TW552296B - Method for producing endothermic pigment - Google Patents

Method for producing endothermic pigment Download PDF

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Publication number
TW552296B
TW552296B TW90128869A TW90128869A TW552296B TW 552296 B TW552296 B TW 552296B TW 90128869 A TW90128869 A TW 90128869A TW 90128869 A TW90128869 A TW 90128869A TW 552296 B TW552296 B TW 552296B
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Taiwan
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heat
pigment
endothermic
coating
item
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TW90128869A
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Chinese (zh)
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Kuen-Shiang Huang
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Kuen-Shiang Huang
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Abstract

A method for producing an endothermic pigment mainly comprises: using an endothermic material easy in storage and heat dissipation; dyeing the endothermic material; and performing a micro-encapsulating treatment to form a pigment to be added in a medium as a coating for spraying on the surface of an object. One main objective of the present invention is to provide a method for producing an endothermic pigment, which mainly uses a micro-encapsulated dyed endothermic material as a pigment to be added in a medium, followed by spraying on the surface of a heat dissipating member as a coating. Another objective of the present invention is to provide a method for producing an endothermic pigment, which provides a covering heat conductive medium with a suitable strength. Such a medium can improve the cosmetic property of a member while increasing the heat dissipation efficiency of the member.

Description

552296552296

案號 9012SRRQ 五、發明說明(1) [創作領域] 本發明係一種塗佈於金屬或 裝顏料並提供散熱功效之吸熱顏太、構件之表面作為塗 吸熱顏料之製作方法。 、 去 特別有關於一種 [先前技術] 顏料」就廣義的說,是一 的物理性及化學性,存在於媒劑4色以安定 活周遭增添了許多的色彩。 使用無異使吾人的生 一般觀察,油漆、塗料在生活 部分做為增加物品表面的色彩為廣泛,大 是,該種用途卻不適合使 =工:龄止乳化用,但 漆、塗料披覆在散敎』σ为的散熱構件,因為油 所以大部分的散Ϊ構=ί:會降低熱量傳導的效率, 此,右该散熱構件使用的是 :::也因 易發生鏽餘的情況,而德总f ^化的材質(如鐵),則容 產品的壽命。 鏽❹對的也降低了散熱的效率及 工作品元件或機械製品等,其在 構件,如風扇、散熱片、導熱管等散熱 效能的脑故ΐ逮消散設備所產生的熱量’但’隨著產品 jjzzvo jjzzvo 1 號 90128869 五、發明說明(2) -----5倐£ _Case No. 9012SRRQ V. Description of the invention (1) [Creation area] The present invention is a method for manufacturing a heat-absorbing pigment coated on a metal or a pigment and providing heat dissipation, and the surface of a component is used as a method for applying a heat-absorbing pigment. In particular, a "prior art" pigment is, in a broad sense, a physical and chemical property. It exists in the four colors of the vehicle to stabilize the environment and adds a lot of colors. The use of no difference makes my life generally observable. Paints and coatings are widely used to increase the color of the surface of articles in the living part. Mostly, this kind of use is not suitable for use. Most of the heat dissipation components due to oil dispersion are due to oil. =: Will reduce the efficiency of heat conduction. Therefore, this heat dissipation component uses ::: It is also prone to rust. The quality of the material (such as iron), which is the total quality of the product, is the life of the product. Rust also reduces the efficiency of heat dissipation and work product components or mechanical products. Its heat dissipation performance in components such as fans, heat sinks, heat pipes, etc., dissipates the heat generated by the equipment 'but' as Product jjzzvo jjzzvo No. 1 90128869 V. Description of the invention (2) ----- 5 倐 £ _

增’溫度甚至高達i 〇 〇 t ^ S 二高的散熱裝置,過高的溫度勢必;展散熱致率 響。 對5又備造成不良的影 一般物質對於熱會 熱,即將熱能表現在溫型態的表現,一為顯 用於相態的變化;而於電腦纟=b上’· 一為潛熱,即將熱能 品等設備所用的散熱構件,大二,子產品元件或機铖製 散熱片儲存顯熱,再經由加大2”、紹等材質,藉由 加與空氣熱交換的效率,每敎:;二氣接觸面積的方式,增 功率時’即達到散熱的功::乂換的速率大於熱源輸出的 綜上所述,為要使物體 ’以油漆或塗料加以披效果及色彩 如此又會影響原來之散熱效果[疋其中解決之道,但 此,若能提供散熱構件一、別疋金屬散熱構件,因 彩,實際上卻仍不影響甚至提ii—種不僅外觀上增加色 勢必會是一舉兩得的處理方式円,、散熱效率之披覆塗料, [創作特點] 辦加2: = ΐ逑所提於散熱構件欲求美觀耐用 ‘加散熱效盃之兩難問題 ρ美觀耐用,卻又無法 究試做較佳具散熱效果之斜*人乃積極潛心構思,研 本發明之主要目的,科i、、冬乃得本發明。 法,其主要以經微膠囊化③:J ί 一種吸熱顏料之製作方 於媒劑中,經嘴塗於散熱二2熱吸收物質做為顏料並加 塗在物體表面上。 、 面後做為塗料之用,並喷 第5頁 ^52296 修正 Λ. 曰Increasing temperature is even as high as 〇 〇 t ^ S two high heat dissipation device, excessively high temperature will inevitably lead to high heat dissipation. The negative effects on 5 are generally caused by heat. The heat energy will be expressed in the form of temperature, one is obviously used for the phase change; and on the computer 纟 = b ', one is the latent heat, which is about the heat energy. Cooling components used in products and other equipment, sophomore, sub-product components or machine-made heat sinks to store sensible heat, and then increase the heat exchange efficiency with air by adding 2 ", Shao and other materials, each 敎:; 二The method of air contact area, when the power is increased, 'that is, the work of heat dissipation :: the rate of change is greater than the output of the heat source. In summary, in order to make the object' paint or coating effect and color will affect the original Cooling effect [疋 One of the solutions, but if you can provide a heat dissipation component I. Do n’t use a metal heat dissipation component, because of the color, it does not actually affect or even mention ii—a kind of treatment that not only increases the appearance of color will definitely serve two purposes. Method 円, the coating of heat dissipation efficiency, [creative features] Banjia 2: = ΐ 逑 The heat dissipation component requires beautiful and durable 'The dilemma of adding a heat dissipation cup is beautiful and durable, but it ca n’t be tried to make it better With The oblique heat effect is conceived actively, and the main purpose of the present invention is to study the present invention. The method is mainly based on microencapsulation. ③: J ί A method for producing endothermic pigment is used as a vehicle. In the mouth, apply the heat absorbing material 2 as a pigment and apply it on the surface of the object. After the surface is used as a paint, and sprayed on page 5 ^ 52296 Amend Λ.

Ά 9012RSRQ 五、發明說明(3) - 法本發明之另一目的,係要提供一種吸熱顏料之製作方 /、係要&供一種略具強度之披覆性導熱媒材,除可增 σ構件美觀性又可提高構件的散熱效率。 ,像貴審查委員更瞭解本發明所應用之技術與原 欲例舉較佳之實施例’並配合圖式說明如后。 [創作說明] 本發明係 儲存並發散熱 囊化處理形成 塗料使用,其 熱吸收材 變化時所需的 高級醇、有機 六醇、十六酸 度會遲滯在相 散熱構件時, 吸收,並可快 產生的熱量。 至於熱吸 之’使熱吸收 理,經過微膠 m,以適合作 上述之媒 量的熱 細微顆 中·· 料可為 能量, 酸等物 之效果 變物質 熱源所 速的將 一種吸熱顏料之製作方 吸收物質,先將 粒的顏料,用以 一種相變物質, 屬潛熱熱儲存材 質,其中特別以 尤佳;當熱吸收 溶點一段時間, 產生的熱量會很 熱發散至空氣中 收材料之染色,選擇與 物質形成具特定顏色以 囊化的熱吸收物質其顆 為添加於媒劑中作為顏 劑,為幫助顏料微膠囊 法,主要係利用容易 其染色,然後做微膠 添加於媒劑當中做為 能吸收熱量做為其相 料,包含有直鏈烷、 -一十烧、十四醇、十 材料吸收熱量時,溫 故當熱吸收材料加於 快的被熱吸收物質所 ’有效的降低熱源所 其性質相容之染料為 做進一步微膠囊化處 粒大小可達1〜1〇〇 # 料使用。 附者於物體表面之接 55229612 9012RSRQ V. Description of the invention (3)-Method Another object of the present invention is to provide a producer of endothermic pigments, and to provide a slightly strong covering heat conductive medium, except that it can increase σ The aesthetics of the components can also improve the heat dissipation efficiency of the components. As for your review committee, you will know more about the technology and the original application of the present invention. The preferred embodiment will be exemplified, and will be described later in conjunction with the drawings. [Creation note] The present invention is used for storage and concurrent heat dissipation encapsulation to form coatings. The higher alcohols, organic hexaols, and hexadecanoic acid required when the heat absorbing material is changed will be absorbed by the phase heat dissipation member, and can be generated quickly. Of heat. As for the heat absorption, the heat absorption principle is passed through the micro glue, and the hot fine particles suitable for the above-mentioned medium amount of material can be energy, the effect of acids and the like can be changed to a material heat source. The production side absorbs the substance, and first uses the granular pigment for a phase change substance, which is a latent heat storage material, which is particularly preferred; when the heat absorbs the melting point for a period of time, the heat generated will be dissipated into the air to collect the material. For dyeing, select and form a specific color of the encapsulated heat-absorbing material. The particles are added to the vehicle as a pigment. To help the pigment microcapsule method, it is mainly used to dye easily, and then added to the vehicle as a microgel. In the agent, it can absorb heat as its phase material, which includes linear alkanes, -ten-carbon, tetradecanol, and ten materials to absorb heat. Therefore, when the heat-absorbing material is added to the fast heat-absorbing material, Dyes that are effective in reducing the heat source and are compatible in nature are used for further microencapsulation where the particle size can reach 1 ~ 100 #. Attachment to the surface of objects 552296

著劑’有環氧型、聚醋型等樹脂類,而以環氧-聚酯樹脂 二取適當比例之顏料微膠囊與環氣—聚脂樹脂,經過 高溫融溶分散後,冷卻、碾碎成粉體可作為塗料,以適當 工法如電暈靜電喷搶喷塗於散熱構件之表面上,可形成一 具一定強度之披覆層。 請參考第1圖,本發明詳細的運作流程如下所述(例 舉:熱吸收物質=十四醇、媒劑=環氧〜聚脂樹脂): a ·取適量熔融之十四醇及有色染料以約丨〇 〇 〇 : 3的比例 相混合直至完全溶解(顏色濃淡可依需求以1〇〇〇:工〜 1 0 0 0 : 3的比例調整)。 b·將上述染色之液態十四醇加入重量比約5%到3〇%的 ?¥八(?〇17“1^1&1〇〇11〇1聚乙烯醇),用均質機6 0 00]^111攪拌 成液滴約1〜1 〇 〇 V m大小之乳液。 c ·將乳液加入重量比約3 0 %到6 0 %的三聚氰胺—甲酿樹 脂預聚物水溶液中以5 5 °C的溫度持續加熱並授掉直至反應 完成,以形成膠囊化。 d ·終止反應後將反應完成之微膠囊過濾乾燥之。 e ·取微膠囊及環氧-聚酯樹脂以1 ·· 2至1 ·· ! 〇的比例混 合,經過高溫融溶分散後,冷卻、碾碎成粉體顏料,以適 當工法如電暈靜電喷搶喷塗於金屬或非金屬物體物體表面 經本發明實施’吾人可在任何物體表面形成一層塗佈 面,由於該塗佈面係由熱固性材質所形成,故具有一定之 強度與固定性’且其中之吸熱顏料扮演著吸熱、放熱的功The fillers include epoxy resin and polyacetate resin. The epoxy-polyester resin is used to take pigment microcapsules and ring gas-polyester resin in appropriate proportions. After melting and dispersing at high temperature, they are cooled and crushed. The powder can be used as a coating, and it can be sprayed on the surface of the heat-dissipating member by a suitable method such as corona electrostatic spraying to form a coating with a certain strength. Please refer to Figure 1. The detailed operation process of the present invention is as follows (for example: heat absorbing substance = tetradecanol, vehicle = epoxy ~ polyester resin): a. Take an appropriate amount of molten tetradecanol and colored dye Mix at a ratio of about 1000: 3 until it is completely dissolved (the color density can be adjusted at a ratio of 1000: 1000 to 100: 3 as required). b. Add the above-mentioned dyed liquid tetradecyl alcohol to a weight ratio of about 5% to 30%?? eight (? 017 "1 ^ 1 & 1001101 polyvinyl alcohol), using a homogenizer 6 00 ] ^ 111 Stirred into an emulsion with a droplet size of about 1 to 1000 V m. C. Add the emulsion to a 30% to 60% melamine-methanol resin prepolymer aqueous solution at 5 5 ° C. The temperature is continuously heated and allowed to cool until the reaction is completed to form an encapsulation. D · After the reaction is terminated, the reaction-completed microcapsules are filtered and dried. E · Take the microcapsules and epoxy-polyester resin at 1 ·· 2 to 1 ··! 〇 mixed in proportion, after melting and dispersing at high temperature, cooled and crushed into powder pigments, and sprayed on the surface of metal or non-metal objects by appropriate methods such as corona electrostatic spraying. A coating surface is formed on the surface of any object. Since the coating surface is formed of a thermosetting material, it has a certain strength and fixability, and the endothermic pigment therein plays a function of absorbing and releasing heat.

552296 _案號90128869 年月日 修正_; 五、發明說明(6) 為幫助散熱之用,查申請前並無相同製法及功效之吸熱顏 料及刊物公開,符合新穎性及創造性之專利要件,爰依法 提出申請,懇請 鈞局惠賜專用是禱。552296 _Case No. 90128869 Rev. _; V. Description of the invention (6) To help dissipate heat, check that the endothermic pigments and publications without the same manufacturing method and efficacy were published before the application, which meet the patent requirements for novelty and creativity, 爰Submit an application in accordance with the law.

Claims (1)

552296 丨公告本、 .L——---------:,4 901288 六、申請專利範圍 1 · 一種吸熱顏料之製作方法,主要係將熱吸收物質染色, 然後經微膠囊化處理,形成顏料,用以添加於媒劑當中做 為塗料喷塗於組件表面者,其主要包含以下步驟: a ·取熔融之十四醇與染料以丨〇 〇 〇 ··〗〜丨〇 〇 〇 : 3的比例相 混合至完全溶解; 本 1]:>552296 丨 Bulletin, .L ——--------- :, 4 901288 6. Scope of patent application 1 · A method for making endothermic pigments, mainly dyeing heat-absorbing substances, and then microencapsulating them To form a pigment, which is added to the vehicle as a coating and sprayed on the surface of the component, which mainly includes the following steps: a. Take the molten tetradecanol and dye to 丨 〇〇〇 ·· 〖~ 丨 〇〇〇 : 3 ratio phase to completely dissolve; this 1]: > 3_a 修正 b·將上述經染色之十四醇加入重量比5〜30%的PVA聚 &烯醇水溶液中,再擾抹士、 , λα ^1 、、+ m评成液滴為1〜1 0 0 # m大小的乳 ,设; c. $預聚 I到反d. e. 例混合 以電暈 2 ·如申 其中埶 1 μ、、有二十 3·如申 其'中媒 4 *如申 更包括 吸收物 5 ·如申 將上述乳液 物水溶液中 應完成以形 將反應完成 取微膠囊及 ,經過高溫 靜電喷搶喷 請專利範圍 吸收物質可 二烧、十四 請專利範圍 劑更包括聚 請專利範圍 熱吸收物質 質中。 請專利範圍 里Ο U u u /u RV二來乳欣—Τ除调· ,以50 Dc至7 0 °c的溫度加熱並持續攪拌成膠囊化; 之微膠囊過濾乾燥; S環氧'聚醋樹脂以1 :2至i :10的比冷卻、礙碎成粉體顏料, ^π屬非金屬物體物體表面上者。 第1項所述一種吸熱顏料之製 者 為直鏈貌、高級'醇、十六醇及十機酸,特別包括 第1項所述一種吸埶声四、十六酸。 禋及熱顏料之制你古土 酯型樹脂。 心衣作方法, 第1項所述一種吸熱顏 在微膠囊化卢wI作方法, 处 刖不必添加染料於熱 第1項所述—種吸熱顏料之製作方法,3_a Correction b. Add the above-mentioned dyed tetradecyl alcohol to a PVA poly & enol aqueous solution with a weight ratio of 5 to 30%, and then disturb the wiper,, λα ^ 1, and + m to evaluate the droplets as 1 to 1. 0 0 # m-sized breast, set; c. $ Pre-polymerized I to anti-de mixed with corona 2 · Ru Shen 埶 1 μ, and twenty three · Ru Shen ''s medium 4 * Ru Shen more Including absorbent 5 · If applying, the above emulsion should be completed in the aqueous solution. The reaction is completed to take microcapsules. After high temperature electrostatic spraying, spray the patent range. The absorbent substance can be burned twice, and the patent range agent can also be collected. Patent scope Heat absorption material. Please apply within the scope of patent 〇 U uu / u RV Erlai Ruxin-T detune ·, heating at 50 Dc to 70 ° C and continuously stirring to form capsules; filtering and drying microcapsules; S epoxy 'poly vinegar The resin is cooled at a ratio of 1: 2 to i: 10 to prevent it from breaking into powder pigments, and ^ π is on the surface of non-metallic objects. The producers of the one endothermic pigment described in item 1 are straight-chain appearance, higher 'alcohols, cetyl alcohol, and decanoic acid, and specifically include the one and four hexadecanoic acids described in item 1.古 and thermal pigments made of your ancient clay ester resin. The method of making heart clothes, a kind of heat-absorbing face described in item 1. In the method of microencapsulation, there is no need to add a dye to heat. The method described in item 1—a kind of heat-absorbing pigment, 2003,07.16.011 552296 案跣 fJ0I28869 —年 a 修正 六、中請專利範阗 其中吸熱顏料喷塗於物體表面,可以導熱線、導熱片將發 熱源之溫度導往該塗佈層,及以發熱源直接接觸物體,達 到幫助散熱之效者。 m 第12頁 2003. 07.16.012 552296 ❖φ^4^4^>4今香令今令令今令2003,07.16.011 552296 case JfJ0I28869 — year a Amendment VI. Chinese Patent Application 阗 where the endothermic pigment is sprayed on the surface of the object, and the heat source can be used to direct the temperature of the heat source to the coating layer and heat The source directly contacts the object to achieve the effect of helping to dissipate heat. m page 12 2003. 07.16.012 552296 ❖φ ^ 4 ^ 4 ^ > 4 圓箄涵聆(澌噼窑洚渰峰韋) 552296Yuanyang Hanling (Yan Kiln Fengfeng Wei) 552296 Γ 敗 7, 1Γ Lost 7, 1 對照组(無塗佈吸熱塗料) 實驗組(有塗佈吸熱塗料) τι 60.0 40.8 Τ2 64.8 43.0 Τ3 56.7 39.6 Τ4 53· 8 38.1 Τ5 52.6 36· 9 Τ6 51.6 36.4 Τ7 51.4 36,4 Τ8 51· 6 36.5 Β1 61.2 42.1 發熱塊 70.1 43.45 Β3 57.4 40.1 Β4 54.6 38.6 Β5 52· 5 36.8 Β6 50.5 36· 3 Β7 51· 8 36· 4 Β8 51.5 36.2 表一Control group (without endothermic coating) Experimental group (with endothermic coating) τι 60.0 40.8 Τ2 64.8 43.0 Τ3 56.7 39.6 Τ4 53 · 8 38.1 Τ5 52.6 36 · 9 Τ6 51.6 36.4 Τ7 51.4 36,4 Τ8 51 · 6 36.5 Β1 61.2 42.1 Heating block 70.1 43.45 Β3 57.4 40.1 Β4 54.6 38.6 Β5 52 · 5 36.8 Β6 50.5 36 · 3 Β7 51 · 8 36 · 4 Β8 51.5 36.2 Table 1
TW90128869A 2001-11-16 2001-11-16 Method for producing endothermic pigment TW552296B (en)

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