TW201334904A - Splitting method of processed object and splitting method of substrate having optical element pattern - Google Patents

Splitting method of processed object and splitting method of substrate having optical element pattern Download PDF

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TW201334904A
TW201334904A TW101142491A TW101142491A TW201334904A TW 201334904 A TW201334904 A TW 201334904A TW 101142491 A TW101142491 A TW 101142491A TW 101142491 A TW101142491 A TW 101142491A TW 201334904 A TW201334904 A TW 201334904A
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laser light
workpiece
scribe line
scribing
irradiation
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Tetsuo Hoki
Shohei Nagatomo
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Mitsuboshi Diamond Ind Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/36Removing material
    • B23K26/38Removing material by boring or cutting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/351Working by laser beam, e.g. welding, cutting or boring for trimming or tuning of electrical components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/50Working by transmitting the laser beam through or within the workpiece
    • B23K26/53Working by transmitting the laser beam through or within the workpiece for modifying or reforming the material inside the workpiece, e.g. for producing break initiation cracks
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B33/00Severing cooled glass
    • C03B33/09Severing cooled glass by thermal shock
    • C03B33/091Severing cooled glass by thermal shock using at least one focussed radiation beam, e.g. laser beam
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02365Forming inorganic semiconducting materials on a substrate
    • H01L21/02656Special treatments
    • H01L21/02664Aftertreatments
    • H01L21/02667Crystallisation or recrystallisation of non-monocrystalline semiconductor materials, e.g. regrowth
    • H01L21/02675Crystallisation or recrystallisation of non-monocrystalline semiconductor materials, e.g. regrowth using laser beams
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76838Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
    • H01L21/76886Modifying permanently or temporarily the pattern or the conductivity of conductive members, e.g. formation of alloys, reduction of contact resistances
    • H01L21/76892Modifying permanently or temporarily the pattern or the conductivity of conductive members, e.g. formation of alloys, reduction of contact resistances modifying the pattern
    • H01L21/76894Modifying permanently or temporarily the pattern or the conductivity of conductive members, e.g. formation of alloys, reduction of contact resistances modifying the pattern using a laser, e.g. laser cutting, laser direct writing, laser repair
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2101/00Articles made by soldering, welding or cutting
    • B23K2101/36Electric or electronic devices
    • B23K2101/40Semiconductor devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/50Inorganic material, e.g. metals, not provided for in B23K2103/02 – B23K2103/26
    • B23K2103/56Inorganic material, e.g. metals, not provided for in B23K2103/02 – B23K2103/26 semiconducting
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/40Details of apparatuses used for either manufacturing connectors or connecting the semiconductor or solid-state body
    • H01L2924/401LASER
    • H01L2924/402Type
    • H01L2924/4025Type being a gas
    • H01L2924/40252CO2 LASER

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical & Material Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Computer Hardware Design (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Laser Beam Processing (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
  • Processing Of Stones Or Stones Resemblance Materials (AREA)
  • Dicing (AREA)

Abstract

This invention provides a splitting method of a brittle material processed object with high precision and high efficiency. The splitting method of a processed object comprises the following steps: irradiating a first laser beam to a scribed surface of the processed object to form a scribed line on the scribed surface; irradiating a second laser beam along the scribed line from a non-scribed surface to heat the processed object along the scribed line; and in the subsequent steps, using the second laser beam to perform relative scanning with the scribed surface being in contact with a cooling medium so as to move and cool down a tensile stress field formed in the processed object and adjacent to the scribed line. Therefore, cracks from the scribed line toward the non-scribed surface generated due to the scribed line within the tensile stress field are allowed to progress along the scribed line sequentially for splitting the processed object.

Description

被加工物之分斷方法及具有光學元件圖案之基板的分斷方法 Method for breaking workpiece and method for breaking substrate with optical element pattern

本發明係關於一種藉由照射雷射光而分斷被加工物之方法。 The present invention relates to a method of breaking a workpiece by irradiating laser light.

作為切出玻璃板或藍寶石基板等較硬且較脆之材料(脆性材料)之加工方法,周知有各種方法。例如,作為玻璃板之加工,熟知有如下方法:以金剛石之結晶等自欲切開之材料之端部呈線狀地設置較淺之傷痕(初期龜裂)即進行所謂之畫線,並對所形成之初期龜裂之兩側施加力而使該初期龜裂沿厚度方向進展,從而分斷玻璃板。 As a method of processing a hard and brittle material (brittle material) such as a glass plate or a sapphire substrate, various methods are known. For example, as a processing of a glass plate, a method of forming a shallow scratch (initial crack) in a line shape from the end portion of a material to be cut, such as a crystal of diamond, is known, and the so-called drawing is performed. A force is applied to both sides of the initial crack formed to advance the initial crack in the thickness direction, thereby breaking the glass sheet.

然而,於此種方法之情形時,當進行分斷作業時,根據畫線之深度或力之施加方向等而於分斷面產生傾斜、或向預料外之方向破裂等,無法獲得所期望之分斷精度,於最差之情形時,亦有整個材料破損之危險性。 However, in the case of such a method, when the breaking operation is performed, the inclination is generated in the sectional section or the direction is unexpectedly broken according to the depth of the drawn line or the direction in which the force is applied, etc., and the desired result cannot be obtained. Breaking accuracy, in the worst case, there is also the risk of damage to the entire material.

又,熟知亦有如下方法:藉由預先對被加工物之端部賦予初期龜裂並自該端部進行利用雷射光之加熱掃描,而使龜裂進展從而分斷被加工物(例如,參照專利文獻1)。 Further, it is known that a method is provided in which an initial crack is applied to an end portion of a workpiece and a heating scan by laser light is applied from the end portion, whereby the crack progresses and the workpiece is separated (for example, reference) Patent Document 1).

於此種方法之情形時,若作為分斷對象之脆性材料為均質且所產生之應力場為理想之應力場,則存在可高精度地控制龜裂進展之位置或方向等之可能性,但現實中,就材料之不均質性、或加熱能量分佈之不均一性、或加熱點之高精度之位置控制之難度等方面而言,很難以高精度控制龜裂進展。此處所謂之高精度,係假設以μm級之精度之 位置控制。 In the case of such a method, if the brittle material as the breaking target is homogeneous and the generated stress field is an ideal stress field, there is a possibility that the position or direction of the crack progress can be controlled with high precision, but In reality, it is difficult to control the progress of cracks with high precision in terms of material inhomogeneity, heterogeneity of heating energy distribution, or difficulty in position control of high-precision heating points. The high precision mentioned here is assumed to be accurate in the order of μm. Position control.

而且,就於被加工物之端部產生應力分散而應力分佈變得不均勻等原因而言,於龜裂進展控制中,需要限制加工順序或進行敢於錯開加熱點之處理等(例如,參照專利文獻2)。 In addition, in the crack growth progress control, it is necessary to limit the processing order or the process of dare to stagger the heating point, for example, in the case where stress dispersion occurs at the end portion of the workpiece and the stress distribution becomes uneven. Literature 2).

又,當將表面二維地排列有單位圖案之脆性材料切出為每單位圖案之單片(晶片單位)之情形時等,於設為藉由雷射割斷而進行在彼此正交之2個方向上之切出之情形時,於某一方向上切出後,再於與該方向正交之方向上進行切出,但在如大量之晶片加工之情形時,初期龜裂之賦予方法等變得更加繁雜。 In addition, when a brittle material in which a unit pattern is two-dimensionally arranged is cut out into a single piece (wafer unit) per unit pattern, two of them are orthogonal to each other by laser cutting. In the case of cutting out in the direction, after cutting in a certain direction, cutting is performed in a direction orthogonal to the direction, but in the case of processing a large amount of wafers, the method of imparting initial cracks is changed. It is more complicated.

作為以上方法之組合,亦已知有如下方法:於利用金剛石或維氏壓頭等在硬脆性材料基板(例如玻璃、矽、陶瓷、藍寶石等)之端部設置微小之傷痕(初期龜裂)後,於基板背面側配置雷射光吸收材,並對基板背面利用經焦點對準之雷射照射進行局部加熱,藉由由此產生之應力集中而使龜裂進展從而分斷玻璃(例如,參照專利文獻3)。 As a combination of the above methods, there is also known a method of providing a minute flaw (initial crack) on the end of a hard and brittle material substrate (for example, glass, enamel, ceramic, sapphire, etc.) by using a diamond or a Vickers indenter. Thereafter, a laser light absorbing material is disposed on the back surface side of the substrate, and the back surface of the substrate is locally heated by the focused laser irradiation, and the stress is concentrated to cause the crack to progress to separate the glass (for example, reference) Patent Document 3).

或者,亦周知有如下方法:於預先在被加工物之表面機械地或藉由雷射光之照射而施加稱為畫線或劃線之線狀加工痕後,沿著此種加工痕進行利用雷射光之照射加熱,而產生自該加工痕之裂痕進展,由此分斷被加工物(例如,參照專利文獻4及專利文獻5)。 Alternatively, it is also known that a method of applying a line-like processing mark called a drawing line or a scribe line to a surface of a workpiece or a laser beam by irradiation of a laser beam in advance is used. When the irradiation of the light is heated, the crack is progressed from the processing mark, and the workpiece is separated (for example, refer to Patent Document 4 and Patent Document 5).

再者,於專利文獻3中,亦揭示有自與畫線相反側之面照射雷射而進行分斷之形態。 Further, in Patent Document 3, a form in which a laser beam is irradiated from a surface opposite to the line to be cut is also disclosed.

進而,亦周知有如下方法:藉由於發光元件之側面藉由乾式蝕刻而設置凹凸而提高發光效率(例如,參照專利文獻6)。 Further, it is known that the light-emitting efficiency is improved by providing irregularities on the side surface of the light-emitting element by dry etching (for example, see Patent Document 6).

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

[專利文獻1]日本專利特公平3-13040號公報 [Patent Document 1] Japanese Patent Special Fair No. 3-13040

[專利文獻2]日本專利特開平9-45636號公報 [Patent Document 2] Japanese Patent Laid-Open No. Hei 9-45636

[專利文獻3]日本專利特開2008-62547號公報 [Patent Document 3] Japanese Patent Laid-Open Publication No. 2008-62547

[專利文獻4]日本專利第2712723號公報 [Patent Document 4] Japanese Patent No. 2712723

[專利文獻5]日本專利第3036906號公報 [Patent Document 5] Japanese Patent No. 3036906

[專利文獻6]日本專利第3852000號公報 [Patent Document 6] Japanese Patent No. 3852000

於專利文獻3中揭示之方法之情形時,藉由雷射光直接加熱者終歸為雷射光吸收材,硬脆性材料基板僅為藉由來自雷射光吸收材之熱傳導而間接被加熱。因此,難以確保熱傳導之均一性,且拉伸應力未必作用於意圖作用之方向上。又,與如專利文獻1中揭示之以往之雷射割斷同樣,難以控制龜裂之進展方向。因此,難以藉由此種方法進行高精度之分斷。 In the case of the method disclosed in Patent Document 3, the direct heating by the laser light is ultimately classified as a laser light absorbing material, and the hard and brittle material substrate is indirectly heated only by heat conduction from the laser light absorbing material. Therefore, it is difficult to ensure the uniformity of heat conduction, and the tensile stress does not necessarily act in the direction in which the action is intended. Further, similarly to the conventional laser cutting as disclosed in Patent Document 1, it is difficult to control the progress direction of the crack. Therefore, it is difficult to perform high-precision breaking by such a method.

又,專利文獻4及專利文獻5中揭示者充其量僅為藉由沿著機械地或利用雷射光形成之加工痕照射雷射光而分斷被加工物之基本原理,關於高效率地進行此種分斷之方法,並未作任何揭示及暗示。 Further, in Patent Document 4 and Patent Document 5, the basic principle of breaking the workpiece by irradiating the laser light with a machining mark formed by mechanical or laser light is sufficient, and such a division is performed efficiently. The method of breaking is not disclosed or implied.

又,專利文獻6中,關於藉由對發光元件之半導體膜之側面實施凹凸加工而提高光掠出效率進行了揭示,但關於對於作為該基材之藍寶石晶圓之加工並未作揭示。若利用專利文獻6中揭示之方法對藍寶石基板實施凹凸加工,則需要重新進行抗蝕劑塗佈處理,並且蝕刻本身需要時間,因而存在生產率較低這一問題。 Further, Patent Document 6 discloses that the light extraction efficiency is improved by performing the uneven processing on the side surface of the semiconductor film of the light-emitting element. However, the processing of the sapphire wafer as the substrate is not disclosed. When the sapphire substrate is subjected to the concavo-convex processing by the method disclosed in Patent Document 6, it is necessary to perform the resist coating treatment again, and the etching itself takes time, so that there is a problem that the productivity is low.

本發明係鑒於上述課題而完成者,其目的在於提供一種可高精度且高效率地分斷包含脆性材料之被加工物之技術。又,特別係提供一種當於表面二維地形成有發光元件圖案之具有圖案之基板為被加工物之情形時,除該等高精度且高效率之加工以外,亦同時實現提高發光元件之發光效率之技術。 The present invention has been made in view of the above problems, and an object thereof is to provide a technique for cutting a workpiece including a brittle material with high precision and high efficiency. Further, in particular, when a substrate having a pattern in which a light-emitting element pattern is two-dimensionally formed on a surface is a workpiece, it is possible to simultaneously improve the light-emitting element in addition to the high-precision and high-efficiency processing. The technology of efficiency.

為解決上述課題,技術方案1之發明之特徵在於:其係分斷被加工物之方法,且包括:劃線加工步驟,藉由使第1雷射光自第1出射源出射,並對上述被加工物之劃線面照射上述第1雷射光,而於上述劃線面上形成劃線;及照射加熱步驟,藉由使第2雷射光自第2出射源出射,並自上述劃線面之相反面即非劃線面側沿著上述劃線照射上述第2雷射光,而將上述被加工物沿著上述劃線進行加熱;且於上述照射加熱步驟中,藉由於以使上述劃線面與冷卻媒體接觸之方式將上述被加工物載置於上述冷卻媒體上之狀態下使上述第2雷射光沿著上述劃線相對地進行掃描,而藉由上述第2雷射光向上述非劃線面之照射,使形成於包含 上述劃線面之上述被加工物之內部且為上述劃線附近的拉伸應力場移動並冷卻,藉此,使因上述劃線位於上述拉伸應力場內而產生之自上述劃線向上述非劃線面之裂痕之進展沿著上述劃線依序產生,從而將上述被加工物分斷。 In order to solve the above problems, the invention of claim 1 is characterized in that it is a method of dividing a workpiece, and includes a scribing processing step of causing the first laser light to be emitted from the first emission source and The scribing surface of the processed object is irradiated with the first laser light, and a scribing line is formed on the scribing surface; and an irradiation heating step is performed by ejecting the second laser light from the second ejecting source and from the scribing surface The opposite surface, that is, the non-scribe surface side, irradiates the second laser light along the scribe line, and the workpiece is heated along the scribe line; and in the irradiation heating step, the scribe line is caused by a second laser light is scanned relative to the scribe line while the workpiece is placed on the cooling medium in contact with the cooling medium, and the second laser light is directed to the non-scribe line Surface illumination The inside of the workpiece on the scribe line is moved and cooled by the tensile stress field in the vicinity of the scribe line, thereby causing the scribe line to be located in the tensile stress field from the scribe line The progress of the cracks on the non-lined surface is sequentially generated along the above-mentioned scribe lines, thereby breaking the above-mentioned workpiece.

技術方案2之發明係如技術方案1之分斷方法,其特徵在於:於上述照射加熱步驟中,於利用調整機構調整自上述第2出射源出射之上述第2雷射光之照射範圍後,將上述第2雷射光照射至上述非劃線面。 According to a second aspect of the invention, in the illuminating and heating step, after the irradiation range of the second laser light emitted from the second emission source is adjusted by an adjustment mechanism, The second laser light is irradiated onto the non-line surface.

技術方案3之發明係如技術方案1或技術方案2之分斷方法,其特徵在於:上述第2雷射光係CO2雷射。 The invention of claim 3 is the method according to the first aspect or the second aspect, characterized in that the second laser light is a CO 2 laser.

技術方案4之發明係如技術方案3之分斷方法,其特徵在於:於上述照射加熱步驟中,以脈衝振盪模式照射上述第2雷射光,於藉由分斷上述被加工物所形成之單片之分斷面上,產生具有與脈衝振盪週期對應之週期之全反射率降低用之起伏。 The invention of claim 4 is characterized in that, in the step of irradiating and heating, the second laser light is irradiated in a pulse oscillation mode to form a single sheet formed by dividing the workpiece. On the divided sections of the sheet, an undulation for reducing the total reflectance with a period corresponding to the pulse oscillation period is generated.

技術方案5之發明係如技術方案1或技術方案2之分斷方法,其特徵在於:上述第1雷射光係YAG(Yttrium Aluminum Garnet,釔鋁石榴石)雷射之3倍高次諧波。 The invention of claim 5 is the method of dividing the first aspect or the second aspect, characterized in that the first laser light YGA (Yttrium Aluminum Garnet) is a triple harmonic of the laser.

技術方案6之發明係如技術方案1或技術方案2之分斷方法,其特徵在於:更包括對上述被加工物之水平面內之姿勢進行修正之對準處理步驟;且對於已進行上述對準處理步驟之上述被加工物,進行上述劃線加工步驟及上述照射加熱步驟。 The invention of claim 6 is characterized in that the method further comprises an alignment processing step of correcting a posture in a horizontal plane of the workpiece; and The object to be processed in the processing step performs the scribing processing step and the irradiation heating step.

技術方案7之發明係如技術方案1或技術方案2之分斷方 法,其特徵在於:於上述劃線加工步驟中,藉由於上述第1雷射光之被照射位置產生熔融及再固化,使上述被照射位置成為變質區域,從而形成上述劃線。 The invention of claim 7 is the breaking side of the technical solution 1 or the technical solution 2 In the above-described scribing processing step, the scribing is performed by melting and re-solidifying the irradiated position of the first laser light to cause the irradiated position to become a modified region.

技術方案8之發明係如技術方案1或技術方案2之分斷方法,其特徵在於:於上述劃線加工步驟中,藉由於上述第1雷射光之被照射位置產生燒蝕(ablation)而於上述被照射位置形成槽部,從而形成上述劃線。 The invention of claim 8 is characterized in that, in the step of scribing, the ablation is caused by the position of the first laser beam being irradiated. The grooved portion is formed at the irradiated position to form the scribe line.

技術方案9之發明係如技術方案1或技術方案2之分斷方法,其特徵在於:於上述劃線加工步驟中,於彼此正交之第1方向與第2方向上分別形成複數條劃線;且於上述照射加熱步驟中,於已進行自上述非劃線面側沿著於上述第1方向上延伸之上述劃線之照射加熱後,進行沿著於上述第2方向上延伸之上述劃線之照射加熱。 The invention of claim 1 is the method according to the first aspect or the second aspect, wherein the plurality of lines are formed in the first direction and the second direction orthogonal to each other. And in the irradiation heating step, after the irradiation of the scribe line extending from the non-scribe surface side along the first direction is performed, the step of extending along the second direction is performed. The line is heated by irradiation.

技術方案10之發明係如技術方案9之分斷方法,其特徵在於:於上述照射加熱步驟中,將上述第2雷射光之照射光束直徑設為形成上述劃線時之間距以下。 The invention of claim 9 is characterized in that, in the illuminating and heating step, the diameter of the irradiation beam of the second laser beam is set to be equal to or less than a distance between the scribe lines.

技術方案11之發明之特徵在於:其係分斷於表面二維地形成有光學元件圖案之具有光學元件圖案之基板之方法,且包括:劃線加工步驟,藉由使第1雷射光自第1出射源出射,並對上述具有光學元件圖案之基板之劃線面照射上述第1雷射光,而於上述劃線面上形成劃線;及照射加熱步驟,使CO2雷射即第2雷射光自第2出射源出射,並自上述劃線面側沿著上述劃線照射上述第2雷射光,而將上述具有光學元件圖案之基板沿著上述劃線進行加熱;且於上述 照射加熱步驟中,藉由使上述第2雷射光沿著上述劃線相對地進行掃描,而使於上述具有光學元件圖案之基板上藉由上述第2雷射光之照射而形成於照射加熱區域之周圍之拉伸應力場移動,藉此,使因上述劃線位於上述拉伸應力場內而產生之自上述劃線向上述非劃線面之裂痕之進展沿著上述劃線依序產生,從而分斷上述具有光學元件圖案之基板,並且藉由使上述第2雷射光以脈衝振盪模式出射,而於藉由分斷上述被加工物所形成之光學元件單片之分斷面上,產生具有與脈衝振盪週期對應之週期之全反射率降低用之起伏。 The invention of claim 11 is characterized in that it is a method of dividing a substrate having an optical element pattern in which an optical element pattern is two-dimensionally formed on the surface, and includes: a scribing processing step by making the first laser light from the first 1 emitting source, irradiating the first laser light on the scribe line surface of the substrate having the optical element pattern, forming a scribe line on the scribe line surface; and irradiating the heating step to make the CO 2 laser, ie, the second ray The emitted light is emitted from the second emission source, and the second laser light is irradiated from the scribing surface side along the scribe line, and the substrate having the optical element pattern is heated along the scribe line; and the irradiation heating step is performed By scanning the second laser light relative to the scribe line, the substrate having the optical element pattern is formed on the substrate around the illuminating heating region by the irradiation of the second laser light. The tensile stress field is moved, whereby the progress of the crack from the scribe line to the non-scribe surface due to the scribe line being located in the tensile stress field is sequentially generated along the scribe line, thereby dividing The substrate having the optical element pattern and the second laser light emitted in a pulse oscillation mode are formed on a cross section of the optical element monolith formed by dividing the workpiece to generate a pulse and a pulse The total reflectance of the period corresponding to the oscillation period is reduced by the fluctuation.

根據技術方案1至技術方案11之發明,藉由沿著藉由照射第1雷射光而預先形成於被加工物之預定分斷位置之劃線照射第2雷射光而加熱被加工物,而使拉伸應力作用於劃線,從而使自劃線向非劃線面之裂痕之進展沿著劃線之延伸方向依序產生,由此可高精度地分斷被加工物。而且,藉由對非劃線面進行第2雷射光之照射而使裂痕之進展更高效率地產生,因此可高效率地進行較高精度之分斷。 According to the inventions of the first aspect to the eleventh aspect, the second laser light is irradiated along the scribe line formed in advance at the predetermined breaking position of the workpiece by the irradiation of the first laser light, thereby heating the workpiece. The tensile stress acts on the scribe line, so that the progress of the crack from the scribe line to the non-scribe surface is sequentially generated along the extending direction of the scribe line, whereby the workpiece can be separated with high precision. Further, since the progress of the crack is more efficiently generated by irradiating the non-line surface with the second laser light, the high-precision division can be performed with high efficiency.

特別係根據技術方案4及技術方案11之發明,可在分斷對象物之分斷面上有目的地產生起伏。藉此,例如,當於表面二維地形成有LED(Light Emitting Diode,發光二極體)圖案之藍寶石基板即LED製造用基板為分斷對象物,且如將該基板分斷成LED晶片單位之單片之情形時,可抑制 在LED晶片之分斷面上之全反射,從而提高LED晶片之發光效率。 In particular, according to the inventions of claim 4 and claim 11, the undulations can be purposefully generated on the cross-section of the object to be separated. Thus, for example, a substrate for LED manufacturing, which is a sapphire substrate in which an LED (Light Emitting Diode) pattern is two-dimensionally formed on the surface, is a dividing object, and the substrate is divided into LED wafer units. In the case of a single piece, it can be suppressed Total reflection on the cross-section of the LED chip to improve the luminous efficiency of the LED chip.

<加工之基本原理> <Basic Principles of Processing>

首先,對於本實施形態之加工(分斷加工)之基本原理進行說明。於本實施形態中進行之分斷加工大致如下:在藉由對被加工物(分斷對象物)W之預定分斷位置照射第1雷射光(劃線用雷射光)而形成劃線SL後,藉由利用第2雷射光(加熱用雷射光)之照射進行加熱(雷射加熱)而於該劃線SL附近產生應力場,藉此,藉由使龜裂(裂痕)自作為初期龜裂之劃線SL開始進展,而分斷被加工物。 First, the basic principle of the processing (breaking processing) of the present embodiment will be described. The cutting process performed in the present embodiment is substantially as follows: after the first laser light (the laser light for scribing) is irradiated to the predetermined breaking position of the workpiece (the object to be separated) W, the scribe line SL is formed. By applying heat by the irradiation of the second laser light (laser light for heating) (laser heating), a stress field is generated in the vicinity of the scribe line SL, whereby cracks (cracks) are used as initial cracks. The scribing SL begins to progress, and the processed object is broken.

作為被加工物W,例如符合的有:玻璃板或藍寶石基板等脆性材料、或在包含該等脆性材料之基板之表面藉由薄膜層等而二維地形成單位圖案而成之基板(以下,具有圖案之基板)等。 The workpiece W is, for example, a brittle material such as a glass plate or a sapphire substrate, or a substrate in which a unit pattern is two-dimensionally formed on a surface of a substrate including the brittle material by a film layer or the like (hereinafter, A substrate having a pattern) or the like.

圖1係模式性地表示在本實施形態中進行之分斷加工中途之情形之圖。更具體而言,圖1係表示藉由沿著預先形成於被加工物W上之劃線SL照射加熱用雷射光LBh而進行雷射加熱之情形。 Fig. 1 is a view schematically showing a state in the middle of the breaking process performed in the embodiment. More specifically, FIG. 1 shows a case where laser heating is performed by irradiating the heating laser light LBh along the scribe line SL formed in advance on the workpiece W.

再者,於以下說明中,將被加工物W中形成有劃線SL之面、或預定形成劃線SL之面稱為劃線面W1,將該劃線面W1之相反面稱為非劃線面W2。又,於圖1中,表示藉由使加熱用雷射光LBh在由箭頭AR1表示之掃描方向(當然亦可為劃線SL之延伸方向)上移動而掃描劃線面W1之情形,但 亦可代替該情形而為如下形態:使加熱用雷射光LBh固定地照射某一照射位置,另一方面,藉由未圖示之移動機構而使被加工物W移動,由此利用加熱用雷射光LBh實現向箭頭AR1方向之相對掃描。 In the following description, the surface on which the scribe line SL is formed in the workpiece W or the surface on which the scribe line SL is to be formed is referred to as a scribe line W1, and the opposite side of the scribe line W1 is referred to as a non-pattern. Line surface W2. In addition, FIG. 1 shows a case where the scribing surface W1 is scanned by moving the heating laser light LBh in the scanning direction indicated by the arrow AR1 (which may of course be the extending direction of the scribe line SL), but In place of this, the heating laser light LBh may be fixedly irradiated to a certain irradiation position, and the workpiece W may be moved by a moving mechanism (not shown). The illuminating light LBh achieves a relative scanning in the direction of the arrow AR1.

若照射加熱用雷射光LBh,則被加工物W之劃線面W1中之加熱用雷射光LBh之照射區域被加熱而膨脹,如圖1所示,成為壓縮應力場SF1。另一方面,該壓縮應力場SF1之外周區域收縮,成為拉伸應力場SF2。若劃線SL包含在該拉伸應力場SF2中,則在被加工物W中,於該劃線SL之側方拉伸應力TS發揮作用。藉由此種拉伸應力TS之作用而裂痕CR自劃線SL向非劃線面W2側之預定分斷位置L0進展。而且,如上所述,由於加熱用雷射光LBh沿著劃線SL相對地進行掃描,因而拉伸應力場SF2亦隨之沿著劃線SL移動。於是,裂痕CR向非劃線面W2側進展之部位沿著劃線SL之延伸方向、即加熱用雷射光LBh之掃描方向遷移。因此,若自設置於劃線面W1側之預定分斷位置之劃線SL之一端至另一端照射加熱用雷射光LBh,則可在劃線SL之整個形成位置,依序產生裂痕CR向預定分斷位置L0之進展,因而,作為結果,可分斷被加工物W。此為本實施形態之分斷加工之基本原理。 When the heating laser light LBh is irradiated, the irradiation region of the heating laser light LBh in the scribing surface W1 of the workpiece W is heated and expanded, and as shown in FIG. 1, the compressive stress field SF1 is obtained. On the other hand, the outer peripheral region of the compressive stress field SF1 contracts to become the tensile stress field SF2. When the scribe line SL is included in the tensile stress field SF2, the tensile stress TS acts on the side of the scribe line SL in the workpiece W. The crack CR progresses from the scribe line SL to the predetermined breaking position L0 on the non-scribe line surface W2 side by the action of the tensile stress TS. Further, as described above, since the heating laser light LBh is relatively scanned along the scribe line SL, the tensile stress field SF2 also moves along the scribe line SL. Then, the portion where the crack CR progresses toward the non-scribe line surface W2 side migrates along the extending direction of the scribe line SL, that is, the scanning direction of the heating laser light LBh. Therefore, when the heating laser light LBh is irradiated from one end to the other end of the scribe line SL provided at the predetermined breaking position on the side of the scribe line W1, the crack CR can be sequentially generated at the entire forming position of the scribe line SL. The progress of the position L0 is broken, and as a result, the workpiece W can be separated. This is the basic principle of the breaking process of the embodiment.

在以此種形態分斷被加工物W之情形時,於準確地定位被加工物W後,將高精度地形成於劃線面W1上之特定位置而成之劃線SL設為初期龜裂,使裂痕CR向非劃線面W2側進展。通常,與劃線SL之長度相比,被加工物W之厚度非 常地小,又,由於藉由加熱用雷射光LBh所形成之拉伸應力場SF2相對均勻,因而不易產生分斷位置之偏移。即,於本實施形態中,可進行精度優異之分斷。作為結果,可實現以μm級之精度之分斷。 When the workpiece W is cut in such a manner, after the workpiece W is accurately positioned, the scribing SL formed at a specific position on the scribing surface W1 with high precision is set as the initial crack. The crack CR is progressed toward the non-line surface W2 side. Generally, the thickness of the workpiece W is different from the length of the scribe line SL. Often small, and since the tensile stress field SF2 formed by the heating laser light LBh is relatively uniform, the offset of the breaking position is less likely to occur. That is, in the present embodiment, it is possible to perform the breaking with excellent precision. As a result, the division with an accuracy of μm level can be achieved.

再者,當將於表面二維地形成有LED圖案之藍寶石基板即LED製造用基板等具有圖案之基板分斷為每單位圖案之單片(晶片單位)之情形時等,於將預定分斷位置設定為格子狀之情形時,在彼此正交之第1方向與第2方向上分別依序形成複數條劃線SL後,對於各方向依序進行利用加熱用雷射光LBh之加熱。於此情形時,若藉由加熱用雷射光LBh而沿著某一在第1方向上延伸之劃線SL(第1劃線)進行雷射加熱,則在與其正交之另一劃線SL(第2劃線)之格子點附近,於沿第2方向延伸之第2劃線上,裂痕CR亦會局部地略微向非劃線面W2進展。然而,於此種情形時,藉由之後進行沿著第2劃線之雷射加熱,亦可進行無精度問題之分斷。 In addition, when a substrate having a pattern such as a sapphire substrate in which an LED pattern is formed two-dimensionally on the surface, which is a substrate for LED production, is divided into a single piece (wafer unit) per unit pattern, the predetermined portion is cut off. When the position is set to a lattice shape, a plurality of lines SL are sequentially formed in the first direction and the second direction orthogonal to each other, and then heating by the heating laser light LBh is sequentially performed for each direction. In this case, if the laser beam LBh is heated to perform laser heating along a scribe line SL (first scribe line) extending in the first direction, another scribe line SL orthogonal thereto is used. In the vicinity of the lattice point of the (second scribe line), the crack CR also partially slightly progresses toward the non-scribe line surface W2 on the second scribe line extending in the second direction. However, in such a case, by performing laser heating along the second scribe line, it is also possible to perform the problem of no precision problem.

對於劃線用雷射光,只要根據被加工物W之材質等選擇適當之脈衝雷射光來使用即可。例如,若在藍寶石基板、或使用藍寶石基板製作之具有圖案之基板即LED製造用基板為被加工物W之情形時,則較佳之一例係使用YAG雷射之3倍高次諧波(波長355 nm)。又,為了提高在預定分斷位置之分斷精度及確實性,較理想為將劃線SL形成為儘可能地細,因此使劃線用雷射光於數μm~十幾μm左右之照射範圍(照射光束直徑)內進行照射。又,就加工效率(能量利 用效率)之觀點而言,劃線用雷射光以在被加工物W之劃線面W1或內部之劃線面W1附近(自劃線面W1起至數十μm左右為止之範圍)聚焦之方式照射。再者,於本實施形態中,所謂照射光束直徑係指在假設所照射之雷射光束之剖面之能量分佈為高斯分佈形狀之情形時,其能量值為中心之最高值之1/e2以上之區域之直徑。 The laser beam for scribing may be used by selecting appropriate pulsed laser light depending on the material of the workpiece W or the like. For example, when the sapphire substrate or the substrate for LED production, which is a patterned substrate made of a sapphire substrate, is the workpiece W, it is preferable to use a YAG laser 3 times higher harmonic (wavelength 355). Nm). Further, in order to improve the breaking accuracy and the reliability at the predetermined breaking position, it is preferable to form the scribe line SL as thin as possible, so that the laser light for scribing is irradiated in an irradiation range of several μm to several tens of μm ( Irradiation is performed within the diameter of the illumination beam. Further, in terms of processing efficiency (energy use efficiency), the laser light for scribing is in the vicinity of the scribing surface W1 of the workpiece W or the inner scribing surface W1 (from the scribing surface W1 to several tens of μm) Range up to the left and right). Further, in the present embodiment, the irradiation beam diameter refers to a case where the energy distribution of the section of the laser beam irradiated is assumed to have a Gaussian distribution shape, and the energy value is 1/e 2 or more of the highest value of the center. The diameter of the area.

又,關於劃線SL,既可為將在劃線用雷射光之被照射位置藉由使物質蒸發所形成之剖面觀察為三角形狀或楔形狀之槽部設為劃線SL之形態,亦可為將在該被照射位置藉由使物質熔融、再固化(融解改質)所形成之剖面觀察為三角形狀或楔形狀之變質區域設為劃線SL之形態。根據採用哪一形態,而決定劃線用雷射光之照射條件(脈衝寬度、重複頻率、峰值功率密度、掃描速度等)。又,圖1中例示了連續地形成有劃線SL之情形,但劃線SL之形成形態並不限於此。例如,亦可為沿著預定分斷位置呈點線狀或虛線狀地形成劃線SL之形態。 Further, the scribe line SL may be a shape in which a groove formed by evaporating a position of the laser light for scribing is formed into a triangular shape or a wedge shape as a scribe line SL, or The deformed region in which the triangular or wedge-shaped shape is observed as a cross section formed by melting and resolidifying (melting and modifying) the material at the position to be irradiated is a scribe line SL. The irradiation conditions (pulse width, repetition frequency, peak power density, scanning speed, etc.) of the laser light for scribing are determined depending on which form is adopted. In addition, although the case where the scribe line SL is continuously formed is illustrated in FIG. 1, the formation form of the scribe line SL is not limited to this. For example, the form of the scribe line SL may be formed in a dotted line or a dotted line along a predetermined breaking position.

另一方面,作為加熱用雷射光LBh,較佳為使用長波長雷射即CO2雷射(波長9.4 μm~10.6 μm)。CO2雷射由於在玻璃或藍寶石之表面確實地被吸收,因而可確實地產生自劃線SL之裂痕CR之進展。再者,與劃線SL之形成之所謂被加工物之加工為目的而照射之劃線用雷射光不同,加熱用雷射光LBh係以藉由加熱被加工物而於形成於加熱區域之壓縮應力場SF1之周圍形成拉伸應力場SF2之目的而照射之雷射光。因此,於不使被加工物破壞或變質、或使拉伸應 力場SF2形成為儘可能地廣時,加熱用雷射光LBh之照射範圍大於劃線用雷射光即可。例如,於被加工物之厚度為150 μm之情形時,只要為100 μm~1000 μm左右即可。 On the other hand, as the heating laser light LBh, a long-wavelength laser, that is, a CO 2 laser (wavelength of 9.4 μm to 10.6 μm) is preferably used. Since the CO 2 laser is surely absorbed on the surface of the glass or sapphire, the progress of the crack CR from the scribe line SL can be surely produced. Further, the laser beam for irradiation for the purpose of processing the so-called workpiece formed by the scribe line SL is different from the laser light for the scribe line, and the heating laser light LBh is a compressive stress formed in the heating region by heating the workpiece. The laser light irradiated for the purpose of stretching the stress field SF2 is formed around the field SF1. Therefore, when the workpiece is not broken or deteriorated, or when the tensile stress field SF2 is formed as wide as possible, the irradiation range of the heating laser light LBh is larger than the laser light for scribing. For example, when the thickness of the workpiece is 150 μm, it may be about 100 μm to 1000 μm.

然而,於如自具有圖案之基板中切出矩形形狀之晶片之情形時,將加熱用雷射光LBh之照射光束直徑設定為與晶片之平面尺寸(與預定分斷位置之間距大致同等)相同或其以下。於使照射光束直徑大於晶片之平面尺寸之情形時,產生無法良好地進行分斷因而無法獲得特定形狀之晶片之情形,故而欠佳。 However, when a rectangular shaped wafer is cut out from a patterned substrate, the irradiation beam diameter of the heating laser light LBh is set to be the same as the planar size of the wafer (substantially the same as the predetermined breaking position) or It is below. When the diameter of the irradiation beam is made larger than the plane size of the wafer, a case where the wafer cannot be well cut and a specific shape cannot be obtained is disadvantageous.

<加熱用雷射光之振盪模式與分斷面之形狀之關係> <Relationship between the oscillation mode of the laser light for heating and the shape of the sectional section>

例如,於使用CO2雷射作為加熱用雷射光LBh之情形時,能以連續振盪模式與脈衝振盪模式此兩種振盪模式照射加熱用雷射光LBh。而且,根據該振盪模式,確認被加工物W之分斷面之形狀產生不同。具體而言,於連續振盪模式之情形時,藉由裂痕進展所形成之分斷面成為非常光滑之平坦面。另一方面,於脈衝振盪模式之情形時,於分斷面上形成與脈衝振盪週期對應之週期性之起伏(凹凸)。圖2係使用CO2雷射作為加熱用雷射光LBh而分斷藍寶石基板時之分斷面之SEM(Scanning Electron Microscope,掃描式電子顯微鏡)像。圖中,「Fracture surface(破裂面)」係分斷面,Groove(溝槽)係劃線,「Feed direction(進給方向)」係藍寶石基板之移動方向(雷射光之掃描方向之相反方向)。於圖2所示之情形時,分斷面雖透明,但卻以數十μm之間距形成有起伏而成。通常,較佳為被加工物W之分 斷面為平坦面,因而多數情形時,加熱用雷射光LBh之照射以連續振盪模式來進行。 For example, when a CO 2 laser is used as the heating laser light LBh, the heating laser light LBh can be irradiated in the two oscillation modes of the continuous oscillation mode and the pulse oscillation mode. Further, according to the oscillation mode, it is confirmed that the shape of the cross-section of the workpiece W is different. Specifically, in the case of the continuous oscillation mode, the section formed by the progress of the crack becomes a very smooth flat surface. On the other hand, in the case of the pulse oscillation mode, periodic fluctuations (concavities and convexities) corresponding to the pulse oscillation period are formed on the cross-section. 2 is an SEM (Scanning Electron Microscope) image of a cross section when a sapphire substrate is separated by using a CO 2 laser as the heating laser light LBh. In the figure, "Fracture surface" is a cross-section, Groove is a scribing line, and "Feed direction" is the moving direction of the sapphire substrate (the opposite direction of the scanning direction of the laser light) . In the case shown in Fig. 2, although the cross-section is transparent, it is formed with undulations at intervals of several tens of μm. In general, it is preferable that the cross-section of the workpiece W is a flat surface. Therefore, in many cases, the irradiation of the heating laser light LBh is performed in a continuous oscillation mode.

相對於此,亦有較佳為在分斷面上有目的地(積極地)產生起伏之情形。例如,於表面二維地形成有LED(發光元件)圖案之藍寶石基板(晶圓)即LED製造用基板為被加工物W,且將該基板分斷為LED晶片單位之單片之情形符合該情形。圖3係表示在分斷面為平坦之情形時與在平坦面存在起伏之情形時之分斷面中之光之前進方向之不同之圖。 On the other hand, it is preferable to have a situation in which the undulation is purposefully (positively) generated on the sectional section. For example, a sapphire substrate (wafer) in which an LED (light-emitting element) pattern is two-dimensionally formed, that is, a substrate for manufacturing an LED, is a workpiece W, and the substrate is divided into individual pieces of LED wafer units. situation. Fig. 3 is a view showing the difference in the forward direction of the light in the cross-section when the split surface is flat and the undulation is present on the flat surface.

通常,發光元件(LED晶片)被要求在設置於基板上之發光元件構造部分產生之發光儘可能地不被遮擋便向外部掠出。由於此種光之一部分亦入射至基板部分,因而為了提高發光元件之實質之發光效率(光之掠出效率),而需要在基板部分亦使發出之光儘可能地透過。另一方面,於光自折射率較大之媒體中向折射率較小之媒體中前進之情形時,有相對於其界面(入射面)以臨界角θc以上入射之光被全反射這一光學上之限制(斯奈爾定律)。例如,於光自藍寶石向空氣前進之情形時,θc=34.4°。 In general, a light-emitting element (LED wafer) is required to illuminate the light emitted from the light-emitting element construction portion provided on the substrate as much as possible without being blocked. Since a part of such light is also incident on the substrate portion, in order to improve the luminous efficiency (light efflux efficiency) of the light-emitting element, it is necessary to transmit the emitted light as much as possible in the substrate portion. On the other hand, when light is advanced from a medium having a large refractive index to a medium having a small refractive index, light incident at a critical angle θ c or more with respect to the interface (incidence surface) is totally reflected. Optical limitations (Snell's Law). For example, when light travels from sapphire to air, θ c = 34.4°.

若分斷面為平坦面,則如圖3(a)所示,於發光元件部分產生之光中以臨界角θc以上之入射角入射至分斷面之光全部被反射。又,理論上,根據產生後之行進方向,繼續遭受全反射,作為結果,亦會產生成為封閉在LED晶片內部之狀態之光。如上所述,若在光自藍寶石向空氣前進之情形時,則以34.4°以上55.6°以下之入射角入射至分斷面之光符合該情形。 When the cross-section is a flat surface, as shown in FIG. 3(a), all of the light incident on the cross-section at an incident angle of a critical angle θ c or more is reflected by the light generated in the light-emitting element portion. Further, in theory, according to the traveling direction after the generation, total reflection is continuously suffered, and as a result, light which is enclosed in the inside of the LED wafer is also generated. As described above, when light is advanced from the sapphire to the air, it is in accordance with this case that the light is incident on the cross-section at an incident angle of 34.4 or more and 55.6 or less.

相對於此,於分斷面存在起伏之情形時,如圖3(b)所示,即便係自與圖3(a)之情形相同之方向入射之光,亦會根據其入射位置而入射角小於圖3(a),因而產生透過分斷面之成分。又,即便在某一分斷面遭到反射,於不同之分斷面進行透過之概率亦會變高。即,可降低入射至分斷面之光在該分斷面被全反射之比例(全反射率)。因此,於分斷面存在起伏之情形時,相較於分斷面為平坦面之情形,實現易於掠出所產生之光之狀態。再者,於實際之發光元件中,LED晶片之基板未必直接露出在外部,有藉由樹脂而密封等情形,但即便於此種情形時,亦同樣地獲得上述效果。 On the other hand, when there is a undulation in the cross-section, as shown in FIG. 3(b), even if light incident from the same direction as in the case of FIG. 3(a), the incident angle is based on the incident position. Less than that of Fig. 3(a), a component that transmits through the cross section is produced. Moreover, even if a certain section is reflected, the probability of passing through different sections will become higher. That is, the ratio (total reflectance) at which the light incident to the cross-section is totally reflected in the cross-section can be reduced. Therefore, in the case where the section has an undulation, it is easy to pluck the state of the light generated compared to the case where the section is a flat surface. Further, in the actual light-emitting element, the substrate of the LED chip is not necessarily directly exposed to the outside, and may be sealed by a resin. However, even in such a case, the above effects are obtained in the same manner.

鑒於以上,於被加工物W為LED製造用基板,且將該基板分斷為LED晶片單位之情形時,藉由以脈衝振盪模式照射加熱用雷射光LBh而於分斷面產生起伏之形態來進行分斷。藉此,可獲得光掠出效率較高之LED晶片。此種方法可與被加工物W之分斷之同時形成起伏,因而與例如如專利文獻6中揭示之使用乾式蝕刻來形成凹凸之方法相比,為高效率且生產率較高之方法。 In the case where the workpiece W is a substrate for LED production and the substrate is divided into LED wafer units, the heating laser light LBh is irradiated in a pulse oscillation mode to cause undulations in the cross-section. Make a break. Thereby, an LED wafer with high light extraction efficiency can be obtained. Such a method can form an undulation at the same time as the breaking of the workpiece W, and thus is a method of high efficiency and high productivity as compared with a method of forming irregularities by dry etching as disclosed in Patent Document 6, for example.

<分斷裝置> <breaking device>

其次,基於上述加工原理,對進行被加工物之分斷之分斷裝置進行說明。圖4係概略地表示分斷裝置100之構成之圖。 Next, based on the above-described processing principle, a breaking device that performs the breaking of the workpiece will be described. FIG. 4 is a view schematically showing the configuration of the breaking device 100.

如圖4所示,分斷裝置100主要包括載物台部10、劃線用雷射光學系統20、加熱用雷射光學系統30、及位置讀取光 學系統40。又,分斷裝置100例如包含未圖示之CPU(Central Processing Unit,中央處理單元)、ROM(Read Only Memory,唯讀記憶體)、RAM(Random Access Memory,隨機存取記憶體)等,且包括控制系統50,藉由於劃線用雷射光學系統20、加熱用雷射光學系統30、及位置讀取光學系統40等之間授受各種信號,而控制各構成要素之動作。再者,控制系統50既可為與其他構成要素作為一體而併入分斷裝置100之本體中之形態,亦可為例如包含個人電腦等,且與分斷裝置100之本體分開地設置之形態。 As shown in FIG. 4, the breaking device 100 mainly includes a stage portion 10, a laser optical system 20 for scribing, a laser optical system 30 for heating, and position reading light. Learning system 40. Further, the breaking device 100 includes, for example, a CPU (Central Processing Unit), a ROM (Read Only Memory), a RAM (Random Access Memory), and the like (not shown). The control system 50 includes various signals transmitted between the laser optical system 20 for scribing, the laser optical system 30 for heating, and the position reading optical system 40, thereby controlling the operation of each component. Further, the control system 50 may be incorporated into the main body of the breaking device 100 as being integrated with other components, or may be provided separately from the main body of the breaking device 100, for example, including a personal computer or the like. .

載物台部10主要包含XY載物台11、及設置於該XY載物台11上之加工用載物台12。 The stage unit 10 mainly includes an XY stage 11 and a processing stage 12 provided on the XY stage 11.

XY載物台11基於來自控制系統50之驅動控制信號sg1,而於水平面內(XY平面內)之彼此正交之2個方向(X方向、Y方向)上移動自如。再者,將XY載物台11之位置信息信號sg2不斷地反饋至控制系統。 The XY stage 11 is freely movable in two directions (X direction, Y direction) orthogonal to each other in the horizontal plane (in the XY plane) based on the drive control signal sg1 from the control system 50. Furthermore, the position information signal sg2 of the XY stage 11 is continuously fed back to the control system.

加工用載物台12係用以在其上載置並固定被加工物W之部位。加工用載物台12包括未圖示之吸附機構,且以如下方式構成:藉由基於來自控制系統50之吸附控制信號sg3而使吸附機構作動,而將被加工物W吸附固定於加工用載物台12之上表面12a。又,加工用載物台12包括未圖示之旋轉驅動機構,且亦可基於來自控制系統50之旋轉控制信號sg4而於水平面內進行旋轉動作。 The processing stage 12 is a portion for placing and fixing the workpiece W thereon. The processing stage 12 includes an adsorption mechanism (not shown), and is configured such that the suction mechanism is actuated by the adsorption control signal sg3 from the control system 50, and the workpiece W is adsorbed and fixed to the processing load. The upper surface 12a of the stage 12. Further, the machining stage 12 includes a rotation drive mechanism (not shown), and can also perform a rotation operation in a horizontal plane based on the rotation control signal sg4 from the control system 50.

再者,雖在圖4中省略圖示,但亦可為如下形態:在向 加工用載物台12固定時,於被加工物W之非劃線面W2側(載置面側)貼附黏著性膜,並將被加工物W與該膜一同固定。 In addition, although illustration is abbreviate|omitted in FIG. 4, it is the following aspect. When the processing stage 12 is fixed, an adhesive film is attached to the non-scribe surface W2 side (the mounting surface side) of the workpiece W, and the workpiece W is fixed together with the film.

劃線用雷射光學系統20係基於由控制系統50提供之劃線用雷射控制信號sg5而對被加工物W照射劃線用雷射光之部位。 The scribing laser optical system 20 is a portion that irradiates the workpiece W with the laser light for scribing based on the scribing laser control signal sg5 supplied from the control system 50.

圖5係表示劃線用雷射光學系統20之詳細構成之圖。如圖5所示,劃線用雷射光學系統20主要包括:雷射振盪器21,其係作為劃線用雷射光LBs之光源(出射源);衰減器22,用以進行自雷射振盪器21出射之劃線用雷射光LBs之光量調整;及物鏡23,用以進行劃線用雷射光LBs之焦點調整。再者,如上所述,作為劃線用雷射光LBs,使用與被加工物W之材質等對應之脈衝雷射光,因而雷射振盪器21只要根據所使用之劃線用雷射光LBs之種類進行選擇即可。 Fig. 5 is a view showing a detailed configuration of the laser optical system 20 for scribing. As shown in FIG. 5, the laser optical system 20 for scribing mainly includes a laser oscillator 21 as a light source (exit source) for laser light LBs for scribing, and an attenuator 22 for performing self-laser oscillation. The line drawn by the device 21 is adjusted by the amount of light of the laser light LBs; and the objective lens 23 is used for adjusting the focus of the laser light LBs for scribing. In addition, as described above, since the laser light corresponding to the material of the workpiece W or the like is used as the laser light LBs for scribing, the laser oscillator 21 is used only for the type of the laser light LBs to be used for the scribing. Just choose.

又,於劃線用雷射光學系統20中亦包括鏡24,藉由反射劃線用雷射光LBs而適當轉變劃線用雷射光LBs之光路方向。再者,於圖5中雖例示了僅包括1個鏡24之情形,但鏡24之數量並不限於此,根據劃線用雷射光學系統20內部或進而根據分斷裝置100內部之佈局上之要求及其他原因,亦可為設置更多之鏡24,且適當設定劃線用雷射光LBs之光路之形態。 Further, the laser optical system 20 for scribing also includes a mirror 24 for appropriately changing the optical path direction of the scribing laser light LBs by reflecting the laser light LBs. Further, although the case where only one mirror 24 is included is illustrated in FIG. 5, the number of the mirrors 24 is not limited thereto, and the inside of the laser optical system 20 according to the scribing or the layout according to the inside of the breaking device 100 is used. For the requirements and other reasons, it is also possible to provide more mirrors 24 and appropriately set the optical path of the laser light LBs for scribing.

更詳細而言,於雷射振盪器21中,設置有用以切換劃線用雷射光LBs之出射/非出射之快門21a。快門21a之開關動 作係基於作為劃線用雷射控制信號sg5之一種之ON(接通)/OFF(斷開)控制信號sg5a而進行控制。又,衰減器22中之劃線用雷射光LBs之光量之調整係基於作為劃線用雷射控制信號sg5之一種之輸出功率控制信號sg5b而進行控制。 More specifically, in the laser oscillator 21, a shutter 21a for switching the non-exiting of the laser light LBs for scribing is provided. Switching of shutter 21a The control is performed based on the ON/OFF control signal sg5a which is one of the scribing laser control signals sg5. Further, the adjustment of the amount of light of the scribing laser light LBs in the attenuator 22 is controlled based on the output power control signal sg5b which is one of the scribing laser control signals sg5.

在劃線用雷射光學系統20中,自雷射振盪器21出射且由衰減器22調整光量之劃線用雷射光LBs以在被加工物W之劃線面W1或內部之劃線面W1附近(自劃線面W1起至數十μm左右為止之範圍)聚焦之方式,且以照射光束直徑成為數μm~十幾μm左右之方式調整物鏡23之配置位置。藉此,形成良好之劃線SL。 In the laser optical system 20 for scribing, the laser light LBs emitted from the laser oscillator 21 and adjusted by the attenuator 22 for the amount of light is applied to the scribing surface W1 of the workpiece W or the inner scribing surface W1. In the vicinity (the range from the scribe line W1 to the range of several tens of μm), the arrangement position of the objective lens 23 is adjusted such that the diameter of the irradiation beam is several μm to several tens of μm. Thereby, a good scribe line SL is formed.

加熱用雷射光學系統30係基於由控制系統50提供之加熱用雷射控制信號sg6而對被加工物W照射加熱用雷射光之部位。 The heating laser optical system 30 is a portion that irradiates the workpiece W with the laser light for heating based on the heating laser control signal sg6 supplied from the control system 50.

圖6係表示加熱用雷射光學系統30之詳細構成之圖。如圖6所示,加熱用雷射光學系統30主要包括:雷射振盪器31,其係作為加熱用雷射光LBh之光源(出射源);衰減器32,用以進行自雷射振盪器31出射之加熱用雷射光LBh之光量調整;光束調整機構33,用以調整對被加工物W之加熱用雷射光LBh之照射範圍;及物鏡34,用以進行加熱用雷射光LBh之焦點調整。如上所述,作為加熱用雷射光LBh使用CO2雷射,因而雷射振盪器31為CO2雷射用之振盪器。 Fig. 6 is a view showing a detailed configuration of the heating laser optical system 30. As shown in FIG. 6, the heating laser optical system 30 mainly includes a laser oscillator 31 as a light source (output source) for heating the laser light LBh, and an attenuator 32 for performing the self-laser oscillator 31. The amount of light for the heating laser light LBh for emission is adjusted; the beam adjusting mechanism 33 is for adjusting the irradiation range of the heating laser light LBh for the workpiece W; and the objective lens 34 is for adjusting the focus of the heating laser light LBh. As described above, the CO 2 laser is used as the heating laser light LBh, and thus the laser oscillator 31 is an oscillator for CO 2 laser.

又,於加熱用雷射光學系統30中亦包括鏡35,藉由反射 加熱用雷射光LBh而適當轉變加熱用雷射光LBh之光路之方向。再者,於圖6中雖例示了僅包括1個鏡35之情形,但鏡35之數量並不限於此,根據加熱用雷射光學系統30內部或進而分斷裝置100內部之佈局上之要求及其他原因,亦可為設置更多之鏡35,且適當設定加熱用雷射光LBh之光路之形態。 Moreover, the mirror 35 is also included in the heating laser system 30 for reflection by reflection. The direction of the optical path of the heating laser light LBh is appropriately changed by heating the laser light LBh. Further, although the case where only one mirror 35 is included is illustrated in FIG. 6, the number of the mirrors 35 is not limited thereto, and the layout of the inside of the laser optical system 30 for heating or the device 100 is broken. For other reasons, it is also possible to provide more mirrors 35 and appropriately set the form of the optical path of the heating laser light LBh.

更詳細而言,於雷射振盪器31中,設置有用以切換加熱用雷射光LBh之出射/非出射之快門31a。快門31a之開關動作係基於作為加熱用雷射控制信號sg6之一種之ON/OFF控制信號sg6a而進行控制。又,衰減器32中之加熱用雷射光LBh之光量之調整係基於作為加熱用雷射控制信號sg6之一種之輸出功率控制信號sg6b而進行控制。 More specifically, in the laser oscillator 31, a shutter 31a for switching the non-exiting of the heating laser light LBh is provided. The switching operation of the shutter 31a is controlled based on the ON/OFF control signal sg6a which is one of the heating laser control signals sg6. Further, the adjustment of the amount of light of the heating laser light LBh in the attenuator 32 is controlled based on the output power control signal sg6b which is one of the heating laser control signals sg6.

又,為了調整自雷射振盪器31直線地出射之加熱用雷射光LBh之照射範圍而包括光束調整機構33。光束調整機構33例如可藉由適當組合各種透鏡而實現,且可藉由調整該等透鏡之位置,而對被加工物W以適當之照射範圍照射加熱用雷射光LBh。再者,於圖6中,例示了藉由利用光束調整機構33之調整,而加熱用雷射光LBh以大於自雷射振盪器31出射時之光束直徑之照射範圍照射至被加工物W之情形。 Moreover, the beam adjustment mechanism 33 is included in order to adjust the irradiation range of the heating laser light LBh that is linearly emitted from the laser oscillator 31. The beam adjustment mechanism 33 can be realized, for example, by appropriately combining various lenses, and by adjusting the positions of the lenses, the workpiece W can be irradiated with the heating laser light LBh in an appropriate irradiation range. Further, in FIG. 6, the case where the heating laser light LBh is irradiated to the workpiece W by an irradiation range larger than the beam diameter when the laser oscillator 31 is emitted by the adjustment of the light beam adjusting mechanism 33 is exemplified. .

位置讀取光學系統40利用未圖示之CCD(Charge Coupled Device,電荷耦合器件)攝像機等對吸附固定於加工用載物台12之被加工物W進行攝像,並將所獲得之攝像圖像之數據作為圖像信息信號sg7而供給至控制系統50。控制系統 50基於所獲得之圖像信息信號sg7而進行XY載物台11之移動範圍、或劃線用雷射光LBs或加熱用雷射光LBh之照射位置等之設定。 The position reading optical system 40 images a workpiece W that is adsorbed and fixed to the processing stage 12 by a CCD (Charge Coupled Device) camera or the like (not shown), and images the obtained captured image. The data is supplied to the control system 50 as the image information signal sg7. Control System The setting of the moving range of the XY stage 11, or the irradiation light of the scribing laser light LBs or the heating laser light LBh is performed based on the obtained image information signal sg7.

在具有如上構成之分斷裝置100中,藉由於將被加工物W吸附固定於加工用載物台12之狀態下使XY載物台11移動,而可將被加工物W相對於劃線用雷射光學系統20、加熱用雷射光學系統30、及位置讀取光學系統40之各者自下方對向配置。再者,於此種情形時,被加工物W以劃線面W1成為上表面(非載置面)之方式固定於加工用載物台12上。 In the breaking device 100 having the above configuration, the workpiece W can be moved relative to the scribing by moving the XY stage 11 while the workpiece W is being adsorbed and fixed to the processing stage 12. Each of the laser optical system 20, the heating laser optical system 30, and the position reading optical system 40 is disposed opposite to the bottom. In this case, the workpiece W is fixed to the processing stage 12 such that the scribing surface W1 becomes the upper surface (non-mounting surface).

而且,藉由於使被加工物W與劃線用雷射光學系統20對向配置之狀態下自劃線用雷射光學系統20對被加工物W照射劃線用雷射光LBs並且使XY載物台11移動,而實現對於被加工物W之劃線用雷射光LBs之相對掃描。藉由使劃線用雷射光LBs沿著劃線面W1之預先假設之預定分斷位置相對地進行掃描,而可形成劃線SL。 In the state in which the workpiece W is aligned with the scribing laser optical system 20, the workpiece W is irradiated with the scribing laser light LBs from the scribing laser system 20, and the XY loading is performed. The stage 11 is moved to realize relative scanning of the laser light LBs for scribing the workpiece W. The scribe line SL can be formed by relatively scanning the predetermined laser beam LBs along the predetermined breaking position of the scribe line W1.

同樣地,藉由於使被加工物W與加熱用雷射光學系統30對向配置之狀態下自加熱用雷射光學系統30對被加工物W照射加熱用雷射光LBh並且使XY載物台11移動,而實現對於被加工物W之加熱用雷射光LBh之相對掃描。藉由使加熱用雷射光LBh沿著藉由劃線用雷射光LBs之照射所形成之劃線SL相對地進行掃描,而使裂痕CR自劃線SL向被加工物W之非劃線面W2之預定分斷位置進展,藉此,可分斷被加工物W。 In the same manner, the workpiece W is irradiated with the heating laser light LBh and the XY stage 11 is irradiated from the heating laser system 30 in a state in which the workpiece W is placed opposite to the heating laser optical system 30. Moving, the relative scanning of the heating laser light LBh for the workpiece W is achieved. By scanning the heating laser light LBh along the scribe line SL formed by the irradiation of the laser light LBs by the scribe line, the crack CR is made from the scribe line SL to the non-scribe surface W2 of the workpiece W. The predetermined breaking position progresses, whereby the workpiece W can be separated.

又,於分斷裝置100中,可在使被加工物W與位置讀取光學系統40對向配置之狀態下進行利用位置讀取光學系統40之被加工物W之攝像,並基於所獲得之攝像圖像數據,而進行修正被加工物W之水平面內之傾斜(姿勢)之對準動作。具體而言,控制系統50基於該攝像圖像數據之圖像內容(例如,對準標記之配置位置或重複圖案之配置位置等)而特定被加工物W之水平面內之傾斜(自XY載物台11之移動方向之傾斜),並對加工用載物台12提供旋轉控制信號sg4,使該加工用載物台12旋轉,以取消此種傾斜。作為特定被加工物W之水平面內之傾斜之主要方法,可應用圖案匹配法等周知之方法。 Further, in the breaking device 100, the workpiece W by the position reading optical system 40 can be imaged while the workpiece W is placed opposite to the position reading optical system 40, and based on the obtained The image data is captured, and an alignment operation for correcting the tilt (posture) in the horizontal plane of the workpiece W is performed. Specifically, the control system 50 specifies the tilt in the horizontal plane of the workpiece W based on the image content of the captured image data (for example, the arrangement position of the alignment mark or the arrangement position of the repeating pattern, etc.) (from the XY load) The tilt of the movement direction of the stage 11 is supplied to the processing stage 12 to provide a rotation control signal sg4 to rotate the processing stage 12 to cancel the tilt. As a main method of tilting in the horizontal plane of the specific workpiece W, a well-known method such as a pattern matching method can be applied.

在通常之分斷加工之情形時,於以劃線面W1成為上表面(非載置面)之方式將被加工物W固定於加工用載物台12之狀態下進行利用位置讀取光學系統40之攝像及其後之對準處理後,進行利用劃線用雷射光學系統20之劃線SL之形成,進而,藉由於加熱用雷射光學系統30中照射加熱用雷射光LBh而分斷被加工物W。 In the case of the normal cutting process, the workpiece W is fixed to the processing stage 12 so that the scribing surface W1 becomes the upper surface (non-mounting surface), and the position reading optical system is used. After the imaging of 40 and the subsequent alignment processing, the formation of the scribe line SL by the laser optical system 20 for scribing is performed, and further, the laser light LBh for heating is irradiated by the heating laser optical system 30. The workpiece W.

<對非劃線面照射加熱用雷射光> <Ironizing the non-lined surface to irradiate the laser light for heating>

以下,對於應用了上述原理之各種分斷處理之形態依序進行說明。圖7及圖8係模式性地表示藉由加熱用雷射光LBh而掃描被加工物W之非劃線面W2之形態之圖。圖7係與劃線SL之延伸方向垂直之被加工物W之剖面圖,圖8係沿著劃線SL之被加工物W之剖面圖。 Hereinafter, the form of various breaking processes to which the above-described principle is applied will be described in order. FIG. 7 and FIG. 8 schematically show a mode in which the non-scribe surface W2 of the workpiece W is scanned by the heating laser light LBh. Fig. 7 is a cross-sectional view of the workpiece W perpendicular to the extending direction of the scribe line SL, and Fig. 8 is a cross-sectional view of the workpiece W along the scribe line SL.

在圖7及圖8所示之情形時,與圖1之情形不同,預先形 成有劃線SL之劃線面W1載置於加工用載物台12,且向作為非載置面之非劃線面W2之預定分斷位置L0照射加熱用雷射光LBh。若以此種形態照射加熱用雷射光LBh,則非劃線面W2之加熱用雷射光LBh之照射位置附近成為壓縮應力場SF1,其周圍亦包含壓縮應力場SF1之下方成為拉伸應力場SF2。再者,於圖7所示之情形時,例示了劃線SL作為槽部而形成之情形,但劃線SL之形成形態並不限於此(圖7、圖14亦同樣)。 In the case shown in FIGS. 7 and 8, unlike the case of FIG. 1, the pre-form The scribing surface W1 having the scribe line SL is placed on the processing stage 12, and the heating laser light LBh is irradiated to the predetermined breaking position L0 which is the non-scribe surface W2 of the non-mounting surface. When the heating laser light LBh is irradiated in this manner, the vicinity of the irradiation position of the heating laser light LBh of the non-scribe surface W2 becomes the compressive stress field SF1, and the vicinity of the compressive stress field SF1 is also the tensile stress field SF2. . In the case shown in FIG. 7, the scribe line SL is formed as a groove portion, but the formation form of the scribe line SL is not limited thereto (the same applies to FIGS. 7 and 14).

更具體而言,若以圖7所示之形態照射加熱用雷射光LBh,則不僅在非劃線面W2而且於被加工物W之內部亦形成拉伸應力場SF2。因此,拉伸應力TS作用於位於被加工物W之內部之劃線SL之前端部分。其結果,裂痕CR自劃線SL向其上方之預定分斷位置L0進展。由於加熱用雷射光LBh沿著圖8中由箭頭AR1表示之掃描方向進行掃描,因而裂痕CR之進展部位亦隨之移動。作為結果,與圖1之情形同樣地實現基板之分斷。 More specifically, when the heating laser light LBh is irradiated in the form shown in FIG. 7, the tensile stress field SF2 is formed not only on the non-scribe surface W2 but also inside the workpiece W. Therefore, the tensile stress TS acts on the front end portion of the scribe line SL located inside the workpiece W. As a result, the crack CR progresses from the scribe line SL to the predetermined breaking position L0 above it. Since the heating laser light LBh is scanned in the scanning direction indicated by the arrow AR1 in Fig. 8, the progress portion of the crack CR also moves. As a result, the division of the substrate is achieved in the same manner as in the case of FIG.

再者,若更詳細來說,則藉由加熱用雷射光LBh所形成之應力場之空間上之分佈本身既與圖1之情形相同又與圖7及圖8之情形相同。於圖1之情形時,將劃線面W1設為加熱用雷射光LBh之被照射面,主要利用作為水平面之該劃線面W1內之應力分佈使裂痕CR進展,相對於此,於圖7及圖8之情形時,主要利用被加工物W之厚度方向(剖面方向)上之應力分佈使裂痕CR進展,於此方面兩者不同。 Further, in more detail, the spatial distribution of the stress field formed by the heating laser light LBh is the same as that of the case of Fig. 1 and the same as the case of Figs. 7 and 8. In the case of FIG. 1, the scribing surface W1 is set as the irradiated surface of the heating laser light LBh, and the crack CR is mainly progressed by the stress distribution in the scribing surface W1 which is a horizontal plane, and FIG. 7 In the case of Fig. 8, the stress distribution in the thickness direction (cross-sectional direction) of the workpiece W is mainly used to progress the crack CR, which is different in this respect.

圖9係表示實現如上對於非劃線面W2照射加熱用雷射光 LBh之分斷裝置200之概略構成之圖。再者,於圖9中,對於與圖4至圖6所示之分斷裝置100相同之構成要素附註相同之符號。又,圖9中雖省略圖示,但分斷裝置200與分斷裝置100同樣地包括控制系統50。 Fig. 9 is a view showing that the laser light for heating is irradiated to the non-line surface W2 as described above. A schematic diagram of the LBh breaking device 200. In FIG. 9, the same components as those of the breaking device 100 shown in FIGS. 4 to 6 are denoted by the same reference numerals. Further, although not shown in FIG. 9, the breaking device 200 includes the control system 50 in the same manner as the breaking device 100.

分斷裝置200概略上具有對於分斷裝置100附加反轉機構60之構成。反轉機構60相對於被加工物W如由箭頭AR3所示般進退自如,且包括:夾頭61,自側方夾持被加工物W;升降部62,使夾持有被加工物W之狀態之夾頭61如箭頭AR4所示般在鉛垂方向上升降;及反轉部63,藉由使夾持有被加工物W之狀態之夾頭61保持其夾持狀態地圍繞與圖式垂直之軸反轉180°而使被加工物W表裏翻轉。反轉機構60按照來自控制系統50之控制信號進行動作。 The breaking device 200 has a configuration in which an inverting mechanism 60 is added to the breaking device 100. The reversing mechanism 60 moves forward and backward with respect to the workpiece W as indicated by an arrow AR3, and includes a chuck 61 that grips the workpiece W from the side, and a lifting portion 62 that holds the workpiece W. The chuck 61 of the state is raised and lowered in the vertical direction as indicated by an arrow AR4; and the reversing portion 63 is surrounded and held by the chuck 61 in a state in which the workpiece W is held. The vertical axis is reversed by 180° to invert the workpiece W. The reversing mechanism 60 operates in accordance with a control signal from the control system 50.

在包括此種反轉機構60之分斷裝置200中,於以劃線面W1成為上表面(非載置面)之方式將被加工物W固定於加工用載物台12之狀態下,與分斷裝置100同樣地,進行利用位置讀取光學系統40之攝像及其後之對準處理、以及劃線用雷射光學系統20中之劃線SL之形成。若完成劃線SL之形成,則使固定有被加工物W而成之加工用載物台12向反轉機構60之下方移動。 In the breaking device 200 including the reversing mechanism 60, the workpiece W is fixed to the processing stage 12 so that the scribing surface W1 becomes the upper surface (non-mounting surface), and Similarly, the breaking device 100 performs imaging by the position reading optical system 40 and subsequent alignment processing, and formation of the scribe lines SL in the scribing laser optical system 20. When the formation of the scribe line SL is completed, the processing stage 12 to which the workpiece W is fixed is moved below the reversing mechanism 60.

若被加工物W位於反轉機構60之正下方,則加工用載物台12中之被加工物之吸附固定被解除,而由夾頭61夾持被加工物W。夾持有被加工物W之夾頭61藉由升降部62而向上方上升。繼而,一旦於加工用載物台12自反轉機構60之正下方退避後,反轉部63使被加工物W反轉。若結束此種 反轉,則將加工用載物台12再次向反轉機構60之下方配置。而且,藉由升降部62使夾頭61下降,則被加工物W在非劃線面W2成為上表面之狀態下被載置於加工用載物台12,並再次被吸附固定。 When the workpiece W is located immediately below the reversing mechanism 60, the suction fixing of the workpiece in the processing stage 12 is released, and the workpiece W is held by the chuck 61. The chuck 61 holding the workpiece W is lifted upward by the lifting portion 62. Then, when the processing stage 12 is retracted from directly below the reversing mechanism 60, the inverting portion 63 reverses the workpiece W. If this is the end When the rotation is reversed, the machining stage 12 is again placed below the reversing mechanism 60. When the chuck 61 is lowered by the lifting unit 62, the workpiece W is placed on the processing stage 12 while the non-scribe line surface W2 is on the upper surface, and is again adsorbed and fixed.

其後,於重新進行利用位置讀取光學系統40之攝像及對準處理後,供於加熱用雷射光學系統30中之分斷處理。 Thereafter, after the image capturing and alignment processing by the position reading optical system 40 is resumed, the cutting process in the heating laser optical system 30 is performed.

再者,亦可為如下形態:在將藉由反轉機構60而反轉之被加工物W以非劃線面W2為上表面而固定於加工用載物台12之前,預先將貼附有黏著性膜之環載置於加工用載物台12上,並在該膜上配置經加工反轉之被加工物W並貼附在該膜上,而將被加工物W與該膜一併固定。 In addition, the workpiece W that is reversed by the reversing mechanism 60 may be attached to the processing stage 12 with the non-scribe line surface W2 as the upper surface, and may be attached in advance. The ring of the adhesive film is placed on the processing stage 12, and the processed object W which is processed and reversed is placed on the film and attached to the film, and the workpiece W is joined together with the film. fixed.

<拉伸應力場之冷卻> <Cooling of tensile stress field>

作為使拉伸應力場SF2中之裂痕CR之進展更有效地產生之方法,有冷卻拉伸應力場SF2之方法。 As a method of generating the progress of the crack CR in the tensile stress field SF2 more efficiently, there is a method of cooling the tensile stress field SF2.

圖10及圖11係表示在對劃線面W1照射加熱用雷射光LBh之構成中,冷卻拉伸應力場SF2之情形之模式圖。圖10係與劃線SL之延伸方向垂直之被加工物W之剖面圖,圖11係被加工物W之俯視圖。 FIG. 10 and FIG. 11 are schematic diagrams showing a state in which the tensile stress field SF2 is cooled in the configuration in which the heating laser light LBh is applied to the scribe line W1. Fig. 10 is a cross-sectional view of the workpiece W perpendicular to the extending direction of the scribe line SL, and Fig. 11 is a plan view of the workpiece W.

在圖10及圖11中,於藉由加熱用雷射光LBh而沿由箭頭AR1所示之掃描方向掃描劃線面W1時,對於所形成之拉伸應力場SF2中之掃描方向後方之部分,噴射冷卻氣體CG。 In FIGS. 10 and 11, when the scribing surface W1 is scanned in the scanning direction indicated by the arrow AR1 by the heating laser light LBh, the portion behind the scanning direction in the formed tensile stress field SF2 is The cooling gas CG is sprayed.

若以此種形態進行冷卻,則拉伸應力場SF2之被冷卻之部位與藉由加熱用雷射光LBh之照射而加熱之壓縮應力場SF1之溫度差變得更高,拉伸應力場SF2中之拉伸應力變得 更強。藉此,提高裂痕CR之進展之確實性。作為結果,可更高精度地分斷被加工物W。 When cooling is performed in this form, the temperature difference between the portion to be cooled of the tensile stress field SF2 and the compressive stress field SF1 heated by the irradiation of the heating laser light LBh becomes higher, and the tensile stress field SF2 is Tensile stress becomes Stronger. Thereby, the accuracy of the progress of the crack CR is improved. As a result, the workpiece W can be separated with higher precision.

再者,作為冷卻氣體CG,例如只要適當使用惰性氣體等與被加工物W不發生反應之氣體即可。 In addition, as the cooling gas CG, for example, a gas that does not react with the workpiece W such as an inert gas may be used as appropriate.

圖12係概略地表示在圖4至圖6所示之分斷裝置100中實現冷卻氣體CG之噴射之構成之一例之圖。即,於圖12所示之情形中,附設有用以對加熱用雷射光學系統30噴射冷卻氣體CG之噴嘴36,且可使自冷卻氣體供給源37通過供給管38而供給之冷卻氣體CG與加熱用雷射光LBh之掃描(相對掃描)同步地自噴嘴36向拉伸應力場SF2噴射。 Fig. 12 is a view schematically showing an example of a configuration for realizing the injection of the cooling gas CG in the breaking device 100 shown in Figs. 4 to 6 . That is, in the case shown in Fig. 12, the nozzle 36 for injecting the cooling gas CG to the heating laser optical system 30 is attached, and the cooling gas CG supplied from the cooling gas supply source 37 through the supply pipe 38 can be supplied. The scanning (relative scanning) of the heating laser light LBh is simultaneously ejected from the nozzle 36 to the tensile stress field SF2.

然而,冷卻拉伸應力場SF2之形態並不限於利用如上冷卻氣體CG之噴射之形態,只要無與被加工物之反應性、或分斷裝置之腐蝕等問題,則亦可進行利用液體之冷卻。即,亦可進行利用包含氣體及液體之流體之冷卻。又,亦可為如藉由使固體冷媒接近或接觸於拉伸應力場SF2而進行冷卻之形態。 However, the form of the cooling tensile stress field SF2 is not limited to the form of the ejection of the cooling gas CG as described above, and the liquid cooling may be performed as long as there is no problem with the reactivity with the workpiece or the corrosion of the breaking device. . That is, cooling using a fluid containing a gas and a liquid can also be performed. Further, it may be a form in which the solid refrigerant is cooled by approaching or contacting the tensile stress field SF2.

圖13係概略地表示在圖9所示之分斷裝置200中設置冷卻拉伸應力場SF2之構成之情形之一例之圖。於分斷裝置200中,自固定於加工用載物台12之被加工物W之內部至載置面側形成有拉伸應力場SF2。因此,如圖13所示,於加工用載物台12上設置用以將載置於其上表面之被加工物W自劃線面W1側進行冷卻之冷卻機構13。藉由設置此種冷卻機構13,而拉伸應力場SF2中之拉伸應力進一步增強。藉此,提高裂痕CR之進展之確實性。作為結果,可更高精 度地分斷被加工物W。 FIG. 13 is a view schematically showing an example of a configuration in which the cooling tensile stress field SF2 is provided in the breaking device 200 shown in FIG. 9. In the breaking device 200, a tensile stress field SF2 is formed from the inside of the workpiece W fixed to the processing stage 12 to the mounting surface side. Therefore, as shown in FIG. 13, the processing stage 12 is provided with a cooling mechanism 13 for cooling the workpiece W placed on the upper surface thereof from the side of the scribe line W1. By providing such a cooling mechanism 13, the tensile stress in the tensile stress field SF2 is further enhanced. Thereby, the accuracy of the progress of the crack CR is improved. As a result, it can be higher The workpiece W is divided in degrees.

作為冷卻機構13,例如可使用珀爾帖(Peltier)元件或冷卻板(coolplate)等。 As the cooling mechanism 13, for example, a Peltier element, a cooling plate, or the like can be used.

如以上說明般,根據本實施形態,藉由照射劃線用雷射光而沿著預先形成於被加工物之預定分斷位置之劃線照射加熱用雷射光,並藉由加熱被加工物而使拉伸應力作用於劃線,而使自劃線向非劃線面之裂痕之進展沿著劃線之延伸方向依序產生,由此可分斷被加工物。又,藉由冷卻拉伸應力場,而可使裂痕之進展更高效率地產生。 As described above, according to the present embodiment, by irradiating the laser beam for scribing, the laser beam for heating is irradiated along a scribe line formed in advance at a predetermined breaking position of the workpiece, and the workpiece is heated by heating. The tensile stress acts on the scribe line, and the progress of the crack from the scribe line to the non-scribe surface is sequentially generated along the extending direction of the scribe line, whereby the workpiece can be separated. Further, by cooling the tensile stress field, the progress of the crack can be generated more efficiently.

而且,照射劃線用雷射光而形成劃線之劃線加工可在高精度地定位加工對象位置後進行。因此,於相同之裝置內,於預定分斷位置高精度地形成劃線,緊接著,進行利用雷射加熱之拉伸應力之產生,由此可高效率地進行高精度之分斷加工。 Further, the scribe line processing in which the scribe line is irradiated with the laser light can be performed after positioning the processing target with high precision. Therefore, in the same apparatus, the scribe line is formed with high precision at the predetermined breaking position, and then the tensile stress by the laser heating is generated, whereby the high-precision breaking processing can be efficiently performed.

<變形例> <Modification>

圖14係表示對非劃線面W2照射加熱用雷射光LBh之另一形態之圖。於上述實施形態中,表示藉由使非劃線面W2朝向上側,且自上方照射加熱用雷射光LBh,而對非劃線面W2照射加熱用雷射光LBh之形態,但亦可代替該形態而如圖14所示,藉由於使非劃線面W2朝向下側之狀態下自下方朝向非劃線面W2照射加熱用雷射光LBh,而使拉伸應力TS作用於劃線SL。此可藉由以下來實現:例如在分斷裝置100中,藉由使加熱用雷射光LBh透過之材質而形成加工用載物台12,並在加工用載物台12之下方設置加熱用雷 射光學系統30。 Fig. 14 is a view showing another form of irradiating the non-line surface W2 with the heating laser light LBh. In the above-described embodiment, the non-line surface W2 is directed upward, and the heating laser light LBh is irradiated from above, and the non-line surface W2 is irradiated with the heating laser light LBh. As shown in FIG. 14, the heating laser light LBh is irradiated from the lower side toward the non-scribe line surface W2 in a state where the non-scribe line surface W2 is directed downward, and the tensile stress TS is applied to the scribe line SL. This can be achieved by, for example, forming the processing stage 12 by the material for transmitting the heating laser light LBh in the breaking device 100, and providing a heating thunder below the processing stage 12. Optical system 30.

10‧‧‧載物台部 10‧‧‧The Stage Department

11‧‧‧XY載物台 11‧‧‧XY stage

12‧‧‧加工用載物台 12‧‧‧Processing stage

13‧‧‧冷卻機構 13‧‧‧Cooling mechanism

20‧‧‧劃線用雷射光學系統 20‧‧‧ Laser optical system for marking

21‧‧‧雷射振盪器 21‧‧‧Laser oscillator

21a‧‧‧快門 21a‧‧ ‧Shutter

22‧‧‧衰減器 22‧‧‧Attenuator

23‧‧‧物鏡 23‧‧‧ Objective lens

24‧‧‧鏡 24‧‧ ‧ mirror

30‧‧‧加熱用雷射光學系統 30‧‧‧Lighting laser system for heating

31‧‧‧雷射振盪器 31‧‧‧Laser oscillator

31a‧‧‧快門 31a‧‧ ‧Shutter

32‧‧‧衰減器 32‧‧‧Attenuator

33‧‧‧光束調整機構 33‧‧‧beam adjustment mechanism

34‧‧‧物鏡 34‧‧‧ Objective lens

35‧‧‧鏡 35‧‧‧Mirror

36‧‧‧噴嘴 36‧‧‧Nozzles

37‧‧‧冷卻氣體供給源 37‧‧‧Cooling gas supply

38‧‧‧供給管 38‧‧‧Supply tube

40‧‧‧光學系統 40‧‧‧Optical system

50‧‧‧控制系統 50‧‧‧Control system

60‧‧‧反轉機構 60‧‧‧Reversal mechanism

61‧‧‧夾頭 61‧‧‧ chuck

62‧‧‧升降部 62‧‧‧ Lifting Department

63‧‧‧反轉部 63‧‧‧Reversal Department

100‧‧‧分斷裝置 100‧‧‧ Breaking device

200‧‧‧分斷裝置 200‧‧‧ Breaking device

CG‧‧‧冷卻氣體 CG‧‧‧Cooling gas

CR‧‧‧裂痕 CR‧‧‧ crack

L0‧‧‧預定分斷位置 L0‧‧‧Predetermined breaking position

LBh‧‧‧加熱用雷射光 LBh‧‧‧Lighting for heating

LBs‧‧‧劃線用雷射光 LBs‧‧‧Leading laser light

SF1‧‧‧壓縮應力場 SF1‧‧‧Compressive stress field

SF2‧‧‧拉伸應力場 SF2‧‧‧ tensile stress field

SL‧‧‧劃線 SL‧‧‧

TS‧‧‧拉伸應力 TS‧‧‧ tensile stress

W‧‧‧被加工物 W‧‧‧Processed objects

W1‧‧‧(被加工物之)劃線面 W1‧‧‧ (worked object) line

W2‧‧‧(被加工物之)非劃線面 W2‧‧‧ (processed material) non-dash surface

圖1係模式性地表示分斷加工中途之情形之圖。 Fig. 1 is a view schematically showing a situation in the middle of the breaking process.

圖2係使用CO2雷射作為加熱用雷射光LBh而分斷藍寶石基板時之分斷面之SEM像。 2 is an SEM image of a cross section of a sapphire substrate when a CO 2 laser is used as the heating laser light LBh.

圖3(a)、(b)係表示在分斷面較為平坦之情形時與在平坦面存在起伏之情形時之分斷面中之光之前進方向之不同之圖。 3(a) and 3(b) are diagrams showing the difference in the forward direction of the light in the cross-section when the split surface is relatively flat and the undulation is present on the flat surface.

圖4係概略地表示分斷裝置100之構成之圖。 FIG. 4 is a view schematically showing the configuration of the breaking device 100.

圖5係表示劃線用雷射光學系統20之詳細構成之圖。 Fig. 5 is a view showing a detailed configuration of the laser optical system 20 for scribing.

圖6係表示加熱用雷射光學系統30之詳細構成之圖。 Fig. 6 is a view showing a detailed configuration of the heating laser optical system 30.

圖7係模式性地表示藉由加熱用雷射光LBh而掃描被加工物W之非劃線面W2之形態之圖。 FIG. 7 is a view schematically showing a state in which the non-scribe surface W2 of the workpiece W is scanned by the heating laser light LBh.

圖8係模式性地表示藉由加熱用雷射光LBh而掃描被加工物W之非劃線面W2之形態之圖。 FIG. 8 is a view schematically showing a state in which the non-scribe surface W2 of the workpiece W is scanned by the heating laser light LBh.

圖9係表示分斷裝置200之概略構成之圖。 FIG. 9 is a view showing a schematic configuration of the breaking device 200.

圖10係表示在對劃線面W1照射加熱用雷射光LBh之構成中,冷卻拉伸應力場SF2之情形之模式圖。 FIG. 10 is a schematic view showing a state in which the tensile stress field SF2 is cooled in the configuration in which the heating laser light LBh is applied to the scribe line W1.

圖11係表示在對劃線面W1照射加熱用雷射光LBh之構成中,冷卻拉伸應力場SF2之情形之模式圖。 FIG. 11 is a schematic view showing a state in which the tensile stress field SF2 is cooled in the configuration in which the heating laser light LBh is applied to the scribe line W1.

圖12係概略地表示在分斷裝置100中實現冷卻氣體CG之噴射之構成之一例之圖。 FIG. 12 is a view schematically showing an example of a configuration for realizing the injection of the cooling gas CG in the breaking device 100.

圖13係概略地表示在分斷裝置200中設置冷卻拉伸應力場SF2之構成之情形之一例之圖。 FIG. 13 is a view schematically showing an example of a configuration in which the cooling tensile stress field SF2 is provided in the breaking device 200.

圖14係表示對非劃線面W2照射加熱用雷射光LBh之另一形態之圖。 Fig. 14 is a view showing another form of irradiating the non-line surface W2 with the heating laser light LBh.

12‧‧‧加工用載物台 12‧‧‧Processing stage

13‧‧‧冷卻機構 13‧‧‧Cooling mechanism

30‧‧‧加熱用雷射光學系統 30‧‧‧Lighting laser system for heating

W‧‧‧被加工物 W‧‧‧Processed objects

Claims (11)

一種被加工物之分斷方法,其特徵在於,其係分斷被加工物之方法,且包括:劃線加工步驟,其係藉由使第1雷射光自第1出射源出射,並對上述被加工物之劃線面照射上述第1雷射光,而於上述劃線面上形成劃線;及照射加熱步驟,其係藉由使第2雷射光自第2出射源出射,並自上述劃線面之相反面即非劃線面側沿著上述劃線照射上述第2雷射光,而將上述被加工物沿著上述劃線進行加熱;且於上述照射加熱步驟中,藉由於以使上述劃線面與冷卻媒體接觸之方式將上述被加工物載置於上述冷卻媒體上之狀態下使上述第2雷射光沿著上述劃線相對地進行掃描,而藉由上述第2雷射光對上述非劃線面之照射,使形成於包含上述劃線面之上述被加工物之內部且為上述劃線附近之拉伸應力場移動並冷卻,藉此,使因上述劃線位於上述拉伸應力場內而產生之自上述劃線向上述非劃線面之裂痕之進展沿著上述劃線依序產生,從而將上述被加工物分斷。 A method for dividing a workpiece, characterized in that it is a method for separating a workpiece, and comprising: a scribing processing step of causing the first laser light to be emitted from the first emission source, and The scribing surface of the workpiece is irradiated with the first laser light, and the scribing surface is formed with a scribe line; and an irradiation heating step is performed by ejecting the second laser light from the second emission source The second laser light is irradiated along the line on the opposite side of the line surface, and the workpiece is heated along the scribe line; and in the irradiation heating step, The second laser light is scanned relative to the scribe line while the scribe line is in contact with the cooling medium, and the second laser light is scanned by the second laser light. Irradiation of the non-line surface, the tensile stress field formed in the inside of the workpiece including the scribing surface and in the vicinity of the scribe line is moved and cooled, whereby the scribe line is located at the tensile stress From the above Sequentially generated along the scribe line to the crack to progress in the face of the non-chain line, thereby breaking the above-mentioned workpiece. 如請求項1之被加工物之分斷方法,其中於上述照射加熱步驟中,於利用調整機構調整自上述第2出射源出射之上述第2雷射光之照射範圍後,將上述第2雷射光照射至上述非劃線面。 The method for dividing a workpiece according to claim 1, wherein in the irradiation heating step, the second laser light is irradiated after the irradiation range of the second laser light emitted from the second emission source is adjusted by an adjustment mechanism Irradiation to the above non-lined surface. 如請求項1或2之被加工物之分斷方法,其中 上述第2雷射光係CO2雷射。 A method of breaking a workpiece according to claim 1 or 2, wherein said second laser light is a CO 2 laser. 如請求項3之被加工物之分斷方法,其中於上述照射加熱步驟中,以脈衝振盪模式照射上述第2雷射光,於藉由分斷上述被加工物所形成之單片之分斷面上,產生具有與脈衝振盪週期對應之週期之全反射率降低用之起伏。 The method for dividing a workpiece according to claim 3, wherein in the illuminating step, the second laser light is irradiated in a pulse oscillation mode to separate a single piece formed by the workpiece In the above, an undulation for reducing the total reflectance with a period corresponding to the pulse oscillation period is generated. 如請求項1或2之被加工物之分斷方法,其中上述第1雷射光係YAG雷射之3倍高次諧波。 The method for breaking a workpiece according to claim 1 or 2, wherein the first laser light system is a triple harmonic of the YAG laser. 如請求項1或2之被加工物之分斷方法,其中更包括對準處理步驟,該對準處理步驟係對上述被加工物之水平面內之姿勢進行修正;且對於已進行上述對準處理步驟之上述被加工物,進行上述劃線加工步驟及上述照射加熱步驟。 The method for breaking a workpiece according to claim 1 or 2, further comprising an alignment processing step of correcting a posture in a horizontal plane of the workpiece; and performing the above alignment processing In the step, the object to be processed is subjected to the scribing processing step and the irradiation heating step. 如請求項1或2之被加工物之分斷方法,其中於上述劃線加工步驟中,藉由於上述第1雷射光之被照射位置產生熔融及再固化,使上述被照射位置成為變質區域,從而形成上述劃線。 The method for dividing a workpiece according to claim 1 or 2, wherein in the scribing processing step, the irradiated position is changed into a metamorphic region by melting and re-solidifying the irradiated position of the first laser light, Thereby the above scribe line is formed. 如請求項1或2之被加工物之分斷方法,其中於上述劃線加工步驟中,藉由於上述第1雷射光之被照射位置產生燒蝕而於上述被照射位置形成槽部,從而形成上述劃線。 The method for dividing a workpiece according to claim 1 or 2, wherein in the scribing step, the groove is formed at the irradiated position by ablation of the irradiated position of the first laser light, thereby forming a groove portion The above line. 如請求項1或2之被加工物之分斷方法,其中於上述劃線加工步驟中,於彼此正交之第1方向與第2方向上分別以特定間距形成複數條劃線;且 於上述照射加熱步驟中,於已進行自上述非劃線面側沿著於上述第1方向上延伸之上述劃線之照射加熱後,進行沿著於上述第2方向上延伸之上述劃線之照射加熱。 The breaking method of the workpiece according to claim 1 or 2, wherein in the scribing processing step, a plurality of scribe lines are formed at a specific pitch in the first direction and the second direction orthogonal to each other; In the irradiation heating step, after the irradiation of the scribe line extending from the non-scribe surface side along the first direction is performed, the scribe line extending along the second direction is performed. Irradiation heating. 如請求項9之被加工物之分斷方法,其中於上述照射加熱步驟中,將上述第2雷射光之照射光束直徑設為形成上述劃線時之間距以下。 The method for dividing a workpiece according to claim 9, wherein in the irradiation heating step, the diameter of the irradiation beam of the second laser light is set to be equal to or less than a distance between the scribe lines. 一種具有光學元件圖案之基板之分斷方法,其特徵在於:其係分斷於表面二維地形成有光學元件圖案之具有光學元件圖案之基板之方法,且包括:劃線加工步驟,其係藉由使第1雷射光自第1出射源出射,並對上述具有光學元件圖案之基板之劃線面照射上述第1雷射光,而於上述劃線面上形成劃線;及照射加熱步驟,其係藉由使CO2雷射即第2雷射光自第2出射源出射,並自上述劃線面側沿著上述劃線照射上述第2雷射光,而將上述具有光學元件圖案之基板沿著上述劃線進行加熱;且於上述照射加熱步驟中,藉由使上述第2雷射光沿著上述劃線相對地進行掃描,而使於上述具有光學元件圖案之基板上藉由上述第2雷射光之照射而形成於照射加熱區域之周圍之拉伸應力場移動,藉此,使因上述劃線位於上述拉伸應力場內而產生之自上述劃線向上述非劃線面之裂痕之進展沿著上述劃線依序產生,從而分斷上述具有光學元件圖案之 基板;並且藉由使上述第2雷射光以脈衝振盪模式出射,而於藉由分斷上述被加工物所形成之光學元件單片之分斷面上,產生具有與脈衝振盪週期對應之週期之全反射率降低用之起伏。 A method for breaking a substrate having an optical element pattern, characterized in that it is a method for dividing a substrate having an optical element pattern in which an optical element pattern is two-dimensionally formed on a surface, and includes: a scribing processing step, The first laser light is emitted from the first emission source, and the first laser light is irradiated onto the scribe line surface of the substrate having the optical element pattern, and a scribe line is formed on the scribe line surface; and an irradiation heating step is performed. The second laser light emitted from the second emission source, which is a CO 2 laser, is emitted from the second emission source, and the second laser light is irradiated from the scribe line side along the scribe line to form the substrate along the optical element pattern. Heating the scribe line; and in the illuminating step, scanning the second laser light along the scribe line to cause the second ray on the substrate having the optical element pattern The tensile stress field formed around the irradiation heating region by the irradiation of the light is moved, thereby causing the crack from the scribe line to the non-scribe surface due to the scribe line being located in the tensile stress field The progress is sequentially generated along the above-mentioned scribe lines to divide the substrate having the optical element pattern; and the second laser light is emitted in a pulse oscillation mode to form an optical body by dividing the workpiece On the cross-section of the component monolith, an undulation for reducing the total reflectance of the period corresponding to the pulse oscillation period is generated.
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