TWI311574B - Manufacturing method of film laminate and manufacturing installation thereof - Google Patents

Manufacturing method of film laminate and manufacturing installation thereof Download PDF

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Publication number
TWI311574B
TWI311574B TW094127266A TW94127266A TWI311574B TW I311574 B TWI311574 B TW I311574B TW 094127266 A TW094127266 A TW 094127266A TW 94127266 A TW94127266 A TW 94127266A TW I311574 B TWI311574 B TW I311574B
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TW
Taiwan
Prior art keywords
film
liquid
polarizing plate
adhesive
light
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TW094127266A
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Chinese (zh)
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TW200610777A (en
Inventor
Nobuyoshi Yagi
Yoshihiro Kameda
Hiroaki Kitagawa
Tsuyoshi Nakamura
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Nitto Denko Corporatio
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Publication of TW200610777A publication Critical patent/TW200610777A/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Fluid Mechanics (AREA)
  • Polarising Elements (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Laminated Bodies (AREA)

Description

if.doc 九、發明說明: 【發明所屬之技術領域】 本發明係’關於在薄膜(mm)之至少— 液設其他薄膜的薄膜積層物的製 =黏^妾 造方法所取得之偏光板,包括該^由該製 顯示裝置。 娜70极之尤學溥犋及圖像 【先前技術】 =’對^經由黏接劑絲著劑之雜 ,之/法’—般係在薄膜塗布黏接液後加以貼人 間等之壓接丰…"黏接液猎由經過-對轉筒_ 此種貼合之際二:t之例如:參照專利文獻υ。 黏接液溢出或流出,黏接 也而部之 成為問題。 越狀在以的_及裝置之污染 對此’在上述專利文獻i係,指 (polarizer)與保護薄膜 、、〜於偏先子 合,由轉筒壓力過旦^ 劑液之供給量過剩之場 加以污毕:二tr劑液從保護薄膜之左右兩端流出 力 薄臈。因此,在下述之專利文獻1係, =護薄膜寬度方向端部:= 亥f吏黏接劑液靠近於寬度中央部的方法。 液由’由^氣之吹喷,特別端部之黏接劑 '〇 *化之關係,偏光子與保護膜不能充份黏 1311獨 if.doc 接固定外,有易成不均勻__1 城^也揭露使由空氣堪靠近於寬度方向中央部之過量 的方法,在此吸引喷嘴之及弓丨喷嘴,_冷除 所供給之水加水喷嘴’由藏供水喷嘴 閉。 .接剑液之固化所引起之吸引口封 但是,供水喷嘴設於吸引喷嘴内之關係 喷::清掃或檢修時係,將清掃工具放進於吸引喷 觜之外。因此,作業成為煩雜。 賀 又,由於使用供水嘴嘴設於吸引噴嘴内,吸引 t吸:空間縮小也有吸引力低降的問題。更且有 水贺嘴所流出之水加以阻害㈣㈣ == 液,有不能順暢吸引的問題。 HP之黏接劍 =且,如上所述,從端部対空氣 糸,不祕在偏舒之兩面貼合健_的上述專利= U方法,由習知方法分取各單㈣㈣有之場合也= 日本細_u侧71號公報。 【發明内容】 本發明係有鑒於上述問題點所進行者,以提供在薄膜 貼合之際’例如使偏光子與保護薄膜加叫合之卜接 液從貼合面漏出者以不固化可能加以防止 f 4按 方法::的。X ’以提供容易清掃 液攸貼合面漏出者以不固化可能加以防^ 、 此之一種薄膜積層 7 13115¾ if.doc 物的製造方法為目的’更且,以提供,由上述製造方法所 得之薄膜積層物,可能利用至端部的偏光板,包括此偏光 板之光學薄膜及圖像顯示裂置為目的。 本申請案發明者等係,為解決上述習知—對 於薄膜積層物的製造方法,由其使用之製造裝置,該製造 方法所得之薄膜積層物,由該製造方法 括偏光板之光學薄膜及圖像顯示裝置加以銳意檢討。其結 果’找出藉由下述構成可解決上述課題以致完成本發明。 的二方t解決上述課題起見’關於本發明之薄膜積層物 積層物的製造方法,其特徵在於,在上述薄膜=少3 ==其他_ ’在上膜與其 =,將抵抗於向薄膜之至少-方的端部流動之黏= 二,’―面從薄膜之至少—方的端部加以供给, 述薄膜與其他薄膜由祕加以貼合。 在上述方法,對於向薄膜 接液’供給對抗之流動液艘的二 ==之黏 貼合所用之轉筒等二:手Γ;可:止薄膜與其他薄膜之 污毕。又,斑= 或’其他薄膜等由黏接液之 生吹喷空氣時之黏接液:止:關係’不產 薄膜^他薄膜確實黏接固化薄膜積=。’可加以製造使 向薄膜i吏ΐ,莫與其他薄膜加以貼合前,係以㈣去r 至方的端部流出之軸液,或由上述^= 1311 ^84pif.d〇c 稀釋之黏接液為宜。 依照上述方法時,使貼合不 去除之關係,在薄臈與其他薄 二;液加以吸引 吸引此種%合_接液之固化。因此,容易加以 度方’使用比上述薄膜寬度較大’在寬 形成範圍内二宜使上述液體之供給以在餘長部之 行,,液體之供給藉由在餘長部之範圍内實 體之稀=防止供給於薄膜與其他薄臈貼合之黏接液由液 声古it上述其他薄膜,使用比上述薄膜寬度較大,在甯 稀釋的黏接液之接液或由上述液體所 行為宜。 |去除以在餘長狀形絲_加以實 以土述方法時,將不供於貼合之多餘黏接液一面 部:盆Ξΐϊί,形成範圍去除之關係,在薄膜之端 W、他4膑以確貫加以壓接固定。 液體’係_可溶解上述黏接液者為宜。 合之黏接出的液體可溶解黏接液時,不供於貼 接液之際稀釋。其結果,在去除多餘之黏 抑制忒黏接液之固化,可使去除容易。 if.doc 以使使用偏光子,並且對於上述其他薄膜 板。猎此’黏接性無不均句,可加以製造面一絲光 的製ί裝決ΐΐ課題起見,關於本發明之薄膜積層物 浐;物二匍二’在溥膜之至少一方的面設其他薄膜之薄膜 製造所使用之薄膜積層物的製造裝置,= 接履仏心手奴係,在上述薄膜與該 其貼合的部份,供給黏驗: ,:丄:=述==二:方 =、、:#合手段係’使上述薄膜與其他薄膜由壓::: 述之構成結構,對於將向其他薄臈之至少古沾 關抗液體之液體 ,轉筒或其他===其他又薄,合 接液之乾燥固化,’不產生以空氣吹嘴時之黏 物。 —果’可加以製造無波紋之薄膜積層 黏接液,或:上述薄膜之至少-方的端部流出之 4由上述液體所稀釋之黏接液的吸引手段=, 13 1 1 5l^4pif.doc 依照上述構成結構時 =化所引起之無法使用的情形。另外黏 供水噴嘴等的關係,可之 :=以=與液體供二= 對於上述作業性。 向具有餘長部的場合,上 :度方 置於餘長部之形购=體(、,遍之达出部分以位 設於藉由將液體供給手段之送出部分 合的黏接液由液體加;γ供給於薄膜與其他薄膜之貼 寬度場述薄膜寬度較大,在 位置於餘長部之形成範^為宜述吸引手段之吸引部分以 形成範二:關:引:段之吸引部分也設於餘長部之 加以去除,置姓果/屬,一面使多餘之黏接液以液體稀釋 接固定:、一果在相之端部與其他_以確實加以黏 該開分係以所定方向成為扇平,以 加以設吸方向與缚膜寬度方向以大略平行之方式 以上述構成結構時,可使吸收部接近於薄膜與其他薄 1311 ^84Pif.d〇c 膜之以良好效率加以吸收黏接液及液體。 膜以使用保;膜:用偏光子,並且,對於上侧 由上述之構成結構,對於磕 4- r i: 黏接性無不均句面内均一之偏= f供能製造 係',在薄本發明之薄膜積層物 上述薄膜與其他__加以=加以供給’一面使 上述構叙_積層物係,對則杨其㈣膜之至 出之黏接液’供給對抗之流動液體,加以防 時,其:====者。即’上述構成 物。又,使黏接液之漏出不由空氣 于之屬膜積層 薄臈與其他_之貼合係無㈣防止之關係, ϊί他=之上貼:係,無由乾燥固化之黏接:::進;ί: ==成之薄膜積層物係,無黏接性不均勻, 又’為解決上述課題起見,關 在偏光子之至少一方的面設保護薄膜之偏=偏= 於’在上述偏光子之至少-方的面配設保“膜 12 'pif.doc 1311 διΤ^ρί 偏光子與保護薄膜之貼合部 於將向保護膜之至少一方的端部;使抵抗 面從保護薄膜之至少一方的立山.出^接液的液體,一 與保護薄膜由擠壓加以貼“,、給’,上偏,子 端構成偏光板係,對於將向保護薄膜<至少-方的 護薄膜之端部漏ί黏加以防止從保 =,_液===時黏 護薄膜之貼止之關係,偏光子與保 ,,, "、、乾屎口化之黏接液加以進行之部分。因 -wf構成之偏向板係’無黏接性之不均勻,面内為均 無波紋。 M 為解決上述課題起見,’本發明之光學薄膜係, 積層之的面設保護薄膜之偏光板至少一片所 予溥膜,在上述偏光子之至少—方的面配設保護 ^膜,在上述偏光子與保護薄膜之貼合部分供給黏接液, =且,使抵抗於將向保護薄膜之至少一方的端部流出之黏 =液岐體,—面從保護薄膜之至少—方的端部加以供 '2^面使上述偏光子與保護薄膜由轉壓加以貼合所取得 者0 又,為解決上述課題起見,關於本發明之圖像顯示置 ^ ’在偏光子之至少一方的面配設保護薄膜之偏光板,又 ^舌°亥偏光板至少一片加以積層的光學薄膜之圖像顯示裝 ,其特徵在於,在上述偏光子之至少—方的面配設保護 13 1311 doc 薄,,偏光子與保護薄膜之貼合部分供給黏接液, 液的液體一面從保方㈣%出之,接 攸侏邊4膜之至少一端部加以供給,_£ 吏处偏光子與保護薄膜由擠壓加以貼合所取得者。 果。本發明係’由上述所說明之手段,可奏出以下述之效 蔣、昆1氣、、關於本發明之薄膜積層物的製造方法時,使 ;Γ^ 均-二積;::可一造無黏接性不均勻,面内 點接,„於本發明之薄膜積層物的製造方法時,使 膜==出由液體加以防止之關係,例 2占合所用之轉筒或,其他薄膜等無由黏接液加3 =一面力•及引去除之關係,可能防止:手= 液體供”上=吏1的情形。更且吸引手段係,與 造㈣成賴係,不需要以複雜構 k於或檢修等之作業性。另外,在吸引手段 等分之周邊或内部不需要設稀釋黏接液之供水噴嘴 4的關係,可圖謀吸引力的提昇與有效率的吸引去除。 液之i::照闞於本發明之薄膜積層物時’-面可使黏接 量液體加以防止,—面在薄膜之端部也供給適當 接液的方式與其他軸加㈣合之_ 不均勻,面内為均一無波紋。 …、If.doc IX. Description of the Invention: [Technical Field] The present invention is a polarizing plate obtained by a method for producing a film laminate of at least a thin film (mm). The device comprising the display device is included. Na 70 Extreme 溥犋 溥犋 图像 图像 先前 先前 先前 先前 先前 先前 先前 = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = 经由 经由 经由Feng..."Adhesive hunting by passing-to-drum _ This kind of fit 2: t for example: refer to the patent document υ. The adhesive overflows or flows out, and the adhesion is also a problem. In the case of the above-mentioned patent document i, the polarizer and the protective film are combined with each other, and the supply of the liquid is excessive by the pressure of the drum. The field is stained: the two tr liquid flows out from the left and right ends of the protective film. Therefore, in Patent Document 1 below, a method in which the end portion in the width direction of the protective film is replaced by the center of the width of the adhesive liquid is determined. The liquid is sprayed by the gas, and the adhesive of the special end is the relationship between the polarizer and the protective film. The polarizer and the protective film cannot be fully adhered to the 1311. If it is fixed, there is a non-uniform __1 city. ^ Also discloses a method of making the air excessively close to the central portion in the width direction, where the nozzle and the bow nozzle are attracted, and the water-adding nozzle supplied by the cold water is closed by the water supply nozzle. . The suction port seal caused by the curing of the sword fluid. However, the relationship between the water supply nozzle and the suction nozzle is: Spraying: When cleaning or repairing, the cleaning tool is placed outside the suction nozzle. Therefore, the work becomes complicated. He also, because the use of the water supply nozzle is located in the suction nozzle, attracting suction: the space is reduced and the problem is attractive and low. Moreover, there is water from the water hemport to prevent it. (4) (4) == Liquid, there is a problem that it cannot be smoothly attracted. HP's bonding sword = and, as mentioned above, the air is smashed from the end, and the above-mentioned patent = U method that is not secretly attached to the two sides of the slanting side is divided by the conventional method (4) (4) = Japan's fine _u side 71 bulletin. SUMMARY OF THE INVENTION The present invention has been made in view of the above problems, and provides a possibility that when a film is bonded, for example, a liquid that is attached to a bonding film and a protective film is leaked from the bonding surface, the curing may be performed without curing. Prevent f 4 by method::. X' is provided by the above manufacturing method for the purpose of providing a method for producing a film laminate 7 131153⁄4 if.doc which is easy to clean and which is leak-proof. The film laminate may be used for the polarizing plate at the end, the optical film including the polarizing plate, and the image display crack. The inventors of the present application have solved the above-mentioned conventional method for producing a thin film laminate, a manufacturing apparatus used therefor, a thin film laminate obtained by the manufacturing method, and an optical film and a polarizing plate according to the manufacturing method. Like a display device for a keen review. As a result, it was found that the above problems can be solved by the following constitutions to complete the present invention. In the case of solving the above problems, the method for producing a laminate of a film laminate according to the present invention is characterized in that the film = less 3 == other _ 'in the upper film and its = will resist the film At least the square end of the viscosity of the flow = two, '- the surface is supplied from at least the end of the film, and the film is bonded to the other film by the secret. In the above method, a tumbler or the like for the adhesion of the two liquids to the film liquid-feeding liquid is provided: the handcuff; the film can be sealed with the other film. Also, the spot = or 'other film, etc., when the air is blown by the adhesive liquid, the adhesive liquid: stop: the relationship 'is not produced. The film ^ the film does adhere to the cured film product =. 'It can be made to make the film i吏ΐ, before it is bonded to other films, the liquid is discharged by (4) r to the end of the square, or the viscosity diluted by the above ^= 1311 ^84pif.d〇c It is advisable to pick up the liquid. According to the above method, the bonding is not removed, and the liquid is attracted to the thin and other thin liquids; Therefore, it is easy to use the 'larger than the above-mentioned film width' in the wide formation range, and it is preferable to supply the liquid to the outer length portion, and the liquid supply is made by the entity in the range of the excess length portion. Dilute = prevent the adhesive liquid supplied to the film and other thin enamel. The other film mentioned above is used, and the width of the film is larger than that of the film, and the liquid of the bonding solution is diluted or immersed by the liquid. . |Removal to the excess length of the wire _ to the actual method of the soil, will not be applied to the excess adhesive liquid one face: basin ί, the formation of the scope of the relationship, at the end of the film W, he 4 膑It is fixed by crimping in a sure manner. It is preferred that the liquid 'system _ can dissolve the above-mentioned adhesive liquid. When the adhered liquid dissolves the adhesive, it is not diluted when the adhesive is applied. As a result, it is easy to remove by removing the excess viscosity and suppressing the curing of the adhesive liquid. If.doc to use polarizers, and for the other film boards mentioned above. Hunting this 'adhesiveness is not uniform, can be made into a silky system. 关于 ΐΐ , , , , , 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜 薄膜A manufacturing apparatus for a film laminate used for the production of a film of another film, = a hand-to-hand slave system, is supplied to the portion where the film is bonded to the film, and is: 丄: = ===二:方=, ,: #合方法系' The film and other films are made of pressure::: The structure is described, for the liquid that will be at least ancient to the other thin sputum, the drum or other === other Thin, dry and solidified with the liquid, 'does not produce sticky substances when blowing with air. - Fruit 'can be made without corrugated film laminating adhesive, or: at least the end of the film outflow 4 of the suction solution diluted by the liquid is the means of attraction =, 13 1 1 5l ^ 4pif. Doc In the case of the above-mentioned structure, it is impossible to use. In addition, the relationship between the water supply nozzle and the like can be as follows: = = = and liquid supply 2 = for the above workability. In the case of having a surplus length portion, the upper side is placed in the shape of the excess length portion (the portion of the adhesive portion which is disposed at the position of the delivery portion of the liquid supply means by the liquid) Adding; γ is applied to the width of the film and the other film. The width of the film is larger, and the formation of the remaining length is the attraction of the attraction means to form the second part: off: lead: the attraction part of the segment Also set in the excess length to remove, set the surname fruit / genus, while the excess adhesive liquid is diluted with liquid to fix: one fruit at the end of the phase and the other _ to be sure to stick to the open line to determine When the direction is fanned, the absorption portion is close to the film and other thin 1311 ^ 84 Pif.d〇c film to absorb the film with the above-mentioned structure in a manner that the suction direction and the width direction of the film are substantially parallel. Adhesive liquid and liquid. The film is used as a film; the film: uses a polarizer, and, for the upper side, the above-mentioned structure, for 磕4-ri: adhesiveness, no unevenness, uniformity of the surface, f = energy supply Manufacturing system', in the thin film laminate of the present invention, the above film and __========================================================================================================= 'The above composition. In addition, the leakage of the adhesive liquid is not caused by the air film in the thin film and the other _ the bonding system is not (four) prevention relationship, ϊί he = above the paste: system, no dry curing接:::入; ί: == into a thin film layer system, non-adhesiveness is uneven, and 'for the purpose of solving the above problem, the protective film is placed on the surface of at least one of the polarizers. Providing a "film 12'pif.doc 1311 διΤ^ρί bonding portion of the polarizer and the protective film to at least one end of the protective film on the surface of at least the above-mentioned polarizer; From the Lishan. At least one of the protective films, the liquid that is connected to the liquid is attached to the protective film by "squeezing", and is applied to the upper end, and the sub-end constitutes a polarizing plate system. For the protective film, at least - The end of the square protective film is leaked and 黏 is adhered to prevent the sticking of the adhesive film from the protective film, _ liquid ===, and the photon is ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, [In the optical film system of the present invention, at least one of the polarizing plates provided with the protective film on the surface of the laminated film is provided with a protective film on at least one side of the polarizer, and the polarizer and the protective film are disposed on the surface of the polarizing film. The bonding portion supplies the adhesive liquid, and, in addition, the surface of the protective film is supplied to the end portion of the protective film by the adhesive portion which is to be discharged to the end portion of at least one of the protective films. In order to solve the above problems, the image display device of the present invention is provided with a protective film on at least one surface of the polarizer. a polarizing plate, and an image display device of at least one optical film laminated thereon, characterized in that at least one side of the polarizer is provided with a protective 13 1311 doc thin, and a photon and a protection The bonding part of the film supplies the bonding solution The liquid from the liquid side of Bulgaria% (iv), then Yau Jurassic edge 4 of the film to be supplied to at least one end, at _ £ officials be a polarizer and the protective film are bonded by the extrusion obtained. fruit. The present invention is a method for producing a film laminate according to the present invention by the means described above, and the method for producing a film laminate according to the present invention is: Γ^ 均-二积;:: Non-adhesive non-uniformity, in-plane point bonding, in the manufacturing method of the film laminate of the present invention, the film == is prevented by the liquid, and the drum or the other film used in the example 2 If there is no relationship between the adhesive solution plus 3 = one side force and the removal, it may prevent: hand = liquid supply "up = 吏 1". The more attractive means are, and the (4) is based on the system, and the workability of complex construction or maintenance is not required. Further, it is not necessary to provide a relationship between the water supply nozzles 4 for diluting the adhesive liquid in the periphery or inside of the suction means, and it is possible to enhance the attraction and the effective suction removal. Liquid i:: When the film laminate of the present invention is used, the '-surface can prevent the amount of liquid from being adhered, and the surface is also supplied with an appropriate liquid at the end of the film to be combined with other shafts (4). Uniform, uniform in-plane without ripples. ...,

Bum: pif.doc 又,依照關於本發明之偏光板時,一面使 出由液體加以防止,一面在偏先早 '妾液之漏 黏接液.的方式與保護薄膜加以貼合二,遽|伊之 勾,面内為均-無波紋。 關仲鞑接性無不均 又,依照關於本發明之光學薄膜時,包括面内均一益 波、、文之偏光板的關係,可提供優於光學特性者。_ ",、 又,依照關於本發明之圖像顯示裝置時 :無波紋優於光學躲之偏光板,紐於絲特 風 薄膜的關係,可提供優於顯示特性者。 尤子 為讓本發明之上述和其他目的特徵和優點能更明顯易 如下下文轉較佳實施例;並配合所關式,作詳細說明 【實施方式】 以下對Γ本發明之實_,—面參照圖1〜圖5加以說明如 二。但’制所不需要之部分加以從略,又為容易侧 起見有以擴大或縮小等加以圖示之部分。 ^先’對關於本發明之薄膜積層物的製造方法,以偏 =為❹以下加以說明。目i係為加以說明關於本發明 之貝_之偏光板的製造方法之斜視圖。圖2係 上述偏光板的製造方法之側面圖,圖3係,將圖 部分擴大的擴大圖。圖4A〜;係,絲關於 置在吸引噴嘴口關σ部分之形狀賴式圖。圖5 係’表示·本實補之偏光板_ 如圖1及圖2所示,首先,在料子_=兩够 15 'pif.doc 配置保護薄膜(其他薄膜 之狀態。以此狀態與保護薄膜;一起偏光子1 之上方向下方以垂直方向加 使偏先子卜從同圖 限定於偏光子1及保護膜2搬送於’在本發明係未必 能適用於水平方向搬送之場合,按昭適^向的場合,也可 上述保護薄膜2係,在寬产方、' 且〶要可加以變更。 偏光子1之寬声較大的搂士 、又方向具有餘長部9,為此 也可使用與偏光子Γ同構==係並非限定於此, 及保護薄《2之詳細情賴於㈣4相。對於偏光子! 在偏光子1與保護薄膜2 人 供給嘴嘴⑽接液供給手段= ’由黏著劑液 給喷嘴11係各配置於偏光7 3 °㈣劑液供 、、口方法係’麟_加㈣ (供 接液3之供▲位|』了抓用滴下法等。黏 以冰〜 置係非特別加以限定,按照適宜需要加 之中:插:列’在貼合部分之近傍,也可從寬度方向 之〒央附近使黏接液3加 尤又 上之貼合部分切從健薄膜2 使黏接液3流向貼 H以滴下’ 需要屮波亚士Ah, 種合,保護薄膜2係, η較上方以所定角度加以傾斜。 位置係也可為複數場所。 Μ更且’滴下 膜分之黏接液3係’在偏光子Η或保護薄 留之^子以形成液滯留12。在通過此液滞 等。每先子1及保護溥膜2可使黏接液3加以塗布於均 16 13115¾ if.doc 黏接液3之供給量、及供給速度等係,按照所使用之 黏接液3的種類或黏度等以適宜加以設定於最適值。 構成黏接液3之黏著劑係,並非特別加以限定,可採 用習知之種種者。例如可舉聚乙烯醇(p〇lyvinyl alcohol)系 黏著劑、聚氨基曱酸酯(polyurethane)系黏著劑、異氰酸酯 (isocyanate)系黏著劑’上述聚乙烯醇系黏著劑與硼酸(b〇ric acid)、石朋砂(borax)、戊二醒_(giutaraidehyde)、密胺(melamine) 及草酸(oxalic acid)等之水溶性架橋劑所構成之黏著劑 ❿等。考慮與偏光子1之黏接性最好者時,以使用聚乙烯醇 為宜。在此聚乙烯醇之平均聚合度係以1〇〇〇〜5〇〇〇為宜, 更好為1500〜4000。又,皂化度係以90〜1〇〇摩爾(m〇1)為 宜。構成黏接液3之溶媒係,一般可例示水等。又,接照 需要也可摻合其他添加劑或酸等。 又,對於上述黏接液3之構成也可使用黏著劑。對於 黏著劑係並非特別加以限定,可採用習知之各種。 ^又,上述黏接液之黏度係以在1〜lOOOmpa.s之範圍為 • f,更好係在1〜100mPa.s之範圍。在上述範圍時,黏接液 各易流出於保護膜2之端部,有容易得到本發明之效果 優點。 、"在此,對於將向保護膜2之兩端側流動之黏接液3, 以從保護膜2之兩端側向寬度方向之中央部分的方式供給 ’夜體6。液體6之供給係’使用供給噴嘴(液體供給手段^ 加以實行。供給喷嘴5係各配置於保護薄膜2之左右方。 此係,以偏光子1及保護薄膜2以平行於水平方向之方式 17 13115神if doc :=右:也水平之關係,多餘之黏接 膜2以傾·===但’偏光子1及保護薄 ρ.Λ§ΛΟ , '方所配置之%5或,一對轉筒4 (後述) 傾斜之之場合雜合部分也按照其傾斜情形加以 、” ,、’黏接液3係流動於一方。因此, 使供給噴嘴僅西?署认私垃、" ⑽婦场合係 之/I f於雜液3之下_就足夠。由液體6 U向保被溥膜2之兩端側流動之Bum: pif.doc Further, according to the polarizing plate of the present invention, one side is prevented from being liquid, and the protective film is attached to the first surface of the liquid immersion liquid. Yizhi hook, the inside is uniform - no ripples. In addition, in the case of the optical film of the present invention, the relationship between the in-plane uniform wave and the polarizing plate of the present invention can provide advantages over optical properties. _ ", and, in accordance with the image display device of the present invention: no ripple is superior to the optically hiding polarizing plate, and the relationship between the neon and the wind film can provide superior performance characteristics. The above and other objects and advantages of the present invention will be more apparent and will be hereinafter described in the following preferred embodiments; and the detailed description will be made in conjunction with the related embodiments. [Embodiment] The following is a simplification of the present invention. The second embodiment will be described with reference to Figs. 1 to 5 . However, the parts that are not required for the system are omitted, and those that are shown in the form of enlargement or reduction are easy to be seen. The method for producing the film laminate of the present invention will be described below with a bias = ❹. The present invention is a perspective view for explaining a method of manufacturing a polarizing plate according to the present invention. Fig. 2 is a side view showing a method of manufacturing the polarizing plate, and Fig. 3 is an enlarged view showing an enlarged view of the drawing. Fig. 4A is a view of the shape of the wire with respect to the portion of the suction nozzle opening σ. Figure 5 is a representation of the polarizing plate of the actual compensation _ as shown in Figure 1 and Figure 2, first, in the material _ = two enough 15 'pif.doc to configure the protective film (other film state. This state and protective film In the direction of the polarizer 1 above, the vertical direction is added in the vertical direction, and the polarizer 1 and the protective film 2 are transferred from the same figure to the case where the invention is not necessarily applicable to the horizontal direction. In the case of the directional direction, the protective film 2 may be used in a wide range of production, and it may be changed. The widened sounder of the polarizer 1 and the excess length 9 in the direction may also be used. The use of the isomorphism with the photon = == is not limited to this, and the protection thin "2 details depends on the (four) 4 phase. For the polarizer! In the polarizer 1 and the protective film 2 person supply nozzle (10) liquid supply means = 'The nozzles 11 are placed in the polarized liquid 7 3 ° (four) agent liquid supply, and the mouth method is 'Lin _ plus (four) (for the liquid supply 3 for the ▲ position | 』 抓 抓 抓 抓 抓 抓 抓 抓Ice ~ The system is not specifically limited, according to the need to add: insert: column 'in the close part of the fit, also The adhesive layer 3 can be cut from the vicinity of the center of the width direction, and the bonding portion of the bonding liquid 3 can be cut from the health film 2 so that the bonding liquid 3 flows to the surface to be dripped, and it is required to be dripped, and the protective film 2 is required. The η is inclined at a predetermined angle from the upper side. The position system can also be a plurality of places. The 黏 and the 'dropping film of the bonding liquid 3 series' are left in the photoreceptor or the protective thin to form a liquid retention 12 . Through the liquid stagnation, etc., each of the precursor 1 and the protective ruthenium film 2 can be applied to the supply amount of the adhesive solution 3, and the supply speed, etc., according to the viscosity used. The type of the liquid contact 3, the viscosity, and the like are appropriately set to an optimum value. The adhesive system constituting the adhesive liquid 3 is not particularly limited, and various conventional ones can be used. For example, polyvinyl alcohol (p〇lyvinyl alcohol) can be used. Adhesive, polyurethane adhesive, isocyanate adhesive 'The above polyvinyl alcohol adhesive and boric acid (b〇ric acid), stone sand (borax), pentylene Water solubility of _(giutaraidehyde), melamine and oxalic acid Adhesive agent composed of a bridge agent, etc. When considering the best adhesion to the polarizer 1, it is preferred to use polyvinyl alcohol. The average degree of polymerization of the polyvinyl alcohol is 1 〇〇〇 5 〇. Preferably, it is preferably 1500 to 4000. Further, the degree of saponification is preferably 90 to 1 Torr (m 〇 1). The solvent system constituting the bonding liquid 3 is generally exemplified by water, etc. Other additives, acids, etc. may be blended as needed. Further, an adhesive may be used for the configuration of the above-mentioned adhesive liquid 3. The adhesive system is not particularly limited, and various conventional ones may be employed. Further, the viscosity of the above-mentioned adhesive liquid is in the range of 1 to 100 μmpa.s, and is preferably in the range of 1 to 100 mPa.s. In the above range, the adhesive liquid easily flows out to the end portion of the protective film 2, and the effect of the present invention can be easily obtained. In the case of the adhesive liquid 3 which flows to the both ends of the protective film 2, the night body 6 is supplied from the both end sides of the protective film 2 to the central portion in the width direction. The supply of the liquid 6 is carried out using a supply nozzle (a liquid supply means). The supply nozzles 5 are disposed on the left and right sides of the protective film 2. This is a mode in which the polarizer 1 and the protective film 2 are parallel to the horizontal direction. 13115 god if doc := right: also horizontal relationship, excess adhesive film 2 to pour ==== but 'polarizer 1 and protection thin ρ.Λ§ΛΟ, 'Party configured %5 or a pair When the drum 4 (described later) is tilted, the hybrid part is also applied according to the tilting condition, "," the adhesive liquid 3 flows to one side. Therefore, the supply nozzle is only allowed to be private, " (10) In the case where the /I f is below the liquid 3, it is sufficient. The liquid 6 U flows toward the both ends of the film 2

在餘長部9之範圍㈣住,可防止黏餘3之漏/。係’ 3之之吐出量。吐出壓係有需要在可輯住黏接液 、車巳圍内。液體6之吐出量多於需要以上時,黏接液3 被稀釋有導致黏接性之低降。又,液體6之吐出方向係 限於向寬度方向之中央部分方向,在可能堵住黏接液3、之 流出範圍内可能有各種變更。 在此,供給噴嘴5係,其供給口 7以位置於比保護骐 2之左古兩端側較在寬度方向内側,即在餘長部$之形成 範圍内的方式加以設置。藉此,液體6加以防止從保護膜 2之左右兩側的漏出。又,防止液體6供給於貼合部分,、 防止在貼合部分之黏接液3的稀釋。其結果,在偏光子丄 之兩端部也可能供給充分量之黏接液3,在偏光子丨之端 部保護薄膜2也可能以確實加以黏接固定。 對於上述液體6係,如可溶解上述黏著劑時並非特別 加衫限定A具體上係,可例示例如曱醇(methanol),乙醇 (et%ii〇l) .':丙醇(propyiaic〇h〇l)等之醇類、丙酮⑽伽加)、 曱基乙基曱酮(methyl ethyl ketone)等之酮類、苯 18 f.doc 131 im (benzene)、甲苯(toluene)、二曱苯(xylene)等之芳香烴 (aromatic hydrocarbon)類、二氣甲烧(methyiene chl〇ride)、 三氯甲烷(chloroform)等之有機溶媒或水。 又,在關於本實施例之製造裝置係,如圖3所示,為 吸引去除不貢獻於偏光子1與保護薄膜2之貼合的多餘黏 接液3設吸引喷嘴(吸引手段)8。藉此,將貼合最適量之黏 著劑液以無不均勻,可供給於偏光子丨之到左右兩端的全 面,其結果,在面内黏接性無不均勻可得面内均一之偏光 板。尚且’吸引喷嘴8係,更詳細說並非吸引多餘之黏接 液3,加以吸引由液體6所稀釋狀態之黏接液3。In the range (4) of the excess length section 9, it is possible to prevent leakage of the residual 3 . The amount of spit out of '3'. The discharge pressure system needs to be able to cover the adhesive liquid and the rim. When the discharge amount of the liquid 6 is more than necessary, the adhesive liquid 3 is diluted to cause a low drop in the adhesiveness. Further, the discharge direction of the liquid 6 is limited to the central portion in the width direction, and various changes may be made in the range in which the adhesive liquid 3 may be blocked. Here, the supply nozzle 5 is provided such that the supply port 7 is positioned inward in the width direction from the left end side of the protective cymbal 2, that is, in the formation range of the excess length portion $. Thereby, the liquid 6 is prevented from leaking from the left and right sides of the protective film 2. Further, the liquid 6 is prevented from being supplied to the bonding portion, and the dilution of the bonding liquid 3 at the bonding portion is prevented. As a result, a sufficient amount of the adhesive liquid 3 may be supplied to both end portions of the polarizer 丄, and the protective film 2 may be adhered and fixed at the end portion of the polarizer 丨. For the liquid 6 system described above, if the above-mentioned adhesive is dissolved, it is not particularly limited to a specific one, and examples thereof include, for example, methanol and ethanol (et% 〇l). ':propanol (propyiaic〇h〇) l) Alcohols such as acetone, acetone (10) gamma), ketones such as methyl ethyl ketone, benzene 18 f.doc 131 im (benzene), toluene, xylene Or an organic solvent such as aromatic hydrocarbons, methyiene chl〇ride, chloroform or water. Further, in the manufacturing apparatus of the present embodiment, as shown in Fig. 3, a suction nozzle (suction means) 8 is provided for sucking and removing the excess adhesive liquid 3 which does not contribute to the bonding of the polarizer 1 and the protective film 2. Thereby, the optimum amount of the adhesive liquid can be applied without unevenness, and can be supplied to the entire left and right ends of the polarizing photon, and as a result, the in-plane adhesiveness is uneven, and the in-plane uniform polarizing plate can be obtained. . Further, the suction nozzle 8 system is not particularly attracted to the adhesive liquid 3 which is attracted by the liquid 6 by attracting the excess adhesive liquid 3.

液3時,順暢之吸引被阻害外,不久黏接液3 堵塞吸引口 10。 M 在此,吸引喷嘴8係、,以位置於餘長部9之範圍内之 方式加以《置。為黏接液3由液體6所稀釋之狀態加 2卜又’吸引口 1G如設於偏光子i之端部 部黏接液3由液體6加以稀釋之關係,至少在端 『2之黏接變成:充分。尚且,吸引噴嘴 二:: 5以個別加以配置的關係’可將結構加 供 容易清掃或檢修。 a早化。因此, 對於上述吸引口 10之開口部分的开 定方向為宜。開口部分之此種形狀例如:圖糸扁平於所 示,可例示橢圓、半圓形、長方形、角 〜圖二所 加工之長方形、扁平狀之菱形,扁平狀之上形狀倒棱 又,開口部分之爲平方向係以與寬度方略平彳^^ 19 1311 ^84Pif.d〇c 加以配置吸引口 i〇為宜。藉此,可使吸引口 i〇接近於偏 光子1與保護膜2之貼合部分’使多餘之黏著劑13及液於 6以有效率的加以吸引去除。In the case of liquid 3, the smooth suction is blocked, and soon the adhesive 3 blocks the suction port 10 . M Here, the suction nozzle 8 is placed so as to be positioned within the range of the excess length portion 9. For the state in which the adhesive liquid 3 is diluted by the liquid 6, a state is added, and the suction port 1G is diluted with the liquid 6 in the end portion of the polarizer i, and at least the bonding at the end 2 It becomes: full. Also, the suction nozzles 2:: 5 are individually configured to provide a structure that can be easily cleaned or overhauled. a early. Therefore, it is preferable that the opening direction of the opening portion of the suction port 10 is appropriate. Such a shape of the opening portion is, for example, flat as shown in the figure, and can be exemplified by an ellipse, a semicircle, a rectangle, a rectangle of the angle ~ FIG. 2, a flat diamond shape, a flat shape, a chamfered shape, and an opening portion. It is suitable to arrange the suction port i to the flat direction and the width of the square 彳 ^^ 19 1311 ^84Pif.d〇c. Thereby, the suction port i is brought close to the bonding portion of the polarizer 1 and the protective film 2, so that the excess adhesive 13 and the liquid 6 are efficiently sucked and removed.

” -人,偏光子1及保護膜2係,以重疊之狀態連續導 引至一對轉筒(貼合手段)4之間。通過轉筒4間^光子、ι 及保護薄膜2,由轉筒壓力以確實加以黏接固定。在此, 對於轉筒4係,並非制加以限定,可採用習知之各種。 但是,為使製造之偏光板4的外觀成為良好起見係,以面 精度高之轉筒為宜。又,對於轉筒4之材質係並非特別加 以限定,例如可例示金屬或橡膠等。尚且,對於貼合手段 係轉筒4之其他也可使用平面狀之擠壓手段。 〇 又 由上述方法所得之關於本實施例的偏光板(薄膜積層 物)21係,如圖5所示,在偏光子丨之㈣各加以積層保 護薄膜2之構成。X,具有在兩端部保護薄膜2彼此以餘 長部9加以黏接之結構。 偏光子1係,在親水性高分子適宜進行膨潤、染色、 延伸、架橋等之處理加以製造。對於親水性高分子係,從 在染色製程之蛾或二色性染料的良好定向性—般雖使用聚 乙烯醇(polyvinyl alchol),在本發明並不特別加以限定。 具體上係例如,可例示聚乙烯醇系薄祺、部分曱縮醛 (formal)化聚乙烯醇系薄膜、聚對笨二曱酸乙二醇酯 (polyethylene terephthalate)系薄膜、乙烯乙酸乙^共^ 物(ehylene-vinyl acetate copolymer)系薄膜,此等之告;八 碱化薄膜、在纖維素(ce腕⑽)*薄膜等之高分子薄= 20 1311574* 以聚乙烯醇之脫水處理物或聚氯化烯(polyvinyl chloride) 脫鹽酸處理等的聚乙烯(p〇lyethylene)系定向薄膜等。 在延伸上述親水性高分子之場合係,使總延伸倍率設 定於3倍至7倍之範圍為宜,更好係設定於4倍至6倍之 範圍。總延伸倍率在未滿3倍之場合係困難取得高偏光度 之偏光板,超過7倍之場合則薄膜有容易破裂之傾向。在 此親水性高分子係,在膨潤、染色、延伸、架橋等之全製 程使總延伸倍率以慢慢延伸到3倍至7倍之範圍也可,也 籲可僅在任何-製程純延伸,在同―製程以複數次加以延 伸也可。 又,偏光子之厚度係不特別加以限制。但一般為 5〜80μιη程度。 對於形成上述保護薄膜2之材料係’以善用優於透明 性、機械強度、熱穩定性、均質性等之聚合物薄膜。具體 上係’可舉例如聚對本一曱酸乙二醇酯(polyethylene terephthalate)或聚本二酸二乙酉旨(p〇iyethyiene naphthalate) 馨 專之t酉日(P〇lyest〇r)糸聚合物、聚苯乙烤(p〇iyStyrene) 或丙細猜-本乙細共聚物(acrylonitrile-styrene copolymer ) (AS樹脂)等之苯乙烯(styrene)系聚合物、二乙酰基纖 維素(diacetyl cellulose )或三乙酸纖維素(triacetyl cellulose)專之纖維素糸聚合物、聚縫;g風(p〇iysulfone) 系翏會物、承碳酸酯(polycarbonate)系聚合物、聚酰胺 (polyamide)糸聚合物、聚酿亞胺(p〇iyimide)系聚合物、 聚烯烴(polyolefine)系聚合物、或者聚曱基丙烯酸甲酯 21 I if.doc (polymethyl methacrylate )等之丙烯基(acryl)系聚合物 等。又,可舉聚乙烯(polyethylene )、聚丙烯 (polypropylene )、具有環(cyclo )系乃至降冰片烯 (norbornene )結構之聚烯烴(polyolefine )、如乙稀-丙 烯共聚物(ethylene-propylene copolymer )之聚稀烴 (polyolefine)系聚合物、氯乙烯(vinyl chloride)系聚合 物、尼龍(nylon )或芳香族聚酰胺(polyamide )等之酰 胺(amide )系聚合物、亞氨基(imido )系聚合物、颯(suifon ) φ 系聚合物、聚醚石風(polyether sulfone)系聚合物、聚醚醚 酮(polyether ether ketone )系聚合物、聚苯硫醚 (polyphenylene sulfide)系聚合物、乙烯醇(Vinyi aich〇i) 糸聚合物、偏二氯乙烯(vinylidene chloride )系聚合物、 聚乙烯醇縮丁酸(vinyl butyral )系聚合物、芳基化物 (arylate)系聚合物、聚氧曱稀(polyoxymethylene)系聚 合物、環氧(epoxy)系聚合物、或者上述聚合物之摻合物 (blend)等。可舉其他丙烯基(acryl)系、氨基曱酸乙酯 φ (urethane)系、丙烯基氨基甲酸乙酯系、環氧系或者硅酮 (silicone)系等之熱硬化或紫外線硬化型樹脂等。. 又’在日本專利特開2001-343529號公報(w0 01/37007)所記載之聚合物薄膜,例如,可舉含有在a側 鍵具有取代及/或非取代亞胺基(imido)之熱可塑性樹脂 與1’丨在马‘外雜具有取代及/或非取代苯基(phenyl)以及梢 基{nitrWX熱可塑性樹脂的樹脂組成物。對於具體例可 舉含有異丁烯(is〇butylene)與N-甲基馬來酸酐縮亞胺 22 •pif.doc (N-methyl maleimide)所構成之交替共聚物與丙睛_苯乙稀 (acrytonitrile-styrene)共聚物的樹脂組成物之薄骐' 此等薄 膜係可使用從樹脂組成物之混合擠壓品所構成之薄膜 '。此 等薄膜係相位差小,光彈性係數小之關係可消除 之歪斜的不均勻等之不適合情況,又透濕度較 優於加濕耐久性。 對保護薄膜2係,相位差盡可能以愈小愈好。又,考 慮有關觀點與偏光特性及耐久性等時,以使用纖唯素系聚 春合物為宜。更且纖維素系聚合物中以三乙酸纖維素為ς 適,又’也可使用由含有微粒子其表面形成為微細凹凸二 構之保護薄膜2。 、 又,保護薄膜2之厚度以1()一以下者較好,更好在 60_以下。例如,薄型偏光板之場合,可使用厚度卿以 程度之三乙酸纖維素(TAC)。此種場合,比通常之偏光 板(厚,80陶之TAC)由本發明之抑制旋度(curi)效 果為較南。總厚度(偏光板之厚度)較薄無剛性之份上, 鲁由偏光板之水分變動容易受旋度之影響。保護薄膜2之透 濕度係’以使用400〜l_g/rrf 4h之範圍内者為宜。雖缺 透濕度在上述範圍外,在使用具有比較透濕度高之保靜 的偏光板時本發明之抑制旋度的效果為較高。透渴度係, 依照脱0208之透濕度試驗(杯模法(cup method)),以 4〇C、9〇%之相對濕度差’使面積J此試料在24小 通之水蒸参的克(g〕數。 又’设於偏光子1之兩面之各保護薄膜2係可使用各 23 I if.doc =同聚合物加以形成者,由不同聚合物封料等所構成 又’使保護薄膜2僅貼合於偏光子】之 力:以貼合之場合,在該他方之面,也:二 ,J ( 叫層之製程或反射防止處理、黏合 防止或擴散以至遮光—細)為目的之處 係為防止偏歧表面之受傷 者。例如,由丙歸基系、硅㈣、等之適 度特性等之硬化皮臈藉由附力二二 Μ 2之表面的方式等加以形成。又, 光板表面之外光的反射防止為目的所施予者,;由:= 知之反射防止臈等的形成加以達成。又, 二 為防止與鄰接層黏合為目的所施予。、口 处王係 :遮:處理係在偏光板之表面為防止由外光之反射阻 ^偏光板透射光之視認㈣目的所料者。例如,由 方式或模壓加卫(_⑽_)方式之粗面化 ^式厂伽微好之摻合方鱗之射方式糾在保護 ^之表面附與微細凹凸構造加以形成。上述表面微細凹凸 構造形成之際所含之微粒子係可使用例如 :乳化錯(zlrconia)、氧化錫 、氧化銦、氧化 2、氧化録等所構成之也有導電性之無機系微粒子、由竿 橋或未架橋之料物等賴成之麵性齡子㈣透明微 24 13115¾ pif.doc 粒子。在形成表面微細凹凸構造之場合,微粒子之使用量 係對於开^成表面凹凸構造之透明樹脂丨⑻重量部一般係以 产里部程度’以5〜50重量部為宜。遮光層係以兼使 透射光加以擴散將視角等擴大之擴散層(視角擴大 機月b等)者也可。 料述反射防止層、黏合防止層、硬塗層、擴散 先料,係以可設於保護薄膜2以外,也可與保護 溥膜2以另外設成為另項之光學機能層。 與機實施例之偏光板21係’‘用途等也可以使光 于枝月匕層加以積層之光學薄膜(未圖示)加以使用。 學魏層並__。例如,在偏光板 ^ θ黏接光學機能層加以使狀場合係,可例 :=:(包含1…4波長薄膜等)等。此等薄膜 Λ用—層或兩層以上。例如,在本發明之 差薄膜,以橢圓偏光板或圓偏光板 光學機能層在使用視野擴大薄膜之場合係, 野角之偏光板。 4㈣加以積層時,可得廣視 反射型偏光板係,在偏井叔9 使從視認側(顯示側)之人射=4射層者,可適用於 晶祕反射型偏光板射顯示之反射型液 與相反侧之保護薄膜2附設由金:二:::層所積層之側 適宜方式加以實行。例如,可^相構成之反射層等之 舉在視需要加以消光(mat) 25 'pif.doc 處理之保護薄膜等之單面附設由鋁等之反射性金屬所構成 膜之箔或蒸鍍膜。又,上述保護薄膜2之含有微粒子的表 面微細凹凸構造上面以蒸鍍方式或電鍍方式等之適宜方式 加以附設金屬反射層者等。上述微細凹凸構造之反射層 係’使入射光由漫反射加以擴散以防止反映或漫反射,具 有抑制明暗之不均勻的優點等。又,含有微粒子之保護薄 膜2係’也具有在入射光及其反射光各透射之際被其擴散- The person, the photon 1 and the protective film 2 are continuously guided to each other between the pair of drums (adhesive means) 4 in an overlapping state. The photon, the protective film 2, and the Here, the drum 4 is not limited to the structure, and various conventional ones can be used. However, in order to make the appearance of the manufactured polarizing plate 4 a good one, the surface precision is high. Further, the material of the drum 4 is not particularly limited, and examples thereof include metal or rubber, etc. Further, a flat pressing means may be used for the bonding means of the drum 4. Further, the polarizing plate (thin film laminate) 21 of the present embodiment obtained by the above method is formed as shown in Fig. 5, and the protective film 2 is laminated on each of the polarized photo defects (X). The protective film 2 is bonded to the excess length portion 9. The polarizer 1 is produced by treating the hydrophilic polymer with swelling, dyeing, stretching, bridging, etc., for the hydrophilic polymer system. Process moth or dichroic dye The directionality is generally not limited to the one used in the present invention. Specifically, for example, a polyvinyl alcohol-based thin enamel or a partially acetal-formed polyvinyl alcohol system can be exemplified. Film, polyethylene terephthalate film, ehylene-vinyl acetate copolymer film, etc.; octagonalized film, in cellulose ( Ce wrist (10))* Thin film such as thin film = 20 1311574* A polyethylene (p〇lyethylene) oriented film such as a dehydrated material of polyvinyl alcohol or a dechlorination treatment of polyvinyl chloride. When the hydrophilic polymer is extended, it is preferred to set the total stretching ratio in the range of 3 to 7 times, more preferably in the range of 4 to 6 times, and the total stretching ratio is less than 3 times. It is difficult to obtain a polarizing plate with a high degree of polarization. When the polarizing plate is more than 7 times, the film tends to be easily broken. In this hydrophilic polymer system, the total stretching ratio is gradually extended in the whole process of swelling, dyeing, stretching, bridging, and the like. Up to 3 times to The range of 7 times is also acceptable, and it is also possible to extend only in any process, and it is also possible to extend the same process in multiple times. Further, the thickness of the polarizer is not particularly limited, but is generally about 5 to 80 μm. The material for forming the protective film 2 described above is a polymer film which is superior to transparency, mechanical strength, thermal stability, homogeneity, etc., and specifically, for example, polyparaben glycolate (for example) Polyethylene terephthalate) or polypyridyl diacetate (p〇iyethyiene naphthalate) 专 专 ( ( (P〇lyest〇r) 糸 polymer, polystyrene (p〇iyStyrene) or accompaniment - this B a styrene polymer such as acrylonitrile-styrene copolymer (AS resin), a cellulose phthalate polymer of diacetyl cellulose or triacetyl cellulose, Poly sewn; g wind (p〇iysulfone) system, polycarbonate polymer, polyamide polymer, polystyrene (p〇iyimide) polymer, polyolefin ( Polyolefine An acryl polymer such as a compound or a polymethyl methacrylate 21 I if.doc (polymethyl methacrylate). Further, a polyethylene, a polypropylene, a polyolefin having a cyclopentene or a norbornene structure, such as an ethylene-propylene copolymer may be mentioned. An amide polymer such as a polyolefine polymer, a vinyl chloride polymer, a nylon or an aromatic polyamide, or an imido polymerization.飒, if (suifon) φ polymer, polyether sulfone polymer, polyether ether ketone polymer, polyphenylene sulfide polymer, vinyl alcohol (Vinyi aich〇i) 糸 polymer, vinylidene chloride polymer, polyvinyl butyral polymer, arylate polymer, polyoxon (polyoxymethylene) polymer, epoxy polymer, or a blend of the above polymers. Other examples of the acryl-based, urethane-based, acryl-based urethane-based, epoxy-based or silicone-based heat-curing or ultraviolet-curable resins may be mentioned. The polymer film described in Japanese Patent Laid-Open Publication No. 2001-343529 (w0 01/37007), for example, includes a heat having a substitution and/or an imido group in the a-side bond. A resin composition of a plastic resin having a substituted and/or unsubstituted phenyl group and a base {nitrWX thermoplastic resin. Specific examples include an isobutylene (is〇butylene) and an N-methyl maleic anhydride imide 22 • pif. doc (N-methyl maleimide) alternating copolymer and acrylonitrile (acrytonitrile- A thin film of a resin composition of a styrene copolymer can be used as a film composed of a mixed extrusion of a resin composition. These films are small in phase difference, and the relationship between the small photoelastic coefficient can eliminate the unsuitability of the skew unevenness, etc., and the moisture permeability is superior to the humidifying durability. For the protective film 2, the phase difference is as small as possible. Further, in consideration of the viewpoint, the polarizing property, the durability, and the like, it is preferred to use a fibrin-based polyvalent compound. Further, in the cellulose-based polymer, cellulose triacetate is suitable, and a protective film 2 formed of a fine concavo-convex structure including fine particles may be used. Further, the thickness of the protective film 2 is preferably 1 () or less, more preferably 60 or less. For example, in the case of a thin polarizing plate, cellulose acetate (TAC) having a thickness of a degree can be used. In this case, the curric effect of the present invention is more south than that of the conventional polarizing plate (thickness, TAC of 80 terra). The total thickness (thickness of the polarizing plate) is thinner and has no rigidity, and the moisture variation of the polarizing plate is easily affected by the degree of rotation. The moisture permeability of the protective film 2 is preferably in the range of 400 to l_g/rrf 4h. Although the moisture permeability is outside the above range, the effect of suppressing the curl of the present invention is high when a polarizing plate having a relatively high moisture permeability is used. Through the dehumidification system, according to the moisture absorption test of 0208 (cup method), the relative humidity difference of 4〇C, 9〇% is used to make the area J of this sample in the water of 24 small pass steamed (g) number. Further, each of the protective films 2 disposed on both sides of the polarizer 1 can be formed by using each of the 23 I if.doc = the same polymer, and is composed of different polymer seals and the like. 2 The force applied only to the polarizer: for the purpose of bonding, on the other side, also: 2, J (called layer process or reflection prevention treatment, adhesion prevention or diffusion, and even shading - fine) In order to prevent the injured person on the surface of the eccentricity, for example, a hardened skin which is moderately characteristic such as a silicon base, a silicon (four), or the like is formed by attaching a surface of the second twentieth 2 or the like. The reflection of the light outside the surface is prevented for the purpose of the object; the formation of the 臈 is prevented by the reflection of the = 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 : The treatment is on the surface of the polarizing plate to prevent the reflection of light from the polarizing plate by the reflection of external light. For example, the method of squeezing and squeezing (_(10)_) is used to form the surface of the protective surface with the fine concavo-convex structure. For the fine particles contained in the formation of the fine concavo-convex structure, for example, inorganic microparticles which are composed of emulsification, tin oxide, indium oxide, oxidation, oxidation, etc., which are also electrically conductive, or by bridge or The material of the bridging material is the surface of the material (4) transparent micro 24 131153⁄4 pif.doc particles. When the surface fine concavo-convex structure is formed, the amount of fine particles used is the weight of the transparent resin crucible (8) for the surface concavo-convex structure. In general, it is preferable that the degree of the inner portion is 5 to 50 parts by weight. The light-shielding layer may be a diffusion layer that expands the viewing angle and the like, and expands the viewing angle or the like. The layer, the adhesion preventing layer, the hard coat layer, and the diffusion precipitating material may be provided in addition to the protective film 2, or may be separately provided as a separate optical functional layer from the protective film 2. The polarizing plate 21 of the embodiment system 'Applications, etc., can also be used to laminate an optical film (not shown) laminated on the layer of the moon. The Wei layer is __. For example, the polarizing plate ^ θ is bonded to the optical functional layer to make it suitable. For example, =: (including a 1...4 wavelength film, etc.), etc. These films are used in layers or in two layers. For example, in the poor film of the present invention, an optical layer of an elliptically polarizing plate or a circular polarizing plate is used. In the case where the field of view is enlarged, the polarizing plate of the wild corner is used. 4 (4) When the layer is laminated, a wide-viewing type polarizing plate system can be obtained, and in the case of the horizontal well, the person from the viewing side (display side) can be shot to 4 layers. The reflective liquid for the crystal-reflective polarizing plate display and the protective film 2 on the opposite side are attached in a suitable manner by the side of the layer of gold: two::: layer. For example, a reflective layer made of a phase or the like may be provided with a foil or a vapor deposited film of a film made of a reflective metal such as aluminum on one side of a protective film such as a 25'pif.doc treatment. Further, the fine fine concavo-convex structure on the surface of the protective film 2 containing the fine particles is provided with a metal reflective layer or the like in a suitable manner such as a vapor deposition method or a plating method. The reflective layer of the fine concavo-convex structure described above diffuses incident light by diffuse reflection to prevent reflection or diffuse reflection, and has the advantage of suppressing unevenness of light and dark. Further, the protective film 2 system containing fine particles is also diffused by the incident light and its reflected light when they are transmitted.

以更抑制明暗不均勻之優點等。使保護薄膜2之表面微細 凹凸構造加以反映之微細凹凸構造的反射層之形成係,例 如可以真空蒸鍍方式、離子電鍍(i〇n plating)方式、濺鍍 (sputtering)方式等之蒸鍍或電鍍方式等之適宜方式將金 屬直接附設薄膜2之表面的方法等加以實行。In order to further suppress the advantages of uneven brightness and the like. The formation of the reflective layer of the fine concavo-convex structure, which reflects the fine concavo-convex structure of the surface of the protective film 2, may be, for example, a vapor deposition method, an ion plating method, a sputtering method, or the like. A method of directly attaching a metal to the surface of the film 2 or the like in a suitable manner such as a plating method or the like is carried out.

又,反射型偏光板係,以替代直接形成於上述偏光板 21之保濩薄膜2的模式,也可使用在按照其保護薄膜2之 適且薄膜a又反射層所構成之反射薄片。尚且,反射層係, 通^由金屬所構成之關係、’其反射面以保護薄膜2或偏光 板等加以覆蓋狀態之使關式時,可防止由氧化所引起之 反射率的降低。更且’使初期反射率以長期加以持續,對 於反射層以另項純積層保制膜2時也可加以迴避。 f透射型偏光板係,藉由在上述以反射層使光加以反 “且成為加以透射之半透明反射鏡㈤制膽)等之 層:加以取得。半透射型偏光板係,設於 t曰秀曰f面側。將包括關於半透射型偏光板之 +透射良液日日顯4置在明亮環境下加以使用的場合係, 26 13115¾ pif.doc f足視認側(顯示面侧)所入射之外光為顯示光加以利用, 境下加以使㈣場合係以從後_ (baeki_ 之先為顯不光加以使用。因此,可圖謀減低消費電力。 對於在偏光板21 ’更加積層相你至權 ™ η 頁“目位差相所構成之橢圓 偏先板或0偏紐純飼。胁錢皱U使相位差薄 方在偏光板21以經由黏著劑層加以積Further, a reflective polarizing plate may be used instead of the protective film 2 formed directly on the polarizing plate 21, and a reflective sheet composed of a protective layer 2 and a reflective layer 2 may be used. Further, in the case where the reflective layer is formed of a metal and the reflective surface is covered by the protective film 2 or the polarizing plate, the decrease in reflectance due to oxidation can be prevented. Further, the initial reflectance is continued for a long period of time, and the film 2 can be avoided when the film is protected by another pure layer. The f-transmissive polarizing plate is obtained by a layer in which the light is reversed by the reflective layer and is made into a translucent mirror (five). The semi-transmissive polarizing plate is provided at t曰. The side of the show 曰 f. The case where the + transmission of the semi-transmissive polarizing plate is used in a bright environment, 26 131153⁄4 pif.doc f is incident on the side (display side) The external light is used for the display light, and the environment is used to make the (4) occasions use the _ (baeki_ first). Therefore, it is possible to reduce the power consumption. For the polarizer 21', you will have more layers. TM η page "Elliptical partial plate formed by the difference of the target position or zero-neutral pure feed. The threat wrinkle U makes the phase difference thin on the polarizing plate 21 to accumulate via the adhesive layer.

接:在將保護薄膜2剝離之面形成 新黏接層加以積層的方法或’不剥離保護薄膜2,以設或 以貼緊積層之方法等。使直線偏光變為橢圓 偏先或Η偏光,使_偏光或圓偏光變為錢偏光,或者 =直線偏光之偏光方法加以變化之場合,係以使用相位差 $等。特別’對於使直線偏光變為圓偏光,使圓偏光變 為直線偏光之相位差薄膜係,以使用所謂ν 用於使直線偏光之偏光方向加以變化之場合。The method of forming a new adhesive layer on the surface on which the protective film 2 is peeled off is laminated or the method of not peeling off the protective film 2, or by laminating the laminate. When the linearly polarized light is changed to an ellipse or a polarized light, and the _polarized or circularly polarized light is changed to the money polarized light, or the polarized light method of the linear polarized light is changed, the phase difference of $ is used. In particular, a phase difference film system in which linearly polarized light is circularly polarized and circularly polarized light is linearly polarized is used, and a so-called ν is used to change the polarization direction of the linearly polarized light.

橢圓偏光板係,例如補償(防止)由超扭曲曲向列 (STN : Super pwisted Nematic )模式之液晶顯示裝置的液 晶f之雙折射所產生之著色(藍或黃),有效使用於無上 迷著色之黑白顯示的場合等。更且,控制三維折射率者係, 也可補償(防止)從斜方向觀察液晶顯示裝置之晝面時所 產生的著色之關係為較好。圓偏光板係,例如有效使用於 顯示之反射型液晶顯示裝置的圖像 ,》周之场合等’又’也具有反射防止之機能。上述相位差 專膜24之具體列係,可舉從聚;5炭酸g旨(p〇IyCarb〇nate )、 27 ipif.doc 聚乙烯醇(polyrinylalchol)、聚苯乙烯(p〇lystyrene)、 聚曱基丙烯酸曱酯(polymethyl methaciylate )、聚丙烯 (polypropylene)或其他聚烯烴(p〇ly〇lefine)、聚芳基化 物(polyarylate)、聚酰胺(polyamide)等之適宜聚二物 所構成之薄膜加以延伸處理所得之雙折射性薄膜或 等。相位差薄膜係,例如由各種波長薄膜或液晶層之雙折 射以著色或視肖等之補償為目的可按照❹目的具有適宜 之相位差’也可使兩種以上之相位差薄膜加以積層以控制 相位差等之光學特性。 又上述之橢圓偏光板或反射型橢圓偏光板係,將偏光 板或反射型偏光板與相位差薄膜以適宜組合加以積層 者。該橢圓偏光板等係,雖可藉由以成為(反射型)偏光 板與相位差薄膜之組合的方式,使其在液晶顯示裝置之製 ίίΓΓ1次個別積層加以形成,如上所述減成為橢圓 學薄膜者係優於品質之安定性或積層作業性 專有k升液日日顯不裝置等之製造效率的優點。 "使偏與亮度提㈣舰合之偏光板係,設於液 :日早兀之“側加則錢。亮度糾薄 置等之後照光或從背面之反射等㈣光入射時 =先軸之直線偏光或所定方向之圓偏光加以反射,盆他 之特性。將亮度提昇薄膜加以積層於偏光板 從後照光等之光_光加狀射以得所 疋偏先狀‘狀透射光的同時,上述所定絲狀態以外之光 28 13115¾ if.doc ==::後=:=提昇薄膜面所反射 亮度提昇薄膜’將其—部分或全部成為==== ===度提昇薄膜之光增量的同時:加以 等可利用之光量增切衫日圖像顯不 昇薄膜,以德日^笠〜使儿度楗升 不使用亮度提 昇巧:从Μ雜液晶單元之f面通過偏光子The elliptically polarizing plate system, for example, compensates (prevents) the coloring (blue or yellow) generated by the birefringence of the liquid crystal f of the liquid crystal display device of the super twisted nematic (STN: Super Pwisted Nematic) mode, and is effectively used in the fascination. The occasion of black and white display of coloring. Further, by controlling the three-dimensional refractive index system, it is also possible to compensate (prevent) the relationship of the coloration which occurs when the pupil plane of the liquid crystal display device is observed from an oblique direction. The circularly polarizing plate system, for example, is effective for use in an image of a reflective liquid crystal display device to be displayed, and has a function of preventing reflection. The specific sequence of the above-mentioned phase difference film 24 is exemplified by poly 5 carbon acid g (p〇IyCarb〇nate), 27 ipif.doc polyvinyl alcohol (polyrinylalchol), polystyrene (p〇lystyrene), polyfluorene A film composed of a suitable polydazole of polymethyl methaciylate, polypropylene or other polyolefin, polyarylate, polyamide, or the like The resulting birefringent film or the like is extended. The retardation film system, for example, may have a suitable phase difference by the birefringence of various wavelength films or liquid crystal layers for the purpose of coloring or viewing, etc., or two or more retardation films may be laminated to control Optical characteristics such as phase difference. Further, in the above-described elliptically polarizing plate or reflective elliptically polarizing plate, a polarizing plate, a reflective polarizing plate and a retardation film are laminated in an appropriate combination. The elliptically polarizing plate or the like can be formed into a single layer of a liquid crystal display device by a combination of a (reflective) polarizing plate and a retardation film, and reduced to an elliptical shape as described above. The film is superior to the manufacturing efficiency of the stability of the quality or the build-up of the proprietary k-liquid liquid daily display device. "The polarizing plate system that makes the bias and brightness (4) ship is set in the liquid: the day and the early day of the "the side plus the money. After the brightness is thinned, etc., after the light or the reflection from the back, etc. (4) When the light is incident, the first axis Linear polarized light or circularly polarized light in a given direction is reflected, and the characteristics of the pot are added. The brightness-enhancing film is laminated on the polarizing plate, and the light is emitted from the backlight, and the light is transmitted to obtain the transmitted light. Light other than the above-mentioned predetermined silk state 28 131153⁄4 if.doc ==:: after =:= Raise the brightness of the film surface to enhance the brightness of the film 'to make it - part or all of the light increase of the film ==== === At the same time: to increase the amount of light available to increase the size of the shirt, the image of the day is not rising, to the German and Japanese ~ 使 ~ make the child soar without using brightness enhancement: from the f-face of the doped liquid crystal unit through the polarizer

ί光Π乎ΐ:Ι—致於偏光子1之偏光軸的偏光方向 ^光=’好被偏光子〗所吸收,不透射偏光子!。且體 光子1 ΞίΓΤΐ光子1之特性’大概有5G%之光被偏 先子1所錄,從其份量,液晶圖像顯轉可利用之光詈 減少’圖賴暗。亮度提⑽鶴,顿 所吸收之偏衫向的光人射於偏光子i以亮度提昇H1 旦加以伙,更經由設於其後側之反射料加以反轉重複 再入射於純提昇_,亮度提㈣膜係僅使在此兩者間 以反射、反轉之光的偏光方向成為可通過偏光子丨之偏光ί光Π ΐ Ι Ι Ι 致 致 致 致 致 致 致 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏 偏. And the photon 1 ΞίΓΤΐ photon 1 characteristic 'about 5G% of the light is recorded by the first sub-1, from its weight, the liquid crystal image can be used to reduce the light. The brightness is raised (10), and the light person absorbed by the slanted shirt is exposed to the polarizer i, and the brightness is increased by H1, and the reflection material placed on the back side is reversed and then incident on the pure lift _, brightness (4) The film system only makes the polarization direction of the reflected and inverted light between the two become polarized by the polarizer.

,向的偏光加以透射供給於偏光子〗。藉此,可使後照光 等之光以有效率的使祕液晶顯示裝置之圖像顯示,^使 顯不晝面明梵。 上亮度提,薄膜與上述反射料之間係,可設擴散板。 由焭度提昇薄膜所反射之偏光狀態的光雖進行於上述反射 層等,所設置之擴散板係使通過之光以均_加以擴散的同 時解除偏絲S,成辆偏光㈣。^擴散板係使偏光 恢设原來之自然光狀癌,此非偏光狀態,即自然光狀熊之 29 I3115Mp,doc 光向反射層等,經由反射層等加以反射,重複再通過擴散 板再^射於壳度提昇薄膜。如此在亮度提昇薄膜與上述反 射層等之間’藉由設使偏級復於絲之自然光狀態的擴 散板時則可提供一面維持顯示晝面之明亮,同時使顯示查 面^示不均勻減低,均—明亮的晝面。藉由設該擴散板―, 初次之人射光細恰好增加反射之重複次數,與擴散板之 擴散機能結合可成為均—明亮之顯示晝面。 *亡述之免度提昇薄膜係,可適宜使用例如介電質之多 層,膜或折射率各向異性不同之薄膜的多層積層體,顯示 戶疋偏光軸之直職光係加以透射其他光係加以反射之特 5者二如膽留醇液晶(cholesteric liquid crystal)聚合物之 膜或其定向液晶層支持於薄膜基材上,顯示使左旋 ^性Ϊ之任何—方的圓偏光加以反射其他光係加以透射之The polarized light is transmitted to the polarizer. Thereby, the light such as the backlight can be efficiently displayed on the image of the liquid crystal display device, so that the display is not visible. The upper brightness is raised, and between the film and the above-mentioned reflective material, a diffusion plate can be provided. The light in the polarized state reflected by the twist-lifting film is applied to the reflective layer or the like, and the diffusing plate is provided so that the passing light is uniformly diffused while releasing the polarized wire S to form a polarized light (four). ^Diffuse plate system restores the original natural light cancer to the polarized light. This non-polarized state, that is, the natural light bear 29 I3115Mp, doc light reflection layer, etc., is reflected by the reflective layer, and then repeatedly passed through the diffusion plate. Shell-lifting film. Thus, by providing a diffusing plate in which the biasing level is restored to the natural light state of the filament between the brightness-enhancing film and the reflective layer or the like, it is possible to maintain the brightness of the display surface while maintaining the display surface unevenness. , both - bright face. By providing the diffusing plate, the first person's illuminating light just increases the number of repetitions of the reflection, and combined with the diffusing function of the diffusing plate, it becomes a uniform-bright display surface. * The thin film system for the elimination of the deadness can be suitably used, for example, a multilayered layer of a dielectric multilayer, a film or a film having different refractive index anisotropy, and a direct light system showing the polarization axis of the household is transmitted through other light systems. The reflection of the special 5, such as a film of cholesteric liquid crystal polymer or its oriented liquid crystal layer supported on the film substrate, showing any circular polarization of the left-handed Ϊ to reflect other light Transmitted

的古^ θ ^之使所定偏絲之直線偏光加以透射類型 藉由使其透射光照原樣使偏光軸以-而ί古2农光板2卜—面抑制由偏光板21之吸收損失一 光純射。—方面’如膽㈣液晶層使圓偏 。爭日、之売度提昇薄膜係,也可照原樣入射於偏 辦由相位#^ *抑射收損失之場合係,使其圓偏光以 i且,對於1广直線偏光化’以人射於偏光板21為宜。 光變換於錢Γΐ魏藉由使们/4波長板時,可將圓偏 在可視光領域等之寬廣波長顧作為賴波長薄膜加 30 I if.doc 議月匕之相位差薄膜係,例如對於波長別_之、、 機能之她差層與顯示其他相位差特性 波長薄膜加以機能之相位差層The ancient θ ^ makes the linear polarization of the fixed partial light to be transmitted type. By making the transmitted light as it is, the polarizing axis is made - and the absorption loss by the polarizing plate 21 is suppressed by the light. - Aspects such as the biliary (four) liquid crystal layer makes the circle biased. In the case of competition for the day and the degree of improvement of the film system, it can also be incident on the occasion where the phase is caused by the phase #^ * suppression, and the circular polarization is i, and for a wide linear polarization, The polarizing plate 21 is preferably used. When the light is converted by Qian Weiwei, by making the /4 wavelength plate, the wide wavelength of the circle in the visible light field can be used as the phase difference film, for example, for the wavelength. The difference between the layer and the other phase difference characteristic wavelength film

拉A、'於膽留醇液晶層’也以組合反射波長相異者 二、目Ix兩層或二層以上加以重疊配置構造時,可取得 :不、7賴等之寬廣波長範圍使圓偏光加以反射者。其 結’可取得寬廣波長範圍之透射圓偏光。 偏光板21係如上述之偏光分離型偏光板,由偏光 、兩層或二層以上之光學機能層加以積層者所構 成因此:也可為使上述反射型偏光板或半透射型偏光板 與相位差薄膜加以組合之反射型侧偏光板或半透射型擴 圓偏光板。 ^關於本發明之偏光板21及包括此偏光板21之光學薄 膜係可適用於液晶顯示裝置或電致發光(EL : Electro Liiminescence)顯示裝置等之各種圖像顯示裝置。When A and 'Cholesterol liquid crystal layer' are overlapped and arranged in a combination of two different reflection wavelengths, and two or more layers of Ix, it is possible to obtain a wide-range wavelength range such as not to be polarized. Reflected. The junction 'is achieved transmission circular polarization over a wide wavelength range. The polarizing plate 21 is a polarization separation type polarizing plate as described above, and is composed of a polarizing layer or two or more optical functional layers. Therefore, the reflective polarizing plate or the semi-transmissive polarizing plate and the phase may be used. A reflective side polarizing plate or a semi-transmissive circularly polarizing plate in which a difference film is combined. The polarizing plate 21 of the present invention and the optical film including the polarizing plate 21 can be applied to various image display devices such as a liquid crystal display device or an electroluminescence (EL) display device.

例如,在適用於透射型之液晶顯示裝置之場合,該液 晶顯不裝置係在一對之透射型偏光板(或光學薄膜)之間 設液晶單元加以構成。透射型偏光板與液晶單元係,由習 知之黏著劑等加以黏接。顯示面側之前面偏光板與液晶單 元之背面側之後面偏光板係可為同種者或異種者。尚且, 在液晶顯示裝置製作時,例如使擴散板、遮光層、反射防 止膜、保護板、棱鏡陣列、透鏡陣列薄片、光擴散板、後 照光等之適宜部件在適宜位置可加以配置一層或兩層以 31For example, when it is applied to a transmissive liquid crystal display device, the liquid crystal display device is constructed by providing a liquid crystal cell between a pair of transmissive polarizing plates (or optical films). The transmissive polarizing plate and the liquid crystal cell are bonded by a conventional adhesive or the like. The front side polarizing plate on the display side and the rear side polarizing plate of the liquid crystal unit may be the same type or a different type. Further, in the production of the liquid crystal display device, for example, a suitable member such as a diffusion plate, a light shielding layer, an antireflection film, a protective plate, a prism array, a lens array sheet, a light diffusing plate, and a backlight can be disposed at one or two positions at appropriate positions. Layer 31

Bum, pif.doc 上 對於液晶顯示裝置之顯示模式 (Twisted Nematic )模式、㈣模式、縱斷^用扭曲向列TN Aligned) ^Bum, pif.doc For the display mode (Twisted Nematic) mode of the liquid crystal display device, (4) mode, and the twisted nematic TN Aligned ^

Self-compensated Birefringence) ^ 又,關於本發明之偏光板21或 於:機EL顯示裝置。一般上,有機乱::置= 明土板上將透明電極、有機發觸極 :以T光體(有機虹發光體)。== 係,為各種有機薄膜 啕执知尤層Self-compensated Birefringence) ^ Further, the polarizing plate 21 of the present invention or the EL display device. In general, organic chaos:: set = transparent electrode on the clay plate, organic emitter: T-light (organic rainbow emitter). == system, for various organic films

Un—)等之 成之正孔注人層與,由惠 H 的有機固體所構成之發光層的積 _ 5 又光層與由茈(Perylene)衍生物等所構成之 層體或此等正孔注入層、發丄= 入層的積成體4 ’所知者有種種組合構成。 J機EL顯示裳置係,藉由在透明電極與金屬電極施 口電昼,正孔與電子^於有機發光層,由此等正孔與電 子之再、k σ所產生之能量(ene㈣激勵螢光物質,被激 勵之勞光物質恢復正常狀態時加以放射光,以此原理加以 1光。中14之再結合機構係,與一般之二極管(di〇de)同 樣’從此可預想到’電流與發光強度係對於施加電壓顯示 隨伴整流性之強非線形性。 ,ι、在有機EL顯示裝置,為取出有機發光層之發光,至 少-方之電極具有透明性就足夠。通常係,將由氧化銦錫 32 13115i7s4pif.doc 等所形成之透明電極以陽極加以使用。一方面, 數容易提昇發光效率起見,在陰極以使用功函 4重要’通常使用Mg_Ag、Al_Li等之金屬電 以;此種構成之有機乱顯示裝置,有機發光層係, 也與透明電極=之。因此,有機發光層 :發光時從透明基板之表:以入二透$二^ 機發光層在金,、… π透射透明電極與有 面侧的關係,從外部==再出於透明基板之表 視如鏡面。相察時,有機EL顯示裝置之顯示面 展之Ϊ:二:光體係由電壓之施加加以發光之有機發光 網時,在有機發光層御 置,在ii日有機el發光體之有機肌顯示裝 透月包極之表面側設偏i 電極與偏光板21之間可設相位差薄^叫纽核明 電極==板21係,具有使從外部入射在金屬 從外部不讓視認二由其偏光作用具有 之偏并方編Ή 且將偏光板21與相位差薄膜 =向所成之角度調整為π/4時,可完全遮蔽金屬電 即,入射於此有機EL 板21僅透射直線偏光成分 顯示裝置之外部光係,由偏光 。此直線偏光係由相位差薄膜— 33 1311574 pif.doc 般成為橢圓偏光。特別,相位差薄膜 偏光板21與相位差薄膜之偏光方向所‘成1/4波長薄膜並且 圓偏光。 成之角為兀/4時成為 此圓偏光係,透射透明基板、 在金屬電極加以反射,再透射有機薄€極、有機薄膜, 基板,在相位差薄膜再成為直線偏光二透明電極、透明 係,與偏光板21之偏光方向直交 ^而,此直線偏光 2卜其結果,可完全遮蔽金屬電極之_、不能透射偏光板 (其他事項) 兄° 在以上說明,對於本發明之最佳 本發明係並非限定於該實施例,說明。但, 專利範圍所述的技術思想同—、、上發明之申請 更。 乾固内可能尚有各種變 即’在本實施例係,如圖1至 5及吸引噴嘴8在 斤不使供給噴嘴 本發明係,供給嘴嘴5及㈣=之模式力以朗。但在 例如’在保護薄臈2 ::之件數並非限定於此。 雖然本㈣之複數件。 限定本發明,任m 4貫也例揭路如上’然其並非用以 和範圍内,當可作::此者’在不脫離本發明之精神 範圍所界定C之更動酬’因此本發明之保】 【圖式簡單說明】 法之為說明關於本發明之實施例之偏光板的製造方 34 f.doc 圖2係為說明上述偏光板的製造方法之侧面圖。 圖3係擴大上述圖2之主要部分的擴大圖。 圖4A〜J係,表示關於上述偏光板的裝造裝置,在吸 引喷嘴之吸引口的開口部分之形狀的模式圖。 圖5係表示關於本發明之實施例的偏光板之概略模式 圖。 【主要元件符號說明】 1. 偏光子(薄膜)Un-), etc. The positive hole injection layer and the light-emitting layer composed of the organic solid of Hui H _ 5 The light layer and the layer composed of Perylene derivatives or the like The hole injection layer and the hair 丄 = the integrated body 4 of the in-layer are known to have various combinations. J machine EL display skirt system, by applying electricity to the transparent electrode and the metal electrode, the positive hole and the electron are in the organic light-emitting layer, thereby the energy generated by the positive hole and the electron, k σ (ene) excitation The fluorescent substance, when the excited light-emitting substance returns to the normal state, emits light, and the principle is used to add 1 light. The recombination mechanism of the middle 14 is the same as the general diode (di〇de). The light-emitting intensity indicates a strong nonlinearity with respect to the applied voltage for the applied voltage. In the organic EL display device, in order to extract the light emitted from the organic light-emitting layer, it is sufficient that at least the electrode has transparency. Usually, it is oxidized. A transparent electrode formed by indium tin 32 13115i7s4pif.doc or the like is used as an anode. On the one hand, the number is easy to improve the luminous efficiency, and it is important to use a work function at the cathode 4, which is usually made of a metal such as Mg_Ag or Al_Li; The organic disorder display device, the organic light-emitting layer system, and the transparent electrode=. Therefore, the organic light-emitting layer: when emitting light from the surface of the transparent substrate: the light-emitting layer is in gold, ... π transmissive transparent electrode and the surface side relationship, from the outside == and then the surface of the transparent substrate as a mirror surface. When observed, the display of the organic EL display device is the same: 2: the application of the light system by the voltage When the organic light-emitting net to be illuminated is placed on the organic light-emitting layer, a phase difference can be set between the surface of the organic muscle display and the polarizing plate 21 on the surface of the organic muscle display. It is called the nucleus of the nucleus of the nucleus of the nucleus of the nucleus of the nucleus of the nucleus of the nucleus. When adjusted to π/4, the metal electricity can be completely shielded, that is, the external light system that is incident on the organic EL panel 21 only transmits the linear polarization component display device, and is polarized. The linear polarization is made of a retardation film - 33 1311574 pif.doc In particular, the retardation film of the retardation film 21 and the retardation film are 1/4 wavelength film and are circularly polarized. When the angle is 兀/4, the circular polarization system is transmitted, and the transparent substrate is transmitted. Reversed at the metal electrode , the organic thin film, the organic film, and the substrate are further formed into a linear polarizing transparent electrode and a transparent system in the retardation film, and are orthogonal to the polarizing direction of the polarizing plate 21, and the linear polarized light 2 can be completely shielded. The metal electrode is not permeable to the polarizing plate (other matters). The above description of the present invention is not limited to the embodiment, but the technical idea described in the patent scope is the same as The application of the above invention is more. There may be various changes in the dry solids, that is, in the present embodiment, as shown in Figs. 1 to 5 and the suction nozzle 8 is not supplied to the nozzle, the nozzle is supplied to the nozzle 5 and (4) = The force is RAN. However, the number of pieces in the case of 'protection 臈 2 :: is not limited to this. Although a plurality of pieces of this (four). The invention is not limited by the scope of the invention, and is intended to be: "there is no change from the definition of C as defined in the spirit of the invention". BRIEF DESCRIPTION OF THE DRAWINGS The method for producing a polarizing plate according to an embodiment of the present invention is shown in FIG. 2 is a side view for explaining a method of manufacturing the above polarizing plate. Fig. 3 is an enlarged view showing an enlarged main portion of Fig. 2; Figs. 4A to 4J are schematic views showing the shape of the opening portion of the suction port of the suction nozzle with respect to the mounting device for the polarizing plate. Fig. 5 is a schematic view showing a polarizing plate according to an embodiment of the present invention. [Main component symbol description] 1. Polarized photo (film)

2. 保護薄膜(其他薄膜) 3·黏著劑液(黏接液) 4. 轉筒(貼合手段) 5. 供給喷嘴(液體供給手段) 6. 液體 7. 供給口 8. 吸引喷嘴(吸引手段) 9. 餘長部2. Protective film (other film) 3. Adhesive liquid (adhesive liquid) 4. Drum (adhesive means) 5. Supply nozzle (liquid supply means) 6. Liquid 7. Supply port 8. Suction nozzle (suction means ) 9. Yu Changbu

10. 吸引口 11. 黏著劑液供給喷嘴(黏著劑液供給手段) 13.黏著劑液(黏接液) 21. 偏光板(薄膜積層物) 22. 保護薄膜(其他薄膜) 3510. Suction port 11. Adhesive solution supply nozzle (adhesive solution supply means) 13. Adhesive solution (adhesive solution) 21. Polarizing plate (film laminate) 22. Protective film (other film) 35

Claims (1)

13115 94127266號中文專利範圍無劃線修正本 13115 94127266號中文專利範圍無劃線修正本 17580pif.doc 征曰期:98年1月23日 修(<)正本 十、申請專利範圍: 1· 一種薄膜積層物的製造方法; 的面配設一其他薄膜,其特徵在於: 、至少一方 在該薄膜之至少一方的面配設該其他薄骐; 在該薄膜與該其他薄膜之貼合部分供給、 且,一面使抵抗於將向該其他薄膜之至少一方 7,並 之該黏接液的-液體,從該其他薄膜之至少流動 以供給;以及 方的端部加 -面使該薄膜與該其他薄膜由擠壓加以貼合。 土 2.如申請專利範圍第!項所述之薄膜積層ς 法,其特徵在於: 幻衣以方 在貼合該賴與該其域狀前,使將向 =至少-方的端部流出之該黏接液、或由該液 $ 該黏接液加以吸引去除。 稀釋的 請專職圍以項所述之薄_ 法,其特徵在於: 』衣运々 對於該其他薄膜,使用比該薄膜寬度較大,在寬度方 向具有一餘長部之場合;以及 使該液體之供給在餘長部之形絲_加以實行。 t如申請專概㈣2項所述之薄膜制物的製造方 法’其特徵在於: =於該其他薄膜,使用比該薄膜寬度較大,在寬度方 向具有一餘長部之場合;以及 使該黏接液或由該液體所稀释之該黏接液之吸引去除 36 i3H574P,d〇c 在該餘長部之形成範圍内加以實行。 、5.如申請專利範圍第1項所述之薄膜積層物的製造方 法,其特徵在於: 對於該液體,以制可使絲魏加以溶解者。 6.如申請專利範圍第1項所述之薄膜積層物的製造方 法’其特徵在於: ,用-偏光子作為該薄膜,並且,使用—保護薄膜作 為該其他薄膜。 + 一7. -種薄膜積層物的製造裝置,係用於在—薄膜之至 的面配設—其他薄膜之—薄膜積層物的製造,其特 徵在於: 一黏接液供給手段係,在該薄膜與該薄膜之至少一方 、:配认的該其他薄膜之貼合部分,加以供給—黏接液; Μ及 牌6一=體供給手段係’使抵抗於從該其他薄膜之中央部 之部流出之該黏接液的—液體,從該其他薄膜 之至;一方的端部加以供給;以及 使該薄膜與其他薄膜由擠壓加以貼合。 置mu範圍第7項所述之薄联積層物的製造裝 流出膜之至少—方的端部 除去。4由該液體所稀釋的該黏接液加以吸引 .如申明專利乾圍第7項所述之薄膜積層物的製造裝 37 J3H574opif.de 置’其特徵在於: 對於該其他薄膜 向具有-餘♦場合;Μ侧驗,在寬度方 範圍^液體供給手段之一送出部以位置於該餘長部之形成 裝置Μ其圍第8項㈣之薄臈制物的製造 向具;薄膜寬度較大,在寬度方 内。該則手段之一吸引部以位置於該餘長部之形成範圍 裝置u其tut糊第ig項所述之薄糊物的製造 向,3吸引部之_^σ部分係,加以扁平於—所定方 行之 裝置概㈣7顿述之祕獅物的製造 該其=膜偏光子作為該薄膜,並且使用一保護薄膜作為 言凡―1 甘3. 了種薄膜積層物,係在一薄膜之至少一方的面配 ^二他薄膜,其特徵在於:該薄膜積層物是使用如 利範圍第1項的薄膜積層物的製造方法而製得。 14. 一種偏光板,係在偏光子之至少一方的面配設一 38 I3ii574 〇pi£doc 保護膜’其特徵在於:該偏光板是使用如申請專利範圍第 6項的薄膜積層物的製造方法而製得。 15. —種光學薄膜,係積層有至少一件偏光板,該偏 光板是在一偏光子之至少一方的面配設一保護薄膜,其特 徵在於:該光學薄膜的該偏光板是使用如申請專利範圍第 6項的薄膜積層物的製造方法而製得。 16. —種圖像顯示裝置,係包括一偏光板或一光學薄 膜’該偏光板是在一偏光子之至少一方的面配設一保護薄 φ 膜,該光學薄膜係積層有至少一件該偏光板一,其特徵在 於:該圖像顯示裝置的該偏光板或該光學薄膜是使用如申 請專利範圍第6項的薄膜積層物的製造方法而製得。13115 94127266 Chinese patent scope without slash correction This 13115 94127266 Chinese patent scope without scribe correction 17580pif.doc levy period: January 23, 1998 repair (<) original ten, the scope of patent application: 1 · A The method for producing a film laminate; the other surface of the film; wherein at least one of the other thin films is disposed on at least one of the surfaces of the film; and the film is supplied to the bonding portion of the film; And, a liquid that resists at least one of the other films and the liquid of the other liquid is supplied from at least the other film to supply; and the end of the square is added to the surface to make the film and the other The film is bonded by extrusion. Soil 2. If you apply for the patent scope! The thin film lamination method according to the item, characterized in that: the phantom is applied to the adhesive liquid which will flow out to the end of at least the square before the affixing and the domain, and the liquid $ The adhesive is removed and removed. For the dilution, please refer to the thin method described in the article, which is characterized in that: the clothing is used for the other film, and the film has a larger width than the film, and has a length in the width direction; The supply of the wire in the excess length is carried out. The manufacturing method of the film material described in the above-mentioned application (4), wherein the other film is used in a larger width than the film and has an excess length in the width direction; The liquid pick-up or the suction removal of the adhesive liquid diluted by the liquid 36 i3H574P, d〇c is carried out within the formation range of the excess length portion. 5. The method for producing a film laminate according to claim 1, wherein the liquid is dissolved in the liquid. 6. The method of producing a film laminate according to claim 1, wherein the film is used as a film, and a protective film is used as the other film. + 7.7. A device for manufacturing a film laminate, which is used for the production of a film laminate on the surface of the film - other film, characterized in that: a bonding liquid supply means, At least one of the film and the film, the bonding portion of the other film to be supplied is supplied with a bonding liquid; the card and the card 6 are supplied to the central portion of the film. The liquid flowing out of the adhesive liquid is supplied from the other film; one end is supplied; and the film is attached to the other film by extrusion. At least the end portion of the manufacturing film of the thin laminated layer described in item 7 of the mu range is removed. (4) The adhesive solution diluted by the liquid is attracted. The manufacturing of the film laminate according to the seventh paragraph of the patent application is JJH574opif.de, which is characterized in that: Occasionally, in the width range, the liquid supply means is one of the liquid supply means, and the forming means of the outer length is formed by the forming device of the remaining length (the fourth) (4); Within the width square. In one of the means, the suction portion is positioned in the formation range of the excess length portion, the manufacturing direction of the thin paste described in the tut paste item ig, and the _^σ portion of the third suction portion is flattened. The device of the square line (4) The manufacture of the secret lion of the 7th narration is the film polarizer as the film, and a protective film is used as the film of the genus-1. A film laminate is at least one of the films. The surface of the film is characterized in that the film laminate is produced by using the method for producing a film laminate of the first item. A polarizing plate in which a 38 I3ii574 〇pi£doc protective film is disposed on at least one surface of a polarizer. The polarizing plate is a method for producing a film laminate according to claim 6 of the patent application. And made. An optical film comprising at least one polarizing plate, wherein the polarizing plate is provided with a protective film on a surface of at least one of the polarizers, wherein the polarizing plate of the optical film is used as an application The method for producing a film laminate according to item 6 of the patent scope is produced. 16. An image display device comprising: a polarizing plate or an optical film; the polarizing plate is provided with a protective thin φ film on at least one surface of a polarizer, the optical film layer having at least one piece The polarizing plate 1 is characterized in that the polarizing plate or the optical film of the image display device is produced by using the method for producing a film laminate according to claim 6 of the patent application. 3939
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