TW202408389A - Sports shoe - Google Patents
Sports shoe Download PDFInfo
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- TW202408389A TW202408389A TW112126852A TW112126852A TW202408389A TW 202408389 A TW202408389 A TW 202408389A TW 112126852 A TW112126852 A TW 112126852A TW 112126852 A TW112126852 A TW 112126852A TW 202408389 A TW202408389 A TW 202408389A
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- Prior art keywords
- shoe
- thermoplastic elastomer
- elastomer
- thermoplastic
- hardness
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- 229920001971 elastomer Polymers 0.000 claims abstract description 68
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 65
- 239000005060 rubber Substances 0.000 claims abstract description 50
- 239000002245 particle Substances 0.000 claims abstract description 46
- 239000006260 foam Substances 0.000 claims abstract description 28
- 229920000728 polyester Polymers 0.000 claims abstract description 21
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 18
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 18
- 239000000835 fiber Substances 0.000 claims abstract description 16
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- 239000004753 textile Substances 0.000 claims abstract description 7
- 239000012798 spherical particle Substances 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 45
- 230000008569 process Effects 0.000 claims description 41
- 229920006346 thermoplastic polyester elastomer Polymers 0.000 claims description 29
- 239000000806 elastomer Substances 0.000 claims description 17
- 230000003014 reinforcing effect Effects 0.000 claims description 15
- 239000004744 fabric Substances 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 9
- -1 polyethylene terephthalate Polymers 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 5
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 5
- 230000005484 gravity Effects 0.000 claims description 3
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 238000005187 foaming Methods 0.000 description 15
- 239000000203 mixture Substances 0.000 description 14
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 8
- 239000003963 antioxidant agent Substances 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 6
- 239000002699 waste material Substances 0.000 description 6
- 239000005062 Polybutadiene Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 229920000578 graft copolymer Polymers 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 229920002857 polybutadiene Polymers 0.000 description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 4
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 4
- 239000004831 Hot glue Substances 0.000 description 4
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 4
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 238000005453 pelletization Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 2
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 2
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- 239000005662 Paraffin oil Substances 0.000 description 2
- 229920005557 bromobutyl Polymers 0.000 description 2
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 2
- 229920005549 butyl rubber Polymers 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000007731 hot pressing Methods 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- RQNVJDSEWRGEQR-UHFFFAOYSA-N tris(prop-2-enyl) borate Chemical compound C=CCOB(OCC=C)OCC=C RQNVJDSEWRGEQR-UHFFFAOYSA-N 0.000 description 2
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- BGQAZAHWMRSYGG-UHFFFAOYSA-N CCCCO.CC(=C)C(O)=O.CC(=C)C(O)=O.CC(=C)C(O)=O Chemical compound CCCCO.CC(=C)C(O)=O.CC(=C)C(O)=O.CC(=C)C(O)=O BGQAZAHWMRSYGG-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Polymers OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920000954 Polyglycolide Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000000386 athletic effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 229920001912 maleic anhydride grafted polyethylene Polymers 0.000 description 1
- 229920001910 maleic anhydride grafted polyolefin Polymers 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000012758 reinforcing additive Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920006249 styrenic copolymer Polymers 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 238000009965 tatting Methods 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B5/00—Footwear for sporting purposes
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/12—Soles with several layers of different materials
- A43B13/125—Soles with several layers of different materials characterised by the midsole or middle layer
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
- A43B13/18—Resilient soles
- A43B13/187—Resiliency achieved by the features of the material, e.g. foam, non liquid materials
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
- A43B23/02—Uppers; Boot legs
- A43B23/0205—Uppers; Boot legs characterised by the material
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
Description
本發明是關於運動鞋,特別是關於一種由熱塑性材料製造的運動鞋。The present invention relates to sports shoes, in particular to a sports shoe made of thermoplastic material.
傳統的運動鞋包括鞋面、鞋底以及將鞋面與鞋底連接在一起的黏著部件。傳統的鞋面可包括皮革、合成革、紡織物、或其組合。傳統的鞋底包括中底以及大底,其中中底可包括乙烯/醋酸乙烯酯共聚物(EVA)而大底可包括橡膠、聚氯乙烯(PVC)、聚氨酯(PU)或其組合。Traditional sports shoes include uppers, soles, and adhesive components that connect the uppers and soles together. Traditional uppers may include leather, synthetic leather, textiles, or combinations thereof. Traditional shoe soles include a midsole and an outsole, where the midsole may include ethylene/vinyl acetate copolymer (EVA) and the outsole may include rubber, polyvinyl chloride (PVC), polyurethane (PU), or a combination thereof.
傳統運動鞋的鞋面、中底與大底中包含的材料不同。因此傳統的廢棄運動鞋的處理方式需包括在粉碎製程、回收製程或焚燒製程之前將廢棄運動鞋的鞋面、中底與大底等各部件分離的分離製程。上述傳統的廢棄運動鞋的處理方式具有程序繁複、回收效率不佳且不環保的缺點。The materials contained in the upper, midsole and outsole of traditional sports shoes are different. Therefore, the traditional treatment method of discarded sports shoes must include a separation process to separate the upper, midsole and outsole of discarded sports shoes before the crushing process, recycling process or incineration process. The above traditional treatment method of discarded sports shoes has the disadvantages of complicated procedures, poor recycling efficiency and environmental protection.
本揭露提供無需分離廢棄運動鞋的各部件即可回收的一種運動鞋。廢棄運動鞋可經過回收生成一再生材料,該再生材料可用於製造一運動鞋。The present disclosure provides a sneaker that can be recycled without separating the components of discarded sneakers. Discarded sports shoes can be recycled to generate a recycled material, which can be used to manufacture a sports shoe.
本揭露的一些實施例提供一種運動鞋,其包括鞋面以及與鞋面連接的鞋底。所述鞋面可包括織物部件,其中織物部件可包括熱塑性聚酯纖維。所述鞋底可包括鞋大底及設置於鞋大底與鞋面之間的鞋中底發泡體。鞋大底可包括動態交聯彈性體且鞋中底發泡體可包括第一熱塑性彈性體。所述動態交聯彈性體可包括橡膠粒子、第二熱塑性彈性體、以及界面相容樹脂,其中橡膠粒子的含量大於第二熱塑性彈性體的含量,且橡膠粒子以粒徑約0.5~10μm的球狀顆粒形式分散在第二熱塑性彈性體中。Some embodiments of the present disclosure provide a sports shoe, which includes an upper and a sole connected to the upper. The upper may include a textile component, wherein the textile component may include thermoplastic polyester fibers. The shoe sole may include a shoe outsole and a shoe midsole foam disposed between the shoe outsole and the shoe upper. The outsole may include a dynamically cross-linked elastomer and the midsole foam may include the first thermoplastic elastomer. The dynamically cross-linked elastomer may include rubber particles, a second thermoplastic elastomer, and an interface compatible resin, wherein the content of the rubber particles is greater than the content of the second thermoplastic elastomer, and the rubber particles are in the form of balls with a particle size of about 0.5 to 10 μm. The particles are dispersed in the second thermoplastic elastomer.
本揭露中使用的「約」係指包含所述值以及在以所屬技術領域具有通常知識者考慮到測量問題及測量誤差(亦即,測量系統的限制性)時的可接受偏差範圍中的值。舉例而言,「約」可表示在所述值的一或多個標準偏差之中或在所述值的± 30%、20%、10%、5%之中的值。在此給定的數量為大約的數量,亦即在沒有特定說明「約」、「大約」、「實質上」的情況下,仍可隱含「約」、「大約」、「實質上」之含義。在本揭露中,「a~b」之表述表示包括大於等於a的值以及小於等於b的值。As used in this disclosure, "about" means a value that encompasses the stated value and a range of acceptable deviations that would be acceptable to a person of ordinary skill in the art taking into account measurement issues and measurement errors (ie, limitations of the measurement system). . For example, "about" can mean a value that is within one or more standard deviations of the stated value, or within ±30%, 20%, 10%, 5% of the stated value. The quantities given here are approximate quantities. That is to say, without specifically stating "about", "approximately" and "substantially", the terms "about", "approximately" and "substantially" can still be implied. meaning. In this disclosure, the expression "a~b" means including values greater than or equal to a and values less than or equal to b.
能理解的是,雖然在此可使用用語「第一」、「第二」、「第三」等來敘述各種元件、組成成分、區域、層、及/或部分,這些元件、組成成分、區域、層、及/或部分不應被這些用語限定,且這些用語僅是用來區別不同的元件、組成成分、區域、層、及/或部分。因此,以下討論的一第一元件、組成成分、區域、層、及/或部分可在不偏離本揭露一些實施例之教示的情況下被稱為一第二元件、組成成分、區域、層、及/或部分。It is understood that, although the terms "first", "second", "third", etc. may be used herein to describe various elements, components, regions, layers, and/or parts, these elements, components, regions, layers, and/or parts should not be limited by these terms, and these terms are only used to distinguish different elements, components, regions, layers, and/or parts. Therefore, a first element, component, region, layer, and/or part discussed below may be referred to as a second element, component, region, layer, and/or part without departing from the teachings of some embodiments of the present disclosure.
在本揭露一些實施例中,相對性的用語例如「下」、「上」、「水平」、「垂直」、「之下」、「之上」、「頂部」、「底部」等等應被理解為該段以及相關圖式中所繪示的方位。此相對性的用語僅是為了方便說明之用,其並不代表其所敘述之裝置需以特定方位來製造或運作。可理解的是,如果將附圖的裝置翻轉使其上下顛倒,則所敘述在「下」側的元件將會成為在「上」側的元件。本揭露的實施例可配合附圖一併理解,本揭露的附圖亦被視為說明書的一部分。應理解的是,本揭露的附圖並未按照比例繪製,事實上,可能任意的放大或縮小元件的尺寸以便清楚表現出本揭露的特徵。In some embodiments of the present disclosure, relative terms such as “lower”, “upper”, “horizontal”, “vertical”, “below”, “above”, “top”, “bottom”, etc. shall be Understand the orientation shown in this paragraph and related figures. This relative terminology is only for convenience of explanation and does not mean that the device described needs to be manufactured or operated in a specific orientation. It will be understood that if the device in the figures is turned upside down, elements described as being on the "lower" side would actually be elements described as being on the "upper" side. The embodiments of the present disclosure can be understood together with the accompanying drawings, which are also considered a part of the specification. It is to be understood that the drawings of the present disclosure are not drawn to scale and, in fact, the dimensions of elements may be arbitrarily exaggerated or reduced in order to clearly illustrate features of the present disclosure.
除非另有定義,否則本文所用之所有用語(包含技術與科學用語)具有與本揭露所屬技術領域中具有通常知識者所通常理解的意義相同之含義。將進一步理解的是,定義於常用字典內之用語,應被解釋為具有與其在相關技術及本揭露的內容意思一致之意思,以及除非明確地於此定義,否則將不以理想化或過於正式的意義解釋。Unless otherwise defined, all terms used herein (including technical and scientific terms) have the same meaning as commonly understood by those with ordinary knowledge in the art to which the present disclosure belongs. It will be further understood that terms defined in commonly used dictionaries should be interpreted as having the same meaning as their meaning in the relevant art and the content of the present disclosure, and will not be interpreted in an idealized or overly formal sense unless explicitly defined herein.
本揭露的用語「熱塑性聚酯彈性體(TPEE)」是指由包括聚對苯二甲酸丁二醇酯(PBT)的硬鏈段和包括聚醚或聚酯的軟鏈段所構成的嵌段式共聚聚合物。聚醚型聚酯彈性體中的軟鏈段的實例可包括但不限於聚四亞甲基醚二醇、聚乙二醇醚、聚丙二醇醚。聚酯型聚酯彈性體中的軟鏈段的實例可包括但不限於聚乙交酯、聚丙交酯、聚已內酯。The term "thermoplastic polyester elastomer (TPEE)" disclosed herein refers to a block copolymer composed of a hard segment including polybutylene terephthalate (PBT) and a soft segment including polyether or polyester. Examples of soft segments in polyether-type polyester elastomers may include, but are not limited to, polytetramethylene ether glycol, polyethylene glycol ether, and polypropylene glycol ether. Examples of soft segments in polyester-type polyester elastomers may include, but are not limited to, polyglycolide, polylactide, and polycaprolactone.
本揭露提供一種運動鞋,其包括鞋面以及與鞋面連接的鞋底。第1圖是根據本揭露一實施例的運動鞋10的爆炸圖。如第1圖所示,運動鞋10包括鞋面101以及與鞋面101連接的鞋底103。以下參照第1圖分別說明本揭露的鞋面101以及鞋底103。The present disclosure provides a sports shoe, which includes an upper and a sole connected to the upper. Figure 1 is an exploded view of a sports shoe 10 according to an embodiment of the present disclosure. As shown in FIG. 1 , the sports shoe 10 includes an upper 101 and a sole 103 connected to the upper 101 . The upper 101 and the sole 103 of the present disclosure will be described below with reference to Figure 1 .
如第1圖所示,鞋底103包括鞋大底1031以及設置於鞋大底1031與鞋面101之間的鞋中底發泡體1033。鞋中底發泡體1033可提供緩衝、回彈以及高舒適度等功能。鞋大底1031具有高耐磨耗性以及高濕止滑性的優點,並可將步行時施加之應力高效率地轉變成動能。As shown in FIG. 1 , the sole 103 includes an outsole 1031 and a midsole foam 1033 disposed between the outsole 1031 and the upper 101. The midsole foam 1033 can provide functions such as cushioning, rebound, and high comfort. The outsole 1031 has the advantages of high wear resistance and high wet anti-slip properties, and can efficiently convert the stress applied during walking into kinetic energy.
在一些實施例中,鞋中底發泡體1033可具有約0.1~0.4g/mL的比重、約50~70%的回彈性、以及約30~60邵氏C硬度的表面硬度。鞋中底發泡體1033包括第一熱塑性彈性體。在一些實施例中,第一熱塑性彈性體可具有約0.8~1.9dL/g的本質黏度(intrinsic viscosity, I.V.)以及約60~95的邵氏A硬度。In some embodiments, the midsole foam 1033 may have a specific gravity of about 0.1-0.4 g/mL, a resilience of about 50-70%, and a surface hardness of about 30-60 Shore C hardness. The midsole foam 1033 includes a first thermoplastic elastomer. In some embodiments, the first thermoplastic elastomer may have an intrinsic viscosity (I.V.) of about 0.8-1.9 dL/g and a Shore A hardness of about 60-95.
在一些實施例中,第一熱塑性彈性體可包括熱塑性聚酯彈性體(TPEE)。在一些實施例中,第一熱塑性彈性體可包括第一再生熱塑性彈性體或可由第一再生熱塑性彈性體所組成。在一些實施例中,第一再生熱塑性彈性體可來自於廢棄的運動鞋,但本揭露不限於此。在一些實施例中,第一再生熱塑性彈性體可自廢棄的聚對苯二甲酸乙二酯(r-PET)經過化學解聚製程以及共聚合製程製得,且製得之第一再生熱塑性彈性體可具有約0.8~1.9dL/g的本質黏度以及約45~95的邵氏A硬度。在一些實施例中,所述第一再生熱塑性彈性體可具有約60~95的邵氏A硬度。In some embodiments, the first thermoplastic elastomer may include thermoplastic polyester elastomer (TPEE). In some embodiments, the first thermoplastic elastomer may include or may consist of the first regenerated thermoplastic elastomer. In some embodiments, the first recycled thermoplastic elastomer may be from discarded sneakers, but the disclosure is not limited thereto. In some embodiments, the first regenerated thermoplastic elastomer can be produced from discarded polyethylene terephthalate (r-PET) through a chemical depolymerization process and a copolymerization process, and the first regenerated thermoplastic elastomer is The body may have an intrinsic viscosity of about 0.8 to 1.9 dL/g and a Shore A hardness of about 45 to 95. In some embodiments, the first regenerated thermoplastic elastomer may have a Shore A hardness of about 60 to 95.
在一些實施例中,鞋中底發泡體1033是使第一熱塑性彈性體經過射出發泡製程、化學押出發泡製程、模壓發泡製程、含浸發泡製程、或前述製程的任意組合製得。具體而言,在一些實施例中,鞋中底發泡體1033的製造過程包括製備第一混合物、製備第一粒子以及使第一粒子發泡之步驟。在一些實施例中,第一混合物可包括第一熱塑性彈性體、泡孔成核劑、泡孔穩定劑、以及其他添加劑。在一些實施例中,其他添加劑可包括流動助劑及/或抗氧化劑,但本揭露不限於此。在一些實施例中,第一粒子可透過使第一混合物經過混煉製程以及切粒製程而製得。鞋中底發泡體1033可透過使第一粒子經過化學發泡製程或物理發泡製程製得。所述之化學發泡製程或物理發泡製程可包括射出發泡製程、化學押出發泡製程、模壓發泡製程、含浸發泡製程、其他適合的發泡製程、或前述製程的任意組合。In some embodiments, the midsole foam 1033 is made by subjecting the first thermoplastic elastomer to an injection foaming process, a chemical extrusion foaming process, a molded foaming process, an impregnation foaming process, or any combination of the foregoing processes. . Specifically, in some embodiments, the manufacturing process of the shoe midsole foam 1033 includes the steps of preparing a first mixture, preparing first particles, and foaming the first particles. In some embodiments, the first mixture may include a first thermoplastic elastomer, a cell nucleating agent, a cell stabilizer, and other additives. In some embodiments, other additives may include flow aids and/or antioxidants, but the disclosure is not limited thereto. In some embodiments, the first particles can be produced by subjecting the first mixture to a mixing process and a pelletizing process. The shoe midsole foam 1033 can be produced by subjecting the first particles to a chemical foaming process or a physical foaming process. The chemical foaming process or physical foaming process may include an injection foaming process, a chemical extrusion foaming process, a molded foaming process, an impregnation foaming process, other suitable foaming processes, or any combination of the foregoing processes.
在一些實施例中,鞋大底1031具有約50~250mg的耐磨耗量以及約0.2~0.45的濕止滑係數。在一些實施例中,鞋大底1031包括動態交聯彈性體。鞋大底1031具是所述動態交聯彈性體經過射出成形製程、擠出成形製程、熱壓成形製程、或前述製程的任意組合製得的。In some embodiments, the outsole 1031 has an abrasion resistance of about 50-250 mg and a wet anti-slip coefficient of about 0.2-0.45. In some embodiments, the outsole 1031 includes a dynamically cross-linked elastomer. The outsole 1031 is made by the dynamically cross-linked elastomer through an injection molding process, an extrusion molding process, a hot pressing process, or any combination of the aforementioned processes.
所述動態交聯彈性體可包括橡膠粒子、第二熱塑性彈性體、以及界面相容樹脂,但本揭露不限於此。在一些實施例中,橡膠粒子的含量大於第二熱塑性彈性體的含量,且橡膠粒子係以粒徑約0.5~10μm的球狀顆粒形式分散在第二熱塑性彈性體中。在一些實施例中,橡膠粒子係以粒徑約0.5~5μm的球狀顆粒形式分散在第二熱塑性彈性體中。在一些實施例中,所述動態交聯彈性體可包括約100重量份的橡膠粒子、約40~90重量份的第二熱塑性彈性體、以及約5~15重量份的界面相容樹脂(即以100重量份的橡膠為基礎,約40~90重量份的第二熱塑性彈性體以及約5~15重量份的界面相容樹脂)。在一些實施例中,所述動態交聯彈性體可包括100重量份的橡膠粒子、約50~80重量份的第二熱塑性彈性體、以及約8~12重量份的界面相容樹脂(即以100重量份的橡膠為基礎,約50~80重量份的第二熱塑性彈性體以及約8~12重量份的界面相容樹脂)。The dynamically cross-linked elastomer may include rubber particles, a second thermoplastic elastomer, and an interface compatible resin, but the present disclosure is not limited thereto. In some embodiments, the content of rubber particles is greater than the content of the second thermoplastic elastomer, and the rubber particles are dispersed in the second thermoplastic elastomer in the form of spherical particles with a particle size of about 0.5 to 10 μm. In some embodiments, the rubber particles are dispersed in the second thermoplastic elastomer in the form of spherical particles with a particle size of about 0.5 to 5 μm. In some embodiments, the dynamically cross-linked elastomer may include about 100 parts by weight of rubber particles, about 40-90 parts by weight of the second thermoplastic elastomer, and about 5-15 parts by weight of an interface compatible resin (i.e. Based on 100 parts by weight of rubber, about 40 to 90 parts by weight of the second thermoplastic elastomer and about 5 to 15 parts by weight of the interface compatible resin). In some embodiments, the dynamically cross-linked elastomer may include 100 parts by weight of rubber particles, about 50 to 80 parts by weight of a second thermoplastic elastomer, and about 8 to 12 parts by weight of an interface compatible resin (i.e., based on Based on 100 parts by weight of rubber, about 50 to 80 parts by weight of the second thermoplastic elastomer and about 8 to 12 parts by weight of the interface compatible resin).
在一些實施例中,第二熱塑性彈性體可具有約45~70的邵氏A硬度以及 約0.8~1.9dL/g的本質黏度。在一些實施例中,第二熱塑性彈性體可包括熱塑性聚酯彈性體(TPEE)。在一些實施例中,第二熱塑性彈性體包括第二再生熱塑性彈性體。在一些實施例中,第二再生熱塑性彈性體可來自於廢棄的運動鞋或其他熱塑性廢棄物。In some embodiments, the second thermoplastic elastomer may have a Shore A hardness of about 45-70 and an intrinsic viscosity of about 0.8-1.9 dL/g. In some embodiments, the second thermoplastic elastomer may include a thermoplastic polyester elastomer (TPEE). In some embodiments, the second thermoplastic elastomer includes a second recycled thermoplastic elastomer. In some embodiments, the second recycled thermoplastic elastomer may come from discarded sports shoes or other thermoplastic waste.
在一些實施例中,橡膠粒子可在製備第二混合物後,透過使第二混合物經過混煉製程、捏合製程以及切粒製程而製得。所述第二混合物可包括苯乙烯共聚物橡膠、交聯劑、以及交聯助劑,但本揭露不限於此。In some embodiments, rubber particles can be produced by subjecting the second mixture to a mixing process, a kneading process, and a pelletizing process after preparing the second mixture. The second mixture may include styrenic copolymer rubber, a cross-linking agent, and a cross-linking assistant, but the present disclosure is not limited thereto.
所述交聯劑可包括2,5-二甲基-2,5-二(三級丁過氧)己烷(2,5-bis(tert-butylperoxy)-2,5- dimethylhexane)、過氧化二異丙苯(dicumyl peroxide, DCP)、苯醯過氧化物 (benzoyl peroxide)、二(三級丁基)過氧化物(di-tert-butyl peroxide)中的其一或其任意組合,但本揭露不限於此。The crosslinking agent may include 2,5-dimethyl-2,5-di(tert-butylperoxy)-2,5-dimethylhexane, dicumyl peroxide (DCP), benzoyl peroxide, di-tert-butyl peroxide, or any combination thereof, but the present disclosure is not limited thereto.
所述交聯助劑可包括三羥甲基丙烷三甲基丙烯酸酯(trimethylolpropane trimethacrylate, TMPTMA)、三烯丙基異三聚氰酸酯(triallyl isocyanurate, TAIC)、三羥甲基丙烷三丙烯酸酯(trimethylolpropane triacrylate, TMPTA)、三烯丙基三聚氰酸酯(triallyl cyanurate, TAC)、 亞磷酸三烯丙酯(triallylphosphate, TAP)與硼酸三烯丙酯(triallyl borate, TAB) 中的其一或其任意組合,但本揭露不限於此。The cross-linking assistant may include trimethylolpropane trimethacrylate (TMPTMA), triallyl isocyanurate (TAIC), trimethylolpropane triacrylate One of (trimethylolpropane triacrylate, TMPTA), triallyl cyanurate (TAC), triallylphosphate (TAP), or triallyl borate (TAB) or any combination thereof, but the disclosure is not limited thereto.
所述之苯乙烯共聚物橡膠可為其中包括苯乙烯基的任意共聚物。在一些實施例中,苯乙烯共聚物橡膠可包括具有高止滑特性的交聯苯乙烯共聚物。在一些實施例中,苯乙烯共聚物橡膠可包括溶聚苯乙烯-丁二烯橡膠(SSBR)、乳聚苯乙烯-丁二烯橡膠(ESBR)、苯乙烯-乙烯-丁烯-苯乙烯(SEBS)橡膠、苯乙烯-乙烯-丙烯-苯乙烯(SEPS)橡膠、苯乙烯-丁二烯(SB)橡膠、苯乙烯-異戊二烯-苯乙烯(SIS)橡膠、苯乙烯-丁二烯-苯乙烯(SBS)橡膠中的其一或其任意組合,但本揭露不限於此。The styrene copolymer rubber may be any copolymer including a styrene group. In some embodiments, the styrene copolymer rubber may include a cross-linked styrene copolymer having high anti-slip properties. In some embodiments, the styrene copolymer rubber may include a solution polystyrene-butadiene rubber (SSBR), an emulsion polystyrene-butadiene rubber (ESBR), a styrene-ethylene-butylene-styrene (SEBS) rubber, a styrene-ethylene-propylene-styrene (SEPS) rubber, a styrene-butadiene (SB) rubber, a styrene-isoprene-styrene (SIS) rubber, a styrene-butadiene-styrene (SBS) rubber, or any combination thereof, but the present disclosure is not limited thereto.
在一些實施例中,第二混合物可進一步包括非芳香族橡膠。所述之非芳香族橡膠為其中不包括芳香基的橡膠。在一些實施例中,非芳香族橡膠可包括丁二烯橡膠(BR)、丁基橡膠(IIR)、溴化丁基橡膠(BIIR)、天然橡膠(NR)中的其一或其任意組合,但本揭露不限於此。非芳香族橡膠可進一步提高包含耐磨性能、耐候性能與耐壓縮變形性能。在一些實施例中,第二混合物可包括約100~80重量份的苯乙烯共聚物橡膠與約0~20重量份的非芳香族橡膠 (即苯乙烯共聚物橡膠:非芳香族橡膠的重量比為10~8:0~2)。在一些實施例中,第二混合物可進一步包括其他添加劑。其他添加劑可包括補強添加物、抗氧化劑、塑化劑、與矽烷偶聯劑中的其一或其任意組合,但本揭露不限於此。In some embodiments, the second mixture may further include non-aromatic rubber. The non-aromatic rubber is a rubber that does not include an aromatic group. In some embodiments, the non-aromatic rubber may include one of butadiene rubber (BR), butyl rubber (IIR), brominated butyl rubber (BIIR), natural rubber (NR) or any combination thereof, but the present disclosure is not limited thereto. Non-aromatic rubber can further improve the wear resistance, weather resistance and compression deformation resistance. In some embodiments, the second mixture may include about 100 to 80 parts by weight of styrene copolymer rubber and about 0 to 20 parts by weight of non-aromatic rubber (i.e., the weight ratio of styrene copolymer rubber: non-aromatic rubber is 10 to 8: 0 to 2). In some embodiments, the second mixture may further include other additives. Other additives may include one or any combination of reinforcing additives, antioxidants, plasticizers, and silane coupling agents, but the present disclosure is not limited thereto.
界面相容樹脂可包括可使橡膠粒子與界面相容樹脂相容的任意樹脂。在一些實施例中,界面相容樹脂可包括馬來酸酐接枝聚合物(maleic anhydride grafted polymer),但本揭露不限於此。The interface-compatible resin may include any resin that can make the rubber particles compatible with the interface-compatible resin. In some embodiments, the interface compatible resin may include maleic anhydride grafted polymer, but the present disclosure is not limited thereto.
馬來酸酐接枝聚合物的實例可包括但不限於馬來酸酐接枝聚乙烯(PE-MAH)、馬來酸酐接枝乙烯-醋酸乙烯酯共聚物(EVA-MAH)、馬來酸酐接枝聚烯烴彈性體(POE-MAH)、馬來酸酐接枝三元乙丙橡膠(EPDM-MAH)、馬來酸酐接枝苯乙烯-乙烯-丁烯-苯乙烯橡膠(SEBS-MAH)與苯乙烯馬來酸酐(SMA),但本揭露不限於此。Examples of maleic anhydride grafted polymers may include, but are not limited to, maleic anhydride grafted polyethylene (PE-MAH), maleic anhydride grafted ethylene-vinyl acetate copolymer (EVA-MAH), maleic anhydride grafted Polyolefin elastomer (POE-MAH), maleic anhydride grafted ethylene propylene diene rubber (EPDM-MAH), maleic anhydride grafted styrene-ethylene-butylene-styrene rubber (SEBS-MAH) and styrene Maleic anhydride (SMA), but the present disclosure is not limited thereto.
在一些實施例中,馬來酸酐接枝聚合物的接枝率為約0.3~2.0%。當馬來酸酐接枝聚合物的接枝率低於約0.3%時,第二熱塑性彈性體可能無法順利進行完整化的接枝反應,且第二熱塑性彈性體與橡膠粒子之相容性可能無法提高。當馬來酸酐接枝聚合物的接枝率高於約2.0 %時,橡膠粒子與第二熱塑性彈性體可能會過度相容,影響後續動態交聯相反轉行為。In some embodiments, the grafting rate of the maleic anhydride grafted polymer is about 0.3-2.0%. When the grafting rate of the maleic anhydride grafted polymer is lower than about 0.3%, the second thermoplastic elastomer may not be able to smoothly undergo a complete grafting reaction, and the compatibility of the second thermoplastic elastomer with the rubber particles may not be improved. When the grafting rate of the maleic anhydride grafted polymer is higher than about 2.0%, the rubber particles and the second thermoplastic elastomer may be overly compatible, affecting the subsequent dynamic crosslinking phase reversal behavior.
在一些實施例中,鞋大底1031可透過聚酯熱熔膠連接鞋中底發泡體1033,但本揭露不限於此。在一些實施例中,鞋大底1031可利用射出成形製程,射出至鞋中底發泡體1033,並透過射出製程期間的高溫直接與鞋中底發泡體1033熱熔貼合而無需使用其他連接劑。In some embodiments, the outsole 1031 can be connected to the midsole foam 1033 by polyester hot melt adhesive, but the present disclosure is not limited thereto. In some embodiments, the outsole 1031 can be injected into the midsole foam 1033 by injection molding process, and directly hot melt bonded to the midsole foam 1033 by the high temperature during the injection process without using other connecting agents.
在一些實施例中,鞋底103可進一步包括設置於鞋面101與鞋中底發泡體1033之間補強平衡片1035。補強平衡片1035可強化鞋底103的抗彎曲強度,同時改善穿著時足弓的舒適程度。補強平衡片1035可包括第三熱塑性彈性體。在一些實施例中,第三熱塑性彈性體可具有約0.8~1.5dL/g的本質黏度以及約40~60的邵氏D硬度。在一些實施例中,第三熱塑性彈性體可包括熱塑性聚酯彈性體(TPEE)。在一些實施例中,在一些實施例中,第三熱塑性彈性體可來自於廢棄的運動鞋或其他熱塑性廢棄物。在一些實施例中,補強平衡片1035可利用該第三熱塑性彈性體,以射出成形製程、擠出成形製程、熱壓成形製程、或前述製程的任意組合製得。In some embodiments, the sole 103 may further include a reinforcing balance sheet 1035 disposed between the upper 101 and the midsole foam 1033 . The reinforcing balance piece 1035 can enhance the bending resistance of the sole 103 and improve the comfort of the arch of the foot when wearing. The reinforcing balance sheet 1035 may include a third thermoplastic elastomer. In some embodiments, the third thermoplastic elastomer may have an intrinsic viscosity of about 0.8-1.5 dL/g and a Shore D hardness of about 40-60. In some embodiments, the third thermoplastic elastomer may include thermoplastic polyester elastomer (TPEE). In some embodiments, the third thermoplastic elastomer may be sourced from discarded sneakers or other thermoplastic waste. In some embodiments, the reinforcing balance sheet 1035 can be made by using the third thermoplastic elastomer through an injection molding process, an extrusion molding process, a hot press molding process, or any combination of the foregoing processes.
在一些實施例中,鞋底103可進一步包括設置於補強平衡片1035與鞋面101之間的鞋墊1037。鞋墊1037可為發泡體,其具有高柔軟度以提高舒適度。在一些實施例中,鞋墊1037可包括熱塑性聚酯彈性體(TPEE)。在一些實施例中,在一些實施例中,鞋墊1037可包括來自於廢棄的運動鞋或其他熱塑性廢棄物的再生材料。In some embodiments, the sole 103 may further include an insole 1037 disposed between the reinforcing balance sheet 1035 and the upper 101 . The insole 1037 may be foam, which has high softness to improve comfort. In some embodiments, insole 1037 may include thermoplastic polyester elastomer (TPEE). In some embodiments, insole 1037 may include recycled materials from discarded athletic shoes or other thermoplastic waste.
鞋面101包括織物部件1011,且織物部件1011可包括熱塑性聚酯纖維。在一些實施例中,熱塑性聚酯纖維可為來自於廢棄的運動鞋或其他熱塑性廢棄物的再生熱塑性聚酯纖維。在一些實施例中,熱塑性聚酯纖維可約50~150丹尼且具有約0.4~0.8dL/g的本質黏度。織物部件1011可為由熱塑性聚酯纖維製成的編織部件、針織部件、無紡部件、紡織部件、或前述部件的其任意組合,但本揭露不限於此。在一些實施例中,織物部件1011可進一步包括第四熱塑性彈性體。在一些實施例中,第四熱塑性彈性體可約50~150丹尼且具有約50~90的邵氏D硬度。在一些實施例中,第四熱塑性彈性體可包括熱塑性聚酯彈性體(TPEE)。在一些實施例中,第四熱塑性彈性體與熱塑性聚酯纖維之重量比為1:4~3:2在一些實施例中,在一些實施例中,第四熱塑性彈性體可來自於廢棄的運動鞋或其他熱塑性廢棄物。織物部件1011可為由熱塑性聚酯纖維與第四熱塑性彈性體製成的編織部件、針織部件、無紡部件、紡織部件、或前述部件的其任意組合。The upper 101 includes a fabric component 1011, and the fabric component 1011 may include thermoplastic polyester fiber. In some embodiments, the thermoplastic polyester fiber may be recycled thermoplastic polyester fiber from discarded sports shoes or other thermoplastic waste. In some embodiments, the thermoplastic polyester fiber may be about 50-150 denier and have an intrinsic viscosity of about 0.4-0.8 dL/g. The fabric component 1011 may be a woven component, a knitted component, a nonwoven component, a woven component, or any combination thereof made of thermoplastic polyester fiber, but the present disclosure is not limited thereto. In some embodiments, the fabric component 1011 may further include a fourth thermoplastic elastomer. In some embodiments, the fourth thermoplastic elastomer may be about 50-150 denier and have a Shore D hardness of about 50-90. In some embodiments, the fourth thermoplastic elastomer may include thermoplastic polyester elastomer (TPEE). In some embodiments, the weight ratio of the fourth thermoplastic elastomer to the thermoplastic polyester fiber is 1:4-3:2. In some embodiments, in some embodiments, the fourth thermoplastic elastomer may come from discarded sports shoes or other thermoplastic waste. The fabric component 1011 may be a woven component, a knitted component, a nonwoven component, a textile component, or any combination thereof made of thermoplastic polyester fiber and the fourth thermoplastic elastomer.
鞋面101可進一步包括設置於織物部件1011邊緣的補強部件1013,補強部件1013可提升鞋面101的整體強度,降低鞋面101破損的可能性。在一些實施例中,補強部件1013可包括第五熱塑性彈性體。第五熱塑性彈性體可具有約0.8~1.5dL/g的本質黏度以及約80~95的邵氏A硬度或約40~60的邵氏D硬度。在一些實施例中,第五熱塑性彈性體可包括熱塑性聚酯彈性體(TPEE)。在一些實施例中,在一些實施例中,第五熱塑性彈性體可來自於廢棄的運動鞋或其他熱塑性廢棄物。The upper 101 may further include a reinforcing component 1013 disposed on the edge of the fabric component 1011. The reinforcing component 1013 may improve the overall strength of the upper 101 and reduce the possibility of damage to the upper 101. In some embodiments, reinforcing component 1013 may include a fifth thermoplastic elastomer. The fifth thermoplastic elastomer may have an intrinsic viscosity of about 0.8-1.5 dL/g and a Shore A hardness of about 80-95 or a Shore D hardness of about 40-60. In some embodiments, the fifth thermoplastic elastomer may include thermoplastic polyester elastomer (TPEE). In some embodiments, the fifth thermoplastic elastomer may be sourced from discarded sneakers or other thermoplastic waste.
鞋面101與鞋底103可分別製得。在一些實施例中,鞋面101與鞋底103可透過聚酯熱熔膠連接,但本揭露不限於此。在一些實施例中,鞋面101與鞋底103可透過加熱連接製程熔化鞋面101與鞋底103的界面後,連接鞋面101與鞋底103。透過使運動鞋10的各部件皆包括聚酯材料,本揭露的運動鞋10可直接進行物理性粉碎的回收製程而無需先經過分離運動鞋的各部件的分離製程。The upper 101 and the sole 103 can be made separately. In some embodiments, the upper 101 and the sole 103 can be connected by polyester hot melt adhesive, but the present disclosure is not limited thereto. In some embodiments, the upper 101 and the sole 103 can be connected by melting the interface of the upper 101 and the sole 103 through a heating connection process. By making all the components of the sports shoe 10 include polyester materials, the sports shoe 10 of the present disclosure can be directly subjected to a physical crushing recycling process without first undergoing a separation process of separating the components of the sports shoe.
以下透過提供具體實施例來說明本揭露的優點。The following illustrates the advantages of the present disclosure by providing specific embodiments.
實施例1Example 1
1.鞋面製備1. Upper preparation
取纖維規格約50~150丹尼且具有約0.4~0.8dL/g的本質黏度的聚對苯二甲酸乙二酯纖維或再生聚對苯二甲酸乙二酯纖維(購自南亞塑膠工業股份有限公司)與纖維規格約50~150丹尼且具有約60~80的邵氏D硬度的熱塑性聚酯彈性體纖維(購自力泰國際股份有限公司),運用梭織法將其製成織物部件。Take polyethylene terephthalate fiber or recycled polyethylene terephthalate fiber with a fiber specification of about 50 to 150 denier and an intrinsic viscosity of about 0.4 to 0.8 dL/g (purchased from Nan Ya Plastics Industry Co., Ltd. Company) and thermoplastic polyester elastomer fiber (purchased from Litai International Co., Ltd.) with a fiber specification of about 50 to 150 denier and a Shore D hardness of about 60 to 80, using a tatting method to make fabric parts.
將具有約0.8~1.5dL/g的本質黏度以及約80~95的邵氏A硬度或約40~60的邵氏D硬度的熱塑性聚酯彈性體(購自杜邦公司)透過薄膜(片材)押出加工成形的方式製得補強部件,並將補強部件以熱壓貼合的方式連接於上述織物部件的邊緣以完成鞋面的製備。A thermoplastic polyester elastomer (purchased from DuPont) having an intrinsic viscosity of about 0.8-1.5 dL/g and a Shore A hardness of about 80-95 or a Shore D hardness of about 40-60 is formed into a reinforcing component by film (sheet) extrusion processing, and the reinforcing component is connected to the edge of the above-mentioned textile component by hot pressing bonding to complete the preparation of the shoe upper.
2.鞋底製備2.Sole preparation
將硬度範圍約60~95邵氏A硬度,本質黏度約0.8~1.9 dL/g的熱塑性聚酯彈性體粒子(購自DSM公司)以約60~80°C進行預乾燥約3~4小時。將約0.5重量份的抗氧化劑配方(受阻酚類抗氧化劑AO1010與亞磷酸酯抗氧劑A168 各0.25重量份)、約0.5重量份的泡孔成核劑配方(奈米碳酸鈣)、約2.0重量份的泡孔穩定劑配方(多官能擴鏈劑 ADR-4370)與約1.0重量份的流動助劑配方(硬酯酸鹽)與約100重量份的乾燥後熱塑性聚酯彈性體粒子混合以獲得中底混合物。將中底混合物以失重進料的方式投入雙螺桿押出機中(25ψ, L/D=45)進行混煉(螺桿溫度約170~200°C,轉速約150~300 rpm)。使混煉後的中底混合物經過切粒製程以獲得中底粒子。將中底粒子在約80~100℃下乾燥約6~8小時。最後透過化學或物理發泡方式自中底粒子製得鞋中底發泡體。Thermoplastic polyester elastomer particles (purchased from DSM) with a hardness range of about 60-95 Shore A hardness and an intrinsic viscosity of about 0.8-1.9 dL/g are pre-dried at about 60-80° C. for about 3-4 hours. About 0.5 parts by weight of an antioxidant formula (0.25 parts by weight each of hindered phenol antioxidant AO1010 and phosphite antioxidant A168), about 0.5 parts by weight of a cell nucleating agent formula (nano calcium carbonate), about 2.0 parts by weight of a cell stabilizer formula (multifunctional chain expander ADR-4370), and about 1.0 parts by weight of a flow aid formula (stearate) are mixed with about 100 parts by weight of the dried thermoplastic polyester elastomer particles to obtain a midsole mixture. The midsole mixture is fed into a twin-screw extruder (25ψ, L/D=45) by weightless feeding for mixing (screw temperature is about 170~200°C, and rotation speed is about 150~300 rpm). The mixed midsole mixture is subjected to a pelletizing process to obtain midsole particles. The midsole particles are dried at about 80~100°C for about 6~8 hours. Finally, a shoe midsole foam is obtained from the midsole particles by chemical or physical foaming.
將約100重量份的溶聚苯乙烯-丁二烯橡膠 (SSBR,購自台橡股份有限公司,型號TAIPOL 1453)、約0.45重量份的過氧化二異丙苯(DCP,用作為交聯劑,購自豪元實業股份有限公司,型號GY-DCP)、約2重量份的羥甲基丙烷三甲基丙烯酸酯(TMPTMA,用作為交聯助劑,購自雙鍵化工股份有限公司,型號DOUBLEMER TMPTMA)、約1.45重量份的抗氧化劑(AO1050,購自安鋒實業股份有限公司)、約15重量份的石蠟油(購自帝一化工,型號EP 石蠟油)與約30重量份的白碳黑投入密煉機中以獲得一橡膠混合物。將橡膠混合物以約60~80°C與約50~100 rpm的螺桿轉速進行捏合與強制造粒,以獲得粒徑約2~3 mm的橡膠粒子。將熱塑性聚酯彈性體粒子 (購自DSM公司,硬度範圍約45~70邵氏A硬度,本質黏度約0.8~1.9 dL/g)預先以約80℃乾燥約3~4小時。將約75重量份乾燥後的熱塑性聚酯彈性體粒子、約100重量份的橡膠粒子、以及約9.2重量份的苯乙烯馬來酸酐(SMA,用作為界面相容樹酯,購自沅鴻股份有限公司,型號SMA1000)進料至雙螺桿押出機中(26ψ, L/D=60)進行動態交聯反應(螺桿溫度約170~200°C,轉速約150~300 rpm)以獲得動態交聯彈性體,此時橡膠粒子以粒徑為0.5~10μm的球狀顆粒形式分散在熱塑性聚酯彈性體中。將動態交聯彈性體經過切粒製程以獲得大底粒子。將大底粒子在約80~100℃下乾燥約6~8小時後透過射出成形方式製造鞋大底。About 100 parts by weight of solution polystyrene-butadiene rubber (SSBR, purchased from Taiwan Rubber Co., Ltd., model TAIPOL 1453) and about 0.45 parts by weight of dicumyl peroxide (DCP) were used as cross-linking agents. , purchased from Guoyuan Industrial Co., Ltd., model GY-DCP), and about 2 parts by weight of methylolpropane trimethacrylate (TMPTMA, used as a cross-linking aid, purchased from Double Bond Chemical Co., Ltd., model DOUBLEMER TMPTMA), about 1.45 parts by weight of antioxidant (AO1050, purchased from Anfeng Industrial Co., Ltd.), about 15 parts by weight of paraffin oil (purchased from Diyi Chemical, model EP paraffin oil) and about 30 parts by weight of white carbon Black is put into an internal mixer to obtain a rubber mixture. The rubber mixture is kneaded and forcibly granulated at about 60~80°C and a screw speed of about 50~100 rpm to obtain rubber particles with a particle size of about 2~3 mm. Thermoplastic polyester elastomer particles (purchased from DSM Company, hardness range is about 45~70 Shore A hardness, intrinsic viscosity is about 0.8~1.9 dL/g) are dried at about 80°C for about 3~4 hours. About 75 parts by weight of dried thermoplastic polyester elastomer particles, about 100 parts by weight of rubber particles, and about 9.2 parts by weight of styrene maleic anhydride (SMA) were used as interface compatible resin, purchased from Yuanhong Co., Ltd. Co., Ltd., model SMA1000) is fed into the twin-screw extruder (26ψ, L/D=60) for dynamic cross-linking reaction (screw temperature is about 170~200°C, rotation speed is about 150~300 rpm) to obtain dynamic cross-linking Elastomer, at this time the rubber particles are dispersed in the thermoplastic polyester elastomer in the form of spherical particles with a particle size of 0.5~10μm. The dynamically cross-linked elastomer undergoes a pelletizing process to obtain large base particles. The outsole particles are dried at about 80 to 100°C for about 6 to 8 hours and then the shoe outsole is manufactured by injection molding.
使用硬度範圍約40~60邵氏D硬度的熱塑性聚酯彈性體粒子(購自DSM公司),透過射出成形方式的製造平衡片。平衡片是透過射出加工製程直接射出熱熔貼合在鞋中底發泡體上。The balance sheet is manufactured by injection molding using thermoplastic polyester elastomer particles (purchased from DSM) with a hardness range of about 40~60 Shore D. The balance sheet is directly injected and hot-melted onto the midsole foam through the injection molding process.
將鞋中底發泡體與鞋大底以聚酯熱熔膠進行貼合,或是透過射出加工製程將鞋大底直接射出熱熔貼合在鞋中底發泡體上。The midsole foam and the shoe outsole are bonded with polyester hot melt adhesive, or the shoe outsole is directly injected and hot melt bonded to the shoe midsole foam through an injection process.
3.運動鞋製備以及性能測試3. Preparation and performance testing of sports shoes
將上述鞋面與鞋底透過聚酯熱熔膠貼合,或是使用加熱連接製程熔化鞋面與鞋底的界面後連接鞋面與鞋底。The above-mentioned upper and sole are bonded together through polyester hot melt adhesive, or a heating connection process is used to melt the interface between the upper and sole and then connect the upper and sole.
以荷蘭DSM的TPE EL250作為比較例1並以日本東洋TPEE P30BP30B作為比較例2。 以DIN 53516測量本揭露實施例的鞋大底以及比較例1與2的耐磨耗量、以ASTM F489測試測量本揭露實施例的鞋大底以及比較例1與2濕止滑性能、以及以ASTM D2240測試測量本揭露實施例的鞋大底以及比較例1與2硬度。測量結果示於以下表1。
表1
以ASTM D297測試測得鞋中底發泡體的比重約0.1~0.4g/mL,回彈性約50~70%且表面硬度約30~60邵氏C硬度。According to the ASTM D297 test, the specific gravity of the shoe midsole foam is about 0.1~0.4g/mL, the resilience is about 50~70%, and the surface hardness is about 30~60 Shore C hardness.
由表1的結果可看出本揭露的運動鞋具有良好的耐磨耗量以及濕止滑性能。除此之外,由鞋中底發泡體的測量結果可看出,本揭露的運動鞋具有高緩衝、高回彈以及高舒適度等特性。本揭露的運動鞋在所有部件皆以熱塑性聚酯材料及/聚酯彈性體製成的情況下可同時保有良好的耐磨耗量、濕止滑性能、高緩衝、高回彈及/或高舒適度等特性。It can be seen from the results in Table 1 that the sports shoes of the present disclosure have good wear resistance and wet anti-slip performance. In addition, it can be seen from the measurement results of the midsole foam that the sports shoes disclosed in the present disclosure have characteristics such as high cushioning, high rebound, and high comfort. The sports shoes disclosed in the present disclosure can simultaneously maintain good wear resistance, wet anti-slip performance, high cushioning, high rebound and/or high Comfort and other characteristics.
除此之外,由於本揭露的運動鞋的所有部件皆以熱塑性聚酯材料及/聚酯彈性體製成,因此本揭露的運動鞋可全鞋直接回收再製利用,而無需先經過分離運動鞋的各部件的分離製程。本揭露的運動鞋於回收後可全鞋直接熔融加工再製成各種的鞋部件,例如鞋大底、鞋中底或補強平衡片。In addition, since all components of the sports shoes of the disclosure are made of thermoplastic polyester materials and/or polyester elastomers, the sports shoes of the disclosure can be directly recycled and reused without first separating the sports shoes. Separation process of each component. After the sports shoes disclosed in the present disclosure are recycled, the entire shoe can be directly melt-processed to be made into various shoe parts, such as outsoles, midsoles or reinforcing balance sheets.
上述實施例之特徵有利於本技術領域中具有通常知識者理解本發明。本技術領域中具有通常知識者應理解可採用本發明作基礎,設計並變化其他製程與結構以完成上述實施例之相同目的及/或相同優點。本技術領域中具有通常知識者亦應理解,這些等效置換並未脫離本發明精神與範疇,並可在未脫離本發明之精神與範疇的前提下進行改變、替換、或更動。The features of the above embodiments are helpful for those with ordinary skill in the art to understand the present invention. Those with ordinary skill in the art should understand that the present invention can be used as a basis to design and change other processes and structures to achieve the same purposes and/or the same advantages of the above embodiments. Those with ordinary skill in the art should also understand that these equivalent substitutions do not depart from the spirit and scope of the present invention, and can be changed, replaced, or modified without departing from the spirit and scope of the present invention.
10:運動鞋 101:鞋面 1011:織物部件 1013:補強部件 103:鞋底 1031:鞋大底 1033:鞋中底發泡體 1035:補強平衡片 1037:鞋墊 10: sports shoes 101: upper 1011: fabric parts 1013: reinforcement parts 103: sole 1031: outsole 1033: midsole foam 1035: reinforcement balance sheet 1037: insole
本揭露將參考其中示出了本揭露的例示性實施例之圖式而更充分地描述,其中: 第1圖是根據本揭露一實施例的運動鞋的爆炸圖。 The present disclosure will be more fully described with reference to the drawings showing exemplary embodiments of the present disclosure, wherein: FIG. 1 is an exploded view of a sports shoe according to an embodiment of the present disclosure.
10:運動鞋 10:Sneakers
101:鞋面 101: Upper
1011:織物部件 1011: Fabric parts
1013:補強部件 1013: Reinforcement parts
103:鞋底 103:Sole
1031:鞋大底 1031: Shoe outsole
1033:鞋中底發泡體 1033: Shoe midsole foam
1035:補強平衡片 1035: Strengthening balance sheet
1037:鞋墊 1037: Insoles
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- 2023-07-19 TW TW112126852A patent/TWI841452B/en active
- 2023-08-23 CN CN202311065160.XA patent/CN117617626A/en active Pending
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TWI841452B (en) | 2024-05-01 |
CN117617626A (en) | 2024-03-01 |
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