五、發明説明（1 ) 經濟部屮央榣準局β工消赀合作社印51 *> 〈發明之領域〉 本發明傺有關白色發光螢光體，尤其是有關一種將一 黃色發光榮光體和一藍色發光螢光體相混合或進一步再混 合一綠色發光螢光體而成立之一白色發光蛮光體。 〈發明之背景〉 目前用於一單色或黑白陰極射線管的一白色發光螢光 體係一藍色發光螢光體和一黃色發光螢光體在適當比例下 混合而成。白色發光螢光體的白色濃淡色調偽由二者混合 比例。比例可以依照需求而加以控制。 由於參考文獻掲露使用一混合之螢光體之一白色發光 螢光體，所以我們引用美國專利第3, 891, 886和4, 694, 217 號。美國專利第3, 891, 886號描述一白色發光混合«,其 主要包括一藍色發光活性金艮化硫化鮮[ZnS : As]螢光艦和 一黃色發光活性錮和紹化硫化鲜鋪[(Zn, Cd)S:Cu, A1] 螢光體•但在此例中，使用ZnS糸統螢光體長期操作陰極 射線管，使ZnS糸統幾光體作一藍色登光髏會增力Π礎螢光 發光之惡化。埋有，CdS条統發光髑有一項不利之缺點， 在污染觀點而言，它並非是可取之材料。 美國専利第4, 694, 217號條敍述一白色發光螢光體， 其主要包括一藍色螢光體，具有組成分子如組成方程式（ NU-x Tbx)2〇2S (在該方式内· Μ偽包括Y和/或Gd之一群 中所選擇出來的至少一項元素，X之範圍>^(0<χ$0·01) ，至少一項另一種營光體並不含有Cd。其它螢光體類係選 自含有ZnS : Au，Αθα Zn2Si04 : Μη群中所選擇出來的第 -3- (諳先閲請背而之ii意事項外填筠^ ) >* 本紙張尺度边用中SH家標iMCNS)T4規怙（210x297公龙） 81. 2. 20,000 經濟部屮央榣準局员工消费合作杜印製 五、發明説明（2 ) 二綠色或黃色榮光«,邐有一第三紅色螢光«I像遵自含有 γ2 0 2S : Eu, InBO 3 : Eu和Zn 3 (Ρ04) 2: Μη群中戸片發生之蝥光 龌。此白色發光螢光體偽包括藍色瑩光體。綠色或黃色榮 光雅有足夠照明売度，但顯示一白色帶有綠色色調。紅色 螢光體增加以後會改正此一顔色之差異•因為其低光度照 明，使白色發光螢光體光度惡化。 〈發明之總論〉 本發明之目的在提供具有高光度之白色發光螢光腰， 而且並無污染，並且能顙示白色明暗度，像選擇混合之螢 光嫌以及其數暈。 為了遑成上述目的，依照本發明之一具》化設計，提 供一白色發光螢光龌，包括一黃色發光螢光饑和一藍色發 光螢光體。其中黃色發光螢光體偽由包括（Carx Msx) S:Mn (0彡X芸0.05)芣口（Carx Mgx) S : Mn, Sc (0彡X备 0· 05 )群中所選出至少一種。藍色發光螢光體條自包括 ZnS ： Ag, ZnS ： Ag. Ga, ZnS ： As, Cl禾口ZnS : Ag, Qa, Cl O 黃色發光螢光體和盤色發光螢光體之最可取之混合比 例俗依照重童計算之30¾和70%的比例以及70¾和3090的 重量比例。 比較好之數量的活化劑Sc加到黃色發光蜜光' (Cax -X Msx) S : Μη, Sc(0各X各0.5)。但活化劑Sc之數童不得大 於500ΡΡΠΙ(百萬分之500)。此偽根據其體（Can Mgx)S之 重童。在藍色發光螢光體ZnS : Ag, Ga^ZnS : Ag, Ga, Cl *4- (請先IW1?背而之注意事項再填窩4 本紙张尺度边用中困困家楳準(CNS)IM規怙（210x297公龙） 31. 2. 20,000 044^3 /\ Η Π 6 經濟部中央櫺準扃0;工消伢合作社印？4 五、發明説明（3 ) 中之活性劑Ga之數:不得大於100ppm,此像根據基鼸重量 ZnS而言。 另一具嫌化之本發明也是提供包括一黃色發光螢光體 • 一藍色發光螢光龌，一綠色發光螢光饈之一白光發光螢 光餵。其中黃色發光螢光體像自含有（Can Mgx) S: Μη (0彡X彡0.05)和（Cat-X Mgx)S : Μη. Sc(0^0.05) 群中選出至少一種。藍色發光螢光賭係自含有ZnS : As, ZnS ： As, Ga, ZnS ： Ag, Cl萃口 ZnS : Αβ· Ga, Cl群中選出 之至少一種。綠色發光螢光嫌傜ZnS : Cu, Cle 較佳的黃色發光螢光醱、藍色發光螢光嫌和綠色發光 營光嫌混合比例條自重量的3的0到7890之比例，自10%到 40 %重董比例以及自10%到5096重比例σ 力Π在黃色發光螢光體（Ca! -X Msx) S，Μη, Sc (0忘X 盔0·05)之活化劑較佳者，其重量不得超過基體的100pPm Ο 本發明的第三項具髓實例係本發明提供含有一黃色發 光螢光體、一藍色發光螢光體和一綠色發光螢光體之一白 色發光螢光體。其中黃色發光螢光體偽包括（Can Msx) S : Μη (Θ^Χ^ 0.05)和(Ca i -x Mgx) S ： Mn, Sc (0^X $0·Θ5)。藍色發光螢光體偽自包括ZnS : Ag, Zns : Ag • Ga, ZnS ： Ag, Cl和ZnS : Ag, Ga, Cl群中選出之至少一 種。綠色發光螢光體傲自含有InBCh : Tb, Zn2Si04 : Μη 和Zn2Si04 : Μη, AsS^中選出至少一種。 黃色發光螢光體，藍色發光螢光髏和綠色發光螢光體 ~5_ (請先IMI价背而之注意亊項洱填穷^ 裝- 訂 線 本紙張尺度边用中困國家樣準（CNS)T4規格（210x297公没） S1. 2. 20,000 4 4 經濟部屮央櫺準局货工消费合作社印製 Λ 6 _η β _ 五、發明説明（4 ) 之較佳混合比為自3096到70¾重量比、自15%到409^重量 比以及自15%到3峡重*比。 加在黃色發光螢光體中之活化劑Sc之較佳數暈像基饑 CaS之重量的10ppm,黃色發光螢光龌之化學方程式為（ Cat -X Msx) S : Μη, Sc (0忘X忘0·05)。應不超過基艚 (Ca i Msx) S重置的300ppm。在藍色發光螢光髏中之 活化劑Ga不應超過基體ZnS重量之100ppmo 〈圖示的簡單說明〉 第1圖像白色發光螢光鼸之CIE色彩分解圖，像依照 本發明之第一實例到第十七實例所製造而成；第2_像白 色發光榮光體之CIE色彩分解圖，依照第18實例到第26實 例製造而成；以及，第3圖俱白色發光螢光髅之CIE色彩 分解圖，依照第27»例到第35實例製造而成。 〈較佳具雅實例之詳細描述〉 本發明將以實例作如下之解禪： <實例1 > 作為一黃色發光螢光聽CaS : Mn, Sc,在此黃色螢光 體中戸/f±曽力Π之活彳匕劑Μη和Sc的數量條各為1.00ΡΡΠΙ，像基體 CaS重量的100ppm。作為一藍色發光蛮光體ZnS : As,在其 中所加之活化劑Ag的數董係根據基體ZnS的10ppm。本實例 一係用己知之方法將所製備活化劑Ag, CaS:Mn, Sc和ZnS :Ag根據重量之比例30 : 70相混合，俾産生一白色發光蝥 光體。 <實例2〜5>V. Description of the invention (1) The 51th work of the β-Consumer Cooperative Society of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs 51 *> <Field of the Invention> The present invention relates to white luminescent phosphors, in particular to a yellow luminescent phosphor and A blue light-emitting phosphor is mixed or further mixed with a green light-emitting phosphor to form a white light-emitting phosphor. <Background of the invention> A white light-emitting phosphor system currently used in a monochromatic or black-and-white cathode ray tube, a blue light-emitting phosphor and a yellow light-emitting phosphor are mixed in an appropriate ratio. The white shades of white luminescent phosphors are pseudo-mixed by the two. The proportion can be controlled according to demand. Because the reference Lulu uses a white phosphor, one of a mixed phosphor, we refer to US Patent Nos. 3, 891, 886 and 4, 694, 217. U.S. Patent No. 3, 891, 886 describes a white luminous hybrid «, which mainly includes a blue luminescent active gold sulfide fresh [ZnS: As] fluorescent ship and a yellow luminescent active sulfonate and Shaohua sulfide fresh shop [ (Zn, Cd) S: Cu, A1] phosphor • However, in this example, ZnS phosphors are used to operate the cathode ray tube for a long time, so that the ZnS phosphors will be used as a blue light-emitting skull. Deterioration of fluorescent light emission. Buried, the CdS system has a disadvantageous disadvantage. It is not a desirable material from a pollution point of view. No. 4, 694, 217 of the United States describes a white luminescent phosphor, which mainly includes a blue phosphor, with a composition molecule such as a composition equation (NU-x Tbx) 2〇2S (in this way · Μ The pseudo includes at least one element selected from the group of Y and / or Gd, the range of X> ^ (0 < χ $ 0 · 01), at least one other type of light-emitting body does not contain Cd. Other fluorescent The body is selected from the group containing ZnS: Au, Αθα Zn2Si04: Mn selected from the -3- (think first, please read the back of the ii matters, please fill out ^) > * This paper is used in the side of the SH Home standard iMCNS) T4 regulations (210x297 male dragons) 81. 2. 20,000 printed by the consumer cooperation of the Department of Economics and Economics of the Ministry of Economic Affairs of the People ’s Republic of China 5. Printed descriptions of inventions (2) Two green or yellow glory «, with a third red screen The light «I image complies with γ2 0 2S: Eu, InBO 3: Eu, and Zn 3 (Ρ04) 2: The canopy occurs in the 戸 slice in the Mn group. The white light-emitting phosphor includes a blue phosphor. Green or yellow glory has enough illumination intensity, but shows a white with green hue. The increase in the red phosphor will correct the difference in this color. Because of its low light illumination, the brightness of the white light-emitting phosphor deteriorates. <Overview of the Invention> The purpose of the present invention is to provide a white luminous fluorescent waist with high luminosity, without pollution, and capable of displaying white lightness and darkness, like the selection of mixed fluorescent light and its number halo. In order to achieve the above purpose, according to one of the present invention, a white design is provided, including a white light-emitting fluorescent light, including a yellow light-emitting fluorescent light and a blue light-emitting fluorescent body. The yellow light-emitting phosphor is selected from the group consisting of (Carx Msx) S: Mn (0 彡 X 芸 0.05) 芣 口 (Carx Mgx) S: Mn, Sc (0 彡 X 备 0 · 05). The blue light-emitting phosphor strips include ZnS: Ag, ZnS: Ag. Ga, ZnS: As, Cl, and ZnS: Ag, Qa, Cl O. Yellow light-emitting phosphors and disk-color light-emitting phosphors are the most preferable The mixing ratio is calculated according to the ratio of 30¾ and 70% calculated by Chongtong and the weight ratio of 70¾ and 3090. A better amount of activator Sc is added to the yellow luminous honeycomb '(Cax -X Msx) S: Mn, Sc (0 each X 0.5 each). However, the number of activators Sc should not be greater than 500PPIII (500 parts per million). This pseudo is based on the heavy child of its body (Can Mgx) S. In the blue luminescent phosphor ZnS: Ag, Ga ^ ZnS: Ag, Ga, Cl * 4- (Please first IW1? Contrary to the precautions before filling the nest 4 This paper scale is used for the sleepy and poor family standard (CNS ) IM regulation (210x297 male dragon) 31. 2. 20,000 044 ^ 3 / \ Η Π 6 Central Ministry of Economic Affairs, Ministry of Economic Affairs 0; printed by the Industrial Cooperative Society? 4 V. The active agent Ga in the description of invention (3) Number: not more than 100ppm, this image is based on the weight of ZnS based on the weight of the base. Another suspected invention also includes a yellow luminescent phosphor • a blue luminescent phosphor, one of a green luminescent phosphor White light-emitting fluorescent feed. The yellow light-emitting fluorescent image is selected from the group consisting of (Can Mgx) S: Mn (0 彡 X 彡 0.05) and (Cat-X Mgx) S: Μη. Sc (0 ^ 0.05). One. The blue light-emitting fluorescent bet contains at least one selected from the group consisting of ZnS: As, ZnS: As, Ga, ZnS: Ag, Cl extraction ZnS: Αβ · Ga, Cl. The green light-emitting fluorescent is suspected to be swollen ZnS: Cu, Cle The preferred mixture ratio of yellow light-emitting fluorescent light, blue light-emitting fluorescent light and green light-emitting fluorescent light is from 0 to 7890 of weight 3, from 10% to 40% of heavy weight ratio and from 10 % To 5096 The ratio σ force Π in the yellow luminescent phosphor (Ca! -X Msx) S, Mn, Sc (0 忘 X helmet 0 · 05) is preferably an activator, the weight of which should not exceed 100 pPm of the substrate. The three pith examples are that the present invention provides a white light-emitting phosphor containing one of a yellow light-emitting phosphor, a blue light-emitting phosphor, and a green light-emitting phosphor. The yellow light-emitting phosphor includes (Can Msx ) S: Mn (Θ ^ Χ ^ 0.05) and (Ca i -x Mgx) S: Mn, Sc (0 ^ X $ 0 · Θ5). The blue light-emitting phosphor includes ZnS: Ag, Zns: Ag Ga, ZnS: Ag, Cl, and ZnS: at least one selected from the group of Ag, Ga, and Cl. The green light-emitting phosphor proudly contains at least one selected from InBCh: Tb, Zn2Si04: Mn, and Zn2Si04: Mn, AsS ^. Yellow Luminescent phosphor, blue luminescent fluorescent skull and green luminescent fluorescent ~ 5_ (please pay attention to the price of IMI first) Please fill in the items ^ Pack-Bookmarking for the borderline and the national standards (CNS ) T4 specifications (210x297 public) S1. 2. 20,000 4 4 Printed by the Cargo Consumers Cooperative of the Central Bureau of Economics, Ministry of Economic Affairs Λ 6 _η β _ V. The best mixing ratio of the invention description (4) is: 3096 to 70¾ by weight, from 15% to 409 ^ 15% by weight and from 3 to Gap * weight ratio. The preferred number of activator Sc added to the yellow luminescent phosphor is 10 ppm of the weight of the halo CaS. The chemical equation of the yellow luminescent phosphor is (Cat -X Msx) S: Mn, Sc (0 忘 X Forget 0 · 05). It should not exceed 300 ppm of Ca i Msx S reset. The activator Ga in the blue light-emitting fluorescent skull should not exceed 100 ppmo of the weight of the substrate ZnS <Simple description of the image> The first image is the CIE color exploded view of the white light-emitting fluorescent eel, like the first example according to the invention Manufactured by the seventeenth example; the second_CIE color exploded view like white luminous glory, manufactured according to the eighteenth to twenty-sixth examples; The exploded view is manufactured according to the 27th to 35th examples. <Detailed description of preferred and elegant examples> The present invention will use the examples as a solution to Zen as follows: < Example 1 > As a yellow luminescent fluorescent listening CaS: Mn, Sc, in this yellow fluorescent body 戸 / f The quantity bars of the active agents Mn and Sc of ± Π are each 1.00PPΠΙ, like 100 ppm of the weight of the base CaS. As a blue light-emitting body ZnS: As, the number of activators Ag added thereto is 10 ppm based on the base ZnS. In this example, the prepared activators Ag, CaS: Mn, Sc and ZnS: Ag are mixed according to a weight ratio of 30: 70 by a known method, so as to produce a white luminescent canthal phosphor. < Example 2 ~ 5 >
(請先閲讀背而之注意事項再填寫A 裝- 線_ 本紙張尺度边用中國Η家榀準（CNS) 規格（210x297公龙) 81. 2. 20,000 ^044¾¾ 經濟部屮央榀準局KX工消费合作社印" 五、發明説明（5) 如實例1 —樣的榮光雅。CaS : Μη· Sc和ZnS : Αβ相混 合。其重董比為40 : 60 (實例2) , 50:50 (實例3). 60:40 (實例4) , 70:30 (實例5)，俾産生白色發光 榮光體。 <實例6 > CaS : Μη作為一黃色發光螢光嫌。它包括有I00ppm Μη 活化劑。ZnS : Ag, Ga作為藍色發光螢光雠含有100ppm之 A«活化劑和10ppm Ga活化劑，偽用已知方法製備而成。 CaS : Μη和ZnS : A«混合。其重β:比例為30 : 70,以産生 一白色發光螢光髓。 <實例7-10> 如資例6之相同螢光嫌。CaS : Μη和ZnS : Α«混合在一 起。其重董比例為40 : 60 (實例7)。50 : 50 (實例8) 〇 60 : 40 (實例9 )禾U70 : 30 (實例10)，俾産生白色 發光螢光體。 <實例11> (Ca0.95 Μ«0·05) S : Mn· Scf^為一黃色發光祭光龌 ，其中含有3000ppm^Mn活化_以及500ppm^_Sc活化劑； ZnS : As, Ga, C1作為一籃色發光螢光嫌，含有200ppm As 活化劑以及100pPm之Ea活化劑。二者像用一已知方法準備 而成，（Ca0*95 M«0,05) S : Mn, Sc和ZnS : As, Ga, C1 二者混合，其重置比為30 : 70,俥産生一白色發光蛮光體 Ο < 實例 12-15> -7- (請先閲讀背而之注意苹項洱填0 本紙張尺度边用中國Η家橒準（CNS) 規格（210x297公；¢) 81· 2. 20,〇〇〇 經濟部中央榀準局A工消许合作杜印5i Λ fi ____Π_β_ 五、發明説明（ε) 如實例11相同之螢光«。（Ca0.95 Μ«0·05) S : Μη, Sc和ZnS : Α«· Ga· Cl相互混合。其重：比為40 : 60 ( 實例 12) , 50 : 50 (實例13) , 60 : 40 (實例 14)和70 :30 (實例15).侔産生白色發光螢光體。 <實例16> (Ca0.98 Ms0.02)S : Mn, Sc作為一黃色發光螢光髏 ,内含有1000ppm Μη活彳匕劑以及100ppm Sc活彳匕剤；ZnS : As, Ca，C1作為一藍色發光螢光餳，其中含有i30ppm^Ae 活化则和30ppm^Ga活化_〇像用一已知方法將所製備（ Ca0.98 Μβθ.02)) ： Μη, ScfaZnS ： As, Ga. Cl相互混合 。其重Jt混合比例為60 :40,俾産生一白色發光螢光讎。 <實例17> (Ca0*97 Μ«0·03) S : Mn· Sc作為一黃色發光费光 讎•其中含有2000ρρπϋ之Μη活<匕_和1 50ppm之Sc活彳匕劑； ZnS : A«, Ga, C1作為藍色發光營光體，内含有50ppm Ag 活化劑和20ppni Ga活化劑。條用一已知方法將所製備（ Ca0.97 Mg0. 03) S ： Μη, Sc苹口ZnS : Ag, Ga, Cl丰目令昆合· 其重量混合比例為55 : 45,俥産生一白色發光之蜜光體。 依照實例1 -17,白色發光螢光體的相對亮度經檢查後 ，結果俗在下列表1 ,以比較含有ΙηΒ03, InB03 : Eu和 ZnS : Ag之白色發光發光體作為和標準（亮度100%)的tb 例。還有依照實例1 17之白色發光螢光體的CIE：色彩之協 調因素亦經檢查。其結果在表1.和第1圖中顯示之。 -8- (請先閱讀背而之注意亊項再構窍4 裝· 線 本紙張尺度边用中困a家橒準（CNS)肀4規格（210><297公龙) 81. 2. 20,000 2044^3 Λ Η 15 6 五、發明説明（7 ) 表 1 白色發光 蟹光腰(Please read the precautions before you fill in the A-line _ The size of this paper is based on the Chinese standard (CNS) specifications (210x297 male dragon) 81. 2. 20,000 ^ 044¾¾ The Central Bureau of Economic Affairs KX Industrial and Consumer Cooperative Print " V. Description of the invention (5) Rong Guangya as in Example 1. CaS: Mn · Sc and ZnS: Αβ are mixed. Its weight ratio is 40: 60 (Example 2), 50: 50 (Example 3). 60:40 (Example 4), 70:30 (Example 5), to produce a white luminescent phosphor. ≪ Example 6 > CaS: Mn as a yellow luminescent phosphor. It includes I00ppm Mn Activator. ZnS: Ag, Ga as blue light-emitting fluorescent chrysanthemum contains 100ppm of A «activator and 10ppm Ga activator, which is prepared by a known method. CaS: Mn and ZnS: A« mixed. Its weight β : The ratio is 30:70 to produce a white luminescent fluorescent pulp. ≪ Example 7-10 > As the same fluorescent material as in Example 6. CaS: Mn and ZnS: Α «Mixed together. The proportion of heavy director is 40: 60 (Example 7). 50: 50 (Example 8) 〇60: 40 (Example 9) and U70: 30 (Example 10) to produce a white light-emitting phosphor. ≪ Example 11 > (Ca0.95 Μ «0 · 0 5) S: Mn · Scf ^ is a yellow luminous sacrificial light, which contains 3000ppm ^ Mn activation_ and 500ppm ^ _Sc activator; ZnS: As, Ga, C1 as a basket of luminescent fluorescence, containing 200ppm As activation Agent and Ea activator of 100pPm. The two are prepared by a known method, (Ca0 * 95 M «0,05) S: Mn, Sc and ZnS: As, Ga, C1 are mixed and their reset The ratio is 30:70, and it produces a white light-emitting luminous body Ο < Examples 12-15 > -7- (please read it first and note that Ping Xiang Er fills in 0. The paper size is based on the Chinese 插 歒 quasi (CNS ) Specification (210x297 g; ¢) 81 · 2. 20, 20,000 Central Ministry of Economic Affairs, Central Bureau of Industry and Engineering, Ai Xiaoxu Cooperation Duin 5i Λ fi ____ Π_β_ V. Invention description (ε) The same fluorescent light as in Example 11 «. (Ca0.95 Μ «0 · 05) S: Mn, Sc and ZnS: Α« Ga · Cl are mixed with each other. Its weight: ratio is 40:60 (Example 12), 50:50 (Example 13), 60: 40 (Example 14) and 70:30 (Example 15). Do not produce white light-emitting phosphors. < Example 16 > (Ca0.98 Ms0.02) S: Mn, Sc as a yellow luminescent fluorescent skull, containing 1000ppm Mn active dagger and 100ppm Sc active dagger; ZnS: As, Ca, C1 as A blue light-emitting fluorescent sugar, which contains i30ppm ^ Ae activation and 30ppm ^ Ga activation _ like prepared by a known method (Ca0.98 Μβθ.02)): Μη, ScfaZnS: As, Ga. Cl Mixed with each other. Its heavy Jt mixing ratio is 60:40, so as to produce a white light-emitting fluorescent lamp. < Example 17 > (Ca0 * 97 Μ «0 · 03) S: Mn · Sc as a yellow light-emitting luminescence compound containing 2,000 ρρπϋ Mn active <dagger _ and 150 ppm Sc active dagger agent; ZnS: A «, Ga, C1 as blue light-emitting phosphors, containing 50ppm Ag activator and 20ppni Ga activator. The strip was prepared by a known method (Ca0.97 Mg0. 03) S: Mn, Sc, ZnS: Ag, Ga, Cl Fengmu Ling Kunhe. Its weight mixing ratio was 55: 45, which produced a white color Glowing honey body. According to Examples 1-17, the relative brightness of the white light-emitting phosphors was examined, and the results are shown in Table 1 below, to compare the white light-emitting phosphors containing ΙηΒ03, InB03: Eu and ZnS: Ag as the standard (brightness 100%) tb example. Also the CIE of white light-emitting phosphors according to Example 17: color coordination factors were also examined. The results are shown in Table 1. and Figure 1. -8- (please read the notes before you re-construct the first item 4 pack · the size of the paper on the edge of the paper is used in the home a standard (CNS) 肀 4 specifications (210> < 297 male dragon) 81. 2. 20,000 2044 ^ 3 Λ Η 15 6 V. Description of the invention (7) Table 1 White light-emitting crab light waist
I 相對光度 CIE調和色度 X I y '" I. Η L_________ 娜酬 12345678901234567 lxxllllx 100 1 0.36 1 0.40 115 1 0.22 1 0.26 116 1 0.26 1 0.30 116 1 0.30 1 0.32 118 1 Θ.33 1 0.36 120 1 0.38 1 0.405 113 1 Θ. 22 1 0.26 114 1 0.26 1 0.30 114 1 0.30 1 0.32 ' 115 1 0.33 1 0.38 117 1 0.38 1 0.405 113 1 0.235 1 0.225 115 0.28 1 0.245 116 1 0.31 1 0.28 117 1 0.37 | 0.32 119 1 0.435 1 0.36 118 1 0.37 1 0.35 117 1 Θ.355 1 0.335 (請先閱1»«背而之注意事項#媾寫^ 裝· 訂 經濟部中央標準局13：工消赀合作杜印製 依照表1 ,相對光度，有關本發明之榮光體要比標準 發光螢光醱光度多13%到20¾，還有，本發明螢光體的 CIE調和色度要低於標準發光螢光體之色度。 〈實例18> CaS : Μη作為黃色發光螢光體；ZnS : As, C1作為藍色 發光螢光艘以及ZnS:Cu, C1作為綠色發光螢光體，均偽 用一種已知方法配製。 CaS ： Μη, ZnS : Ag, Cl和 ZnS : Cu, (：1偽用重量比例 60 : 20 : 20混合，俾産生一白色發光螢光體。 <實例19> CaS : Mn. Sc作為黃色發光蜜光體•内含300ΡΡΠ»之Sc -9- 線 本紙尺度边用中SS家樣準規格（210x297公龙) 51. 2. 20,⑽ 1?•〇44以 Λ fi Η 6 五、發明説明（《=) 閲 itx -背 之 注 意 事 項 塡 % 活化劑；ZnS : A«, Ga, C1作為一藍色發光螢光雅，内含 100ppm^Ga活化劑；以及ZnS : Cu, C1作為綠色發光發光 體，均像用一已知方法配製而成。CaS : Mn, Sc, ZnS : Ag ,Ga, Cl和ZnS : Cu, Cl像用重量比例70 : 20 : 10酉己合而 成，俾産生白色發光登光龌。 〈實例20-24〉 如實例19—樣之發光螢光體CaS : Mn. Se, ZnS : As, Ga, Cl和ZnS : Cu, Cl像用重暈比例60 : 20 : 20 (實例20 ),50 ： 20 ： 30 (實例21) · 40 ： 20 ： 40 (實例21) , 30 :20 ·· 50 (實例23)和60 : 10 : 30 (實例24)，俾産生白 色發光螢光鱷。 <賞例25> Τ (Ca0,95 Ms:0.05) S:Mn, Sc作為黃色發光蜜光釅， 其中包括30ppm之Sc活化劑，ZnS : Asr. Ga, C1作為一藍色 發光螢光體，其中包括Ga活化劑；以及ZnS : Cu, C1作為 綠色發光螢光體均傑用一已知方法所配製而成。（Ca0. 95 Mg0.05) S : Μη, Sc, ZnS ： Ag, Ga, Cl以及 ZnS : Cu, Cl 像用重最fcb例50 : 30 : 20混合，俾産生一白色發光營光體 Ο 經濟部中央搮準局贸工消伢合作社印製 <實例26> 如實例25,使用相同的發光螢光體（Ca0.95 Ms0.05) S : Mn. Sc, ZnS ： Ag, Ga, Cl和ZnS : Cu. Cl 像用重量比 50 : 40 : 10混合而成，俾産生發光發光體。 然後，俗照第18到26實例，白色發光蜜光體之相對光 -10- 81. 2. 20,000 本紙张尺度边用中國Η家標毕(CNS) TM規格（210X297公龙) Λ 6 η 6 五、發明説明（s) 度像經過檢査。其結果在表2中所顯示出來，乃如下，其 和含有InB03 : Tb, InB03 : Eu和ZnS : Ag之白色發光螢光 體作為標準（光度10096)相比較〇邐有依照實例18-26 ，白色發光螢光應的CIEI»和色度均經檢査。其結果在表 2和第2國中載明。 I-· 表 2 相對光度~Γ l· (%) CIE調和色度 yI Relative luminosity CIE Harmonic chromaticity XI y '" I. Η L_________ Na reward 12345678901234567 lxxllllx 100 1 0.36 1 0.40 115 1 0.22 1 0.26 116 1 0.26 1 0.30 116 1 0.30 1 0.32 118 1 Θ.33 1 0.36 120 1 0.38 1 0.405 113 1 Θ. 22 1 0.26 114 1 0.26 1 0.30 114 1 0.30 1 0.32 '115 1 0.33 1 0.38 117 1 0.38 1 0.405 113 1 0.235 1 0.225 115 0.28 1 0.245 116 1 0.31 1 0.28 117 1 0.37 | 0.32 119 1 0.435 1 0.36 118 1 0.37 1 0.35 117 1 Θ.355 1 0.335 (please read first 1 »« Backward notes # 媾 写 ^ 装 · 訂 訂 號 Central Standard Bureau of the Ministry of Economic Affairs 13: Cooperative du printing in accordance with the work Table 1. Relative luminosity. The luminosity of the present invention is 13% to 20¾ more than that of the standard luminescent phosphor. Also, the CIE blending chromaticity of the phosphor of the present invention is lower than that of standard luminescent phosphor <Example 18> CaS: Mn as a yellow light-emitting phosphor; ZnS: As, C1 as a blue light-emitting phosphor and ZnS: Cu, C1 as a green light-emitting phosphor, all of which are prepared by a known method. : Mn, ZnS: Ag, Cl and ZnS: Cu, (: 1 pseudo weight ratio 60: 20: 20 mixed to produce a white luminescent phosphor. ≪ Example 19 > CaS: Mn. Sc as a yellow luminescent honeycomb • Sc -9- containing 300PPΠ »-line paper scale side with medium SS home sample standard Specifications (210x297 male dragon) 51. 2. 20, ⑽ 1? • 〇44 to Λ fi Η 6 V. Description of the invention (《=) Read itx-Notes on the back 塡% activator; ZnS: A «, Ga, C1 as a blue light-emitting fluorescent elegant, containing 100ppm ^ Ga activator; and ZnS: Cu, C1 as a green light-emitting luminous body, are prepared as if using a known method. CaS: Mn, Sc, ZnS: Ag, Ga, Cl, and ZnS: Cu, Cl images are formed by combining the weight ratio of 70:20:10, so as to produce white luminescence. <Example 20-24> As in Example 19, the luminescent phosphor CaS: Mn. Se, ZnS: As, Ga, Cl, and ZnS: Cu, Cl image with a halo ratio of 60: 20: 20 (Example 20), 50: 20: 30 (Example 21) · 40: 20: 40 (Example 21), 30: 20 · · 50 (Example 23) and 60: 10: 30 (Example 24) to produce a white light-emitting fluorescent crocodile. < Appreciation Example 25 > Τ (Ca0,95 Ms: 0.05) S: Mn, Sc as a yellow luminous honey tincture, including 30 ppm of Sc activator, ZnS: Asr. Ga, C1 as a blue luminous phosphor , Which includes Ga activator; and ZnS: Cu, C1 as green luminescent phosphors are prepared by a known method. (Ca0. 95 Mg0.05) S: Mn, Sc, ZnS: Ag, Ga, Cl, and ZnS: Cu, Cl. The most important weight is fcb. Example 50: 30: 20 mixed to produce a white light emitting body. Economy Printed by the Ministry of Industry and Commerce Cooperative Society of Central Bureau of Trade and Industry <Example 26> As in Example 25, using the same luminescent phosphor (Ca0.95 Ms0.05) S: Mn. Sc, ZnS: Ag, Ga, Cl and ZnS: Cu. Cl image is mixed by weight ratio 50: 40: 10 to produce luminous luminous body. Then, according to examples 18 to 26, the relative light of the white luminous honey body -10- 81. 2. 20,000 The size of the paper is based on the Chinese standard (CNS) TM specification (210X297 male dragon) Λ 6 η 6 5. Description of the invention (s) The degree image has been checked. The results are shown in Table 2 as follows, compared with white luminescent phosphors containing InB03: Tb, InB03: Eu and ZnS: Ag as the standard (luminosity 10096). According to Examples 18-26, The CIEI »and chromaticity of the white luminescence should be checked. The results are shown in Table 2 and the second country. I- · Table 2 Relative luminosity ~ Γ l · (%) CIE harmonic chromaticity y
·*I 白色發光 JKTCoS X 標準 1 100 1 0.36 | 0.40 實例 18 | 131 1 0.38 | 0-385 19 | 127 1 0.41 | 0.38 20 | 129 1 0.38 | 0.385 21 | 130 1 0.365 | 0.405 22 I 132 1 0.345 | 0.405 23 | 133 1 0.32 | 0.43 24 | 137 1 0.39 | 0.425 25 | 130 1 0.335 | 0.36 26 1 129 1 Θ*3Θ | Θ.28 Η —Η (請先WI1?背而之注意事項再蜞窵.*-,〇 裝. 訂_ 線 經濟部屮央櫺準局员工消费合作社印驭 依照表本發明的發光螢光髁的相對光度僳較樣準 螢光髖之光度高出27%到37%。 <實例27> 以CaS:Mn作為一黃色發光蛮光礎，其中包括1500ΡΡΠΙ之 Μη活化劑；ZnS : As作為一藍色發光碟，其中包括130ppm 之Ag活化劑；InB〇3 : Tb作為一綠色發光營光體，其中含 有700ppm之Tbi舌4匕劑，均偽用一己矢口方法酉己製而成。 CaS ： Μη, ZnS : Ag芣口ΙηΒ03 : 用重Jltb伊J 50 : 20 :30·混合而成，俾産生一白色發光螢光應。 <貢例28> -11 卜紙張尺度边用中a Η家榣準（CNS) 規格（210x297公没） 81. 2. 20,000 Λ Λ Λ 6η 6 經濟部中央標準局貝工消f合作杜印3i 五、發明説明（10) 如實例27中一樣的CaS : Μη 和ZnS : Αβ ;以及使用 Zn2Si04 : Μη以代替ΙηΒ〇3 : Tbf^為貢例27中之一嫌色發光 蠆光黼，上述三種酱光讎像用重:K比例50 : 20 : 3Θ混合， 侔産生一白色發光螢光《〇 <實例29> CaS: Mn, Sc作為一黃色發光蛮光體，其中含有1000 ppm之Μη活化劑和100ppm之Sc活化劑；ZnS : As, Ga, C1作 為一藍色發光螢光嫌，其中有50ppm^：A«活化劑和20ppm 之Ga活化劑；以及InBCh : Tb和Zn2SiO 4 : Μη, As作為 二種綠色發光蛮光體•均像用一種已知的方法配製而成〇 CaS ： Μη, Sc 苹口 ZnS ： Ag, Ga, Cl 芣Cl InB03 : Tb 以及 Zn2Si04 : Μη，As像用重量比例50 : 20 : 20 : 10配製而成 ，俾産生一白色發光螢光體。 <實例30> (Ca0.95 1%0.05) S : Mn, Sc作為一黃色發光螢光 體，其中包括3000ppm之Μη活化劑和30Θρρπι之Sc發光螢光 體；ZnS : Ag, Ga, C1作為一藍色發光螢光體，其中包括 200PPIU之Ag活化劑和100 ρρπ»之Ga活化劑；InB03 : Tb含 有1500 ppm之Tb活化劑和Zn2Si04 : Mn, As作為二種 綠色發光發光體，均係*用一已知方法配製而成。（Ca0. 95 Mg0.05) S ： Μη, Sc, ZnS ： Ag. Qa, Cl, InB03 : Tb 和 Zn2Si04 : Μη, As均偽用重量比例40 : 30 : 20 : 10混合而 成，俾産生白色發光螢光髏。 <實例31〉 -12 - (請先IU11?背而之注意事項再填Τ?ΤΑ 裝· 本紙張尺度边用中國國冢梂準（CNS)甲4規岱（210Χ297公龙） 3i. 2· 20,000 ο 經濟部屮央#準局β工消伢合作杜印製 Λ f>_ η β_ 五、發明説明（1 1) (Ca0*98 MS0.02) S : Μη, Sc作為黃色發光费光讎 ，其中含有2000ppro^· Μη活化劑和30ppm之Sc活化劑； ZnS ： Ag, Ga, Cl作為一藍色發光螢光體.含有50ppm之Ag 活化剤和I10ppm^lGa活化剤；InB03 : Tb含有3000ppm之Tb 活化劑以及Zn 2 Si04 : Μη, As作為二種綠色發光螢光髏， 均條用一已知方法配製而成。（Ca0.98 Mg0.02)S:Mn, Sc, ZnS ： Ag, Ga, Cl, InBO3 : Tb和Zn2SiO4 : Mn, As 像 用重量比例30 : 40 : 10 : 20M合而成，俾産生一白色發光 螢光髗。 < 實例32-35> 如實例31中相同之發光螢光雅〇 (Ca0.98 MS0.02) S ϊ Μη, Sc ; ZnS : Ag, Ga, Cl ; InBO 3 : Tb和ZmSiO 4 : Μη ,As,利用重量比例50 : 30 : 10 : 10 (實例32)，或60 : 25 ： 10 ： 5 (實例33) , 70 : 15 : 10 : 5 (實例34)和60 : 20 : 5 : 15 (實例35),俥産生白色發光發光體。 然後，依照實例27到35,白色發光營光體之照明亮度 僳經檢查過。其結果載明於表 3,俾與含有InBO3 : Tb, InBO3 : Eu和ZnS : Ag稼準（照明亮度10096)相比較。運 有，依照27到35實例中，白色發光螢光體之CIE調和色度 均經檢査。其結果在表3和第3圖中載明： (請先閱讀背而之注意事項洱填寫4 裝· 線 -13- 本紙張尺度边用中8 a家標毕（CNS)T4規格（210x2974*) S1. 2. 20,000 五、發明説明（12) 表 3 A 6 Η 6 白色發光 螢光體 相對光度(%) CIE調和色度 y 標準 I 100 1 0.36 實例 27 | 115 1 0.375 28 | 120 1 Θ.345 29 | 118 1 0.355 30 | 116 1 0.31 31 | 114 1 0.285 32 1 113 1 0.31 33 | 116 1 0.345 34 1 114 1 0.385 35 | 113 1 0.38 08059 始 2ί<3Λβ5ί4 43433^3a3^3i3-·♦·♦··♦*♦♦ 0000000000 (請先閲讀背v--'IJ·之>i意^項#碭其^ 經濟部中央捣準局貝工消伢合作杜印驭 依照表3 ,本發明之發光螢光嫌相對光度條高於標準 礎螢光臞1396到29%。 第1、2和3圖像依照實例1到實例17所製造之白色 發光螢光體之CIE調和色度，以及依照實例18到26和實例 27到35所製造之白色發光螢光體的CIE調和色度圖。 依照第1圖到第3圖，顯示根據白色圖（w)之CIE調 和色度本發明之上述發光螢光體有廣泛的範圍。選擇混合 螢光體以及增加的數量，可以提供任何明暗度之白色。 如上所解釋，本發明之白色發光螢光體具有高度之亮 度並且顯示廣泛範圍之白色。邇不會造成污染。 對技術熟悉人士而言，白色發光螢光體可以有很多改 變而不會失去本發明之精神和範圍，若其改變仍為本申請 專利範圍所涵蓋時，仍然應該在本案之申請專利範圍。 -14- 本紙张尺度边用中S困家標準（CNS)甲4規tS(210x297公没) SI. 2. 20,000 裝. 線·* I white luminescence JKTCoS X Standard 1 100 1 0.36 | 0.40 Example 18 | 131 1 0.38 | 0-385 19 | 127 1 0.41 | 0.38 20 | 129 1 0.38 | 0.385 21 | 130 1 0.365 | 0.405 22 I 132 1 0.345 | 0.405 23 | 133 1 0.32 | 0.43 24 | 137 1 0.39 | 0.425 25 | 130 1 0.335 | 0.36 26 1 129 1 Θ * 3Θ | Θ.28 Η -Η (Please WI1? . *-, 〇 装. Order _ The Ministry of Line Economy, Ministry of Economic Affairs, Pyongyang Bureau, Employee Consumer Cooperative, Yinyu, the relative luminosity of the luminescent fluorescent condyle according to the present invention is 27% to 37% higher than that of the quasi-fluorescent hip ≪ Example 27 > With CaS: Mn as a yellow light emitting base, which includes Mn activator of 1500PPIII; ZnS: As as a blue light emitting disc, which includes 130 ppm of Ag activator; InB〇3: Tb as A green luminescent luminous body, which contains 700ppm of Tbi tongue 4 dagger, all of which are prepared by the method of one's own mouth. CaS: Μη, ZnS: Ag 芣 口 ΙηΒ03: heavy Jltb Yi J 50: 20: 30 · Mixed to produce a white light-emitting fluorescent light. ≪ Gong Example 28 > -11 BU paper scale edge used in a Η 家 榣Standard (CNS) specifications (210x297) 81. 2. 20,000 Λ Λ Λ 6η 6 Ministry of Economic Affairs, Central Standards Bureau, Bei Gongxiao cooperation Du Yin 3i V. Description of the invention (10) CaS as in Example 27: Μη and ZnS: Αβ; and the use of Zn2Si04: Mn instead of ΙηΒ〇3: Tbf ^ is one of the trivial color-emitting luminous light curtains in Example 27, the above three kinds of sauce light image are mixed with weight: K ratio 50: 20: 3Θ, Produces a white light-emitting fluorescent light "〇 < Example 29 > CaS: Mn, Sc as a yellow light-emitting phosphor, which contains 1000 ppm Mn activator and 100 ppm Sc activator; ZnS: As, Ga, C1 as a Blue light-emitting fluorescent light, including 50ppm ^: A «activator and 20ppm Ga activator; and InBCh: Tb and Zn2SiO 4: Mn, As as two green light-emitting luminous bodies The method is prepared by 〇CaS: Mn, Sc, and ZnS: Ag, Ga, Cl, Cl, InB03: Tb, and Zn2Si04: Mn, As. The image is prepared with a weight ratio of 50: 20: 20: 10, so as to produce a white light. Phosphor. < Example 30 > (Ca0.95 1% 0.05) S: Mn, Sc as a yellow luminescent phosphor, including 3000ppm Mn activator and 30Θρρπι Sc luminescent phosphor; ZnS: Ag, Ga, C1 as A blue light-emitting phosphor, including 200PPIU of Ag activator and 100 ρρπ »Ga activator; InB03: Tb contains 1500 ppm of Tb activator and Zn2Si04: Mn, As as two kinds of green light-emitting emitters, both are * Formulated with a known method. (Ca0. 95 Mg0.05) S: Μη, Sc, ZnS: Ag. Qa, Cl, InB03: Tb and Zn2Si04: Mn, As are all pseudo-weight ratio of 40: 30: 20: 10 mixed to produce white Glowing fluorescent skull. < Example 31> -12-(please fill in the IU11? and then fill in the T? TA). The size of this paper is the Chinese National Mounding Standard (CNS) A 4 gauge Dai (210Χ297 公 龙) 3i. 2 · 20,000 οMinistry of Economic Affairs # Public Bureau β 工 消 伢 Cooperation Duprinting Λ f > _ η β_ V. Description of the invention (1 1) (Ca0 * 98 MS0.02) S: Mn, Sc as yellow light雠, which contains 2000ppro ^ · Mn activator and 30ppm Sc activator; ZnS: Ag, Ga, Cl as a blue light-emitting phosphor. Contains 50ppm Ag activation and I10ppm ^ lGa activation; InB03: Tb contains 3000ppm Tb activator and Zn 2 Si04: Mn, As are two kinds of green light-emitting fluorescent skulls, and the average strips are prepared by a known method. (Ca0.98 Mg0.02) S: Mn, Sc, ZnS: Ag , Ga, Cl, InBO3: Tb and Zn2SiO4: Mn, As The image is composed of a weight ratio of 30: 40: 10: 20M, so as to produce a white luminescent fluorescent beetle. ≪ Examples 32-35 > Same as in Example 31 The luminescence of fluorescent light (Ca0.98 MS0.02) S ϊ Μη, Sc; ZnS: Ag, Ga, Cl; InBO 3: Tb and ZmSiO 4: Mn, As, the use of weight ratio 50: 30: 10: 10 ( Example 32), or 60: 25: 1 0: 5 (Example 33), 70: 15: 10: 5 (Example 34) and 60: 20: 5: 15 (Example 35), the white light emitting luminous body is produced. Then, according to Examples 27 to 35, the white light emitting camp The brightness of the light body has been checked. The results are shown in Table 3, compared with those containing InBO3: Tb, InBO3: Eu and ZnS: Ag (lighting brightness 10096). Yes, according to examples 27 to 35 The CIE blending chromaticity of the white light-emitting phosphors has been checked. The results are shown in Table 3 and Figure 3: (Please read the notes before filling in 4 sets · line-13- the paper size In the edge use 8 a home standard (CNS) T4 specifications (210x2974 *) S1. 2. 20,000 V. Description of the invention (12) Table 3 A 6 Η 6 White luminescent phosphor relative luminosity (%) CIE harmonic chromaticity y Standard I 100 1 0.36 Example 27 | 115 1 0.375 28 | 120 1 Θ.345 29 | 118 1 0.355 30 | 116 1 0.31 31 | 114 1 0.285 32 1 113 1 0.31 33 | 116 1 0.345 34 1 114 1 0.385 35 | 113 1 0.38 08059 Start 2ί < 3Λβ5ί4 43433 ^ 3a3 ^ 3i3- · ♦ · ♦ ·· ♦ * ♦♦ 0000000000 (Please read the back v-'IJ · 之> gt; i 意 ^ 项 # 砀 其 ^ Ministry of Economy Article luminosity higher than a standard base 1396 to 29% fluorescence Qu tamper central registration cancellation HIGHLAND Board printed Yu Ya cooperatives According to Table 3, the light emitting phosphor of the present invention is relatively too. The first, second and third images are based on the CIE blending chromaticity of the white light-emitting phosphors manufactured in Examples 1 to 17, and the CIE blending of the white light-emitting phosphors manufactured in Examples 18 to 26 and Examples 27 to 35 Chromaticity diagram. According to Fig. 1 to Fig. 3, it is shown that the above-mentioned light-emitting phosphor of the present invention has a wide range according to the CIE adjusted chromaticity of the white diagram (w). Choosing to mix the phosphors and increasing the quantity can provide white with any brightness. As explained above, the white light-emitting phosphor of the present invention has a high degree of brightness and displays a wide range of white. It will not cause pollution. For those skilled in the art, the white light-emitting phosphor can be changed a lot without losing the spirit and scope of the present invention. If the changes are still covered by the patent scope of this application, it should still be covered by the patent application of this case. -14- This paper scale is used in the middle-S sleepy home standard (CNS) A 4 gauge tS (210x297 public) SI. 2. 20,000 pack. Thread ·