TWI456037B - 塗佈外觀缺點經改善之抗靜電聚酯膜及其製造方法 - Google Patents

塗佈外觀缺點經改善之抗靜電聚酯膜及其製造方法 Download PDF

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TWI456037B
TWI456037B TW098110386A TW98110386A TWI456037B TW I456037 B TWI456037 B TW I456037B TW 098110386 A TW098110386 A TW 098110386A TW 98110386 A TW98110386 A TW 98110386A TW I456037 B TWI456037 B TW I456037B
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antistatic
weight
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polyester film
parts
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TW098110386A
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TW201031740A (en
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Jae Hoon Kim
Kyu Suk Lee
Sang Weon Seo
Jeong Tae Seo
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Toray Advanced Mat Korea Inc
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/044—Forming conductive coatings; Forming coatings having anti-static properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/18—Homopolymers or copolymers of aromatic monomers containing elements other than carbon and hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21—Anti-static
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2475/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)

Claims (6)

  1. 一種塗佈外觀缺點經改善之抗靜電塗佈組成物，其含有：傳導性高分子樹脂100重量份；水分散性聚胺基甲酸酯樹脂100重量份~1000重量份，其具有選自羥基、胺基、烷基及羧基所構成之群中至少1種官能基；交聯劑樹脂100重量份~1000重量份，其選自異氰酸酯系、羰基醯亞胺系、噁唑啉系、環氧系及三聚氰胺系所構成之群中任意1種，以及；氟樹脂10重量份~100重量份，並且相對於該組成物100重量份添加有矽烷系界面活性劑0.001重量份~1重量份，而使其充分滿足如下所述之物性：1)每1m2檢查面積觀察到由塗佈組成物內之微細氣泡所致的塗佈外觀缺點為0~1個；2)該抗靜電聚酯膜與由聚酯基材及丙烯酸酯黏著劑構成之膠帶(NITTO # 31B)的剝離力為300g/in以上；3)與由紙材質之基材及丙烯酸酯黏著劑構成之膠帶(3M # 244)的剝離力為100g/18mm以上。
  2. 如申請專利範圍第1項之抗靜電塗佈組成物，其中該氟樹脂為選自聚四氟乙烯、聚三氟乙烯、六氟丙烯-乙烯共聚物、聚氯三氟乙烯、聚四氟乙烯共聚物、氯三氟乙烯、聚氟乙烯及聚偏二氟乙烯所構成之群中至少1種。
  3. 如申請專利範圍第1項之抗靜電塗佈組成物，其中該抗靜電塗佈組成物內之固體成分含量為0.5重量%~10.0重量%。
  4. 一種塗佈外觀缺點經改善之抗靜電聚酯膜，其於聚酯膜之一面或兩面上具有抗靜電層，該抗靜電層係藉由線上塗佈方式塗佈如申請專利範圍第1項之抗靜電塗佈組成物而成者。
  5. 如申請專利範圍第4項之塗佈外觀缺點經改善之抗靜電聚酯膜，其維持著如以下之抗靜電性，即用選自乙醇、甲基乙基酮、甲苯及乙酸乙酯所構成之群中任意1種有機溶劑進行清洗該抗靜電聚酯膜表面時，清洗前之表面電阻值及清洗後之表面電阻值未滿1×1011Ω/sq。
  6. 如申請專利範圍第4項之塗佈外觀缺點經改善之抗靜電聚酯膜，其中抗靜電聚酯膜之水接觸角為90°以上。
TW098110386A 2009-02-17 2009-03-30 塗佈外觀缺點經改善之抗靜電聚酯膜及其製造方法 TWI456037B (zh)

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KR1020090012676A KR101077822B1 (ko) 2009-02-17 2009-02-17 코팅외관 결점이 개선된 대전방지 폴리에스테르 필름 및 그제조방법

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TWI456037B true TWI456037B (zh) 2014-10-11

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JP2010189616A (ja) 2010-09-02
CN101805558B (zh) 2013-04-24
KR101077822B1 (ko) 2011-10-31
KR20100093635A (ko) 2010-08-26
CN101805558A (zh) 2010-08-18
TW201031740A (en) 2010-09-01
JP5428089B2 (ja) 2014-02-26

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