TW523394B - Compost granulation method and product - Google Patents

Compost granulation method and product Download PDF

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TW523394B
TW523394B TW089123376A TW89123376A TW523394B TW 523394 B TW523394 B TW 523394B TW 089123376 A TW089123376 A TW 089123376A TW 89123376 A TW89123376 A TW 89123376A TW 523394 B TW523394 B TW 523394B
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Taiwan
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fertilizer
mixture
patent application
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container
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TW089123376A
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Chinese (zh)
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Robin Phinney
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Airborne Ind Minerals Inc
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Priority claimed from PCT/CA2000/000522 external-priority patent/WO2000067550A1/en
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Abstract

Method and product of granulating compost for formulation of fertilizers. In one embodiment, the compost is ground to dust and pan granulated. A variety of ancillary materials may be incorporated into the compost mix for a wide range of possible applications. An embodiment is provided where agricultural seeds may be encapsulated in compost to enhance the quality of seed and reduce wastage during planting.

Description

523394523394

【相關參考案】 本發明申請案係請求下列兩案之優先權,美國發明I 利臨時申請案號6 0/ 1 32, 5 6 9,其申請日為1 9 9 9年5月5日, 以及60/132, 6 81,其申請日為1999年5月5日。 【技術領域】 本發明係有關肥料(compos t)粒化方法,更明確的 說,係有關一種生產高品質肥料粒化物及多成份肥料粒 物,以便用於肥料領域之應用。 【技術背景】 粒化技術是一成熟之技術領域,且近期重要的改良可 參閱德達爾等人(Derdall et al·)所擁有之美國專利第5 460, 765號,其發證日為1995年10月24日。以及,後續之’ 費尼(Phi nney)之美國專利第6, 013, 209號,其發證日$為 2 0 0 0年1月1 1日。 戍…’ 關於德達爾等人之專利案’此係揭露改良此技術,其 顯示出一超微細(-2 0 0號篩網)並未造成粉末之核化:作 是,卻造成材料之黏合而形成大的圓形丸狀物。此過程並 非不像眾所週知的雪球之成長。此德達爾等人所發明之技 術’清楚的提供一種極佳之過程控制,其有效的將粒子與 結合劑接觸而變大。結果,使用一般之5%或更少量之結合 劑添加物’卻大約將此量加倍。證據顯示,若結合劑之量 可以減少的話,則此粒化物之供給料量可以增加,換勺节 說,提供了一改進的丸狀物或粒化物。 、 此德達爾等人所建立之處理程序為,用極大量之晶體[Related References] This application claims priority to the following two cases. The United States Invention Provisional Application No. 6 0/1 32, 5 6 9 has an application date of May 5, 1999. And 60/132, 6 81, the application date of which was May 5, 1999. [Technical Field] The present invention relates to a method for granulating fertilizer (compos t), and more specifically, to a method for producing high-quality fertilizer granules and multi-component fertilizer granules for use in the field of fertilizers. [Technical background] Granulation technology is a mature technology field, and recent important improvements can be found in US Patent No. 5 460, 765 owned by Derdall et al., The date of issue is 1995 October 24. And, the follow-up US patent No. 6,013,209 of Phinney, the date of issue of the certificate is January 11, 2000.戍 ... 'About the patent case of Dedal et al.' This is a disclosure to improve this technology, which shows that an ultra-fine (-200 mesh) has not caused the nucleation of the powder: Yes, but it caused the adhesion of the material A large round pellet is formed. This process is not unlike the growth of the well-known snowball. The technology invented by Dedal et al. Clearly provides an excellent process control which effectively contacts the particles with the binder to grow larger. As a result, the usual use of 5% or less of the binding agent additive 'has approximately doubled this amount. Evidence shows that if the amount of the binding agent can be reduced, the amount of granules supplied can be increased. According to the spoon changing section, an improved pellet or granule is provided. The process established by Dedal et al. Is to use a very large number of crystals.

523394 五、發明說明(2) (crystal)或種子,在一步驟中 為本項技術領域之重大改良 θ 成形。雖然此 亩接蔣姑祖私艮仁疋,匕並不打算在容器中 ==化成型。如果一材料之混合物包括供給料以 便粒彳’且水伤由一已預先溼化之混合物提供,它可以有 ίΠ?:或核化劑。然後’此材料可以直接在容器 中使用,/、係包含粉狀之供給料以便成長成一粒化物。 等人很顯著的改進了粒化技術,其係藉由示範 叙狀材料可以被粒化’並提供一種子材料,其係做為一核 心以便形成:丸狀物。纟申請人努力研發前,德達爾等人 已有效的教不此新技術’而且’當種子材料可以被使用 時,是一極為有效之粒化成形過程。這樣的粒狀物在其中 心處具有明顯的核心。 在此技藝中,大家都瞭解任何粒子大於+ 150號篩網及 - 100號篩網將導致在容器中過度核化 (over-nucleation),其不可避免的會造成各粒子黏在一 起成為許多團。結果’為了要獲得具有足夠強度之丸狀 物’一般會使用4%至10%之結合劑,以便使材料具有適當 之黏結力,進而成為一強固之粒狀物。 德達爾等人很清楚的教示,如果所用之種子超過一預 定尺寸,則在過程中會有穩定性之問題。總之,德達爾等 人係最先提供將粉狀材料粒化之過程。 關於費尼之揭鉻技術’比起德達爾等人之最初的專利 而δ ’又更進一步改進。在費尼之專利中,他發現了如果 使用一尺寸分佈介於-35號至150號篩網之核化劑,一種子523394 V. Description of the invention (2) (crystal) or seed, a major improvement in this technical field in one step θ forming. Although this acre is connected to Jiang Guzu's private property, the dagger is not intended to be formed in the container. If a mixture of materials includes a feed to pill 'and the water damage is provided by a pre-wetted mixture, it may have a nucleating agent. Then this material can be used directly in the container. It contains powdered feed material to grow into a pellet. Et al. Have significantly improved the granulation technique by demonstrating that the material can be granulated ' and provide a sub-material that acts as a core to form: pellets.前 Before the applicant's hard work in research and development, Dedal et al. Have effectively taught this new technology ' and ' when the seed material can be used, it is an extremely effective granulation forming process. Such granules have a clear core at the center. In this technique, everyone knows that any particles larger than +150 mesh and -100 mesh will cause over-nucleation in the container, which will inevitably cause the particles to stick together into many clusters. . As a result, in order to obtain a pellet having sufficient strength, 4% to 10% of a binding agent is generally used, so that the material has a proper cohesive force, and then becomes a strong pellet. Dedal et al. Clearly teach that if the seeds used exceed a predetermined size, there will be stability problems in the process. In short, Dedal et al. First provided the process for granulating powdery materials. The Fenni's chrome-discovering technology is further improved than the original patent of Dedal et al. In Fenni's patent, he found that if a nucleating agent with a size distribution between -35 and 150

第5頁 523394 五、發明說明(3) , 會成長且包含與最終產品相同之材料,且其尺寸分佈大約 介於-8至+4號篩網。德達爾等人之專利與費尼之專利間之 差異為在費尼的技術中’ 一開始並不需要一種子來達到粒 化之目的。此種子可藉由使用一初始核化劑於粉中,以形 成一種子,在稍後之粒化過程中,該種子會繼續成長。此 使得最終產品的品質有顯著的改進。主要的優點之一是粒 化物的強度以及對種子之均一材料之成長。對於所使用的 核化劑,其效力係極渺小。比起依照德達爾等人之專利所 製成之粒化物,依照費尼之專利所製成之粒化物則沒有核 心。亦即,根據費尼之方式所製成之粒化物具有均勻且連丨_ 續之剖面。據此,對於在每一個粒化物或是丸狀物中,它 所包含之供給料量較高。 費尼及德達爾等人之專利均對於具有高散裝密度 (bulk density)材料粒化技術均有很深入的介紹。在這些 例子中,硫是被拿來做粒化之範例來說明。硫具有相當高 之散裝密度,大約是每立方英呎30至35磅之間。此散裝密 度代表一粒子之尺寸介於180號至300號篩網。在此散裝密 度下,有足夠之質量來允許產品粒化之形成。此亦可發 現,這並非適用所有的材料。當此散裝密度大幅下降,例 如由硫降至肥料時,可能會產生一些問題。肥料材料之粒 化是十分複雜的。當肥料呈粉狀時,具有極輕之重量’具 抗水性,而且由於靜電之作用’各別之粒狀物彼此排斥。 肥料之散裝密度大約是介於每立方英呎20至25磅間’大約 是粒狀物尺寸在2 4 0號至4 0 0號篩網間。依照粉狀物之狀態Page 5 523394 5. Description of the invention (3), will grow and contain the same materials as the final product, and its size distribution is about -8 to +4 sieve. The difference between the patents of Dedal et al. And Fenni's patent is that in Fenni's technology, 'a seed is not needed to achieve the purpose of granulation. This seed can be formed into a seed by using an initial nucleating agent in the flour, and the seed will continue to grow during later granulation. This leads to a significant improvement in the quality of the final product. One of the main advantages is the strength of the pellets and the growth of a uniform material for the seeds. The effectiveness of the nucleating agents used is extremely small. Compared to granules made according to the patent of Dedal et al., Granules made according to the patent of Feney have no core. That is, the granules made according to the Fenny method have a uniform and continuous cross section. According to this, for each granule or pellet, it contains a higher amount of feed. The patents of Feney and Dedal et al. Both have a deep introduction to the granulation technology of materials with high bulk density. In these examples, sulfur is used as an example for granulation. Sulfur has a fairly high bulk density, which is between 30 and 35 pounds per cubic foot. This bulk density represents a particle size between 180 and 300 mesh. At this bulk density, there is sufficient quality to allow the granulation of the product. It can also be found that this is not applicable to all materials. Problems can arise when this bulk density decreases significantly, such as from sulfur to fertilizers. Granulation of fertilizer materials is very complicated. When the fertilizer is in a powder form, it is extremely light-weight ' it is water-resistant, and due to the effect of static electricity ' The bulk density of the fertilizer is between about 20 and 25 pounds per cubic foot, and it's about the size of granules between 2400 and 400 mesh. According to the state of powder

第6頁 523394 五、發明說明(4) 與肥料之性質’就習知技術與費尼及德達爾等人所教示之 技術而言,若要將有價值之農作穀物化合物製成粒化物, 則必須做相當之修改。 肥料粒化方式已見於習知技術中,如以鍍層之方式, 或是以其他包裹(或包覆)之方式 將種子保護住,直到現 在,需要將它發芽。 在此技術領域之典型前案,有美國專利第3, 905, 796 號,1975年頒發給葛爾費(Ghelfi)。此案教示了一將已脫 水之天然肥料為主之肥料,其中,一均勻且且耐久之漿狀 物(p u 1 ρ )被粒化 美國專利第 露了一種製造擠 牲畜天然肥料係 50%至55%之水份 一步打碎成更小 一步討論加至肥 化。而且發現一 介面活化劑,則 何解決這些問題 戴維斯(D a v 人工肥料(ferti 產品之方法。此 源’其係放入一 混合泥狀物係被 4, 082, 532號,1978年4月4日發證,其揭 制牲畜天然肥料丸狀物之方法,其中,該 混合成為一漿狀物,其包括重量比例約 。此材料先透過一絞繩而被擠製,再更進 /的顆粒。在此案與前述之前案中,並未進 料中之農業添加物,而且,只稍微提到粒 it料材料成為乾燥之粉狀時,如果沒有 L、t將材料加濕。而此等前案均未教示如 而達到粒化的目的。 is)在美國專 四寻利第5, 〇43, 007號中提供了一 nzer)之產 〇 + H t 崇袒似 σσ或疋無結合劑之人工肥料之 示供了 一他從7 攪扮播由^ 及—第一及第二營養 偉、" 熱直到成為一混合泥狀物。此 傳运至-乾燥器中,並且,纟真空令乾Page 6 523394 V. Description of the invention (4) and the nature of fertilizers' As far as the conventional technology and the technology taught by Fenni and Dedal et al. Are concerned, if valuable agricultural grain compounds are to be granulated, then Substantial changes must be made. The granulation method of fertilizer has been seen in the conventional technology. For example, the seed is protected by plating, or by other coating (or coating), until now, it needs to be germinated. A typical previous case in this technical field is US Patent No. 3,905,796, issued to Ghelfi in 1975. This case teaches a fertilizer based on dehydrated natural fertilizers. Among them, a uniform and durable slurry (pu 1 ρ) was granulated. The US patent discloses a natural fertilizer system for squeezed livestock. 55% of the water is broken up into smaller steps to discuss the addition to the fertilizer. And found an interface activator, how to solve these problems Davis (D av artificial fertilizer (ferti product method. The source 'It is put into a mixed mud system is No. 4, 082, 532, 1978 4 A certificate was issued on April 4 for the method of exposing livestock natural fertilizer pellets, in which the mixing becomes a slurry, which includes a weight ratio of approximately. This material is extruded through a stranded rope, and then further In this case and the previous case, there are no agricultural additives in the feed, and only a slight mention is made that when the pellet material becomes a dry powder, the material is humidified without L and t. And These previous cases have not been taught to achieve the purpose of granulation. Is) The product of a zzer) is provided in US Patent No. 5, 〇43, 007. 0 + H t is like σσ or nothing The display of the artificial fertilizer of the binding agent is provided from 7 to 12 and the first and the second nutrition, and heat until it becomes a mixed mud. This is transported to a desiccator and dried under vacuum

523394 五、發明說明(5) 無’之後冷卻以產生'粒狀物或1 一半粒狀之人工肥料,而 其中包覆一種子核心,且包覆另一層次要的營養晶狀層。 在美國專利第5, 72 5, 6 3 0號專利,1 998年3月1〇日頒發 給羅伯兹(Roberts)等人’其係為一如前所述之肥料顧^以 及一乾燥之粒化肥料。此粒化肥料包含一 C1-C6烧酸 (alkanoic acid)或此化合物之鹽加在一乾燥載運器上, 以形成一粒化肥料。此為^一間早錢覆過程,但是並未提供 一具有均勻附屬或輔助肥料化合物之粒化物。 對於其他有關人工肥料/種子包覆技術之前案,美國 專利第4,779,376號’ 1998年10月25日,其係揭露了一種 包覆方法,將植物種子包入一含飽合水之水凝膠之膠囊 中 〇 強生(Johnson)等人,於美國專利第3, 648, 4〇9號, 1 9 7 2年3月1 4日發證之專利,則揭露一除草劑運送過程以 便製造此產品。此揭露一種抗除草劑晶片(wafer),其包 裹一種子及一水溶性營養結合劑之蛭石(vermicuHte)及 活性的木碳之混合物’其係最後會壓縮成一預定之形狀, 在此例中則為一晶片狀。 其他參考前案一般是關於鍍層或是包覆技術,如美國 專利第 4, 759, 151、5, 849, 320、3, 950, 891、3, 950, 152、 5, 435, 82 1 及3, 651,772 ° 此前案不論是單獨引用或是結合引用,均未提供肥料 粉材料之粒化方法’該肥料可以包括輔助肥料、時間釋放 材料、或其他適合的習知添加劑。另外,事實上也未教示523394 V. Description of the invention (5) After the absence of ', it is cooled to produce' grained or 1 half-grained artificial fertilizer, which is covered with a sub-core and covered with another layer of nutritional crystalline layer. In U.S. Patent No. 5,72 5,630, issued to Roberts et al. On March 10, 1998 'It is a fertilizer as described previously and a dried Granulated fertilizer. The granulated fertilizer comprises a C1-C6 alkanoic acid or a salt of the compound and is added to a dry carrier to form a granulated fertilizer. This is an early process, but it does not provide a granulate with uniform auxiliary or auxiliary fertilizer compounds. For other previous cases of artificial fertilizer / seed coating technology, US Patent No. 4,779,376 'October 25, 1998, discloses a coating method that encapsulates plant seeds in a saturated water solution. In a hydrogel capsule, Johnson et al., A patent issued in U.S. Patent No. 3,648,409, March 14, 1972, discloses a herbicide delivery process in order to Make this product. This disclosure discloses a herbicide-resistant wafer, which is a mixture of vermicuHte with a water-soluble nutrient binding agent and active wood charcoal, which is finally compressed into a predetermined shape. In this example, It is a wafer. Other previous cases are generally related to coating or coating technology, such as U.S. Patent Nos. 4,759,151, 5,849,320, 3,950,891, 3,950,152, 5,435,821 and 3 , 651,772 ° The previous case, whether alone or in combination, did not provide a method for granulating fertilizer powder materials. The fertilizer may include auxiliary fertilizers, time-release materials, or other suitable conventional additives. Also, it ’s not actually taught

第8頁 523394 丨丨- 五、發明說明(6) __ 有關肥料之粒化。同時 一 提供一種粒化物產品,具 出已檢視之習知技術未能 持所需之特性,例如圓球,子包裹在$,而且仍然維 率等等。我們一直希望能有一孓、,子破裂之強度、溶解 料,而這些肥料包括呈種產品直接強化土壤的肥 或更小之筛網尺;:ί:;狀:肥料材料,其係在-150號 化,此肥料材料可為前述對二二肥料材料一起粒 知肥料。本發明也滿足其它=:。料無抗水性問題之習 【產業上之利用性】 而 本發明係在肥料技術i Jb I Q 【本發明之目的】 *領域中具有產業上之利用性。 本發明之一目料提供一種無需核化劑、種 其他初始材料之粉狀肥料粒料之改進方法。本^ ^ :例,另-目的是提供一種包覆之方法,#由粒化之;J 作殺物種子包裹而達到包裹種子之目的。 將農 本發明之又一目的在於提供一種肥料粒化之方法,苴 特徵在於該方法包括下列步驟: … 知供一乾燥之粉狀肥料,其中90%之尺寸之分佈小 於-1 5 0號篩網; ' 形成一由乾燥之粉狀肥料與含水份結合劑所組成之 濕潤混合物,該混合物之中含有1 1 %重量比例之水份; 混合該混合物至一足以將該乾燥之粉狀肥料之抗水 性消除,使該乾燥之粉狀肥料吸收該結合劑中之水份, 並形成一可流動之合成物;Page 8 523394 丨 丨-5. Description of the invention (6) __ About granulation of fertilizer. At the same time, a granulated product is provided, which has the characteristics that the conventional techniques reviewed have not been able to maintain the required characteristics, such as round balls, sub-packages in $, and still the dimensions and so on. We have always hoped to have the strength and dissolution of the seeds, and these fertilizers include fertilizers that directly strengthen the soil with a product or a smaller sieve ruler: ί :; shape: fertilizer material, which is -150 No., this fertilizer material can be the same fertilizer as the aforementioned two-two fertilizer material. The present invention also satisfies other = :. No water resistance problem [Industrial applicability] The present invention is in fertilizer technology i Jb I Q [Objective of the present invention] * It has industrial applicability in the field. One aspect of the present invention provides an improved method for pulverizing fertilizer granules without nucleating agents and other starting materials. This ^ ^: example, another-the purpose is to provide a coating method, # by granulating; J as the killer seed wrap to achieve the purpose of wrapping seeds. Another objective of the present invention is to provide a method for granulating fertilizer, which is characterized in that the method includes the following steps:… for a dry powdery fertilizer, in which 90% of the size distribution is less than −150 sieve Net; 'forming a moist mixture consisting of dry powdery fertilizer and moisture-containing binder, the mixture containing 11% by weight of water; mixing the mixture to a level sufficient to dry the powdery fertilizer The water resistance is eliminated, so that the dry powdery fertilizer absorbs the water in the binder and forms a flowable composition;

第9頁 523394Page 9 523394

五、發明說明(7) 藉由接觸該混合物及加上額外的結合劑及—介面、、舌 性劑’於一容器中,將該混合物粒化成為複數個2 / 物;及 ' 形成肥料粒狀物,其尺寸之分佈介於3號至丨2穿& 網。 ^師 有利的是、,當被加熱及乾燥後,此肥料已被消毒殺 - 囷’因此’臭味及病菌源均非問題。此亦允許此肥料'由任 - 何形式之來源製成,包括動物、植物或兩者均有皆可。 關於粉狀肥料之抗水性,它被發現若在該容器中提供 一重量百分比例達1 0%之自由基水份時,此製造過程將可八 行,且產生粒狀物。在此情形下,本發明之一重要作法是 加入介面活化劑已便降低肥料之表面張力,並且允許在缺 之核化劑或其他初始材料之情形下,仍可在容器内直接產 生粒化過程。此過程係可有效的達到肥料粒化之目的。 習知技術中已揭示了使用核化劑以達到將供給材料在 ”乾燥的情形下粒化。此亦在費尼之美國專利中討論到。 關於這一種情形也見於德達爾等人之專利。在費尼之進一 步改進後,特別是指在PCT申請第PCT/CA9 9/ 0 0 3 0 0號之公 告資料(國際公告號WO/9 9/5402 9公開於1 9 9 9年10月28日) _ 中,已發現在容器中之粒化透過提供一溼混合物(混合物 _ 包括水份、供給物及介面活化劑)是可達到的,而且,在 ^ 容器中使其接觸此溼混合物。此亦達到了在欠缺核化劑或 - 種子的情形下’直接在容器申形成粒化物^即,此粒化可 -以刪去形成一種子之步驟。V. Description of the invention (7) By contacting the mixture and adding additional binding agents and -interfaces, tongue agents 'in a container, the mixture is granulated into a plurality of 2 / things; and' form fertilizer particles The size distribution of the object is between No. 3 and No. 2 through & net. It is advantageous that, when heated and dried, the fertilizer has been disinfected and killed-囷 'Therefore, odor and pathogenic sources are not a problem. It also allows this fertilizer to be 'made from any form of source, including animals, plants or both. Regarding the water resistance of the powdery fertilizer, it was found that if a weight percentage of free radical water of up to 10% was provided in the container, the manufacturing process would be eight lines and produce granules. In this case, an important method of the present invention is to reduce the surface tension of the fertilizer by adding an interface activator, and allow the granulation process to be directly generated in the container in the absence of a nucleating agent or other initial materials . This process can effectively achieve the purpose of fertilizer granulation. The use of nucleating agents has been disclosed in the prior art to achieve "drying" of the feed material. This is also discussed in Fenni's U.S. patent. This situation is also seen in Dedal et al. After the further improvement of Fenny, especially referring to the publication information of PCT Application No. PCT / CA9 9/0 0 3 0 0 (International Publication No. WO / 9 9/5402 9 published on October 28, 1999 It has been found that granulation in a container is reachable by providing a wet mixture (mixture_ including water, supplies, and interface activators), and contacting the wet mixture in a container. This also achieves the formation of granules directly in the container in the absence of nucleating agents or seeds. That is, the granulation can be-to delete the step of forming a child.

第10頁 523394 視肥料 密度及 。對於 利合作 乾燥法 此對於 來看, 因是此 簡言之 排斥的 乏核化 標9 ,在完 ,要來 達爾等 之外, 法主要 與肥料 一特殊 是可以 應用。 化物。 中被粒 轉速度 之特性而 其他姓質 這些性質 條約之簡 ,特別是 肥料之特 此材料被 粉狀肥料 ,對於具 且抗水的 劑及一種 全瞭解肥 解決肥料 人之方法 沒有一個 是解決具 之性質不 用途之較 被允許的 也有可能 如德達爾 化後將會 ’容器傾 定,肥料製程設計者將面 已被提及可能會將此肥料 ’直接之容器粒化,例如 稱)案中是不方便的β方 藉由一梭化劑之運作將一 性而言,亦無法被滿足。 非有益於一核化劑之準 具有抗水性之問題以及靜 有這些特性之材料而言, ,而無法有效的粒化成一 子時,難以達到市場可^ 料性質 教化之 與費尼 方法特 有較高 同。 大尺寸 °較大 是為了 等人之 達到一 斜度及 五、發明說明(8) 如上所述, 臨新問題。散裝 粒化過程複雜化 在前述之PCT(專 考慮其他現存之 種子預先成形, 以核化劑之尺寸 備。一部份的原 電作用之困擾, 它本來就是自我 丸狀物,特別缺 受之粒化物之目 在此例子中 程經驗的情形下 人都可同意,德 進此技術β除此 化,因為這些方 題,而它的性質 如果要形成 之肥料粒化程序 在高爾夫球場之 而做成較大之粒 法,材料在容器 點,此視容器選 以及具有深度之 實際問題。大部: 之方法已羥大鴨改 別適用於肥料之. 散裝密度材料之問 之粒化物’多階段 的粒化物是可 要有時間釋敌功致 方法與費尼之方 適當尺寸之平衡 其他參數而定 第11頁 523394 五、發明說明(9) 此’在此情況下,若有需要,可以搭配一第二容器以便作 材料之成長。 據此’根據本發明一實施例之目的,係提供一種肥料 粒化方法’其特徵在於包括下列步鱗: 提供一乾燥之粉狀肥料,其中9〇 %之尺寸之分佈小 於-1 5 0號篩網; 形成一由乾燥之粉狀肥科與含水份結合劑所組成之 濕潤混合物,該混合物之中含有11 %重量比例之水份; 混合該混合物至一足以將該乾燥之粉狀肥料之抗水 性消除,使該乾燥之粉狀肥料吸收該結合劑中之水份,丨_ _ 並形成一可流動之合成物; 藉由接觸該混合物及加上額外的結合劑及一介面活 性劑,於一容器中,將該混合物在一第一階段中粒化成 為複數個粒狀物,該複數粒狀物之尺寸係分佈介於3號 至12號篩網,且至少包括一部份之尺寸介於8號至12號 篩網; 將該已成型之複數個8號至12號篩網之粒狀物在一 第二階段中再接觸該混合物與結合劑;及 形成介於-3號至+ 8號筛網尺寸之肥料粒狀物。 在某些情形下’希望要產生比刖述目的所述尺寸還大4 之粒化物。例如,以製程之觀點而言’將_ 3號至+ 8號篩網 尺寸之粒化物更進一步成長至〇·5英叶或更大。此係可使 用一鼓式粒化器而達成。類似之早元操作如結合劑之添加 物、表面活化劑、與結合劑攪拌混合等,均可觀察到在鼓Page 10 523394 Depending on fertilizer density and. For the cooperative drying method, this is because, in a nutshell, the depleted nucleation standard 9 is used. In addition to Dal, etc., the method is mainly applicable to fertilizers. Compound. The characteristics of the medium-speed conversion rate and other properties are simplified, especially the fertilizer. This material is powdered fertilizer. For a water-resistant agent and a comprehensive understanding of fertilizers, there is no solution to solve fertilizer problems. The nature and use of the fertilizer is more likely to be allowed. For example, after the Dadalization, the container will be decanted. The designer of the fertilizer process will be mentioned that the fertilizer may be directly granulated in the container, for example. The inconvenient beta side cannot be satisfied by the operation of a shuttle agent. For materials that are not beneficial to a nucleating agent and have quasi-water resistance problems, and materials that have these characteristics, but cannot effectively granulate into a child, it is difficult to achieve marketable properties. Gao Tong. The large size ° is larger in order to wait for people to reach a slope and 5. Description of the invention (8) As mentioned above, new problems are encountered. The bulk granulation process is complicated in the aforementioned PCT (specially considering the pre-formation of other existing seeds, prepared in the size of a nucleating agent. Part of the original electrical effect is troubled, it is originally a self-pill, especially a grain that is not affected In the case of intermediate-range experience in this example, everyone can agree that Dejin's technology β is eliminated because of these topics, and its properties are made if the fertilizer granulation process to be formed is made on the golf course. For the larger grain method, the material is at the container point. This depends on the container selection and the practical problems of depth. Most of the methods: The method has been changed to apply to fertilizers. Granulation is determined by the time required to balance the enemy ’s power with the appropriate size and other parameters of Fener ’s formula. Page 11 523394 V. Description of the invention (9) In this case, if necessary, it can be combined with a The second container is used for material growth. Accordingly, according to the purpose of an embodiment of the present invention, a method for granulating fertilizer is provided, which is characterized by including the following steps: Powdery fertilizer, 90% of which has a size distribution smaller than -150 mesh; Forms a wet mixture consisting of dry powdery fertilizer and moisture binder, the mixture contains 11% Water content by weight; mix the mixture to a level sufficient to eliminate the water resistance of the dry powdery fertilizer, so that the dry powdery fertilizer absorbs the water in the binder, and form a flowable synthesis By contacting the mixture and adding additional binding agents and a surfactant, in a container, the mixture is granulated into a plurality of granules in a first stage, the size of the plurality of granules It is distributed between the No. 3 to No. 12 sieve, and at least includes a part of the size between No. 8 to No. 12; In the second stage, the mixture and the binder are contacted again; and fertilizer granules with a size of -3 to +8 are formed. In some cases, it is' desired to produce a size larger than that described for the purpose described. Granules of 4. For example, from a process standpoint, 'will_ 3 to + No. 8 mesh size granules grow even further to 0.5 inches or larger. This can be achieved using a drum granulator. Similar early-stage operations such as additives for binding agents, surfactants, Mixing with the binding agent, etc., can be observed in the drum

第12頁 523394 五、發明說明(ίο) 式容器中達到0. 5英叶粒化物之成長。 對於那些熟習該技術之人士而言,結合劑之介面活化 劑在加到該粒化容器中之特殊臭味並不有任何影響,關鍵 點是,在容器中之材料必須供應適當的介面活化劑,以便 有效的將粒化物與結合劑黏杰在一起而成為該肥料混合 物。此時,結合劑之介面活化劑可以被混合且添加至11 % 之重量比例,或是同步分開的加入。當然,亦可由熟習該 技術之人士來修改。 本發明之更進一步應用,此技術已觸及農作穀物種子 包覆技術,亦即,發明之另一目的是提供一種將一穀類種 子外包覆肥料而成為一粒化丸狀物之方法,其特徵在於包 括下列步驟: 提供一乾燥且呈粉狀之粉狀肥料,其中9 0%之尺 寸之分佈小於-1 5 0號篩網; 提供複數個榖類種子; 形成一由乾燥之粉狀肥料與含水份結合劑所組成之 濕潤混合物,該混合物之中含有11 %重量比例之水份; 混合該混合物至一足以將該乾燥之粉狀肥料之抗水 性消除,使該乾燥之粉狀肥料吸收該結合劑中之水份, 並形成一可流動之合成物; 提供一粒化容器; 將該容器與該穀類種子接觸; 將該容器與該混合物接觸; 於該容器中,藉由接觸該混合物與該穀物種子,將Page 12 523394 V. Description of the invention (ίο) The growth of 0.5-ying leaf granules in the container. For those who are familiar with this technology, the special odor of the binder's interface activator added to the granulated container has no effect. The key point is that the material in the container must be supplied with an appropriate interface activator. In order to effectively bind the granules and the binder together into the fertilizer mixture. At this time, the interface activator of the binding agent can be mixed and added to a weight ratio of 11%, or added simultaneously and separately. Of course, it can also be modified by those familiar with the technology. A further application of the present invention is that this technology has touched the agricultural grain seed coating technology, that is, another object of the invention is to provide a method for coating a grain seed with fertilizer and turning it into a pellet. The method comprises the following steps: providing a dry and powdery powdery fertilizer, wherein 90% of the size distribution is less than -150 mesh screen; providing a plurality of maggot seeds; forming a dry powdery fertilizer and A moist mixture composed of a moisture-containing binder, the mixture containing 11% by weight of water; mix the mixture to a level sufficient to eliminate the water resistance of the dry powdery fertilizer, and absorb the dry powdery fertilizer Moisture in the binder and form a flowable composition; provide a granulated container; contact the container with the cereal seeds; contact the container with the mixture; in the container by contacting the mixture With that grain seed will

523394523394

該縠物種子外包覆混合物而粒化;及 形成穀物種子外包覆肥料之粒狀物。 :何種子材料均可以被包覆。適當之種子例如為卡諾 ^ ^ : UanoU seeds)、加納利種子(carary “以幻、油 吹跑至別Ϊ其Ϊ ί。問題是’由於這些種子非常輕,常被 夫空中撒到預定之地點,如此,造成農 中撒"插早貝士。另外,在許多國家,居民已不喜歡以"空 住,重旦辦之加式種植農作。然而’藉由將這些種子包覆 化勺種子被保護住…當種子被種植時,粒 種二料《二=各種子間具有間隔°而種子包覆物之其中一 提供鍤覆肥料,因此,它也可做為種子之肥料,更能 砷二 、長所需。另外’添加其他適當之材料,將如下 1 j ^成一所要之產品。The mash seed is coated with a mixture to granulate it; and the grain seed is coated with a fertilizer to form a pellet. : Any sub-material can be coated. Suitable seeds are, for example, Kano ^: UanoU seeds), Canary seeds (carary "with magic, oil blown away to don't Ϊ Ϊ 问题. The problem is' Because these seeds are very light, they are often scattered in the air to the intended The location, in this way, has caused early crops to be planted among the farmers. In addition, in many countries, residents no longer like to use the "vacant living", Chongdan-based additive farming. Spoon seeds are protected ... when the seeds are planted, the two kinds of seeds "Second = There is an interval between various seeds, and one of the seed coatings provides a covering fertilizer, so it can also be used as a seed fertilizer, more Can be arsenic II, long as needed. In addition 'add other appropriate materials, will be the following 1 j ^ into a desired product.

读厭士工肥料鹽放置位置不可以太靠進種子,因為鹽之滲 太強’會使的種子無法發芽。在該肥料之 / 一 1 ’係值物可以吸收且不會改變滲透壓力。 單一有利的是’本方法將可達到粒化物中之30%以上具有 ^ 0 子。另外,包覆後之種子自動的提供了種子養份, 會浪費 之尺寸為(6號炱8號篩網)小種子,在種植時不 爲。此包覆也確定了種子之可流動性,如此,在處理 及運輪時更為容易。 50%。去旱大典型之過度播種(〇Ver Seeding)可能高達 你1虽種子之成本為每噸5 〇 〇元時,能節省5 0%是幅度可 爾》的 ° 你宣凿 jn. 爭晨業的人都知道,若要達到最大之產量,種子It should not be placed too close to the seeds, because the penetration of salt is too strong, and the seeds cannot germinate. The fertilizer's / -1 1 'value can be absorbed without changing the osmotic pressure. The single advantage is that 'this method will reach more than 30% of the granules with ^ 0 ions. In addition, the coated seeds automatically provide seed nutrients, and the size that will be wasted is (No. 6 to No. 8 sieve) small seeds, which is not good when planting. This coating also determines the flowability of the seeds, which makes handling and shipping easier. 50%. Excessive seeding (〇Ver Seeding), which is typical of drought relief, may be as high as you. Although the cost of the seed is 5,000 yuan per ton, it can save 50%. The degree is Kerr. ° You declare jn. Everyone knows that for maximum yield, seeds

523394 —---—· 發明說明(12) ----- 量 費 T本】=隔巧。方太多植物擠在一起則會顯著降低產 。*則提供一種成本效益高之種子,以避免這種浪 =的應用方面,此農作穀物種子可以被一適當之 人工肥料材料所取代。冑此’本發明之一實施例提供了一 種肥料,化方法,其特徵在於包括下列步驟: 提供一乾燥且呈粉狀之粉狀肥料,其中9〇%之尺寸 之分佈小於-1 5 0號篩網; 提供一人工肥料做為一種子替代物;523394 —---- · Description of the invention (12) ----- Volume cost T]]. Crowding too many plants together can significantly reduce yield. * These provide a cost-effective seed to avoid such waves. In terms of application, this agricultural grain seed can be replaced by a suitable artificial fertilizer material. Herein, one embodiment of the present invention provides a fertilizer and chemical conversion method, which is characterized by including the following steps: providing a dry and powdery powdery fertilizer, wherein the size distribution of 90% is less than -150 Screens; providing an artificial fertilizer as a sub-substitute;

形成一由乾燥之粉狀肥料與含水份結合劑所組成之 濕潤混合物,該混合物之中含有丨丨%重量比例之水份; 混合該混合物至一足以將該乾燥之粉狀肥料之抗水 性消除’使該乾燥之粉狀肥料吸收該結合劑中之水份, 並形成一可流動之合成物; 提供一粒化容器; 將該容器與該人工肥料接觸; 將該容器與該混合物接觸; 於該容器中,藉由接觸該混合物與該人工肥料,將 該人工肥料外包覆混合物而粒化;及 形成人工肥料外包覆肥料之粒狀物。 本發明之另一目的在於提供一種肥料粒化產品,其特 徵在於該產品包括· 一穀類種子;及 一肥料包覆於該榖物種子外而呈粒狀。Form a moist mixture composed of dry powdery fertilizer and moisture-containing binder, the mixture containing water content of 丨% by weight; mix the mixture to a water resistance sufficient to dry the powdery fertilizer Eliminate 'to make the dry powdery fertilizer absorb water in the binder and form a flowable composition; provide a granulated container; contact the container with the artificial fertilizer; contact the container with the mixture; In the container, the artificial fertilizer is externally coated with the mixture to be granulated by contacting the mixture with the artificial fertilizer; and a granule of the artificial fertilizer is coated with the fertilizer. Another object of the present invention is to provide a granulated fertilizer product, which is characterized in that the product includes: a grain seed; and a fertilizer coated on the seeds of the mash to be granular.

第15頁 523394 五、發明說明(13) 本發明之又一目的在於提供一種肥料粒化產品,其特 徵在於該產品包括· 一由肥料及人工肥料之均句混合物。 本發明之再一目的在於提供一種肥料粒化產品,其特 徵在於該產品包括: 一中央的人工肥料核;及 一肥料包覆於該穀物種子外而呈粒狀。 根據上述方法所形成之產品之優點包括: a. 產品是粒化的且乾燥的; b. 粒子尺寸可以被調整至特定之用途; g c. 比起習知方法,在運輸上大幅減化; d. 粒化物在土壤中之水份提供穀物在成長時最乾旱 之承受力; e. 耗盡(run-off)及營養流失均被避免; f. 提昇土壤交換以及緩衝能力; g. 產品是無毒且無燃性; h. 對土壤提供長期具體利益,而非由化學之人工肥 料之相對短期利益; i. 提供一水溶性氮之來源,其係可長時間釋放; j. 提供一機會結合有機及無機肥料兩者之優點之粒 0 化;及 k. 對於以空中撒種方式,提供更精確且減少浪費之 簡易應用。 本發明之另一目的在於提供一種複合粒化產品,其特Page 15 523394 V. Description of the invention (13) Another object of the present invention is to provide a fertilizer granulated product, which is characterized in that the product includes a homogenous mixture of fertilizer and artificial fertilizer. It is another object of the present invention to provide a fertilizer granulated product, which is characterized in that the product includes: a central artificial fertilizer core; and a fertilizer coated on the grain seeds to be granular. The advantages of the products formed according to the above methods include: a. The product is granulated and dry; b. The particle size can be adjusted to a specific use; g c. It is significantly reduced in transportation compared to conventional methods; d. The water content of granules in the soil provides the most drought-resistant capacity of the grain during growth; e. Run-off and nutrient loss are avoided; f. Improved soil exchange and buffering capacity; g. The product is Non-toxic and non-flammable; h. Provide long-term specific benefits to the soil, rather than the relatively short-term benefits of chemical artificial fertilizers; i. Provide a source of water-soluble nitrogen, which can be released for a long time; j. Provide an opportunity to combine Granulation of the advantages of both organic and inorganic fertilizers; and k. Simple application that provides more precision and reduces waste for aerial seeding. Another object of the present invention is to provide a composite granulated product,

第16頁 523394 五、發明說明(14) 徵在於該產品包括: 一穀類種子其尺寸分佈介於+ 35號篩網至-8號篩網 間; 複合的材料以層狀包覆一榖類種子外而形成粒狀, 其尺寸分佈介 於6號至8號篩網間。 【簡單圖式說明】 第一圖係根據本發明一實施例之肥料粒化之適合處理 過程之示意圖 第二圖係根據本發明之肥料粒化之另一處理過程之示 意圖 第三圖係根據本發明之肥料粒化之又一處理過程之示 意圖 【圖號說明】 肥料加入處1 0 粉化器1 2 肥料流1 4 收集器16 袋狀室18 閥20 容室22 混合器2 3 供給器2 4 載運體26 容器28 、 30 濕潤槍3 0 斗器32 供料器3 3 上刮板34 下到板3 6 刮板3 8及4 0 傳動帶4 1 流動體42 篩網組4 4 再循環流4 6 最終產品4 8 管線54 斗部56 管線58 管線60 鼓式粒化器6 2 【較佳實施例之詳細說明之前言】Page 16 523394 V. Description of the invention (14) The product is characterized by: a grain seed whose size distribution is between +35 mesh screen to -8 mesh screen; a composite material covers a class of seeds in a layered manner It is granular and has a size distribution between No. 6 to No. 8 sieve. [Simplified schematic description] The first diagram is a schematic diagram of a suitable treatment process for fertilizer granulation according to an embodiment of the present invention. The second diagram is a diagram of another treatment process for fertilizer granulation according to the present invention. The third diagram is according to the present invention. Schematic diagram of another treatment process for fertilizer granulation of the invention [Illustration of drawing number] Fertilizer adding point 1 0 Pulverizer 1 2 Fertilizer flow 1 4 Collector 16 Bag-shaped chamber 18 Valve 20 Container 22 Mixer 2 3 Feeder 2 4 Carrier 26 Container 28, 30 Humidity gun 3 0 Bucket 32 Feeder 3 3 Upper scraper 34 Down to board 3 6 Scraper 3 8 and 4 0 Drive belt 4 1 Flow body 42 Screen set 4 4 Recirculation flow 4 6 Final product 4 8 Line 54 Bucket 56 Line 58 Line 60 Drum granulator 6 2 [Detailed description of the preferred embodiment]

523394 五、發明說明(15) _ ----- 矣* $筛網號數係指泰勒(Tyler)標準篩網值。NPKS則代 比氮硫’此為熟習農業工程領域之人士所瞭解。百分 产^部份’除非特別註明,則以重量比例做基礎。容器速 卞度及傾斜度可以視所要形成之產品來改變參數值。 較佳實施例之詳細說明】523394 V. Description of the invention (15) _ ----- 矣 * $ The screen number refers to the standard screen value of Tyler. NPKS is compared to nitrogen and sulfur. This is known to those familiar with agricultural engineering. Percent Production ^ Portions' are based on weight unless otherwise specified. The speed and inclination of the container can be changed according to the product to be formed. Detailed description of the preferred embodiment]

在詳細說明本發明之前,重要的是要注意,不論植物 肥料’當要對具有約介於每立方呎20至25磅之極低 在、1度(bulk density)之粉狀材料以容器做肥料粒化, 料^ 4並為被提出。又,以靜電之觀點而言,由於粉狀肥 自纖維本質,粉狀肥料具有相當之抗水性,很難壓縮或 技(self-repulsive)成型。 化要擁有上述複雜問題之解決方法,以容器做肥料粒 以奋特別是對於肥料之散裝密度而言,是無法在一容器上 以®動方式成型的。材料加濕、成長及固化均不能忽視, 果Μ知技術實在無法達到本發明。透過實驗證明發現,如 物,料之散裝密度能增加至足夠的值時,將會形成丸狀 、妹人而且,藉由與其它肥料材料或輔助人工肥料化合物之 ::而成長增大。將粉狀之肥料、適當的介面活化劑與結 、=所構成之混合物來成型,是一成功的解決方案。此介Before explaining the present invention in detail, it is important to note that regardless of the plant's fertilizer, it is necessary to use a container as a fertilizer for powdery materials with extremely low bulk density of about 20 to 25 pounds per cubic foot. Granulate, feed ^ 4 and for is presented. From the standpoint of static electricity, powdery fertilizers are inherently fibrous, and powdery fertilizers have considerable water resistance, making them difficult to compress or self-repulsive. To have the solution to the above complex problems, using containers as fertilizer granules, especially for the bulk density of fertilizers, cannot be formed on a container in a dynamic manner. Humidification, growth, and curing of materials cannot be ignored, and it is known that the technology cannot achieve the present invention. It has been found through experiments that if the bulk density of the material can be increased to a sufficient value, it will form pellets and sisters, and grow with other fertilizer materials or auxiliary artificial fertilizer compounds ::. Forming a mixture of powdered fertilizer, a suitable interface activator, and a knot is a successful solution. This introduction

/化劑係用以降低肥料之表面張力,以允許水份、結合 肥料混合在一起。一旦混合後,此混合物可以進一步 混合物相同之額外的結合劑在一容器上被粒化,故, 二額外的結合劑的加入,使的它可以由習知喷撒器具來 $仃噴撒應用。Chemicals are used to reduce the surface tension of fertilizers to allow moisture to be combined with the fertilizers. Once mixed, this mixture can be further granulated in a container with the same additional binder. Therefore, the addition of two additional binders allows it to be applied by conventional spraying devices.

第18頁 523394Page 18 523394

舉例而言,根據第一圖所示之流程, 粒化。 本發明可以達到 請參閱第一圖,其顯示一 此,肥料粒化物可以形成。標 術允許大多數肥料粒化產品之 鹽、鹼灰(soda ash)、硫、钟 鎂、氯化鉀、氣化鈉及氣化銨 meals)、及其它物質。 粒化方法之總體示意圖,藉 號1 〇代表肥料加入處。本技 成型’包括各式各樣的硫酸 、白陶土(kaolin)、氧化 '鱗化物、粗碾轂物(bl〇odFor example, according to the process shown in the first figure, granulation. The present invention can be achieved. Please refer to the first figure, which shows that granules of fertilizer can be formed. The standard allows most fertilizer granulated products to be salt, soda ash, sulfur, bell magnesium, potassium chloride, sodium vaporized and ammonium vaporized meals), and other substances. The overall schematic diagram of the granulation method. The number 10 represents the place where the fertilizer is added. This technology molding ’includes a variety of sulfuric acid, kaolin

此肥料加入處及結合劑在加入後進入一粉化器丨2,以 便將進入之物體變成粉狀,其90%之尺寸分佈係小於-15〇 號師網。絕大部伤疋- 200號篩網。此粉化器I?可以為一分 級粉化器或一掃器式粉化器或是其他適當 -旦粉化後,此肥料流,一般而言是以標號=化;導 引至一密閉的收集器,在本文中是以標號16代表,該收集 器16包括一用來收集灰塵之袋狀室18。收集器16也包括適 當的閥20以便能調控灰塵進入一容室22,該容室22係連 接至一混合器2 3以便能與結合劑混合(大約5 § %固體)。After the fertilizer is added and the binding agent is added, it enters a pulverizer 2 to change the entered object into a powder, and its 90% size distribution is less than -150. Most injuries-200 mesh screen. The pulverizer I? Can be a graded pulverizer or a sweeper type pulverizer or other suitable-once powdered, the fertilizer stream is generally labeled with =; led to a closed collection The collector, represented herein by the reference numeral 16, includes a bag-like chamber 18 for collecting dust. The collector 16 also includes a suitable valve 20 to regulate the entry of dust into a container 22, which is connected to a mixer 23 to enable mixing with the binder (approximately 5 §% solids).

在此實施例中,此結合劑係採用濃的木質硫績酸 (lignosulfonate)溶液。在短時間的混合後,此混合物被 調製成具有粒化的特性。此乾燥之粉狀肥料,通常是具有 抗水性的,可以被觀察到,它已轉變成為親水性的,其原 因為此結合劑中之水份以被蓄意的或是轉移的進入此肥料 中,且結合劑固體在此粉狀混合物中散佈。此導致顯著的 增加了其散裝密度,以便提供一可流動之粉狀物。In this embodiment, the binder is a concentrated lignosulfonate solution. After mixing for a short period of time, this mixture is formulated to have granulating properties. This dry powdery fertilizer is usually water-resistant, and it can be observed that it has become hydrophilic because the water in the binder is deliberately or transferred into the fertilizer. And the binder solids are dispersed in this powdery mixture. This results in a significant increase in its bulk density in order to provide a flowable powder.

523394 五、發明說明(17) 由混合器23出來後’此已預先加入水份之混合物被傳 遞至一供給器24。 水份及介面活化劑透過習知技術之載運體可以被加 入,此載運體被標號為26。混合物中水份之重量比例可以 看出已增加至11%。此部份勿與已鍵結之水化物|中之水混 淆。此水份係指自由之水份,對於粒化過鞋十分重要。一 旦獲得正確的水份,此混合物將通過一容器式=化器28。 為了要形成粒狀物,額外的結合劑或是介面活化材料可以 加=,例如煙霧膠(aer〇s〇1)。此煙霧膠係被一適當之霧 化器或是濕潤搶30來噴灑。此煙霧膠結合 與肥料粉化之相同材料,或去B ★处人 ^ ^ ^ μ 料或者疋,此結合劑可以選用不同 々'士匕 助之人工肥料化合物,可溶於該結合劑 之溶劑中。 此谷器式粒化器28包括一上刮板34及一下刮板36。在 12點鐘至15點鐘方向& @ ρ , 、々十 〇位置&間之任一位置可加入此結合劑 ^ ^ ^ ]心政果取佳。藉由使用介面活化劑,可降 低該肥料之表面張力+本 刀 此表面張力實為抗水性,如此,此 祀料之散裝密度可以掷“ ^ ., & j Μ增加,並且達到加濕、成長及固化之 的。適^之界面活化劑包括碳C4-C8磺酸(sulfonic = ldS 、%酸、破辑酸納(sodium succinate)、及其他物 $ ;1面活化劑可以與結合劑一起混合或是加入此容器 σ田正確的自由水份以取得達到1 0%之重量比例時,此 容器將保,在此一穩定之狀態。 由谷器28形成之產物典型的尺寸是介於3號及12號篩523394 V. Description of the invention (17) After coming out of the mixer 23, the mixture which has been added with water in advance is transferred to a feeder 24. Moisture and interface activators can be added through a carrier known in the art, and this carrier is designated 26. It can be seen that the weight proportion of water in the mixture has increased to 11%. This part should not be confused with the water in the bonded hydrate | This moisture means free water, which is very important for granulated shoes. Once the correct moisture is obtained, the mixture will pass through a container type carburetor 28. In order to form granules, additional binders or interface-activating materials can be added, such as aerosol gel (aeros01). The aerosol adhesive is sprayed by a suitable atomizer or moisturizer. This aerosol glue combines the same material as fertilizer powder, or go to B. ★ ^ ^ ^ ^ μ material or 疋, this binder can choose different artificial fertilizer compounds, which can be dissolved in the solvent of the binder in. The grainer type granulator 28 includes an upper scraper 34 and a lower scraper 36. This binding agent can be added at any position between 12 o'clock and 15 o'clock in the direction of & @ ρ, 々々〇 position & By using an interface activator, the surface tension of the fertilizer can be reduced + the surface tension of the knife is water-resistant, so that the bulk density of the target material can be increased by "^., &Amp; j Μ increased, and humidification, Growth and curing. Suitable interface activators include carbon C4-C8 sulfonic acid (sulfonic = ldS,% acid, sodium succinate), and others. 1 surface activator can be used together with the binding agent When mixing or adding the correct free water in this container to obtain a weight ratio of 10%, the container will remain in a stable state. The typical size of the product formed by the trough 28 is between 3 and 3. No. 12 sieve

523394 五、發明說明 ,間,此產品導入一乾燥器39而乾燥。舉例而言,此乾 ,器39可以選自於開利(Carrier)式乾燥器、盤式乾燥 f、或羅托陸佛(r〇t〇 louver)式乾燥器之一。由該乾燥 斋2 8產出之產物在被運到該乾燥器3 9間,係可藉由一適當 的傳動帶來達成,此整篇文中以標號41表示。523394 V. Description of the invention In the meantime, this product is introduced into a dryer 39 and dried. For example, the dryer 39 may be selected from one of a Carrier dryer, a tray dryer f, or a Rotorou dryer. The product produced by the drying room 28 is transported to the drying room 39, which can be achieved by a suitable drive belt, which is indicated by reference numeral 41 throughout the text.

^ 產品離開、乾燥器3 9後經由一流動體4 2先經過〆適當之 篩網組44,此篩網組包括3號、8號及-20號篩網。設置此 一 2 0號篩網部份之目的是將它送至粉化器1 2,以便再循環 運作。此再循環流係以標號4 6所代表。而過大的塊狀物則 被諸如佛瑞茲磨(Fritz mill)敲碎,然後再運回容器28 中。而介於3號至1 2號部份之產物則為最終產品,並且被 運離篩網組44,此最終產品被標示為48。 任何殘留在該乾燥器39的灰,可以透過管線54而離開 該乾燥器39裝入一斗部56,而且,在該斗部56中所收集的 東西’不是透過管線58進入袋狀室18,就是透過管線6〇進 入肥料加入處10。進入該袋狀室18之較細物質或灰則可以 再做補助之處理,例如加濕刮除,即如第一圖中所示之標 號6 0。其他之範例則屬於熟習該項技術者所知之部份。丁 關於此容器28,它可以調整角度及轉速,另外,已知 的優點不僅在改變該容器的水平角度,還有可側傾該容器 以便能夠強化該粒化過程之效率。至於此傾’斜之特定角度 或水平之特定角度則依據轉速以及要被粒化產品之尺寸^ 關於本發明之第二實施例,如第二圖所示,其為一可^ After the product leaves, the dryer 39 passes through a mobile body 4 2 and then passes through the appropriate screen group 44. The screen group includes 3, 8 and -20 screens. The purpose of setting this sieve part 20 is to send it to the pulverizer 12 for recycling operation. This recirculating stream is designated by the reference numeral 46. Oversized lumps are crushed by, for example, a Fritz mill, and then returned to container 28. The product between parts 3 to 12 is the final product and is removed from the screen group 44. This final product is labeled 48. Any ash remaining in the dryer 39 can leave the dryer 39 through the line 54 and be loaded into a bucket 56, and what is collected in the bucket 56 does not enter the bag-shaped chamber 18 through the line 58, It is through the pipeline 60 to enter the fertilizer adding place 10. The finer materials or ash entering the bag-shaped chamber 18 can be further supplemented, such as humidification and scraping, that is, the number 60 shown in the first figure. Other examples belong to those skilled in the art. D. Regarding the container 28, it can adjust the angle and the rotation speed. In addition, the known advantages are not only changing the horizontal angle of the container, but also tilting the container so as to enhance the efficiency of the granulation process. As for the specific angle of the inclination or the specific angle of the horizontal, it depends on the rotation speed and the size of the product to be granulated. ^ As for the second embodiment of the present invention, as shown in the second figure, it is a possible

523394 >發明說明(19) 行之迴路。 在此實施例中,一斗器32係被導致 :以穀r子源',例如加納利種子^ 卡諾杈種子(canola seeds)等等。關於尺寸分 .^ j *該農作縠物種子外圍包覆於肥料後,則成為產 用之產品之有用尺寸分佈-般是介於6號至气 產品的口此極有用之最終產品則是,包有種子之最終 最小兔Q j 包括單一種子。此百分比之部份也可提高至 在二= 90%,其係藉由在該容器中增加種子體積。此部份 業上特別有用,亦即,以最終產品之尺寸分佈之觀點 廢料已被減至最低,且過度集中之種子已非欲解決 :。在農業技術中,過度集中之種子已及空t涵蓋不 主要問題,而且,也導致在此工業中之額外成本。另 面’此斗器32可以包括一人工肥料材料,例如硫酸銨 ’且其尺寸分佈係介於—35號至+150號篩網,而且, 為核化劑。此加大了粒化程序,並導致了一複合的肥 二粒化ΐ之形成,其具有一人工肥料於核心。此肥料之材 ’’如前所述,亦可包括許多不同之材質。 見在明參閱第三圖’其係顯示本發明之另一實施例。 f此實施例中,使用兩個容器28及30,此分別形成第一階 =之=化物及第二階段之較大粒化物。混合物,如前所 述奋被導引至一小容器30以形成尺寸介於3號至12號篩 物 /、中一部份是介於8號至1 2號。此混合物係一供 料器33運送至容器30。該容器30中包括刮板38及40。此+8523394 > Description of the Invention (19) Circuit of the line. In this embodiment, the one bucket device 32 is caused by the following sources: for example, canary seeds, canola seeds, and the like. About size points. ^ J * After the seed of the crop is coated with fertilizer, it becomes a useful size distribution of the product used-generally between 6 and the mouth of the gas product. The extremely useful final product is, The seeded final minimal rabbit Qj includes a single seed. This percentage can also be increased to 2 = 90% by increasing the seed volume in the container. This part is particularly useful in the industry, that is, from the perspective of the size distribution of the final product, waste has been minimized, and excessively concentrated seeds are no longer intended to be solved:. In agricultural technology, over-concentration of seeds has not covered the major issues, and it has also led to additional costs in this industry. On the other hand, the bucket device 32 may include an artificial fertilizer material, such as ammonium sulfate, and its size distribution ranges from -35 to +150 mesh, and is a nucleating agent. This increases the granulation process and results in the formation of a compound fertilizer and two granules, which have an artificial fertilizer at the core. As mentioned above, the material of the fertilizer can also include many different materials. See FIG. 3 in the next figure, which shows another embodiment of the present invention. f In this embodiment, two containers 28 and 30 are used, which respectively form the first-stage compound and the second-stage larger pellets. The mixture, as previously described, is directed to a small container 30 to form a sieve having a size between 3 to 12 /, and a portion of the mixture is between 8 to 12 in size. This mixture is transported to a container 30 by a feeder 33. The container 30 includes scrapers 38 and 40. This +8

523394523394

五、發明說明(20) 號篩網及1 2號篩網之粒子係通過至該容器2 8中,並進行如 第一圖所示之處理,直到其尺寸分佈達到-3至+ 8號篩網為 止。當然,此尺寸分佈如有需要,可以進一步的加大’即 藉由將48處產出之粒化物導引至一鼓式粒化器62,以便 更進一步的加大材料尺寸至0.5英吋之丸狀物。在此鼓式 粒化器6 2中大體上是依照如前所述之容器之處理程序而 得。此外,再一種選擇是,在此迴路中可使用斗器32。 此很明顯的表達出數個容器之是可以裝設於本系統 中’以便積極的成長或結合成一丸狀物。為達此目的,本V. Description of the invention The particles of No. 20 sieve and No. 12 sieve pass through the container No. 28 and are treated as shown in the first figure until the size distribution reaches -3 to + No. 8 sieve So far. Of course, if necessary, this size distribution can be further enlarged, that is, by directing the granules produced at 48 places to a drum granulator 62, so as to further increase the size of the material to 0.5 inches. Pills. In this drum granulator 62, it is obtained substantially in accordance with the container processing procedure described above. Furthermore, another option is that the bucket 32 can be used in this circuit. This clearly shows that several containers can be installed in the system 'so as to actively grow or combine into a pill. To this end, this

程序係可被中斷且可以依情況設計來生產具有多層材料之 粒化物,而形成複數個有價值之粒化物。對於那些熟習本 項技術之人士而言,此用以生產不同形式之人工肥料的程 序係十分有效的,而且,對於形成使用於高爾夫球場等地 區之高等級之人工肥料而言,亦具有特定之產利用 性。 對於結合劑而言,適當的範例包括 斤 -中性之木質琉續 =氣(lignosulfonate of ammonia)、中性之木質硫磺酸 鉀(lignosuIfonate potassium)、澱粉 '糖、 水、硫酸鈣、乾麵筋、小麥穀粒、大麥 磷酸鈣、或結合數項。此結合劑之選 ^ ^ ϋ hi ο ^ a. a、+、 ^ 、疋,係依照粒化物所The program can be interrupted and can be designed to produce granules with multiple layers of material, forming a number of valuable granules. For those familiar with this technology, this procedure for producing different forms of artificial fertilizer is very effective, and it is also specific for the formation of high-grade artificial fertilizers used in areas such as golf courses. Product utilization. For binding agents, suitable examples include cationic-neutral lignosulfonate of ammonia, neutral lignosuIfonate potassium, starch 'sugar, water, calcium sulfate, dry gluten, Wheat grain, barley calcium phosphate, or a combination of several items. The choice of this binding agent ^ ^ ϋ hi ο ^ a. A, +, ^, 疋, according to the granulate

而之特性,且,據此,前述之範例僅A 雖然本發明之實施例已詳述,例說明用二 圍,對於熟習該項技藝之人士而言,任^制其保濩祀 所作之修改,乡未脫離本發明所述及所要求之巾請專利範And the characteristics, and according to this, the foregoing example is only A. Although the embodiment of the present invention has been described in detail, the example illustrates the use of the two surroundings. , The township does not depart from the towels described and claimed in the present invention, please patent

523394 五、發明說明(21) 圍,仍屬於本發明之保護範圍 1^· 第24頁 523394 圖式簡單說明 【簡單圖式說明】 第一圖係根據本發明一實施例之肥料粒化之適合處理 過程之不意圖 第二圖係根據本發明之肥料粒化之另一處理過程之示 意圖 第三圖係、根據本發明之肥料粒化之又一處理過程之示 意圖 【圖號說明】 肥料加入處1 0 粉化器1 2 肥料流1 4 收集器16 袋狀室18 閥20 容室22 混合器2 3 供給器24 載運體26 容器2 8、3 0 濕潤槍3 0 斗器32 供料器33 上刮板34 下刮板3 6 刮板3 8及4 0 傳動帶41 流動體4 2 篩網組4 4 再循環流4 6 最終產品48 管線54 斗部56 管線58 管線60 鼓式粒化器6 2523394 V. Description of the invention (21), which still belongs to the protection scope of the present invention 1 ^ · Page 24 523394 Brief description of the drawings [simple illustration] The first diagram is suitable for the granulation of fertilizer according to an embodiment of the present invention The treatment process is not intended. The second diagram is a schematic diagram of another treatment process of fertilizer granulation according to the present invention. The third diagram is a schematic diagram of another treatment process of fertilizer granulation according to the present invention. [Illustration of drawing number] Fertilizer adding place 1 0 Powderer 1 2 Fertilizer flow 1 4 Collector 16 Pouch chamber 18 Valve 20 Container 22 Mixer 2 3 Feeder 24 Carrier 26 Container 2 8, 3 0 Humidity gun 3 0 Bucket 32 Feeder 33 Upper scraper 34 lower scraper 3 6 scraper 3 8 and 4 0 drive belt 41 fluid body 4 2 screen set 4 4 recirculation flow 4 6 final product 48 line 54 bucket 56 line 58 line 60 drum granulator 6 2

第25頁Page 25

Claims (1)

523394 六、申請專利範圍 1 · 一種肥料粒化方法,其特徵在於包括下列步驟· 提供一乾燥之粉狀肥料,其中9 0%之尺寸之分佈 小於-150號篩網; 形成一由乾燥之粉狀肥料與含水份結合劑所組成 之濕潤混合物,該混合物之中含有11 %重量比例之水 份; 混合該混合物至一足以將該乾燥之粉狀肥料之抗 水性消除,使該乾燥之粉狀肥料吸收該結合劑中之水 份,並形成一可流動之合成物; 藉由接觸該混合物及加上額外的結合劑及一介面 活性劑,將該混合物粒化成為複數個粒狀物於一容器 中·,及 形成肥料粒狀物,其尺寸之分佈介於3號至12號 篩網。 2 ·如申請專利範圍第1項所述之肥料粒化方法,其特徵 在於該方法又包括下列步驟,即將該已成型之複數個 粒狀物通過一第二粒化容器,以便更進一步將該混合 物增長。 3 ·如申請專利範圍第1項所述之肥料粒化方法,其特徵523394 VI. Application Patent Scope 1. A method for granulating fertilizer, which is characterized by the following steps: Providing a dry powdery fertilizer, where 90% of the size distribution is smaller than -150 mesh screen; forming a dry powder A moist mixture composed of a powdery fertilizer and a moisture-containing binder, the mixture containing 11% by weight of water; mix the mixture to a level sufficient to eliminate the water resistance of the dried powdery fertilizer, so that the dried powder The fertilizer in the form absorbs the water in the binder and forms a flowable composition; by contacting the mixture and adding additional binder and a surfactant, the mixture is granulated into a plurality of granules. In a container, and form fertilizer granules, the size distribution of which is between No. 3 to No. 12 sieve. 2. The method for granulating fertilizer as described in item 1 of the scope of patent application, characterized in that the method further comprises the following steps, that is, passing the formed granules through a second granulation container so as to further The mixture grows. 3. The method for granulating fertilizer as described in item 1 of the scope of patent application, characterized by 在於該混合物又包括硫、微養份、pH緩衝劑、PH修飾 劑、細菌、離子交換黏土、分子篩器、人工肥料化合 物、人工肥料混合劑、除蟲劑 '殺真菌類劑、礦物之 一*項或其結合數項。 4 •如申請專利範圍第1項所述之肥料粒化方法,其特徵The mixture contains sulfur, micronutrients, pH buffers, pH modifiers, bacteria, ion exchange clay, molecular sieves, artificial fertilizer compounds, artificial fertilizer mixtures, insecticides, fungicides, and minerals * Item or a combination of items. 4 • The method for granulating fertilizer as described in item 1 of the scope of patent application, its characteristics 第26頁 523394 六、申請專利範圍 在於該結合劑包括至少選自下列一数質、澱粉、中性 之木貝硫續酸氣(lign〇 sulfonate of ammonia)、中 性之木質硫磺酸鉀(lignosulf〇nate 〇f potassium)、小麥縠粒、大麥穀粒、稻米穀粒、木膠 物質之中的一項或結合數項。 5 · —種肥料粒化方法,其特徵在於包括下列步驟·· 提供一乾燥之粉狀肥料,其中9〇 %之尺寸之分佈 小於-1 5 0號篩網; 形成一由乾燥之粉狀肥料與含水份結合劑所組成 之濕潤混合物,該混合物之中含有11 %重量比例之水 份; 混合該混合物至一足以將該乾燥之粉狀肥料之抗 水性消除,使該乾燥之粉狀肥料吸收該結合劑中之水 份’並形成^一可流動之合成物; 藉由接觸該混合物及加上額外的結合劑及一介面 活性劑,將該混合物在一第一階段中粒化成為複數個 粒狀物於一容器中’該複數粒狀物之尺寸係分佈介於 3號至12號篩網,且至少包括一部份之尺寸介於8號至 1 2號篩網; 將該已成型之複數個8號至12號篩網之粒狀物在❿ 一第二階段中再接觸該混合物與結合劑;及 形成介於-3说至+ 8號師網尺寸之肥料粒狀物。 6 ·如申請專利範園第5項所述之肥料粒化方法’其特徵 在於該方法又包括下列步驟··Page 26 523394 6. The scope of the patent application is that the binding agent includes at least one of the following materials: starch, neutral lignosulfonate of ammonia, and neutral lignosulfate. 〇nate 〇f potassium), wheat kernels, barley grains, rice grains, wood gum material, or a combination of several items. 5 · A method for granulating fertilizer, which is characterized by including the following steps: · Providing a dry powdery fertilizer, in which 90% of the size distribution is smaller than -150 mesh; forming a dry powdery fertilizer A moist mixture composed of a water-containing binder, and the mixture contains 11% by weight of water; mix the mixture to a level sufficient to eliminate the water resistance of the dry powdery fertilizer, so that the dry powdery fertilizer Absorb the water in the binder and form a flowable composition; by contacting the mixture and adding additional binder and a surfactant, the mixture is granulated into a plurality in a first stage Each granule is in a container. The size of the plurality of granules is between the No. 3 to No. 12 sieve, and at least a part of the size is between No. 8 to No. 12 sieve; The formed granules of No. 8 to No. 12 meshes are then contacted with the mixture and the binding agent in the second stage; and fertilizer granules having a size ranging from -3 to + 8 division mesh are formed. 6 · The method for granulating fertilizer as described in item 5 of the patent application park 'is characterized in that the method further includes the following steps. · 第27頁 523394 六、申請專利範圍 將該介於-3號至+8號篩網尺寸之粒化物與該混合 物及結合劑一起震擊,而形成約為二分之一英吋尺寸 分佈之複數個粒狀物。 7 如申請專利範圍第5項所述之肥料粒化方法,其特徵 在於又包括下列步驟·· 8 加入一辅助人工肥料於該混合物中。 9 如申請專利範圍第7項所述之肥料粒化方法,其特徵 在;該辅助人工肥料包括琉酸銨、鱗酸錄、微養份、 =緩衝劑、pH修飾劑、細菌、離子交換黏土、分子篩 J菌劑、除蟲劑、殺 圍f5項所逑之肥料粗化方法,其待徵 Μ乾燥之粉狀肥料中白 〇 ·—種將一穀類種子 ^化。 之方法,其特徵在於包=肥料而成為粒化丸狀物 楹根 社说 匕括下列步驟·· 寸之分佈:二粉狀肥料’其中m之尺 提供複數個穀類種子; 之濕潤i合:u:::料與含水份結合劑所組成 份; 物之中含有11 %重量比例之水丨 混合該混合物至一足 J性消除,使該乾燥之粉狀= 狀肥料之抗 伤,並形成一可流動之合成物枓收該結合劑中之水 第28頁 523394 六、申請專利範園 提供一粒化容器; 將該容器與該榖類種子接觸; 將該容器與該混合物接觸; 於該容器中,藉由接觸該混合物與該穀物種子, 將該榖物種子外包覆混合物而粒化;及 形成穀物種子外包覆肥料之粒狀物。 1 1 ·如申請專利範圍第1 0項所述之方法,其特徵在於 該種子包括農作榖物種子。 1 2 ·如申請專利範圍第1 1項所述之方法,其特徵在於 該種子之尺寸分佈介於+ 3 至_ 8號篩網間。 墦寒 1 3 ·如申請專利範圍第1 1項所述之方法,其特徵在於 該包有種子之粒狀物之尺寸分佈介於3號至12號篩網 1 4 ·如申請專利範圍第1 1項所述之方法,其特徵在於 該包有種子之粒狀物之中至少30%之粒狀物包含有單 一種子。 1 5 ·如申請專利範圍第1 1項所述之方法,其特徵在於 該混合物至少包括硫、微養份、pH緩衝劑、pH修飾 劑、細菌、離子交換黏土、分子篩器、人工肥料合成 物、人工肥料混合劑、除蟲劑、殺真菌類劑、礙物之j 一項或其結合數項。 1 Θ · —種肥料粒化方法,其特徵在於包括下列步驟: 提供一乾燥且呈粉狀之粉狀肥料,其中之尺 寸之分佈小於-1 5 0號篩網;Page 27 523394 VI. Patent application scope The granules with the size of -3 to +8 sieve are shaken together with the mixture and binder to form a multiple of about one-half inch size distribution. Grains. 7 The method for granulating fertilizer as described in item 5 of the scope of patent application, further comprising the following steps ... 8 Adding an auxiliary artificial fertilizer to the mixture. 9 The method for granulating fertilizer as described in item 7 of the scope of patent application, characterized in that the auxiliary artificial fertilizer includes ammonium sulphate, scaly acid, micronutrients, = buffering agent, pH modifier, bacteria, ion exchange clay 3. Molecular sieve J bacteria, insecticide, fertilizer roughening method described in item f5, the powdered fertilizer to be dried in the white powder is a kind of cereal seed. The method is characterized in that it contains granulated pellets into fertilizers. The root company says that the following steps are taken: distribution of two inches: two powdery fertilizers, in which the ruler of m provides a plurality of cereal seeds; u ::: The composition of the material and the moisture content binder; the content contains 11% by weight of water 丨 mix the mixture until the J-like elimination is eliminated, so that the dry powdery = fertilizer-like is resistant to damage and forms A flowable composition collects the water in the binder. Page 28 523394 6. The patent application park provides a granulated container; the container is in contact with the tritium seed; the container is in contact with the mixture; In the container, the mixture seed and the grain seed are contacted, the mash seed is outer-coated with the mixture and granulated; and the grain seed is coated with fertilizer and granulated. 1 1 · The method as described in item 10 of the scope of patent application, characterized in that the seed includes agricultural crop seeds. 1 2 · The method according to item 11 of the scope of patent application, characterized in that the size distribution of the seeds is between + 3 to _ 8 sieve.墦 寒 1 3 · The method described in item 11 of the scope of patent application, characterized in that the size distribution of the seed-coated granules is between 3 to 12 sieve 1 4 · as in the scope of patent application No. 1 The method according to item 1, characterized in that at least 30% of the seed-coated granules contain a single seed. 15 · The method according to item 11 of the scope of patent application, characterized in that the mixture includes at least sulfur, micronutrients, pH buffers, pH modifiers, bacteria, ion-exchange clay, molecular sieves, artificial fertilizer compounds , An artificial fertilizer mixture, an insecticide, a fungicide, an obstacle j, or a combination thereof. 1 Θ · A method for granulating fertilizer, which is characterized by including the following steps: providing a dry and powdery powdery fertilizer, wherein the size distribution is smaller than -150 mesh; 第29頁 523394 六、申請專利範圍 提供一人工肥料做為一種子替代物; 形成一由乾燥之粉狀肥料與含水份結合劑所組成 之濕潤混合物,該混合物之中含有11 %重量比例之水 份; 混合該混合物至一足以將該乾燥之粉狀肥料之抗 水性消除,使該乾燥之粉狀肥料吸收該結合劑中之水 份,並形成一可流動之合成物; 提供一粒化容器; 將該容器與該人工肥料接觸; 將該容器與該混合物接觸; ^ 於該容器中,藉由接觸該混合物與該人工肥料, 將該人工肥料外包覆混合物而粒化;及 形成人工肥料外包覆肥料之粒狀物。 1 7 · —種肥料粒化產品,其係該據申請專利範為第1項 所述之方法所製成。 1 8 · —種肥料粒化產品,其係該據申請專利範為第5項 所述之方法所製成。 1 9 · 一種肥料粒化產品,其係該據申請專利範為第1 0 項所述之方法所製成。 2 0 · —種肥料粒化產品,其係該據申請專利範為第1 6 · 項所述之方法所製成。Page 29 523394 6. The scope of the patent application provides an artificial fertilizer as a sub-substitute; forming a moist mixture composed of dry powdered fertilizer and moisture binder, the mixture contains 11% by weight Moisture; mix the mixture to a level sufficient to eliminate the water resistance of the dry powdery fertilizer, so that the dry powdery fertilizer absorbs the moisture in the binder and form a flowable composition; provide a pellet A container; contacting the container with the artificial fertilizer; contacting the container with the mixture; ^ granulating in the container by contacting the mixture with the artificial fertilizer and coating the artificial fertilizer with the mixture; and forming artificial The fertilizer is covered with granular fertilizer. 1 7 · A granular fertilizer product, which is made according to the method described in item 1 of the patent application. 1 ·· A kind of fertilizer granulated product, which is made according to the method described in item 5 of the patent application. 1 9 · A granulated fertilizer product, which is made according to the method described in item 10 of the patent application. 2 0 · — Granulated fertilizer product, which is made according to the method described in Item 16 · of the patent application. 第30頁Page 30
TW089123376A 1999-05-05 2000-11-03 Compost granulation method and product TW523394B (en)

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US13268199P 1999-05-05 1999-05-05
US13256999P 1999-05-05 1999-05-05
PCT/CA2000/000522 WO2000067550A1 (en) 1999-05-05 2000-05-05 Compost granulation method

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