TW438621B - Purification method for contaminants caused by halogenated organic compounds - Google Patents

Abstract

A method for purifying matter contaminated with a halogenated organic compound is disclosed. The method includes the step of adding a reducing agent and a nutritional source for a heterotrophic anaerobic microorganism to the contaminated matter. The reducing agent is reduced iron, cast iron, iron-silicon alloy and so on, or a water soluble compound. A combination of chemical reactions with microorganisms allows to decompose the halogenated organic compound. The nutritional source including an organic carbon and 20 to 50 percent by weight of an oxidized form of nitrogen is added, thereby preventing by products of the decomposition such as generation of noxious gases and decoloration of soil. A method includes the steps of mixing a reducing agent and a nutritional liquid with the contaminated matter, wherein the mixing step including a step of adjusting the contaminated matter at pH ranging from 4.5 to 9.0; and keeping the mixture in a condition that air hardly penetrates through a matrix, thereby allowing to uniformly mix a large amount of the contaminated matter.

Description

经 "· 部 中 定 # 准 局 员 ^ Consumer Cooperation Mu Yin" 4 3 8 6 2 1 A7 B7 V. Description of the Invention (1) Invention of this invention , Especially pollutants containing contaminated organic matter, such as soil, sediment, sludge, and water. This purification method is based on a special transportable dehalogenation reaction combining chemical reactions with biological reactions. Decomposes pollutants contaminated by halogenated organics. There have been reports in recent years. In the degreasing, cleaning agents, and dry cleaning detergents widely used in electronic machinery parts, tetrachloroethylene, three atmosphere ethylene, 1,1,1-three gas ethane, two gas ethylene and other halogen-containing rhenium compounds pollute the soil and groundwater channels. These halogen-containing compounds are difficult to decompose in nature and are hardly soluble in water, so they tend to accumulate in the soil of contaminated areas or penetrate into groundwater. In addition, halogen-containing organic substances can cause liver damage and are carcinogenic. For this reason, it is expected that halogenated organic compounds such as tritium compounds contained in soil can be decomposed. Recently, the microbial treatment method (biochemical breeding) has attracted attention as a method for purifying pollutants such as soils and groundwater channels contaminated by halogenated tritium. Although the stimulant treatment method also has a high cost relative to the effect and safety. However, the microbiological treatment method also has the limitation of a long treatment period and the types and concentrations of degradable substances as described below, so it may not be completely satisfactory. An example of this microbial treatment method is a method in which methane-utilizing bacteria and toluene, phenol-decomposing bacteria, ammonia-oxidizing bacteria, and ene-utilizing bacteria decompose trichloroethylene aerobically in most reports. However, its shortcomings are: 1) unstable decomposition reaction, 2) Fan Yuanzhang, which is the target substance of decomposition, 3) the national standard (CNS) Α4 specification (210 × 297 mm) is applicable to the paper standard of tetra atmosphere ethylene or tetrahydro. " (Please read the notes on the back before filling in this page} '1Τ A7 438621 B7 V. Description of the invention (2) Highly chlorinated substances of carbonized carbon do not decompose. On the other hand, there are many anaerobic microorganisms which High-atom organic materials such as tetrachloroethylene, tri-atom ethylene, and tetra-atomized carbon have a wide range of decomposition. However, there are still: 1) very slow reproduction of microorganisms, 2) high toxicity produced during the decomposition process Disadvantages of Nakayama metabolites (Uchiyama Yufu, Yagi Slim, Biosciance and Induotriy, 1994, Vol. 52, No. 11, No. 8 7 9 ~ 88 4). On the other hand, the technology of decomposing halogen-containing organic compounds using chemical reactions has been reported to treat chlorine-containing organic compounds with Takihara Tsubakihara (Tsaki Saki, organic atmosphere contaminated groundwater, 1M metal-containing activated carbon at low temperature Technology, "PPM", 1995, Vol. 26, No. 5, pp. 64-70). Therefore, the inventors of the present invention tested the microorganisms by adding gold to the soil in a carbon-free state to perform a dechlorination test. However, under non-cultivated conditions, especially in the combination of the original environment and neutral conditions, no deaeration reaction was found. Even when Fe 即使, FeCl3, and FeS〇4 were added instead of metal 塩, no dechlorination reaction was found. Furthermore, there have been reports that gold-touched iron and high scraping air were irrigated into the contaminated soil. Harmless treatment method for halogenated organic compounds to react with powder cuts to mineralize them (Japanese Kaikai Hei 8-257570). However, in this method, there are still problems with equipment for injecting air and Gu Lu with the scattering of halogen-containing europium compounds. Furthermore, the use of pressurized air causes cost problems and is not practical. In addition, there are also reports combining natural substances with micro-dehalogenation and micro-organisms (please read the precautions on the back and then fill out this page) '11 Printed by the member of the Ministry of Intermediate Standards Bureau, Consumer Cooperatives, this paper applies to China National Standard (CNS) A4 Specification (210X 297 Gong) 2 39498 438621 A7 Printed by B in the Ministry of Standards " Standards Bureau Consumers Cooperatives Co. B7 V. Invention Description (3) Biological treatment, M removes contaminated soil and groundwater There is a method for gas-containing compounds ("Nikkei Biotechnology" (issued by Nikkei BP & Co., Ltd. > October 1996? Issued, No. 361, pp. 14-15). However, all natural substances and microorganisms are There is no specific record. US Patent No. 5,411,644 describes a method of adding fibrous organic matter and iron and other multivalent gold tincture particles to pollutants to decompose halogen-containing organic compounds. However, in this US patent There is no record of Kanbara. Reducing agents such as biogenics, alloys, and water-soluble Kangen agents. There is also no record of how to keep the pollutants in the Harahara environment and a specific ρ Η after adding the rhenium agent. In addition, the added nutritional ingredients may occur in the soil, such as sulfonium sulfate, methane fermentation, and other biological advancement reactions, and produce sulfur odor gases such as hydrogen sulfide, methanol, or combustible gases such as methane. Also, soil It may also become black due to the accompanying sulfidation. It may even generate flammable hydrogen due to the reaction of metal powder with water. Furthermore, in the laboratory, it is easy to combine primogens, nutrients and pollutants in the laboratory. Uniform mixing. In contrast, in order to purify pollutants such as soil, there must be a civil engineering that combines a large amount of reducing agent with the former source. It is not easy to mix uniformly. Furthermore, when mixing is expected The conditions will affect the decomposition rate of halogen-containing organic compounds. Especially if you want to purify the la3M upper body horizontal, or even the volume of pollutants on the 10m3M volume, you must consider the "mixing method. The invention of K slightly / the purpose of the present invention is to improve. For the purpose of combining chemical reactions and biological properties. The paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 3 39498 (Read the precautions on the back first before filling in this )

, 1T ί 43 86 2 1 Α7 It is clearly stated that there is a halogen in the hair and five-in-one combination machine, a net product is combined with a chemical compound, a halogen-containing compound is decomposed, and the halogenated material should be decontaminated. Proteomics can be considered as a state of greatness 1 The first manifestation of the present invention should be combined with a halogen-containing solution. The halogenated solution should be reversed. The second aspect of the present invention is well-organized. The halogen-containing solution should be equal to the anti-loaming soil, the halogen, and the dehydration, the original body ventilation and flame retardation may be possible, or the body-like gaseous odor. The things with the same degree of color change stain the buildings with the combined things. «Heda Mixture is stained with stains and its agents, as it is, and the original source of the 4th source of the book Mingying will be added to the original effect of 0 from Dingte buried in the original state of the book Halogen degeneration should be reversed to promote the quotation of T " T. The original characteristics of the original are added to the special state of the 2nd, the first manifestation of the inevitable, but the same, not the same as the original state of 1 Determining the special issue of the book with 〇 but can 〇 should also be related to the inversion of the halogen should be reversed, and the student should be promoted. 1 The physical and chemical machine has a good halogen, and it can be reversed (# 先 读(Back.7 " Notes before filling out this page)

1T -.f Member of the Middle Standard Bureau of the Ministry of Economic Affairs, J. Consumer Cooperatives, the carbon state machine contains the use of China-Malaysia camps, so the state 3 % Of the amount of oxidized oxygen due to the production of loam, and the reaction of the thiologenic phase of microalcohols, such as odorous substances, odors, and odors, should be reversed. Yang Ying and 0 Yuan Shi will have the product of the 4th Mingfa in this special situation, because the mixture of the step is contaminated with the source to the highest M. The mixture can be evenly contaminated by the time.雅 ： Upper M This paper size is applicable _: Standard (™ Specification U10X Supplement 3 9 498 43 86 2 1 A7 B7 in the Ministry of Economic Affairs " Printed by the Consumers' Cooperatives? The fifth, invention description (5) 1 and • The kangen agent used in the third aspect and the fourth aspect of the present invention > x 1 I The user in the first aspect or the second aspect of the present invention is preferred, but is not limited to 1 1 I using this Invention No. 1 The m original agent used in the aspect or the second aspect. 〇1 I Read 1 I The 1st aspect of the present invention is the purification method for halogenated organic compound pollutants. The first I 1 I method »The method provided is κ 25. For the standard electrode of the 檷% hydrogen electrode μ »Back 1 \ 13 m π 2 m original agent and 2 dependent anaerobic microorganisms Note 1 1 1 Ψ J < nutrient source is added to the aforementioned pollutants step «Its, A ·, and U. The original agent is m. The original item is 1 4 1. The percentage of ferrous metals is cut off — silicon alloy Λ titanium alloy \ zinc alloy manganese alloy, aluminum alloy | gold-magnesium alloy, calcium alloy, and water-soluble compounds In the group of groups, at least m is selected!! I 1 species 0 The existence of the m original agent »can promote chemical reactions and debiological binding 1! The dehalogenation of halogens 0 i 1 is described in the present invention m The original agent M sets the potential of the quasi-hydrogen electrode at 25 at a potential of "4 0 C bV -2400b V", and it is a reduction susceptor, osmium sulfide, and A * ti susceptor-Silicon 1 I gold-titanium alloy zinc alloy > At least one of the manganese alloy, aluminum alloy magnesium alloy, and calcium alloy 1 I is preferably selected thinly. 刖 mentioned kangen agent > λ containing kan original suspect is better 〇1 Λ.Λ * month [J It is better that the original agent also contains suspects. ^ U The original reason is also based on m — I silicon alloy Λ titanium — silicon alloy > titanium-aluminum alloy > zinc-aluminum alloy% manganese-magnesium 1 1 Alloy aluminum—zinc—calcium alloy—aluminum—tin alloy, aluminum—silicon alloy magnesium— 1 1 At least one selected from the group of manganese alloy and calcium—silicon alloy is preferred. 0 1 1 Preferably, the aforementioned m is m, which is an organic 1 1 acid or a derivative thereof, a hypophosphorous acid or a derivative thereof, or a sulfide, and is more preferably i 〇 »> Particles with a particle size of 5 0 0 ju η Μ are better. 0 The aforementioned contamination 1 1 1 is better if the moisture content is at least 25% by weight. 0 1 1 This paper size is in accordance with China National Standard (CNS) Α4 size (210 × 2). ? 7 mm) 5 3949 8 4386 2 1 Λ7 Α7 Β7 Seal of the Ministry of Economic Affairs, Ministry of Economy, Trade and Industry Bureau, Consumer Cooperatives ^ · V. Description of the Invention (6) 1 | M 1 1 I halogenated organic compounds dehydrohalogenated t The aforementioned pollutants have a pH of 1 in the range of 4.5 ^ -9.0 1 1 1 It is better to have the step 0 If the other steps after the aforementioned addition step to maintain the aforementioned stain 1 ! 诮 1 1 Dyestuffs are better in the original environment in the range of ρΗ4.5 ~ 9.0 0 Read II Read 1 I Describe dyestuffs M Add various kinds of stacks of organic matter m > Stacks have back 1¾ 1 Μ Organic matter, or waste water or waste containing organic matter, and If there are mixed steps, the book 1 \ I is better 0 项 item and then 11 1 1 In the first aspect of the present invention, the aforementioned water-soluble entrapment agent is 1 ~ 20 carbon 'Xing script £ 1 1 atom and hydroxyl substitution It is not possible to use carboxylic acid, dicarboxylic acid, tricarboxylic acid, 1 1 I or tetracarboxylic acid or its derivatives, polyhydroxyaryl compounds, or hypophosphorous acid or its phosphonium 1 1 is preferably 0. In addition, 9 the aforementioned water solubility Bulk agent 4 is preferably hypophosphorous acid or its phosphonium. 0 1 1 Describes the water-soluble entrapment agent organic acid or hypophosphorous acid or with iron \ 呔 \ zinc, manganese 1 or aluminum or magnesium. 0 1 1 is Adjust the pH of the »* -mentioned contaminants» Describe the contaminants M. It is better to add at least one of the alkali metal contacts 1 I compounds N alkaline earth metal compounds, and the steps are as follows. The step is to convert the halogenated organic compounds into halogen-free organic compounds. It is preferable that the above-mentioned holding step M can convert the above-mentioned toothed compound 1 1 to a hydrocarbon compound that does not contain a halogen atom. It is preferably 0 I i The second state of the present invention provides a purifying factor. Method for 1 compounds to cause 1 1 pollutants • Including the steps of reducing the 祢 standard electrode of 25 pairs of standard hydrogen electrodes to 1 1 position 130 η V ~ 2 4 0 0 1 V 剤 adding to the aforementioned pollutants, 1 I · »* -Describes that Kanhara is considered to be selected from the group consisting of Kanbara iron and Ni, a silicon alloy titanium alloy Λ zinc alloy 1 1 gold-manganese alloy aluminum alloy magnesium alloy, calcium alloy and water-soluble compounds At least 1 type 0 1 1 This paper size is applicable to Chinese National Standard (CNS) Α4 size (21 〇 × 297 mm) 6 3949 8 4386 2 1 A7 B7 Ministry of Economic Affairs " Standards Bureau member J · xiao fr Cooperatives printed five, Description of the invention (7) 1 I In the second step of the present invention, the former m agent M 25 V The standard electrode potential of the 檷 quasihydrogen 1 1 I electrode is -400 Β V -24001 V. It is entangled with the original, 1 1 and the cut off_ silicon alloy titanium alloy% zinc alloy manganese gold aluminum alloy m /-*, ii Please select at least one of the 1 alloy and calcium alloy is better. Read I i ύ i | The former reducing agent contains m original iron is better 0 > Better 0 The foregoing agents are iron-silicon alloy, titanium-silicon alloy titanium—m meaning 1 thing L alloy> zinc—aluminum alloy manganese—magnesium alloy S aluminum—zinc—calcium alloy% aluminum—item 1 4 1 tin alloy > Aluminium-silicon alloy, magnesium-manganese alloy, and calcium-silicon alloy group. At least one selected from the group I is more preferable. 0 Η 1 1 I The former transport agent is also a water-soluble compound. Buried raw m Μ has 榇 1 1 acid or its derivative> The hypophosphorous acid or its derivative or m compound is preferred 0 1 1 The aforementioned m original agent> X powder with a particle size of 5 0 0 // 〇Μ Order 1 for the best. The third aspect of the present invention is to provide a method for purifying the pollutants caused by halogenated hafnium compounds. The standard electrode contains 25 counter-electron quasi-hydrogen electrodes. The I position is 1 30 n. 2400 bV kangen agent, and the trophic anaerobic microbiotic 1 tt nutrient source added to the above mentioned pollutants »丄 刖 逑 nutrition source contains cl organic carbon and the aforementioned organic carbon 20 50 The oxidized state by weight% 〇 t 1 and t The aforementioned nutrient source contains 20 30% by weight of the above-mentioned oxygen-containing carbon 1 1 chemical nitrogen is more preferable. The organic carbon is used to supply a water-soluble fluorinated carbon source as佳 1 1 1 〇 Further »The standard of the standard argon electric hibiscus under the predetermined agent M 25 The electrode 1 1 I has a potential of -400 ancestor V " w -2400, V is preferably a metal substance. The aforementioned primogenizer K 1 | m is considered to be pig iron-silicon alloy, titanium alloy, zinc alloy, manganese alloy 1 1 and at least one of m in the group of aluminum alloy magnesium alloy and calcium alloy is better. National Standard (CNS) A4 specification (210X 297 mm) 7 3949 8 43 86 2 1 A7 B7 V. Description of the invention (8) Or, the aforementioned water-soluble compounds of kanji agents are also good. Powders of i D or less are preferred. The Ministry of Economic Affairs has determined that the standard of J-Consumer Cooperative Society shall be in accordance with the requirements of the J-Consumer Cooperative Society, and the addition and selection of fermentation and physical processes. Adding gold selection for the best-in-class bio-electricity step, the state and low He Jizhan's fan solution before. In the middle, add λ before the shape of the person, the nature of convergence 0 focus on the good titanium body Tim ^ = of the rri Mi wall 臛 _. The mixture of materials and gas is a plus, and there are many in the group Take it! One or calcium its. Halogenated hydrogen contamination P and the original silicon contamination have been added with aluminate or nitric acid, and are included in the entanglement | Calcium and added state nitric acid and nitric acid are classified as standard precursors. Nitrate or glutamate is mixed with the former wm, gold in wfl > step oxygen, potassium, containing the lower agent, and the contaminated parts will not be combined into 1 as a manganic acid. Powder and 50 mg of magnesium * Continued with the former auric acid nitrate which contains 25% of the former gas, the diameter, "II is more than that of koji nitrate, osmium, or. It is included with the regularizer to granulate the gold-cutting step. Nanometer liquid sample, liquid ην lower the original mixed CM original mixture ~ 1 add suspended nitric acid, waste state cultivation 00 Contained in the 遢 re-better agent Kalumi section 1, 3 containing acid nitrate source enzyme 4 Fang Ying 24 The description is the original M,.之 之 合 第 M Nitrocarbon-containing 酦 第 的 'Before the step, the internal compound Jin Jia 1 mixed with the amount of 塩, with 物 or the substance of water V mixed with the original compound as the first titanium titanate塩 有 、 明 染 and 01 are mixed with dyed and then mixed with manganese species, the dyes are nitric acid, and the source of pollution is described above. 13 mentioned before, the pollution is described as above. In this description, the former Jin Shao described the pollution before and the waste body camp. Suspected, Gu Zhidian-Step ahead of He Zinc (please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 size (210X297 mm) 8 3949 8 438621 A7 B7 恕 部 中 泱 支 Jujube Bureau Member-x Consumption Hezhusheyin 'f' 5. Description of the Invention (9) The step of nourishing fluid is better 0 1! Or »It is better to include the aforementioned pollutants in the first step Add 1! | Mix the aforementioned nutrient solution in the amount of 1 to 5% by volume of the stated pollutants, and then read 1 1 in step I 2 and add 1 to the stated pollutants and mix with the first phase First read 1 1 1 5 ~ 10% by volume of the previously mentioned nutrient solution, which is described as 1 J. The amount of pollutants mentioned above, and then add the above-mentioned JW ·· month U pollutants to the first stage or the second stage. At this stage, a larger amount of precautions 1 * 1, the previously filled liquid 0 items and then fill in 1 1 In addition, t describes the original agent M water-soluble compound 1 or Said the original agent is written on this page 1 It is better to dissolve in the aforementioned nutrient solution. Another 1 Λ. * · In the rest step t Λ, «· 刖, ^ 1 I The above-mentioned pollutants are at least the first 3 days. It is better to keep the inner M at 17 Q0V. 0 1 1 I In the fourth aspect of the present invention, the aforementioned nutrient solution 1 1 added to the r u- described contamination 1 > λ is finally 15 25% by volume of the aforementioned pollutant amount It ’s better. Also, > In the above-mentioned standing step »Keep the above 1 1 at least the first 5 days Contaminant at 17 60 Ό is better 0 In addition * In the above-mentioned standing step 1 Μ to 1 | Less in In the first 3 months, or preferably within 5 months, it is better to keep the aforementioned pollutants at 岫, 20 4〇υ 0 | The aforementioned standing step > λ and the surroundings are separated from each other and it is better to 0 to maintain 1 1 Low aeration conditions September IJ mentioned pollutants are best covered with non-aerated material 0 will be 1 1 It is also good to keep the pollutants in an aqueous liquid to maintain low aeration conditions. The above mentioned pollutants 1 1 are preferably mixed with the nutrient solution of A * month IJ in the container > >-the reducing agent is preferably 0 1 1 A simple explanation of the formula 1 The first picture shows the result of the test of the iodine detoxification reaction 1 1 I in which the four-gas ethylene-contaminated soil 1 I Μ for the production of tofu was tested under anaerobic conditions according to the present invention σ 1 1 This paper size applies Chinese national standard ((.: NS) Λ4 specification (2 丨 0 > < 297 gong)) 9 3 9 498 4386 2 1 A7 B7 The Ministry of Consumer Affairs and the Ministry of Standards and Decision Bureau have a negative T and eliminate cooperation印 印 5. Description of the invention (10) I The second figure shown in Fig. 2 is the soil contaminated with tetramethylene ethylene in accordance with the present invention. Fruit 〇 Reading Xian 1 i I a. Ming harm m Form 1 | Read 1 \ The 1st sample of the 2nd state of the present invention > and the 3rd state are cleaned by the halogenated back 1 hosiery compounds and pollutants. 0 Halogen refers to the atmosphere and the atmosphere in this manual V Note 1 *丨 _ Bromine N sulphur. The present invention can purify dyes containing halogen compounds with m compounds. 1 * Particularly, it can purify pollutants containing organic compounds containing chlorine and bromine atoms. Page V on this page is even more special. ≫ Pollutants with atomic compounds. This gasification is not limited to-1 I organic compounds. For example,-tetramethylene ethylene three gas ethylene 1, 1, dioxan 1 1 J aliphatic compounds such as ethanedichloroethylene, pentachloro. Aromatic compounds such as phenols 1 1 can also be decomposed. Order 1 The first aspect of the present invention, the second aspect, the third aspect, and the fourth aspect, which can be treated by I 1 include: soil, bad sediment, sludge Wait 〇 this Out of t compost 1 | compost m can be treated with methane m waste, etc. In addition »1st aspect of the invention Ί 2nd and 3rd aspects can also handle groundwater, m water and other water, Ί 1 property Liquids: The aqueous liquids in this description include: • Aqueous solutions \ suspensions 1 i 1% emulsions and mixtures thereof 0 1 1 Where the contaminant is soil, sediment, sludge, etc. 1 Water content M at least 1 1 Above 25% by weight, 40% by weight and 60% by weight are more preferable. 0 For breeding of anaerobes. 1 1 Sexual microorganisms ψ Soil sludge is not easily accessible by air. 1 I 〇 Water content (%) The definition is as follows: 01 I Moisture content = (Weight of water / Weight of pollutants of water content) X 100 1 1 1 W · When the pollutant is groundwater Λ m water, etc., the water content must be at 1! This paper size applies China National Standard ((.'NS) Α4 Specification (2f〇X297 mm) 10 3 9 498 Ministry of Labor " Printed by the Standards Bureau Employees' Cooperatives ^ 4 3 8 6 2 1 a? B7 V. Description of the invention (11) 25% by weight Μ. In the first aspect of the present invention, the aforementioned pollutant is added with a standard electrode potential of 130bV--2400η \ ί to a standard hydrogen electrode at 25T, and a nutrient source of anaerobic microorganisms derived from tritium, M promotes chemical reactions and biological reactions, and decomposes halogenated europium compounds. Where the potential of the quasi-electrode of the substance is higher than 130bV, sufficient reducing power cannot be obtained. On the other hand, the standard electrode potential of the substance is lower than -2400iV. For example: salty gold carvings such as gold tincture, gold tin potassium, etc., because the primordial force is too strong, it is prone to eruption in the presence of water and generate hydrogen. Dangerous and therefore inappropriate. The quasi-electrical potential (E °) of the standard hydrogen electrode below 25 is shown in the table below. (Please read the back of the page first, and pay attention to this page before filling in this page.) This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) 39 498 438621 A7 B7 V. Description of the invention (12) Standard hydrogen electrode at 25C The quasi- 电位 potential (ε °) is printed by the iodine ministry standard standard bureau and consumer cooperation " '霣 hibin reaction E ° UV) Ca2 + + 2 & ~ < r Ca -286 5 Na + + e- < --> Na -2714 Hg2 + + 2e_ — 4 Mg-23 63 Al3 + 3e ~ <-> Al -1662 Z n 2 + 2e- ^ Zn -763 Fe ^ + + 2e-^-Fe -440 Cd2 + + 2e- <--> Cd -403 N i 2 + 2 e-f N i -250 Sn2 + + 2e ~ < r Sn -136 Fe3 + + 3e- <-— Fe -36 2H + + 2e '^-> H2 0 Ascorbic acid (pH7. 0) 58 (Please read the precautions on the back before filling out this page) '11 The potential of the quasi-electrode, that is, in the battery reaction, Each chemical species that reacts with the battery is under a pseudo-state (pure solid phase, pseudo-concentration, standard pressure, etc.), and the potential measured when the K-argon electrode is used for comparison electrode measurement is the pseudo-potential E. . This value can be expressed by the following formula. Ε ° ~-Δ G ° / nF where AG. For the response of the battery, Gibb's free energy changes, 12 paper sizes are in accordance with the Chinese National Standard (CNS) A4 (210X297 mm) 3 9 498 438621 A7 ____ B7 V. Description of the invention (丨 3) η is the reaction phase Number of electrons, F is Faraday constant. It must be noted that, in general, the oxidation potential is measured using a saturated silver nitride electrode as the comparison electrode. The measured value in this case is more than that shown in the measurement using the hydrogen quasi-electrode as the comparison electrode. The quasi-potential is about 200niV lower. In the present invention, the above-mentioned "primitive agent" is at least one selected from the group consisting of Tongyuangan, Shengyuan, Si-Si alloy, titanium alloy, zinc alloy, manganese alloy, aluminum alloy, magnesium alloy, aluminum alloy, and water-soluble compounds. For the aforementioned kangen agent, M is preferably applied to a standard hydrogen electrode at 251 (gold surface material with an electrode potential of _400nV to 2400biV). As one of the actual pickled forms of the present invention, the use of Shivagen is a rhenium agent, and the cut powder usually forms oxide scales due to surface oxidation. In contrast, the scale of Yunyuan 镪 (read the precautions on the back and then fill out this page) seeding * quantity purchase is good »use to Jianyi, with Hansi as a benefit? Ϊ Ke Zhigong can be reconstituted in the form of _. It is also considered to be limited. The original M miscellaneous form)). However, the content of the raw material can be reduced to the original β public oxygen, and the cut-off of the stock will be limited to the industry and the net cost will be higher. Oxygen content can also make Cheng Jia's chemical industry more pure and pure oxygen. It is called light-but it can be attributed to quality and medium-time debris. Fingers stand. Self-esteem is similar to suspicion of making a high, the last Communist Party can be like, raw powder, originalization: The principle is that the original will be aerobic, it will be aerobic and truthful, but it will also return to the finest example. He Yu-Shi, the Micro-Hydrogen limit its easy to confirm the extreme series. In addition, it is suspected that the tweezers of oxygen can be combined with the full cut, which will be easy, the classics will be safe, and the temperature will be warmed. One of the suspects is a high-oxygen 90 biofilm. Made. This paper size applies Chinese National Standard (CNS) A4 specifications (2) 0XW7 mm) 13 3 9498 438621 A7 B7 The final bid rate of the Ministry of Economic Affairs is negative T. Consumption Cooperation Private Printing 5. Inventory (14) 1 1 It becomes the iron for industrial use »The carbon m degree is about 2% (heavy director) M is 1 1 | m, and carbon containing in this M is called the birth m (" Physical and Chemical Dictionary "4th edition, II | 1 9 87 p. 411). The mechanical properties of steel are better.> Industrial products that can be processed and used as many as 1 1 1 are counted. 0 In exploring the use of cutting m chips to purify contamination caused by halogenated organic materials, please read I 1 1 compounds.% However, the oil back is used in the cutting process. Therefore, there is oil in the cuttings of steel products. Because of the use of the belly, it is necessary to pay attention to the organic atmosphere in the present invention. 1 ^ |. The method of purifying the pollutants caused by the compound may be caused by the oil 2 Sub-item again 1 [Pollution 0 Relatively 9 Razor made use of suspicion 1 Because the oil written on page I when cutting is not used »Do not worry about the cutting chips (raw rust) of m products as mentioned above mm 1 1 2 times contamination of I chippings 0 1 1 In other embodiments of the present invention, the alloy can be used as the original m 0 or 1 1 to use a silicon alloy, a titanium alloy, a zinc alloy, a manganese alloy, and an aluminum alloy. magnesium alloy Calcium alloy 0 Titanium alloy such as grain silicon alloy> Titanium—Aluminum 1! Alloy 〇Zinc alloy t such as zinc-aluminum alloy 〇Manganese alloy • For example: manganese—t | magnesium alloy 0 aluminum alloy * such as aluminum—zinc—calcium alloy aluminum — Tin alloys> 0 magnesium alloys such as aluminum-silicon alloys ♦ Example: Magnesium-manganese alloy ΰ Calcium alloy 1 case \} -1 I such as calcium-silicon alloy 〇1 1 Where the action of kangen agent can be reduced by the original source As an example to illustrate the reaction mechanism of the 1 J m gas dehalogenation reaction of metal susceptibility * The reaction of 遢 hara cutoff is based on the report of 1 1 (“Treatment of groundwater contaminated by organochlorine compounds-~ Μ 金 靥 搛 靥 搛 1 I activity Technology for the treatment of carbon at low temperature J PPH, 1995, Vol. 26, 1 I Page 5 虢 1 Page 64 70)), the adsorption of halogenated 1 I compounds will occur on the surface of Tanglehara E » Due to the difference between the original surface of the m and the environmental aspect of the m 1 1 I condition Polarization of anode and cathode occurs> Therefore, there will be a current pulsation 〇I 1 14 This paper size applies the Chinese National Standard (CNS) Λ4 specification (2) 0 × 297 mm 3 9 498 4 3 8 6 2 1 a7 B7 Warp ,% · Ministry " Yinjin Bureau Zhen-τ · Consumer Cooperative Press 5 、 Invention Note (I5) 1 I At the same time, m on the anode forms 1 ion dissolution f electrons are implanted on the anion m due to 1 I tt Halogenation reaction, etc. 1 Through the original reaction 0 1 1 I Yang plant: F e F e2 + + 2 e _ 谙 I 1 | Health m As mentioned above refers to the carbon concentration of 2% or more,-generally the weight first read ik 1 t [3 Λ -3 .596 »The capacity is graphite, which contains 13 -W 14% carbon with a large amount of carbon. The cutting chips (raw chips) of milled m are used as waste, r- 刖 Note 1 k 1. — Generally, it is pulverized by a pulverizer. During the pulverization, part of the graphite is removed, and the suction item is attached to the surface of the pig iron. It is inferred that when this pig iron powder is coated with water film, the graphite page, -1 has the function of hibiscus. The other is that it has the function of anode. 9 It will dissolve on 9 yang m when the current flows as described in A 丄 刖 1 1 j. I suspect that the dehydrogenation reaction occurs on the cathode 1 1 reactions such as 0. The above alloys also have a deuterium effect »so it should be able to dissolve the alloy 1 1 On the other hand, a dehalogenation reaction occurs on the cathode 0 Order 1 In addition» In the case of alloys with a stronger original force than metal *, it is easier to maintain the original environment of 1 1 m. • The potential difference with halogenated organic compounds is larger. 9 De_chemical reaction 1 1 The speed is also faster. 0. JV Furthermore 9 uses magnesium — 镒Zinc alloy—Aluminum alloy—Zinc—Calcium alloy I Gold-Aluminum—Tin alloy and other alloys * May be attached to metal surface due to oxide film or corrosion products »I may not be fine due to adhesion (No pure state 1 1) Pfl hinders the reaction and does not cause the problem of reducing the contact efficiency by the kangen reaction. 1 1 Therefore, the purification reaction has a high efficiency. 01 1 -W4- One of the aspects of the present invention Agent M Water-soluble compound is better than 1 I. Compared with the case where solids such as powder are added. • Its contact efficiency with 1 1 I of halogenated organic compounds will increase suddenly. • It will speed up the dehalogenation reaction. Due to its ability to penetrate into human soil, m 1 1 15 can be applied to the paper size using the Chinese standard (CNS) A4 specification (210 × 297 mm) 3949 8 4386 2 1 A7 B7 The Ministry of Justice and the Ministry of Justice decided to issue the J-consumer cooperation privately issued V. Invention Description (16) 1 1 Original m Note to people »Therefore, there is no need to physically dig for mixed operations. Unstable field in its original state Contains > Can also recover leaching of pollutants Add 9 water-soluble m to the original m 1 and then inject t to easily restore the original state. 1 Read 1 1 The water-soluble reducing agent is organic acid or its derivative hypophosphorous acid or its derivative. T & Cautions or sulfides 塩 0 Organic acids include carboxylic acids, sulfonic acids> phenols or their derivatives, etc. 1 ^ j. 0 carboxylic acids 1 such as monocarboxylic acids containing carbon atoms 1 to 2 0 * and hydroxyl substituted Please fill in this page again on page 1 acid \ dicarboxylic acid, tricarboxylic acid or tetracarboxylic acid. Specifically, formic acid | acetic acid, acetic acid, m-terephthalic acid, etc. are preferred > special M birch m 1 I acid An aliphatic dicarboxylic acid having 2 to 10 carbon atoms such as oxalic acid is preferred. I 1 I Phenol derivatives are preferably polyhydroxyaryl compounds. Polyhydroxyaryl compounds refer to 1 1 aryl compounds substituted with two or more hydroxyl groups. 9 Aryl compounds include benzene, naphthyl, etc. m and m can also be polyhydroxyaryl compounds 1 1 9 such as 1, 2, 3-trihydroxybenzyl 1, 4-dihydroxybenzyl is preferred 0 here 1 1 1,2,3-dihydroxybenzene is also known Pyrogallic acid > Pyrogallol. Its m-based solution reacts with oxygen to form oxides. 0 JTI organic acid derivatives are 塩 m S 醢 amino anhydride, etc. 1 and M 塩 is better 1 1 I 〇 As for the counter ion There are no special restrictions 1 ions such as nano ions, gold ion ions, calcium ion 1 1 I ions, etc. m earth ions ions i imitated s, ions, titanium ions, etc. transition gold ions, etc. 1 1 inorganic ions 9 or tetraalkyl ions, etc. organic Ions can also be derived from 次 m, etc. There is no particular limitation on the reverse engraving 1 1 ions, such as r nano ions, such as gold ions, · aluminum ions, etc. m soil I 1 I gold ions, etc. * ions > titanium m Hatchling »1 I or organic ions such as tetraalkyl ions can also be used 0 1 1 This paper size applies to Chinese national materials (called Zhige Ui ⑽ Chu Chu) 39498 ^ 386 2 1 A7 B7 Ministry of Economy and Trade Standards, negative T; consumption Cooperative cooperative printing V. Description of the invention (17) 1 I The aforementioned original agent is organic acid N hypophosphorous acid and its Λ titanium zinc > manganese 1 I can be aluminum or magnesium hafnium 0 1 1 I When this original agent is added 9 Few—L-like reports often read in anaerobic. 1 1 I Intermediate metabolites such as vinyl chloride accumulate during the dehalogenation reaction »1 1 I Therefore, we can know that all reaction products are 7ϋ fully converted to dehalogenation Releasing things 1¾ out of gas part 0 In addition Use quasi-electrode potential equal to gold 靥 m or pay attention to the case of m under 1 'j. It is better to use ginseng because the 罨 position term of the compound with halogenated m is further filled with 1 1 and the difference is larger, which can promote dehalogenation reaction. 0 m The use of the original agent ft On the page of the pollutant, V. I is the combination of soil ** Μ per 100g of soil 0.01 0g is better, 0. 05 ~ 1 0 g 1 1 I is better 0 pollutant In the case of water, t Μ is preferably 0.10 g of water per 100 magnets, 1 1 I 0. 2-2 0 g is more preferable 0, but in any case 9 in the halogenated object of dehalogenation 1 of organic compounds Pollution degree fit in the field of 50 1 g / kg (or 50® g / 1) »It is necessary to add a ratio of 0.5 to 0.1 g per 1 B g of halogenated organic compound 壜 1 1 plus The amount of m original agent such as gold tincture powder is 0, but this is 1 under ideal conditions [the value of t in the η pollution site> where the microorganisms ca n’t consume oxygen wisely * The original force 0 of the original agent is consumed in addition to m. In addition, the suitable original force of the original agent can be easily consumed by the supply of oxygen in the rain or the atmosphere 1 1 > Therefore, a monthly U test must be performed before the actual field of m. Determine the concentration of each additive in accordance with the conditions of the field of the 11 1 o 1 to increase the efficiency of the original agent and pollutants m-The original agent is preferably a powder 1 I or a solution. However, the above substances tend to react with water easily. It becomes an oxidation state of 1 I * Therefore, in this case, the PΛ pollutant is directly mixed with the kanji agent * or mixed, and then 1 1 I Μ water is better to dissolve. 0 1 1 P In the case of Tongyuaner powder, t particle size 5 0 0 w β Μ The lower one is better 1 1 17 This paper size applies Chinese National Standard (CNS) Λ4 specification (210X297 male 1 > 3949 8 A7 Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs ^ 4386 2 1 B7 5. Description of the invention (18). This is because when the particle diameter is small, the resolution of the halogenated europium compound can be improved. In addition, the rhenium agent is preferably a powder having a particle size of 0.001 · »to 5 mB depending on the application, and a powder of O.OlBiMliDin is more preferable. The particle size can affect the speed of the chemical adaptation reaction. Therefore, it is necessary to pay attention to the increase of the particle size to reduce the kanyuan reaction rate per unit weight. In addition, when the particle size is above, the surface of the gold particles in the case of gold-contacting materials will be covered with a thicker layer of thorium oxide, so the central part of the gold particles may not be used. In addition, when the particle size is less than OOlaa, the oxidation speed is extremely fast, which increases the risk of oxidation by contact with water during transportation and mixing. In the case where the original agent is a metallic substance, because the surface of the powder may be entangled when the surface is oxidized, it must be oxidized before it can be used. Employ vegetative anaerobic microorganisms, for example: methanogenic bacteria (for example: Methanosarc inaS, Methanothr ixB, MethanobacteriuiaB, Methanobrev iba ^ terM) sulfate transport bacteria (for example: DesulfovibrioM, Desulfotomac u Lujn B, DesulfobacteriuaB, DesulfobacterU

Desulfococcuss), acid-producing bacteria (for example: ClostridiufflB, Acetivibnio 、), B a ct & _rooides Ruminococcus plaque), facultative bacteria (for example: B aci 1 1 n sJI, Lactobaci1lusB, AeromonasB, Streptococcus 臛, Micrococcus Bi), etc., and B aci 1 1 as Μ, PseudononasM, Aeromonas 臞,

Streptococcus, HicrococcusB has oxidation state nitrogen kanyuan activity The paper size is applicable to Chinese National Standard (CMS) Λ4 specification (2) 0X297 mm 18 39498 (Please read the precautions before filling this page)

438621 A7 B7 The Ministry of Economic Affairs and the Ministry of Justice Standards Bureau Jr Consumption Cooperation Private Printing $ ί 5. Description of the Invention (19) 1 I better 0 1 I Dependent on the type of anaerobic microorganisms, the source of the epidemic »in the pollutants The characteristics of the microbiotic 1 1 i substance can be selected as appropriate. For example, g can be used to form a microbial culture medium r— ', please 1 1 I > m acidic bacterial medium > nitric acid m original biological medium, etc. Interim reading 1 1 Choose any one. 9 When you choose, you can first determine the purification efficiency of halogenated organic compounds by using the purification treatment capability test (purification test). ί Event 1 1. Zeng Xiangyuan of Methanogenic Microbes 9 Commonly Known Methanogenic Microbiotics 1] Representative growth of lactic acid formase N ethanol acetate acetic acid% of this page VI > Pyruvate Polyprotein glands and other nutrients are available. Also, the growth source of phytoplankton microorganism 1 I is the co-culture source f. M acid m lactic acid represented by the growth source of probiotic microorganism 1 1 I methanol acetic acid > acetic acid N propyl m Acids, polyproteins, 耱, L1, 榇, etc. — * Commonly known ingredients are available. 榇 Methane, methane, organic waste water for fermentation treatment, m waste, such as 1 1 beer m grinding water m powder wastewater dairy farming m water * sugar m water or beer 1 1 distiller's meal bean dregs staining ΑΕ3 m and other more effective »can be used as the growth of the affiliated anaerobic anaerobic microorganisms When liquid 撖 biological culture medium 9 is added too much »May cause halogenated 1 1 I organic compounds to penetrate the ground and expand pollution» Conversely, when t is small, there is no 1 1 method to maintain the entanglement of microbial growth When the water content will inhibit growth 〇So 1 soil 1 1 堳 The water content (soil and other soils as the basis) The liquid-added microorganism 1 1 medium is preferably adjusted to 25 60% and preferably 35 60%. Addition 9 must fully consider the soil moisture content, porosity, particle size, composition, permeability coefficient, etc., and then determine 0. Therefore, the microorganisms added with M are cultured 1 1 | the concentration of the substrate t depends on the state of the contaminated soil, and the amount of the medium varies. 1 1 This paper music scale is applicable to the Chinese national standard (CNS} Α4 size Γ210 × 297 mm) 19 39498 43 86 2 1 at B7 Printed by the Consumers' Cooperatives of the Bureau of Decision and Standards of the Ministry of Consumer Affairs ^ V. Description of the invention (20) 1 | Prudence Jingjing Determined after the treatment capacity test. 〇1 1 In addition, the stability of the water content in the soil is maintained »mixed with silica m soil 1 1 I or various water-retaining materials N humus soil, etc. have an effect 〇 ^ _____ 1 I Please I For clay-like soil or agglomerated silty soil and other low-permeability materials, please read 1 I Read 1 I for high-quality occasions * Only use entangled m for low contact efficiency when descaling treatment> It takes a long period of time to carry out »Therefore The external oxide supply conditions may cause the reduction state to pay attention! Instability 0 This kind of plutonium can be supplemented with the microbial growth item in addition to the original agent 1 Fill 1 The substrate has a carbon source to decompose under neutral conditions Purify and stabilize the original manuscript in the state of one hundred and one, and achieve complete dehalogenation purification. η '· 1 1 1 After the reducing agent is added in the present invention, it is better for M to maintain the radon contamination in the environment of Kanbara 1 1 0. The reducing environment here is to cut off the oxygen L 1 gas in the air, such as water. The subordinate anaerobic anaerobic microorganisms are decomposed and decomposed. »When oxygen is used, the growth of chlorophyte will be inhibited. 0 m The oxidation of the original agent is easy to reach m. The original 1 1 environment 0. On occasions, there are also cases where the dimensionality is maintained by the 埵 hara 1 1 environment. 0 In this case, the standard electrode potential of the quasi-hydrogen electrode at 25 times the original environment is (j 1 + 200 " 2400m V range is better, + 2 0 0 ~-1000 it V range is better% + 100 1 1 -600 mV range picture is even better 0 1 1 In the present invention, the original halogenated halogenation reaction is in progress 9 Μ Maintaining the predetermined pH 1 1 is good. Specific α of * That is, M PH5. 8 ~ 8 • 5 is better * ρ Η 6 ~ 8 is better, 1 I PH6. 2 ~ 7 • 6 is even better 0 So 9 In the stable environment to maintain a specific pH and anaerobic 1 I in the environment of the environment * can be maintained M on the surface of the primogenizer compounds 1 1 Halogenation activity 0 1 1 At the same time »It is also possible to pre-add a pH adjuster in the pollutants 0 The pH is adjusted 1 1 This paper size is applicable to the Chinese National Standard (CNS) Λ4 size (2! 0X297 mm) 20 3 9 49 8 A7 438621 B7 V. Description of the invention (21) (Please read the notes on the back before filling in this page.) In the case of acid soil, it is better to use _t metal compound or gold-earth metal gold-earth compound, specifically In other words, it is possible to use general soilless material for soil improvement. For example: limestone, quick lime, slaked lime, calcium osmate (stone), magnesia, geotechnical, perlite, zeolite, etc. In addition, in the progress of the reaction during the treatment, it is better to add various piles, piles, and β-eaves. This is mainly because it is known as a long-lasting organic soil improvement material, which has the effect of adding microorganisms, supplying nutrient sources for removing organisms, and maintaining water. This microorganism has the function of originating and maintaining the anaerobic environment, and at the same time, it also decomposes and removes the odorous gases that are produced at the same time when the anaerobic fermentation of soil is destroyed, especially the sulfonium-based odor gas led by M hydrogen sulfide and methyl hydration. The role of «. In addition, it is generally known that various composts include various microorganisms such as actinomycetes and bacteria. Among them, there are many microorganisms that can effectively decompose sulfur-type malodorous substances. Therefore, it is easy to speculate that a variety of useful microorganisms can be separated from various composts. And, compost can be used as a countermeasure for removing malodor in livestock manure treatment. According to the conditions of the Ministry of Central Standards Administration of the Ministry of Standards-T-elimination cooperatives, according to the aforementioned conditions, the soil is added with an inorganic substance such as a metal test compound and an "I soil gold compound" (mostly referred to as an inorganic soil improvement). Materials) After pH regulators, phytoplankton (organic matter-based soil improvement materials), and microbial culture media, the anaerobic microorganisms in the soil immediately began to grow, and the soil quickly formed neutral, anaerobic The environment, which is the buried source of the chemical dehalogenation reaction in the present invention _ when it is combined with human soil, when adding inorganic substances, organic actinides, and bio-implantation substrates, mixing at the same time is not without any trouble, even At the same time, it is more helpful to keep the paper size applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) 21 39498 A7 438621 87 V. Description of the invention (22) Long-term anaerobic environment, and the cost is low, which is conducive to pollution Management of purification procedures. When the reductive dehalogenation reaction of the present invention is applied to an actual contaminated area, no construction of large-scale equipment is required, as long as various soil improving materials and reducing agents are mixed in the contaminated soil of the subject, and then microorganisms are added to cultivate the substrate. At the same time, it is enough to cover the purification area with K polyvinyl chloride plastic cloth and other M to prevent water evapotranspiration and the mixing of South water and keep warm. In addition, in order to prevent the occurrence of catastrophic obesity and suppress the evaporation of water, it is best to spread mulched leaf soil or compost on the soil surface of the purification area as needed. In the reaction eaves system of the degenerative dehalogenation reaction of the present invention, there is still not fully understood at present, and the present inventors believe that it is as follows. First, keep the soil and other pollutants at pH 4.5 to 9.0, and maintain the potential of the quasi-electrode at 25t under the anaerobic environment at +200 to-2400 «V, and add inorganic substances to the soil Microbial activators based on systemic substances and actinides and microbial culture media will help create an anaerobic environment to take advantage of the growth response of the organisms in the soil. In this case, because the anaerobic withering organisms grow rapidly in the soil, the chemical dehalogenation reaction will hardly be inhibited. Therefore, the biological dehalogenation reaction and the chemical dehalogenation reaction begin almost simultaneously. The biology and enzyme responsiveness of the control system have not been studied by the researchers, so it is still unclear, but the anaerobic microorganisms such as methanogenesis organisms and acid-protozoic microorganisms and various species in the anaerobic environment are still unknown. In the case of anaerobic sludge and bottom mud, when anaerobic excitants are growing, they can be deaerated one at a time for the slow microorganism reaction (please read the precautions on the back before filling this page)

.IV The Central Bureau of Standards of the Ministry of Economic Affairs of the People ’s Republic of China is responsible for cooperating with consumers. The paper size is applicable to the Chinese National Standard (CNS) A4 (210X29 · / mm) 22 39 498 43862 1 B; Shell- " Printing Cooperative Co., Ltd. V. Description of the Invention (23) ί 1 Report plus K Reasoning »In the present invention, the same slow m original desulfurization 1 1 halogenation reaction should be performed 〇1 | After purification starts in the present invention Initial reaction time of 1 m month * Chemical demineralization 1 1 1 Most of halogenated anti-m occupies the majority • Later, as the halogenated hafnium compound contamination concentration decreases, the original activity of the original agent m is reduced. ♦ Chemical dehalogenation reaction Decrease * area> Note I Relative biological decomposition reaction is gradually becoming an advantage > However, dechlorination is a long-term intuition j. It is going on. When the biological dehalogenation reaction starts to work, the halogenation has a coking term. Fill 1 The concentration of chemical pollution has been considerably reduced. 1 It will not become a biological dehalogenation reaction. V 1 Concentration barriers r will become the most low-level pollution that can be exerted by biological reactions. 1 Desulfurization, _ >-· 1 I halogenation reaction More active 0 Therefore * In the purification effect of halogenated I 1 1 compound pollution due to halogenation »From chemical dehalogenation reaction and biological dehydration 1 1 Order 1 The interaction of the dentification reaction can be purified to a very low level Concentration 〇 The chemical and biological radon degassing method of the present invention »Combining low-solubility 1 1 soil modifiers with inorganic% substances and organic matter, not only does 1 1 cause halogenated organic compounds to be dissolved in the polluted soil radon »And because the water retention of the contaminated soil is maintained, the halogenated organic compound is not polluted and re-infiltrated 1 I into the deep ground below the contaminated site M * Therefore > It can be cheap in a short period of time and J 1 I simply purifies the halogenated organic compound to contaminate the soil. 0 1 1 The reaction of the present invention * can be carried out until W. The monthly dechlorination reaction is completed * 1 1 This is the best case for the full purification of halogenated organic 1 1 compound pollutants, such as the purification of tetrachloroethylene and 2 1 1 gas ethylene pollutants. * The main product is TC ethylene free of chlorine > 1 j Acetyl organic compound 1 In this reaction, there is almost no harmful intermediate product containing atmosphere 1 I Product 1 can obtain excellent results. 0 1 1 This paper uses the Chinese National Standard (CNS) Λ4 specification (210X297). 23 39498 438621 A7 B7 V. Description of the invention (24) In the second aspect of the present invention, the kangen agent used in the first aspect of the present invention can be used. The halogenated compounds can be decomposed even when no specific host source is added and there is no biological reaction. The rhenium agent used in the third aspect and the fourth aspect of the present invention will be described below. In the third aspect and the fourth aspect of the present invention, a suitable activator having a standard electrode potential of the pseudo-hydrogen electrode at 25t of 130nV to -2400mV can be used. Preferably, the reducing agent used in the first aspect or the second aspect of the present invention is used. However, the rhenium agent used in the third aspect and the fourth aspect of the present invention is not limited to the original agent used in the first * 1 aspect and the second aspect of the present invention, and can be used as: Tangled iron, raw), manganese, nickel, magnesium, copper. The metal susceptible to gold, manganese and manganese exist in a large amount in an oxidized state in natural soil, and even if the addition has a small impact on the ecosystem, it is safe. In addition, it is easily accessible because it is trafficked. The amount of the primordial solution used is as described above. The kangen agent used in the third aspect and the fourth aspect of the present invention has a standard electrode position of -400bV to -2400bV at 25 υ for a standard hydrogen electrode. Gold tincture is preferred. It is preferable that at least one selected from the group consisting of the above-mentioned virgin agent M, suitable raw material I, raw material, silicon-alloy, titanium alloy, zinc alloy, manganese alloy, aluminum alloy, magnesium alloy, and calcium alloy. In addition, the aforementioned transport agent is preferably a water-soluble compound. The aforementioned transport agent is also preferably a powder having a particle size of 500w βK. The third aspect of the present invention will be mainly described below. The common features with the first aspect of the present invention will be omitted. In the third aspect of the present invention, it includes a transport agent that sets the 25C counter-quasi-hydrogen electrode to a quasi-electrode position of 130 nV-2400 iaV and a slave-type anaerobic withdrawal. (This page)

The paper size of the V edition applies to the Chinese National Standard (CNS) A4 specification (210X 297 mm) 24 39498 438621 A7 B7 The member of the Central Bureau of Standards of the Ministry of Economic Affairs of the People's Republic of China printed the fifth, the invention said / (25) Biological nutrition The step t of adding the source to the pollutant can thus decompose the halogenated organic compound via m-original dehalogenation as described above. In the third aspect of the present invention »The aforementioned nutritional domain is composed of organic carbon and the aforementioned organic state. 20 50% by weight of oxidized nitrogen and 20 30% by weight of oxidized nitrogen containing the stated organic carbon are preferred. This can change the microbiome associated with the degenerative dehalogenation reaction when decomposing halogenated europium compounds > Suppression of susceptibility to blackening soil odor, and generation of malodorous gases such as sulfur fermentation. Here the content of oxidized nitrogen is 9. For example, the combination of osmium nitrate refers to the weight of nitrogen atoms in osmium nitrate. Similarly, 9 organic state The content refers to the weight of the carbon atoms contained in the m. 0-In the process of dehalogenation. 1 By adding the source ingredient, the soil will cause entrapment of sulfuric acid > Malodorous gases such as hydrogen sulfide fermentation and methane gas Αγν may be generated. In addition, • The gold layer powder reacts with water to generate hydrogen under entrapped conditions. In addition, there are also m acids and m sources, and as a result, sulfur is suspected to cause soil pollution. Where it turns black, but where the nutrient source contains 20 to 50% by weight of oxidized nitrogen in the form of carbon, 1 these reactions can be suppressed. That is, the organic carbon source of the growth substrate has been determined to be mainly in the oxidized state by soil tests. Nitrogen can be used by active microorganisms9 As a result, the inhibition of Ayuan fermentation and sulphuric acid burial reaction is inhibited. 0 Nitrogen is mainly produced in the soil. Generated hydrogen 9 so there is no concern about pyrophoric explosions 0 In addition > Because the materials added to the source do not use sulfur-containing components or sulfate radicals »It can more reliably inhibit hydrogen sulfide fermentation gas and sulfide m from generating 0 pollutants Where ft is added in the oxidation state of nitrogen 9 9 Because the organic nitrogen is sized in accordance with the Chinese National Standard (CNS) A4 (210X297 mm) 25 39498 # Please read the precautions on the back 1¾ before filling out this page 438621 A7 B7 蚵部 部 中 定 #Beijuan, overworked and consumed by the Hezhu Society 5. Introduction to the Invention (26) 1 1 Oxidized nitrogen will be retained after consumption 9, so it is impossible to maintain a sufficient suitable environment. Example 1 | If you can only reduce the oxidized m potential of the saturated silver chloride electrode to + 100 mV range 1 I degree, you need to pay attention that it will become almost impossible to perform the degenerative dehalogenation reaction. 0 Please 1 1 first 1 In addition »Conversely When the amount of oxidation-state nitrogen source added is extreme compared to the organic-state carbon source, the amount of nitrogen generated at the beginning is almost depleted of the oxidation-state nitrogen. Therefore, surface I-1 Note |原 原 反 懕 〇 Therefore • Adding notes • 丨 '1 The ratio of the carbon source with carbon dioxide and the nitrogen source with oxidation state is very important. 0 then fill in 1 Λ-Generally known. A 1 ca 1 i κ ene S manuscript Leut η Q Ρ huarac 〇〇c U d ft nit Γ if 1 〇aj \ _Sl ^ Gasification in aqueous solution 1 1 The consumption rate of nitrogen is organic carbon source 40 50% by weight, but the inventors have added! 1 I added as a result of the protozoan reaction of various soils in the present invention 1 order of oxidation state nitrogen as the organic carbon source 20 50% by weight 9 or better 20 1 When 30% by weight is added in proportions »No Jiayuan f sulphur yellow malodorous gas produced 1 1» and the oxidation of nitrogen and nitrogen has completely disappeared and halogenated organic compounds can reach a complete 1 1 dehalogenation plant. The addition of oxidation state nitrogen during the degenerative dehalogenation reaction will} \ I hinder the reaction (Putian et al., P Γ 0 C. 8 th I nternat I ο η a 1 C on t * 1 1 I on anaer 〇bi CD igest 1 on »1 97 1997 t Vol 2» 49 2, -4 9 9 Page 1 ί) 〇 However, in the present invention, the addition ratio of oxidized nitrogen and fluorinated carbon is appropriately adjusted, 1 1 can prevent oxidation Nitrogen reducing active microorganisms predominate and produce sulfur 1 1 series malodorous gas A flammable gas, such as a hospital, maintains the original 1 1 state in the pollutant *. It should be possible to achieve a stable and effective dehalogenation reaction 1 I that cannot be achieved by metal powder alone. Therefore, the present invention can be said to break the common sense. New Purification Method 1 I Method 0 1 1 This paper relies on China's national compensation cnS) M specifications (Training x Tenglu) 3 9 4 9 8 438621 B7 Economics & Printed by the Ministry of China Precision Industry Bureau Consumer Consumption Cooperatives V. Description of the invention (27) 1 I oxidation state M 塩 塩 nitrate form is better 0 The aforementioned 塩 塩 contains m gold 1 | belongs to m 塩 塩 m earth metal 塩 > iron nitrate Λ titanium nitrate > zinc nitrate, 1 I manganese nitrate, aluminum nitrate and Magnesium nitrate is better * The aforementioned hafnium nitrate > Λ contains nitric acid 1 1 potassium nitrate or calcium nitrate is better. Read first 1 1 In the present invention, it is better to supply water-soluble organic carbon. I without In the 3m sample of the present invention t Use the first aspect of the present invention 1 • 丨 and the 4th aspect can also be 0 Water-soluble organic carbon with sugar organic acids and their derivatives Please complete this page 1 Λ | Bio-lower fermentation, m molasses solution, or fermentation waste solution and mixtures thereof are preferred. Organic carbon has the function of a growth matrix. J Makes m organisms grow 0. There is 1 I m. Carbon can also use glucose N m Sugars and other sugars N Acetic acid vinegar yogurt 1 1 j Organic acids such as acid or 欐 m 塩 1 耱 Honey waste liquid fermentation Fermented liquid beer lees 1% Organic waste liquid waste such as bean dregs o The amount of organic carbon added must be First consider the oxidizing power of the pollutants and the concentration of the halogenated organic compounds 1 1 before deciding > But the pollutants are generally a mixture of soil and soil »To maintain the original state of m 1 1 t to 1 kg The soil must be added with about 1 kg of organic carbon. The concentration of the halogenated organic compound whose halogenated object is more than 50Bg / kg in the field τ I combined> The amount of halogenated organic compound added to 1 * g must be increased by 1 0 ~ 2 0 ag 1 1 | ratio of organic carbon. However, this is a standard. ♦ In actual pollution sites, 1 1 not only has the oxidizing power of pollutants, but also the oxygen supplied by rain or air. 1 1 Consumption of organic carbon and the rigorous power of gold powder described below. 9 Perform 1 1 on-site to determine the concentration of each additive after the test is performed. 0 1 1 The fourth aspect of the present invention is a halogenated organic compound% solid pollutant 1 I purification method 0 The pollutant is as above ♦ The fourth aspect of the present invention includes a step of sticking a specific carrier liquid and a specific m original agent in the stain 1 1 I dye. This mixing step 1 1 This paper size is applicable to the State Council of China (™ size⑽x 腾 楚) 3949 8 438621 B7 Economic " —Middle and Medium Standard Bureau Member ^- Printed by Fei Cooperative Co., Ltd. 5. Description of the invention (28)! | And adjust the pollutants to a range of PH 4. 5 ~ 9 .0 _ 〇I 1 Μ, 丨 _ Yue ϋ When the appropriate agent is in the form of powder »it is best to »-R- Add the nutrient in 1 [January] [] and remix the f in the pollutant, and then add the m or m original agent to the above please 1 1 1 1 in the mixture and then re-mix 0 to prevent The oxidizing agent is oxidized in the 1 1 liquid that was previously read, so that the priming force can be exerted in the pollutants 0 or 9 »* .. The reducing agent is a water-soluble compound, and the aforementioned priming agent is soluble. Note It ’s better to understand in the nutrient solution described in the month. So it ’s easier to fill in the field than the solid-level protozoal agent. Reimplement it at the same time. At the same time, it is easy to save and move a lot of liquids. In addition, to prevent writing this page I Zhiliyuan m is oxidized during storage 9 The nutrient solution containing m source is best stored In a tightly closed container-1 1 0 1 | | In the mixing step, the solution can be added to the contamination 1 in 2 times. A large amount of solution is mixed with the soil stick, for example. Suitable occasions »Because the soil mass in the liquid is difficult to cut m, the force K is difficult to act 1 so the soil mass cannot be broken > It is not easy to move in the fluid 1 1 body. Relative to this * When a small amount of nutrient solution is added * can be 1 i Η easier The soil is broken by the cutting force. * It is easy to mix more evenly. Therefore, it can be added at the next time. Once more nutrient solution is added. 0 One of the spring application states, i.e., the best r I is in the first stage. ^ > Add 1 ~ 10% by volume of the aforementioned nutrient solution to the above-mentioned pollutants and add the above-mentioned pollutants to the pollutants, and then add M to the above-mentioned pollutants in the first 11 steps. \ The mixing is more than that in the first stage. A lot of the aforementioned 1 1 nutrient solution 0 other fruits It is best to add and mix the first step in the first stage of the contamination. If. The above mentioned 1 1 nutrient solution is 1 to 5 vol% of the amount of the contaminated »The second stage step is followed by W · Add to the above-mentioned pollutants> Mix 1 I and the first stage add up to 5 to 10% by volume of the above-mentioned pollutants 1 1 I nutrient solution 9 In addition, add t to the above-mentioned pollutants in steps > Mixing ratio No. 1 1 1 This paper size is applicable _ home standard (⑽Μ specifications (Dan Tengdong) 3 9498 kl Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economy 438621 __ B7 V. Description of the invention (2 9) stage and In the second stage, a larger amount of the aforementioned nutrient solution is added. However, regardless of the implementation state, only the nutrient solution for young children is added in the first stage. Therefore, the cutting force in the mixture is easily exerted, and the mixture can be mixed more easily. In any embodiment, the nutrient solution added to the pollutant is preferably 15 to 25% by volume of the amount of the former pollutant. The so-called final refers to the sum of the nutrient solution in the occasion where the nutrient solution has been added several times. Second, the mixture was left to stand under low aeration conditions. Contaminant dehalogenation in a standing project removes contaminants. For example, it is more difficult to stand for 2 or more, and it is more to be left for 1 month. The standing state M is preferably separated from Zhou Yuan's sickle. In this way, halogenated hafnium compounds in the mixture can be prevented from diffusing and penetrating to the surroundings. In order to maintain low aeration conditions, the aforementioned pollutants are preferably covered with non-aerated material. For example, it is better to cover with polyethylene plastic cloth. This is to promote the cultivation of anaerobic organisms. To maintain low aeration conditions, the aforementioned contaminants are preferably immersed in an aqueous solution. In the aforementioned standing step, the aforementioned pollutant is preferably maintained at 17 to 60 TC for at least the first 3 days, so as to promote the cultivation of microorganisms in the mixture to increase the concentration. In the aforementioned standing step, it is preferable that the aforementioned pollutant M is maintained at 17 to 60C for at least the first 5 days. In the aforementioned standing step, the aforementioned pollutants can be maintained for at least the first 3 days, preferably 5 days, and more preferably between 20 and 40¾. Exemplary Examples The following examples specifically illustrate the present invention. However, the present invention is not limited to these embodiments. This paper size applies to Chinese National Standard (CNS) Α4 specification (210X297 mm) (Please read the precautions on the back before filling this page}

3 9498 29 4 3 86 2 1 Λ7 B7 V. Description of the invention (30) The purification experiment of the four atmosphere ethylene in the example of the present invention, the biological medium is the culture medium used in Table 1 to produce microorganisms, or Table 2 is a medium for carbohydrate-producing microorganisms. Each purification experiment was performed under a chamber irrigation (12 ~ 23C). The soil of the Phyllanthus pupae was determined by pure water = 1: 1 (weight ratio), and then measured by a pH meter HM-5b manufactured by Miyako Industrial Co., Ltd. For the measurement of the original tritium oxide position of the saturated silver chloride electrode, the soil: anaerobic water = 1: 1 (weight ratio), and the ORP meter 0D1C-3 type ORP composite electrode PS made by East Asia Radio Industry Type -8160 is immersed in humans. After 30 minutes of standing, it will be stable. The analysis of vinyl chloride in soil is based on the method developed by Yokohama National University in Japan (Miyamoto Kenichi et al., "Measurement Method for Pollution Content of Low-boiling Point Eaves in Soil", Journal of the Water Environment Society, 1995, 18th Volume 6, No. 6, pp. 47 ~~ 488 > After immersing the soil test sample in acetic acid to extract the ethylene from the acetic acid, then extract the ethylene with decane, and then inject the ethylene decyl complex solution into Hitachi In the column of the gas chromatograph G-5000, the WFID detector analyzes the gasification of ethylene gas produced in the β gas phase. It is printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Gas Economy (please (Read the precautions on the back before filling this page.) Polyethylene gas injection into the Hitachi G-5000 20% TCP chΓololosorbWAWDHCS60 ~ 80Besh column, detection and analysis by MFID detector. Determination of gas phase For the generation of ethylene and ethane gas, use Porapack Q column, Hitachi gas phase analyzer G-5000, FID detector to detect and analyze. The hydrogen, carbon dioxide and methane produced in the gas phase are determined. With GL-Scientific Gas Chromatograph-Model 320, TCD Detector, activated carbon 30/60 or Mcclecular Sieve 13X analysis. This paper size applies Chinese National Standard (CNS) Λ4 ^ grid (210X297 mm) 30 39498 438621 Λ7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Explanation (3 1) Reduction 锇 Use of Wako Pure Chemical Industries Co., Ltd., Wako 1 Raw Materials, Article No. 0 9 6-0 0 7 8 5. Unless specifically stated, 载 hara birch finger powder. Examples 1 ~ 5, and 7 ~ 10 are mainly the same as the first aspect of the present invention. Moglun Li 1 In Example 1, Tongyuaner used reduced iron powder. The contaminated soil taken from the contaminated soil surface of the A factory was used. The polluting substance is mainly tetrachloroethylene, and the amount of tetrachloroethylene contained in the Iks dry contaminated soil is 25mg. M125ml capacity sample bottles each take 14 g of this contaminated soil, and 14 kinds of experimental conditions shown in MG, Measure the pH of contaminated soil, the oxidative potential of the saturated atmospheric silver electrode and the time variation of the reduction of tetrachloroethylene. The moisture content of each experimental group is in the range of 48-50%. Replace with nitrogen The gas phase part of the bottle. The contaminated soil in the test was taken from the soil layer. Its physical characteristics are 47% moisture content, water permeability coefficient 10_4 ~ 10 ~ 5cm / sec, PH6.6. The original potential was 380 mV. Experimental conditions: A. Use methanogens to form microorganisms (Table 1) to react (please read the precautions on the back before filling this page). Soil staining and soiling ①② Soil staining and soiling of Liaopu soil ③ Φ Basic culture and growth of alkyl alkane methylation and growth of raw alkane 0 0 The original paper can be mixed and mixed. The paper size is applicable to China National Standard (CNS) A4 (210 X 2 to 7 mm) 31 3 9 49 8 A7 Printed by the Ministry of Economic Affairs " Standards Bureau Consumers' Co-operative Co., Ltd. 438621 __ B7 V. Description of the invention (32) Lime and fertilizer A (main component limestone) l.〇 s + cow manure compost 1.0s + rotten leaf soil 0.5 g

⑤ Contaminated soil + methane generation medium 9.0b1 + ® original cut 1.0S + mixed limestone fertilizer B1 main components limestone and Wo Zhimin) 1.0g ten sewer sludge piles El.〇s + rotten soil 0.5S ⑥ Contaminated soil + methane generation medium 9.0 b1 + Kanhara iron 1.0s + mixed shellfish fossil fertilizer (main ingredient shell fossil) 1.0g + sewer sludge pile IE 1.0g + rotten leaf soil 0.5g ⑦ contaminated soil + formazan production medium 9.0ml + Kanahara 1.0g + Mixed calcareous fertilizer A 1.0g + humic soil l.Og Here, "Wo Zhimin" is humic acid rhodochloite, and its composition is humic acid (50 ~ 60%), rhodochloite (15%) ), Total nitrogen (3%), silicic acid (3%). (Please read the notes on the back before filling this page)

Table 1 Compositions of methanogenic organisms for tapping and biodegradation composition Tap water 8 0 0 b 1 Inorganic rhenium solution 1 50m 1/1 Inorganic rhenium solution 2 50 * 1/1 Inorganic rhenium solution 1 〇ι 1/1 Vitamin solution 1 0a 1/1 NaHCOs 5. 0g / 1 Enzyme extract 1. Og / 1 Polyprotein 20 g / 1 Glucose 25 g / 1 1 Sodium citrate 25 g / 1 1 Formic acid 50n 1/1 L-cysteine gallate solution 5 0m 1/1 Na2S * 9H2〇 solution 5.0e I / 1 pH 6 · 9 ~ 7. 2 This paper size is applicable to China National Standard (CNS) A4 size (210X297 male f) 32 3 9 498 438621 A7 B7 Description of the invention (33) In the foregoing experimental conditions, the content of the content indicated by the aforementioned reaction system formula is verified 5) 2 ④ 1 As in the example, as follows. Ming: Say: S ο soiled with loam 3 For the quantity of the sample, add the table M, cover and re-glue the rubber, the base material in the rubber, and then cover and mix it. After mixing, add the soil material, base leaf, fertilizer, and humus, and use 5g of stone. 0 The piles of synbiotics and mixed micro-fertilizers, og raw dung, 1 ox and iron, og original show 1 Dinglan and show the picture 1 Test the species 7 mentioned above. The silverized atmosphere of the prepared pre-tightened paper and foil aluminum and the saturation value of the pair 7 Η 7 ′ 后 含 含 含 3 3 3 3 3 3 3 3 3 l l l l l l l l l l 2 / / The in situ display of tv-based culture microphysical micrometer C shows that the acid source of the electricity station is used to make oxygen B. The figure is shown in Figure 1X The first compartment (Please read the precautions on the back before filling this page ) Organized control of soil pollution ① The foundation is based on the cultivation and cultivation of the original protozoan acid and thiosulfur acid + + + I 8 I soil and soil pollution and contamination ②③④ Sugawara suitable for Sugawara Compatible limestone content into main A 4 g material 5 κ ο quality soil ash floc decomposing + IB heap MU cattle-based culture original 0 acid sulfur + vermiculite contamination ⑤ suspected original + mix 1. S Stucco and stone dirt combine with the soil and the limestone to form the main soil rot underwater g mud: S g Road. 0 underwater iron 0 ^ 遢. 0 1 +) -1 stone ο chemical ^ 0 Pei Chengyuan S Sulfuric acid as main acid + soil-like soil stained with soil-like soil © Soil «Rotten + This paper applies Chinese National Standard (C-NS) Λ4 regulations (210 × 297 mm) 33 3 9 498 438621 A7 B7 V. Description of the invention (34) ⑦ Contaminated soil + sulphuric acid medium 9.0 »1+ Shiyuanlang ll.〇s + mixed shell fossil fertilizer (main component shell fossil) 1.0g + sewage sludge compost 1.0g + saprophytic soil 0.5g ⑧ contaminated soil + tartarium tellurate culture medium 9.0inl + Sugawara Hungarian 1.0g + mixed calcareous fertilizer A (main ingredient limestone) 1.0g + saprolite 1. s + Rotten leaf soil 0.5 g Table 2 Composition of the components of the medium for sulphate suitable microorganisms Tap water 1 0 0 0 b 1 K2HPO4 0 + 5 g / 1 NH4C 1 1. 0g / 1 N a 2 S 0 4 1. 1.0g / 1 CaC12 · 2H2〇0. Is / 1 M g S 0 4 ♦ 7 H 2 0 2. 0g / 1 Yeast extract 1.0 g / 1 FeS〇 4 · 7H2 0 0.2g / 1 trace vitamin solution 1 0m 1/1 sodium lactate 25m 1/1 Sodium ester acid 25n 1/1 Sodium ethionate 0.1 g / 1 Ascorbic acid 0.1 g / 1 pH 6. 6 ~ 7. 0 (Please read the precautions on the back first Fill out this page} This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 34 3 9498 438621 A7 __B7_ V. Description of the invention (35) The test results of Baoshi Example 1 are shown in Section 1 A second mouse. In the fourth experiment, ⑤ r ④- S test 贲 and ⑤, ④ 1 A test test B test test and ⑦'⑥. In everything. The raw material is slightly less than that of the original fertilization system a. The organic acid is not sulfur-free, and it is slightly different from the original culture of the province. This mixture is also used in combination. The knowledge of the former can be further reduced, and the cyclicity of the chlorinated chlorinated ethene is about 7 附 ρ in the loam soil. It can be used in culture and cultivation, and it can be used for cultivation. Ethylene chloride and tetrachloromethane in the environment of cyclic gas anorexia and environmental separation method are not contaminated with loam soil and the mixed iron source is only shown in Fig. 2 and _ 1 Use the second sample of chlorine, which is followed by 〇ί 〇 maleene, to obtain the gas, and then use the control system to control the powder, and use the powder to control the original lotus. Use 0) I0 (sulfur in the original truncated acid 2 and the example, application I ) Assets (I ferrochemical and loam soil contaminated by ethylene chloride four extraction plant Η A in the same phase 11 cases of implementation § Example of implementation k} 1 The same as every 0 for the test and then make the whole soil preparation, limonene Acetochlor, chlorene, and tetraethyl aeration add four or four medium-sized loam soils that are suspected of being dry loam soil (Please read the precautions on the back before filling out this page) Printed on the Central Standards Bureau of the Ministry of Economic Affairs® C Industrial Consumer Cooperatives to develop a test for the reduction of each amount of reduced ethylene,-real carbon type electrochemical CO Can be converted to K in original oxygen, then in oxygen and hydrogen, and the sum of alkane-like chloroethyl in the silver product of the extreme amount of the battery, and the amount of planene capacity is verified on the gaseous tetradecane. 0 ί 8 4 The rate of water contained in Junjie ’s test results is 0% raw ul-t. The saprophytic and defertilization of the soil extermination groups of the exhumed soil, the raw mud plain B, will be under the water. Contamination-steam in the steam ④-B-high test kettle bacteria and killing ④ phase of the product used in the Department of gas phase internal removal of the bottle sample should be taken instead of the degassing nitrogen nitrogen M acetone Inspection product M. Agaricus The paper size is in accordance with Chinese National Standard (CNS) Α4 specification (2 × 297 mm) 35 3949 8 4 3 86 2 1 at * B7 V. Description of the invention (36) Experimental conditions: A. Use of methane Formation group for forming microorganisms (Table 1) Reaction group ① Contaminated soil + methane production medium 9,0 (〇1 + 1 raw iron 1.0g + mixed calcareous fertilizer B (main components are limestone and wozhimin) 1.0g + sewage sludge 1, Og + rotten soil 0.5g ② contaminated soil + methane generation medium 9.0ml + FeC 丨 2 l.〇 s + mixed calcareous fertilizer B (main ingredient limestone and wozhimin) 1.0g + sewage sludge compost 1. 〇S + rotten soil 0.5s ③ polluted soil 堳 + methane generation medium 9,0iil + FeS〇4 1.0g + mixed Calcareous fertilizer B (main ingredient limestone and Wo Zhimin) 1.0g + sewage sludge compost 1.0g + saprophytic soil 0.5s ④ Contaminated soil of #borrowed soil + methane generation medium 9.0al + 1.0 g of burial soil + mixed calcareous fertilizer B (Main ingredients limestone and Wo Zhimin) 1.0s + sterilized sewage sludge compost 1.0g + aunt. Bacteroides rotten leaf soil 0.5g B. reaction group using lutetium tellurate culture medium (Table 2) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) ① Contaminated soil + sulphuric acid medium 9.0ml + reduced iron 1.0g + mixed calcareous fertilizer B (main ingredients limestone and fertilized Min) 1.0 g + 1.0 g of sewage sludge compost + 0.5 g of saprophytic soil ② Contaminated soil + sulfuric acid into the original culture medium 9.0ml + FeClz 1, 0g + mixed calcareous fertilizer B (main ingredients limestone and Wo Zhimin) 1.0g + sewage sludge compost 1.0s + humus soil 0.5g ③ polluted soil + hafnium tellurate Original medium 9.0ml + FeS〇4 l.〇s + mixed calcareous fertilizer B (main ingredients limestone and Wo Zhimin) 1.0g + water The paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 36 3 9 49 8 438621 Λ7 Printed B7 by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Description (37) Road sludge compost 1.0g + humus soil 0.5g ④Contaminated contaminated soil + Sulfate medium 9.0IB1 + Suppressed iron 1. ¢) g + mixed calcareous SB material B (main ingredients limestone and wozhimin) 1.0 g + sterilized sewage sludge compost 1.0 g + sterilized saprophytic soil 0 · 5 g The results of Example 2 are shown in Tables 3 and 4. It can be seen from Tables 3 and 4 that scandium iron can decompose tetragas ethylene. In contrast, the ferrites such as F e C 1 2 and F e S 0 4 or the males of P e C1 3 cannot be decomposed. At the same time, it can be known that the mixed soil can be mixed with the original and inorganic fertilizer (pH adjuster), various kinds of piles, and the medium for methanogenic microorganisms or the medium for sulfuric acid, which can keep the soil stable and stable near PH7 The sexual environment and the anaerobic environment make the tetraethylene in the soil quickly decompose. It is also known that when FeCU or FeS04 is added to replace Korihara, the decomposition of tetrachloroethylene is almost impossible. In addition, in the case of microbial sterilization (Experiments A-④, B-④), there is only a relatively small amount of tetrahydroethylene decomposition, indicating that the method of the present invention is reducing by the multiplication of biological reactions and chemical reactions. Dehalogenation reaction Table 4 shows the analysis results of the gas components in the sample bottles in experiments A-① and B-①. It is known that a large amount of hydrogen, carbon dioxide, ethylene, and ethane can be generated in these experimental groups. At the same time, the tetrachloroethylene, Cis, and DcE measured in experiments A -① and B -① were all in a very small amount. Calculating the material balance of experiments A-① and B-①, we can know that the decomposition amount of tetrachloroethylene in the soil can be transformed into 71% and 58% of ethylene and ethane. The same results can be obtained by using livestock compost instead of sewage sludge compost. The paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) (please read the precautions on the back before filling this page). The middle and second grades of Part II are negative. J. Consumption Hezhu Private Printing 4 386 2 1 at B7 V. Description of the invention 3fc) Table 3 Test results of dehalogenation reaction using contaminated soil with high concentration (after 55 days of culture) [A] Blank group of methanogenesis-removing medium project group ① Yuan Hung ② FeCl2 ③ FeS〇4 © Sterilization treatment pH 5.31 7.55 4.98 6.91 7.30 0RP * 266 -288 90 -189 -47 PCESW 75 0.5 67 58 46 [B] Blank group of the medium for the use of the metabolite for telluric acid ① Shimon iron ② FeCl2 ③ FeSCU ④ Sterilization treatment pH 5.31 7.19 4.89 7.39 7.36 0RP * 266 -414 109 -138 -52 PCE *-75 6 61 51 55 Unit * 〇RP (iV) wpCEUg / dried soil lkg) This paper is applicable to the standard (CNS) A4 specification (2) OX 297 mm) '38 39498 (Please read the notes on the back before filling this page)

438621 Printed by the Central Standards Bureau of the Ministry of Economy—Industrial and Consumer Cooperatives A7 B7 V. Description of the invention (39) Even in the case of the decomposition of tetra-aqueous ethylene, there is no residual dihydroethylene and it can be decomposed into ethylene and ethane. Table 4: Gas produced during the dehalogenation reaction of ethylene under anaerobic conditions (after 5 and 5 days of cultivation) H2 C〇2 CH4 Ethylene ethane unit ml / dry soil 1 kg / iffiol / dry soil 1 kg blank group 0 30 0 0 0 Experiment A -① 1270 1890 trace 172 146 Experiment B -① 770 1850 0 138 101 g _Example 3 In Example 3, Kashihara was considered to be a entanglement agent. Add tetrachloroethylene to the lake sediment (X) and wetland surface sediment (Y) in the contiguous industrial area, and adjust to the final concentration of 35ng tetrachloroethylene / 1kg dry mud. In a 25-liter cylindrical non-embroidery can (with a diameter of 330mniX and a height of 3? 0βηι), 15kg of contaminated bottom sediment were put into 4 series of experimental groups (control group and purification group in zone X, control group in zone Y And purification group). The conditions of each experimental group are as follows. In addition, for the purpose of preventing water evapotranspiration, water mixing, and heat preservation, each experimental container is covered with M. Spreading compost or rotten soil on the surface of the sediment is not necessary, so it will not be performed in this experiment. Set up the experimental sister in this 3 area outdoors, and then measure the pH at each time to saturate the gas (please read the precautions on the back before filling this page)

This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 39 39498 Λ7 438621 _ B7 V. Description of the invention (40) The oxidation-reduction potential of silver electric hibiscus and the elimination of four-gas ethylene are less volatile. During the experiment, the outdoor temperature range was 7-18T, and the moisture content of the sediment was about 41-50%. (Please read the precautions on the back before filling this page) (Experimental conditions) X zone control group: polluted bottom mud + 3000ml of pure water X zone purification group: polluted bottom mud + beer saccharified wine meal wastewater 3200ml + kanbara tincture 500g + mixed Lime Fertilizer B (main ingredients limestone and Wo Zhimin) 500g + sewage sludge compost 500s + humus soil 250g Y zone control group: polluted bottom mud + pure water 3300mi Y plaque purification group: polluted bottom mud + beer saccharified wine meal wastewater 3500 * 1 + 500 g of Liaoyuan iron + mixed lime-lime fertilizer B (main ingredients limestone and Wo Zhimin) 500 g + sewage sludge compost 500 g + rotten leaf soil 2 5 0 g Among them, the main component of beer puppet vineyard wastewater is Liaoyuan sugar 96〇〇w / l, acetic acid 180ng / l, lactic acid 3100ag / l, suspended matter 8100mg / l, BOD (Biochemical Oxygen Demand) 12700Bg / 1, and total organic carbon concentration 5100 a ε / 1 〇 Employees ’consumption The results of the changes in the concentration of tetrachloroethylene printed by the cooperative are shown in Table 5. The pH and oxidation potential of the hall and the oxidized silver electrode are both pH 4.6 ~ 5.3 in the X-zone control group and the Y-zone control group. PH7 ~ 7.4, 0RP- 400 ~-570bV, it can be known that the four gas ethylene in the X-zone purification group and the Y-zone purification group can be effectively decomposed by the purification method of the present invention. This paper size is applicable to the Chinese National Standard (CMS) A4 (210X297 mm) 40 3949 8 Printed by the Sub-consumer Cooperative of the Intermediate Standards Bureau of the Ministry of Iodine 39498 4 3 862 1 at ______B7 V. Description of the invention < «) 5 Changes in the concentration of four gas ethylene in table bottom mud (Unit: mg / dried sludge 1kg) Day 0: Day 19, Day 28, Day 40, Day 57 X Plaque Control Group 33 30 28 29 30 5 {plaque purification group 28 9.3 5.9 2.7 1.8 Y plaque control group 35 28 30 27 29 Y zone purification group 31 16 10.6 6. 1 3.3 In the present invention, the chemical reaction combined with the biological anaerobic reaction can quickly and easily purify soil water and sewer water Pollutants contaminated by halogenated organic compounds. At the same time, the method of the present invention does not dissolve halogenated compounds in the pollutants during purification. For example, in the case of contaminated soil, as long as the conserved water retention of the contaminated soil is maintained, K plus K purification can be performed without causing the contamination of the tritiated compound to penetrate deeper into the ground than the contaminated site. Halogenated organic compounds are converted into chlorine-free organic compounds such as ethylene or ethane, and no harmful intermediate products remain in the reaction, so no problem of harmful intermediate products occurs. Example 4: Buried raw mash or raw mash was used as the kangen agent in Example 4. In the four-smooth ethylene soil purification experiment of Example 4, the stilbene-forming microorganism bases shown in Table 6 were used. At the same time, the tension scale shown in Example 4 applies the Chinese National Standard (CNS) A4 specification (2 丨 OX297 mm) 41 (Please read the precautions on the back before filling this page)

4386 2 1 ;; 5. Description of the invention (42) The potential of the lutetium is measured by using a platinum electrode as a metal electrode and a saturated silver chloride electrode as a comparison electrode. Table 6 Addition amount of methanogenic microorganism culture medium Tap water 880ml Inorganic rhenium solution 1 5 Obi 1/1 Inorganic rhenium solution 2 50m 1/1 Inorganic rhenium solution 10b 1/1 Vitamin solution 1 Oi 1/1 NaHC〇3 5. 0g / 1 Yeast Extract 1.0g / 1 Polyprotein 2 2.0g / 1 Glucose 2.5g / 1 Sodium gallate 2. 5g / 1 Formazan 50a 1/1 1 Cysteine gallate 0. lg / 1 R a 2 S * 9 Η 2 0 0. Lg / 1 pH 6.9 ~ 7.2 2 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Purification Experiment A Factory Contaminated soil with tetrachloroethylene (contamination concentration is 1kg dry soil, 25ig > in the soil. In the experiment, 30g of contaminated soil was used in a 125nl sample bottle, and the paper size is applicable to China Standard (CNS) A4 specification (210X297 mm) 42 394 98 438621 Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Λ7 B7 V. Description of the invention (43) The conditions shown in MM will generate methane microbial culture medium, reduce tritium or produce After mixing the compost and sewage sludge, Determining the decomposition of tetrachloroethylene. The amount of compost in the soil, raw crumbs, and sewage sludge compost is 5% by weight. Raw crumbs are sieved and classified. The diameter of 500wmM is pig iron scrap A, 5 0 0 ~ 8 0 0 π is raw swarf chip B, and below 80 0 // m is pig iron chip C. At the same time, the sample is adjusted by K nitrogen to replace the gas phase part of the sample bottle. Water in the soil during soil purification The moisture content is 48.4 ~ 48.9%. The moisture content (%) here is the value obtained by (water weight / wet soil weight) X100. Experiment culture for 60 days. Then measure the pH in the soil and measure the saturated chlorine The redox potential of the silver halide pole, the small amount of tetrahydroethylene, and the amount of ethylene, ethane, S gas, carbon dioxide, and methane produced in the gas phase. The first-class burying of the original powder was sold by Wako Pure Chemical Co., Ltd. Window inspection conditions ① 30g of contaminated soil (control group, comparative example) ② 30g of contaminated soil + 9.0ml of methane production medium + 1.5s of reduction + + 1.5 of sewage sludge pile g ③ 30g of contaminated soil + 9.0b1 of methane production medium + pig iron scrap A 1.5g + sewage sludge 1.5g of fertilizer ④ 30g of contaminated soil + 9.0bi1 of methane production medium + raw crumbs B 1.5s + sewage sludge compost 1.5g ⑤ 30g of contaminated soil + 9.0ml of methane production medium + raw waste C 1.5g + sewage sludge compost 1.5g_ This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X2W male) " 43 39498 (Jing first read the precautions on the back before filling out this page) Λ7 B7 43 86 2 1 V. Description of Invention (44) Implementation The test results of Example 4 are shown in Tables 7 and 8. (Please read the precautions on the back before filling this page.) Table 7 shows the concentration of tetraamethylene in the soil when purifying with pig iron scraps. Table 8 shows the aerial photo generated when the tetrachloroethylene in the soil was purified with pig iron scraps and the like. Table 7 Purification results of tetrahydroethylene in soil by raw dander (after 60 days of culture) PCE in soil (g / dry soil 1kg) pH ORP (mV) ①Contaminated soil (controlling sister) 23 6.63 307 ②Return to suspect + Compost 0 7. 58 -537 ③ Raw sickle A + compost 0 7.27 -375 ④ Raw suspect B + compost 16 7.25 -229 ⑤ Raw i 骟 C + compost 20 7. 27 -225 Staff Consumer Cooperative of Central Standards Bureau, Ministry of Economic Affairs The paper size for printing is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 44 3 94 98 4 3 B 6 2 1 A7 B7 V. Description of the invention Us) Production amount of gas during purification (after 60 days of culture) Ethylene and ethane conversion rate of PCE (⑹ Η2 (nl / kg- ±) CH4 {l / kg- ±) c〇2 (ml / kg-i) ① Contaminated soil (control group) 0 0 0 trace ②Returned iron + compost 79 3.4 trace 190 ③Pig iron scrap A + compost 73 2.3 〇243 ④Raw raw scrap B + compost 25 1.6 〇366 ⑤Raw scrap C + compost 7.6 1.8 〇414 Meanwhile, "tetrahydroethylene (PCE), pH, ORP in the soil" shown in Table 7 is the value after 60 days of culture. "Ethylene and ethane conversion rate of tetrachloroethylene (PCE)" shown in Table 8 is the ratio of tetrachloroethylene to ethylene and ethane within 60 days of culture. "H2, CH4, and Co2j represent the amount of pith produced per kg of dry soil in each period. Using the EBARA group and the pig iron chip A group, tetrachloroethylene in the soil can be purified to an undetectable level. At the same time, it can be seen that the use of raw discrimination chips is the same as that of Sugawara. Tetrahydroethylene can be dechlorinated and converted into ethylene and ethane. Especially when using raw cuttings A, that is, raw crumbs with small particle sizes, Tetrachloroethylene can be extremely effective in deaeration. When the slag is used to purify contaminated soil in the soil, the soil can be maintained at a neutral pH of 7.2 ~ 7.3 and the oxidation of the saturated atmosphere of silver is extremely difficult. Paper size selection Chinese National Standard (CNS) A4 specification (210X297 male f) 4 5 3 9 498 — — — — — — 01 —. 4 (Please read the notes on the back before filling this page) ^ 38621 Economy Printed by the Ministry of Standards and Labor ’s Consumer Cooperatives Ί 7 B7 V. Description of the invention (46) "Original environment" with original potential of -225 ~ 375nV. Therefore, compare the soil purification method using Liaoyuan iron and the soil using pig iron scraps In the purification method, the soil environment of the two is almost the same. The addition of ②③④ and ⑤ sister to the methane-generating extracting biological medium both generate carbon dioxide in the gas phase part of the kneading bottle, so there should be extractive growth. In other words, pig iron 1 is a substance that is not harmful to the growth of soil microorganisms. Pipe oil 俐 利 5 First prepare the same tetra-ethylene ethylene-contaminated soil as in SIS Example 4 or add another contaminated soil sample with different content of tetrachloroethylene. In this way, you can get 1 kg of dry soil and four gases in the soil. Ethylene contained 50 mg of contaminated soil, 75 mg of contaminated soil, and 140 mg of contaminated soil. Purification tests were performed on each contaminated soil. The experiment was the same as in Example 4, with a capacity of 125 m 1 Take 30 g of contaminated soil in a sample bottle scale, and then mix with 9.0 ml of the medium for methane generation in Table 6, 1.5 g of pig iron scrap A with a particle size of 500 wai or less, and 1.5 g of sewage sludge compost to measure the decomposition of tetrachloroethylene. The gas phase part of the sample bottle was replaced by nitrogen when the sample was prepared. The experiment was performed at room temperature and the pH in the soil was measured after 63 days. The oxidation potential of the saturated silver chloride electrode and the tetrachloroethylene were measured. Reduction Production of ethylene and ethane in Μ and gas phase. Actual test conditions ① Contaminated soil (5 S tetramethylene / kg dry refining soil) 30g (control group) ② Contaminated soil (50ag tetrahydroethylene / kg dry) Soil) 30S + methane generation (please read the notes on the back before filling this page) This paper size applies to Chinese National Standard (CNS) A4 (2 丨 0X297 mm) 46 3 9 4 9 8 Employees of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperative 4 3 8 6 2 1 A7 B7 V. Description of the invention (47) Use 9.0ml of culture medium + 1.5g of raw soup shield A + 1.5s of sewage sludge compost ③ Contaminated soil (75ng tetrachloroethylene / kg dry soil ) 30g (control group) ④ Contaminated soil (75iag four atmosphere ethylene / ks dry-refined soil) 30s + methane generation medium 9.0m 丨 + raw interception MA 1.5g + sewage sludge compost 1.5g ⑤ contaminated soil (140 ng Four atmosphere ethylene / kg dry soil 干燥) 30g (control group) ⑥ Contaminated soil (140ms four gas ethylene / kg dry soil 炼) 30g + medium for methane generation 9.0 »1+ raw crumb A 1.5g + sewage sludge compost The test results of 1.5 g of Example 5 are shown in Table 9. From this table, it can be known that the soil containing 1kg of dry gas soil containing 1kg of dry gas contains 50bS, 75ns, and 140ns of high-concentration contaminated soil. It can be degassed with raw grains A and particle sizes of 500ϋΐ® or less. Ethane, showing the effectiveness of this soil purification method. In this soil purification experiment, the decomposition products of tetrachloroethylene were only produced in the gas phase and in the soil with the withdrawal of three gas ethylene and cis-DCE, and it was almost impossible to obtain chlorinated ethylene. In addition, pig iron scrap A is used to purify the soil contaminated with high concentration of tetrachloroethylene. The soil can be stably maintained at a neutral pH of 7.2 ~ 7.3, and the osmium oxide potential of the saturated gasified silver electrode is -350 ~. 3 80 i »V, The Original Environment. The "tetraamethylene, pH, 0RP in the soil" shown in Table 9 is the value after 63 days of culture. The "Ethylene, ethane conversion rate of tetrachloroethylene" shown in Table 9 is the ratio of tetrachloroethylene to ethylene and ethane after 63 days of culture. (Please read the precautions on the back before filling out this page) This paper size is applicable to Chinese National Standard (CNS) A4 (2! 0 X 297 mm) 3 9 49 8印 ι 印 $; 4386 2 1 at B7 V. Inventive reading (Aunt) Table 9 Purification results of suspected high-temperate four-atmosphere ethylene-contaminated soil (after 63 days of culture > PCE in soil (ag-PCE / kg- Conversion rate of ethylene and ethane in dry soil 1 PCE (%) pH 0RP (mV) ①Contaminated soil (control group) 45 0 6.71 360 ②Green cuttings A + compost 4.0 65 7.28 -380 ③Contaminated soil (control group) 73 0 6.75 345 ④Pig iron filings A + compost 19 58 7.19 -375 ⑤Contaminated soil (control group) 139 0 6.86 336 ⑤Pig iron filings A + compost 78 28 7.31 -347 (Read the precautions on the back before filling this page) This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210 × 297 publicly available) 39498 43 86 2 1 at Β7 V. Description of the invention (49) It can be seen from the present invention that metal powders that are suspected of being powders or unbelievable powders are used in the present invention. It can be used for chlorinated organic compounds in a wide range of low to high concentrations of pollution. Achieve a high purification rate of substances. That is, the use of raw materials such as raw crumbs can be low-cost, safe and simple to process and purify pollutants contaminated by chlorinated compounds, and can effectively use industrial waste. Combined with a low-solubility soil improver, it is possible to prevent dissolved organic compounds from dissolving in the contaminated soil. At the same time, while maintaining the water retention capacity of the contaminated soil, purification can be achieved and the pollution of organic chlorine compounds that have been generated underground can be maintained. It will not penetrate deeper from the contaminated location to a deeper depth. Emu Oil? Li Fi Example 6 corresponds to the second aspect of the present invention. Practical Example 6 shows that even without adding anaerobic microorganisms from the former In the case of nutrition sources, halogenated organic compounds can also be decomposed by M. The appropriate principles for the use of tetrafluoride are: (1) metallic iron (comparative example), (2) manganese, (3) aluminum-silicon alloy, and (4) sodium hypophosphite. The standard electrode potentials of each reducing agent are pleased to be in Table 10. Table 10 The quasi-electron potentials of the suitable agents (please read the precautions on the back before filling out this page).檷 Quasi-electrode potential UV) (1) Jinguo-440 (2) Manganese-1180 (3) Aluminum-silicon alloy-1600 (4) Sodium hypophosphite-499 This paper is applicable to China National Standards (CNS) Α4 Specifications (2 丨 0 × 297 mm) 49 3 9 4 9 8 Λ7 4 3 86 2 1 __B7 V. Description of the invention (50) Will (1) gold drive 20g, (2) manganese 10g, ( 3) Aluminum-silicon alloy 1 and (Please read the precautions on the back before filling this page) (4) Add 20g of sodium hypophosphite to 6500g (water content of 60%) containing tetragas ethylene 1 5 0 »g / kg loamy soil, maintained at 200, and the subsequent state was measured. (2) and (3) The osmium oxide oxidation potential decreased to -500jiV or less within 1 hour, and it was maintained at -500bVM for the next 10 days. After 10 days, tetrachloroethylene can be completely dehalogenated to ethylene and ethane. (4) The oxidation potential decreased to -450mVM within 1 hour, and then held at -450n \ iM for 10 days. Four atmosphere ethylene was completely dehalogenated to ethylene and ethane after 10 days. In contrast, it took 5 days for the lutetium oxide potential of (1) to decrease to _400bV, and it remained at -400bV for the next 5 days. After 10 days, only 20% of tetrachloroethylene was dehalogenated to ethylene and ethane. Fen Fu Li 7 Comparison (1) The group containing only rhenium agent and no rhenium carbon source, and (2) the group containing the diagen agent and organic carbon source, where calcium-silicon alloy is used as the diagen agent (Pseudoelectrode potential-1900mV), organic tritium source uses sodium tritate. Printed in (1) and (2) of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. Add 100g of calcium-silicon alloy to 65kg (55% moisture content) of clay soil with 200 m g / k g of trichloroethylene. In (2), add 70g of sodium acetate and other nutrition sources for 7s. Each group was maintained at a temperature of 2 and the subsequent state was measured. Both (1) and (2) decrease the oxidative peptogen potential to below 1 hour. (1) The redox potential was maintained at _500bVM for 10 days. After that, it gradually changed to an oxidized state. Between 40 days, the oxidation suitable potential was on the paper. The Chinese standard (CNS) A4 specification (210X 297) (Mm) 50 39498 43862 t A7 ______ 5. Description of the invention (Si) rose to OmV. Eighty percent of trichloroethylene is ethylene and ethane, and the remaining 20% is left in soil. In contrast, (2) maintain the osmium oxide potential within 40 days. At -500nVM, 99% of the three atmosphere ethylene can be ethylene and ethane. The kanji agent of the present invention is not easy to cover a stable oxide film on the surface, and is not easy to dissolve in water, so it is easy to contact with pollutants and improve decomposition speed. In addition, when B dyes are bottom-permeable materials such as clay soil or agglomerated silty soil, dehalogenation can also be carried out by adding a carbon source as the growth-removing substrate. (Please read the notes on the back before filling out this page) Printed and used by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (1) Gold powder (control group), (2) Sodium hypophosphite powder Ή or (3) 撺 Birch An aqueous solution of titanium acid is a kangen agent. The actual m condition is converted to dry soil with 120k g / kg of soil containing tetrachloroethylene. At the initial stage, the oxidation potential is + 350mV and the soil volume is 100b3. The results of the rounds (2), (3) reduced the entanglement potential to -450 nVK within 1 hour, and within 5 hours, the inner male maintained at -450b VM. Tetrachloroethylene is completely dehalogenated to ethylene and ethane after 5 days. In contrast, the 1 (1) group used a single knotting machine to mix the soil and metal completely within 10 days. After that, it would take 5 E 丨 to reduce the oxidative kangen potential to-400 m V. The next 5 days remained below -400 bV. Twenty percent of tetrachloroethylene is dehalogenated to ethylene and ethane after the 20th. Example 9 The ascorbic acid was used as the transport agent in each group. (1) Organic is not added to the group. The paper size is in accordance with Chinese National Standard (CNS) A4 (210X297 cm) 5 1 3949 8 A7 438621 B7 V. Description of the invention (52) Carbon source. In contrast, in the group (2), sodium gallate was used as the organic carbon source. (Please read the precautions on the back before filling out this page.) Use the converted dry soil as a clay containing tetrahydroethylene lOOng / ks. The initial oxidation potential is + 32〇1 ^. 11 is 6.5. Results of the W-channel (1) and (2) groups were all reduced to +130 mVM within 1 hour after the entanglement agent was injected. (1) During the 10th day, the oxidative potential was maintained at + 130bVM, after which the photoperiod changed to an oxidized state. After 40 days, the oxidative potential was gradually increased to +3 00 »^.卩 11 gradually decreased from 6.3 on the 0th to 5.5 on the 40th. Siqi ethylene was 50% converted into ethylene and ethane, and the remaining 50% was left in the soil. In contrast, (2) the oxidative tunogen potential gradually decreased after that, to -150mVM after 20 days, and to -150nVM after 40 days. The pH gradually decreased from 7.5 on day 0 to 6.8 after 40 days. 99.9% of tetrachloroethylene is ethylene and ethane. The raw cocoon used in this actual pickled state is water-soluble, so pollutants contaminated with organic compounds can be contacted with kanogen agents to promote kangaric de-salinization reactions. Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Commerce " The original agent used in this experimental state has a potential of approximately equal to or below the potential of the quasi-electrode potential. Therefore, it has a large potential difference from the halogenated organic compound. , Which can accelerate the advantages of dehalogenation. In addition, when the pollutants are low-permeability materials such as clay soil and agglomerated silty soil, they can also be dehalogenated in conjunction with the organic carbon source of microbial growth substrate. At the same time, these rhenium agents do not appear to be passivated. Window example 1 〇 This paper size applies Chinese national standard (〇 «) / \ 4 specifications (210: > < 297 public 1) 52 39 498 43 86 2 1 A7 __B7 V. Description of the invention (5 3) The invention It has been shown that halogenated aromatic compounds can be decomposed. 20g of gold-layer iron was added to 6s loam soil with a concentration of 110g / ks of PCP. In the group 10-1, another 1 liter of the nitric acid-cancerous culture medium shown in Table 11 was added. In contrast, the 10-2 group is the control group, and only 1 liter of water is added. Table 11 Addition amount of nitric acid-producing olive organism medium potassium 4.5g / 1 potassium 8.5g / 1 sodium bicarbonate 5.0g / 1 hexahydrate and atmospheric magnesium 0.2g / 1 yeast extract 0.1 g / 1 Dilution water tap water pH 6.9 ~ 7.4 (please read the precautions on the back before filling this page). Ding-5 The Bank of China's Ministry of Finance will print $ in the negative quasi-government consumer cooperative, and then, after mixing Maintained at 281C, and then measured the changes in PCP concentration and product concentration. The results are shown in Tables 12 and 13. This paper size applies Chinese storehouse standard ([-! ^) 8 4 specifications (210 乂 297 mm) 3 9 4 9 8 43 86 2 1 at B7 V. Description of invention (54) Table 12: 10-1 Result Compound name: after 20 days and 40 days? C? (Mg / kg) 10.1 0.58 0. 0 1 ^ TeCPiffig / kg) 0.00 2. 0 0.00 CP (η g / kg) 0.00 2.3 0.02 Phenol 0.00 1.2 3.1 Eh ( aV) + 312 -380 -423 Table 13: Results of the 10-2 group Compound name PCP (丨 g / kg) after 20 days and 40 days after 10.2 2.4 0.9. TeCPfmg / kg) 0.00 1.0 0.00 CP (ig / kg) 0.00 2.1 2.8 Phenol 0.00 0.8 1.0 Eh (aV) + 308 -1 70 + 118 Printed by the Women's Workers Consumer Cooperatives of the Ministry of Economic Affairs, Zhongrui Standard Bureau ^ (Please read the precautions on the back before filling this page) -〇, Table 12 and In Table 13, TeCP and CP each represent 2,3, 5,6-tetraphenol and 3-phenol. At the same time, Eh is a value converted to a standard electric hibiscus potential for a standard hydrogen electric hibiscus. 0 Comparative Example 10-1 and Group 10-2 show that pentaphenol can be rapidly decomposed. This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) 54 3 9498 438621 B7 Employees of the Intermediate Standards Bureau of the Ministry of Economic Affairs, China Consumers' Union, Yinfan 5. Inventive Notes (55) 1 1 10 -1 Pentachlorophenol in the group should be decomposed into tritium through 2,3,5,6-tetrachlorophenol and / or 3-chlorophenol ί 1 I simultaneously 2, 3, 5, 6-tetrachlorophenol and 3-chlorophenol m This can be further divided into 1! I is decomposed into other compounds 0 1 | Please II directly JL1 read 1 I read 1 | Real W Example 1 1 mainly corresponds to the third aspect of the present invention. The back of 1 I Example 1 1 uses the oxidation state nitrogen of Table 1 4 in the original state of the use of biological culture medium and Table 15 for the formation of microorganisms for the formation of formazan microorganisms (control group) to purify the four atmosphere of the second hospital item 1 fill Λ contaminated soil 〇 Table 14 The content of the oxidized nitrogen in the medium composition of Table 4 corresponds to 23% by weight of the organic carbon page W 1 〇 Purification experiments are performed at room temperature (12 ~ 23C > 30 days 1 test 1 i 1 determine the properties of the soil The changes are recorded in Table 16. The measurement of pH 01 is adjusted to soil pure water = 1: 1 (wt), and then measured by Toya Denki 1-wave industrial pH meter HH-5 B type. For saturated silver chloride electrode Measurement of oxidative suitability iT I in situ (0RP) to prepare the soil: anaerobic water = = 1 1 (wt), 1 I Immerse the electrode of UK-2020, a central scientifically manufactured meter, UK-20 3 0, and leave it for 30 minutes Measurement 1 I 〇 Further, the pair of saturated gasified silver electrodes shown in this example Oxidation of the original source r1) Potential »Metal electric hibiscus for platinum electrode 9 Use saturated silver chloride as the ratio [yJ I The position shown on the pole is determined. The analysis of soil atmospheric vinyl is based on 1 1 Method developed by Yokohama National University (Miyamoto Ken--etc., "A method for determining the content of halogenated organic compounds in the soil with low boiling point 1 1 point J Journal of the Water Environment Society» 1 1 1995 Vol. 8 * No. 6 9 477 ~ 488 Page), after extraction with acetic acid, 1 I was converted to Guiyuan and M Yue Li gas chromatography G-5000. F ID detector, 1 | 20% TCP ch Γ 0 IQ 0 SO rb WAV DHCS 60 -80 aesh column analysis 0% hydrogen produced in gas I 1 i phase carbon dioxide > methane nitrogen gas determination 1 then 1 1 GL scientific gas phase analyzer GC-3 20 TCD detector, A ctive 1 1 Paper size applies Chinese National Standard (rNS) A4 specification (210X297 mm) 55 3 9 498 4 3 8 6 2 1 Λ7 Β7 V. Description of invention (56) carbon 30/60 or Mol ecular sieve 13X. The acidic nitrogen and nitrite nitrogen ions in the soil were measured by Hitachi Anion Chromatograph 2010i. Soil: pure water = 1: l (wt) adjusted extraction water. Table 14 Bioreduction medium for oxidation reduction of nitrogen (please read the precautions on the back before filling in this page) Ingredients potassium nitrate 4.5 g / 1 potassium acetate 8. 5 g / 1 sodium bicarbonate 5.0 g / 1 Water and magnesium chloride 0.2g / 1 Yeast extract 0.1 g / 1 Diluted water tap water pH 6, 9 ~ 7.4 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Table 15 Addition amount of methanogenic microorganism culture medium L-cysteine Amino acid 塩 塩 塩 0. 1 g / 1 Polyprotein Chen 2 · 0 g / 1 Glucose 2 * 5 g / 1 Sodium acid 2.5 g / 1 Methanol 5. 0 m 1/1 Sodium bicarbonate 5.0 g / 1 Nine water and Sodium sulfide 0.1 g / 1 Yeast extract 1.0 g / 1 Diluted water tap water pH 6. 9 ~ 7. 2 This paper size applies Chinese National Standard (CNS) A4 specification (2 丨 0X2? 7 mm) 56 3949 8 43 86 2 1 Member of the Bureau of Standards of the Ministry of Economic Affairs of the People's Republic of China, J-F, Cooperative Association, A7, B7 V. Description of the invention (57) 1 1 Purification η Four gas and η contaminated soil (Dye! | Concentration about 2 5 ntkg dry Suspected soil) η Tuobao test to search Sample of Guang M I 1 I bottle weigher takes 30g of contaminated upper soil and then lowers the mixture of cattle under VX to train 1 1 | Basic > Determination of white tetrachloroethylene decomposed soil after 30 days Property A. Read 1 1! Change status, etc. (Table. 16). Gold powder is reduced to m powder using Wako Pure M grade 1 back 1¾ of Γ. At the same time, when steel samples are used, M helium replaces the sample bottle. The gas department 5. Italian food 〇 Ύ item and then 1 4 S. 旃 conditions this page 1 ① contaminated soil 30 ε _ < · 1 I ② contaminated soil 30 Ε + water S .0〇] + m 07 g 1 1 ③ 30 g of contaminated soil + 90ml of biological removal medium for oxidized nitrogen through the original-! 1 1 Order 0. 07 S 1 ④ 30 δ of contaminated soil ♦ Medium for methanogenic microorganisms 9. 0 B1 1 +原 锇 i 1 0. 07 g The experimental results of II are shown in Table 16. It can be determined that t can be used in the oxidation state nitrogen m original r \ culture medium 9 not only tetragas ethylene can be dechlorinated to form ethylene and ethylene 1 and j can inhibit the blackening of methane and methane production> The occurrence of sulfur odor and odor can be found at the same time III. The nitrogen produced can be diluted by the hydrogen produced. In addition, no residual oxidized nitrogen and sub-oxidized nitrogen in the soil 1 i have been found. 0 1 1 In the group of adding metal and water, ρ Η is greatly reduced, and the oxidative passivated potential of saturated I 1 and oxidized silver electrodes also rises to + 2 mV after 30 days.> Because 1 1 cannot fully degassing Kanbara Decomposition 0 so the results are-part of tetrachloroethylene 1 1 ene is still left in the soil. The conversion of ethylene is only 26% 〇 This shows »1 1 | The group with only metal powder is difficult to maintain in the long term Current state of restoration * Only 1 1 paper size applies to China Standard home U, NS) Λ4 current cell (210X2W mm) 57 3 9 4 9 8 f 438621 A7 B7 V. invention is described in (58)

Ding'an Ding'an Jl · 11 Beck 10 is only near the beginning, born at the time of the production meeting, the same anti-powder material is gold, so that the additives are nourished. In addition to this, there is a percentage of C gas hydrogen Kansas nitrogen withdraws into biochemical oxane plus formazan added as an additional factor », the interphase of gas-ground nitrogen pairs ο 0 The base of the middle-risk group of the risk of frying and cultivating something that wants to be promoted to promote this use is because the original odor is high It has been shown that hydrogen-based release nutrients from the gas group can be grown, and the addition of microcarbons to the oxygenated oxane dimethyl oxine can produce soil-based nutrients in the soil. Biochemical products full gas —— —— —— ο— — > — (Please read the precautions on the back before filling out this page) Ding'-b Jing 1¾—Ministry of China Final Vehicle Bureau MJ-Consumer Cooperative The size of the printed paper is in accordance with the Chinese National Standard (CMS) M specification (210X 297 mm) 58 3 9 498 438621 Λ7 B7 Printed by the Consumers 'Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs of the People's Republic of China to print the 5' invention description (5 $ Table 16 Four atmospheres in the soil Purification results of ethylene (PCE) (after 30 days of cultivation) ① Polluted soil ② Polluted soil ③ Polluted soil Φ Polluted soil + Water + Oxidation state + Methanogenesis (control group) + Gold sulphur nitrogen reduced to cultivate base + metal + PCE 22.5 8.6 0.0 'J 0.0 (ag-PCE / kg) pH 6.82 5.37 7.48 7.52 ORP (mV) +289 * 2 -376 -542 PCE ethylene ethane 0 26 81 84 Conversion rate (% ) H2 (inl / kg_ soil) 0.00 1.3 2.8 3.5 CH4 (seed 1 / kg soil) 0.00 0.07 0.00 0.52 C〇2 (al / kg soil) 0.00 0.15 0.10 182 N2 (Bl!; / Lcg) 0.05 0.04 110 0.10 No.3-HUl / kg ±) 0.5 0.3 0.0 0.0 No.2-N (Bl / kE: ±) 0.0 0.0 0.0 0.0 Odor No No No Discoloration No part of discoloration Discoloration becomes discoloration into light blue light blue black black This paper ruler is thin 59 39498 I——ί—ίο—— ♦-(Please (Please read the notes on the back before filling in this page) T *-" 438621 A7 Printed by the Consumer Consumption Cooperative of the Bureau of Standards of the Ministry of M__B7 V. Description of the invention (60) In the third aspect of the present invention, The nutrient source used contains 20 to 50% by weight of oxidized nitrogen in organic carbon. Therefore, when the halogenated organic compounds are decomposed, the blackening of soil can be suppressed, and malodorous gases such as methane gas and alcohol can be generated. Tube Example 1 2 In Example 12, organic carbon was supplied from a water-soluble organic carbon source. For 5kg of 10bs of organic gas compounds per kg of soil (60% moisture), add 6g each of (1) grape mash, (2) molasses waste liquid, (3 > heap 脃 as an organic carbon source, and then add 20〇ag The once-raised tadpoles were maintained at 28X: temperature. The subsequent state was measured. In (1) and (2), the number of anaerobic bacteria proliferated to 107 bacterial / g soil in a few days, and saturated atmosphere The oxidation potential (0RP) of the silver electrode was maintained below -600bV for 30 days, so tetrachloroethylene could be dehalogenated to Ethylbenzene and Ethylpyrene. In contrast, the microorganisms in (3) multiplied to 107 bacteria / It takes 20 days for g soil, 0 RP starts to rise after 13 days, and after 30 days it is -2 3 m V. Tetrachloroethylene has 50% KCDCE (fluorene-dihydroethylene) remaining, Therefore, it cannot be fully dehalogenated. Fenfu Example 13 Adds 240g of glucose as an organic carbon source to 200kg of 30mg_ of organic compounds per kg of soil (65% moisture), and then adds 8g of other previously cultivated pupae for purification in winter. Each operation is covered with a polyethylene blanket greenhouse, and heated with warm water (average temperature 2 2 1C), and (2) treated under good conditions. (Please read the precautions on the back before filling in this page) The paper size is applicable to Chinese national standard 4M CNS) Λ4 specification (2ΙΟχ 297mm) 60 39498 43 86 2 1 Αν B7 V. Description of the invention () In (1) The number of anaerobic bacteria proliferated to 107 bacterial / g soil within a few days, and ORP was maintained at -600 nVM for 30 days, so tetrachloroethylene alkane and 0 ethanoate were left late for phase ε. In the presence of ethylenic bacteria, the soil should be slightly opened after the ascension, and then generate chlorine 7} ο 4 1 to VO ra colony 2 f 5 increase + can be 0 Can not be% without M% is / after the day E (like the ethylenic chloride B substance olefin dyeing ethyl pollution chlorine four dyeing. B internal sample pit state sludge 4 0 water first to put the bright halogen storage storage Due to the cost, the construction site should be chemically processed. The plant owner ’s purification plant has 14 soil cleanliness, soil engineering, evolution, actual pollution, and the original degree of m. Method 3 of the operation method is described below. Please fill in this page again) ο. Member of Zhongrong Standards Bureau, Ministry of Economic Affairs_τ Consumer Cooperative Co., Ltd. 2 The table and the supplementary supplements are cultivated in the culture, and the products are inferior. The internal proton can accommodate nitrogen behavior 5η Hydration will leak Oxygen's No. 14 shovel bucket table will be used to make the plate. Make the steel 3B, 10 small accumulations into the soil and dye 0 in the pit mud, 3 of the 5 water in the machine to dissolve the spatula and use it to raise the water. The agent for raising internal camps is the steel plate under the plate / IV base plus-supplementation} cultivation% using 01 things 4 micro soil to form soil 3 3 2 2 A 0.4 soil / / \ 3 m% Yingyu loam soil mixer shoveled down Μ-ΓΤ ο so that it will be mixed again, and then inside 0 barrels to mix the mixed plate A net agent to raise and add camp and A loam agent soil to raise the camp to the middle of the barrel board _____ A articles Add the agent into the soil and mix the second soil camp with the loam again. 0 A 4 Agent 1. Nourish and add A 0. The nutrition has been used with the loam soil to apply the Chinese paper standard (&post; 4 specifications (210: 〇97mm} 11 6 3 9 498 4386 2 1 B7 Μ Tellurium " Standard Bureau Negative J Consumer Cooperative Co., Ltd. $ 1 5. Description of Invention (62) 1 | m A After thorough mixing > Dismantle the original soil in the m-plate bucket, and mix again with 1 I. Pour the mixed soil back into the cement pit. 0 1 1 I [ Method 2] 1 I read | Move the contaminated soil in the cement pit of 5 α 3 into the aforementioned steel plate. Read 1 I read 1 bucket. Secondly, 1.1 1D 3 (22 V 0 1% of soil). The back of the aforementioned nutrient A ('-1 I was added to the m-plate bucket, and then the soil and nutrient A were mixed with a backhoe. Note η | 1 1 Things 1 After thoroughly mixing the soil and nutrient A »Put the 遢 原 m 撖 in the contaminated soil of the steel plate bucket 1 and 9 again and mix again. 0 The mixed soil is poured back Cement pit book W Page 1 inside 0 1 | [Method 3] 1 1 1 Move the contaminated soil in the cement pit of 5 9 3 K backhoe to the above-mentioned stencil board 1 order 1 bucket 0 second> before adding 1 5 ~ 20 hours 9 The oxidized nitrogen-containing microbial culture medium in Table 14 and the microbial culture medium in Table 15 were used to generate microorganisms, and 1 1 Suspension solution of Sugawara (hereinafter referred to as nutrient B) 0.2n3 ( 1 i 4 V 0 196 of soil) was added to the m-plate bucket, and then the soil and nutrient B were mixed with a backhoe and then 0.2 m 3 (4 V of the soil 0 96) of nutrient B Added by Λ 1 1 m inside the slab »Use a backhoe to mix the soil and nutrient shaving B. Add 1! 0.7m 3 (14 V 0.01% of soil soil) of former nutrient B into the stencil drum, 1 1 Mix it thoroughly 0 Mix the soil soil and pour it back into the water puddle. 1 1 Method 1 ~ 3 mixed soil--Partially removed and sieved through a 10mm mesh screen 1 1 The mesh was sieved Κ Jushi determines the amount of soil mass in the soil after mixing, the results show II t Method 1 and Method 3 The amount of soil in the soil is 1 ~ 10% of the soil, phase 1 I is on the ground. Method 2 is 1 ~ 30% of the soil. »The degree of stick mixing will vary depending on the addition method and mixing method of the nutrient 1 1 1 0 1 1 This paper size applies Chinese National Standards (CNS) Λ4 specifications (210X29? Mm) 62 3 9 498 B7 V. Description of the invention (6 3) However, regardless of methods 1 ~ 3, in order to prevent outside oxygen from entering and mixing after mixing The surface of the soil in the cement pit is covered with PVC tape and the M iron plate is fixed. In addition, in addition to the method M covered with polyethylene gas blanket, the water can be covered with KM water to about 5 ~ 15cm on the surface of the soil, so as to soak the soil, and M can prevent the ingress of external oxygen and maintain sufficient water in the soil. At the same time, in methods 1 to 3, the soil is moved back to the cement pit, which is to prevent the outflow of ethylene and other gases. In practice, move the contaminated soil in the ground into a bucket, mix the contaminated soil and nutrient solution in the bucket, and then return the mixture to the pit that was originally removed from the contaminated soil. Or do not mix in the barrel, but in the field. The concentration of tetrachloroethylene in the soil was measured 2 months after the vinyl blanket was covered. This result is shown in Table 17. Table 17 Results of the purification project of soil with four atmospheres of ethylene pollution Method 1 Method 2 Method 3 PC E concentration at day 0 (mg / 1) 5 5 5 PCE concentration after 2 months Ug / 1) 0.01 0.55 1,9 Decomposition rate 99.8 89 62 Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Μ99.8% of the mixed soil is decomposed and 89% in the method 2 In Method 3, 62% were decomposed. Therefore, it can be known that when the nutrient is added and mixed in several times as in Method 1, the decomposition rate can be improved. In addition, it can also be seen that if Method 2 is used, the solution is mixed with the soil, and then the powdered entanglement agent is added to increase the decomposition rate. This paper size is applicable to China National Standard (CNS) A4 specification (210 × 297 mm) 63 3 9 49 8

Claims (1)

Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A84386 2 1-88 D8 VI. Application for Patent Scope 1. A method for purifying pollutants contaminated by halogenated organic compounds, the method has the standard electric potential of standard hydrogen electrodes added to 25¾ It is a step of 130biV ~ 2400bV reducing agent and nutrient source of auxotrophic anaerobic microorganisms, wherein the aforementioned primogenizing agent is suitable iron, pig iron, silicon-silicon alloy, titanium alloy, zinc alloy, manganese alloy, aluminum alloy At least one selected from the group of magnesium, magnesium alloy, calcium alloy, and water-soluble compounds. For example, the method of item 1 of the patent application, wherein the aforementioned protonator is a standard electrode potential of a pseudo-hydrogen electrode at 25 t. It is -400®V ~ -2400nV, and it is at least one selected from Riyuan grade, raw iron, iron-silicon alloy, titanium alloy, zinc alloy, manganese alloy, aluminum alloy, magnesium alloy, and calcium alloy. 3. The method of item 1 of Shen Lili Fanpu, in which the above 1 original agent is the one containing the suitable original. 4. The method according to item 1 of the scope of patent application, in which the aforementioned buried original pin is raw W. 5. For the method of applying for the No. 1 item in the Fanli Fanpu, in which the aforementioned rhenium agent is composed of iron-silicon alloy, titanium-silicon alloy, titanium-aluminum alloy, zinc-aluminum alloy, fierce-continuous alloy, Ming-Xin-consumption Alloy, Ming-tin alloy, Ming-silicon alloy, magnesium-manganese alloy, and calcium-silicon alloy. 6. The method according to item 1 of the scope of application, in which the aforementioned rhenium agent is a water-soluble compound. 7. If you apply for the method of item 6 of the Patent Fanyuan, the former 原 ® original agent is available (please read the precautions on the back before filling this page) This paper size applies the Chinese National Standard (CNS) A4 specification ( (210 X 297 mm) 64 3 9 49 8 ABCD 4386 21 6. Apply for a patent of dry organic acid or its derivative, hypophosphorous acid or its derivative, or a compound of halide. (Please read the precautions on the back before filling out this page) 8. If you apply for the method of No. 1 plaque, the aforementioned rhenium agent is a powder with a particle size of 500 # b or less. 9. The method according to Shen Lili Fan_ Item 1, wherein the water content of the aforementioned pollutants is at least 25% by weight. 10. For the method of Shenyang Patent Fanyuan Item 1, after the aforementioned adding step, there is another step of maintaining the aforementioned pollutants in the range of pH 4.5 to 9.0 to promote the dehalogenation of the aforementioned halogenated halogenated compounds. . 11. For the method of applying for the first item of the patent park, after the above-mentioned adding step, there is another step of maintaining the aforementioned pollutants at the range of pH 4.5 ~ 9.0 and the original environment. 12. For the method of applying for the first item of the Lili Garden, there is a step of adding various compost, composted organic matter, or organic matter-containing waste water and waste to the above-mentioned sewage beam, and then mixing them. 13. —A method for purifying pollutants contaminated by halogenated organic compounds, the method has a potential of 13C at 25C to a standard hydrogen electrode. ~~~~~~~~~~~~~~~~~~~~~~~~~ The step of adding 0 m V of the phytogenic agent to the aforementioned pollutants, wherein the aforementioned strontium is composed of "original iron, raw iron, silicon-silicon alloy, titanium alloy, zinc alloy, manganese alloy, aluminum alloy, magnesium alloy, Calcium alloy and water-soluble compounds are buried in 1 μM. 14. The method according to item 13 of the scope of patent application, wherein the potential of the aforementioned rhenium agent to the quasi-hydrogen quasi-electrode at 25t: -400bV ~ -2400HV, and the reason is based on the original iron, raw intercept, A silicon alloy and titanium alloy. The paper size is applicable to China National Standards (CNS) A4 (210 X 297 mm) 65 3 9 4 9 8 438621 Employees of the Central Standards Bureau of the Ministry of Economic Affairs have printed the D0 hole and applied for patents. 1 I Zinc alloy, manganese alloy, aluminum alloy, magnesium alloy% and at least one of m 1 1 1 selected in the aluminum alloy 1 1 1 1 5. For example, the method of the 13th item of the patent application Meiyuan 9 In which the original agent is described To include ^ ~, 1 I please 1 1 遒 原 铁 者 <? Read 1 I read 1 1 6. The method of applying for the scope of the patent item 13 »Where the aforementioned reducing agent is I with the back 1 | 0 Attention repetition I 1 7 · If you ask, please refer to Item 13 of the Patent Fan Garden Method 1 where the foregoing m original is due to the repetition of the peak c iron-silicon alloy> titanium-silicon alloy, titanium-aluminum alloy, zinc-aluminum alloy Maben k page 1, manganese-magnesium alloy> aluminum- Zinc—Calcium alloy—Aluminium alloy— 1 Silicon alloy—Magnesium—Manganese alloy, and Calcium—Silicon alloy. At least one of these is selected. 0 1 1 1 8. Method > Where the original m agent is water-soluble 1 soluble compound 〇1 I 1 9. The method of the patent application No. 18 »Where the original magenta agent is II organic acid or its derivative hypophosphorous acid Or its derivatives or vulcanized vulcanizates 0 «| 20. For example, method 1 of Patent Application No. 13 of the Patent Application 1, where the former 逑 m original agent is a powder containing 1 with a particle size of 50 0 um 〇 0 I 2 1 . — Quinine halogenated Purification method for pollutants contaminated by chemical compounds. The method 1 of this method has a standard electrode potential of 25 volts against quasi-hydrogen, 130® V 1 1-2 400bV, and a nutrient-type anaerobic property. Camp of Microorganisms 1 I Nutrient > Step i added to the aforementioned pollutant and its stated nutrient swim 1 I is organic carbon and an oxidation state 1 containing 25% by weight of the aforementioned organic carbon 1 ί I nitrogen 1 1 22. The method of item 21 of Shenyang Patent Fanpu 9 where the aforementioned nutrient source contains 1 1 This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) 66 39498 43 86 2 1 D8 Economy Printed by the Consumer Standards Cooperative of the Ministry of Standards of the People's Republic of China J. Application scope of patents 1 I Ί, ίι 月 [J Describing 2 to 30% by weight of nitrogen in the form of carbon in the form of oxidized nitrogen 〇1 I 2 3 Method of scope item 21 of which »J. states that the carbon is supplied from an aqueous organic carbon source 0 1 I Please 1 I 24 · If you ask for the method of the 21st paragraph of the patent fan garden 1 where the% of the original agent is read first 1 I read 1 25 The standard electrode potential for the standard argon electrode is -400aV back 1¾ I of; -2 400b V of gold tincture. Note I 25 · If method 1 of the scope of the patent is requested, the above 1% of the original agent is from item 再 and then 1 I fill in the original susceptible m, susceptible to a sand alloy titanium-alloy, zinc alloy Λ manganese writing book 1 Alloys, aluminum alloys, magnesium alloys, and calcium alloys in the group of m at least 1 selected 0 1 1 26. For example, please refer to the method of item 21 of the Li Fanyuan, where the m agent is water [1 soluble compound 0 for 1 27 • Method of applying for patent _ item 21 method * where X f. · Month "J s m original agent is powder containing 1 I particle size 500 m a K 0 1 I 2 8 · — cause Purification of halogen-containing organic compounds and solid-contaminated pollutants Method 9 This method has a standard for hydrating anaerobic microorganisms and water in nutrient solutions * and a standard of quasi-hydrogen at 25 ° Pole 1 1 Mixture of a potential agent with a potential of 130®V- 2400nV and the aforementioned pollutants 1 1 Step 1 This (1) (1) (1) The mixing step is suspected and the pollutants have to be adjusted to pH 4. 5 1 1 9. 0 Fan Pu Steps; and the step of statically aerating the aforementioned mixture under low aeration conditions i 0 1 1 ϊ 29. For example, please refer to the method 1 of the patent range 28, where Λ ft states that the original cocoon is powder 1 1 and the final form * will be After the narrative solution is added to the narrative pollutants, 1 1 is added to the narrative stick compound t, and then mixed 1 1 This paper size applies the Chinese National Standard (CNS) A4 Specifications (210X297 mm) 67 3 9 4 9 8 Cd D06. The scope of patent application is in line. 30. The method according to item 28 of the patent application plaque, wherein the aforementioned protogen is a powder having a particle size of 500 W b M. 31. The method according to item 28 of the patent application, wherein the aforementioned rhenium agent is a group consisting of reduced iron, pig iron, iron-silicon alloy, titanium alloy, zinc alloy, manganese alloy, aluminum alloy, magnesium alloy, and calcium alloy. At least one of the _ selected. 32. For the method of claim 28 in the patent application, the first step of the method is to add and mix the aforementioned nutrient solution in an amount of 1 to 10 vol% of the amount of the aforementioned pollutants, followed by 2 kinds of the aforementioned pollutants. The nutrient solution is added and blended in a larger amount than in the first stage. 33. The method of item 28 of Shenyang Lifan Garden, the first step of which is to add and mix the aforementioned nutrient solution in an amount of 1 to 5 vol% of the amount of the aforementioned pollutants, and the second step is to perform the aforementioned steps Addition, mixing and first stage of the pollutants are 5 ~ 10 vol% of the aforementioned former nutrient solution, and there are projects that add and mix the aforementioned pollutants in a larger amount than the first stage or the second stage. The aforementioned campers. Printed by the Consumers' Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs (please read the precautions on the back before filling out this page). Revision 34. For the method of applying for Patent No. 28, where the aforementioned primogenogen is a water soluble compound and Daoyuan agent is dissolved in the aforementioned nutrient solution. 35. If the method of applying for benefit range item 28 is applied, in the aforementioned standing step, the aforementioned pollutants are maintained at 17 ~ 6010 for at least the first 3 days. This paper size applies to China National Standard (CNS) A4 (210X297 mm) 68 3 9 498