TWI312274B - Method for controlling particular insect pests by applying anthranilamide compounds - Google Patents

Method for controlling particular insect pests by applying anthranilamide compounds Download PDF

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TWI312274B
TWI312274B TW91118098A TW91118098A TWI312274B TW I312274 B TWI312274 B TW I312274B TW 91118098 A TW91118098 A TW 91118098A TW 91118098 A TW91118098 A TW 91118098A TW I312274 B TWI312274 B TW I312274B
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insect pests
particular insect
anthranilamide compounds
controlling particular
application
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TW91118098A
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Philip Lahm George
Frederick Mccann Stephen
Maganbhai Patel Kanu
Paul Selby Thomas
Martin Stevenson Thomas
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Du Pont
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/86—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/72—Hydrazones
    • C07C251/74—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C251/76—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/76—Nitrogen atoms to which a second hetero atom is attached
    • C07D213/77—Hydrazine radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/06—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/06—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D231/08—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with oxygen or sulfur atoms directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/16—Halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings

Description

1-312274 益第〇91118〇98號專利申請案 g中文申請專利範圍替換本(100年3月) 六、申請專利範圍 代基取代：鹵素、CN、SCH3及OCH3 ;位於笨環位 置 2 之 R5 為 ch3、Cl、Br 或 F ; R6 為 F、Cl、、 C1-C4鹵烷基或（：丨-(：4鹵貌氧基；R7為在位置3經選 自F、C1或Br之一取代基取代，及在位置5經選自 Η、F或C1之一取代基取代之吡啶；及r8為η，則R4 位於苯環之位置4時非為c Ν。
2.如申請專利範圍第1項之方法，其中 Α及Β均為〇 ; R7為苯基環或選自下列之5 -或6-員雜芳族環：
各環視情況經1至3個獨立選自R9之取代基取代； Q 為 Ο、S、NH 或 NR9 ;及 W、X、Y及z獨立為N、CH或CR9，但J-3及J-4中W、 X、Y及Z之至少一個為ν。 3.如申請專利範圍第2項之方法，其中 R1、R2及R8均為Η ; R3為視情況經i素、CN、〇CH3或S(0)pCH3取代之C丨-C4 烷基； R4基係在2-位置鍵結； R4為 CH3、CF3、OCF3、OCHF2、CN或鹵素； R5為Η、CH3或鹵素； 79948-1000308.doc 本纸張尺度適用中國國家標準(CNS) Α4規格(210 X 297公爱〉 1312274 申請專利範園 益第〇91118〇98號專利申請案 g中文申請專利範圍替換本(100年3月) R為CH3、CF3或鹵素； R7為苯基或2-,比咬基，各視情況經取代；及 p為〇 〇 4.如申請專利範圍第3項之方法，其中 R為C1-C4统基及R6為CF3。
如申請專利範圍第3項之方法，其中 R為0^-〇4烧基及R6為C1或Br。 如申請專利範圍第1項之方法，其中式丨化合物包含於又 包括有效量之至少一種額外生物活性化合物或藥劑之組 合物中。 7. 如申請專利範圍第6項之方法’其中該至少一種額外生 物活性化合物或藥劑係選自擬除蟲菊酯、胺基甲酸酯、 新菸鹼酸、神經元鈉通道阻斷劑、殺昆蟲亘環内酯、^ _ 胺基丁酸（GAB Α)拮抗劑、殺昆蟲尿素及幼年激素擬物 所成組群。 8. 如申請專利範圍第6項之方法，其中該至少一種額外生 物活性化合物或樂劑係選自阿巴丁（ abamectin) '歐殺松 (acephate)、乙.醯滅譜靈（acetamiprid)、醯胺氟滅 (amidoflumet)(S-1955) ' 愛瓦滅 ir(avermectin)、阿代羅 '/丁（azadirachtin)、谷速松（gzinphos-methyl)、必芬靈 (bifenthrin)、必芬对（binfenazate)、佈芬淨（buprofezin) 、加保扶（carbofuran)、氣芬普（chlorfenapyr)、克福隆 (chlorfluazuron)、陶斯松（chlorpyrifos)、曱基陶斯松、 哈馬芬查（chromafenozide)、羅塞靈咬（clothianidin)、賽 -4 - 79948-1000308.doc 本纸張尺度適用中國國家標準(CNS) A4规格<210X297公釐) 1312274 ^第091118098號專利申請案 盟中文申請專利範圍替換本(100年3月) 六、申請專利範圍
扶寧（cyfluthrin)、冷-賽扶寧、賽洛寧（cyhalothrin)、A -赛洛寧、赛滅寧（cypermethrin)、赛滅淨（cyromazine)、 第滅寧（deltamethrin)、汰芬隆（diafenthiuron)、大利松 (diazinon)、二福隆（diflubenzuron).、大滅松（dimethoate) 、代芬隆（diofenolan)、艾馬滅 ίτ (emamectin)、安殺番 (endosulfan)、益化利（esfenvalerate)、艾普（ethiprole)、 芬硫克（fenothicarb)、芬諾克（fenoxycarb)、芬普帕靈 (fenpropathrin)、芬普（fenproximate).、芬化利 (fenvalerate)、芬普寧（fipronil)、氟尼卡麥（flonicam'id) 、護賽寧（Hucythrinate)、. r -福利松（tau-fluvalinate)、 氟諾寧（flufenerim)(UR-50701)、氣芬諾隆（flufenoxuron) 、大福松（fonophos)、齒芬查（halofenozide)、六伏隆 (hexaflumuron)、益達胺（imidacloprid) 、丨嗓卡 (indoxacarb)·、亞芬松（isofenphos)、盧芬隆（lufenuron) 、馬拉松（malathion)、馬拉路（metaldehyde)、達馬松 (methamidophos)、滅大松（methidathion)、納乃得 (methomyl)、美梭坪（methoprene) 、曱氧’拉草 (methoxychlor)、亞速靈（monocrotophos)、曱氧芬查 (methoxyfenozide)、尼塞井（nithiazin)、諾瓦隆 (novaluron)、諾比氟姆隆乂 noyiflumuron) ( XDE-007)、歐 殺滅（oxamyl)、帕塞隆（parathion)、帕塞隆-曱基、百滅 寧（permethrin)、福瑞松（phorate)、裕必松（phosalone)、 益減松（phosmet)、福賜米松（phosphamidon)、比加普 (pirimicarb)、佈飛松（profenofos)、派滅淨（pymetrozine) 79948-1000308.doc 本纸張尺度適用中國國家標準(CNS) A4規格(210X297公釐) 1312274 bs第091118098號專利申請案 C8 D8中文申請專利範圍替換本(100年3月) 六、申請專利範園
、比利塔（pyridalyl)、百利普芬（pyriproxyfen)、魚藤精 (rotenone)、賓諾殺（spinosad)、螺美辛芬（spiromesifin) (BSN 2060)、舒普發（sulprofos)、得芬諾（tebufenozide) 、得福隆（teflubenzuron)、得芬賓（tefluthrin)、托福松 (terbufos)、樂本松（tetrachlorvinphos)、塞螺比 (thiacloprid)、塞美脫瓦（thiamethoxam)、硫敵克 (thiodicarb)、硫疏特-納（thiosultap-sodium)、泰滅寧 (tralomethrin)、三氣松（trichlorfon)及赛福座 (triflumuron)、得滅克（aldicarb)、歐殺滅（oxamyl)、芬 滅松（fenamiphos)、三亞蜗（amitraz)、滿離丹 (chinomethionat)、克氣苯（c+hlorobenzilate)、錫蜗丹 (cyhexatin)、大克蜗（dicofol)、得氣蜗（dienochlor)、艾 脫 β坐（etoxazole)、芬殺蜗（fenazaquin)、芬佈賜 (fenbutatin oxide)、芬普寧（fenpropathrin)、芬普 (fenpyroximate)、合.赛多（hexythiazox)、歐虫笛多 (propargite)、畢達本（pyridaben)、特芬得（tebufenpyrad) ;及生物藥劑如蘇雲金芽范桿菌（Bacillus thuringiensis) 包含ssp. aizawai及kurstaki，蘇雲金芽范桿菌（5内毒素.、 桿病毒、及蟲致病細菌、病毒及真菌。 9.如申請專利範圍第6項之方法，其中該至少一種額外生 物活性化合物或藥劑係選自赛滅寧（cypermethrin)、賽洛 寧（cyhaloth.rin)、赛扶寧（cyfluthrin)及 /3-赛扶寧、益化 利’（esfenvalerate)、芬化利（fenvalerate)、泰滅寧 (tralomethrin)、芬硫克（fenothicarb)、納乃得（methomyl) -6 - 79948-1000308.doc 本纸張尺度適用中國國家榡準(CNS) A4規格(210 X 297公釐) 1-312274 益第〇9〗118〇98號專利申請案 益中文申請專利範圍替換本(100年3月〉 六、申請專利範圍
、歐殺滅（oxamyl)、硫敵克（thiodicarb)、螺塞啶 (clothianidin)、益達胺（imidacloprid)、塞滅利 (thiacloprid)、Θ 卜朵卡（indoxacarb)、史賓殺（spinosad)、 阿巴汀（abamectin)、阿瓦美ί丁（avermectin)、艾馬美汀 (emamectin)、安殺番（endosulfan)、艾埔（ethiprole)、芬 普尼（fipronil)、氟芬隆（.flufenoxuron)、催氟姆隆 (triflumuron)、代芬簡（diofenolan)、比埔氧芬 (pyriproxyfen)、派滅淨（pymetrozine)、三亞蜗（amitraz) 、蘇雲金芽苑桿菌及蘇雲金芽筢桿菌5内毒素以及昆蟲 致病性真菌。 10.如申請專利範圍第1項之方法，.其中至少一種控制之昆 蟲害蟲係選自Alabama argillacea Hiibner (斜紋夜蛾）、 Archips argyrospila Walker (果樹捲夜蛾）、A. rosana Linnaeus (歐洲捲夜蛾）及其他捲蛾種、Chilo suppressalis Walker (稻水培）、Cnaphalocrosis medinalis Guenee (稻捲夜蛾）、Crambus caliginosellus Clemens (玉米根草棋）、Crambus teterrellus Zincken (早熟褐草 填）、Cydia pomonella Linnaeus (嶺果蠹蛾）、Earias insulana Boisduval (埃及金剛鑽）、Earias vittella Fabricius (翠紋金剛鐵）、Helicoverpa armigera Hubner (美洲金剛鑽）、Helicoverpa zea Boddie (美洲棉铃蟲）、 Heliothis virescens Fabricius (美洲於葉蛾）、 He.rpetogramma licarsisalis Walker (甜菜二星瘤蛾）、 Lobesia botrana Denis & Schiffermiiller (葡萄小食心 79948-1000308.doc 本纸張尺度逋用中固國家標準(CNS) A4规格(210 X 297公釐) 1312274 益第〇91118〇98號專利申請案 漂中文申請專利範圍替換本(100年3月) 六、申請專利範園
蟲）、Pectinophora gossypiella Saunders (紅鈴盖）、 Phyllocnistis citrella Stainton (橘細潛蛾）、Pieris brassicae Linnaeus (大菜粉蝶）、Pieris rapae Linnaeus (小白粉蝶）、Plutella xylostella Linnaeus (小菜蛾）、 Spodoptera exigua Htibner (甜菜夜蛾）、Spodoptera litura Fabricius (斜紋夜蛾、葉蜂幼蟲）、Spodoptera frugiperda J. Ε· Smith (草地黏蟲）、Trichoplusia ni Htibner (粉紋夜蛾）及 Tuta absoluta Meyricjc (蕃兹潛葉 蟲））、Acyrthisiphon pisum Harris (婉豆.坊）、Aphis craccivora Koch (豆財）' Aphis fabae Scopoli (槐财）、 Aphis gossypii Glover (棉財、.甜瓜坊）、Aphis pomi De Geer (蘋果均1 ) ' Aphis spiraecola Patch (總線菊财）、 Aulacorthum solani Kaltenbach (指頂花無網長財管）、 Chaetosiphon fragaefolii Cockerell (草莓财）、Diuraphis noxia Kurdjumov/Morcjvilko (小麥財）' Dysaphis plantaginea Paaserini (蘋粉紅劣财）、Eriosoma lanigerum Hausmann (蘋果棉财）、Hyalopterus pruni Geoffroy (梅大尾財）、Lipaphis erysimi Kaltenbach (蘿 蔔财）、Metopolophium dirrhodum Walker (蕃薇麥财）、 Maerosipum euphorbiae Thomas (莊長管坊）、Myzus persicae Sulzer (桃祐長管財、桃赤财）、Nasonovia ribisnigri Mosley (萵苣财）、痏·棉財（Pemphigus)屬（食根 財.及蟲癭财）、Rhopalosiphum maidis Fitch (玉米溢管 坊）、Rhopalosiphum padi Linnaeus (粟溢財）、 79948-1000308.doc 本紙張尺度適用中國圉家標準(CNS) A4规格(210X297公釐) 1-312274 益第〇91118〇98號專利申請案 S中文申請專利範圍替換本(100年3月) 六、申請專利範園
Schizaphis graminum Rondani (麥二岔财）、Sitobion avenae Fabricius (麥管長財）、Therioaphis maculata Buckton (藉苜斑翅財）、Toxoptera aurantii Boyer de Fonscolombe (橘二叉坊）及 Toxopte-ra citricida Kirkaldy (橘二叉蚜）；瘤球蚜（Adelges)屬（瘤球蚜）；Phylloxera devastatrix Pergande (美桃核根瘤財）；Bemisia tabaci Gennadius (終草粉虱、棉粉風）、Bemisia argentifolii Bellows & Perring (印度棉粉風）、Dialeurodes citri Ashmead (橘黃粉虱）及 Trialeurodes ’vaporariorum Westwood (溫室白—粉致）；Empoasca fabae Harris (馬鈴 薯微葉蟬）、Laodelphax striatelLus Fallen (稻灰核風）、 Macrolestes quadrilineatus Forbes (紫莞葉蟬）、 Nephotettix cinticeps Uhler (大青葉禪）、Nephotettix nigropictus Stal (黑尾葉蟬）、Nilaparvata lugens Stal (稻褐飛風）、Peregrines maidis Ashmead (菲島玉米葉 蟬）、Sogatella furcifera Horvath (白背飛乳）、Sogatodes orizicola Muir (美洲稻飛乱）、Typhlocyba jjomaria McAtee(蘋白小葉輝）、斑葉輝（Erythroneoura)屬（葡萄二 星斑葉輝）；Magicidada septendecim Linnaeus (十七年 蟬）；Icerya purchasi Maskell (吹綿价）、 Quadraspidiotus perniciosus Comstock (果圓纷）； Planococcus citri Risso (粉橘纷）；粉紛（Pseudococcus) 屬（其他粉靖複合體）；Cacopsylla pyricola Foerster (架 黃木風）、Trioza diospyri Ashmead (柿木風）、 -9 - 79948-1000308.doc 本纸張尺度逍用中國國家標準(CNS) A4规格(210X297公釐) 1312274 ' * ^第091118098號專利申請案 适中文申請專利範圍替換本(100年3月) 六、申請專利範圍
Acrosternum hilare Say (喜綠蝽）、Anasa tristis De Geer (南瓜緣缚）、Blissus leucopterus leucopterus Say (麥長 墙）、Corythuca gossypii Fabricius (棉網蝽）、 Cyrtopeltis modesta Distant (棉鈴蟲）、Dysdercus suturellus Herrich-Schaffer (棉紅缚）、Euchistus servus Say (褐臭墙）、Euchistus variolarius Palisot de Beauvois
(一點褐蝽）、小捲蛾（Graptosthetus)屬（·實蜂之複合 體）、Leptoglossus corculus Say (葉足緣.墙）、Lygus lineolaris Palisot de Beauvois (牧草盲缚）、Nezara viridula Linnaeus.(稻綠蝽）、Oebalus pugnax Fabricius (美洲稻盾絲）、Oncopeltus fasciatus Dallas (大馬利筋 長缚）、Pseudatomoscelis seriatus Reuter (棉跳盲缚）、
Frankliniella occidentalis Pergande (蓿苜薊馬）、 Scirthothrips. citri Moulton (橘實薊馬）、Sericothrips variabilis Beach (大豆莉馬）及 Thrips tabaci Lindeman (洋蔥薊馬）、Leptinotarsa decemlineata Say (馬鈐薯曱 蟲）、Epilachna varivestis Mulsant (墨西哥豆瓢蟲）及叩 甲屬、Athous或金針蟲之叩頭蟲）。 11·如申請專利範圍第1項之方法，其中將一組合物以液體 調配物浸透土壌之形式施用，俾使其與植物接觸，該組 合物包含式I化合物，其N -氧化物或其農業適宜鹽。 -10 - 79948-1000308.doc 本纸張尺度適用中囷國家標準(CNS) A4規格(210 X 297公釐)
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