unit via an inlet pipe, and is connected to the product tank via a finished input pipe, wherein the inlet pipe and the finished product inlet pipe are respectively A controller is provided, and the controller assembled in the inlet pipe can control whether the aqueous solution flows into the reaction tank, and the controller assembled in the finished product inlet tube can control whether the oxidized composite gaseous aqueous solution flows to the finished tank. The electrolysis device according to claim 13, wherein the finished product input pipe is connected to a finished product output pipe, and an end portion remote from the controller is assembled to adjust a feed amount capable of controlling whether the aqueous solution of the second aqueous solution flows into the finished product tank. The product output pipe is connected to a storage container and assembled with a discharge regulator capable of controlling whether the aqueous solution of the above-mentioned dioxide flows into the storage tank. The electrolysis device of claim 13, wherein the finished product input tube is connected to a storage container via a finished output tube, and a switching valve is disposed between the finished product input tube and the finished product output tube, and the switching valve can The finished product input tube is selectively connected or blocked to the finished product output tube. The electrolysis device according to claim 13, wherein a product inlet pipe for the aqueous solution to flow into between the product tank and the inlet pipe is provided, and the product inlet pipe is assembled with an aqueous solution regulator, and the aqueous solution regulator can be controlled. Whether or not the aqueous solution can flow into the finished product tank can further adjust the concentration of the oxidizing complex type gas in the oxidized composite gaseous aqueous solution in the finished product tank.