TW201621039A - Non fermented beer-like foaming beverages - Google Patents

Non fermented beer-like foaming beverages Download PDF

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TW201621039A
TW201621039A TW104137933A TW104137933A TW201621039A TW 201621039 A TW201621039 A TW 201621039A TW 104137933 A TW104137933 A TW 104137933A TW 104137933 A TW104137933 A TW 104137933A TW 201621039 A TW201621039 A TW 201621039A
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beer
fermented beer
foaming
beverage
concentration
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瀧下誠一
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朝日啤酒股份有限公司
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/38Other non-alcoholic beverages
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L11/00Pulses, i.e. fruits of leguminous plants, for production of food; Products from legumes; Preparation or treatment thereof
    • A23L11/60Drinks from legumes, e.g. lupine drinks
    • A23L11/65Soy drinks
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12GWINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G3/00Preparation of other alcoholic beverages
    • C12G3/04Preparation of other alcoholic beverages by mixing, e.g. for preparation of liqueurs

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nutrition Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
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  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Non-Alcoholic Beverages (AREA)
  • Alcoholic Beverages (AREA)

Abstract

The present invention provides a non fermented beer-like foaming beverage having rich body in spite of an extremely low purine concentration. The present invention is a non fermented beer-like foaming beverage in which an amount of a raw material including a purine body added has been adjusted, the non fermented beer-like foaming beverage having a purine concentration of 0.2 mg/100mL or lower, containing 40-700 ppm of at least one organic acid selected from the group consisting of phosphoric acid and lactic acid, and having a pH value of 3.2-4.5, the above non fermented beer-like foaming beverage further containing at least one member selected from the group consisting of citric salts and gluconates, and either of the above non fermented beer-like foaming beverages further containing a soluble fiber.

Description

非發酵之類啤酒發泡性飲料 Non-fermented beer foaming beverage

本發明係關於一種未經醱酵步驟而製造、儘管嘌呤體濃度非常低亦具有充分之醇香的非醱酵之類啤酒發泡性飲料。 The present invention relates to a non-fermented beer-flavored beverage which is produced without a fermentation step and which has a sufficiently mellow taste despite the very low concentration of the steroid.

本申請案係基於2014年12月8日於日本提出申請之日本專利特願2014-248154號而主張優先權,將其內容引用至本文中。 The present application claims priority based on Japanese Patent Application No. 2014-248154, filed on Jan.

嘌呤體成為高尿酸血症、甚至痛風之原因,故而於啤酒或發泡酒等類啤酒發泡性飲料中,消費者對減少嘌呤體含量、並且保持先前啤酒等所具有之香味的類啤酒發泡性飲料之期待不斷提高。然而,對於大多數之類啤酒發泡性飲料而言,為了維持類似啤酒味道而使用麥芽或啤酒花等含有相對較多之嘌呤體之原料,因此存在最終製品中之嘌呤體含量變多之問題。因此,例如於專利文獻1及2中揭示有如下情況:對麥芽等含有相對較多之嘌呤體之原料的添加量進行調整,進而不經醱酵步驟而進行製造,藉此可製造最終製品中之嘌呤體濃度前所未有地低至0.2mg/100mL以下的非醱酵之類啤酒發泡性飲料。藉由預先將源自原料之嘌呤體之量抑制為較低,即便不進行活性碳處理或沸石處理等嘌呤體去除處理,亦可抑制最終製品中之嘌呤體含量。 The corpus callosum is a cause of hyperuricemia and even gout. Therefore, in beer-like foaming beverages such as beer or sparkling wine, consumers are concerned with reducing the carcass content and maintaining the aroma of previous beer. The expectation of foaming beverages continues to increase. However, for most beer-like beverages, in order to maintain a beer-like taste, a raw material containing a relatively large amount of carcass such as malt or hop is used, so that there is a problem that the carcass content in the final product becomes large. . For example, in Patent Documents 1 and 2, it is disclosed that the amount of the raw material containing a relatively large amount of carcass such as malt is adjusted, and the production is carried out without the fermentation step, whereby the final product can be produced. A non-fermented beer-flavored beverage with a concentration of less than 0.2 mg/100 mL as never before. By suppressing the amount of the carcass derived from the raw material to a low level in advance, the carcass content in the final product can be suppressed without performing the carcass removal treatment such as activated carbon treatment or zeolite treatment.

又,根據近年來之消費者之健康意向,對低卡路里或低糖類之類啤酒發泡性飲料之需求亦不斷提高。藉由抑制麥芽等原料之使用量,可減少類啤酒發泡性飲料之卡路里或糖類含量,但存在飲用感亦 降低之問題。因此,於專利文獻3中揭示有如下方法:針對麥芽等成分濃度較低、低萃取物量之類啤酒發泡性飲料,將pH值調整為2.7以上且4.5以下之範圍內,藉此賦予飲用感。 Moreover, according to the health intentions of consumers in recent years, the demand for beer-foaming beverages such as low-calorie or low-sugar is also increasing. By suppressing the amount of raw materials such as malt, the calorie or sugar content of the beer-like sparkling beverage can be reduced, but there is also a sense of drinking. Reduce the problem. For this reason, Patent Document 3 discloses a method for providing a beer-foaming beverage having a low concentration of components such as malt and a low extract amount, and adjusting the pH to a range of 2.7 or more and 4.5 or less. sense.

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

[專利文獻1]日本專利特開2014-183855號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2014-183855

[專利文獻2]日本專利特開2014-195475號公報 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2014-195475

[專利文獻3]日本專利特開2013-255504號公報 [Patent Document 3] Japanese Patent Laid-Open Publication No. 2013-255504

本發明之目的在於提供一種儘管嘌呤體濃度非常低亦具有充分之醇香的非醱酵之類啤酒發泡性飲料。 SUMMARY OF THE INVENTION An object of the present invention is to provide a non-fermented beer-foaming beverage which has a sufficient mellowness even in a very low steroid concentration.

本發明者為解決上述課題而進行了努力研究,結果發現了如下情況:藉由對麥芽等含有相對較多之嘌呤體之原料的添加量進行調整,且不經醱酵步驟而進行製造,可製造最終製品中之嘌呤體濃度前所未有地低至0.2mg/100mL以下的非醱酵之類啤酒發泡性飲料;且對於以上述方式製造之非醱酵之類啤酒發泡性飲料,藉由將pH值設為特定範圍內,進而添加選自由磷酸及乳酸所組成之群中之1種以上的有機酸,可賦予醇香,從而完成了本發明。 The present inventors have made an effort to solve the above problems, and as a result, it has been found that the amount of the raw material containing a relatively large amount of carcass such as malt is adjusted, and the production is carried out without a fermentation step. It is possible to manufacture a non-fermented beer-flavored beverage having an steroid concentration in the final product as low as 0.2 mg/100 mL or less; and for a non-fermented beer-flavored beverage manufactured in the above manner, by The present invention has been completed by adding one or more organic acids selected from the group consisting of phosphoric acid and lactic acid in a specific range, and imparting an alcoholic scent.

本發明之非醱酵之類啤酒發泡性飲料係下述[1]~[9]。 The non-fermented beer foaming beverage of the present invention is the following [1] to [9].

[1]一種非醱酵之類啤酒發泡性飲料,其係含有嘌呤體之原料之添加量經調整,嘌呤體濃度為0.2mg/100mL以下,選自由磷酸及乳酸所組成之群中之1種以上之有機酸的含量為40~700ppm,且pH值為3.2~4.5。 [1] A non-fermented beer-flavored beverage, wherein the amount of the raw material containing the steroid is adjusted, and the steroid concentration is 0.2 mg/100 mL or less, which is selected from the group consisting of phosphoric acid and lactic acid. The above organic acid content is 40 to 700 ppm, and the pH is 3.2 to 4.5.

[2]如上述[1]之非醱酵之類啤酒發泡性飲料,其進而含有選自由 檸檬酸之鹽類及葡萄糖酸之鹽類所組成之群中之1種以上。 [2] The non-fermented beer foaming beverage according to the above [1], which further comprises One or more of the group consisting of a salt of citric acid and a salt of gluconic acid.

[3]如上述[1]之非醱酵之類啤酒發泡性飲料,其以非醱酵之類啤酒發泡性飲料每單位之檸檬酸濃度成為10~650ppm之方式含有檸檬酸之鈉鹽。 [3] The non-fermented beer-foaming beverage according to the above [1], which contains a sodium salt of citric acid in such a manner that the citric acid concentration per unit of the non-fermented beer foaming beverage is 10 to 650 ppm per unit. .

[4]如上述[1]至[3]中任一項之非醱酵之類啤酒發泡性飲料,其中嘌呤體濃度為0.08mg/100mL以下。 [4] The non-fermented beer-foaming beverage according to any one of the above [1] to [3] wherein the steroid concentration is 0.08 mg/100 mL or less.

[5]如上述[1]至[4]中任一項之非醱酵之類啤酒發泡性飲料,其中糖類濃度為0.5g/100mL以下。 [5] The non-fermented beer-foaming beverage according to any one of the above [1] to [4] wherein the saccharide concentration is 0.5 g/100 mL or less.

[6]如上述[1]至[5]中任一項之非醱酵之類啤酒發泡性飲料,其中選自由磷酸及乳酸所組成之群中之1種以上之有機酸的含量為40~500ppm。 [6] The non-fermented beer-foaming beverage according to any one of the above [1] to [5] wherein the content of one or more organic acids selected from the group consisting of phosphoric acid and lactic acid is 40 ~500ppm.

[7]如上述[1]至[6]中任一項之非醱酵之類啤酒發泡性飲料,其進而含有水溶性食物纖維。 [7] The non-fermented beer-foaming beverage according to any one of [1] to [6] above which further comprises a water-soluble dietary fiber.

[8]如上述[7]之非醱酵之類啤酒發泡性飲料,其中上述水溶性食物纖維為大豆食物纖維。 [8] The non-fermented beer foaming beverage according to [7] above, wherein the water-soluble dietary fiber is a soybean dietary fiber.

[9]如上述[1]至[8]中任一項之非醱酵之類啤酒發泡性飲料,其進而含有乙醇。 [9] The non-fermented beer-foaming beverage according to any one of [1] to [8] above which further contains ethanol.

本發明之非醱酵之類啤酒發泡性飲料係儘管可將嘌呤體濃度抑制為非常低之0.2mg/100mL以下,亦具有充分之醇香的官能性非常高之類啤酒發泡性飲料。 The non-fermented beer-foaming beverage of the present invention is a beer-foaming beverage having a very high alcoholicity and a very high functionality, although the concentration of the steroid is suppressed to be 0.2 mg/100 mL or less.

本發明及本申請案說明書中,所謂「類似啤酒味道」,意指不管製品名稱‧標示如何,香味上想起啤酒之味道。即,所謂具有類似啤 酒味道之發泡性飲料(類啤酒發泡性飲料),係指不管酒精含量如何、有無使用麥芽及啤酒花、有無醱酵,具有與啤酒同等或與其類似之味道、味覺及質地的發泡性飲料。 In the present invention and the specification of the present application, the phrase "similar to beer taste" means that the flavor of the beer is recalled regardless of the name of the product. That is, the so-called beer A sparkling beverage (flavored beer-like beverage) of wine taste refers to foaming that has the same taste or taste and texture as beer, regardless of the alcohol content, whether or not malt and hop are used, and whether or not it is fermented. Sex drinks.

又,所謂本發明及本申請案說明書中之非醱酵之類啤酒發泡性飲料,意指不經醱酵步驟而製造,且具有類似啤酒味道與基於二氧化碳氣體之發泡性的飲料。非醱酵之類啤酒發泡性飲料可為酒精飲料,亦可為酒精含量未達1體積%之所謂無酒精飲料或低酒精飲料。具體而言,可列舉:啤酒、發泡酒、低酒精發泡性飲料、無酒精啤酒等。 Further, the present invention and the non-fermented beer foaming drink in the specification of the present application mean a beverage which is produced without a fermentation step and which has a beer-like taste and a foaming property based on carbon dioxide gas. Non-fermented beer foaming beverages may be alcoholic beverages, or so-called non-alcoholic beverages or low-alcoholic beverages having an alcohol content of less than 1% by volume. Specific examples include beer, sparkling wine, low alcohol sparkling beverage, and non-alcohol beer.

本發明之非醱酵之類啤酒發泡性飲料之特徵在於:含有嘌呤體之原料之添加量經調整,且嘌呤體濃度為0.2mg/100mL以下。關於本發明之非醱酵之類啤酒發泡性飲料,藉由調整含有嘌呤體之原料之添加量,進而不經醱酵步驟而進行製造,可無需活性碳處理或沸石處理等嘌呤體去除步驟而將嘌呤體濃度抑制為前所未有之低濃度。本發明之非醱酵之類啤酒發泡性飲料之嘌呤體濃度較佳為未達0.2mg/100mL,更佳為0.1mg/100mL以下,進而較佳為未達0.08mg/100mL。 The non-fermented beer foaming beverage of the present invention is characterized in that the amount of the raw material containing the steroid is adjusted, and the steroid concentration is 0.2 mg/100 mL or less. The non-fermented beer-flavored beverage of the present invention can be produced without adjusting the amount of the raw material containing the steroid, and can be produced without the fermentation step, and the carcass removal step such as activated carbon treatment or zeolite treatment can be eliminated. The concentration of steroids is suppressed to an unprecedented low concentration. The carcass concentration of the non-fermented beer-flavored beverage of the present invention is preferably less than 0.2 mg/100 mL, more preferably 0.1 mg/100 mL or less, still more preferably less than 0.08 mg/100 mL.

再者,本發明及本申請案說明書中,所謂嘌呤體,係指腺嘌呤、黃嘌呤、鳥嘌呤、次黃嘌呤之四種嘌呤體鹼之總量。非醱酵之類啤酒發泡性飲料或原料中之嘌呤體含量例如可藉由以下方法測定:於利用過氯酸之水解後,使用LC-MS/MS進行檢測之方法(「酒類之嘌呤體之微量分析之指南」,財團法人日本食品分析中心,網際網路<URL:http://www.jfrl.or.jp/item/nutrition/post-31.html>,2013年1月檢索)。 Furthermore, in the present invention and the specification of the present application, the so-called corpus callosum refers to the total amount of four steroidal bases of adenine, scutellaria, guanine, and hypoxanthine. The content of the steroid in the non-fermented beer-flavored beverage or raw material can be determined, for example, by the method of LC-MS/MS after hydrolysis with perchloric acid ("Carcass of alcohol" Guide to Microanalysis, Japan Food Analysis Center, Internet <URL: http://www.jfrl.or.jp/item/nutrition/post-31.html >, retrieved in January 2013).

麥芽或蛋白質分解物等源自生物之原料因嘌呤體含量相對較多,故於本發明之非醱酵之類啤酒發泡性飲料中,以作為最終製品之飲料中之嘌呤體濃度成為0.2mg/100mL以下之方式將使用量抑制為較低而進行調整。另一方面,源自該等原料之成分亦有助於類啤酒發 泡性飲料之醇香,若該等原料之使用量變低,則醇香亦易受損。於本發明之非醱酵之類啤酒發泡性飲料中,藉由選自由磷酸及乳酸所組成之群中之1種以上之有機酸的含量為特定範圍內,且pH值為3.2~4.5,即便於源自生物之原料之使用量較少之情形時,亦具有充分之醇香。 In the non-fermented beer-foaming beverage of the present invention, the concentration of the steroid in the beverage as the final product is 0.2 in the bio-derived material such as malt or protein decomposition product. The amount of mg/100 mL or less is adjusted so that the amount of use is suppressed to be low. On the other hand, ingredients derived from these raw materials also contribute to beer-like hair The mellowness of the foaming beverage, if the amount of the raw materials used is low, the mellow is also easily damaged. In the non-fermented beer foaming beverage of the present invention, the content of one or more organic acids selected from the group consisting of phosphoric acid and lactic acid is within a specific range, and the pH is 3.2 to 4.5. That is, when the amount of the raw material derived from the living organism is small, the mellow is also sufficient.

本發明之非醱酵之類啤酒發泡性飲料含有磷酸與乳酸中之至少一者,且磷酸或乳酸之含量為40~700ppm。於本發明之非醱酵之類啤酒發泡性飲料不含後述水溶性食物纖維之情形時,磷酸或乳酸之含量較佳為40~500ppm,更佳為40~300ppm,進而較佳為40~100ppm,進而更佳為50~100ppm。於本發明之非醱酵之類啤酒發泡性飲料含有後述水溶性食物纖維之情形時,磷酸或乳酸之含量較佳為40~700ppm,更佳為40~500ppm。 The non-fermented beer foaming beverage of the present invention contains at least one of phosphoric acid and lactic acid, and the content of phosphoric acid or lactic acid is 40 to 700 ppm. In the case where the non-fermented beer foaming beverage of the present invention does not contain the water-soluble dietary fiber described later, the content of phosphoric acid or lactic acid is preferably 40 to 500 ppm, more preferably 40 to 300 ppm, and still more preferably 40 to 40. 100 ppm, and more preferably 50 to 100 ppm. In the case where the non-fermented beer foaming beverage of the present invention contains a water-soluble dietary fiber to be described later, the content of phosphoric acid or lactic acid is preferably 40 to 700 ppm, more preferably 40 to 500 ppm.

於本發明之非醱酵之類啤酒發泡性飲料含有磷酸與乳酸兩者之情形時,較佳為磷酸與乳酸之含量之和為40~700ppm,更佳為乳酸之含量為10ppm以上,磷酸之含量為10~500ppm,且磷酸與乳酸之含量之和為40~700ppm。 In the case where the non-fermented beer foaming beverage of the present invention contains both phosphoric acid and lactic acid, the sum of the content of phosphoric acid and lactic acid is preferably 40 to 700 ppm, more preferably 10 ppm or more of lactic acid, and phosphoric acid. The content is 10 to 500 ppm, and the sum of the content of phosphoric acid and lactic acid is 40 to 700 ppm.

本發明之非醱酵之類啤酒發泡性飲料之pH值為3.2~4.5。藉由飲料之pH值為上述範圍內,即便於為賦予醇香感而含有充分量之磷酸及/或乳酸之情形時,亦可抑制過度之酸味,達成類似啤酒之醇香。作為本發明之非醱酵之類啤酒發泡性飲料之pH值,較佳為3.2~4.2,更佳為3.5~4.1。尤其於本發明之非醱酵之類啤酒發泡性飲料不含乙醇之情形時,pH值較佳為3.5以上且未達4.0。 The pH value of the non-fermented beer foaming beverage of the present invention is 3.2 to 4.5. When the pH of the beverage is within the above range, even when a sufficient amount of phosphoric acid and/or lactic acid is contained in order to impart a mellow sensation, excessive acidity can be suppressed, and a beer-like mellow can be obtained. The pH of the non-fermented beer-flavored beverage of the present invention is preferably from 3.2 to 4.2, more preferably from 3.5 to 4.1. In particular, when the non-fermented beer foaming beverage of the present invention does not contain ethanol, the pH is preferably 3.5 or more and less than 4.0.

非醱酵之類啤酒發泡性飲料之pH值可藉由調配如有機酸鹽或碳酸氫鹽等般於酸性之飲食品中用作pH值調整劑之酸味料而進行調整。作為用作pH值調整劑之有機酸鹽,可列舉:檸檬酸、葡萄糖酸、酒石酸、蘋果酸、琥珀酸、己二酸、及富馬酸等之鹽類。作為上 述鹽類,可僅使用1種,亦可組合使用2種以上。作為本發明之非醱酵之類啤酒發泡性飲料,就可於不損及類似啤酒之香味的情況下調整pH值之方面而言,較佳為含有選自由檸檬酸之鹽類及葡萄糖酸之鹽類所組成之群中之1種以上,更佳為含有選自由檸檬酸之鈉鹽、檸檬酸之鉀鹽、葡萄糖酸鉀、及葡萄糖酸鈉所組成之群中之1種以上,進而較佳為含有選自由檸檬酸三鈉、葡萄糖酸鉀、及葡萄糖酸鈉所組成之群中之1種以上。其中,就可將使用量抑制為相對較低,亦可將飲料之糖類含量抑制為更低之方面而言,尤佳為含有檸檬酸三鈉。 The pH of the non-fermented beer-flavored beverage can be adjusted by blending a sour material used as a pH adjuster in an acidic food or drink such as an organic acid salt or a hydrogencarbonate. Examples of the organic acid salt used as the pH adjuster include salts of citric acid, gluconic acid, tartaric acid, malic acid, succinic acid, adipic acid, and fumaric acid. As above The salt may be used alone or in combination of two or more. The non-fermented beer-flavored beverage of the present invention preferably contains a salt selected from the group consisting of citric acid and gluconic acid in that the pH is adjusted without damaging the flavor of the beer. One or more of the group consisting of a salt, and more preferably one or more selected from the group consisting of sodium salt of citric acid, potassium salt of citric acid, potassium gluconate, and sodium gluconate, It is preferable to contain one or more selected from the group consisting of trisodium citrate, potassium gluconate, and sodium gluconate. Among them, the use amount can be suppressed to be relatively low, and the sugar content of the beverage can be suppressed to be lower, and it is particularly preferable to contain trisodium citrate.

關於本發明之非醱酵之類啤酒發泡性飲料中之pH值調整劑的含量,只要為將飲料之pH值調整為3.2~4.5之範圍內之量即可,考慮磷酸及/或乳酸之含量或其他原料之種類或使用量等而適當調節。例如,於本發明之非醱酵之類啤酒發泡性飲料含有檸檬酸之鈉鹽的情形時,較佳為以非醱酵之類啤酒發泡性飲料每單位之檸檬酸濃度成為10~650ppm之方式含有檸檬酸之鈉鹽,更佳為以非醱酵之類啤酒發泡性飲料每單位之檸檬酸濃度成為30~650ppm之方式含有檸檬酸之鈉鹽,進而較佳為以非醱酵之類啤酒發泡性飲料每單位之檸檬酸濃度成為80~500ppm之方式含有檸檬酸之鈉鹽,進而更佳為以非醱酵之類啤酒發泡性飲料每單位之檸檬酸濃度成為80~400ppm之方式含有檸檬酸之鈉鹽。 The content of the pH adjuster in the non-fermented beer foaming beverage of the present invention may be adjusted to a pH of 3.2 to 4.5 in the range of the pH of the beverage, and phosphoric acid and/or lactic acid may be considered. The content or the type of other raw materials, the amount of use, and the like are appropriately adjusted. For example, in the case where the non-fermented beer foaming beverage of the present invention contains a sodium salt of citric acid, it is preferred that the concentration of citric acid per unit of the non-fermented beer foaming beverage is 10 to 650 ppm per unit. The method comprises a sodium salt of citric acid, more preferably a non-fermented beer foaming beverage containing a sodium salt of citric acid per citric acid concentration of 30 to 650 ppm, and more preferably a non-fermented yeast Such a beer foaming beverage contains a sodium salt of citric acid in a manner that the concentration of citric acid per unit is 80 to 500 ppm, and more preferably, the concentration of citric acid per unit of non-fermented beer foaming beverage becomes 80~. The 400 ppm method contains a sodium salt of citric acid.

本發明之非醱酵之類啤酒發泡性飲料較佳為進而含有水溶性食物纖維。所謂水溶性食物纖維,意指溶解於水,且不因人類之消化酵素而被消化或難以被消化之碳水化合物。水溶性食物纖維除提高醇香感外,亦可降低源自磷酸與乳酸之酸味。因此,藉由含有水溶性食物纖維,與不含有水溶性食物纖維之非醱酵之類啤酒發泡性飲料相比,可於不賦予過度之酸味的情況下含有更多量之磷酸及/或乳酸。又,水溶性食物纖維進而亦作為起泡劑發揮功能,因此即便不另調配起泡 劑亦可獲得泡品質良好之非醱酵之類啤酒發泡性飲料。作為水溶性食物纖維,例如可列舉:大豆食物纖維、聚葡萄糖、難消化性糊精、半乳甘露聚糖、菊糖、瓜爾膠分解物、果膠、阿拉伯膠等。作為本發明之非醱酵之類啤酒發泡性飲料,較佳為含有大豆食物纖維。 The non-fermented beer-foaming beverage of the present invention preferably further contains a water-soluble dietary fiber. The so-called water-soluble dietary fiber means a carbohydrate that is dissolved in water and is not digested or difficult to be digested by human digestive enzymes. In addition to improving the mellow sensation, the water-soluble dietary fiber can also reduce the sour taste derived from phosphoric acid and lactic acid. Therefore, by containing a water-soluble dietary fiber, it is possible to contain a larger amount of phosphoric acid and/or an excessive sour taste than a non-fermented beer-flavored beverage which does not contain water-soluble dietary fiber. Lactic acid. Moreover, the water-soluble dietary fiber further functions as a foaming agent, so that even if no foaming is additionally formulated A non-fermented beer foaming beverage with good foam quality can also be obtained. Examples of the water-soluble dietary fiber include soybean dietary fiber, polydextrose, indigestible dextrin, galactomannan, inulin, guar gum, pectin, gum arabic, and the like. As the non-fermented beer foaming beverage of the present invention, it is preferred to contain soy dietary fiber.

為了可更充分地發揮磷酸或乳酸之醇香感賦予效果,作為本發明之非醱酵之類啤酒發泡性飲料,較佳為糖類含量較低,更佳為糖類濃度為0.5g/100mL以下,進而較佳為糖類濃度未達0.5g/100mL。 In order to more fully exhibit the mellow sensation imparting effect of phosphoric acid or lactic acid, the non-fermented beer foaming beverage of the present invention preferably has a low sugar content, more preferably a saccharide concentration of 0.5 g/100 mL or less. Further preferably, the concentration of the saccharide is less than 0.5 g/100 mL.

本發明之非醱酵之類啤酒發泡性飲料亦可含有水溶性食物纖維以外之起泡劑。作為此種起泡劑,例如可列舉:大豆肽、大豆皂苷、海藻酸酯、皂樹皂苷等。該等起泡劑可僅使用1種,亦可併用2種以上。 The non-fermented beer foaming beverage of the present invention may also contain a foaming agent other than the water-soluble dietary fiber. Examples of such a foaming agent include soybean peptide, soybean saponin, alginate, and saponin. These foaming agents may be used alone or in combination of two or more.

本發明之非醱酵之類啤酒發泡性飲料較佳為進而含有色素。作為本發明之非醱酵之類啤酒發泡性飲料所含有之色素,只要為可賦予類似啤酒之顏色、且可飲食之色素,則無特別限定,尤佳為焦糖化反應物(焦糖色素)。 The non-fermented beer foaming beverage of the present invention preferably further contains a coloring matter. The pigment contained in the non-fermented beer-flavored beverage of the present invention is not particularly limited as long as it is a color that can be similar to beer and can be eaten, and is preferably a caramelized reaction product (caramel coloring matter). ).

本發明之非醱酵之類啤酒發泡性飲料較佳為進而含有苦味劑。作為此種苦味劑,只要於作為製品之非醱酵之類啤酒發泡性飲料中呈現出與啤酒同質或近似之苦味,則無特別限定,可為啤酒花中所含之苦味成分,亦可為不含於啤酒花中之苦味成分。作為此種苦味劑,具體而言,可代表性地列舉:鎂鹽、鈣鹽、檸檬酸三丁酯、檸檬酸三乙酯、柚皮苷(Naringin)、苦木素(Quassin)、異α酸、四異α酸、β酸之氧化物、奎寧、苦瓜葉素、槲皮苷、可可鹼、咖啡因等苦味賦予成分;及苦瓜、當藥茶、苦丁茶、苦艾萃取物、龍膽萃取物、奎寧萃取物等苦味賦予素材。該等苦味劑可僅使用1種,亦可併用2種以上。 The non-fermented beer foaming beverage of the present invention preferably further contains a bittering agent. The bittering agent is not particularly limited as long as it exhibits a bitter taste similar to or similar to beer in a beer-foaming beverage which is a non-fermented product, and may be a bitter component contained in the hop or may be Contains no bitter ingredients in hops. Specific examples of such a bittering agent include magnesium salt, calcium salt, tributyl citrate, triethyl citrate, Naringin, Qurasin, and α. Acid, tetraisoalpha acid, beta acid oxide, quinine, bitter melon, quercetin, theobromine, caffeine and other bitterness imparting ingredients; and bitter gourd, herbal tea, Kudingcha, absinthe extract, A bitter taste such as gentian extract or quinine extract is added to the material. These bittering agents may be used alone or in combination of two or more.

本發明之非醱酵之類啤酒發泡性飲料較佳為進而含有1種或2種以上之甜味成分。作為此種甜味成分,較佳為與單糖相比而甜味度相 對較低者,具體而言,可列舉:多糖類、甜味系胺基酸、高感度甜味劑等。所謂多糖類,意指3個以上之單糖聚合而成之糖類。多糖類主要根據其大小而大致分為澱粉、糊精、及寡糖。寡糖係3~10個左右之單糖聚合而成之糖類,糊精係指使澱粉水解而獲得之糖類,且較寡糖大。作為甜味系胺基酸,可列舉丙胺酸或甘胺酸,較佳為丙胺酸。作為上述高感度甜味劑,可列舉:乙醯磺胺酸鉀、阿斯巴甜、甜菊、酵素處理甜菊、蔗糖素等。作為本發明之非醱酵之類啤酒發泡性飲料,就能以少量之含量達成充分之甜味、且亦抑制卡路里之方面而言,較佳為使用高感度甜味劑。 The non-fermented beer-foaming beverage of the present invention preferably further contains one or more sweetener components. As such a sweet component, it is preferred that the sweetness phase is compared with the monosaccharide. Specific examples of the lower ones include polysaccharides, sweet amino acids, and high-sensitivity sweeteners. The term "polysaccharide" means a saccharide obtained by polymerizing three or more monosaccharides. Polysaccharides are roughly classified into starch, dextrin, and oligosaccharides depending mainly on their size. The oligosaccharide is a saccharide obtained by polymerizing about 3 to 10 monosaccharides, and the dextrin is a saccharide obtained by hydrolyzing starch, and is larger than oligosaccharides. Examples of the sweet amino acid include alanine or glycine, and alanine is preferred. Examples of the high-sensitivity sweetener include potassium sulfonate, aspartame, stevia, enzyme-treated stevia, and sucralose. As the non-fermented beer-flavored beverage of the present invention, it is preferred to use a high-sensitivity sweetener in order to achieve a sufficient sweetness in a small amount and to suppress calories.

作為本發明之非醱酵之類啤酒發泡性飲料,亦可進而含有香味劑。作為此種香味劑,可列舉:啤酒風味物質(beer flavor)、啤酒香料、啤酒花香料等。所謂啤酒花香料,例如為含有啤酒花所含之香味成分即沉香醇(Linalool)、蛇麻葫烯環氧化物(Humulene epoxide)、酯類等作為主要成分之香料。作為上述酯類,具體而言,可列舉:異丁酸乙酯、2-甲基丁酸乙酯、及異戊酸乙酯等。 The beer-foaming beverage which is not fermented in the present invention may further contain a flavoring agent. Examples of such a flavoring agent include a beer flavor, a beer flavor, and a hop flavor. The hop flavor is, for example, a fragrance containing, as a main component, a fragrance component contained in hop, that is, Linalool, Humulene epoxide, and an ester. Specific examples of the esters include ethyl isobutyrate, ethyl 2-methylbutyrate, and ethyl isovalerate.

本發明之非醱酵之類啤酒發泡性飲料亦可進而含有乙醇。於本發明之非醱酵之類啤酒發泡性飲料含有乙醇之情形時,飲料中之乙醇濃度較佳為1體積%以上且未達10體積%,更佳為1~9體積%,進而較佳為1~8體積%,進而更佳為1~7體積%。再者,乙醇可使用酒類之製造中通常所使用之原料乙醇。 The non-fermented beer-flavored beverage of the present invention may further contain ethanol. When the non-fermented beer foaming beverage of the present invention contains ethanol, the ethanol concentration in the beverage is preferably 1% by volume or more and less than 10% by volume, more preferably 1 to 9% by volume, and further Preferably, it is 1 to 8% by volume, and more preferably 1 to 7% by volume. Further, ethanol can be used as the raw material ethanol which is usually used in the manufacture of alcohol.

本發明之非醱酵之類啤酒發泡性飲料例如可藉由將各原料混合之方法(調合法)而製造。具體而言,可藉由具有以下之步驟(a)~(b)之製造方法而製造。 The non-fermented beer foaming beverage of the present invention can be produced, for example, by a method in which each raw material is mixed (adjusted method). Specifically, it can be produced by the production method having the following steps (a) to (b).

(a)藉由將原料混合而製備調合液之步驟;及(b)向藉由上述步驟(a)而獲得之調合液中添加二氧化碳氣體之步驟。 (a) a step of preparing a conditioned liquid by mixing raw materials; and (b) a step of adding carbon dioxide gas to the conditioned liquid obtained by the above step (a).

首先,步驟(a)中,藉由將原料混合而製備調合液。步驟(a)中, 較佳為製備將二氧化碳氣體以外之所有原料混合而成之調合液。混合各原料之順序並無特別限定。可向原料水中同時添加所有原料,亦可使先添加之原料溶解後添加剩餘之原料等而依序添加原料。又,例如可於原料水中混合固體(例如粉末狀或顆粒狀)之原料及酒精,亦可事先將固體原料製成水溶液,將該等水溶液及酒精、視需要之原料水混合。 First, in the step (a), a preparation liquid is prepared by mixing raw materials. In step (a), It is preferred to prepare a blending liquid obtained by mixing all raw materials other than carbon dioxide gas. The order in which the respective raw materials are mixed is not particularly limited. All the raw materials may be simultaneously added to the raw material water, and the raw materials may be sequentially added after the first added raw materials are dissolved and the remaining raw materials are added. Further, for example, a raw material (for example, a powder or a granule) and an alcohol may be mixed in the raw material water, or the solid raw material may be prepared as an aqueous solution in advance, and the aqueous solution and the alcohol, if necessary, the raw material water may be mixed.

於步驟(a)中所製備之調合液中產生不溶物之情形時,較佳為於步驟(b)前,對該調合液進行過濾等將不溶物去除之處理。不溶物去除處理並無特別限定,可利用過濾法、離心分離法等該技術領域中通常使用之方法進行。本發明中,較佳為將不溶物過濾去除,更佳為藉由矽藻土過濾而將不溶物去除。 When the insoluble matter is produced in the preparation liquid prepared in the step (a), it is preferred to subject the preparation liquid to a treatment such as filtration to remove the insoluble matter before the step (b). The insoluble matter removal treatment is not particularly limited, and it can be carried out by a method generally used in the technical field such as a filtration method or a centrifugal separation method. In the present invention, it is preferred to remove the insoluble matter by filtration, and it is more preferable to remove the insoluble matter by filtering the diatomaceous earth.

繼而,作為步驟(b),向藉由步驟(a)而獲得之調合液中添加二氧化碳氣體。藉此獲得非醱酵之類啤酒發泡性飲料。藉由添加碳酸而賦予與啤酒相同之爽快感。再者,二氧化碳氣體之添加可藉由常法進行。例如可將藉由步驟(a)而獲得之調合液、及碳酸水混合,亦可向藉由步驟(a)而獲得之調合液中直接添加二氧化碳氣體並溶入。 Then, as step (b), carbon dioxide gas is added to the preparation liquid obtained by the step (a). Thereby, a beer-flavored beverage such as non-fermented is obtained. By adding carbonic acid, it gives the same refreshing taste as beer. Further, the addition of carbon dioxide gas can be carried out by a usual method. For example, the preparation liquid obtained by the step (a) and the carbonated water may be mixed, or the carbon dioxide gas may be directly added to the preparation liquid obtained by the step (a) and dissolved.

亦可於添加二氧化碳氣體後,對所獲得之非醱酵之類啤酒發泡性飲料進而進行過濾等將不溶物去除之處理。不溶物去除處理並無特別限定,可利用該技術領域中通常使用之方法進行。 After the addition of the carbon dioxide gas, the obtained non-fermented beer foaming beverage may be subjected to filtration or the like to remove the insoluble matter. The insoluble matter removal treatment is not particularly limited and can be carried out by a method generally used in the art.

[實施例] [Examples]

繼而示出實施例對本發明進一步詳細地進行說明,但本發明並不限定於以下之實施例。 The present invention will now be described in further detail with reference to examples, but the present invention is not limited to the following examples.

[參考例1] [Reference Example 1]

對市售之5種非醱酵之類啤酒發泡性飲料測定pH值、磷酸濃度、乳酸濃度、檸檬酸濃度、嘌呤體濃度、及乙醇濃度。市售品A及B係無酒精之類啤酒發泡性飲料,市售品C~E係含酒精之類啤酒發泡性 飲料。再者,pH值、磷酸濃度、乳酸濃度、檸檬酸濃度、及乙醇濃度係藉由常法而進行測定。於所使用之測定方法中,磷酸及乳酸之定量極限值為6ppm,檸檬酸之定量極限值為4ppm,乙醇之定量極限值為0.005體積%。 The pH value, the phosphoric acid concentration, the lactic acid concentration, the citric acid concentration, the steroid concentration, and the ethanol concentration were measured for five commercially available non-fermented beer-flavored beverages. Commercial products A and B are non-alcoholic beer-flavored beverages, and commercial products C-E are alcohol-based beer foaming properties. Drink. Further, the pH, the phosphoric acid concentration, the lactic acid concentration, the citric acid concentration, and the ethanol concentration were measured by a usual method. In the measurement method used, the quantitative limit value of phosphoric acid and lactic acid was 6 ppm, the limit value of citric acid was 4 ppm, and the limit value of ethanol was 0.005% by volume.

各飲料中之嘌呤體含量係藉由在利用過氯酸之水解後使用LC-MS/MS之方法(日本食品分析中心:「酒類之嘌呤體之微量分析之指南」)進行測定。於該測定方法中,腺嘌呤、鳥嘌呤、黃嘌呤、及次黃嘌呤各自之定量極限值為0.02mg/100mL。 The carcass content in each beverage was measured by a method of LC-MS/MS after hydrolysis with perchloric acid (Japanese Food Analysis Center: "Guide to Microanalysis of Carcasses of Alcohols"). In the assay, the quantitative limit values for each of adenine, guanine, xanthine, and hypoxanthine were 0.02 mg/100 mL.

將測定結果示於表1。表1中,磷酸及乳酸之欄之「6>」、檸檬酸之欄之「4>」、嘌呤體之欄之「0.08>」、及乙醇之欄之「0.005>」分別表示未達定量極限值。 The measurement results are shown in Table 1. In Table 1, "6>" in the column of phosphoric acid and lactic acid, "4>" in the column of citric acid, "0.08>" in the column of the body, and "0.005>" in the column of ethanol indicate that the quantitative limit is not reached. value.

[實施例1] [Example 1]

於包含表2所記載之組成之基質液中以成為0、40、80、320、560、或720ppm之方式添加磷酸,測定pH值後,以成為2.8gas vol.之方式添加二氧化碳氣體,藉此製備樣品1-1~1-6。再者,該基質液之嘌呤體濃度未達0.08mg/100mL,於該基質液添加磷酸與二氧化碳氣體而成之各樣品之嘌呤體濃度亦未達0.08mg/100mL。 Phosphoric acid was added to the matrix liquid having the composition described in Table 2 so as to be 0, 40, 80, 320, 560, or 720 ppm, and after measuring the pH value, carbon dioxide gas was added so as to be 2.8 vol. Samples 1-1 to 1-6 were prepared. Furthermore, the corpus callosum concentration of the substrate solution was less than 0.08 mg/100 mL, and the steroid concentration of each sample obtained by adding phosphoric acid and carbon dioxide gas to the substrate solution was less than 0.08 mg/100 mL.

對於各樣品,由4名專業官能檢查員於蒙眼情況下對醇香與類似啤酒味道實施官能評價。評價係以5等級評價(5:有醇香/類似啤酒、4:略有醇香/略類似啤酒、3:說不清、2:醇香略微不足/略微不類似啤酒、1:醇香非常不足/不類似啤酒)進行。 For each sample, four professional panelists were functionally evaluated for mellow and similar beer flavors in the case of a blindfold. The evaluation was evaluated on a 5th scale (5: mellow/similar beer, 4: slightly mellow/slightly similar to beer, 3: unclear, 2: slightly mellow mellow/slightly not similar to beer, 1: mellow is very insufficient/not similar Beer).

將評價結果與磷酸之含量及pH值之測定結果一併示於表3。評語欄之數值表示給出該評語之專業官能檢查員之人數。調配有磷酸之樣品1-2~1-6與未添加磷酸之樣品1-1相比,醇香改善。尤其pH值為3.2以上且4.0以下之樣品1-2及1-3之酸味較少,且類似啤酒味道亦得到改善。 The evaluation results are shown in Table 3 together with the measurement results of the phosphoric acid content and the pH value. The value of the comment bar indicates the number of professional inspectors who gave the comment. The mellowness of the sample 1-2 to 1-6 prepared with phosphoric acid was improved as compared with the sample 1-1 to which no phosphoric acid was added. In particular, samples 1-2 and 1-3 having a pH of 3.2 or more and 4.0 or less have less sourness and are similar in beer taste.

[實施例2] [Embodiment 2]

於包含表2所記載之組成之基質液中以成為0、50、100、300、500、或700ppm之方式添加磷酸,進而添加檸檬酸三鈉而將pH值調整為3.8後,以成為2.8gas vol.之方式添加二氧化碳氣體,藉此製備樣品2-2~2-6。作為對照,於包含表2所記載之組成之基質液(pH值6.18)中以成為2.8gas vol.之方式添加二氧化碳氣體,藉此製備樣品2-1。 以與實施例1相同之方式對各樣品之醇香與類似啤酒味道實施官能評價。將評價結果與磷酸濃度及由添加檸檬酸三鈉所得之檸檬酸濃度一併示於表4。 Phosphoric acid was added to the matrix liquid having the composition described in Table 2 to be 0, 50, 100, 300, 500, or 700 ppm, and trisodium citrate was added thereto to adjust the pH to 3.8 to obtain 2.8 gas. Samples 2-2 to 2-6 were prepared by adding carbon dioxide gas in the form of vol. As a control, carbon dioxide gas was added to the substrate liquid (pH 6.18) having the composition described in Table 2 so as to be 2.8 gas vol., thereby preparing Sample 2-1. Functional evaluation of the mellowness and similar beer taste of each sample was carried out in the same manner as in Example 1. The evaluation results are shown in Table 4 together with the phosphoric acid concentration and the citric acid concentration obtained by adding trisodium citrate.

如表4所示,於藉由檸檬酸三鈉而將pH值調整為3.8之樣品2-2~2-6中,磷酸濃度為50~500ppm之樣品2-2~2-5之醇香與類似啤酒味道得到改善。即表明,於將pH值調整至作為類啤酒發泡性飲料而較佳之範圍內之情形時,藉由將磷酸濃度設為50~500ppm,可賦予醇香感,且改善類似啤酒味道。 As shown in Table 4, in the sample 2-2 to 2-6 in which the pH was adjusted to 3.8 by trisodium citrate, the mellow of the sample 2-2 to 2-5 having a phosphoric acid concentration of 50 to 500 ppm was similar. The beer taste is improved. That is, when the pH is adjusted to a range which is preferable as a beer-like sparkling beverage, by setting the phosphoric acid concentration to 50 to 500 ppm, it is possible to impart a mellow sensation and to improve a beer-like taste.

又,使用包含表5所記載之組成之基質液(於表2所記載之基質液中添加乙醇而成者)代替表2所記載之基質液,以與樣品2-1~2-6相同之方式製備樣品,對所獲得之樣品進行官能評價,結果同樣地,將pH值調整為3.8、且磷酸濃度為50~500ppm之樣品之醇香與類似啤酒味道得到改善。 Further, in place of the sample liquids described in Table 2, the base liquids containing the composition described in Table 5 (the base liquid added in Table 2 were added) were the same as those of the samples 2-1 to 2-6. The sample was prepared in a manner, and the obtained sample was subjected to a sensory evaluation. As a result, the mellow taste and the similar beer taste of the sample having a pH adjusted to 3.8 and a phosphoric acid concentration of 50 to 500 ppm were improved.

[實施例3] [Example 3]

於包含表2所記載之組成之基質液中以成為0、50、100、300、500、或700ppm之方式添加乳酸,測定pH值後,以成為2.8gas vol.之方式添加二氧化碳氣體,藉此製備樣品3-1~3-6。以與實施例1相同之方式對各樣品之醇香與類似啤酒味道實施官能評價。 Lactic acid was added to the matrix liquid having the composition described in Table 2 to be 0, 50, 100, 300, 500, or 700 ppm, and after measuring the pH value, carbon dioxide gas was added so as to be 2.8 gas vol. Samples 3-1 to 3-6 were prepared. Functional evaluation of the mellowness and similar beer taste of each sample was carried out in the same manner as in Example 1.

將評價結果與乳酸之含量及pH值之測定結果一併示於表6。調配有乳酸之樣品3-2~3-6與未添加乳酸之樣品3-1相比,醇香改善。尤其pH值為3.2以上且4.0以下之樣品3-2、3-3、及3-4之酸味較少,且類似啤酒味道亦得到改善。 The evaluation results are shown in Table 6 together with the measurement results of the lactic acid content and the pH value. The mellowness of the sample 3-2 to 3-6 in which lactic acid was formulated was improved as compared with the sample 3-1 in which lactic acid was not added. In particular, samples 3-2, 3-3, and 3-4 having a pH of 3.2 or more and 4.0 or less have less sourness and are similar in beer taste.

[實施例4] [Example 4]

於包含表2所記載之組成之基質液中以成為0、50、100、300、500、或700ppm之方式添加乳酸,進而添加檸檬酸三鈉而將pH值調整為3.8後,以成為2.8gas vol.之方式添加二氧化碳氣體,藉此製備樣品4-2~4-6。作為對照,於包含表2所記載之組成之基質液(pH值6.18)中以成為2.8gas vol.之方式添加二氧化碳氣體,藉此製備樣品4-1。以與實施例1相同之方式對各樣品之醇香與類似啤酒味道實施官能評價。將評價結果與乳酸濃度及由添加檸檬酸三鈉所得之檸檬酸濃度一併示於表7。 In the base liquid containing the composition described in Table 2, lactic acid was added at 0, 50, 100, 300, 500, or 700 ppm, and trisodium citrate was added to adjust the pH to 3.8 to obtain 2.8 gas. Samples 4-2 to 4-6 were prepared by adding carbon dioxide gas in the form of vol. As a control, carbon dioxide gas was added to the substrate liquid (pH 6.18) having the composition described in Table 2 so as to be 2.8 gas vol., thereby preparing Sample 4-1. Functional evaluation of the mellowness and similar beer taste of each sample was carried out in the same manner as in Example 1. The evaluation results are shown in Table 7 together with the lactic acid concentration and the citric acid concentration obtained by adding trisodium citrate.

如表7所示,於藉由檸檬酸三鈉而將pH值調整為3.8之樣品4-2~4-6中,乳酸濃度為50~500ppm之樣品4-2~4-5之醇香與類似啤酒味道得到改善。即表明,於將pH值調整至作為類啤酒發泡性飲料而較佳之範圍內之情形時,藉由將乳酸濃度設為50~500ppm,可賦予醇香感,且改善類似啤酒味道。 As shown in Table 7, in the samples 4-2 to 4-6 in which the pH was adjusted to 3.8 by trisodium citrate, the mellows of the samples 4-2 to 4-5 having a lactic acid concentration of 50 to 500 ppm were similar. The beer taste is improved. That is, when the pH is adjusted to a preferred range as a beer-like sparkling beverage, by setting the lactic acid concentration to 50 to 500 ppm, the mellow feeling can be imparted, and the beer-like taste can be improved.

又,製備將實施例2中所製造之樣品與本實施例中所製造之樣品混合而成之樣品,以相同方式進行官能評價。具體而言,製備將樣品2-2與4-2、樣品2-3與4-3、樣品2-4與4-4、樣品2-5與4-5、樣品2-6與4-6分別以1:1混合而成之樣品,對所獲得之樣品進行官能評價。其結果為,磷酸與乳酸之濃度之和為50~500ppm之樣品(樣品2-2與4-2之混合樣品、樣品2-3與4-3之混合樣品、樣品2-4與4-4之混合樣品、及樣品2-5與4-5之混合樣品)之醇香與類似啤酒味道得到改善。即表明,於將pH值調整至作為類啤酒發泡性飲料而較佳之範圍內之情形時,藉由將磷酸與乳酸之濃度之和設為50~500ppm,可賦予醇香感,且改善類似啤酒味道。 Further, a sample obtained by mixing the sample prepared in Example 2 with the sample produced in the present example was prepared, and the sensory evaluation was carried out in the same manner. Specifically, samples 2-2 and 4-2, samples 2-3 and 4-3, samples 2-4 and 4-4, samples 2-5 and 4-5, samples 2-6 and 4-6 were prepared. The samples obtained were mixed with a 1:1 sample, and the obtained samples were subjected to sensory evaluation. As a result, the sum of the concentration of phosphoric acid and lactic acid is 50 to 500 ppm (mixed sample of samples 2-2 and 4-2, mixed sample of samples 2-3 and 4-3, samples 2-4 and 4-4) The mellow and similar beer flavors of the mixed sample, and the mixed samples of samples 2-5 and 4-5 were improved. That is, when the pH is adjusted to a preferred range as a beer-like sparkling beverage, by setting the sum of the concentrations of phosphoric acid and lactic acid to 50 to 500 ppm, the mellow feeling can be imparted, and the similar beer can be improved. taste.

又,使用包含表5所記載之組成之基質液代替表2所記載之基質液,以與樣品4-1~4-6相同之方式製備樣品,對所獲得之樣品進行官能評價,結果同樣地,將pH值調整為3.8、且乳酸濃度為50~500ppm之樣品之醇香與類似啤酒味道得到改善。 Further, a substrate liquid having the composition shown in Table 5 was used instead of the substrate liquid described in Table 2, and samples were prepared in the same manner as in Samples 4-1 to 4-6, and the obtained samples were subjected to sensory evaluation, and the results were similarly The mellow and similar beer flavor of the sample having a pH adjusted to 3.8 and a lactic acid concentration of 50 to 500 ppm was improved.

[實施例5] [Example 5]

於包含表2所記載之組成之基質液中以成為500ppm之方式添加磷酸,進而添加表8所示之各鹽類而將pH值調整為3.8後,以成為2.8gas vol.之方式添加二氧化碳氣體,藉此製備樣品5-1~5-7。由4名專業官能檢查員於蒙眼情況下對各樣品之類似啤酒味道實施官能評價。評價係以4等級評價(◎:類似啤酒、○:略微類似啤酒、△:略微不類似啤酒、×:不類似啤酒)進行。 Phosphoric acid was added to the matrix liquid having the composition shown in Table 2 to add 500 ppm, and each salt shown in Table 8 was added to adjust the pH to 3.8, and then carbon dioxide gas was added so as to be 2.8 vol. Thus, samples 5-1 to 5-7 were prepared. A sensory evaluation of the similar beer taste of each sample was performed by four professional inspectors in the case of a blind eye. The evaluation was carried out in four grades (◎: similar to beer, ○: slightly similar to beer, Δ: slightly different from beer, ×: not similar to beer).

將評價結果與酸味料之濃度(ppm)一併示於表8。使用檸檬酸三鈉、葡萄糖酸鉀、及葡萄糖酸鈉之樣品5-1~5-3與使用其他酸味料而調整了pH值之樣品相比,類似啤酒之香味優異。其中,使用檸檬酸三鈉之樣品5-1之使用量較葡萄糖酸鉀及葡萄糖酸鈉少。 The evaluation results are shown in Table 8 together with the concentration (ppm) of the sour material. Samples 5-1 to 5-3 using trisodium citrate, potassium gluconate, and sodium gluconate were superior to beer-like flavors compared to samples adjusted to pH values using other sour materials. Among them, Sample 5-1 using trisodium citrate was used in a smaller amount than potassium gluconate and sodium gluconate.

[實施例6] [Embodiment 6]

於包含表2所記載之組成之基質液中以成為1.5g/L之方式添加大豆食物纖維(不二製油股份有限公司之「SOYAFIBE S-LA200」),以成為300、500、700、或1000ppm之方式添加磷酸,進而添加檸檬酸三鈉而將pH值調整為3.8後,以成為2.8gas vol.之方式添加二氧化碳氣體,藉此製備樣品6-1~6-4。以與實施例1相同之方式對各樣品之醇香與類似啤酒味道實施官能評價。將評價結果與磷酸濃度及由添加檸檬酸三鈉所得之檸檬酸濃度一併示於表9。 Soybean dietary fiber ("SOYAFIBE S-LA200" of Fuji Oil Co., Ltd.) was added to the base liquid containing the composition described in Table 2 so as to be 1.5 g/L to become 300, 500, 700, or 1000 ppm. In the manner of adding phosphoric acid, and adding trisodium citrate to adjust the pH to 3.8, carbon dioxide gas was added so as to be 2.8 vol., thereby preparing samples 6-1 to 6-4. Functional evaluation of the mellowness and similar beer taste of each sample was carried out in the same manner as in Example 1. The evaluation results are shown in Table 9 together with the phosphoric acid concentration and the citric acid concentration obtained by adding trisodium citrate.

如表9所示,於含有大豆食物纖維且藉由檸檬酸三鈉而將pH值調整為3.8之樣品中,磷酸濃度為300~700ppm之樣品6-1~6-3之醇香與類似啤酒味道均得到改善。即表明,於將pH值調整至作為類啤酒發泡性飲料而較佳之範圍內,且亦含有水溶性食物纖維之情形時,藉由將磷酸濃度設為700ppm以下,可明顯改善醇香感與類似啤酒味道兩者。 As shown in Table 9, in the sample containing soybean dietary fiber and adjusting the pH to 3.8 by trisodium citrate, the mellow flavor of the sample 6-1~6-3 with a phosphoric acid concentration of 300-700 ppm and the taste similar to beer. Both have been improved. That is, when the pH is adjusted to a preferred range as a beer-like sparkling beverage, and the water-soluble dietary fiber is also contained, the mellow odor and the like can be remarkably improved by setting the phosphoric acid concentration to 700 ppm or less. Beer tastes both.

又,使用包含表5所記載之組成之基質液代替表2所記載之基質液,以與樣品6-1~6-4相同之方式製備樣品,對所獲得之樣品進行官能評價,結果同樣地,將pH值調整為3.8、亦含有水溶性食物纖維、且磷酸濃度為300~700ppm之樣品之醇香與類似啤酒味道兩者得到改善。 Further, a sample liquid containing the composition described in Table 5 was used instead of the substrate liquid described in Table 2, and a sample was prepared in the same manner as Samples 6-1 to 6-4, and the obtained sample was subjected to sensory evaluation, and the results were similarly The mellow and the similar beer taste of the sample having a pH adjusted to 3.8, also containing water-soluble dietary fiber, and having a phosphoric acid concentration of 300 to 700 ppm were improved.

[實施例7] [Embodiment 7]

於包含表2所記載之組成之基質液中以成為1.5g/L之方式添加大豆食物纖維(不二製油股份有限公司之「SOYAFIBES-LA200」),以成為300、500、700、或1000ppm之方式添加乳酸,進而添加檸檬酸三鈉而將pH值調整為3.8後,以成為2.8gas vol.之方式添加二氧化碳氣體,藉此製備樣品7-1~7-4。以與實施例1相同之方式對各樣品之醇香與類似啤酒味道實施官能評價。將評價結果與乳酸濃度及由添加檸 檬酸三鈉所得之檸檬酸濃度一併示於表10。 Soybean dietary fiber ("SOYAFIBES-LA200" of Fuji Oil Co., Ltd.) was added to the substrate liquid containing the composition described in Table 2 to be 1.5 g/L to be 300, 500, 700, or 1000 ppm. In the manner of adding lactic acid and further adding trisodium citrate to adjust the pH to 3.8, carbon dioxide gas was added so as to be 2.8 vol., thereby preparing samples 7-1 to 7-4. Functional evaluation of the mellowness and similar beer taste of each sample was carried out in the same manner as in Example 1. Will evaluate the results with lactic acid concentration and add lemon The citric acid concentration obtained from trisodium citrate is shown in Table 10.

如表10所示,於含有大豆食物纖維且藉由檸檬酸三鈉而將pH值調整為3.8之樣品中,乳酸濃度為300~700ppm之樣品7-1~7-3之醇香與類似啤酒味道均得到改善。即表明,於將pH值調整至作為類啤酒發泡性飲料而較佳之範圍內,且亦含有水溶性食物纖維之情形時,藉由將乳酸濃度設為700ppm以下,可明顯改善醇香感與類似啤酒味道兩者。 As shown in Table 10, in the sample containing soybean dietary fiber and adjusting the pH to 3.8 by trisodium citrate, the mellow flavor of the sample 7-1~7-3 with the lactic acid concentration of 300-700 ppm and the taste similar to beer. Both have been improved. That is, when the pH is adjusted to a preferred range as a beer-like sparkling beverage, and the water-soluble dietary fiber is also contained, the mellow sensation and the like can be remarkably improved by setting the lactic acid concentration to 700 ppm or less. Beer tastes both.

又,製備將實施例6中所製造之樣品與本實施例中所製造之樣品混合而成之樣品,以相同之方式進行官能評價。具體而言,製備將樣品6-1與7-1、樣品6-2與7-2、樣品6-3與7-3、樣品6-4與7-4分別以1:1混合而成之樣品,對所獲得之樣品進行官能評價。其結果為,磷酸與乳酸之濃度之和為300~700ppm之樣品(樣品6-1與7-1之混合樣品、樣品6-2與7-2之混合樣品、及樣品6-3與7-3之混合樣品)之醇香與類似啤酒味道得到改善。即得知,於將pH值調整至作為類啤酒發泡性飲料而較佳之範圍內,且亦含有水溶性食物纖維之情形時,藉由將磷酸與乳酸之濃度之和設為700ppm以下,可明顯改善醇香感與類似啤酒味道兩者。 Further, a sample obtained by mixing the sample prepared in Example 6 with the sample produced in the present example was prepared, and the sensory evaluation was carried out in the same manner. Specifically, preparations were prepared by mixing 1:1 and 7-1, samples 6-2 and 7-2, samples 6-3 and 7-3, and samples 6-4 and 7-4, respectively, in a ratio of 1:1. The sample was subjected to a sensory evaluation of the obtained sample. As a result, the sum of the concentration of phosphoric acid and lactic acid is 300 to 700 ppm (mixed sample of samples 6-1 and 7-1, mixed sample of samples 6-2 and 7-2, and samples 6-3 and 7-) The mellow and similar beer flavor of the mixed sample of 3 was improved. In other words, when the pH is adjusted to a preferred range as a beer-like sparkling beverage, and the water-soluble dietary fiber is also contained, the sum of the concentrations of phosphoric acid and lactic acid is 700 ppm or less. Significantly improved both mellow and beer-like taste.

又,使用包含表5所記載之組成之基質液代替表2所記載之基質液,以與樣品7-1~7-4相同之方式製備樣品,對所獲得之樣品進行官 能評價,結果同樣地,於將pH值調整為3.8、亦含有水溶性食物纖維、且乳酸濃度為300~700ppm之樣品之醇香與類似啤酒味道兩者得到改善。 Further, a substrate liquid having the composition shown in Table 5 was used instead of the substrate liquid described in Table 2, and samples were prepared in the same manner as in Samples 7-1 to 7-4, and the obtained sample was subjected to an official procedure. As a result, in the same manner, both the mellow and the beer-like taste of the sample having the pH adjusted to 3.8, the water-soluble dietary fiber, and the lactic acid concentration of 300 to 700 ppm were improved.

[實施例8] [Embodiment 8]

於包含表2所記載之組成之基質液中調配磷酸、乳酸、檸檬酸三鈉、乙醇、其他各種成分而製備樣品8-1~8-3。以與參考例1相同之方式對各樣品之pH值、磷酸濃度、乳酸濃度、檸檬酸濃度、嘌呤體濃度、及乙醇濃度進行測定。將測定結果示於表11。所獲得之樣品8-1~8-3均為具備充分之醇香、類似啤酒、溫和且調和之可口性非常高的非醱酵之類啤酒發泡性飲料。 Samples 8-1 to 8-3 were prepared by mixing phosphoric acid, lactic acid, trisodium citrate, ethanol, and other various components in the substrate liquid containing the composition described in Table 2. The pH, the phosphoric acid concentration, the lactic acid concentration, the citric acid concentration, the steroid concentration, and the ethanol concentration of each sample were measured in the same manner as in Reference Example 1. The measurement results are shown in Table 11. The obtained samples 8-1 to 8-3 were all non-fermented beer-flavored beverages having a sufficient mellow flavor, similar to beer, mild and harmonious, and very high in palatability.

[產業上之可利用性] [Industrial availability]

本發明之非醱酵之類啤酒發泡性飲料係含有嘌呤體之原料之添加量經調整,儘管嘌呤體濃度非常低亦具有充分之醇香,因此尤其可用於類啤酒發泡性飲料及其製造領域中。 The non-fermented beer foaming beverage of the present invention is adjusted in the amount of the raw material containing the carcass, and is particularly useful for beer-like foaming beverages and the manufacture thereof, although the carcass concentration is very low and has sufficient mellow flavor. In the field.

Claims (9)

一種非醱酵之類啤酒發泡性飲料,其係含有嘌呤體之原料之添加量經調整,嘌呤體濃度為0.2mg/100mL以下,選自由磷酸及乳酸所組成之群中之1種以上之有機酸的含量為40~700ppm,且pH值為3.2~4.5。 A non-fermented beer-flavored beverage, wherein the amount of the raw material containing the steroid is adjusted, and the steroid concentration is 0.2 mg/100 mL or less, and is selected from the group consisting of phosphoric acid and lactic acid. The organic acid content is 40 to 700 ppm, and the pH is 3.2 to 4.5. 如請求項1之非醱酵之類啤酒發泡性飲料,其進而含有選自由檸檬酸之鹽類及葡萄糖酸之鹽類所組成之群中之1種以上。 The beer-flavored beverage of the non-fermented product of claim 1 further contains one or more selected from the group consisting of salts of citric acid and salts of gluconic acid. 如請求項1之非醱酵之類啤酒發泡性飲料,其以非醱酵之類啤酒發泡性飲料每單位之檸檬酸濃度成為10~650ppm之方式含有檸檬酸之鈉鹽。 The beer-flavored beverage of the non-fermented beer of the claim 1 contains a sodium salt of citric acid in such a manner that the citric acid concentration per unit of the non-fermented beer foaming beverage is 10 to 650 ppm. 如請求項1至3中任一項之非醱酵之類啤酒發泡性飲料,其中嘌呤體濃度為0.08mg/100mL以下。 The non-fermented beer foaming beverage according to any one of claims 1 to 3, wherein the steroid concentration is 0.08 mg/100 mL or less. 如請求項1至4中任一項之非醱酵之類啤酒發泡性飲料,其中糖類濃度為0.5g/100mL以下。 The non-fermented beer foaming beverage according to any one of claims 1 to 4, wherein the saccharide concentration is 0.5 g/100 mL or less. 如請求項1至5中任一項之非醱酵之類啤酒發泡性飲料,其中選自由磷酸及乳酸所組成之群中之1種以上之有機酸的含量為40~500ppm。 The non-fermented beer-foaming beverage according to any one of claims 1 to 5, wherein a content of one or more organic acids selected from the group consisting of phosphoric acid and lactic acid is 40 to 500 ppm. 如請求項1至6中任一項之非醱酵之類啤酒發泡性飲料,其進而含有水溶性食物纖維。 A non-fermented beer-foaming beverage according to any one of claims 1 to 6, which further comprises a water-soluble dietary fiber. 如請求項7之非醱酵之類啤酒發泡性飲料,其中上述水溶性食物纖維為大豆食物纖維。 The non-fermented beer foaming beverage according to claim 7, wherein the water-soluble dietary fiber is soybean dietary fiber. 如請求項1至8中任一項之非醱酵之類啤酒發泡性飲料,其進而含有乙醇。 A non-fermented beer-foaming beverage according to any one of claims 1 to 8, which further contains ethanol.
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