TWI334388B - - Google Patents

Description

IX. Description of the Invention: [Technical Field] The present invention relates to a method for producing a film composite material, and more particularly to a method for producing a solvent-free environment-friendly thermoplastic film composite material in which a solvent is not blended in a process. [Prior Art] It is usually applied to the cloth material such as table cloth or lining cloth for shoes, leather goods, backpacks or cushions. A layer of PU glue is applied on the surface of the cloth material to make a composite film of PU film, and then the surface layer is applied. Attached or attached to the inner layer, it is easy to be worn by the PU thin-film money-saving cloth material and effectively prevent the fiber from falling off and increase the service life of the product. In addition, by heating, the PU film can smoothly bond the composite material to other materials. The material surface 'so' is a film composite that has been widely used in the processing of various industrial products, and PU is a film material that is currently used. Referring to FIG. 1 and FIG. 2', a method for manufacturing a film composite material comprises the following steps: Step 101 is to provide a polyurethane (polyurethane 'abbreviated as PU) compound liquid prepared by using an organic solvent and having a predetermined viscosity. That is, the PU dope 100 is filled in a feed tank U. Usually, the PU raw material having an original viscosity value of 50 and 〇〇〇cps~60,000 cps is diluted with an organic solvent to a viscosity value of 6,000 cps to 10, and the PU gum solution of 〇〇〇cps is 1 Torr. Step 102 is to use a glue extractor 12 to draw the glue liquid 1 from the feed barrel and guide it to a gumming unit 13, the glue unit 13 has a pressure wheel 131, a pressure and a pressure The rubber plate 132 is abutting and upwardly inclined, and a pressing roller 133 disposed above the pressing wheel 131 and moving relative to the pressing wheel ι31 1334388, the glue liquid 100 is poured on The pressure roller 131 is interposed between the pressure plate 131 and the rubber plate 132. The above-mentioned pressure roller 131 may not be heated during operation, and if heating is required, the heating temperature is between 50 ° C and 90 ° C. Step 103 is to provide a substrate layer 200 which is sent from a feed roller 14 and bypasses a plurality of spaced apart support rollers 15 and then passes through the pressure roller 131 and the stopper. A gap between the plates 132 is wound around the pressing wheel 131, and is sandwiched between the pressing wheel 131 and the pressing roller 133. The gap between the rubber sheet 13 2 and the pressure roller 13 1 is just enough for the substrate layer 200 to pass through, and the glue liquid 100 is sprayed on the substrate layer 2 . Further, the thickness of the applied rubber layer can be determined by moving the pressing roller 133 to adjust the gap between the pressing roller and the pressing roller 133. Step 104 is: conveying the substrate layer 2 which has been coated with the glue liquid to an oven 16 for drying, so that the glue liquid is dried and shaped into a film 300, and the solvent is made. The composite material 400 is produced by volatilizing and evaporating from the film 3〇〇. In step 105, the composite material 4 is wound up by using a roll of the reel 17 , and the composite material 400 to which the film 3 is bonded can be produced by the above-described manufacturing method, and can be reinforced by the film 3 of the PU material. The durability of the composite material _, but actually there are still the following defects: First, the PU (four) liquid _ must be prepared with an organic solvent capable of dissolving PU. 'The solvent is a volatile and harmful substance, and in order to achieve Good dissolution effect 'usually the compound 9_plus _ 9CTC or so' will cause more solvent to volatilize and release to the environment. In addition, 6 1334388 applies the glue solution 1GG to the substrate layer and sends it. When drying to the tank i, the same manufacturing method that releases a large amount of vaporized solvent during the drying process is relatively environmentally unfriendly and can be detrimental to the health of the operator. 1. Although the existing manufacturing method can volatilize the mixture in the thin m 3 ' by the flooding, there is still solvent residue in the composite material, so that the composite material produced by the existing manufacturing method is still It has the disadvantage of jeopardizing the health of the user. 3. Referring to FIG. 2 and FIG. 3, if the substrate layer 2 used is a three-layer mesh type 4, since the two-layer mesh is composed of a honeycomb layer portion, a bottom portion 202, and a plurality of branches When the connecting fiber 203 between the honeycomb layer portion 2 and the bottom portion μ is formed, the pu compound liquid is applied to the honeycomb layer portion 2 of the substrate layer 200. When the concentration of the rubber liquid (10) is relatively low and has high fluidity, the rubber liquid is more likely to infiltrate into the connecting fiber 203 from the mesh layer 201 before drying, resulting in « The guillotine connecting fiber 203 hardens after drying, which affects its elastic compression performance, and the existing manufacturing method has the disadvantage of wasting raw materials compared to the use of more sizing liquid 100, and at the same time, due to the connecting fibers 2〇 The elasticity of 3 is broken, and the quality of the composite material produced is relatively poor. When the substrate layer 200 is in a single layer cloth type, the consistency of the glue liquid 100 is relatively low and difficult to control, resulting in the glue liquid 100 from the substrate during the coating process. The surface of the layer 2 渗透 penetrates into the interior, and after drying, the 'dry and hardened rubber compound may cause the hardness of the substrate layer to increase and unevenly distribute, and lose the softness of the original cloth material, so that the The prior art manufacturing method of 7 1334388 also has the disadvantage of making the quality of the composite material 400 produced less desirable. SUMMARY OF THE INVENTION Therefore, the object of the present invention is to provide a method for producing a solvent-free environment-friendly thermoplastic film composite which can save the amount of the film raw material without using a solvent and which is less likely to affect the quality of the finished product. Therefore, the method for producing the solvent-free environment-friendly thermoplastic film composite of the present invention comprises the following steps: (1) providing a granular polymer component, wherein the polymer component is selected from the group consisting of copolymerization Ester (c〇p〇lyester) particles or copolyamide particles; (ii) hot melt and extrusion, the high molecular polymer component is put into a screw extruder and at a predetermined temperature Heating to form a polymer polymer melt, and then extruding the melt out of the screw extruder;

Providing a substrate layer conveyed at a predetermined speed, and guiding the high molecular polymer melt to a side surface adjacent to the substrate layer, and then applying a predetermined pressure to polymerize the polymer The adhesive layer of the transfer adhesive or the coating layer; and the base (4) cold air drying, the substrate layer which has been transferred or coated with the polymer _ is subjected to cold air drying, and the melt is dried to form a film, and Joining the substrate layer into a composite product. The invention has the beneficial effects that when a high molecular polymer component made of a copolyester or a copolymerized decylamine is used as a raw material of a film, it can be directly heated by a screw extruder to form a melted state, and the state can be made It is directly transferred to: 8 1334388 cloth forms a film on the substrate layer to enhance the wear resistance and durability of the substrate layer, and can be easily adhered to other materials through the film, 'because, high No solvent is added to the molecular polymer component, so that the formed melt has high viscosity and low fluidity, thereby not only making the material less likely to penetrate into the interior of the substrate layer, but also forming a film on the surface of the substrate layer. It can effectively control the amount of coating (4), so that the manufacturing method of the invention has the advantages of less waste of raw materials, material properties that are less likely to affect the substrate layer, and environmental protection without using a solvent. < • [Embodiment] The foregoing and other technical contents, features, and effects of the method for producing a solvent-free environmentally-friendly thermoplastic film composite according to the present invention are as follows in the detailed description of the two preferred embodiments with reference to the drawings. Will be clearly understood. Referring to FIG. 4 and FIG. 5, a first preferred embodiment of the method for manufacturing a solvent-free environment-friendly thermoplastic film composite of the present invention comprises the following steps: Step 501 is to provide a granular polymer component 61, and The knife polymer component 61 is selected from copolyester particles or cpolyamide particles. Step 502 is hot melt and extrusion, and the polymer component 61 is thrown into a screw extruder 71 and heated at a predetermined temperature to form a molecular polymer melt 62. The melt 62 is extruded out of the screw extruder 71. Preferably, the high molecular polymer component 61 is heated to form the high molecular polymer melt 62 in a temperature range of 150 C to 250 ° C, and in the preferred embodiment is substantially employed at a temperature. The polymer component 61 is heated to form a melt 62, and the viscosity of the polymer gel 62 is preferably 20,000 cps to 60,000 cps.

Step 503 is to provide a substrate layer 63 that is conveyed at a predetermined speed, and a pressing wheel 72 is disposed corresponding to a back surface 631 of the substrate layer 63 to guide the polymer melt 62 to the pressure roller. A surface 721 of the 72 is further transferred to the adhesion surface 631 of the base material layer 63 by a predetermined pressure by applying a predetermined pressure to the pressure roller 72. In this embodiment, it is preferable to set the viscosity of the base polymer layer 63 to 15 m/min in consideration of the viscosity and transfer effect of the polymer polymer melt 62. Preferably, a rubber plate 73 is further disposed between the screw extruder 71 and the pressure roller 72, and the rubber plate 73 extends obliquely downward from the screw extruder 7ι, and The surface 721 of the pressure wheel 72 cooperates to define a gap 73. The polymer polymer 62 is adhered to the surface 721 of the pressure wheel 72 through the gap 1 and then transferred through the pressure wheel 72. To the bonding surface 631 of the substrate layer 63. Wherein, the temperature range of the stretcher plate 73 and the pressure roller 72 are both set at 15〇t:~25〇

The molecular polymer dissolves... in a molten state that does not solidify: it is printed. Furthermore, the thickness of the sol 62 attached to the pressure roller 72 can be controlled by adjusting the width of the gap 731 between the barrier rib 73 and the pressure roller 72 to further control the transfer to the substrate layer 63. The thickness of the glue layer. 63 is a squeeze roller 75 and a cooling roller 76 which are wound out from a feeding roller 74, wherein the substrate layer is arranged to be spaced apart from the front and rear by a pressing roller 75 and a cooling roller. 76 is disposed on the same side of the substrate layer ' and is opposite to the pressure wheel 72, and the substrate layer 63 is conveyed and clamped to the 5 压 pressure wheel 7 2 and the Squeeze the cruise wheel 7 between the conventional & sight wheel 75 to provide a predetermined pressure with respect to the pressure roller 72 by means of the squeeze roller 10 1334388 wheel 75, thereby causing the directional molecule 1 attached to the surface 7 21 of the pressure roller 7 2 The glaze is smoothly transferred to the bonding surface 631 of the substrate layer 63. The temperature of the pressing guest 76 is preferably set at 150 ° C to 250 ° C and transferred to the substrate layer 63. The thickness of the adhesive layer of the polymer polymer melt is preferably between 0. Olmni and 0.2 mm. After the polymer melt 62 is pressed and transferred from the pressure roller 72 to the substrate layer 63, the substrate layer 63 continues to be fed backward and wound around the substrate layer 63.

The cooling roller 76 is cooled to shape the polymer melt 62 by the cooling roller 76. The temperature range of the cooling roller 76 is set to 10 ° C to 40 ° C. Step 504 is cold air drying, and the substrate layer 63 to which the polymer polymer viscous gel 62 has been transferred is transported into a cold air drying box 77, and the polymer polymer melt 62 is further dried by blowing cold air. A film 64 is formed and bonded to the substrate layer 63 as a composite finished product. ,

Step 505 is a winding take-up, which is wound up by the take-up reel 78 to take the finished composite 60' and form a roll-like package. 6 and FIG. 7′ are a second preferred embodiment of the method for manufacturing a solvent-free environment-friendly thermoplastic film composite according to the present invention. The main difference between the second preferred embodiment and the first preferred embodiment is : Polymerization: Melting

The glue 62 is applied to the substrate layer (4) and the back surface 631 by coating, and the following steps are carried out: I Step 801 is to provide the polymer component 61. Step 802 is heat squeezing and extruding, the high molecular polymer is passed into a screw extruder 91, and heated at a material temperature to form the ^ 11 1334388 subpolymer melt 62, and then The melter 62 extrudes the screw extruder 91. The step 803 is to provide a substrate layer 输送 conveyed at a predetermined speed, and to guide the south molecular polymer melt 62 to the back surface 631 of the substrate layer 63. And applying the predetermined pressure to the polymer polymer melt 62 to the bonding surface 631. Step 804 is cold air drying, and the polymer polymer melt 62 is dried in a cold air drying box 92 to form the film 64, and joined to the substrate layer 63 as the composite product 60. Step 805 is to wind up the composite product 60 by using a take-up roller 93. The steps 801, 802, 804, and 805 are the same as the steps 501, 502, 504, and 505 of the first preferred embodiment, respectively. Therefore, it will not be detailed. In step 803, a rubber plate 94 and a pressure roller 95 extending obliquely downward from the screw extruder 91 are defined to cooperate with each other, and the substrate layer 63 passes through the gap 941. Then, it is wound around a surface 95 of the pressure roller, and the bottom surface 631 of the substrate layer 63 is in contact with the lower end side of the rubber sheet 94. The polymer melt a is a pilot flow to the The rubber sheet 94 flows along the rubber sheet 94 to the substrate layer 63 and adheres to the bonding surface 631. Preferably, the substrate layer 63 is wound from a feed roller 96 and sequentially passed through a support roller 97' through the gap 941, wound around the pressure roller 95, and then wound. a squeeze roller 98 and a cooling roller 99 are arranged at intervals, the support roller 97 and the disk wheel % are located on the same side of the substrate layer 12 1334388 63, and the squeeze roller % is The bottom surface 631 of the substrate layer 63 is disposed opposite to the pressure roller 95 and is movable relative to the pressure roller to apply a predetermined pressure thereto. The substrate layer 63 is first passed through the gap 941. The polymer polymer melt 62 is attached to the adhesive surface ,1, and continues to be transported backward to be clamped between the pressure roller 95 and the squeeze roller wheel % to utilize the squeeze roller 98 against the pressure roller. The pressure of 95 causes the high molecular polymer melt 62 to be pressed to be applied to the adhesive surface at a predetermined thickness.

The cooling roller 99 and the pressure roller 95 are also disposed on the same side of the substrate layer 63. When the polymer melt 62 is pressed and applied to the bonding surface 631, the substrate layer 63 continues to be rearward. It is conveyed and wound around the cooling roller 99 to cool the polymer polymer by the cooling roller 99. t, the temperature range setting of the rubber sheet 94, the pressing roller 98 and the cooling roller 99 is the same as the first preferred embodiment (4), and will not be described again. The thickness of the adhesive layer of the polymer polymer melt coated on the base material layer 63 is preferably between 0.01 mm and 0.2 mm.

Preferably, the substrate layer used in the two embodiments is a substance in the following group: a single layer cloth, a three layer mesh cloth, 63 is a material selected from the group consisting of paper and plastic film _ 5 ' Fig. 8 9' when a three-layer mesh is used as the substrate layer 63, then the three-layer mesh has a honeycomb layer portion 63 joined to the film 64 and spaced apart from the honeycomb layer portion 631. The bottom portion 632, and a plurality of connecting fibers 633 that are connected and filled between the honeycomb layer portion 631 and the bottom portion 632. Through the manufacturing method of the above-mentioned first and second preferred embodiments, since the film 64 is directly melted by the polymer component 61, 13 == line transfer or coating, so that the ... is relatively high and . Transfer or coating on the honeycomb layer portion 631, it is not easy to penetrate the connecting fibers 633, so that the substrate layer 63 can be formed by the surface of the kelly rd film 64 to form a higher wear resistance. The sturdy and non-hookable Table® reinforced structure, the bucking gum 62 is less likely to intrude into the substrate layer 63 and the interior (4) is less affected. See Figure 5, ® 1G and Figure u' when using a single layer of cloth as the substrate layer

― It is also possible to apply a high-molecular polymer melt 62 which is relatively high in viscosity to the surface of the single-layer cloth by the present manufacturing method, so that the film formed by the melt 62 stays only on the surface of the base (63) without oozing. To the inside, due to. The viscosity of Xuan Xuan kick 62 is relatively high. When applied to the surface of a single layer of cloth, the dust wheel 72, which forms a dot pattern with the surface cut and 951, will form a dot-shaped film 64, so that the same can be maintained. The material of the base material layer 63 is transparent to the film to protect the base material layer 63 from being worn by the hook yarn, etc., so that the composite material 60 has high wear resistance, and further, since the _ Μ is

It is made of a thermoplastic copolymerized vinegar or a copolymerized amine, and the composite material 6 can also be used for bonding to other materials by laminating the film 64 to bond the inner and outer layers. Referring to Fig. 12, when a paper material is used as the base material layer 63, the paper material has a bismuth resin layer portion 634 joined to the film 64, and - with the enamel resin layer portion 634 The connected paper layer portion 635 may be used to adhere the side of the thin web 64 not bonded to the base material layer 63 to the first bonding material 65, since the other side of the film 64 is The base resin layer portion 634 is joined, so that the base material layer 63 can be easily peeled off, leaving the thin film 14 4^^4388 64 alone, and then a second bonding material (not shown) is attached thereto. The other side of the film μ, and heating the film 64, the first bonding material 65 and the second bonding material are adhered by the heat-melted viscosity of the film 64, and after cooling and drying, the first bonding The material of the second adhesive material can form a tight joint. The above-mentioned method and method for manufacturing the solvent-free environmentally-friendly thermoplastic thin-twist composite material of the present invention can achieve the following effects and advantages, thereby achieving the object of the present invention: The invention forms the state of the melt 62 by heating the copolyester or the copolymerized guanamine, without using solvent to be blended. The molten rubber 62 is transferred or coated on the base (4) 63Jl by the pressure rollers 72, 95, and then processed by the cold air (four), the composite material (9) to which the film 64 is bonded can be smoothly obtained, and the composite material and the composite material can be obtained. 60 is applied to the inner layer bonding or the outer layer protection' so that the invention does not need to make the timing solvent in the manufacturing process, and has the advantages of being more environmentally friendly and less harmful to the health of the field workers. In the manufacturing method of the present invention, since the solvent is not used in the process, the finished composite material 60 has no problem of residual solvent, so that the composite material 60 produced by the invention is more environmentally friendly and has no harm. The health benefits of the user. 3. The present invention melts the high molecular polymer component 61 by direct heating without using a bath, so that the formed polymer polymer melt enthalpy has a relatively south viscosity value when transferred or coated on the base. When the surface of the layer is crucible, the melt 62 does not easily penetrate into the interior of the substrate layer 63, and the film 64' is formed only on the surface so that the characteristics of the substrate layer 63_member f are less susceptible (Example 15 substrate layer 63) In the case of a cloth, it is less likely to be flexible by the joining of the film 64, and the present invention has an advantage that it is difficult to lose the original material properties of the substrate layer. Match. The manufacturing method of the present invention uses a copolyester or a copolymerized decylamine as a raw material for forming the _64. Compared with the pu raw material of the existing film, the copolymerized vinegar and the copolymerized chelating amine have lower cost, so that the present invention has relatively high energy. The advantage of reducing raw material costs. 5. By the manufacturing method of the present invention, the film 64 can be smoothly formed on the substrate layer 63 without using a solvent, thereby producing the composite material 60, and when the composite material 6 is applied When the outer layer of a wearable product such as a shackle or a shoe last is worn, 'the abrasion resistance of the base material layer can be improved through the film 64', and the hooking is less likely to occur. Since the briquettes 62 do not contain a solvent, they have a high The viscosity, when dried and shaped, has higher abrasion resistance than the substrate layer 63 of the uncoated film (when the substrate layer is tested for abrasion resistance), under the condition of applying 1 kg of pressure, The base material layer 63 of the uncoated film is damaged after rubbing 2G times. 'The composite material 60 produced by the manufacturing method of the present invention can withstand at least 300 times of friction when subjected to a friction test of 1 kg of pressure. In the case of occurrence of breakage, the production method of the present invention has the advantage of being able to produce a composite material having a high abrasion resistance. 6. Since the thin web 64 of the composite material 60 is made of a thermoplastic material, the reheating causes the film 64 to melt and soften, and the composite material 60 can be directly bonded to other materials, which can be conveniently The composite material is applied to the inner and outer layers. Further, when the composite material 6 is discarded, the thin crucible 64 can be melted and softened by reheating for recycling, so that the composite material 60 produced by the invention 16 is easy to be used. Sex. The above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention, that is, the application of the present invention: a simple equivalent change with the scope of the invention and the description of the invention Modifications are still within the scope of the invention. [Simple description of the map]

1 is a flow chart of a method for manufacturing a conventional film composite; FIG. 2 is a schematic view showing a manufacturing process of the prior art manufacturing method; and FIG. 3 is a schematic cross-sectional view showing a film of a composite material produced by a conventional manufacturing method. FIG. 4 is a flow chart of a first preferred embodiment of a method for manufacturing a solvent-free environment-friendly thermoplastic film composite according to the present invention; FIG. 5 is a first preferred embodiment of the present invention; Manufacturing process diagram;

6 is a flow chart of a second preferred embodiment of the method for manufacturing a solvent-free environment-friendly thermoplastic film composite of the present invention; FIG. 7 is a manufacturing process of the second preferred embodiment FIG. 8 is a perspective view showing a substrate layer used in the first and second preferred embodiments in a three-layer mesh pattern; FIG. 9 is a schematic cross-sectional view showing the first and second comparisons. A case where a film of a composite material obtained by a preferred embodiment is bonded to a substrate layer of a three-layer mesh type; FIG. 10 is a perspective view showing the base used in the first and second preferred embodiments. The material layer is a single-layer cloth type, and the film is distributed in a point shape on a surface of the substrate layer, and the surface is distributed in a dot shape. The U-cross-sectional schematic view illustrates the first and second preferred embodiments. The case where the film of the double-layered material is bonded to the substrate layer of the single-layer cloth type; and FIG. 12 is not considered, and the substrate layer used in the second-second preferred embodiment is The case of a paper type that is torn away from the film.

18 1334388

[Description of main component symbols] 60 ••... Composite 75 .·····Squeeze roller 61 .·····Polymer polymer component 76 •....Cooling roller 62 ••... Polymer polymer melt 77 ·...·...cold air drying box 63.........substrate layer 78••...winding roller 631····...beehive mesh layer 91 ••... screw pressure Outlet 632····...bottom part 92 ...··...cold air drying box 633···....connecting fiber 93 •...·...revolving the cruiser 634.···...矽 resin layer part 94... Rubber sheet 635····...connecting fiber 941... gap 64...film 95 ...···pressure roller 65.........·body bonding material 951 ··· _...surface 71... •...screw extruder 96 ···.. ...feed roller 72 .....·pressure roller 97 ...support roller 721··· •...surface 98 ···.. •... squeeze roller 73 •... rubber plate 99 ·····....Cooling roller 731·····Gap 74.......Feed roller 19

Claims (1)

1334388 X. Patent Application Range: Package 1. A method for manufacturing a solvent-free environmentally-friendly thermoplastic film composite comprising the following steps: (〇 provides a granular polymer component, and the polymer component is Selected from copolyester particles or copolymerized amide particles; (η) hot-melting and extruding, the high-molecular polymer component is put into a screw extruder, and heated at a temperature of 敎 to form a high score: a polymer melt, and then the melt Extruding the screw extruder; (n〇 provides a substrate layer conveyed at a predetermined speed, and diverting the polymer gel to the adjacent layer of the substrate layer, ^ matching Applying a predetermined pressure, transferring or coating the high-knife paste onto the bonding surface of the 4 substrate layer; and “wind drying” the substrate layer that has been transferred or coated with glue. Private π 刀丁不物物... Cold wind 1, the material is dried to form a film, and joined with the substrate layer as a composite product., film 2 · According to the application scope of the patent scope, + · The method for manufacturing a solvent-free environmentally friendly thermoplastic film composite according to ^ ^ The injectable polymer component is in the diagram ("), the polymer is in the range of 1S (rc) Into the high molecular polymer (4). Under the condition of 5〇C, the heat form 3 is based on the prescription of the film composite material. Decontamination of the solvent-free environmentally friendly thermoplastic polymer component: / 2 'where 'in step (9), the high molecular polymer polymer melt. Under the condition of C, the heat is formed. 4. According to the scope of the patent application 2 Item, U... Solvent-based environmentally friendly thermoplastic 20 1334388 Method for manufacturing a film composite, preferably, in the step (π), the polymer of the polymer is 20,000 cps~60 000cps. 5. According to the manufacturer of the solvent-free environmentally friendly thermal film composite material described in the 4th edition of the application of the 6th edition of the application, the product, the Gans + clothing & method, in In the step (out), the transport speed of the substrate layer is substantially 15 m/min. 6. According to the scope of the patent, the solvent-free (four) (four) _ film composite manufacturing method 'in the step (4), there is - a pressure roller disposed toward the bottom surface of the substrate layer and the height The molecular polymer viscous glue is firstly guided to the surface of the pressure roller, and the polymer polymer melt adhesive is transferred to the adhesion surface of the substrate layer by the pressure roller. 7. The method for manufacturing a non-solvent_environmental thermoplastic (four) composite material according to item 6 of the scope of the patent application, wherein 'in step (4), further comprising - extending obliquely downward from the screw extruder, and The surface of the pressure roller cooperates to define a gap rubber plate, and the polymer polymer glue adheres to the surface of the pressure roller through the gap and is transferred to the substrate layer through the pressure roller. The end of the face. 8. The method for producing a solvent-free environmentally-friendly thermoplastic film-bonding composite according to claim 7, wherein the temperature range of the rubber sheet is set to 150. (:~250t:' and the temperature range of the pressure roller is also set at 15CTC ~ 250〇C. 9. The method for manufacturing a solvent-free environmentally-friendly thermoplastic film composite according to claim 8 of the patent application scope, wherein In the step, the method further includes: a pressing roller disposed opposite to the pressing wheel with respect to the substrate layer, the substrate layer being conveyed and clamped between the pressing wheel and the pressing roller, The polymer adhered to the surface of the pressure roller is transferred to the bonding surface of the substrate layer by the pressure of the pressing roller relative to the pressure of the pressure roller at 21 1334388. 1 依据 According to the patent application scope In the method for producing a solvent-free environment-friendly thermoplastic plastic film composite, 苴曰 > "the temperature range of the squeeze roller is set at 150. (: ~250. (:. Π, according to the application Patent No. 1 〇 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The layer # degree is between 0.OImm~〇.2mm. 12·«中专利范范(四)u The method for manufacturing a solvent-free environmentally-friendly thermoplastic plastic composite according to the invention, wherein, in the step (4), further comprising a layer on the same side as the pressing roller relative to the substrate layer and disposed in the extrusion Cooling after the round (4), after the polymer sol is pressed and transferred to the substrate layer, the cooling roller is bypassed to cool the polymer polymer melt. The solvent-free environmentally-friendly thermoplasticity described in the above-mentioned item 12: the method for producing a film composite, wherein the temperature range of the cooling light wheel is set at lot: ~40 ° C. 4. 4. According to the patent application -12 The method for manufacturing a solvent-free environment-friendly dog-shaped film composite material, wherein, in the step (4), the substrate layer to which the south molecular polymer rubber compound has been transferred is conveyed into a human-cold air drying box: two blowing The cold air method enables the high-divided polymer to melt and dry the shape: According to the method for manufacturing the solvent-free environmentally friendly thermoplastic 22 1334388 film composite according to the above-mentioned patent application (4), the method further comprises a step (iv) Steps (10 steps (7) It is a winding s, which is a package type that uses a roll of light-receiving wheel to collect the finished product of the composite material and forms a drum. 16· The solvent-free environmentally-friendly thermoplastic u-composite m according to item 5 of the patent scope The method 'where' also includes, in step (10), a rubber plate and a pressure roller extending obliquely downward from the screw extruder, the substrate layer being re-wound through the gap a surface of the pressure roller and having a contact surface abutting the lower end side of the rubber sheet, the polymer polymer melt is first guided to the rubber sheet, and then flows along the rubber sheet The method of manufacturing a solvent-free environmentally-friendly plastic film composite according to claim 16, wherein in the step (4), the method further comprises - facing the base The bottom surface of the material layer is disposed on the pressing rough wheel that moves relative to the pressure roller and applies a helium pressure, and the base material layer first passes the polymer polymer sol to the bonding surface through the gap, and then continues to convey Pressing between the pressure roller and the squeeze (four) wheel to utilize (4) Pro wheel relative to the pressure of the calendar wheel 'polymer melt so that a pressure and a predetermined thickness is then coated on the surface. 18. According to the scope of the patent application, the manufacturer of the film composite is set at 150 ° C ~ 250 ° C 150 ° C ~ 250 ° C. The solvent-free environmentally-friendly thermoplastic method according to Item 7, wherein the temperature range of the rubber sheet is set, and the temperature range of the pressure wheel is also set at 19 · According to the patent application, the manufacturing method of the J 8 film composite material The solvent-free plow environmentally-friendly thermoplasticity described in the item, wherein the temperature range of the extrusion roller 23 1334388 is set at 150 ° C to 250 ° C. 20. According to the method for manufacturing a solvent-free environment-friendly thermoplastic film composite according to claim 19 of the patent application scope, in the step (ill), the two molecules coated on the substrate layer are privately dispersed. A. The thickness of the glue layer of the material melt is between 0.01 mm and 0.2 mm. 21. Manufacture of a film composite according to the scope of the patent application. With respect to the substrate layer, a support roller before the pressure roller is delivered to the pressure roller. The solvent-free environmentally-friendly thermoplastic method described in the above, wherein, in the step (iii), the method further comprises: the support roller is disposed on the same side as the pressure roller and disposed on the s-base layer The second method of manufacturing a solvent-free environment-friendly thermoplastic film composite according to the scope of the patent application No. 2 1 n, +, & - 罕固*1, directly from the 'in step (iii) And a cooling roller which is disposed on the same side of the substrate and disposed behind the pressing wheel with respect to the substrate layer, and the polymer (4) is pressed and coated to the bonding surface The cooling of the parent wheel is bypassed to cool the polymer polymer melt. 23. According to the application method of the solvent-free environmentally-friendly thermoplastic film composite tested in accordance with Article 22 of the patent application scope, 1 兮,, 〃 ' 温度 玄 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷 冷It is set at 10 ° C ~ 40 ° C. Solvent-free environmentally friendly thermoplasticity 2 4 · According to the scope of the patent application, the second part of the household _ _ box-shaped film composite manufacturing method, which, force Fengqu,. 丄β /, Υ 'in the step (lv In the case, the substrate layer which has been coated with the polymer polymer is conveyed into a cold air drying, and the polymer polymer is dried to form the film by blowing cold air. 24 1334388 25. The method for manufacturing a solvent-free environmentally-friendly thermoplastic film composite according to claim 24 of the patent application, further comprising a step (v) after the step (v), the step (v) is a roll The winding is collected by using the winding-receiving wheel to collect the finished product of the composite material and forming a drum-shaped packaging pattern. 26. The method for producing a solvent-free environmentally-friendly thermoplastic film composite according to the patent application scope 5th if**, ^1, wherein the ^~ base layer is selected from the group consisting of Substance: single layer cloth, = - layer mesh cloth, paper and plastic film. 27. The method for manufacturing a bathless type environmentally-friendly thermoplastic film composite according to claim 26, wherein the base (four) is a three-layer mesh-layer mesh having a honeycomb joined to the film. The mesh layer portion, a bottom portion of the ρ5 μ-β phase with the honeycomb layer portion, and a plurality of connecting fibers filled with the connecting fibers between the honeycomb layer portion and the Λ Λ bottom portion. 28. According to the manufacturing method of the solvent-free environmentally-friendly thermoplastic plastic ruthenium film after the application of the patent, Α θ _ lt "中' the substrate layer is made of paper, _ E / film-bonded tantalum resin a layer, and a layer of paper that is connected to the layer of the scorpion. 25