TWI500123B - Methods of forming bonded semiconductor structures including interconnect layers having one or more of electrical, optical, and fluidic interconnects therein, and bonded semiconductor structures formed using such methods - Google Patents

Methods of forming bonded semiconductor structures including interconnect layers having one or more of electrical, optical, and fluidic interconnects therein, and bonded semiconductor structures formed using such methods Download PDF

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Publication number
TWI500123B
TWI500123B TW101124121A TW101124121A TWI500123B TW I500123 B TWI500123 B TW I500123B TW 101124121 A TW101124121 A TW 101124121A TW 101124121 A TW101124121 A TW 101124121A TW I500123 B TWI500123 B TW I500123B
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Taiwan
Prior art keywords
layer
semiconductor structure
interconnect
processed semiconductor
bonded
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TW101124121A
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Chinese (zh)
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TW201308541A (en
Inventor
Bich-Yen Nguyen
Mariam Sadaka
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Soitec Silicon On Insulator
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Priority claimed from US13/206,242 external-priority patent/US8728863B2/en
Priority claimed from FR1157426A external-priority patent/FR2979168A1/en
Application filed by Soitec Silicon On Insulator filed Critical Soitec Silicon On Insulator
Publication of TW201308541A publication Critical patent/TW201308541A/en
Application granted granted Critical
Publication of TWI500123B publication Critical patent/TWI500123B/en

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24Coupling light guides
    • G02B6/42Coupling light guides with opto-electronic elements
    • G02B6/43Arrangements comprising a plurality of opto-electronic elements and associated optical interconnections
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Description

包含內有一個或多個電性、光學及流體互連之互連層之黏附半導體構 造之形成方法及應用此等方法形成之黏附半導體構造Adhesive semiconductor structure comprising interconnect layers of one or more electrical, optical, and fluid interconnects Formation method and application of the bonded semiconductor structure formed by the method

本發明與利用三度空間集積(three-dimensional integration)技術形成鍵結半導體結構之方法,以及應用此等方法形成之鍵結半導體結構有關。The present invention relates to a method of forming a bonded semiconductor structure using a three-dimensional integration technique, and a bonded semiconductor structure formed using such methods.

兩個或更多個半導體結構之三度空間集積(3D integration)可替微電子應用帶來許多好處。舉例而言,微電子構件之三度空間集積可以使電性能及電力消耗獲得改進,並同時減少元件所佔面積。相關資料可參見諸如P.Garrou等人所編之《The Handbook of 3D Integration》(Wiley-VCH出版,2008年)。The three dimensional integration of two or more semiconductor structures can bring many benefits to microelectronic applications. For example, a three-dimensional spatial accumulation of microelectronic components can improve electrical performance and power consumption while reducing the area occupied by components. For related information, see The Handbook of 3D Integration, edited by P. Garrou et al. (Wiley-VCH Publishing, 2008).

半導體結構之三度空間集積可以透過以下方式或該些方式之組合而達到:將一半導體晶粒附著至其他的一個或多個半導體晶粒(亦即晶粒對晶粒(D2D)),將一半導體晶粒附著至一個或多個半導體晶圓(亦即晶粒對晶圓(D2W)),以及將一半導體晶圓附著至其他的一個或多個半導體晶圓(亦即晶圓對晶圓(W2W))。The three-dimensional spatial accumulation of the semiconductor structure can be achieved by attaching a semiconductor die to other one or more semiconductor dies (ie, die-to-die (D2D)), A semiconductor die is attached to one or more semiconductor wafers (ie, die-to-wafer (D2W)), and a semiconductor wafer is attached to one or more other semiconductor wafers (ie, wafer-to-wafer Round (W2W)).

將一半導體結構鍵結至另一半導體結構所用之鍵結技術可以不同方式分類,一種是按兩個半導體結構間有無一層中間材料將其鍵結在一起而分類,第二種則是按鍵結界面是否允許電子(亦即電流)通過該界面而分類。所謂「直接鍵結方法」乃是在兩個半導體結構間建立直接的固體對固體化學鍵,以將其鍵結在一起而無需在這兩個半導體結構間使用 中間鍵結材料之方法。目前已發展出金屬對金屬之直接鍵結方法,可將一第一半導體結構中一表面上之金屬材料,鍵結至一第二半導體結構中一表面上之金屬材料。The bonding technique used to bond a semiconductor structure to another semiconductor structure can be classified in different ways. One is to classify the two semiconductor structures by an intermediate material, and the second is the key interface. Whether electrons (ie, current) are allowed to be classified through the interface. The so-called "direct bonding method" is to establish a direct solid-to-solid chemical bond between two semiconductor structures to bond them together without using between the two semiconductor structures. The method of bonding materials in the middle. At present, a metal-to-metal direct bonding method has been developed for bonding a metal material on a surface of a first semiconductor structure to a metal material on a surface of a second semiconductor structure.

金屬對金屬之直接鍵結方法亦可以按各方法操作時的溫度範圍加以分類。例如,一些金屬對金屬之直接鍵結方法是在相對高溫下進行,因此會造成鍵結界面處之金屬材料至少有部分熔化。此等直接鍵結製程可能不適合用於鍵結含有一個或多個元件結構之已處理半導體結構,因其相對高溫可能對之前形成之元件結構有不利影響。The metal-to-metal direct bonding method can also be classified according to the temperature range at which each method operates. For example, some metal-to-metal direct bonding methods are performed at relatively high temperatures, thus causing at least partial melting of the metallic material at the bonding interface. Such direct bonding processes may not be suitable for bonding processed semiconductor structures containing one or more component structures, as their relatively high temperatures may adversely affect previously formed component structures.

「熱壓鍵結」方法乃是在介於攝氏200度(200℃)及大約攝氏500度(500℃)間之高溫下,通常為介於大約攝氏300度(300℃)及大約攝氏400度(400℃)之間,於鍵結表面間施加壓力之直接鍵結方法。The "hot press bonding" method is performed at a high temperature between 200 ° C (200 ° C) and approximately 500 ° C (500 ° C), usually between approximately 300 ° C (300 ° C) and approximately 400 ° C A direct bonding method of applying pressure between the bonding surfaces between (400 ° C).

其他直接鍵結方法目前也已發展出來,該些方法可以在攝氏200度(200℃)或更低之溫度下進行。對於在攝氏200度(200℃)或更低溫度下進行之此等直接鍵結製程,本說明書稱為「超低溫」直接鍵結方法。超低溫直接鍵結方法可以經由仔細移除表面雜質及表面化合物(例如原生氧化層),以及經由在原子級尺度上增加兩個表面間緊密接觸之面積而實施。兩個表面間緊密接觸之面積通常經由以下方式達成:研磨該些鍵結表面以降低其表面粗度至接近原子級尺度之數值、於鍵結表面間施加壓力以造成塑性形變、或既研磨鍵結表面又對其施加壓力以達到此種塑性形變。兩個表面有直接的實際接觸後,一鍵結波便會在兩個緊靠表面間之界面被啟始並沿著該界面傳遞。當該波前傳遍兩個緊靠表面間之鍵結界面時,兩個緊靠表面間在波前所及之處便會建立起一直接化學鍵結。Other direct bonding methods have also been developed, which can be carried out at temperatures of 200 degrees Celsius (200 ° C) or lower. For such direct bonding processes performed at 200 degrees Celsius (200 ° C) or lower, this specification is referred to as an "ultra-low temperature" direct bonding process. The ultra-low temperature direct bonding process can be carried out by careful removal of surface impurities and surface compounds (eg, native oxide layers), and by increasing the area of intimate contact between the two surfaces on an atomic scale. The area of intimate contact between the two surfaces is typically achieved by grinding the bonding surfaces to reduce the surface roughness to a value close to the atomic scale, applying pressure between the bonding surfaces to cause plastic deformation, or both grinding keys. The surface of the junction is then stressed to achieve such plastic deformation. After direct physical contact between the two surfaces, a one-click wave is initiated at and along the interface between the two abutting surfaces. When the wavefront propagates through the bonding interface between the two abutting surfaces, a direct chemical bond is established between the two abutting surfaces at the wavefront.

一些超低溫直接鍵結方法之實施,可以不需在鍵結表面間之鍵結界面施加壓力,但在其他超低溫直接鍵結方法中,為了在鍵結界面達到合適的鍵結強度,可以在鍵結表面間之鍵結界面施加壓力。在本發明所屬技術領域中,於鍵結表面間施加壓力之超低溫直接鍵結方法通常稱為「表面輔助鍵結」或「SAB」方法。因此,在本說明書中「表面輔助鍵結」及「SAB」係指並包括在攝氏200度(200℃)或更低之溫度下,將一第一材料緊靠一第二材料,並在該些鍵結表面間之鍵結界面施加壓力,以使該第一材料直接鍵結至該第二材料之任何直接鍵結製程。Some ultra-low temperature direct bonding methods can be applied without the need to apply pressure at the bonding interface between the bonding surfaces, but in other ultra-low temperature direct bonding methods, in order to achieve a suitable bonding strength at the bonding interface, the bonding can be performed. Pressure is applied to the bonding interface between the surfaces. In the art to which the present invention pertains, an ultra-low temperature direct bonding method for applying pressure between bonding surfaces is generally referred to as a "surface assisted bonding" or "SAB" method. Therefore, in the present specification, "surface auxiliary bonding" and "SAB" mean and include a first material against a second material at a temperature of 200 degrees Celsius (200 ° C) or lower, and Pressure is applied to the bonding interface between the bonding surfaces to directly bond the first material to any direct bonding process of the second material.

本概要之提供旨在以簡要形式介紹一系列概念。該些概念將在本發明示範性實施例中進一步詳述。本概要之用意並非指出所主張專利標的之主要特點或基本特點,亦非用於限制所主張專利標的之範圍。The purpose of this summary is to present a series of concepts in a concise form. These concepts are further detailed in the exemplary embodiments of the invention. This summary is not intended to identify key features or essential features of the claimed subject matter, and is not intended to limit the scope of the claimed subject matter.

在一些實施例中,本發明包括形成鍵結半導體結構之方法。依照此等方法,可以提供一底材結構,其在相對較厚之一底材本體上包含相對較薄之一材料層。形成多個穿透晶圓互連(through wafer interconnect)並使之穿透該第一底材結構之較薄材料層。在該第一底材結構相反於該較厚底材本體之一面,將一第一已處理半導體結構鍵結在該第一底材結構之較薄材料層上方,並使該第一底材結構之至少一個導電部件在電性上與該些穿透晶圓互連中至少一個穿透晶圓互連耦合。在該第一已處理半導體結構相反於該第一底材結構之一面,將一轉移材料層提供於該第一已處理半導體結構上方。在該轉移材料層中形成電性互連、光學互連 及流體互連其中至少一種。在該轉移材料層相反於該第一已處理半導體結構之一面,將一第二已處理半導體結構提供於該轉移材料層上方。移除該底材結構之較厚底材本體,留下該底材結構之較薄材料層鍵結至該已處理半導體結構。該些穿透晶圓互連中至少一個穿透晶圓互連可以在電性上耦合至另一結構之一導電部件。In some embodiments, the invention includes a method of forming a bonded semiconductor structure. In accordance with such methods, a substrate structure can be provided that includes a relatively thin layer of material on a relatively thick substrate body. A plurality of thinner material layers are formed that penetrate the through wafer interconnect and penetrate the first substrate structure. A first processed semiconductor structure is bonded over the thinner material layer of the first substrate structure, and the first substrate structure is bonded to the first substrate structure opposite to one side of the thicker substrate body At least one electrically conductive component is electrically coupled to at least one of the through wafer interconnects. A layer of transfer material is provided over the first processed semiconductor structure opposite the first processed semiconductor structure opposite the first substrate structure. Forming electrical interconnections, optical interconnections in the layer of transfer material And fluid interconnecting at least one of them. A second processed semiconductor structure is provided over the layer of transfer material opposite the surface of the first processed semiconductor structure. The thicker substrate body of the substrate structure is removed leaving a thinner layer of material of the substrate structure bonded to the processed semiconductor structure. At least one of the through-wafer interconnects of the through-wafer interconnects can be electrically coupled to one of the conductive features of the other structure.

在其他實施例中,本發明包括應用本說明書所述方法而製作之鍵結半導體結構。舉例而言,在一些實施例中,本發明包括之鍵結半導體結構含有一底材結構、多個已處理半導體結構,以及該些已處理半導體結構上方之一轉移材料層,其位於該些已處理半導體結構相反於該底材結構之一面。該底材結構包含被多個穿透晶圓互連所穿透之相對較薄之一材料層,以及鍵結至該材料層之相對較厚之一底材本體。在該較薄材料層相反於該較厚底材本體之一面,該些已處理半導體結構在電性上耦合至該些穿透晶圓互連。電性互連、光學互連及流體互連其中至少一種配置在該轉移材料層中。In other embodiments, the invention includes bonded semiconductor structures fabricated using the methods described herein. For example, in some embodiments, the present invention includes a bonded semiconductor structure comprising a substrate structure, a plurality of processed semiconductor structures, and a layer of transfer material over the processed semiconductor structures, the The semiconductor structure is processed opposite one side of the substrate structure. The substrate structure includes a relatively thin layer of one material that is penetrated by a plurality of through-wafer interconnects, and a relatively thick one of the substrate bodies bonded to the layer of material. The processed semiconductor structures are electrically coupled to the through wafer interconnects in a side of the thinner material layer opposite the thicker substrate body. At least one of an electrical interconnect, an optical interconnect, and a fluid interconnect is disposed in the layer of transfer material.

本說明書提出之闡釋,其用意並非對任何特定半導體結構、元件、系統或方法之實際意見,而僅是用來描述本發明實施例之理想化陳述。The description of the present specification is not intended to be an actual description of any particular semiconductor structure, component, system or method, but is merely an idealized description for describing embodiments of the invention.

本說明書所用任何標題不應認定為限制本發明實施例之範圍,該範圍係由以下申請專利範圍及其法律同等效力所界定。在任何特定標題下所敘述之概念,通常亦適用於整份說明書之其他部分。The use of any headings in this specification should not be construed as limiting the scope of the embodiments of the invention, which is defined by the scope of the following claims and their legal equivalents. The concepts described under any particular heading also generally apply to the rest of the specification.

本說明書引用了一些參考資料,為所有目的,該些參考資料之完整揭露茲以此參照方式納入本說明書。此外,相對於本發明主張之專利標 的,該些引用之參考資料,不論本說明書如何描述其特點,均不予承認為習知技術。This specification is hereby incorporated by reference. In addition, the patent standard claimed with respect to the present invention The references cited herein, regardless of how they are described in the specification, are not admitted as prior art.

在本說明書中,「半導體結構」一詞係指並包括一半導體元件形成時所用之任何結構。舉例而言,半導體結構包括晶粒和晶圓(例如載體底材及元件底材),以及組裝或複合結構中含有在三度空間上彼此集積之兩個或更多個晶粒及/或晶圓者。半導體結構亦包括完全製作之半導體元件,以及半導體元件製作期間所形成之中間結構。In the present specification, the term "semiconductor structure" means and includes any structure used in the formation of a semiconductor element. For example, a semiconductor structure includes a die and a wafer (eg, a carrier substrate and an element substrate), and an assembled or composite structure containing two or more grains and/or crystals that are stacked on each other in three dimensions. Round. The semiconductor structure also includes fully fabricated semiconductor components, as well as intermediate structures formed during fabrication of the semiconductor components.

在本說明書中,「已處理半導體結構」一詞係指並包括任何半導體結構中含有至少已局部形成之一個或多個元件結構者。已處理半導體結構為半導體結構之一子集,所有已處理半導體結構均為半導體結構。In the present specification, the term "processed semiconductor structure" means and includes any semiconductor structure having at least one or more component structures that have been partially formed. The processed semiconductor structure is a subset of the semiconductor structure, and all of the processed semiconductor structures are semiconductor structures.

在本說明書中,「鍵結半導體結構」一詞係指並包括任何結構中含有附著在一起之兩個或更多個半導體結構者。鍵結半導體結構為半導體結構之一子集,所有鍵結半導體結構均為半導體結構。此外,鍵結半導體結構中含有一個或多個已處理半導體結構者,亦為已處理半導體結構。In the present specification, the term "bonded semiconductor structure" means and includes any structure having two or more semiconductor structures attached thereto. The bonded semiconductor structure is a subset of the semiconductor structure, and all of the bonded semiconductor structures are semiconductor structures. In addition, one or more of the processed semiconductor structures in the bonded semiconductor structure are also processed semiconductor structures.

在本說明書中,「元件結構」一詞係指並包括一已處理半導體結構之任何部分,其乃是、包含或定義出一半導體元件中一主動或被動組件之至少一部分,而該半導體元件乃是待形成於該半導體結構上方或之中者。舉例而言,元件結構包含積體電路之主動及被動組件,像是電晶體、換能器、電容、電阻、導電線、導電通孔及導電接觸墊。In the present specification, the term "elemental structure" means and includes any part of a processed semiconductor structure that is, includes, or defines at least a portion of an active or passive component of a semiconductor component. It is to be formed above or in the semiconductor structure. For example, the component structure includes active and passive components of the integrated circuit, such as transistors, transducers, capacitors, resistors, conductive lines, conductive vias, and conductive contact pads.

在本說明書中,「電性互連」一詞係指並包括一半導體結構中,經由在至少兩個元件結構間提供一電流路徑之至少一部分,而將該至少兩個元件結構在電性上連結起來之任何導電部件。In the present specification, the term "electrical interconnection" means and includes a semiconductor structure by electrically providing at least a portion of a current path between at least two component structures. Any conductive parts that are joined together.

在本說明書中,「穿透晶圓互連」或「TWI」一詞係指並包括穿透一第一半導體結構至少一部分之任何導電通孔,其跨越該第一半導體結構與一第二半導體結構間之一界面,在該第一半導體結構與該第二半導體結構間提供一結構上及/或電性上之互連。在本發明所屬技術領域中,穿透晶圓互連亦有其他名稱,像是「穿透矽通孔(through silicon vias)」、「穿透底材通孔(through substrate vias)」、「穿透晶圓通孔(through wafer vias)」,或前述名稱之英文簡稱,譬如「TSV」或「TWV」。穿透晶圓互連穿透一半導體結構之方向,通常大致垂直於該半導體結構中大致平坦之該些主要表面(亦即平行於「Z」軸之方向)。穿透晶圓互連為一種電性互連。In the present specification, the term "through-wafer interconnect" or "TWI" means and includes any conductive via that penetrates at least a portion of a first semiconductor structure, spanning the first semiconductor structure and a second semiconductor An interface between the structures provides a structural and/or electrical interconnection between the first semiconductor structure and the second semiconductor structure. In the technical field of the present invention, there are other names for penetrating wafer interconnects, such as "through silicon vias", "through substrate vias", and "through". Through-wafer vias, or the abbreviation of the above name, such as "TSV" or "TWV". The direction through which the through-wafer interconnect penetrates a semiconductor structure is generally substantially perpendicular to the substantially planar major surfaces of the semiconductor structure (ie, parallel to the "Z" axis). The penetrating wafer interconnect is an electrical interconnect.

在本說明書中,「光學互連」一詞係指並包括一半導體結構中,用於在至少兩個光學元件結構間提供一路徑之任何部件,該路徑有助於傳遞一種或多種波長之電磁輻射。雖然使用與視覺有關之「光學」二字,但對於在電磁輻射光譜中可見區段內或可見區段外(例如,在電磁輻射光譜可見區段及紅外區段內其中之一或兩者)之一種或多種波長之電磁輻射,光學互連亦可用於為其提供一路徑。In the present specification, the term "optical interconnection" means and includes any component in a semiconductor structure for providing a path between at least two optical element structures that facilitates the transmission of electromagnetic waves of one or more wavelengths. radiation. Although the term "optical" is used in relation to vision, it is outside the visible or visible region of the electromagnetic radiation spectrum (for example, one or both of the visible and infrared segments of the electromagnetic radiation spectrum) One or more wavelengths of electromagnetic radiation, optical interconnects may also be used to provide a path thereto.

在本說明書中,「流體互連」一詞係指並包括一半導體結構中,用於提供一流體路徑或通道之一部分之任何部件,該流體路徑或通道係用於傳送一流體通過該半導體結構之至少一部分。舉例而言,一種流體互連可以包含一流體通道之第一部分,其將該流體通道之第二部分與該流體通道之第三部分互相連接起來。In the present specification, the term "fluid interconnection" means and includes any component in a semiconductor structure for providing a fluid path or a portion of a channel for transporting a fluid through the semiconductor structure. At least part of it. For example, a fluid interconnect can include a first portion of a fluid passage that interconnects a second portion of the fluid passage with a third portion of the fluid passage.

依照本發明一些實施例,一可回收底材結構可以暫時鍵結至一半導 體結構,並用於一鍵結半導體結構之形成。當該半導體結構經過處理後,該可回收底材結構便可以自該半導體結構移除,以形成該鍵結半導體結構。該處理可以包含在該半導體結構上提供一轉移材料層、在該轉移材料層中形成電性互連、光學互連及流體互連其中至少一種,以及將另一已處理半導體結構鍵結在該轉移材料層上方。According to some embodiments of the invention, a recyclable substrate structure can be temporarily bonded to a half lead Body structure and used for the formation of a bonded semiconductor structure. After the semiconductor structure is processed, the recyclable substrate structure can be removed from the semiconductor structure to form the bonded semiconductor structure. The processing can include providing a layer of transfer material on the semiconductor structure, forming at least one of an electrical interconnect, an optical interconnect, and a fluid interconnect in the layer of transfer material, and bonding another processed semiconductor structure to the Transfer the material layer above.

圖1A至1C呈現一底材結構120(圖1C)之製作,該底材結構可為本發明一些實施例所採用。參照圖1A,提供一底材結構100,其在相對較厚之一底材本體104上包含相對較薄之一材料層102。在一些實施例中,該底材結構100可以包含平均直徑為數百公釐或更大之一晶圓級底材。作為非限制性質之範例,該較薄材料層102所具有之平均厚度可以為大約20微米(20 μm)或更薄、大約2微米(2.0 μm)或更薄、大約1.5微米(1.5 μm)或更薄,或甚至大約1微米(1 μm)或更薄。該較厚底材本體104所具有之平均厚度,舉例而言,可以介於大約600微米(600 μm)及數公分之間。1A through 1C illustrate the fabrication of a substrate structure 120 (Fig. 1C) that may be employed in accordance with some embodiments of the present invention. Referring to FIG. 1A, a substrate structure 100 is provided that includes a relatively thin layer of material 102 on a relatively thick substrate body 104. In some embodiments, the substrate structure 100 can comprise a wafer level substrate having an average diameter of hundreds of meters or more. As an example of non-limiting properties, the thinner material layer 102 can have an average thickness of about 20 microns (20 μm) or less, about 2 microns (2.0 μm) or less, about 1.5 microns (1.5 μm), or Thinner, or even about 1 micron (1 μm) or thinner. The thicker substrate body 104 has an average thickness, for example, of between about 600 microns (600 μm) and a few centimeters.

該較薄材料層102可以包含一種半導體材料,例如矽或鍺。此種半導體材料可以為多晶或至少實質上由單晶材料組成,且此種半導體材料可以為有摻雜或無摻雜。在其他實施例中,該較薄材料層102可以包含一種陶瓷材料,像是一種氧化物(例如氧化矽(SiO2 )、氧化鋁(Al2 O3 )等等)、一種氮化物(例如氮化矽(Si3 N4 )、氮化硼(BN)等等),或一種氮氧化物(例如氮氧化矽(SiON))。The thinner material layer 102 can comprise a semiconductor material such as tantalum or niobium. Such a semiconductor material may be polycrystalline or at least substantially composed of a single crystal material, and such semiconductor material may be doped or undoped. In other embodiments, the thinner material layer 102 may comprise a ceramic material such as an oxide (eg, yttrium oxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), etc.), a nitride (eg, nitrogen). Hydrazine (Si 3 N 4 ), boron nitride (BN), etc., or an oxynitride (such as cerium oxynitride (SiON)).

該較厚底材本體104所具有之組成可以不同於該較薄材料層102之組成,但其本身可以包含上文中關於該較薄材料層102所述之一種半導 體材料或一種陶瓷材料。在其他實施例中,該較厚底材本體104可以包含一種金屬或金屬合金。The thicker substrate body 104 can have a composition that is different from the composition of the thinner material layer 102, but can itself comprise a semi-conductive material as described above with respect to the thinner material layer 102. Body material or a ceramic material. In other embodiments, the thicker substrate body 104 can comprise a metal or metal alloy.

在一些實施例中,可以利用暫時性鍵結技術,例如Sadaka等人於2010年7月15日在美國專利申請案12/837,326號中所揭露者,該申請案全部內容茲以此參照方式納入本說明書,將該較薄材料層102暫時附著至該較厚底材本體104。In some embodiments, a temporary bonding technique can be utilized, such as that disclosed in U.S. Patent Application Serial No. 12/837,326, the entire disclosure of which is incorporated herein by reference. In this specification, the thinner material layer 102 is temporarily attached to the thicker substrate body 104.

該較厚底材本體104可以包含該底材結構100中可回收及可再利用之一部分,如下文所詳述。The thicker substrate body 104 can comprise a portion of the substrate structure 100 that is recyclable and reusable, as described in more detail below.

參照圖1B,可以使多個穿透晶圓互連112形成並穿透該較薄材料層102,以形成圖1B之底材結構110。形成該些穿透晶圓互連112之各種不同方法已為本發明所屬技術領域所知,且可以為本發明之實施例所採用。作為非限制性之一範例,可以在該較薄材料層102之曝露主要表面上提供帶有圖案之一遮罩層。該圖案遮罩層可以包含多個孔隙,該些孔隙在欲形成穿過該較薄材料層102之該些穿透晶圓互連112之位置處穿透該圖案遮罩層。接著可以利用一種蝕刻製程(例如各向異性濕式化學蝕刻製程,或各向異性乾式反應離子蝕刻製程)蝕刻出穿透該較薄材料層102之通孔。該些通孔形成後,便可以移除該圖案遮罩層,然後將一種或多種導電之金屬或金屬合金(例如銅或一種銅合金)填入該些通孔,以形成該些穿透晶圓互連112。舉例而言,可以使用物理氣相沉積(PVD)製程、化學氣相沉積(CVD)製程、無電電鍍製程及電解電鍍製程其中一種或多種,在該些通孔中提供導電材料。將該導電材料以沉積或其他方式提供於該些通孔內後,便可以利用一種蝕刻或研磨製程,將仍存在 於該表面102上之任何導電材料移除,以形成該些穿透晶圓互連112。Referring to FIG. 1B, a plurality of through wafer interconnects 112 can be formed and penetrated through the thinner material layer 102 to form the substrate structure 110 of FIG. 1B. Various different methods of forming the through-wafer interconnects 112 are known in the art to which the present invention pertains and may be employed in embodiments of the present invention. As a non-limiting example, one of the patterned mask layers may be provided on the exposed major surface of the thinner material layer 102. The patterned mask layer can include a plurality of apertures that penetrate the patterned mask layer at locations where the through-wafer interconnects 112 are to be formed through the thinner material layer 102. The vias penetrating the thinner material layer 102 can then be etched using an etch process such as an anisotropic wet chemical etch process or an anisotropic dry reactive ion etch process. After the through holes are formed, the patterned mask layer can be removed, and then one or more conductive metals or metal alloys (such as copper or a copper alloy) are filled into the through holes to form the through crystals. Circular interconnect 112. For example, one or more of a physical vapor deposition (PVD) process, a chemical vapor deposition (CVD) process, an electroless plating process, and an electrolytic plating process may be used to provide a conductive material in the via holes. After the conductive material is deposited or otherwise provided in the through holes, an etching or polishing process can be utilized, which will still exist. Any conductive material on the surface 102 is removed to form the through wafer interconnects 112.

形成穿透該較薄材料層102之該些穿透晶圓互連112後,便可以在該較薄材料層102相反於該較厚底材本體104之一面,選擇性地將一個或多個重分佈層(RDL)122形成於該較薄材料層102上方,以形成圖1C所示之底材結構120。如同在本發明所屬技術領域中已知,重分佈層可以用於重新分佈一第一結構或元件之電性部件之位置,以容納所要耦合之另一結構或元件上之導電部件模式。換言之,一重分佈層可以在其第一面具有一第一導電部件模式,並在與該第一面相反之第二面具有不同之第二導電部件模式,其中,該第一面上的該些導電部件透過該重分佈層,分別與位於相反第二面之對應導電部件在電性上互連。After forming the through-wafer interconnects 112 that penetrate the thinner material layer 102, one or more of the thinner material layers 102 may be selectively opposite one of the thicker substrate bodies 104. A distribution layer (RDL) 122 is formed over the thinner material layer 102 to form the substrate structure 120 shown in FIG. 1C. As is known in the art to which the present invention pertains, a redistribution layer can be used to redistribute the position of an electrical component of a first structure or component to accommodate a pattern of conductive features on another structure or component to be coupled. In other words, a redistribution layer may have a first conductive component pattern in its first mask and a second conductive component pattern in a second surface opposite the first surface, wherein the first surface The conductive members are electrically connected to the corresponding conductive members on the opposite second side through the redistribution layer.

如圖1C所示,該重分佈層122可以包含多個導電部件124,該些導電部件配置在一介電材料126內並被該介電材料圍繞。該些導電部件124可以包含導電墊、橫向延伸之導電線或導電跡線,及縱向延伸之導電通孔其中一種或多種。此外,該重分佈層122可以包含一層一層依序覆蓋而形成之多層,其中每一層皆包含導電部件124及介電材料126,且某一層中的導電部件124可以與相鄰層之導電部件124有直接的物理接觸及電性接觸,這樣該重分佈層122之該些導電部件124便會從該重分佈層122之一面,連續穿過該介電材料126,延伸到該重分佈層122之相反面。在該重分佈層122與該較薄材料層102及該些穿透晶圓互連112相鄰之那一面,該重分佈層122中該些導電部件124所配置之模式,可以與該些穿透晶圓互連112所配置之模式互補,這樣該些穿透晶圓互連112便會與該重分佈層122中該些對應導電部件124有直接的物理接觸 及電性接觸。如上文所述,該重分佈層122中該些導電部件124之模式可以從該重分佈層122之一面,跨越該重分佈層122之厚度,重分佈至該重分佈層122之另一面。As shown in FIG. 1C, the redistribution layer 122 can include a plurality of electrically conductive features 124 disposed within and surrounded by a dielectric material 126. The conductive features 124 can include one or more of a conductive pad, laterally extending conductive or conductive traces, and longitudinally extending conductive vias. In addition, the redistribution layer 122 may comprise a plurality of layers formed by sequentially covering one layer, wherein each layer includes a conductive member 124 and a dielectric material 126, and the conductive member 124 in one layer may be connected to the conductive member 124 of the adjacent layer. There is direct physical contact and electrical contact, such that the conductive members 124 of the redistribution layer 122 extend from the surface of the redistribution layer 122 continuously through the dielectric material 126 to the redistribution layer 122. The opposite side. On the side of the redistribution layer 122 adjacent to the thinner material layer 102 and the through-wafer interconnects 112, the patterns of the conductive members 124 in the redistribution layer 122 can be matched with the patterns The patterns of the through-wafer interconnects 112 are complementary such that the through-wafer interconnects 112 are in direct physical contact with the corresponding conductive features 124 in the redistribution layer 122. And electrical contact. As described above, the pattern of the conductive members 124 in the redistribution layer 122 may be redistributed from one surface of the redistribution layer 122 across the thickness of the redistribution layer 122 to the other side of the redistribution layer 122.

參照圖1D,形成該重分佈層122之後,便可以在該底材結構120之較薄材料層102相反於該較厚底材本體104之一面,將至少一個已處理半導體結構132A鍵結在該較薄材料層102上方,以形成圖1D之結構130。舉例而言,該至少一個已處理半導體結構132A可以直接鍵結至該重分佈層122,如圖1D所示。Referring to FIG. 1D, after the redistribution layer 122 is formed, at least one processed semiconductor structure 132A can be bonded to the thinner material layer 102 of the substrate structure 120 opposite to one of the thicker substrate bodies 104. Above the thin material layer 102 to form the structure 130 of Figure 1D. For example, the at least one processed semiconductor structure 132A can be directly bonded to the redistribution layer 122, as shown in FIG. 1D.

在一些實施例中,可以在該底材結構120之較薄材料層102相反於該較厚底材本體104之一面,將多個已處理半導體結構132A、132B、132C鍵結至該較薄材料層102上方之重分佈層122,如圖1D所示。該些已處理半導體結構132A、132B、132C可以沿著一共同平面在橫向上並列配置,該共同平面乃平行於該第一底材結構120之一主要表面,如圖1D所示。換言之,該些已處理半導體結構132A、132B、132C中的每一個可以在該底材結構120上佔據一不同區域,且從其所在位置可以畫出一平面,該平面會通過該些已處理半導體結構132A、132B、132C中每個已處理半導體結構,且平行於該第一底材結構120之一主要表面。In some embodiments, a plurality of processed semiconductor structures 132A, 132B, 132C can be bonded to the thinner material layer on a side of the thinner material layer 102 of the substrate structure 120 opposite one of the thicker substrate body 104. The redistribution layer 122 above 102 is as shown in FIG. 1D. The processed semiconductor structures 132A, 132B, 132C may be juxtaposed in a lateral direction along a common plane that is parallel to one of the major surfaces of the first substrate structure 120, as shown in FIG. 1D. In other words, each of the processed semiconductor structures 132A, 132B, 132C can occupy a different area on the substrate structure 120, and a plane can be drawn from its location that passes through the processed semiconductors. Each of the structures 132A, 132B, 132C has a semiconductor structure processed and is parallel to one of the major surfaces of the first substrate structure 120.

該些已處理半導體結構132A、132B、132C中的一個或多個可以包含像是半導體晶粒,亦可以包含電子信號處理器、記憶元件及光電元件(例如發光二極體、雷射、光電二極體、太陽能電池等等)其中一種或多種。One or more of the processed semiconductor structures 132A, 132B, 132C may comprise, for example, a semiconductor die, and may also include an electronic signal processor, a memory component, and a photovoltaic component (eg, a light emitting diode, a laser, a photodiode) One or more of a polar body, a solar cell, and the like.

將該些已處理半導體結構132A、132B、132C鍵結至該底材結構120 時,該些已處理半導體結構132A、132B、132C之導電部件134可以在電性上與該重分佈層122之導電部件124及穿透該較薄材料層102之該些穿透晶圓互連112耦合。Bonding the processed semiconductor structures 132A, 132B, 132C to the substrate structure 120 The conductive features 134 of the processed semiconductor structures 132A, 132B, 132C can be electrically interconnected with the conductive features 124 of the redistribution layer 122 and the through wafers that penetrate the thinner material layer 102. 112 coupled.

將該些已處理半導體結構132A、132B、132C鍵結至該底材結構120所用之鍵結製程,可以在大約400℃或更低之一個或多個溫度下進行。在一些實施例中,可以利用在大約400℃或更低之一個或多個溫度下實施之一種熱壓或非熱壓直接鍵結製程,將該些已處理半導體結構132A、132B、132C鍵結至該底材結構120。在一些實施例中,可以利用在大約200℃或更低之一個或多個溫度下實施之一種超低溫直接鍵結製程,將該些已處理半導體結構132A、132B、132C鍵結至該底材結構120。在一些例子中,該鍵結製程可以在大約為室溫之溫度下進行。在此等較低溫度下進行鍵結製程,可以避免在無意間損壞該些已處理半導體結構132A、132B、132C中的元件結構。此外,在一些實施例中,該鍵結製程可以包含一表面輔助鍵結製程。該直接鍵結製程可以包含氧化物對氧化物(例如二氧化矽對二氧化矽)之直接鍵結製程,及/或金屬對金屬(例如銅對銅)之直接鍵結製程。The bonding process used to bond the processed semiconductor structures 132A, 132B, 132C to the substrate structure 120 can be performed at one or more temperatures of about 400 ° C or less. In some embodiments, the processed semiconductor structures 132A, 132B, 132C can be bonded using a hot or non-hot press direct bonding process implemented at one or more temperatures of about 400 ° C or less. To the substrate structure 120. In some embodiments, the processed semiconductor structures 132A, 132B, 132C can be bonded to the substrate structure using an ultra-low temperature direct bonding process implemented at one or more temperatures of about 200 ° C or less. 120. In some examples, the bonding process can be carried out at a temperature of about room temperature. Performing the bonding process at such lower temperatures can avoid unintentional damage to the component structures in the processed semiconductor structures 132A, 132B, 132C. Moreover, in some embodiments, the bonding process can include a surface assist bonding process. The direct bonding process can include a direct bonding process of an oxide to oxide (eg, ceria versus cerium oxide), and/or a direct bonding process of a metal to metal (eg, copper to copper).

在一些實施例中,可以利用一種或多種三度空間集積製程,將額外的已處理半導體結構堆疊在該些已處理半導體結構132A、132B、132C上方,並使其與該些已處理半導體結構132A、132B、132C在電性上及物理上耦合。茲將此等製程之範例,參照圖1E至1H敘述如下。In some embodiments, additional processed semiconductor structures may be stacked over the processed semiconductor structures 132A, 132B, 132C and associated with the processed semiconductor structures 132A using one or more three-dimensional spatial accumulation processes. 132B and 132C are electrically and physically coupled. An example of such processes will be described below with reference to Figures 1E to 1H.

參照圖1E,將該些已處理半導體結構132A、132B、132C鍵結至該底材結構120後,便可以將一介電材料138沉積在該些已處理半導體結 構132A、132B、132C上方及四周,以形成圖1E之結構140。該介電材料138可以包含,舉例而言,一種聚合物材料或一種氧化物材料(例如氧化矽),且該介電材料138可以利用諸如一種旋轉塗佈製程或化學氣相沉積(CVD)製程而沉積。可以以低應力及相對較高沉積速率沉積之一種氧化物材料可能是比較適合的材料。該氧化物材料所具有之組成不會因為後續處理(例如在高達400℃溫度下進行之回火)而分解。作為非限制性質之範例,在一些實施例中,該介電材料138可以包含厚度大於為30微米(30 μm)之一氧化物層,其係在大約400℃之溫度下利用一電漿增強化學氣相沉積(PECVD)製程沉積而成。該氧化物層可以以介於每分鐘1.8微米及每分鐘3.0微米間之速率沉積。此種沉積薄膜之殘留應力可以低至大約為15 MPa。Referring to FIG. 1E, after the processed semiconductor structures 132A, 132B, 132C are bonded to the substrate structure 120, a dielectric material 138 can be deposited on the processed semiconductor junctions. The upper and the periphery of the structures 132A, 132B, and 132C are formed to form the structure 140 of FIG. 1E. The dielectric material 138 can comprise, for example, a polymeric material or an oxide material (e.g., yttria), and the dielectric material 138 can utilize, for example, a spin coating process or a chemical vapor deposition (CVD) process. And deposition. An oxide material that can be deposited at low stress and relatively high deposition rates may be a suitable material. The composition of the oxide material does not decompose due to subsequent processing, such as tempering at temperatures up to 400 °C. As an example of non-limiting properties, in some embodiments, the dielectric material 138 can comprise an oxide layer having a thickness greater than 30 microns (30 μm), which is enhanced by a plasma at a temperature of about 400 ° C. A vapor deposition (PECVD) process is deposited. The oxide layer can be deposited at a rate of between 1.8 microns per minute and 3.0 microns per minute. The residual stress of such a deposited film can be as low as about 15 MPa.

該介電材料138可以保形(conformal)方式沉積在圖1D之結構130上方,以使該介電材料138之曝露主要表面139包含高峰及低谷。該些高峰可以位於該些已處理半導體結構132A、132B、132C上方,該些低谷可以位於該些已處理半導體結構132A、132B、132C之間區域上方方,如圖1E所示。The dielectric material 138 can be deposited in a conformal manner over the structure 130 of FIG. 1D such that the exposed major surface 139 of the dielectric material 138 includes peaks and valleys. The peaks may be located above the processed semiconductor structures 132A, 132B, 132C, which may be located above the area between the processed semiconductor structures 132A, 132B, 132C, as shown in FIG. 1E.

參照圖1F,該介電材料138之曝露主要表面139可以予以平坦化,且該介電材料138之一部分可加以移除,以使該些已處理半導體結構132A、132B、132C穿過該介電材料138曝露出來,並形成圖1F所示之結構150。舉例而言,可以利用一種化學蝕刻製程(乾式或濕式)、一種機械研磨製程,或一種化學機械研磨(CMP)製程,使該介電材料138之曝露主要表面139平坦化、移除該介電材料138之一部分,並使該些 已處理半導體結構132A、132B、132C穿過該介電材料138曝露出來。Referring to FIG. 1F, the exposed major surface 139 of the dielectric material 138 can be planarized, and a portion of the dielectric material 138 can be removed to pass the processed semiconductor structures 132A, 132B, 132C through the dielectric. Material 138 is exposed and forms structure 150 as shown in FIG. 1F. For example, a chemical etching process (dry or wet), a mechanical polishing process, or a chemical mechanical polishing (CMP) process can be used to planarize the exposed major surface 139 of the dielectric material 138 and remove the dielectric. a part of the electrical material 138 and make these The processed semiconductor structures 132A, 132B, 132C are exposed through the dielectric material 138.

如圖1G所示,可以形成額外之多個穿透晶圓互連162並使之至少局部穿過該些已處理半導體結構132A、132B、132C,以形成該結構160。所形成之該些額外穿透晶圓互連162可以從該些已處理半導體結構132A、132B、132C之曝露主要表面穿過該些已處理半導體結構132A、132B、132C,而延伸至該些已處理半導體結構132A、132B、132C內之導電部件134。該些穿透晶圓互連162可以如前文中關於形成該些穿透晶圓互連112所敘述而形成。但可以將該些製程之溫度限制在大約400℃或更低,以免損及該些已處理半導體結構132A、132B、132C內之元件結構。As shown in FIG. 1G, an additional plurality of through wafer interconnects 162 may be formed and passed at least partially through the processed semiconductor structures 132A, 132B, 132C to form the structure 160. The additional through-wafer interconnects 162 formed may extend from the exposed major surfaces of the processed semiconductor structures 132A, 132B, 132C through the processed semiconductor structures 132A, 132B, 132C to the The conductive features 134 within the semiconductor structures 132A, 132B, 132C are processed. The through wafer interconnects 162 can be formed as described above with respect to forming the through wafer interconnects 112. However, the temperature of the processes can be limited to about 400 ° C or less to avoid damaging the component structures within the processed semiconductor structures 132A, 132B, 132C.

參照圖1H,形成該些額外穿透晶圓互連162之後,便可以利用上文中參照圖1D至1G所述之該些製程提供額外之已處理半導體結構132D、132E、132F,使之在縱向上位於該些已處理半導體結構132A、132B、132C上方,以形成圖1H所示之鍵結半導體結構170。作為一範例,一已處理半導體結構132D可以直接鍵結至該已處理半導體結構132A,一已處理半導體結構132E可以直接鍵結至該已處理半導體結構132B,且一已處理半導體結構132F可以直接鍵結至該已處理半導體結構132C。該些鍵結製程之溫度可以限制在大約400℃或更低,以免損及該些已處理半導體結構132A至132F內之元件結構,且該些鍵結製程可以包含一種熱壓直接鍵結製程、一種非熱壓直接鍵結製程,或一種超低溫直接鍵結製程。此外,在一些實施例至,該些直接鍵結製程可以包含表面輔助鍵結製程。Referring to FIG. 1H, after forming the additional through-wafer interconnects 162, additional processed semiconductor structures 132D, 132E, 132F may be provided in the vertical direction using the processes described above with reference to FIGS. 1D through 1G. The upper portion is over the processed semiconductor structures 132A, 132B, 132C to form the bonded semiconductor structure 170 shown in FIG. 1H. As an example, a processed semiconductor structure 132D can be directly bonded to the processed semiconductor structure 132A, a processed semiconductor structure 132E can be directly bonded to the processed semiconductor structure 132B, and a processed semiconductor structure 132F can be directly bonded. The resulting semiconductor structure 132C is bonded. The bonding process temperature may be limited to about 400 ° C or lower to avoid damaging the component structures in the processed semiconductor structures 132A to 132F, and the bonding processes may include a hot pressing direct bonding process, A non-hot pressing direct bonding process, or an ultra-low temperature direct bonding process. Moreover, in some embodiments, the direct bonding processes can include surface assist bonding processes.

在此組構中,該些已處理半導體結構132D、132E、132F沿著垂直於該第一底材結構120中該些主要表面之直線,在縱向上分別配置在該些已處理半導體結構132A、132B、132C上方。舉例而言,該已處理半導體結構132A及該已處理半導體結構132D係沿著垂直於該第一底材結構120中該些主要表面之一條共同線,在縱向上配置成一個在上一個在下。換言之,從該已處理半導體結構132A及該已處理半導體結構132D配置之方式可以畫出一條共同線,其穿過該已處理半導體結構132A及該已處理半導體結構132D而垂直於該第一底材結構120之該些主要表面。In this configuration, the processed semiconductor structures 132D, 132E, 132F are disposed in the longitudinal direction of the processed semiconductor structures 132A along a line perpendicular to the major surfaces of the first substrate structure 120, Above 132B and 132C. For example, the processed semiconductor structure 132A and the processed semiconductor structure 132D are disposed along a common line perpendicular to one of the major surfaces of the first substrate structure 120, and are disposed one above the other in the longitudinal direction. In other words, a common line can be drawn from the processed semiconductor structure 132A and the processed semiconductor structure 132D, which passes through the processed semiconductor structure 132A and the processed semiconductor structure 132D perpendicular to the first substrate. The major surfaces of structure 120.

將該些已處理半導體結構132D、132E、132F鍵結至該些已處理半導體結構132A、132B、132C之後,便可以形成額外之穿透晶圓互連172,並使其至少局部穿過該些已處理半導體結構132D、132E、132F。所形成之該些額外穿透晶圓互連172可以從該些已處理半導體結構132D、132E、132F之曝露主要表面穿過該些已處理半導體結構132D、132E、132F,而延伸至該些穿透晶圓互連162或該些已處理半導體結構132A、132B、132C之其他導電部件。該些穿透晶圓互連172可以如前文中關於形成該些穿透晶圓互連112所敘述而形成。但可以將該些製程之溫度限制在大約400℃或更低,以免損及該些已處理半導體結構132A至132F內之元件結構。After the processed semiconductor structures 132D, 132E, 132F are bonded to the processed semiconductor structures 132A, 132B, 132C, additional through-wafer interconnects 172 can be formed and at least partially passed through the portions. Semiconductor structures 132D, 132E, 132F have been processed. The additional through-wafer interconnects 172 formed may extend from the exposed major surfaces of the processed semiconductor structures 132D, 132E, 132F through the processed semiconductor structures 132D, 132E, 132F to the Through-wafer interconnect 162 or other conductive features of the processed semiconductor structures 132A, 132B, 132C. The through wafer interconnects 172 can be formed as described above with respect to forming the through wafer interconnects 112. However, the temperature of the processes can be limited to about 400 ° C or less to avoid damaging the component structures within the processed semiconductor structures 132A through 132F.

上文中關於圖1D至1G所述之該些製程可以視需要重複一次或多次,以在三度空間集積製程中將任何數目之其他已處理半導體結構層,在縱向上集積於該些已處理半導體結構132A至132F上方。The processes described above with respect to Figures 1D through 1G may be repeated one or more times as needed to accumulate any number of other processed semiconductor structural layers in the three-dimensional spatial accumulation process in the longitudinal direction. Above the semiconductor structures 132A-132F.

形成圖1H之鍵結半導體結構170後,便可以在該些已處理半導體結構132A至132F相反於該底材結構120之一面,將一轉移材料層212(圖1K)提供於該些已處理半導體結構132A至132F上方。茲將可用於將該轉移材料層212(圖1K)提供於該些已處理半導體結構132A至132F上方之方法之範例,參照圖1I至1K敘述如下。After forming the bonded semiconductor structure 170 of FIG. 1H, a transferred material layer 212 (FIG. 1K) can be provided to the processed semiconductors on the opposite side of the processed semiconductor structures 132A-132F opposite the substrate structure 120. Above the structures 132A to 132F. An example of a method that can be used to provide the transfer material layer 212 (Fig. 1K) over the processed semiconductor structures 132A-132F is described below with reference to Figures 1I through 1K.

作為非限制性之一範例,可以利用本發明所屬技術領域中所稱之SMARTCUT®製程,將該轉移材料層212提供於該些已處理半導體結構132A至132F上方,以形成圖1K之鍵結半導體結構210。此等製程詳述於,舉例而言,美國專利RE 39,484號(2007年2月6日核發予Bruel)、美國專利6,303,468號(2001年10月16日核發予Aspar等人)、美國專利6,335,258號(2002年1月1日核發予Aspar等人)、美國專利6,756,286號(2004年6月29日核發予Moriceau等人)、美國專利6,809,044號(2004年10月26日核發予Aspar等人),及美國專利6,946,365號(2005年9月20日核發予Aspar等人)中,該些專利之完整揭露茲以此參照方式納入本說明書。As a non-limiting example, the transfer material layer 212 may be provided over the processed semiconductor structures 132A-132F using the SMARTCUT® process referred to in the art to which the present invention pertains to form the bonded semiconductor of FIG. 1K. Structure 210. Such processes are detailed, for example, in U.S. Patent No. RE 39,484 (issued to Bruel on February 6, 2007), U.S. Patent No. 6,303,468 (issued to Aspar et al. on October 16, 2001), and U.S. Patent No. 6,335,258. (issued to Aspar et al. on January 1, 2002), US Patent 6,756,286 (issued to Moriceau et al. on June 29, 2004), and US Patent 6,809,044 (issued to Aspar et al. on October 26, 2004). And U.S. Patent No. 6,946,365 issued to Aspar et al.

參照圖1I,在一種SMARTCUT®製程中,多個離子(例如氫離子、氦離子或惰性氣體離子其中一種或多種)可以沿著一離子植入平面192植入一額外底材結構190。在一些實施例中,該些離子植入該額外底材結構190之時機,可以為該額外底材結構190鍵結在該些已處理半導體結構132A至132F上方前,如下文參照圖1J所述。Referring to FIG. 1I, in a SMARTCUT® process, a plurality of ions (eg, one or more of hydrogen ions, helium ions, or inert gas ions) can be implanted along an ion implantation plane 192 with an additional substrate structure 190. In some embodiments, the timing of implantation of the ions into the additional substrate structure 190 can be prior to bonding the additional substrate structure 190 over the processed semiconductor structures 132A-132F, as described below with respect to FIG. 1J. .

該額外底材結構190可以包含一種半導體材料,譬如矽或鍺。此種半導體材料可以為多晶或至少實質上由單晶材料組成,且此種半導體材 料可以為有摻雜或無摻雜。在其他實施例中,該額外底材結構190可以包含一種陶瓷材料,像是一種氧化物(例如氧化矽(SiO2 )、氧化鋁(Al2 O3 )等等)、一種氮化物(例如氮化矽(Si3 N4 )、氮化硼(BN)等等),或一種氮氧化物(例如氮氧化矽(SiON))。在一些實施例中,該額外底材結構190可以包含一晶圓級底材。The additional substrate structure 190 can comprise a semiconductor material such as tantalum or niobium. Such a semiconductor material may be polycrystalline or at least substantially composed of a single crystal material, and such semiconductor material may be doped or undoped. In other embodiments, the additional substrate structure 190 can comprise a ceramic material such as an oxide (eg, yttrium oxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), etc.), a nitride (eg, nitrogen). Hydrazine (Si 3 N 4 ), boron nitride (BN), etc., or an oxynitride (such as cerium oxynitride (SiON)). In some embodiments, the additional substrate structure 190 can comprise a wafer level substrate.

離子可以沿著實質上垂直於該額外底材結構190中通常為平坦之主要表面之一方向而植入。如同在本發明所屬技術領域中已知,該些離子植入該額外底材結構190之深度,至少有部分為該些離子植入該額外底材結構190時所具能量之一函數。一般而言,以較低能量植入之離子,其植入深度相對較淺,以較高能量植入之離子,其植入深度相對較深。The ions may be implanted in a direction substantially perpendicular to one of the generally planar major surfaces of the additional substrate structure 190. As is known in the art to which the present invention pertains, the depth at which the ions are implanted into the additional substrate structure 190 is at least partially a function of the energy of the ions implanted into the additional substrate structure 190. In general, ions implanted at lower energies have a relatively shallow depth of implantation, and ions implanted at higher energies have a relatively deep implant depth.

離子可以以一預定能量植入該額外底材結構190,該預定能量之選定,旨在將該些離子植入該額外底材結構190內一理想深度。該些離子植入該額外底材結構190之時機,可以為該額外底材結構190鍵結在該些已處理半導體結構132A至132F上方之前或之後,如下文參照圖1J所述。作為一特定之非限制性範例,該離子植入平面192可以配置在該額外底材結構190內一深度D處,其與該額外底材結構190之一主要表面194相距從大約100奈米(100 nm)至大約1,000奈米(1,000 nm)。如同在本發明所屬技術領域中已知,一些離子被植入之深度無可避免地可能並非所要求之植入深度D,且作為該些離子從該額外底材結構190之主要表面至該額外底材結構190內某一深度之函數,該離子濃度(例如鍵結前)之圖表可能會顯示大致為鐘形(對稱或不對稱)之一曲線,該曲線在所要求之植入深度處具有一最大值。The ions may be implanted into the additional substrate structure 190 at a predetermined energy, the predetermined energy being selected to implant the ions into the additional substrate structure 190 at a desired depth. The timing at which the ions are implanted into the additional substrate structure 190 can be prior to or after the additional substrate structure 190 is bonded over the processed semiconductor structures 132A-132F, as described below with respect to FIG. 1J. As a specific, non-limiting example, the ion implantation plane 192 can be disposed at a depth D within the additional substrate structure 190 that is about 100 nanometers from one of the major surfaces 194 of the additional substrate structure 190 ( 100 nm) to approximately 1,000 nm (1,000 nm). As is known in the art to which the present invention pertains, the depth at which some ions are implanted may inevitably not be the desired implant depth D, and as the ions from the major surface of the additional substrate structure 190 to the additional A plot of the depth of the substrate structure 190, such as before the bond, may show a curve that is generally bell-shaped (symmetric or asymmetrical) having a desired implant depth A maximum.

將離子植入該額外底材結構190後,該些離子便可以在該額外底材結構190內定義出一離子植入平面192(在圖1I中以虛線呈現)。該離子植入平面192可以包含該額外底材結構190內之一層或一區域,其與該額外底材結構190內帶有最高離子濃度之平面對準(例如以其為中心圍繞)。該離子植入平面192可以在該額外底材結構190內定義出一弱化區域,在一後續製程中,該額外底材結構190可以沿著該弱化區域剝離或裂開。After implanting ions into the additional substrate structure 190, the ions can define an ion implantation plane 192 (shown in phantom in Figure 1I) within the additional substrate structure 190. The ion implantation plane 192 can include a layer or region within the additional substrate structure 190 that is aligned (eg, centered about) with the plane having the highest ion concentration within the additional substrate structure 190. The ion implantation plane 192 can define a weakened region within the additional substrate structure 190 that can be stripped or split along the weakened region in a subsequent process.

參照圖1J,在該些已處理半導體結構132A至132F相反於該第一底材結構120之一面,將該額外底材結構190鍵結至圖1H之半導體結構170中該些已處理半導體結構132A至132F上方,以形成圖1J所示之鍵結半導體結構200。在一些實施例中,可以利用一直接鍵結製程將該額外底材結構190鍵結至該鍵結半導體結構170。另外,可以選擇性使用一鍵結材料(未顯示)將該額外底材結構190鍵結至該鍵結半導體結構170。此種鍵結材料可以包含,舉例而言,氧化矽、氮化矽及兩者混合物其中一種或多種。此種鍵結材料可以形成或以其他方式提供於該額外底材結構190及該鍵結半導體結構170之該些緊靠表面其中之一或兩者,以改進兩者間之鍵結。Referring to FIG. 1J, the additional substrate structures 190 are bonded to the processed semiconductor structures 132A in the semiconductor structure 170 of FIG. 1H, opposite to one of the processed semiconductor structures 132A-132F opposite to the first substrate structure 120. Above 132F, a bonded semiconductor structure 200 as shown in FIG. 1J is formed. In some embodiments, the additional substrate structure 190 can be bonded to the bonded semiconductor structure 170 using a direct bonding process. Additionally, the additional substrate structure 190 can be selectively bonded to the bonded semiconductor structure 170 using a bonding material (not shown). Such a bonding material may comprise, for example, one or more of cerium oxide, cerium nitride, and a mixture of the two. Such bonding material may be formed or otherwise provided to one or both of the additional substrate structure 190 and the abutting surfaces of the bonding semiconductor structure 170 to improve bonding therebetween.

在一些實施例中,該額外底材結構190可以在大約400℃或更低之溫度下,或甚至在大約350℃或更低之溫度下鍵結至該鍵結半導體結構170。但在其他實施例中,該鍵結製程可以在更高之溫度下進行。In some embodiments, the additional substrate structure 190 can be bonded to the bonded semiconductor structure 170 at a temperature of about 400 ° C or less, or even at a temperature of about 350 ° C or less. However, in other embodiments, the bonding process can be performed at a higher temperature.

將相對較厚之額外底材結構190鍵結至該鍵結半導體結構170後,便可以將該額外底材結構190薄化,以形成該轉移材料層212及圖1K 所示之鍵結半導體結構210。該額外底材結構190之一部分196(見圖1J)可以從該額外底材結構190移除,而將相對較薄之轉移材料層212留在該鍵結半導體結構170之表面103上。After the relatively thick additional substrate structure 190 is bonded to the bonded semiconductor structure 170, the additional substrate structure 190 can be thinned to form the transfer material layer 212 and FIG. 1K. The illustrated semiconductor structure 210 is shown. A portion 196 (see FIG. 1J) of the additional substrate structure 190 can be removed from the additional substrate structure 190 while leaving a relatively thin layer of transfer material 212 on the surface 103 of the bonded semiconductor structure 170.

舉例而言,可以對該額外底材結構190加熱,以造成該額外底材結構190沿著該離子植入平面192裂開或斷裂。在一些實施例中,該額外底材結構190在此裂開製程期間之溫度可以維持在大約400℃或更低,或甚至在大約350℃或更低。但在其他實施例中,該裂開製程可以在更高之溫度下進行。另外,可以選擇性對該額外底材結構190施加機械力,以造成或協助該額外底材結構190沿著該離子植入平面192裂開。For example, the additional substrate structure 190 can be heated to cause the additional substrate structure 190 to crack or break along the ion implantation plane 192. In some embodiments, the temperature of the additional substrate structure 190 during this cleavage process can be maintained at about 400 ° C or less, or even at about 350 ° C or less. In other embodiments, however, the cleavage process can be performed at a higher temperature. Additionally, a mechanical force may be selectively applied to the additional substrate structure 190 to cause or assist in rupturing the additional substrate structure 190 along the ion implantation plane 192.

在其他實施例中,可以經由將該額外底材結構190(例如平均厚度大於約100微米之一層)鍵結至該鍵結半導體結構170,接著從該額外底材結構190相反於該鍵結半導體結構170之一面將該額外底材結構190薄化,而將該較薄轉移材料層212提供於該鍵結半導體結構170上方。舉例而言,可以經由從該額外底材結構190之一曝露主要表面移除材料,而使該額外底材結構190薄化。例如,可以利用一種化學製程(例如濕式或乾式化學蝕刻製程)、一種機械製程(例如研磨或舐磨製程),或經由一種化學機械研磨(CMP)製程,將材料從該額外底材結構190之曝露主要表面移除。經由實施此等鍵結及薄化製程,該較薄材料層102之厚度在一些實施例中可以大於20微米(20 μm)。在其他實施例中,該較薄材料層102之厚度在一些實施例中可以小於20微米(20 μm)。在一些實施例中,此等製程可以在大約400℃或更低,或甚至大約350℃或更低之一個或多個溫度下進行。但在其他實施例中,此等製程可以在更 高溫度下進行。In other embodiments, the additional substrate structure 190 (eg, a layer having an average thickness greater than about 100 microns) can be bonded to the bonded semiconductor structure 170, followed by the opposite substrate structure 190 opposite the bonded semiconductor One side of the structure 170 thins the additional substrate structure 190, and the thinner transfer material layer 212 is provided over the bonded semiconductor structure 170. For example, the additional substrate structure 190 can be thinned by exposing the primary surface removal material from one of the additional substrate structures 190. For example, material may be removed from the additional substrate structure 190 using a chemical process (eg, a wet or dry chemical etch process), a mechanical process (eg, a grinding or honing process), or via a chemical mechanical polishing (CMP) process. The main surface is removed by exposure. By performing such bonding and thinning processes, the thickness of the thinner material layer 102 can be greater than 20 microns (20 μm) in some embodiments. In other embodiments, the thickness of the thinner material layer 102 can be less than 20 microns (20 μm) in some embodiments. In some embodiments, such processes can be carried out at one or more temperatures of about 400 ° C or less, or even about 350 ° C or less. But in other embodiments, such processes can be more Perform at high temperatures.

在另外之實施例中,該較薄轉移材料層212可以原地 形成於該鍵結半導體結構170之曝露主要表面上方(例如該表面上)。舉例而言,圖1K之鍵結半導體結構210可以經由在該鍵結半導體結構170之一曝露主要表面上將諸如矽、多晶矽或非晶質矽之半導體材料沉積至一理想厚度而形成。在一些實施例中,該沉積製程可以在大約400℃或更低,或甚至在大約350℃或更低之一個或多個溫度下進行。舉例而言,如本發明所屬技術領域中已知,用於形成該較薄轉移材料層212之一低溫沉積製程可以利用一電漿增強化學氣相沉積製程而實施。但在其他實施例中,該沉積製程可以在更高溫度下進行。In other embodiments, the thinner transition material layer 212 can be formed in situ over the exposed major surface of the bonded semiconductor structure 170 (e.g., on the surface). For example, the bonded semiconductor structure 210 of FIG. 1K can be formed by depositing a semiconductor material such as germanium, polysilicon or amorphous germanium onto a desired thickness on one of the exposed major surfaces of the bonded semiconductor structure 170. In some embodiments, the deposition process can be performed at about one or more temperatures of about 400 ° C or less, or even at about 350 ° C or less. For example, as is known in the art, a low temperature deposition process for forming the thinner transfer material layer 212 can be performed using a plasma enhanced chemical vapor deposition process. In other embodiments, however, the deposition process can be performed at higher temperatures.

圖1K之鍵結半導體結構210為一中間結構,其可以受到進一步處理,以形成可操作之半導體元件成品。舉例而言,形成圖1K之鍵結半導體結構210後,便可以在該轉移材料層212中形成電性互連、光學互連及流體互連其中至少一種,並可以在另外之三度空間集積製程中,將一個或多個額外之已處理半導體結構提供於該轉移材料層212上方。The bonded semiconductor structure 210 of Figure 1K is an intermediate structure that can be further processed to form a finished semiconductor component. For example, after forming the bonded semiconductor structure 210 of FIG. 1K, at least one of electrical interconnection, optical interconnection, and fluid interconnection can be formed in the transfer material layer 212, and can be accumulated in another three-dimensional space. In the process, one or more additional processed semiconductor structures are provided over the layer of transfer material 212.

茲將可用於在圖1K之鍵結半導體結構210之轉移材料層212中形成一個或多個電性互連之方法之實施例範例,參照圖2A至2E敘述如下。An example of an embodiment of a method that can be used to form one or more electrical interconnections in the transfer material layer 212 of the bonded semiconductor structure 210 of FIG. 1K is described below with reference to FIGS. 2A through 2E.

參照圖2A,該轉移材料層212中可以形成多個電性互連302,以形成圖2A之鍵結半導體結構300。在一些實施例中,該些電性互連302可以包含穿透晶圓互連,且每個電性互連302可以穿透該轉移材料層212而延伸至該些穿透晶圓互連172其中之一,這樣,每個電性互連302在結構上及電性上便與該些穿透晶圓互連172其中之一耦合。該些電性互 連302可以包含一種導電材料,例如一種金屬或金屬合金(例如銅或一種銅合金)。該些電性互連302可以利用前文中參照圖1B所述與該些穿透晶圓互連112有關之方法而形成。Referring to FIG. 2A, a plurality of electrical interconnects 302 may be formed in the transfer material layer 212 to form the bonded semiconductor structure 300 of FIG. 2A. In some embodiments, the electrical interconnects 302 can include through-wafer interconnects, and each electrical interconnect 302 can extend through the transfer material layer 212 to the through-wafer interconnects 172 In one of these, each electrical interconnect 302 is structurally and electrically coupled to one of the through wafer interconnects 172. The electrical mutual Connection 302 can comprise a conductive material such as a metal or metal alloy (e.g., copper or a copper alloy). The electrical interconnects 302 can be formed using the methods previously described with respect to the through wafer interconnects 112 as described above with respect to FIG. 1B.

在該轉移材料層212中形成該些電性互連302後,便可以在該轉移材料層212相反於該些已處理半導體結構132A至132F之一面,選擇性地將一個或多個重分佈層(RDL)312形成於該轉移材料層212上方,以形成圖2B所示之鍵結半導體結構310。該重分佈層312可以包含多個導電部件314,該些導電部件配置在一介電材料316內並被該介電材料圍繞,該重分佈層312可以如前文中參照圖1C有關該重分佈層122之敘述而形成。該些導電部件314可以包含導電墊、橫向延伸之導電線或導電跡線,及縱向延伸之導電通孔其中一種或多種。此外,該重分佈層312可以包含一層一層依序覆蓋而形成之多層,其中每一層皆包含導電部件314及介電材料316。After the electrical interconnects 302 are formed in the transfer material layer 212, one or more redistribution layers can be selectively disposed on the transfer material layer 212 opposite one of the processed semiconductor structures 132A-132F. A (RDL) 312 is formed over the transfer material layer 212 to form the bonded semiconductor structure 310 shown in FIG. 2B. The redistribution layer 312 can include a plurality of conductive features 314 disposed within and surrounded by a dielectric material 316 that can be associated with the redistribution layer as previously described with reference to FIG. 1C. Formed by the description of 122. The conductive features 314 can include one or more of a conductive pad, laterally extending conductive or conductive traces, and longitudinally extending conductive vias. In addition, the redistribution layer 312 may comprise a plurality of layers formed by sequentially covering one layer, wherein each layer includes a conductive member 314 and a dielectric material 316.

參照圖2C,形成該重分佈層312之後,便可以在該轉移材料層212相反於該些已處理半導體結構132A至132F之一面,將至少一個已處理半導體結構322鍵結在該轉移材料層212上方,以形成圖2C之鍵結半導體結構320。舉例而言,該至少一個已處理半導體結構322可以直接鍵結至該重分佈層312,如圖2C所示。該已處理半導體結構322中一個或多個導電部件324,像是鍵結墊,可以在結構上及電性上與該重分佈層312中該些導電部件314,以及該轉移材料層212中該些電性互連302耦合。Referring to FIG. 2C, after the redistribution layer 312 is formed, at least one processed semiconductor structure 322 can be bonded to the transfer material layer 212 on the opposite side of the transfer material layer 212 opposite the processed semiconductor structures 132A-132F. Above, to form the bonded semiconductor structure 320 of FIG. 2C. For example, the at least one processed semiconductor structure 322 can be directly bonded to the redistribution layer 312, as shown in FIG. 2C. One or more conductive features 324 of the processed semiconductor structure 322, such as bond pads, may be structurally and electrically coupled to the conductive features 314 of the redistribution layer 312, and the transfer material layer 212. Electrical interconnects 302 are coupled.

作為非限制性之範例,該額外已處理半導體元件322可以包括一半 導體晶粒,亦可以包含電子信號處理器、記憶元件及光電元件(例如發光二極體、雷射、光電二極體、太陽能電池等等)其中一種或多種。As a non-limiting example, the additional processed semiconductor component 322 can include half The conductor die may also include one or more of an electronic signal processor, a memory component, and a photovoltaic component (eg, a light emitting diode, a laser, a photodiode, a solar cell, etc.).

該額外已處理半導體結構322可以直接鍵結至該重分佈層312之介電材料316或電性互連314,或直接鍵結至該重分佈層312之介電材料316及電性互連314。將該額外已處理半導體元件322鍵結至該介電材料316及/或該些電性互連314所用之直接鍵結製程,可以在大約400℃或更低之一個或多個溫度下實施。在一些實施例中,該鍵結製程可以包含在大約400℃或更低之一個或多個溫度下實施之一種熱壓直接鍵結製程或一種非熱壓直接鍵結製程。在其他實施例中,該鍵結製程可以包含在大約200℃或更低之一個或多個溫度下實施之一種超低溫直接鍵結製程。在一些例子中,該鍵結製程可以在大約為室溫之溫度下實施。此外,在一些實施例中,該鍵結製程可以包含一種表面輔助鍵結製程。該直接鍵結製程可以包含氧化物對氧化物(例如氧化矽對氧化矽)之直接鍵結製程,及/或金屬對金屬(例如銅對銅)之直接鍵結製程。The additional processed semiconductor structure 322 can be directly bonded to the dielectric material 316 or the electrical interconnect 314 of the redistribution layer 312, or directly to the dielectric material 316 and the electrical interconnect 314 of the redistribution layer 312. . The direct bonding process used to bond the additional processed semiconductor component 322 to the dielectric material 316 and/or the electrical interconnects 314 can be performed at one or more temperatures of about 400 ° C or less. In some embodiments, the bonding process can include a hot press direct bonding process or a non-hot press direct bonding process performed at one or more temperatures of about 400 ° C or less. In other embodiments, the bonding process can comprise an ultra-low temperature direct bonding process implemented at one or more temperatures of about 200 ° C or less. In some examples, the bonding process can be carried out at a temperature of about room temperature. Moreover, in some embodiments, the bonding process can include a surface assisted bonding process. The direct bonding process can include a direct bonding process of an oxide to oxide (eg, yttria to yttrium oxide), and/or a direct bonding process of a metal to metal (eg, copper to copper).

參照圖2D,將該額外已處理半導體結構322鍵結至圖2B之鍵結半導體結構310後,便可以將該第一底材結構120之較厚底材本體104移除,留下該較薄材料層102及穿透其中之該些穿透晶圓互連112鍵結至該重分佈層122及該些已處理半導體結構132A至132F。舉例而言,可以採取不會對該較厚底材本體104造成顯著或無法修復損壞之方式,將該較厚底材本體104從該較薄材料層102分離並回收。Referring to FIG. 2D, after the additional processed semiconductor structure 322 is bonded to the bonded semiconductor structure 310 of FIG. 2B, the thicker substrate body 104 of the first substrate structure 120 can be removed, leaving the thinner material. Layer 102 and the through-wafer interconnects 112 penetrating therethrough are bonded to the redistribution layer 122 and the processed semiconductor structures 132A-132F. For example, the thicker substrate body 104 can be separated and recovered from the thinner material layer 102 in a manner that does not cause significant or unrepairable damage to the thicker substrate body 104.

將該底材結構120之較厚底材本體104從該鍵結半導體結構320(圖2C)移除後,便可以將該較厚底材本體104回收及再利用。舉例而言, 在諸如下文所述之鍵結半導體結構形成方法中,該較厚底材本體104可以重複使用一次或多次。After the thicker substrate body 104 of the substrate structure 120 is removed from the bonded semiconductor structure 320 (FIG. 2C), the thicker substrate body 104 can be recovered and reused. For example, In a bonded semiconductor structure forming method such as described below, the thicker substrate body 104 can be reused one or more times.

在每一穿透晶圓互連112之曝露端上,可以選擇性地提供一導電凸塊332,以形成圖2D之鍵結半導體結構330。該些導電凸塊332可以包含一種導電金屬或金屬合金,諸如可迴流軟焊接之合金,且該些導電凸塊332可以使該鍵結半導體結構330中該些穿透晶圓互連112在結構上及電性上易於與另一結構之導電部件耦合,該另一結構可以為更高等級之一底材或元件,或包含更高等級之一底材或元件。On each exposed end of the through wafer interconnect 112, a conductive bump 332 can be selectively provided to form the bonded semiconductor structure 330 of FIG. 2D. The conductive bumps 332 may comprise a conductive metal or metal alloy, such as a reflow solderable alloy, and the conductive bumps 332 may cause the through-wafer interconnects 112 in the bonded semiconductor structure 330 to be in the structure. It is electrically and electrically apt to couple with a conductive member of another structure, which may be one of a higher grade substrate or component, or a higher grade one of the substrates or components.

例如,在圖2E中,圖2D之鍵結半導體結構330可以在結構上及電性上耦合至一結構342而形成圖2E所示之鍵結半導體結構340。舉例而言,該結構342可以包含另一已處理半導體結構或一印刷電路板。如圖2E所示,該結構342可以包含多個導電部件344及一圍繞介電材料346。舉例而言,該些導電部件344可以包含鍵結墊。該些導電凸塊332可以對準並緊靠該些導電部件344。該些導電凸塊332可以受熱,以造成該些導電凸塊332之材料回流,之後,該材料可予以冷卻並固化,從而形成該些穿透晶圓互連112與該結構342中該些導電部件344間之結構性及電性鍵結。For example, in FIG. 2E, the bonded semiconductor structure 330 of FIG. 2D can be structurally and electrically coupled to a structure 342 to form the bonded semiconductor structure 340 of FIG. 2E. For example, the structure 342 can include another processed semiconductor structure or a printed circuit board. As shown in FIG. 2E, the structure 342 can include a plurality of conductive features 344 and a surrounding dielectric material 346. For example, the conductive members 344 can include a bond pad. The conductive bumps 332 can be aligned and abutted against the conductive members 344. The conductive bumps 332 may be heated to cause the materials of the conductive bumps 332 to reflow. Thereafter, the material may be cooled and solidified to form the conductive vias 112 and the conductive portions of the structures 342. Structural and electrical bonding between components 344.

圖2E之鍵結半導體結構340可以視需要予以進一步處理,使之適合其預定用途。作為非限制性之一範例,可以在該鍵結半導體結構340之至少一部分上方提供一種保護性之塗層或包覆材料,及/或在該結構342與各個導電凸塊332間及四周之材料層102間,提供一種保護性之鍵結材料。The bonded semiconductor structure 340 of Figure 2E can be further processed as needed to suit its intended use. As a non-limiting example, a protective coating or cladding material may be provided over at least a portion of the bonded semiconductor structure 340, and/or materials between and around the structure 342 and each of the conductive bumps 332. Between layers 102, a protective bonding material is provided.

如前所述,在圖1K之鍵結半導體結構210之轉移材料層212中,除了可以形成電性互連外,還可以形成光學互連及流體互連。茲將可用於在圖1K之鍵結半導體結構210之轉移材料層212中形成一個或多個光學互連之方法之實施例範例,參照圖3A至3C及圖4A至4D敘述如下。As previously mentioned, in the transfer material layer 212 of the bonded semiconductor structure 210 of FIG. 1K, in addition to the formation of electrical interconnections, optical interconnections and fluid interconnections can be formed. An example of an embodiment of a method that can be used to form one or more optical interconnects in the transfer material layer 212 of the bonded semiconductor structure 210 of FIG. 1K is described below with reference to FIGS. 3A through 3C and FIGS. 4A through 4D.

如圖3A所示,一個或多個光學互連402可以形成於該轉移材料層212中。在一些實施例中,該些光學互連402可以包含一般直線垂直方向(亦即從圖3A之觀點而言為垂直)之管柱(例如圓筒),該些管柱具有之組成、尺寸及形狀,會使其表現為一種或多種波長之電磁輻射之波導。該些光學互連402可以包含本發明所屬技術領域稱為「光學通孔」(optical vias,OVs)或「矽導光學通孔」(through silicon optical vias,TSOVs)者。As shown in FIG. 3A, one or more optical interconnects 402 can be formed in the layer of transfer material 212. In some embodiments, the optical interconnects 402 can comprise columns (eg, cylinders) that are generally perpendicular to the vertical direction (ie, perpendicular from the perspective of FIG. 3A), the columns having the composition, dimensions, and The shape is such that it appears as a waveguide of electromagnetic radiation of one or more wavelengths. The optical interconnects 402 may comprise those known in the art as "optical vias" (OVs) or "through silicon optical vias" (TSOVs).

該些光學互連402之組成可以不同於該轉移材料層212之組成,這樣,跨越該些光學互連402與該轉移材料層212間之邊界便會有折射率之變化。換言之,該轉移材料層212可以包含一種展現一第一折射率之材料,該些光學互連402則可以包含一種展現不同之第二折射率之材料。作為非限制性之範例,在一些實施例中,該轉移材料層212可以包含矽,該些光學互連402則可以包含一種聚合物材料(例如一種聚原冰片烯聚合物材料)。The composition of the optical interconnects 402 can be different from the composition of the transfer material layer 212 such that there is a change in refractive index across the boundary between the optical interconnects 402 and the transfer material layer 212. In other words, the transfer material layer 212 can comprise a material exhibiting a first index of refraction, and the optical interconnects 402 can comprise a material exhibiting a different second index of refraction. As a non-limiting example, in some embodiments, the transfer material layer 212 can comprise germanium, and the optical interconnects 402 can comprise a polymeric material (eg, a polynorbornene polymer material).

形成像是該些光學互連402之各種製程已為本發明所屬技術領域所知,且可以為本發明之實施例所採用。茲將可用於在該轉移材料層212中製作此等光學互連402之方法之一範例,參照圖4A至4D敘述如下。 圖4A為該轉移材料層212之放大簡化圖。如圖中所示,可以形成多個孔隙404並使之穿透該轉移材料層212。為形成該些孔隙404,可以在該轉移材料層212之曝露主要表面406上提供具有圖案之一罩幕層。該有圖案罩幕層可以在欲形成穿過該轉移材料層212之該些孔隙404(及該些光學互連402)之位置處,包含穿透該有圖案罩幕層之孔隙。接著可以利用一種蝕刻製程(例如各向異性濕式化學蝕刻製程,或各向異性乾式反應離子蝕刻製程)蝕刻出穿透該轉移材料層212之該些孔隙404。Various processes for forming such optical interconnects 402 are known in the art to which the present invention pertains and may be employed in embodiments of the present invention. An example of a method that can be used to fabricate such optical interconnects 402 in the layer of transfer material 212 is described below with reference to Figures 4A through 4D. 4A is an enlarged, simplified view of the transfer material layer 212. As shown in the figures, a plurality of apertures 404 can be formed and penetrated through the layer of transfer material 212. To form the apertures 404, a mask layer having a pattern can be provided on the exposed major surface 406 of the layer of transfer material 212. The patterned mask layer can include apertures penetrating the patterned mask layer at locations where the apertures 404 (and the optical interconnects 402) are to be formed through the layer of transfer material 212. The apertures 404 that penetrate the layer of transfer material 212 can then be etched using an etch process (eg, an anisotropic wet chemical etch process, or an anisotropic dry reactive ion etch process).

若該轉移材料層212包含矽,則可以選擇性地將該些孔隙404中,該轉移材料層212之該些曝露表面408加以氧化,以在該些曝露表面408形成一層二氧化矽。在此組構中,該氧化物材料層可以作為圍繞該些光學互連402之一種光學被覆材料。If the transfer material layer 212 comprises germanium, the exposed surfaces 408 of the transfer material layer 212 may be selectively oxidized to form a layer of germanium dioxide on the exposed surfaces 408. In this configuration, the layer of oxide material can serve as an optical covering material surrounding the optical interconnects 402.

參照圖4B,形成該些孔隙404後,便可以將該有圖案罩幕層移除,並在該轉移材料層212之曝露主要表面406上及該些孔隙404內至少一部分,覆上一種聚合物前驅材料。例如,可以利用一旋轉塗佈製程,將一種液態聚合物前驅材料410塗敷在該轉移材料層212之曝露主要表面406上及該些孔隙404內至少一部分。該些孔隙404內之表面可以選擇性地以一種介電材料覆蓋住至少一部分,例如二氧化矽、另一種氧化物材料或一種氮化物材料。如圖4B所示,在一些實施例中,於初步之沉積製程後,該些孔隙404內可能僅局部有該聚合物前驅材料410填充。Referring to FIG. 4B, after forming the apertures 404, the patterned mask layer can be removed, and a polymer is coated on the exposed main surface 406 of the transfer material layer 212 and at least a portion of the apertures 404. Precursor material. For example, a liquid polymer precursor material 410 can be applied to the exposed major surface 406 of the layer of transfer material 212 and at least a portion of the apertures 404 using a spin coating process. The surfaces within the apertures 404 may optionally be covered with at least a portion of a dielectric material, such as cerium oxide, another oxide material, or a nitride material. As shown in FIG. 4B, in some embodiments, the polymer precursor material 410 may only be partially filled within the pores 404 after the preliminary deposition process.

參照圖4C,可以利用諸如加壓氣體之方式,在該沉積液態聚合物前驅材料410上方施加一壓力,造成該聚合物前驅材料410至少實質上填滿該些孔隙404,之後,可以使該聚合物前驅材料410發生聚合反應, 以形成配置在該些孔隙404內之一固態聚合物材料412。在一些方法中,該材料410可以進入並填滿該些孔隙404而無需任何施加壓力之協助。Referring to FIG. 4C, a pressure may be applied over the deposited liquid polymer precursor material 410 by means such as a pressurized gas, causing the polymer precursor material 410 to at least substantially fill the pores 404, after which the polymerization may be made. The precursor material 410 is polymerized, To form a solid polymer material 412 disposed within the apertures 404. In some methods, the material 410 can enter and fill the apertures 404 without the aid of any applied pressure.

將該固態聚合物材料412提供於該些孔隙404內後,便可以如圖4C所示,將多餘之固態聚合物材料412配置在該轉移材料層212之主要表面406上方。如圖4D所示,該主要表面406上方之多餘固態聚合物材料412可以利用,舉例而言,一種化學蝕刻製程、一種機械研磨製程,及/或一種化學機械研磨(CMP)製程加以移除。該多餘固態聚合物材料412之移除將定義出並形成該些光學互連402,其包含該些孔隙404內之聚合物材料412餘下部分。After the solid polymer material 412 is provided in the apertures 404, excess solid polymer material 412 can be disposed over the major surface 406 of the layer of transfer material 212 as shown in FIG. 4C. As shown in FIG. 4D, excess solid polymer material 412 over the major surface 406 can be removed using, for example, a chemical etching process, a mechanical polishing process, and/or a chemical mechanical polishing (CMP) process. Removal of the excess solid polymer material 412 will define and form the optical interconnects 402 that include the remainder of the polymeric material 412 within the voids 404.

再次參照圖3A,各光學互連402可以分別對準,並在光學上耦合至其下方已處理半導體結構132A至132F內一波導或其他光學元件或結構(例如雷射、發光二極體、光電二極體等等)。Referring again to FIG. 3A, each optical interconnect 402 can be individually aligned and optically coupled to a waveguide or other optical component or structure within the processed semiconductor structures 132A-132F (eg, laser, light emitting diode, optoelectronics). Diode, etc.).

參照圖3B,在該轉移材料層212中形成該些光學互連402之後,便可以在該轉移材料層212相反於該些已處理半導體結構132A至132F之一面,將至少一個已處理半導體結構422鍵結至該轉移材料層212上方,以形成圖3B之鍵結半導體結構420。作為非限制性之範例,該額外已處理半導體元件422可以包含一半導體晶粒,亦可以包含一個或多個光電元件424(例如發光二極體、雷射、光電二極體、太陽能電池等等),其被組構為接收並/或發出電磁輻射。如圖3B所示,該已處理半導體元件422亦可以包含一個或多個波導426,其可以包含橫向延伸區段及/或縱向延伸區段(從圖3B之觀點而言)。該些波導426可以在操作上(亦即 在光學上)與該些光電元件424耦合,以使電磁輻射經由該些波導426在該些光電元件424間傳遞。該些波導426亦可以在操作上與該轉移材料層212中該些光學互連402耦合,並可以耦合至該鍵結半導體結構420內其他主動元件結構(或耦合至一光學輸出部分,以耦合至該鍵結半導體結構420外之另一光學主動元件)。Referring to FIG. 3B, after the optical interconnects 402 are formed in the transfer material layer 212, at least one processed semiconductor structure 422 can be disposed on the transfer material layer 212 opposite to one of the processed semiconductor structures 132A-132F. Bonded over the layer of transfer material 212 to form the bonded semiconductor structure 420 of FIG. 3B. As a non-limiting example, the additional processed semiconductor component 422 can include a semiconductor die, and can also include one or more photovoltaic components 424 (eg, light emitting diodes, lasers, photodiodes, solar cells, etc.) ), which is configured to receive and/or emit electromagnetic radiation. As shown in FIG. 3B, the processed semiconductor component 422 can also include one or more waveguides 426, which can include laterally extending sections and/or longitudinally extending sections (from the perspective of FIG. 3B). The waveguides 426 can be operationally (ie, Optoelectronically coupled to the optoelectronic components 424, electromagnetic radiation is transmitted between the optoelectronic components 424 via the waveguides 426. The waveguides 426 can also be operatively coupled to the optical interconnects 402 in the layer of transfer material 212 and can be coupled to other active device structures within the bonded semiconductor structure 420 (or to an optical output portion for coupling) To the other optical active component outside the bonded semiconductor structure 420).

該額外已處理半導體結構422可以直接鍵結至該轉移材料層212。將該額外已處理半導體元件422鍵結至該轉移材料層212所用之直接鍵結製程可以在大約400℃或更低之一個或多個溫度下實施。在一些實施例中,該鍵結製程可以包含在大約400℃或更低之一個或多個溫度下實施之一種熱壓直接鍵結製程或一種非熱壓直接鍵結製程。在其他實施例中,該鍵結製程可以包含在大約200℃或更低之一個或多個溫度下實施之一種超低溫直接鍵結製程。在一些例子中,該鍵結製程可以在大約為室溫之溫度下實施。此外,在一些實施例中,該鍵結製程可以包含一種表面輔助鍵結製程。該直接鍵結製程可以包含氧化物對氧化物(例如氧化矽對氧化矽)之直接鍵結製程,及/或金屬對金屬(例如銅對銅)之直接鍵結製程。The additional processed semiconductor structure 422 can be bonded directly to the transfer material layer 212. The direct bonding process used to bond the additional processed semiconductor component 422 to the transfer material layer 212 can be performed at one or more temperatures of about 400 ° C or less. In some embodiments, the bonding process can include a hot press direct bonding process or a non-hot press direct bonding process performed at one or more temperatures of about 400 ° C or less. In other embodiments, the bonding process can comprise an ultra-low temperature direct bonding process implemented at one or more temperatures of about 200 ° C or less. In some examples, the bonding process can be carried out at a temperature of about room temperature. Moreover, in some embodiments, the bonding process can include a surface assisted bonding process. The direct bonding process can include a direct bonding process of an oxide to oxide (eg, yttria to yttrium oxide), and/or a direct bonding process of a metal to metal (eg, copper to copper).

參照圖3C,將該額外已處理半導體結構422鍵結至圖3B之鍵結半導體結構400,以形成該鍵結半導體結構420之後,便可以如前文參照圖2D及2E所述,使該鍵結半導體結構420受到進一步處理,以形成圖3C所示之鍵結半導體結構430。舉例而言,可以將該第一底材結構120之較厚底材本體104移除(並可選擇性地將其回收及再利用),並在每個 穿透晶圓互連112之曝露端上提供一導電凸塊432,由此而產生之結構可以在結構上及電性上耦合至另一結構434,以形成圖3C所示之鍵結半導體結構430。舉例而言,該結構434可以包含另一個已處理半導體結構或一印刷電路板。如圖3C所示,該結構434可以包含多個導電部件436(例如鍵結墊)及一圍繞介電材料438。該些導電凸塊432可以對準、緊靠並鍵結至該些導電部件436,從而形成該些穿透晶圓互連112與該結構434之導電部件436間之結構性及電性鍵結。Referring to FIG. 3C, after the additional processed semiconductor structure 422 is bonded to the bonded semiconductor structure 400 of FIG. 3B to form the bonded semiconductor structure 420, the bonding can be performed as described above with reference to FIGS. 2D and 2E. The semiconductor structure 420 is further processed to form the bonded semiconductor structure 430 shown in FIG. 3C. For example, the thicker substrate body 104 of the first substrate structure 120 can be removed (and optionally recycled and reused) and A conductive bump 432 is provided on the exposed end of the through wafer interconnect 112, and the resulting structure can be structurally and electrically coupled to the other structure 434 to form the bonded semiconductor structure shown in FIG. 3C. 430. For example, the structure 434 can include another processed semiconductor structure or a printed circuit board. As shown in FIG. 3C, the structure 434 can include a plurality of conductive features 436 (eg, bond pads) and a surrounding dielectric material 438. The conductive bumps 432 can be aligned, abutted, and bonded to the conductive features 436 to form structural and electrical bonds between the through wafer interconnects 112 and the conductive features 436 of the structures 434. .

圖3C之鍵結半導體結構430可以視需要予以進一步處理,使之適合其預定用途。作為非限制性之一範例,可以在該鍵結半導體結構430中至少一部分上方提供一種保護性之塗層或包覆材料,及/或在該結構434與各個導電凸塊432間及四周之材料層102間,提供一種保護性鍵結材料。The bonded semiconductor structure 430 of Figure 3C can be further processed as needed to suit its intended use. As a non-limiting example, a protective coating or cladding material may be provided over at least a portion of the bonded semiconductor structure 430, and/or materials between and around the structure 434 and each of the conductive bumps 432. Between layers 102, a protective bonding material is provided.

茲將可用於在圖1K之鍵結半導體結構210之轉移材料層212中形成一個或多個流體互連之方法之實施例範例,參照圖5A至5E敘述如下。An example of an embodiment of a method that can be used to form one or more fluid interconnects in the transfer material layer 212 of the bonded semiconductor structure 210 of FIG. 1K is described below with reference to Figures 5A through 5E.

待形成之該些流體互連可以為一流體迴路之部分,一流體可以透過該流體迴路流動,以達到在操作期間使該鍵結半導體結構內該些已處理半導體結構冷卻之目的。The fluid interconnects to be formed may be part of a fluid circuit through which a fluid may flow to cool the processed semiconductor structures within the bonded semiconductor structure during operation.

如圖5A所示,可以在該轉移材料層212中形成(例如至少局部穿過)一個或多個凹槽(例如溝槽)502,以形成圖5A所示之鍵結半導體結構500。舉例而言,如圖5A及5B所示,可以在該轉移材料層212中形成單一個凹槽502,並使其至少局部穿過該轉移材料層212,該凹槽 502具有來回彎曲橫越該轉移材料層212之一盤繞形狀。但在本發明其他實施例中,該一個或多個凹槽502可以具有任何其他形狀。As shown in FIG. 5A, one or more recesses (eg, trenches) 502 may be formed (eg, at least partially) through the transfer material layer 212 to form the bonded semiconductor structure 500 illustrated in FIG. 5A. For example, as shown in FIGS. 5A and 5B, a single groove 502 may be formed in the transfer material layer 212 and passed at least partially through the transfer material layer 212. 502 has a coiled shape that traverses across the layer of transfer material 212. However, in other embodiments of the invention, the one or more grooves 502 can have any other shape.

可以用於形成此種凹槽502之各種製程已為本發明所屬技術領域所知,且可以為本發明之實施例所採用。作為非限制性之一範例,可以在該轉移材料層212之曝露主要表面上提供帶有圖案之一遮罩層。該圖案遮罩層可以包含一個或多個孔隙,該些孔隙在該轉移材料層212中欲形成該一個或多個凹槽502之位置處穿透該圖案遮罩層。接著可以利用一種蝕刻製程(例如各向異性濕式化學蝕刻製程,或各向異性乾式反應離子蝕刻製程)在該轉移材料層212中蝕刻出該一個或多個凹槽502。形成該一個或多個凹槽502後,便可以將該圖案遮罩層移除。Various processes that can be used to form such grooves 502 are known in the art to which the present invention pertains and can be employed in embodiments of the present invention. As a non-limiting example, one of the patterned mask layers may be provided on the exposed major surface of the transfer material layer 212. The patterned mask layer can include one or more apertures that penetrate the patterned mask layer at locations where the one or more recesses 502 are to be formed in the layer of transfer material 212. The one or more recesses 502 can then be etched into the layer of transfer material 212 using an etch process (eg, an anisotropic wet chemical etch process, or an anisotropic dry reactive ion etch process). Once the one or more recesses 502 are formed, the patterned mask layer can be removed.

參照圖5C,在一些實施例中,可以提供一層保護材料512,使之在該些凹槽502內至少覆蓋住該轉移材料層212之該些曝露表面。在一些實施例中,該層保護材料512亦可以提供於該些凹槽502外之該轉移材料層212之主要表面214上,如圖5C所示。Referring to FIG. 5C, in some embodiments, a layer of protective material 512 may be provided to cover at least the exposed surfaces of the layer of transfer material 212 within the recesses 502. In some embodiments, the layer of protective material 512 may also be provided on the major surface 214 of the layer of transfer material 212 outside the recesses 502, as shown in FIG. 5C.

該層保護材料512可以用於保護該些凹槽502內該轉移材料層212之該些曝露表面,使其不因流過將由該些凹槽502所形成之該些流體互連之流體而受損。舉例而言,在該轉移材料層212包含矽或鍺之實施例中,該層保護材料512可以分別包含氧化矽或氧化鍺。此種氧化物材料可以經由使該轉移材料層212之表面氧化(例如使用一低溫氧化製程)而形成,或以諸如低溫化學氣相沉積(CVD)製程沉積一種氧化物材料而形成。The layer of protective material 512 can be used to protect the exposed surfaces of the layer of transfer material 212 within the recesses 502 from being exposed to fluids interconnecting the fluids formed by the recesses 502. damage. For example, in embodiments where the transfer material layer 212 comprises tantalum or niobium, the layer of protective material 512 can comprise tantalum oxide or tantalum oxide, respectively. Such an oxide material may be formed by oxidizing the surface of the transfer material layer 212 (for example, using a low temperature oxidation process) or by depositing an oxide material such as a low temperature chemical vapor deposition (CVD) process.

參照圖5D,在該轉移材料層212中形成該些凹槽502後,便可以將另一材料層522提供於該轉移材料層212上方,使之覆蓋並封住該些凹槽502,以形成圖5D所示之鍵結半導體結構520。經由覆蓋並封住該些凹槽502可以定義出一個或多個流體互連504(亦即流體通道),其在該轉移材料層212與該材料層522間之界面穿過該鍵結半導體結構520。Referring to FIG. 5D, after the recesses 502 are formed in the transfer material layer 212, another material layer 522 may be provided over the transfer material layer 212 to cover and seal the recesses 502 to form The bonded semiconductor structure 520 shown in FIG. 5D. One or more fluid interconnects 504 (ie, fluid channels) may be defined by covering and enclosing the recesses 502, passing through the bonded semiconductor structure at an interface between the transfer material layer 212 and the material layer 522. 520.

該材料層522可以包含一底材結構之至少一部分,在一些實施例中,該材料層522亦可以包含一晶圓級底材結構之至少一部分。該材料層522可以包含,舉例而言,前文有關圖1I之額外底材結構190敘述中所提及之任何材料。在一些實施例中,該材料層522可以具有與該轉移材料層212相同之組成。The material layer 522 can comprise at least a portion of a substrate structure. In some embodiments, the material layer 522 can also comprise at least a portion of a wafer level substrate structure. The material layer 522 can comprise, for example, any of the materials mentioned above in relation to the additional substrate structure 190 of FIG. In some embodiments, the material layer 522 can have the same composition as the transfer material layer 212.

作為非限制性之一範例,可以利用一種SMARTCUT®製程將該材料層522提供於該轉移材料層212上方,如前文參照圖1I及1J所述。舉例而言,可以將多個離子(例如氫離子、氦離子或惰性氣體離子其中一種或多種)沿著一離子植入平面植入一額外底材結構(未顯示),接著將該額外底材結構鍵結至該轉移材料層212,之後,使該額外底材結構沿著該離子植入平面斷裂,以移除該底材結構之一部分,而留下該材料層522鍵結至該轉移材料層212。As a non-limiting example, the material layer 522 can be provided over the transfer material layer 212 using a SMARTCUT® process, as previously described with reference to Figures 1I and 1J. For example, a plurality of ions (eg, one or more of hydrogen ions, helium ions, or inert gas ions) can be implanted along an ion implantation plane into an additional substrate structure (not shown), followed by the additional substrate The structure is bonded to the transfer material layer 212, after which the additional substrate structure is broken along the ion implantation plane to remove a portion of the substrate structure leaving the material layer 522 bonded to the transfer material Layer 212.

該材料層522可以直接鍵結至該轉移材料層212。將該材料層522鍵結至該轉移材料層212所用之直接鍵結製程可以在大約400℃或更低之一個或多個溫度下實施。在一些實施例中,該鍵結製程可以包含在大 約400℃或更低之一個或多個溫度下實施之一種熱壓直接鍵結製程。在其他實施例中,該鍵結製程可以包含在大約200℃或更低之一個或多個溫度下實施之一種超低溫直接鍵結製程。在一些例子中,該鍵結製程可以在大約為室溫之溫度下實施。此外,在一些實施例中,該鍵結製程可以包含一種表面輔助鍵結製程。該直接鍵結製程可以包含氧化物對氧化物(例如氧化矽對氧化矽)之直接鍵結製程,及/或金屬對金屬(例如銅對銅)之直接鍵結製程。The material layer 522 can be bonded directly to the transfer material layer 212. The direct bonding process used to bond the layer of material 522 to the layer of transfer material 212 can be carried out at one or more temperatures of about 400 ° C or less. In some embodiments, the bonding process can be included in a large A hot press direct bonding process performed at one or more temperatures of about 400 ° C or less. In other embodiments, the bonding process can comprise an ultra-low temperature direct bonding process implemented at one or more temperatures of about 200 ° C or less. In some examples, the bonding process can be carried out at a temperature of about room temperature. Moreover, in some embodiments, the bonding process can include a surface assisted bonding process. The direct bonding process can include a direct bonding process of an oxide to oxide (eg, yttria to yttrium oxide), and/or a direct bonding process of a metal to metal (eg, copper to copper).

在一些實施例中,可以將一鍵結層524形成或以其他方式提供在待鍵結至該轉移介電材料212之材料層522之表面上。舉例而言,在該層保護材料512亦包含一氧化物層之實施例中,該鍵結層524可以包含一氧化物層(例如二氧化矽)。使該鍵結層524及該層保護材料512之組成相匹配,亦可以使該材料層522在一直接鍵結製程(例如氧化物對氧化物之直接鍵結製程)中易於鍵結至該轉移介電材料212。In some embodiments, a bonding layer 524 can be formed or otherwise provided on the surface of the material layer 522 to be bonded to the transfer dielectric material 212. For example, in embodiments where the layer of protective material 512 also includes an oxide layer, the bonding layer 524 can comprise an oxide layer (eg, hafnium oxide). Matching the bonding layer 524 and the composition of the layer of protective material 512 may also facilitate bonding of the material layer 522 to the transfer in a direct bonding process (eg, an oxide-to-oxide direct bonding process). Dielectric material 212.

將該轉移材料層212中該些凹槽502以該材料層522覆蓋並封住而形成該些流體互連504後,便可以形成一個或多個接入開孔532A、532B,使之穿透該材料層522並延伸至該轉移材料層212中之流體互連504,如圖5E之鍵結半導體結構530中所示。舉例而言,可以利用前文所述之一種遮罩及蝕刻製程,在該鍵結半導體結構530內形成穿透該材料層522並延伸至該流體互連504之該些接入開孔532A、532B。例如,一第一接入開孔532A可以通向一流體互連504之第一端,一第二接入開孔532B可以通向該流體互連504之相反第二端。在此組構中,該第 一接入開孔532A可以提供進入該流體互連504之一流體入口,該第二接入開孔532B則可以提供離開該流體互連504之一流體出口。接著,可以將一第一流體管道534A耦合至該第一接入開孔532A,及將一第二流體管道534B耦合至該第二接入開孔532B,如圖5E所示。After the recesses 502 in the layer of transfer material 212 are covered with the material layer 522 and sealed to form the fluid interconnects 504, one or more access openings 532A, 532B may be formed to penetrate The material layer 522 extends to the fluid interconnect 504 in the transfer material layer 212, as shown in the bonded semiconductor structure 530 of FIG. 5E. For example, the access openings 532A, 532B that penetrate the material layer 522 and extend to the fluid interconnect 504 may be formed in the bonded semiconductor structure 530 using a masking and etching process as described above. . For example, a first access opening 532A can lead to a first end of a fluid interconnect 504, and a second access opening 532B can lead to an opposite second end of the fluid interconnect 504. In this fabric, the first An access opening 532A can provide access to one of the fluid interconnects 504, and the second access opening 532B can provide a fluid outlet away from the fluid interconnect 504. Next, a first fluid conduit 534A can be coupled to the first access opening 532A and a second fluid conduit 534B can be coupled to the second access opening 532B, as shown in FIG. 5E.

在此組構中,於該鍵結半導體結構530內該些已處理半導體結構132A至132F之操作及使用期間,便可以使流體(例如一冷卻流體)流過該第一流體管道534A及該第一接入開孔532A而進入該流體互連504,流過該流體互連504,然後經由該第二接入開孔532B及該第二流體管道534B流出該流體互連504,如該些流體管道534A、534B內之方向箭頭所呈現。這樣,一個或多個流體互連504便可以在該轉移材料層212中形成。In this configuration, during operation and use of the processed semiconductor structures 132A-132F in the bonded semiconductor structure 530, a fluid (eg, a cooling fluid) can flow through the first fluid conduit 534A and the first An access opening 532A enters the fluid interconnect 504, flows through the fluid interconnect 504, and then flows out of the fluid interconnect 504 via the second access opening 532B and the second fluid conduit 534B, such as the fluid The directional arrows in the conduits 534A, 534B are presented. As such, one or more fluid interconnects 504 can be formed in the layer of transfer material 212.

形成圖5E之鍵結半導體結構530後,便可以使該鍵結半導體結構530受到進一步處理,如前文中參照圖2C至2E關於該鍵結半導體結構320所述,以及如前文中參照圖3B及3C關於該鍵結半導體結構420所述。After forming the bonded semiconductor structure 530 of FIG. 5E, the bonded semiconductor structure 530 can be further processed, as described above with respect to the bonded semiconductor structure 320 with reference to FIGS. 2C through 2E, and as previously described with reference to FIG. 3B and 3C is described with respect to the bonded semiconductor structure 420.

如上文所討論,本發明之實施例讓跨層(inter-strata)之電性、光學及微流體互連得以製作於在三度空間上集積之鍵結半導體結構中,該些鍵結半導體結構包含多層,每層皆包含一個或多個已處理半導體結構。在上述該些實施例中,每一跨層互連層僅包含單一類型之互連(亦即電性互連、光學互連及流體互連其中之一)。在本發明之其他實施例中,該些跨層互連層的其中一個或多個,可以包含二或三種不同類型之互連(例 如電性及光學互連、電性及流體互連、光學及流體互連,或電性、光學及流體互連)。此等互連層可以利用上文所述之方法製作,將該轉移材料層212上欲包含某一類互連之區域以遮罩覆蓋並保護,並在該轉移材料層212上未覆蓋遮罩之不同區域製作另一類互連。然後移除該遮罩,將另一遮罩覆蓋在之前製作之互連上,並在該轉移材料層212上未覆蓋遮罩之不同區域製作另一類互連。As discussed above, embodiments of the present invention enable inter-strataelectric, optical, and microfluidic interconnects to be fabricated in bonded semiconductor structures that are stacked in a three-dimensional space, the bonded semiconductor structures Multiple layers are included, each layer containing one or more processed semiconductor structures. In these embodiments described above, each cross-layer interconnect layer contains only a single type of interconnect (i.e., one of an electrical interconnect, an optical interconnect, and a fluid interconnect). In other embodiments of the present invention, one or more of the cross-layer interconnect layers may include two or three different types of interconnections (eg, Such as electrical and optical interconnects, electrical and fluid interconnects, optical and fluid interconnects, or electrical, optical, and fluid interconnects. The interconnect layers can be formed by the method described above, the regions of the transfer material layer 212 that are intended to contain a certain type of interconnect are covered and protected by a mask, and the mask layer is not covered on the transfer material layer 212. Another type of interconnection is made in different regions. The mask is then removed, another mask is overlaid on the previously fabricated interconnect, and another type of interconnect is made on the transfer material layer 212 that does not cover the different regions of the mask.

圖6為一鍵結半導體結構600之簡化局部剖面透視圖,該鍵結半導體結構包含兩個跨層互連層602A及602B,該些互連層可以如前文所述,依照本發明方法之實施例製作。6 is a simplified partial cross-sectional perspective view of a bonded semiconductor structure 600 comprising two inter-layer interconnect layers 602A and 602B, which may be implemented as described above in accordance with the method of the present invention Example production.

該鍵結半導體結構600包含一第一層604A之已處理半導體結構132A至132F、一第二層604B之已處理半導體結構132G至132L,以及一第三層604C之已處理半導體結構132M至132R。該些已處理半導體結構132A至132R可以包含,舉例而言,半導體晶粒,亦可以包含電子信號處理器、記憶元件及光電元件(例如發光二極體、雷射、光電二極體、太陽能電池等等)其中一種或多種。在該些層604A至604C中,該些已處理半導體結構132A至132R中的某些已處理半導體結構可以在縱向上彼此堆疊,亦可以在操作上彼此耦合。The bonded semiconductor structure 600 includes a processed semiconductor structure 132A-132F of a first layer 604A, processed semiconductor structures 132G-132L of a second layer 604B, and processed semiconductor structures 132M-132R of a third layer 604C. The processed semiconductor structures 132A to 132R may comprise, for example, semiconductor dies, and may also include an electronic signal processor, a memory element, and a photovoltaic element (eg, a light emitting diode, a laser, a photodiode, a solar cell). Etc.) One or more of them. In the layers 604A-604C, some of the processed semiconductor structures 132A-132R may be stacked one on another in the longitudinal direction or may be operatively coupled to each other.

該些互連層602A及602B中的每一層皆可以包含如上文所述之一轉移材料層212。如圖6所示,該些互連層602A及602B中的每一層皆包含至少一個電性互連302、至少一個光學互連402,及至少一個流體互連504。在一些實施例中,該些電性互連302、光學互連402及流體互連504 中的一個或多個,可以在操作上與該些已處理半導體結構132A至132R中的一個或多個耦合。Each of the interconnect layers 602A and 602B can comprise a transfer material layer 212 as described above. As shown in FIG. 6, each of the interconnect layers 602A and 602B includes at least one electrical interconnect 302, at least one optical interconnect 402, and at least one fluid interconnect 504. In some embodiments, the electrical interconnects 302, optical interconnects 402, and fluid interconnects 504 One or more of the ones may be operatively coupled to one or more of the processed semiconductor structures 132A-132R.

該鍵結半導體結構600亦包含如前文所述之一底材結構120,而該第一層604A之已處理半導體結構132A至132F則鍵結在該底材結構120上方。如前文所討論,該底材結構120可以在相對較厚之一底材本體104上包含相對較薄之一材料層102,且有多個穿透晶圓互連112形成並穿透該材料層102。而且,一重分佈層122可以如前文所述提供於該材料層102上方。如圖6所示,在一些實施例中,至少一個光學互連402及/或至少一個微流體互連504亦可以形成於該較薄材料層102中。The bonded semiconductor structure 600 also includes a substrate structure 120 as previously described, and the processed semiconductor structures 132A-132F of the first layer 604A are bonded over the substrate structure 120. As discussed above, the substrate structure 120 can include a relatively thin layer of material 102 on a relatively thick substrate body 104 with a plurality of through wafer interconnects 112 formed and penetrating the layer of material. 102. Moreover, a redistribution layer 122 can be provided over the material layer 102 as previously described. As shown in FIG. 6, in some embodiments, at least one optical interconnect 402 and/or at least one microfluidic interconnect 504 can also be formed in the thinner material layer 102.

此外,如圖6所示,該些互連層602A及602B中的每一層皆可以包含一重分佈層122,其可以用於重新分佈該些電性互連302、光學互連402及流體互連504。In addition, as shown in FIG. 6, each of the interconnect layers 602A and 602B can include a redistribution layer 122 that can be used to redistribute the electrical interconnects 302, optical interconnects 402, and fluid interconnects. 504.

上文所述該些製程可以重複任何次數,以在互連層之間形成任何所需數目之已處理半導體結構層。The processes described above can be repeated any number of times to form any desired number of processed semiconductor structure layers between the interconnect layers.

形成圖6所示之鍵結半導體結構600後,便可以使該鍵結半導體結構600受到進一步處理,如前文中參照圖2C至2E關於該鍵結半導體結構320所述,以及如前文中參照圖3B及3C關於該鍵結半導體結構420所述。After forming the bonded semiconductor structure 600 shown in FIG. 6, the bonded semiconductor structure 600 can be further processed, as described above with respect to the bonded semiconductor structure 320 with reference to FIGS. 2C through 2E, and as previously described with reference to FIG. 3B and 3C are described with respect to the bonded semiconductor structure 420.

在圖6之鍵結半導體結構600中,每一互連層皆包含電性互連、光學互連及流體互連。在其他實施例中,每一互連層可以只包含單一類型之互連,或只包含兩個類型之互連。In the bonded semiconductor structure 600 of FIG. 6, each interconnect layer includes electrical interconnects, optical interconnects, and fluid interconnects. In other embodiments, each interconnect layer may comprise only a single type of interconnect, or only two types of interconnects.

舉例而言,圖7呈現一鍵結半導體結構700,其與圖6之鍵結半導體結構600類似,且包含一第一層604A之已處理半導體結構132A至132F、一第二層604B之已處理半導體結構132G至132L,以及一第三層604C之已處理半導體結構132M至132R。一第一跨層互連層702A配置在該第一層604A之已處理半導體結構132A至132F與該第二層604B之已處理半導體結構132G至132L間,一第二跨層互連層702B則配置在該第二層604B之已處理半導體結構132G至132L與該第三層604C之已處理半導體結構132M至132R間。For example, FIG. 7 presents a bonded semiconductor structure 700 that is similar to the bonded semiconductor structure 600 of FIG. 6 and that has processed a processed semiconductor structure 132A-132F, a second layer 604B of a first layer 604A. Semiconductor structures 132G through 132L, and processed semiconductor structures 132M through 132R of a third layer 604C. A first cross-layer interconnect layer 702A is disposed between the processed semiconductor structures 132A-132F of the first layer 604A and the processed semiconductor structures 132G-132L of the second layer 604B, and a second cross-layer interconnect layer 702B is disposed. Disposed between the processed semiconductor structures 132G-132L of the second layer 604B and the processed semiconductor structures 132M-132R of the third layer 604C.

該些互連層702A及702B中的每一層皆可以包含如上文所述之一轉移材料層212。如圖7所示,該些互連層702A及702B中的每一層皆包含至少一個電性互連302。該第一互連層702A亦包含流體互連504,但不包含任何光學互連402。該第二互連層702B包含光學互連402,但不包含任何流體互連504。舉例而言,當實施例中該些已處理半導體結構132A至132L其中一個或多個包含一高功率半導體元件(例如電子信號處理器)時,以及當實施例中該些已處理半導體結構132M至132R其中一個或多個包含一個或多個光學元件(例如雷射、發光二極體或光電二極體)時,便可能適合此種配置。Each of the interconnect layers 702A and 702B can comprise a transfer material layer 212 as described above. As shown in FIG. 7, each of the interconnect layers 702A and 702B includes at least one electrical interconnect 302. The first interconnect layer 702A also includes a fluid interconnect 504, but does not include any optical interconnects 402. The second interconnect layer 702B includes an optical interconnect 402 but does not include any fluid interconnects 504. For example, when one or more of the processed semiconductor structures 132A-132L in the embodiment comprise a high power semiconductor component (eg, an electronic signal processor), and in the embodiment, the processed semiconductor structures 132M are One or more of the 132Rs may be suitable for this configuration when one or more optical components (such as lasers, light-emitting diodes, or photodiodes) are included.

該鍵結半導體結構700亦包含如前文所述之一底材結構120,而該第一層604A之已處理半導體結構132A至132F則鍵結在該底材結構120上方。如前文所討論,該底材結構120可以在相對較厚之一底材本體104上包含相對較薄之一材料層102,且有多個穿透晶圓互連112形成並穿 透該材料層102。而且,一重分佈層122可以如前文所述提供於該材料層102上方。雖然未顯示於圖7,但在一些實施例中,至少一個光學互連402及/或至少一個微流體互連504也可以形成於該較薄材料層102中。The bonded semiconductor structure 700 also includes a substrate structure 120 as previously described, and the processed semiconductor structures 132A-132F of the first layer 604A are bonded over the substrate structure 120. As discussed above, the substrate structure 120 can comprise a relatively thin layer of material 102 on a relatively thick substrate body 104, and a plurality of through wafer interconnects 112 are formed and worn. The material layer 102 is penetrated. Moreover, a redistribution layer 122 can be provided over the material layer 102 as previously described. Although not shown in FIG. 7, in some embodiments, at least one optical interconnect 402 and/or at least one microfluidic interconnect 504 can also be formed in the thinner material layer 102.

此外,如圖7所示,該些互連層702A及702B中的每一層亦可以包含一重分佈層122,其可以用於重新分佈該些電性互連302、光學互連402及流體互連504。In addition, as shown in FIG. 7, each of the interconnect layers 702A and 702B may also include a redistribution layer 122 that may be used to redistribute the electrical interconnects 302, optical interconnects 402, and fluid interconnects. 504.

形成圖7所示之鍵結半導體結構700後,便可以使該鍵結半導體結構700受到進一步處理,如前文中參照圖2C至2E關於該鍵結半導體結構320所述,以及如前文中參照圖3B及3C關於該鍵結半導體結構420所述。After forming the bonded semiconductor structure 700 shown in FIG. 7, the bonded semiconductor structure 700 can be further processed, as described above with respect to the bonded semiconductor structure 320 with reference to FIGS. 2C through 2E, and as previously described with reference to FIG. 3B and 3C are described with respect to the bonded semiconductor structure 420.

茲將本發明其他非限制性質之示範性實施例敘述如下。Exemplary embodiments of other non-limiting properties of the invention are described below.

實施例1:一種形成鍵結半導體結構之方法,其包括:提供一底材結構,其在相對較厚之一底材本體上包含相對較薄之一材料層;形成多個穿透晶圓互連,使之穿透該第一底材結構之較薄材料層;在該第一底材結構之較薄材料層相反於該較厚底材本體之一面,將一第一已處理半導體結構鍵結在該較薄材料層上方,並將該第一已處理半導體結構中至少一個導電部件在電性上與該些穿透晶圓互連中至少一個穿透晶圓互連耦合;在該第一已處理半導體結構相反於該第一底材結構之一面,將一轉移材料層提供於該第一已處理半導體結構上方;在該轉移材料層中形成電性互連、光學互連及流體互連其中至少一種;在該轉移材料層相反於該第一已處理半導體結構之一面,將一第二已處理半導體結構提供於 該轉移材料層上方;移除該底材結構之較厚底材本體,留下該底材結構之較薄材料層鍵結至該第一已處理半導體結構;以及將該些穿透晶圓互連中至少一個穿透晶圓互連在電性上耦合至另一結構之一導電部件。Embodiment 1 : A method of forming a bonded semiconductor structure, comprising: providing a substrate structure comprising a relatively thin layer of material on a relatively thick substrate body; forming a plurality of through wafers Connecting the thinner material layer of the first substrate structure; bonding a first processed semiconductor structure to a thinner material layer of the first substrate structure opposite to one side of the thicker substrate body Above the thinner material layer, and electrically coupling at least one of the first processed semiconductor structures to at least one of the through wafer interconnects; The processed semiconductor structure is opposite to one side of the first substrate structure, a layer of transfer material is provided over the first processed semiconductor structure; electrical interconnects, optical interconnects, and fluid interconnects are formed in the layer of transfer material At least one of the same; a second processed semiconductor structure is provided on the side of the transfer material opposite to the first processed semiconductor structure Overlying the layer of transfer material; removing a thicker substrate body of the substrate structure, leaving a thinner layer of material of the substrate structure bonded to the first processed semiconductor structure; and interconnecting the through wafers At least one of the through-wafer interconnects is electrically coupled to one of the conductive members of the other structure.

實施例2:如實施例1之方法,其中提供該底材結構更包含將該較薄材料層暫時鍵結至該較厚底材本體,且其中移除該底材結構之較厚底材本體,留下該底材結構之較薄材料層鍵結至該至少一個已處理半導體結構包含使該較厚底材本體從該較薄材料層分離。Embodiment 2: The method of Embodiment 1, wherein providing the substrate structure further comprises temporarily bonding the thinner material layer to the thicker substrate body, and wherein the thicker substrate body of the substrate structure is removed, leaving Bonding the thinner material layer of the substrate structure to the at least one processed semiconductor structure includes separating the thicker substrate body from the thinner material layer.

實施例3:如實施例1或實施例2之方法,其更包括在該底材結構之較薄材料層相反於該較厚底材本體之一面,將至少一個重分佈層形成於該較薄材料層上方後,再將該第一已處理半導體結構鍵結在該底材結構之較薄材料層上方,且其中將該第一已處理半導體結構鍵結在該底材結構之較薄材料層上方包含將該第一已處理半導體結構鍵結至該重分佈層。Embodiment 3: The method of Embodiment 1 or Embodiment 2, further comprising forming at least one redistribution layer on the thinner material on a side of the thinner material layer of the substrate structure opposite to one side of the thicker substrate body After the layer is over, the first processed semiconductor structure is bonded over the thinner material layer of the substrate structure, and wherein the first processed semiconductor structure is bonded over the thinner material layer of the substrate structure The bonding of the first processed semiconductor structure to the redistribution layer is included.

實施例4:如實施例1至3中任一項之方法,其中將該第一已處理半導體結構鍵結在該底材結構之較薄材料層上方包含在低於大約400℃之一個或多個溫度下,將該第一已處理半導體結構鍵結在該底材結構之較薄材料層上方。The method of any one of embodiments 1 to 3, wherein the first processed semiconductor structure is bonded to one or more of less than about 400 ° C above the thinner material layer of the substrate structure. The first processed semiconductor structure is bonded over the thinner layer of material of the substrate structure at a temperature.

實施例5:如實施例1至4中任一項之方法,其更包括選定該另一結構,使之包含一印刷電路板。Embodiment 5: The method of any of embodiments 1 to 4, further comprising selecting the other structure to include a printed circuit board.

實施例6:如實施例1至5中任一項之方法,其更包括將該第一已處理半導體結構鍵結在該底材結構之較薄材料層上方後,形成額外之多 個穿透晶圓互連,使之穿透該第一已處理半導體結構。Embodiment 6: The method of any of embodiments 1 to 5, further comprising forming the first processed semiconductor structure over the thinner layer of material of the substrate structure to form an additional One penetrates the wafer interconnect to penetrate the first processed semiconductor structure.

實施例7:如實施例1至6中任一項之方法,其更包括在一種形成鍵結半導體結構之方法中重複使用該底材結構之較厚底材本體。The method of any of embodiments 1 to 6, further comprising reusing the thicker substrate body of the substrate structure in a method of forming a bonded semiconductor structure.

實施例8:如實施例1至7中任一項之方法,其中在該第一已處理半導體結構相反於該第一底材結構之一面,將該轉移材料層提供於該第一已處理半導體結構上方包括:在該第一已處理半導體結構相反於該第一底材結構之一面,將包含一種半導體材料之一額外底材結構鍵結在該第一已處理半導體結構上方;以及形成該轉移材料層,使之包含該額外底材結構之半導體材料之至少一部分。The method of any one of embodiments 1 to 7, wherein the first processed semiconductor structure is opposite to the one side of the first substrate structure, the transfer material layer is provided to the first processed semiconductor The structure includes: bonding an additional substrate structure comprising one of the semiconductor materials over the first processed semiconductor structure at a side of the first processed semiconductor structure opposite to the first substrate structure; and forming the transfer A layer of material comprising at least a portion of the semiconductor material of the additional substrate structure.

實施例9:如實施例8之方法,其更包括:將離子沿著一離子植入平面植入該額外底材結構;以及將該額外底材結構鍵結在該第一已處理半導體結構上方後,使該額外底材結構沿著該離子植入平面斷裂。Embodiment 9: The method of Embodiment 8, further comprising: implanting ions along the ion implantation plane into the additional substrate structure; and bonding the additional substrate structure over the first processed semiconductor structure Thereafter, the additional substrate structure is fractured along the ion implantation plane.

實施例10:如實施例9之方法,其中使該額外底材結構沿著該離子植入平面斷裂包含將該額外底材結構加熱至低於大約400℃之一個或多個溫度,以造成該額外底材結構沿著該離子植入平面斷裂。Embodiment 10: The method of embodiment 9, wherein the breaking the additional substrate structure along the ion implantation plane comprises heating the additional substrate structure to one or more temperatures below about 400 ° C to cause the Additional substrate structures break along the ion implantation plane.

實施例11:如實施例1至10中任一項之方法,其中在該轉移材料層中形成電性互連、光學互連及流體互連其中至少一種包含在該轉移材料層中形成電性互連、光學互連及流體互連其中兩種或更多種。The method of any one of embodiments 1 to 10, wherein an electrical interconnection, an optical interconnection, and a fluid interconnection are formed in the layer of the transfer material, at least one of which comprises forming an electrical property in the layer of the transfer material Two or more of interconnections, optical interconnections, and fluid interconnections.

實施例12:如實施例1至11中任一項之方法,其中在該轉移材料層中形成電性互連、光學互連及流體互連其中至少一種包含形成額外之多個穿透晶圓互連,使之穿透該轉移材料層。The method of any one of embodiments 1 to 11, wherein an electrical interconnect, an optical interconnect, and a fluid interconnect are formed in the layer of transfer material, at least one of which comprises forming an additional plurality of through wafers Interconnected to penetrate the layer of transfer material.

實施例13:如實施例12之方法,其更包括使該些額外穿透晶圓互連中至少一個穿透晶圓互連在電性上與該第二已處理半導體結構之一導電部件耦合。Embodiment 13: The method of Embodiment 12, further comprising: coupling at least one of the additional through-wafer interconnects electrically coupled to one of the conductive components of the second processed semiconductor structure .

實施例14:如實施例1至11中任一項之方法,其中在該轉移材料層中形成電性互連、光學互連及流體互連其中至少一種包含形成至少一個光學互連,使之穿透該轉移材料層。The method of any one of embodiments 1 to 11, wherein an electrical interconnection, an optical interconnection, and a fluid interconnection are formed in the layer of transfer material, at least one of which comprises forming at least one optical interconnection such that Penetrating the layer of transfer material.

實施例15:如實施例14之方法,其中該第二已處理半導體結構包含至少一個光學組件,且其中該方法更包括使該至少一個光學互連在操作上與該第二已處理半導體結構中該至少一個光學組件耦合。Embodiment 15: The method of embodiment 14, wherein the second processed semiconductor structure comprises at least one optical component, and wherein the method further comprises operatively interacting the at least one optical interconnect with the second processed semiconductor structure The at least one optical component is coupled.

實施例16:如實施例1至11中任一項之方法,其中在該轉移材料層中形成電性互連、光學互連及流體互連其中至少一種包含在該轉移材料層中形成至少一個流體互連。The method of any one of embodiments 1 to 11, wherein an electrical interconnection, an optical interconnection, and a fluid interconnection are formed in the layer of transfer material, at least one of which comprises forming at least one in the layer of transfer material Fluid interconnection.

實施例17:一鍵結半導體結構,其包括:一底材結構,該底材結構包含:穿透相對較薄之一材料層之多個穿透晶圓互連;以及鍵結至該材料層之相對較厚之一底材本體;在該較薄材料層相反於該較厚底材本體之一面,在電性上耦合至該些穿透晶圓互連之多個已處理半導體結構;在該第一已處理半導體結構相反於該底材結構之一面,該第一已處理半導體結構上方之一轉移材料層;以及該轉移材料層中之電性互連、光學互連及流體互連其中至少一種。Embodiment 17: A bonded semiconductor structure comprising: a substrate structure comprising: a plurality of through-wafer interconnects penetrating a relatively thin layer of material; and bonding to the layer of material a relatively thick substrate body; wherein the thinner material layer is electrically coupled to the plurality of processed semiconductor structures that penetrate the wafer interconnect; a first processed semiconductor structure opposite one side of the substrate structure, a transfer material layer over the first processed semiconductor structure; and an electrical interconnect, an optical interconnect, and a fluid interconnect in the transfer material layer One.

實施例18:如實施例17之鍵結半導體結構,其中該較薄材料層具有之平均厚度為大約一又二分之一微米(1.5μm)或更薄。Embodiment 18: The bonded semiconductor structure of Embodiment 17, wherein the thinner material layer has an average thickness of about one and a half microns (1.5 [mu]m) or less.

實施例19:如實施例17或實施例18之鍵結半導體結構,其更包括該轉移材料層中之電性互連、光學互連及流體互連其中至少兩種。Embodiment 19: The bonded semiconductor structure of Embodiment 17 or Embodiment 18, further comprising at least two of an electrical interconnect, an optical interconnect, and a fluid interconnect in the layer of transfer material.

實施例20:如實施例17至19中任一項之鍵結半導體結構,其更包括在該轉移材料層相反於該些已處理半導體結構之一面,該轉移材料層上方之至少一個額外已處理半導體結構。Embodiment 20: The bonded semiconductor structure of any of embodiments 17 to 19, further comprising at least one additional processed layer over the transfer material layer opposite the one of the transferred semiconductor structures Semiconductor structure.

實施例21:如實施例20之鍵結半導體結構,其中該轉移材料層中之電性互連、光學互連及流體互連其中至少一種在操作上與該至少一個額外已處理半導體結構耦合。Embodiment 21: The bonded semiconductor structure of Embodiment 20, wherein at least one of the electrical interconnect, the optical interconnect, and the fluid interconnect in the layer of transfer material is operatively coupled to the at least one additional processed semiconductor structure.

上述該些示範性實施例並不會限制本發明之範圍,因為這些實施例僅為本發明實施例之範例,而本發明係由所附之申請專利範圍及其法律同等效力所界定。任何等同之實施例均在本發明之範圍內。事實上,對於本發明所屬技術領域具有通常知識者而言,除本說明書所示及所述者外,對於本發明之各種修改,例如替換所述元件之有用組合,都會因本說明書之敘述而變得顯而易見。換言之,本說明書所述任一示範性實施例之一項或多項特點,可以與本說明書所述另一示範性實施例之一項或多項特點結合,而成為本發明之額外實施例。此等修改及實施例亦落在所附之申請專利範圍內。The above-described exemplary embodiments are not intended to limit the scope of the invention, as these embodiments are only examples of the embodiments of the invention, and the invention is defined by the scope of the appended claims and their legal equivalents. Any equivalent embodiments are within the scope of the invention. In fact, various modifications of the invention, such as a substitute for a useful combination of the elements, in addition to those shown and described herein, will be apparent from the description of the specification. Become obvious. In other words, one or more of the features of any one of the exemplary embodiments described herein may be combined with one or more features of another exemplary embodiment described herein as an additional embodiment of the invention. Such modifications and embodiments are also within the scope of the appended claims.

100、110、120‧‧‧底材結構100, 110, 120‧‧‧ substrate structure

102‧‧‧材料層102‧‧‧Material layer

103‧‧‧鍵結半導體結構之表面103‧‧‧ Bonded surface of semiconductor structure

104‧‧‧底材本體104‧‧‧Substrate body

112、162、172‧‧‧穿透晶圓互連112, 162, 172‧‧‧through wafer interconnect

122、312‧‧‧重分佈層122, 312‧‧‧ redistribution layer

124、134、324、344、436‧‧‧導電部件124, 134, 324, 344, 436‧‧‧ conductive parts

126、138、316‧‧‧介電材料介電材料126, 138, 316‧‧‧ Dielectric materials

132A、132B、132C、132D、132E、132F、132G、132H、1321、132J、 132K、132L、132M、132N、132O、132P、132Q、132R‧‧‧已處理半導體結構132A, 132B, 132C, 132D, 132E, 132F, 132G, 132H, 1321, 132J, 132K, 132L, 132M, 132N, 132O, 132P, 132Q, 132R‧‧‧ processed semiconductor structures

139、406‧‧‧曝露主要表面139, 406‧‧‧ exposed main surface

130、140、150、160、170、200、210、300、310、320、330、400、420、500、520、530、600‧‧‧鍵結半導體結構130, 140, 150, 160, 170, 200, 210, 300, 310, 320, 330, 400, 420, 500, 520, 530, 600 ‧ ‧ bonded semiconductor structure

190‧‧‧額外底材結構190‧‧‧Additional substrate structure

192‧‧‧離子植入平面192‧‧‧Ion implantation plane

194‧‧‧主要表面194‧‧‧ main surface

196‧‧‧額外底材結構之一部分196‧‧‧One part of the additional substrate structure

212‧‧‧轉移材料層212‧‧‧Transfer material layer

302、314‧‧‧電性互連302, 314‧‧‧ Electrical interconnection

322、422‧‧‧已處理半導體元件322, 422‧‧‧Processed semiconductor components

332、432‧‧‧導電凸塊332, 432‧‧‧ conductive bumps

342‧‧‧電性上耦合至一結構342‧‧‧ Electrically coupled to a structure

346、438‧‧‧圍繞介電材料346, 438‧‧‧ Around dielectric materials

402‧‧‧光學互連402‧‧‧ Optical Interconnection

404‧‧‧孔隙404‧‧‧ pores

408‧‧‧曝露表面408‧‧‧ exposed surface

410‧‧‧聚合物前驅材料410‧‧‧Polymer precursor material

412‧‧‧固態聚合物材料412‧‧‧Solid polymer materials

424‧‧‧光電元件424‧‧‧Optoelectronic components

426‧‧‧波導426‧‧‧Band

502‧‧‧凹槽502‧‧‧ Groove

504‧‧‧流體互連504‧‧‧ Fluid Interconnect

512‧‧‧保護材料512‧‧‧Protective materials

522‧‧‧材料層522‧‧‧Material layer

524‧‧‧鍵結層524‧‧‧bonding layer

532A、532B‧‧‧接入開孔532A, 532B‧‧‧ access opening

534A‧‧‧第一流體管道534A‧‧‧First fluid pipeline

534B‧‧‧第二流體管道534B‧‧‧Second fluid pipeline

602A、602B‧‧‧跨層互連層602A, 602B‧‧‧cross-layer interconnect layer

604A‧‧‧第一層604A‧‧‧ first floor

604B‧‧‧第二層604B‧‧‧ second floor

604C‧‧‧第三層604C‧‧‧ third floor

儘管本說明書以申請專利範圍作結,而該些申請專利範圍已具體指出並明確主張何謂可視為本發明實施例者,但配合所附圖式閱讀本發明實施例某些範例之敘述,將更容易明白本發明實施例之優點,在所附圖 式中:圖1A至1K為半導體結構之簡化截面圖,其描繪一中間結構之形成,該中間結構可在依照本發明之示範性實施例製作鍵結半導體結構期間形成;圖2A至2E為半導體結構之簡化截面圖,其描繪依照本發明之示範性實施例,從圖1K所示之中間結構形成一鍵結半導體結構,其中,電性互連係形成於該中間結構上一轉移半導體層中;圖3A至3C為半導體結構之簡化截面圖,其描繪依照本發明之其他示範性實施例,從圖1K所示之中間結構形成另一鍵結半導體結構,其中,光學互連係形成於該中間結構上一轉移半導體層中;圖4A至4D為半導體結構之簡化截面圖,其描繪依照可供圖3A至3C所述方法採用之技術之範例所形成之光學互連;圖5A至5E為半導體結構之簡化截面圖,其描繪依照本發明之其他示範性實施例,從圖1K所示之中間結構形成另一鍵結半導體結構,其中,流體互連係形成於該中間結構上一轉移半導體層中;圖6為在三度空間上集積之一鍵結半導體結構之簡化局部剖面透視圖,該鍵結半導體結構可以應用本發明方法之實施例形成,且該鍵結半導體結構包含多個已處理半導體結構層,該些已處理半導體結構層之間有互連層,該些互連層內有三種不同類型之互連;以及圖7為在三度空間上集積之另一鍵結半導體結構之簡化局部剖面透視圖,該鍵結半導體結構可以應用本發明方法之實施例形成,且該鍵結 半導體結構包含多個已處理半導體結構層,該些已處理半導體結構層之間有互連層,該些互連層內有兩種不同類型之互連。While the specification has been described in the specification of the invention, and the claims of the invention are intended to be It is easy to understand the advantages of the embodiments of the present invention, 1A to 1K are simplified cross-sectional views of a semiconductor structure depicting the formation of an intermediate structure that can be formed during fabrication of a bonded semiconductor structure in accordance with an exemplary embodiment of the present invention; FIGS. 2A through 2E are semiconductors A simplified cross-sectional view of a structure, in accordance with an exemplary embodiment of the present invention, forming a bonded semiconductor structure from the intermediate structure illustrated in FIG. 1K, wherein an electrical interconnect is formed in a transfer semiconductor layer on the intermediate structure; 3A through 3C are simplified cross-sectional views of a semiconductor structure depicting another bonded semiconductor structure formed from the intermediate structure illustrated in FIG. 1K in accordance with other exemplary embodiments of the present invention, wherein an optical interconnect is formed in the intermediate structure 4A to 4D are simplified cross-sectional views of a semiconductor structure depicting optical interconnections formed in accordance with examples of techniques that may be employed in the methods described in FIGS. 3A through 3C; FIGS. 5A through 5E are semiconductor structures A simplified cross-sectional view depicting another bonded semiconductor structure formed from the intermediate structure illustrated in FIG. 1K in accordance with other exemplary embodiments of the present invention, wherein the flow An interconnect is formed in the transfer semiconductor layer on the intermediate structure; FIG. 6 is a simplified partial cross-sectional perspective view of a bonded semiconductor structure in a three-dimensional space, the bonded semiconductor structure can be formed using an embodiment of the method of the present invention And the bonded semiconductor structure comprises a plurality of processed semiconductor structure layers, wherein the processed semiconductor structure layers have interconnect layers, and the interconnect layers have three different types of interconnects; and FIG. 7 is in three A simplified partial cross-sectional perspective view of another bonded semiconductor structure that is spatially accumulated, the bonded semiconductor structure can be formed using an embodiment of the method of the present invention, and the bonding The semiconductor structure includes a plurality of processed semiconductor structure layers having interconnect layers between the processed semiconductor structure layers, the interconnect layers having two different types of interconnects.

100‧‧‧底材結構100‧‧‧Material structure

102‧‧‧材料層102‧‧‧Material layer

104‧‧‧底材本體104‧‧‧Substrate body

Claims (21)

一種形成一鍵結半導體結構之方法,其包括:提供一底材結構,該底材結構在相對較厚之一底材本體上包含相對較薄之一材料層;形成多個穿透晶圓互連(through wafer interconnect),使之穿透該底材結構之相對較薄材料層,並形成包含該相對較薄材料層及該多個穿透晶圓互連之一互連層;在該底材結構之相對較薄材料層相反於該相對較厚底材本體之一面,將一第一已處理半導體結構鍵結在該相對較薄材料層上方,並將該第一已處理半導體結構中至少一個導電部件在電性上與該些穿透晶圓互連中至少一個穿透晶圓互連耦合;在該第一已處理半導體結構相反於該底材結構之一面,將一轉移材料層提供於該第一已處理半導體結構上方;在該轉移材料層中形成電性互連、光學互連及流體互連其中至少一種;在該轉移材料層相反於該第一已處理半導體結構之一面,將一第二已處理半導體結構提供於該轉移材料層上方;移除該底材結構之相對較厚底材本體,並留下該底材結構之相對較薄材料層鍵結至該第一已處理半導體結構;以及 將該些穿透晶圓互連中至少一個穿透晶圓互連在電性上耦合至另一結構之一導電部件。 A method of forming a bonded semiconductor structure, comprising: providing a substrate structure comprising a relatively thin layer of material on a relatively thick substrate body; forming a plurality of through wafers Through a wafer interconnect that penetrates a relatively thin layer of material of the substrate structure and forms an interconnect layer comprising the relatively thin layer of material and the plurality of through wafer interconnects; a relatively thin layer of material opposite the one side of the relatively thick substrate body, bonding a first processed semiconductor structure over the relatively thin layer of material, and at least one of the first processed semiconductor structures Conductive features are electrically coupled to at least one of the through-wafer interconnects of the through-wafer interconnects; a layer of transfer material is provided on the first processed semiconductor structure opposite one side of the substrate structure Overlying the first processed semiconductor structure; forming at least one of an electrical interconnect, an optical interconnect, and a fluid interconnect in the layer of transfer material; wherein the layer of transfer material is opposite one side of the first processed semiconductor structure, Providing a second processed semiconductor structure over the layer of transfer material; removing a relatively thick substrate body of the substrate structure and leaving a relatively thin layer of material of the substrate structure bonded to the first processed Semiconductor structure; At least one of the through-wafer interconnects of the through-wafer interconnects is electrically coupled to one of the conductive features of the other structure. 如申請專利範圍第1項之方法,其中提供該底材結構更包含將該相對較薄材料層暫時鍵結至該相對較厚底材本體,且其中移除該底材結構之相對較厚底材本體並留下該底材結構之相對較薄材料層鍵結至該至少一個已處理半導體結構包含將該相對較厚底材本體從該相對較薄材料層分離。 The method of claim 1, wherein the providing the substrate structure further comprises temporarily bonding the relatively thin layer of material to the relatively thick substrate body, and wherein the relatively thick substrate body of the substrate structure is removed And bonding the relatively thin layer of material of the substrate structure to the at least one processed semiconductor structure comprises separating the relatively thick substrate body from the relatively thinner layer of material. 如申請專利範圍第1項之方法,其更包括在該底材結構之相對較薄材料層相反於該相對較厚底材本體之一面,將至少一個重分佈層形成於該相對較薄材料層上方後,再將該第一已處理半導體結構鍵結在該底材結構之相對較薄材料層上方,且其中將該第一已處理半導體結構鍵結在該底材結構之相對較薄材料層上方包含將該第一已處理半導體結構鍵結至該重分佈層。 The method of claim 1, further comprising forming at least one redistribution layer over the relatively thinner material layer on a side of the relatively thinner material layer of the substrate structure opposite the one of the relatively thicker substrate body Thereafter, the first processed semiconductor structure is bonded over a relatively thin layer of material of the substrate structure, and wherein the first processed semiconductor structure is bonded over a relatively thin layer of material of the substrate structure The bonding of the first processed semiconductor structure to the redistribution layer is included. 如申請專利範圍第1項之方法,其中將該第一已處理半導體結構鍵結在該底材結構之相對較薄材料層上方包含在低於大約400℃之一個或多個溫度下,將該第一已處理半導體結構鍵結在該底材結構之相對較薄材料層上方。 The method of claim 1, wherein the first processed semiconductor structure is bonded to the relatively thin layer of material of the substrate structure at one or more temperatures below about 400 ° C, The first processed semiconductor structure is bonded over a relatively thin layer of material of the substrate structure. 如申請專利範圍第1項之方法,其更包括選定該另一結構,使之包含一印刷電路板。 The method of claim 1, further comprising selecting the other structure to include a printed circuit board. 如申請專利範圍第1項之方法,其更包括將該第一已處理半導體結構鍵結在該底材結構之相對較薄材料層上方後,形成額外之多個穿透晶圓互連,使之穿透該第一已處理半導體結構。 The method of claim 1, further comprising bonding the first processed semiconductor structure over a relatively thin layer of material of the substrate structure to form an additional plurality of through-wafer interconnects Passing through the first processed semiconductor structure. 如申請專利範圍第1項之方法,其更包括在一種形成鍵結半導體結構之方法中重複使用該底材結構之相對較厚底材本體。 The method of claim 1, further comprising reusing the relatively thick substrate body of the substrate structure in a method of forming a bonded semiconductor structure. 如申請專利範圍第1項之方法,其中在該第一已處理半導體結構相反於該底材結構之一面,將該轉移材料層提供於該第一已處理半導體結構上方包括:在該第一已處理半導體結構相反於該底材結構之一面,將包含一種半導體材料之一額外底材結構鍵結在該第一已處理半導體結構上方;以及形成該轉移材料層,使之包含該額外底材結構之半導體材料之至少一部分。 The method of claim 1, wherein the first processed semiconductor structure is opposite to one side of the substrate structure, the layer of the transfer material being provided over the first processed semiconductor structure comprises: at the first Processing the semiconductor structure opposite to one side of the substrate structure, bonding an additional substrate structure comprising one of the semiconductor materials over the first processed semiconductor structure; and forming the transfer material layer to include the additional substrate structure At least a portion of the semiconductor material. 如申請專利範圍第8項之方法,其更包括:將離子沿著一離子植入平面植入該額外底材結構;以及將該額外底材結構鍵結在該第一已處理半導體結構上方後,使該額外底材結構沿著該離子植入平面斷裂。 The method of claim 8, further comprising: implanting ions along the ion implantation plane into the additional substrate structure; and bonding the additional substrate structure over the first processed semiconductor structure The additional substrate structure is fractured along the ion implantation plane. 如申請專利範圍第9項之方法,其中使該額外底材結構沿著該離子植入平面斷裂包含將該額外底材結構加熱至低於大約400℃ 之一個或多個溫度,以造成該額外底材結構沿著該離子植入平面斷裂。 The method of claim 9 wherein the additional substrate structure is fractured along the ion implantation plane comprising heating the additional substrate structure to less than about 400 ° C. One or more temperatures to cause the additional substrate structure to fracture along the ion implantation plane. 如申請專利範圍第1項之方法,其中在該轉移材料層中形成電性互連、光學互連及流體互連其中至少一種包含在該轉移材料層中形成電性互連、光學互連及流體互連其中兩種或更多種。 The method of claim 1, wherein the forming of the electrical interconnect, the optical interconnect, and the fluid interconnect in the layer of transfer material comprises at least one of forming an electrical interconnect, an optical interconnect, and Two or more of the fluid interconnections. 如申請專利範圍第1項之方法,其中在該轉移材料層中形成電性互連、光學互連及流體互連其中至少一種包含形成額外之多個穿透晶圓互連,使之穿透該轉移材料層。 The method of claim 1, wherein the forming at least one of the electrical interconnect, the optical interconnect, and the fluid interconnect in the layer of transfer material comprises forming an additional plurality of through-wafer interconnects to penetrate The layer of transfer material. 如申請專利範圍第12項之方法,其更包括使該些額外穿透晶圓互連中至少一個穿透晶圓互連在電性上與該第二已處理半導體結構之一導電部件耦合。 The method of claim 12, further comprising coupling at least one of the additional through-wafer interconnects electrically coupled to one of the second processed semiconductor structures. 如申請專利範圍第1項之方法,其中在該轉移材料層中形成電性互連、光學互連及流體互連其中至少一種包含形成至少一個光學互連,使之穿透該轉移材料層。 The method of claim 1, wherein the forming at least one of the electrical interconnect, the optical interconnect, and the fluid interconnect in the layer of transfer material comprises forming at least one optical interconnect to penetrate the layer of transfer material. 如申請專利範圍第14項之方法,其中該第二已處理半導體結構包含至少一個光學組件,且其中該方法更包括使該至少一個光學互連在操作上與該第二已處理半導體結構中該至少一個光學組件耦合。 The method of claim 14, wherein the second processed semiconductor structure comprises at least one optical component, and wherein the method further comprises operatively interacting the at least one optical interconnect with the second processed semiconductor structure At least one optical component is coupled. 如申請專利範圍第1項之方法,其中在該轉移材料層中形成 電性互連、光學互連及流體互連其中至少一種包含在該轉移材料層中形成至少一個流體互連。 The method of claim 1, wherein the layer of the transfer material is formed At least one of the electrical interconnect, the optical interconnect, and the fluid interconnect includes forming at least one fluid interconnect in the layer of transfer material. 一鍵結半導體結構,其包括:一底材結構,其包含:穿透相對較薄之一材料層之多個穿透晶圓互連;包含該相對較薄材料層及該多個穿透晶圓互連之一互連層;以及鍵結至該相對較薄材料層之相對較厚之一底材本體;在該相對較薄材料層相反於該相對較厚底材本體之一面,在電性上耦合至該些穿透晶圓互連之多個已處理半導體結構;在該第一已處理半導體結構相反於該底材結構之一面,該第一已處理半導體結構上方之一轉移材料層;以及該轉移材料層中之電性互連、光學互連及流體互連其中至少一種。 A bonded semiconductor structure comprising: a substrate structure comprising: a plurality of through-wafer interconnects penetrating a relatively thin layer of material; comprising the relatively thin layer of material and the plurality of through-crystals An interconnect layer of a circular interconnect; and a relatively thick one of the substrate bodies bonded to the relatively thinner material layer; wherein the relatively thinner material layer is opposite to one of the relatively thicker substrate bodies, in electrical Upper to be coupled to the plurality of processed semiconductor structures penetrating the wafer interconnect; wherein the first processed semiconductor structure is opposite to one side of the substrate structure, one of the transfer material layers above the first processed semiconductor structure; And at least one of an electrical interconnection, an optical interconnection, and a fluid interconnection in the layer of transfer material. 如申請專利範圍第17項之鍵結半導體結構,其中該相對較薄材料層具有之平均厚度為大約一又二分之一微米(1.5μm)或更薄。 The bonded semiconductor structure of claim 17, wherein the relatively thin material layer has an average thickness of about one and a half micrometers (1.5 μm) or less. 如申請專利範圍第17項之鍵結半導體結構,其更包括該轉移材料層中之電性互連、光學互連及流體互連其中至少兩種。 The bonded semiconductor structure of claim 17 further comprising at least two of the electrical interconnection, the optical interconnection, and the fluid interconnection in the layer of the transfer material. 如申請專利範圍第17項之鍵結半導體結構,其更包括在該轉移材料層相反於該些已處理半導體結構之一面,該轉移材料層上方之至少一個額外已處理半導體結構。 The bonded semiconductor structure of claim 17, further comprising at least one additional processed semiconductor structure over the transfer material layer opposite the one of the processed semiconductor structures. 如申請專利範圍第20項之鍵結半導體結構,其中該轉移材料層中之電性互連、光學互連及流體互連其中至少一種在操作上與該至少一個額外已處理半導體結構耦合。The bonded semiconductor structure of claim 20, wherein at least one of the electrical interconnect, the optical interconnect, and the fluid interconnect in the layer of transfer material is operatively coupled to the at least one additional processed semiconductor structure.
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