TW201023964A - Optimal operation control method and apparatus applied to concentration wheel system - Google Patents

Optimal operation control method and apparatus applied to concentration wheel system Download PDF

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TW201023964A
TW201023964A TW97149892A TW97149892A TW201023964A TW 201023964 A TW201023964 A TW 201023964A TW 97149892 A TW97149892 A TW 97149892A TW 97149892 A TW97149892 A TW 97149892A TW 201023964 A TW201023964 A TW 201023964A
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concentration
runner
vocs
desorption
concentrated
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TW97149892A
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Chinese (zh)
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Feng-Tang Chang
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Jg Environmental Tech Co Ltd
Feng-Tang Chang
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Abstract

The present invention relates to optimal operation control method and apparatus applied to concentration wheel system. The concentration wheel is a multi-channel honeycomb-like concentration wheel, which is employed for adsorbing, purifying and concentrating treatments of volatile organic compounds. By way of a mathematical relationship of optimal operation, this invention proposes a method of optimal operation control and an apparatus to provide concentration wheel factories with online automatic monitoring control to assist in the operation of concentration wheel to optimal efficiency. It can at the same time achieve environmental protection and energy saving, and fulfill the concept of comprehensive carbon tax.

Description

201023964 六、發明說明: 【發明所屬之技術領域】 本發明係揭示-種用於濃縮轉輪系統最佳化運轉控 制之方法及裝置’更具體而言,係關於一種用於多孔道蜂 巢狀吸附濃縮轉輪系統中,可即時監控揮發性有機物之淨 化及處理過程’並即時控制該漢縮轉輪之運轉及相關操作 條件,以達最佳化運轉該濃縮轉輪之方法及 【先前技術】 、 現今工業界或高科技業者於處理揮發性有機物時,於◎ 高濃度時多採用冷凝法收集該揮發性有機物,而於低濃度 且大風量時則採用以物理吸附方式濃縮處理後,再送往小 型焚化爐燃燒或以冷凝裝置回收,其中又以冷凝裝置回收 較具經濟效益。 於吸附方法處理揮發性有機物時,係使用含吸附劑之 多孔性物質將廢氣中所含之揮發性有機物(Vo·201023964 VI. Description of the Invention: [Technical Field of the Invention] The present invention discloses a method and apparatus for optimal operation control of a concentrated reel system. More specifically, it relates to a honeycomb adsorption for a porous channel. In the concentrated reel system, the process of purifying and treating volatile organic compounds can be monitored immediately and the operation of the Han revolver and related operating conditions can be controlled in time to optimize the operation of the concentrated reel and [prior art] In today's industrial or high-tech industries, when volatile organic compounds are treated, the volatile organic compounds are collected by condensation at high concentrations, and concentrated at a low concentration and high air volume by physical adsorption. It is more economical to burn to a small incinerator or to recover it with a condensing unit. When the volatile organic matter is treated by the adsorption method, the volatile organic substance contained in the exhaust gas is used by using a porous substance containing an adsorbent (Vo·

Organic Compounds,V0Cs)或臭味經由物理或化學方式 吸附,以達到淨化該揮發性有機廢氣之目的。而當該吸附〇 劑達飽和之後,須再經由-脫附程序將吸附劑所吸附之物 質去除,才可重覆使用。 例如,於PU合成皮之製程中,係大量採用如丁嗣 (methyi ethyl ketone,MEK)及 f 笨(T〇iuene)及異丙醇 (is〇pr〇Pyl alc〇hol,IPA)及二甲基甲醯胺(dmf)等等之容 劑,且該等溶劑於其溶液中之比率約為6〇〜8〇%。於 之後,須再經過烘乾處理’方可將所有溶劑蒸發;於其製 201023964 程中,平均製造一碼合成皮須使用35〇克溶劑,亦即一碼 合成皮之完成須排放350克溶劑於大氣中,造成大量v〇Cs 污染,以全台九千萬碼為產量為單位基礎,每年會有三萬 噸的有機溶劑被排放於大氣中,造成相當嚴重的環境污 染,叙若該等廢氣於排放前未經充分有效的淨化處理,將 會嚴重污染我們周遭的大氣環境,則曰後將耗費更大量資 . 源來排除該等污染。 . 再者,電子產業為了有效處理於其相關製程中所產生 • 的有機廢氣,係採用沸石濃縮轉輪並搭配焚化爐來處理其 有機廢氣,此一方法須耗用大量的焚化燃料及能源,非為 去除有機廢氣諸多方法中最為經濟實用者。 以半導體業晶圓廠所產生的有機廢氣成分為例,其所 排放之廢氣中常含有如二甲亞砜(Dimethyl Sulf〇xide)、N_ 曱基0比嘻酮(N_Methyl Pyrolidone)、乙醇銨 (2-Aminoethanol)、二甲基二硫醇(Dithi〇lethylene ❷ Glyco1)、一曱基硫醇(Dimethyl Sulfide)、異丙醇(IsopropylOrganic Compounds (V0Cs) or odors are physically or chemically adsorbed for the purpose of purifying the volatile organic waste gas. When the adsorbent is saturated, the adsorbed material must be removed by a desorption procedure before it can be reused. For example, in the process of PU synthetic skin, a large number of such methods are used such as methyi ethyl ketone (MEK) and f 〇 ene (ene) and isopropanol (is〇pr〇Pyl alc〇hol, IPA) and dimethyl A monomer such as carbamide (dmf) or the like, and the ratio of the solvents in the solution is about 6 〇 to 8 〇%. After that, it must be dried again to evaporate all the solvents; in the process of 201023964, an average of one yard of synthetic leather must be used with 35 grams of solvent, that is, one yard of synthetic leather must be discharged 350 grams of solvent. In the atmosphere, a large amount of v〇Cs pollution is caused. Based on the output of 90 million yards of Taiwan, 30,000 tons of organic solvents are emitted into the atmosphere every year, causing considerable environmental pollution. If the exhaust gas is not fully and effectively cleaned before discharge, it will seriously pollute the surrounding environment. After that, it will consume a lot of resources to eliminate the pollution. Furthermore, in order to effectively treat the organic waste gas generated in its related processes, the electronics industry uses a zeolite concentration runner and an incinerator to treat its organic waste gas. This method requires a large amount of incineration fuel and energy. It is not the most economical and practical method for removing organic waste gas. Taking the organic waste gas component produced by the semiconductor fab as an example, the exhaust gas discharged from the semiconductor industry often contains, for example, Dimethyl Sulfxide, N_Methyl Pyrolidone, and Ethyl Ammonium (2). -Aminoethanol), Dithi〇lethylene ❷ Glyco1, Dimethyl Sulfide, Isopropyl

Alcohol)、丙酮(Acet〇ne)等化合物,於運用沸石轉輪吸附 濃縮廢氣後’再經焚化爐於攝氏25〇〜9〇〇〇c以上之溫度燃 燒’來分解這些揮發性有機物質、臭氣及毒氣最為有效。 ’ 目前以吸附濃縮沸石轉輪處理搭配燃燒焚化的方式,進行 揮發性有機氣體的廢氣排放處理,已在半導體及光電業界 廣為採用。 又,揮發性有機物 (volatile organic compounds, VOCs) 是台灣地區常見空氣污染物之一,其主要來源為化學工 5 201023964 廠、石化工業、印刷業、塗裝業以及目前新興之半導體與 光電液晶顯示器產業。由於VOCS所具備之毒性以及引起 臭氧產生與光化學效應形成之特質,若不加以控制使其恣 意排放在大氣中,將會帶來相當重大之危害。國内曰前已 經立法針對石化工業、塗裝業、半導體業、合成皮革及乾 洗相關行業之VOCs排放污染進行嚴格管制;另,國家目 前重點發展之薄膜電晶體液晶顯示器(Thin-Film Transistor Liquid-Crystal Display, TFT LCD),亦已公告實 施「光電材料及元件製造業空氣污染管制及排放標準」,® 期能對VOCs排放量曰趨增大之TFT-LCD產業能夠加以 妥善管制。 沸石濃縮轉輪系統為利用吸附一脫附一濃縮焚化等 三項連續程序使VOCs裂解為無害之H20及co2,其設備 特性適合處理高流量、中低污染物濃度及含一種或多種類 之VOCs廢氣,亦可應用於排放較稀薄且接近周界溫度之 污染物工業。而VOCs廢氣進入系統後,首先係經過多通❹ 道蜂巢狀轉輪’例如蜂巢狀沸石濃縮轉輪為以陶瓷纖維紙 上塗覆不同比例之ZSM-5與Y型式等沸石經特殊加工後 成型,可達到VOCs吸附量大、氣流壓損小及整體重量輕 量化之目的》 其中該VOCs污染物質可同時於轉輪上進行吸附及濃 縮脫附;通常蜂巢狀轉輪可分為三部分:較大之吸附區 (adsorption zone)及兩個較小且面積相當之脫附區 (desorption zone)及冷卻區(co〇iing z〇ne)。第一階段之吸附 6 201023964 程序是將進入系統後之VOCs廢氣於常溫下予以吸附淨化 後直接排放至大氣,接著因轉輪之轉動而進入第二階段之 脫附程序’此脫附所須之熱空氣是由冷卻區出口之預熱空 氣與後端焚化系統熱交換後之熱空氣(約150〜300。〇來提 供’使其進入轉輪内將有機物脫附再生出來,此時出流污 染物濃度大約為入流廢氣之5〜20倍左右,而脫附再生出 來之有機物則可於第三階段之熱焚化爐進行高溫(直燃爐 .於600°C以上或觸媒爐於25〇eC以上)之焚化或是進行低溫 ® 之冷凝回收再利用等程序,如此可以減少後續之廢氣處理 單元尺寸’並節省初設費用及運轉費用》Alcohol), acetone (Acet〇ne) and other compounds, after using the zeolite wheel to adsorb concentrated exhaust gas, 'burning in the incinerator at a temperature above 25 ° C ~ 9 ° C to decompose these volatile organic substances, stinky Gas and gas are most effective. At present, the exhaust gas treatment of volatile organic gases has been widely used in the semiconductor and optoelectronic industries by means of adsorption-concentrated zeolite rotor treatment combined with combustion incineration. Moreover, volatile organic compounds (VOCs) are one of the most common air pollutants in Taiwan. Their main sources are chemical industry 5 201023964 plant, petrochemical industry, printing industry, coating industry and emerging semiconductor and optoelectronic liquid crystal displays. industry. Due to the toxicity of VOCS and the characteristics that cause the formation of ozone and photochemical effects, if it is not controlled to be released into the atmosphere, it will bring considerable harm. At present, China has already legislated to strictly control the emission of VOCs in the petrochemical industry, coating industry, semiconductor industry, synthetic leather and dry cleaning related industries. In addition, the country's current development of thin film transistor liquid crystal display (Thin-Film Transistor Liquid- Crystal Display (TFT LCD) has also announced the implementation of "Opto-Electric Materials and Components Manufacturing Air Pollution Control and Emission Standards". The TFT-LCD industry, which is capable of increasing the emission of VOCs, can be properly controlled. The zeolite concentration runner system uses three consecutive procedures such as adsorption-desorption-concentration incineration to crack the VOCs into harmless H20 and co2. The equipment characteristics are suitable for treating high-flow, medium-low pollutant concentrations and VOCs containing one or more types. Exhaust gas can also be used in industries that emit thinner and near-perimeter temperatures. After the VOCs exhaust gas enters the system, it is firstly processed through a multi-pass tunnel honeycomb rotor, such as a honeycomb zeolite concentrate runner, which is coated with ceramic fiber paper with different proportions of ZSM-5 and Y-type zeolites. It can achieve the purpose of large adsorption amount of VOCs, small pressure loss of gas flow and light weight of the whole body. The VOCs pollutants can be adsorbed and concentrated and desorbed on the runner at the same time; usually the honeycomb rotor can be divided into three parts: larger The adsorption zone and two smaller and equivalent desorption zones and cooling zones. The first stage of adsorption 6 201023964 The procedure is to discharge the VOCs after entering the system to the atmosphere at a normal temperature, and then directly discharge to the atmosphere, and then enter the second stage of the desorption process due to the rotation of the wheel. The hot air is the hot air after the heat exchange between the preheated air at the exit of the cooling zone and the back end incineration system (about 150~300. 提供 to provide 'to make it into the runner to desorb the organic matter, then the outflow pollution The concentration of the substance is about 5 to 20 times that of the inflowing exhaust gas, and the organic matter desorbed and regenerated can be subjected to high temperature in the third stage of the heat incinerator (direct combustion furnace. Above 600 ° C or catalyst furnace at 25 ° eC) The above incineration or the process of condensing recovery and reuse of low temperature® can reduce the size of the subsequent exhaust gas treatment unit 'and save initial installation cost and running cost”

Mitsuma 等人研究(Mitsuma,Υ·,H. Yamauchi,and T. Hirose, ^Analysis of VOC reversing adsorption and desorption characteristics for actual efficiency prediction for ceramic honeycomb adsorbent”,J. Chem. Eng. Japan, 1998, 31(2),ρρ·253-257)指出轉輪轉速、轉輪脫附面積比、轉輪 φ 寬度及脫附氣流流速為影響沸石轉輪去除VOCs之主要操 作參數,經由所歸納出之操作參數關係式可符合於當地之 實場運作值;另外 Chang 等人(Chang, F.T.,B.S. Pei,and Y.K. Chuah, “Performance of Honeycomb VOCs • concentrators for An Exhaust Gas·”,Proceedings 8thMitsuma et al. (Mitsuma, H. Yamauchi, and T. Hirose, ^Analysis of VOC reversing adsorption and desorption characteristics for actual efficiency prediction for ceramic honeycomb adsorbent), J. Chem. Eng. Japan, 1998, 31 ( 2), ρρ·253-257) indicates that the rotational speed of the runner, the ratio of the decoupling area of the runner, the width of the rotor φ and the velocity of the desorbed airflow are the main operational parameters affecting the removal of VOCs by the zeolite runner, and the operational parameter relationships are summarized. The model can be adapted to the local field operation value; in addition, Chang et al. (Chang, FT, BS Pei, and YK Chuah, “Performance of Honeycomb VOCs • concentrators for An Exhaust Gas·”, Proceedings 8th

Conference on Aerosol Science and Technology, 2000, pp.552-557, Hsin-Chu,Taiwan)修正上述]Vlitsuma 等人之最 適化無因次操作參數,加入沸石轉輪基體與廢氣熱傳性 質、再生溫度、脫附濃縮比、VOCs進流濃度及轉輪寬度 7 201023964 等實際影響沸石轉輪性能之應用操作參數值,其推論結果 除與實場運作效能驗證後更具一定之可信度外,亦發現 VOCs濃度過高或是再生溫度太低,會在質量與熱能平衡 限制下導致沸石轉輪系統處理效率顯著下降。 除了上述操作參數預估轉輪效能關係式歸納之外,Conference on Aerosol Science and Technology, 2000, pp. 552-557, Hsin-Chu, Taiwan) Correcting the above-mentioned optimal operating parameters of Vlitsuma et al., adding zeolite runner substrate and heat transfer properties, regeneration temperature, Desorption concentration ratio, VOCs influent concentration and runner width 7 201023964 and other practical operating parameter values that affect the performance of the zeolite runner. The inference results are more reliable than the real-world operational efficiency verification. If the concentration of VOCs is too high or the regeneration temperature is too low, the treatment efficiency of the zeolite runner system will be significantly reduced under the limitation of mass and heat balance. In addition to the above operational parameters, it is estimated that the runner performance relationship is summarized.

Chang 等人(Chang,F.T.,Y.C. Lin,H. Bai,B.S. Pei,Chang et al. (Chang, F.T., Y.C. Lin, H. Bai, B.S. Pei,

Adsorption and Desorption Characteristics of VOCs on theAdsorption and Desorption Characteristics of VOCs on the

Thermal Swing Honeycomb Zeolite Concentrator,,,Journal of the Air & Waste Management Association,2003,53,❹ pp. 1384-1390)針對進流廢氣溫濕度變化及各重要操作參 數’進行該系統去除效率之影響探討,結果顯示系統去除 效率與升高之廢氣進流溫度及環境相對濕度呈現反比,而 此兩條件可列為系統效率之檢核因子,研究中亦發現沸石 轉輪系統最佳效能所相對應之轉速需隨著v〇Cs進流濃度 上升而增加;而當降低系統處理時之濃縮倍率將有助於 VOCs去除效率之提升,不過所降低之濃縮倍率將相對使❹ 得後端焚化能源耗用增多。在系統節能研究方面一項於實 廠沸石轉輪系統所進行調校再生溫度及再生風量等兩個 操作參數值之研究,結果發現經適度調整此兩參數其系統 效能可向上提升至96.5%、大於原廠建議操作值下95%, 亦可相對節省23%之後段焚化燃料費用。 然而,上述研究所提出關於進流濃度、轉輪轉速、濃 縮濃度、再生溫度等是決定沸石濃縮轉輪之運轉效率重要 操作參數,脫附濃縮比也將決定後端焚化爐操作時所需投 201023964 ,制端::二:旦目別使用沸石濃縮轉輪之廠家僅在中央 =:根據調整者的經驗以試誤法進行調t=: 運轉實場操作有其複雜性及困難度,有待進一步提出有 效控制違縮轉輪運轉之方法及裝置,以為達成濃縮轉輪之 便㈣錢本祕狀 e 有鑑於上述習知濃縮轉輪於操作時之 =:完善’遂蝎其心智悉心研究克服 項產業多年之累積經驗,進而研發出一套最佳化 ❹ t方法及裝置,藉由-最佳化操作之數學關係式,以= 參數以調整效率及能源耗用,係直接整合於同—操作平 台,如此可以大幅減少廠務人員之工作負擔及調整人員經 驗之不足與誤判,若面對工廠製程負載情況所造成之進流 濃度或風量變化,能直接進行各項參數調整,旅即時獲得 處理效能、轉輪運轉與後端終處理單元能源消耗,使得濃 縮轉輪系統操作上更簡潔、方便。 ' 為提成上述之目的,本發明係提供一種用於濃縮轉輪 系統最佳化運轉控制之方法,.其係提供該濃縮轉輪系統中 各控制因子之一數學關係式(1)如下:Thermal Swing Honeycomb Zeolite Concentrator,,,Journal of the Air & Waste Management Association,2003,53,❹ pp. 1384-1390) Discussion on the effect of the system removal efficiency on the temperature and humidity changes of the inflow exhaust gas and various important operating parameters The results show that the system removal efficiency is inversely proportional to the increased exhaust gas inflow temperature and the relative humidity of the environment. These two conditions can be listed as the check factor of the system efficiency. The best performance of the zeolite runner system is also found in the study. The rotational speed needs to increase as the influx concentration of v〇Cs increases; while the concentration ratio when the system is reduced will contribute to the improvement of VOCs removal efficiency, but the reduced concentration ratio will relatively reduce the consumption of the back-end incineration energy. increase. In the system energy-saving research, a study on the two operating parameters of the regenerative temperature and the regenerative air volume in the real-world zeolite reel system, the system performance of the two parameters can be improved to 96.5%. It is greater than 95% of the original recommended operating value, and can also save 23% in the subsequent period of incineration fuel costs. However, the above research suggests that the influent concentration, the rotating speed, the concentrated concentration, the regeneration temperature, etc. are important operational parameters that determine the operating efficiency of the zeolite concentrate runner. The desorption concentration ratio will also determine the investment required for the operation of the back end incinerator. 201023964, the end of the system:: two: Dan manufacturers do not use the zeolite concentrate runner only in the center =: according to the adjuster's experience with the trial and error method t =: The operation of the real field operation has its complexity and difficulty, pending Further proposes a method and device for effectively controlling the operation of the deflated reels, in order to achieve the condensed reel (4) money secrets e in view of the above-mentioned conventional condensed reels in operation =: perfect '遂蝎 心 心 心 心 心 心 心 心The accumulated experience of the industry for many years has led to the development of a set of optimized methods and devices. By optimizing the mathematical relationship of operations and using = parameters to adjust efficiency and energy consumption, they are directly integrated into the same Operation platform, which can greatly reduce the workload of the factory staff and adjust the lack of experience and misjudgment of personnel experience, if the flow concentration or air volume change caused by the factory process load situation You can directly adjust the parameters, trip instant access processing performance, and the rear wheel final operation processing unit energy consumption, such concentrated cleaner operation runner system convenient. For the purposes of the above, the present invention provides a method for optimal operation control of a condensed reel system, which provides a mathematical relationship (1) of one of the control factors in the condensed reel system as follows:

C *)x (r)° x 473C *)x (r)° x 473

xCcxVpd =,K 其中: Ν =濃縮轉輪之轉速(RPH); 201023964 t=濃縮轉輪之厚度(m); r=濃縮倍率;xCcxVpd =, K where: Ν = speed of concentrated runner (RPH); 201023964 t = thickness of concentrated runner (m); r = concentration ratio;

Td =脫附溫度(Κ=ΐ:+273 15); c =入口總碳氫化合物之濃度值(ppm);Td = desorption temperature (Κ = ΐ: +273 15); c = concentration of total hydrocarbons in the inlet (ppm);

Vp =吸附入口風速(m/s);及 數值a、b、c、d、c*及常數κ係依據不同漢縮轉輪 及實麻場合經數次操作即可求得其值。 並上述數學關係式中之數值a最佳係介於等於〇〜3 之間,而數值b、c、d最佳係介於等於_3〜3之間,且數❹ 值c*係與轉輪滚縮器之質傳帶彳!^“ transfer zone)有關, 其數值係介於等於〇〜濃縮轉輪厚度t之間。 如上所述之方法,其中該脫附溫度係界於15(TC至 300°C,且其中該濃縮轉輪之轉速係界於1至1〇 rph。 如上所述之方法,其中該濃縮轉輪之轉輪型式可為轉 環式或轉盤式;且於該濃縮轉輪上塗覆之多孔性吸附劑可 為沸石、活性碳、矽膠或活性氧化鋁。 q 如所述之方法,其中該方法之實施步驟為: (a) 設定去除效率(r?R)之一目標值; (b) 選定脫附溫度(Td)值; (c) 依據人口總碳氫化合物之濃度值(C)及選定之吸附 入口風速(Vp),調整濃縮轉輪之轉速(N); (d) 確認去除效率0/r)是否大於等於目標值; (e) 調整脫附風量(即調整濃縮倍率);以及 (f) 去除效率0R)等於目標值。 201023964 如所述之方法,其中該去除效率係界於70%至99.9%。 如所述之方法’其中除該步驟(a)設定去除效率之一目 標值及⑴去除效率等於目標值之次序不可變動外,步驟(b) 至步驟(e)中之各項因子皆可變動其選定或調整次序。 本發明提供一種用於濃縮轉輪系統最佳化運轉控制 之裝置1其係用以執行如上所述之方法,其係包含: 一浪縮轉輪,用以吸附VOCs,且包含一吸附區、一 再生脫附區及一冷卻區; 一第一風車’係抽送VOCs廢氣流經該濃縮轉輪之吸 附區, 第一熱交換器,係提供該濃縮轉輪之再生脫附區脫 附氣流之熱源以加熱該濃縮轉輪之再生脫附區; 一第二風車,用於抽送來自該第一熱交換器之熱氣, 以自該濃縮轉輪之脫附區脫附VOCs ; 一第二熱交換器’係用以加熱該經脫附之v〇Cs; 一焚化爐’以燃燒淨化VOCs ;以及 一數據處理器,以監控相關運轉參數。 本發明並提供另一種用於濃縮轉輪系統最佳化運轉 控制之裝置,其係用以執行如上所述之方法,其係包含: 一濃縮轉輪,用以吸附VOCs,且包含一吸附區、一 再生脫附區; 一第一風車,係抽送VOCs廢氣流經該濃縮轉輪之吸 11 201023964 附區; 一第一熱交換器’係提供該濃縮轉輪之再生脫附區脫 附氣流之熱源以加熱該濃縮轉輪之再生脫附區; 一第二風車,用於抽送來自該第一熱交換器之熱氣, 以自該濃縮轉輪之脫附區脫附VOCS ; 一終端處理單元,以淨化VOCs ;以及 一數據處理器,以監控相關運轉參數。 如上所述之裝置中,其中該終端處理單元係進一步包◎ 含一冷凝器、一焚化爐及一觸媒氧化器。 如上所述之裝置,其中該熱交換器可為間接加熱式或 直接加熱式之熱交換器。 藉此,本發明之一種用於漠縮轉輪系統最佳化運轉控 制之方法及裝置,藉由一最佳化操作之數學關係式,以操 作參數以調整效率及能源耗用,係直接整合於同一操作平 台,如此可以大幅減少廠務人員之工作負擔,若面對工廠❹ 製程負載情況所造成之進流濃度變化,能直接進行各項參 數調整’並即時獲得處理效能、轉輪運轉與後端焚化能源 消耗’使得濃縮轉輪系統操作上更簡潔、方便。 【實施方式】 為使充分瞭解本發明之目的、特徵及功效,茲藉由下 述具體之實施例,並配合所附之圖式,對本發明做一詳細 說明,說明如後: 一般簡易而言,濃縮轉輪之VOCs去除效率(t?r)定義: 12 201023964 %=心^^啤..(%) PPmV(X) 其中該ppmv(入)為入口總碳氫化合物之濃度值,而 ppm〇則為出口總碳氳化合物之濃度值,而該去除效率係 由濃縮轉輪運轉後所得出之結果,而濃縮轉輪之運轉係由 諸多因子所控制,於本發明中基於該等控制因子而提出一Vp = adsorption inlet wind speed (m/s); and the values a, b, c, d, c* and constant κ can be obtained by several operations according to different Han revolving wheels and solid hemp occasions. And the value a in the above mathematical relationship is between 〇~3, and the values b, c, d are between _3 and 3, and the value c is c* The transfer zone of the wheel reducer is related to the transfer zone, and its value is between 〇~concentration runner thickness t. As described above, the desorption temperature is bounded by 15 (TC). Up to 300 ° C, and wherein the speed of the concentrated reel is between 1 and 1 〇 rph. The method as described above, wherein the revolving wheel of the condensing wheel can be a rotary ring or a rotary disk; and The porous adsorbent coated on the runner may be zeolite, activated carbon, silicone or activated alumina. q As described, wherein the method is carried out as follows: (a) setting one of removal efficiency (r?R) Target value; (b) Select the desorption temperature (Td) value; (c) Adjust the rotation speed (N) of the concentration wheel according to the population total hydrocarbon concentration value (C) and the selected adsorption inlet wind speed (Vp); (d) confirm whether the removal efficiency 0/r) is greater than or equal to the target value; (e) adjust the desorption air volume (ie, adjust the concentration ratio); and (f) remove the efficiency 0R) 201023964 The method as described, wherein the removal efficiency is between 70% and 99.9%. The method as described above, wherein the step (a) sets one of the removal efficiency target values and (1) the removal efficiency is equal to the target value. The order of the steps (b) to (e) can be changed by the selection or adjustment order. The present invention provides an apparatus for optimizing the operation control of a concentrated reel system. To perform the method as described above, comprising: a wave revolving wheel for adsorbing VOCs, and comprising an adsorption zone, a regeneration desorption zone and a cooling zone; a first windmill's pumping VOCs exhaust gas flow through The adsorption zone of the concentration runner, the first heat exchanger provides a heat source for desorbing the gas stream in the regeneration desorption zone of the concentration wheel to heat the regeneration desorption zone of the concentration wheel; and a second windmill for pumping The hot gas from the first heat exchanger desorbs VOCs from the desorption zone of the concentration wheel; a second heat exchanger 'is used to heat the desorbed v〇Cs; an incinerator' to burn Purify VOCs; and a data processor to monitor related Operational Parameters The present invention provides another apparatus for optimal operation control of a concentrating reel system for performing the method as described above, comprising: a concentrating reel for absorbing VOCs, and comprising An adsorption zone, a regeneration desorption zone; a first windmill, which pumps the VOCs exhaust gas through the suction wheel of the concentration wheel; 201023964 attachment zone; a first heat exchanger' provides the regeneration desorption zone of the concentration runner Desorbing a heat source of the gas stream to heat the regeneration desorption zone of the concentration wheel; a second windmill for pumping hot gas from the first heat exchanger to desorb the VOCS from the desorption zone of the concentration wheel; A terminal processing unit to purify the VOCs; and a data processor to monitor the relevant operating parameters. In the apparatus as described above, wherein the terminal processing unit further comprises a condenser, an incinerator and a catalyst oxidizer. The apparatus as described above, wherein the heat exchanger is an indirect heated or directly heated heat exchanger. Therefore, the method and device for optimizing the operation control of the desert runner system are directly integrated by operating parameters to adjust efficiency and energy consumption by a mathematical relationship of optimized operation. On the same operating platform, this can greatly reduce the workload of the factory personnel. If the influent concentration change caused by the factory's process load is changed, the parameters can be directly adjusted' and the processing efficiency and the running of the runner can be obtained immediately. The back-end incineration energy consumption makes the concentrated reel system more compact and convenient to operate. DETAILED DESCRIPTION OF THE INVENTION In order to fully understand the objects, features and effects of the present invention, the present invention will be described in detail by the following specific embodiments and the accompanying drawings. , VOCs removal efficiency (t?r) definition of concentrated runner: 12 201023964 %=heart^^ beer..(%) PPmV(X) where ppmv(in) is the concentration of total hydrocarbons in the inlet, and ppm The enthalpy is the concentration value of the total carbon cerium compound for export, and the removal efficiency is the result obtained after the operation of the concentrating runner, and the operation of the concentrating runner is controlled by a plurality of factors, which are based on the control factors in the present invention. Propose one

數學關係式(1)為: N x(t — c *)x (r)a 其中: xThe mathematical relation (1) is: N x(t - c *)x (r)a where: x

Td \bTd \b

xCcxV^ =K ⑴ N =濃縮轉輪之轉速(RPH); t =濃縮轉輪之厚度(m); r =濃縮倍率;xCcxV^ =K (1) N = speed of the concentrated runner (RPH); t = thickness of the concentrated runner (m); r = concentration ratio;

Td =脫附溫度(K=°C+273.15); C =入口總礙氫化合物之濃度值(ppm);Td = desorption temperature (K = °C + 273.15); C = concentration of the total hydrogen barrier compound (ppm);

Vp =吸附入口風速(m/s);以及 數值a、b、c、d、c*及常數K係依據不同濃縮轉輪 及實廠場合經數次操作即可求得其值。 並上述數學關係式中之數值a最佳係介於等於0〜3 之間,而數值b、c、d最佳係介於等於-3〜3之間,且數 值c*係與轉輪濃縮器之質傳帶(mass transfer zone)有關, 其數值係介於等於0〜濃縮轉輪厚度t之間。 上述之數學關係式(1)係為濃縮轉輪之最佳化控制 中,用於控制濃縮轉輪之操作因子,包含:N-濃縮轉輪之 13 201023964 轉速、W農縮轉輪之厚度、4縮倍率(=廢氣風量/脫附風 量)Td-脫附溫度、c_入口總碳氮化合物之漠度值及外 吸,入口風速,其中,於實廠中使用固定之漠縮轉輪進行 特疋VOCs處理時,該濃縮轉輪厚度⑴及入口總碳氨化合 物為確定’此時,當設定去除效率⑹之一目標 ,時,尚需考慮之因子包含:N、r、T(^Vp值,係由實 场操作者,先订設定其中兩因子,例如選定脫附溫度 及吸附入口風速(vP)值,再調整該轉輪速度(N)即可決定濃 縮倍率進㈣魏附風量,即可達至所訂定之去除效率。 第一圖係為本發明中I缩轉輪㈣最佳化運轉控制 之方法之-具體實施步驟,其中,首先於狀去除效 之一目標值後,再選定脫附溫度Td值,接著,依據入= PPmV(入)及選定之吸入口風逮Vp,再調整濃縮轉輪之轉 速(N),此時,檢驗該去除效率⑹是否大於等於目標值, 若否,則繼續調整濃縮轉輪之轉速;若該肽等於目標值, 則完成最佳化調整;當該去除效率⑹大於目標值則調 整脫附風量(即改調整濃縮倍率)’使該去除效率(Μ)等於 目標值’即完成最佳化調整;若仍大於目標值,則繼續調 整脫附風量,使最終該去除效率等於目標值,而完成 最佳化調整。 疋 而於上述第一圖中之步驟,針對各個操作因子之調整 順序並非絕對,係可基於實薇操作人員之需求,先行選定 其所預設定之因子,再基於本發明中所提供之數學關係^ (1) ’決定其他因子之數值,最終完成濃縮轉輪系統之最佳 201023964 化運轉控制。 而數學關係式(1)係為本發明所建立,其係用於提供 本發明中用於執行濃縮轉輪運轉最佳方法之一數據處理 器’藉以判斷、調整各項操作參數以達到理想V0Cs去除 效率。 另’本發明濃縮轉輪系統最佳化運轉控制裝置之一具 體實施例如第二圖所示,其中V〇Cs廢氣氣流⑴進入一濃 縮轉輪10(本實施例中之濃縮轉輪為轉盤式,但亦可為轉 ❷ 環式)之吸附區經過吸附處理後(本實施例中之多孔性吸附 劑為沸石,但亦可為活性碳、矽膠或活性氧化鋁),淨化 後之乾淨氣流(II)則經由一第一風車12之抽引、排放,而 該濃縮轉輪10處理VOCs之效率值可經由置於該濃縮轉 輪10入口前與出口後之總碳氫化合物分析儀42及44,分 別檢測處理前後之各V0Cs濃度計算得之,該總碳氫化合 物分析儀之檢測方法係依照環保署公告之「排放管道中總 _ 碳氫化合物及非甲烷總碳氫化合物含量自動檢測方法-線 上火燄離子化偵測法」進行檢測。而部分VOCs作為冷卻 氣流(III)通入沸石轉輪之冷卻區,降低該濃縮轉輪10因熱 脫附後所殘留之熱量’此股氣流經過一第一熱交換器52 提升溫度後’轉變成高溫脫附氣流(IV)通入脫附區將原本 吸附在該濃縮轉輪10上之有機廢氣吸附物質以高溫脫附 而出,其中脫附氣流量可由一變頻器48控制一第二風車 14所決定,其中V〇Cs之脫附濃縮比定義為經脫附之乾淨 氣流II流量除以進入脫附區之高溫脫附氣流IV流量。 15 201023964 兩濃度v〇cs經脫附離開濃縮轉輪10之後進入一第 二熱交換器54進行預熱,隨後導入一焚化爐6〇進行高溫 氧化,焚化後之乾淨氣體經由該第二熱交換器54降溫, 並流經後績管線進行排放。其中該濃縮轉輪1〇之轉速經 由一變頻器46搭配一驅動馬達5〇加以控制。而由於脫附 濃縮比之調整會使得脫附後高濃度VOCs進入焚化爐之流 量有所改變,因此該焚化爐6〇另設有電熱偶計,並配合 燃料進流流量計控制進流燃料以維持一定高溫,以有效焚 化該濃縮後V0Cs。 ❹ 其中,VOCs處理前後濃度分別由總碳氫化合物分析 儀42及44所監測,且由一廢氣流量計32監控其流量; 而轉輪轉速係由變頻器46搭配驅動馬達50所控制;而脫 附氣流抽氣量係由變頻器48搭配第二風車14所控制,並 由一脫附風量流量計34所監控;並由一脫附溫度計36監 測脫附溫度;另具一作動器38調整冷卻氣流(in)及高溫氣 流(IV)之值,並將以上相關操作參數均連接至終端一數據 處理器80。 ® 系統可依照VOCs進流濃度變化,進行轉輪轉速調 整’若VOCs進流濃度增加、為避免轉輪吸附區吸附貫穿 現象,則需提升轉輪轉速、使吸附區及早進入脫附區進行 熱脫附,而提高轉速亦使得脫附停留時間減短,此時就需 提高熱能量才能充分VOCs自沸石轉輪脫附而出。提高熱 能量可用提高脫附溫度或提高脫附風量或同時提高兩項 參數來達成,後端焚化爐為應付此時所提高之處理風量, 201023964 需增加適當之燃料、以維持焚化溫度,確保v〇Cs焚化效 率,反之若VOCs進流濃度降低,則轉輪轉速即可調降, 接著可降低脫附風量,在處理風量較少之情況之下,後端 焚化爐所使用之燃料亦可減少。 此外焚化爐所使用之燃料大多為天然氣,若焚化後出 口檢測到偵測CHU濃度,則代表燃燒溫度不足,在此溫度 下天然氣無法完全獲得燃燒,所以出口端CH4之檢測可作 • 為判定燃燒溫度設定是否恰當之指標,處理系統可依照焚 參 化爐尾氣ch4濃度高低進行焚化爐焚化溫度及風量調 整’ CH4漢度過面需要提高燃燒溫度或降低天然氣進流 量’另外亦可能脫附風量不足,使得焚化爐内燃燒氣流形 成層流(laminar flow)所引起之不完全燃燒所致,因此需 提升脫附風量。 再者,本發明濃縮轉輪系統最佳化運轉控制裝置之另 一具體實施例如第三圖所示,其裝置大致如第二圖中所 示,僅該濃輪轉輪10中僅具吸附區及脫附區,並流經該 脫附區之乾淨氣流(11)可再流經該第一熱交換器5 2提升溫 度,成高溫脫附氣流(IV)而通入該濃縮轉輪(10)之脫附 區,進行脫附作用,其中該高溫脫附氣流(IV)係由該作動 器38所控制調整;並經脫附之VOCs由該第二風車之抽 吸而進入一終處理單元70,進行後續V〇Cs之處理,且該 終處理單元70係可含冷凝器、焚化爐及觸媒氧化器,以 完成VOCs之淨化。 本發明中所設置一即時數據處理器即可利用上述方 17 201023964 法之操作模式使得濃縮轉輪運轉效能可達到最佳化控 制’並可由終端監控人員依當時實際需要直接在控制平台 修正操作參數,就能調整沸石轉輪運轉、並立即獲得各項 操作參數、VOCs處理效率及焚化燃料耗用之現況回報。 實施例 實施例一及實施例二係以第二圖之裝置進行測試,以 高科技業實廠 VOCs 為 IPA(20%)、Acteone(15%)、 PGME(20%)及PGMEA(45%)作為該VOCs之廢氣來源,並 其入口溫濕度:20〜30。(:及35〜70%RH,且該疏水性沸石❹ 漢縮轉輪厚度為〇.4m(實施例一)及0.45m(實施例二),並 該轉輪之風面比= 10:14(吸附:脫附··冷卻),脫附溫度 控制介於160〜250°C,轉輪轉數控制於2〜6RPH間,終處 理單元為焚化爐以淨化處理v〇Cs;第三圖為實施例三所 使用之裝置,以實廠VOCs為DMF(l〇〇%)作為該VOC之 廢氣來源,並其入口溫濕度:25〜4〇£>c及35〜6〇%RH,且 該活性碳纖維濃縮轉輪厚度為〇 4m(實施例三),並該轉輪❹ 之風面比=5:1 (吸附:脫附),脫附溫度控制介於15〇〜22〇 C ’轉輪轉數控制於Ho,間,終處理單元為冷凝吸 收器以回收DMF溶劑;進而分別以習知濃縮轉輪(無本發 明中之數據處理器參照數學關係式⑴之監控),與本案發 明中使用之方法進行測試,其結果如下表一所示。 18 201023964 表 比較例一 實施例一 比較例二 實施例二 比較例三 實施例三 率及耗能之比較 最佳化運轉控制 iif單70脫附風車平 +均耗能量均耗電量及 脫附平均耗 無 有 無 有 並 有 70%~97〇/〇 90% 70%~90°/〇 85% 70%~90% 95% 100% <50% 100% <40% 100% ^40% 100% <90% 100% <75% 100% <50%Vp = adsorption inlet wind speed (m/s); and the values a, b, c, d, c* and constant K can be obtained by several operations according to different concentrated runners and actual occasions. And the value a in the above mathematical relationship is between 0 and 3, and the values b, c, and d are between -3 and 3, and the value c* is concentrated with the runner. The mass transfer zone is related to a value equal to 0 to the thickness t of the concentrated runner. The above mathematical relationship (1) is an operation factor for controlling the concentrated revolving wheel in the optimization control of the concentrated revolving wheel, including: N-concentration runner 13 201023964 rotation speed, thickness of W agricultural revolving runner, 4 reduction ratio (= exhaust air volume / desorption air volume) Td-desorption temperature, c_ingress total carbon and nitrogen indifference value and external suction, inlet wind speed, wherein, in the factory, a fixed desert wheel is used. When the VOCs are treated, the concentration of the concentrated runner (1) and the total carbon ammonia at the inlet are determined. At this time, when setting one of the removal efficiency (6) targets, the factors to be considered include: N, r, T (^Vp The value is determined by the real-world operator, first setting two factors, such as selecting the desorption temperature and the adsorption inlet wind speed (vP) value, and then adjusting the reel speed (N) to determine the concentration ratio into the (four) Wei air volume. The removal efficiency can be achieved. The first figure is the method for optimizing the operation control of the I revolving wheel (4) in the present invention - the specific implementation step, wherein, firstly, one target value is removed after the shape is removed, and then Select the desorption temperature Td value, then, based on the input = PPmV (in) and selected Inhaling the wind and catching Vp, and then adjusting the speed of the concentrated reel (N). At this time, check whether the removal efficiency (6) is greater than or equal to the target value. If not, continue to adjust the rotation speed of the concentrated reel; if the peptide is equal to the target value, Then, the optimization adjustment is completed; when the removal efficiency (6) is greater than the target value, the desorption air volume is adjusted (ie, the concentration ratio is adjusted), so that the removal efficiency (Μ) is equal to the target value, that is, the optimization adjustment is completed; if still greater than the target For the value, the desorption air volume is continuously adjusted so that the removal efficiency is equal to the target value, and the optimization adjustment is completed. However, in the steps in the first figure above, the adjustment order for each operation factor is not absolute, and may be based on the actual Wei's operator needs to select the pre-set factors first, and then based on the mathematical relationship provided by the invention ^ (1) 'determine the value of other factors, and finally complete the optimal 201023964 operation control of the concentrated runner system. The mathematical relation (1) is established by the present invention, and is used to provide a data processor for performing the concentrated rotation operation of the present invention. Disconnect and adjust various operating parameters to achieve the desired V0Cs removal efficiency. Another embodiment of the optimized operation control device of the concentrated revolver system of the present invention is as shown in the second figure, wherein the V〇Cs exhaust gas flow (1) enters a concentrated transfer. The adsorption zone of the wheel 10 (the concentrating wheel in this embodiment is a rotary disk type, but may also be a rotary ring type) is subjected to adsorption treatment (the porous adsorbent in the present embodiment is zeolite, but may also be activated carbon). , 矽 或 or activated alumina), the cleaned clean air stream (II) is drawn and discharged through a first windmill 12, and the efficiency value of the concentrating wheel 10 for processing VOCs can be placed at the inlet of the concentrating wheel 10 The total hydrocarbon analyzers 42 and 44 after the front and the exit are respectively calculated by measuring the concentration of each V0Cs before and after the treatment. The method for detecting the total hydrocarbon analyzer is in accordance with the EPA's “Total _ Carbon in the discharge pipeline”. The automatic detection method for the content of hydrogen compounds and non-methane total hydrocarbons - on-line flame ionization detection method is tested. And part of the VOCs are passed into the cooling zone of the zeolite runner as the cooling gas stream (III), and the residual heat of the concentration wheel 10 after the thermal desorption is reduced. 'This gas stream passes through a first heat exchanger 52 to raise the temperature and then transforms. The high-temperature desorption gas stream (IV) is introduced into the desorption zone to desorb the organic waste gas adsorbing substance originally adsorbed on the concentration reel 10 at a high temperature, wherein the degassing gas flow rate can be controlled by a frequency converter 48 to control a second windmill 14 determines that the desorption concentration ratio of V〇Cs is defined as the desorbed clean gas stream II flow divided by the high temperature desorption gas flow IV flow entering the desorption zone. 15 201023964 The two concentrations v〇cs are desorbed from the concentration runner 10 and then enter a second heat exchanger 54 for preheating, and then introduced into an incinerator 6 for high temperature oxidation, and the cleaned gas after incineration passes the second heat exchange. The device 54 cools down and flows through the post-performance pipeline for discharge. The speed of the concentrating wheel 1 is controlled by a frequency converter 46 in combination with a driving motor 5 。. Since the desorption concentration ratio adjustment will change the flow rate of the high concentration VOCs entering the incinerator after desorption, the incinerator 6 has a thermocouple meter and controls the inflow fuel with the fuel inflow flow meter. Maintain a certain high temperature to effectively incinerate the concentrated V0Cs. ❹ wherein the concentration of the VOCs before and after the treatment is monitored by the total hydrocarbon analyzers 42 and 44, respectively, and the flow rate is monitored by an exhaust gas flow meter 32; and the rotational speed of the rotor is controlled by the inverter 46 in conjunction with the drive motor 50; The airflow volume is controlled by the frequency converter 48 in conjunction with the second windmill 14, and is monitored by a desorption air flow meter 34; and the desorption temperature is monitored by a desorption thermometer 36; and an actuator 38 is used to adjust the cooling airflow. (in) and the value of the high temperature airflow (IV), and the above related operational parameters are all connected to the terminal-data processor 80. The system can adjust the rotation speed according to the VOCs influent concentration change. If the VOCs inflow concentration increases, in order to avoid the adsorption penetration phenomenon in the reel adsorption area, the rotation speed of the reel should be increased, and the adsorption area should enter the desorption area early for heat. Desorption, and increasing the rotational speed also makes the desorption retention time shorter. At this time, it is necessary to increase the thermal energy to fully desorb the VOCs from the zeolite rotor. Increasing the heat energy can be achieved by increasing the desorption temperature or increasing the amount of desorbed air or increasing the two parameters. In order to cope with the increased air volume at this time, the 201023964 needs to add appropriate fuel to maintain the incineration temperature and ensure that v 〇Cs incineration efficiency, if the VOCs inflow concentration is reduced, the rotation speed of the rotor can be reduced, and then the desorption air volume can be reduced. Under the condition of less air volume, the fuel used in the back-end incinerator can also be reduced. . In addition, most of the fuel used in the incinerator is natural gas. If the outlet detects the detection of CHU concentration after incineration, it means that the combustion temperature is insufficient. At this temperature, the natural gas cannot be completely burned, so the detection of CH4 at the outlet end can be used to determine the combustion. Whether the temperature setting is appropriate or not, the treatment system can adjust the incineration temperature and air volume of the incinerator according to the concentration of the tail gas of the incinerator. The CH4 Handu surface needs to increase the combustion temperature or reduce the natural gas inflow rate. In addition, the air volume may be insufficient. Therefore, the combustion gas flow in the incinerator is caused by incomplete combustion caused by laminar flow, so the amount of desorption air needs to be increased. Furthermore, another specific embodiment of the optimized operation control device of the concentrated reel system of the present invention is shown in the third figure, and the device is substantially as shown in the second figure, and only the concentrating wheel 10 has only the adsorption zone. And the desorption zone, and the clean gas stream (11) flowing through the desorption zone can be further passed through the first heat exchanger 52 to raise the temperature, and the high temperature desorption gas stream (IV) is introduced into the concentration revolving wheel (10). Desorption zone, wherein the high temperature desorption gas stream (IV) is controlled by the actuator 38; and the desorbed VOCs are pumped by the second windmill into a final processing unit 70. Perform subsequent V〇Cs processing, and the final processing unit 70 may include a condenser, an incinerator, and a catalytic converter to complete the purification of the VOCs. The instant data processor provided in the invention can utilize the operation mode of the above-mentioned party 17 201023964 method to make the concentrated runner running performance achieve optimal control' and the terminal monitoring personnel can directly correct the operating parameters on the control platform according to the actual needs at the time. The zeolite runner can be adjusted and the operating parameters, VOCs processing efficiency and incineration fuel consumption can be immediately obtained. EXAMPLES Example 1 and Example 2 were tested with the apparatus of the second figure, with high-tech VOCs as IPA (20%), Acteone (15%), PGME (20%) and PGMEA (45%). As the source of exhaust gas for the VOCs, and its inlet temperature and humidity: 20~30. (: and 35 to 70% RH, and the thickness of the hydrophobic zeolite ❹ 缩 wheel is 〇.4m (Example 1) and 0.45m (Example 2), and the wind ratio of the runner = 10:14 (Adsorption: desorption · · cooling), desorption temperature control is between 160~250 °C, the number of revolutions is controlled between 2~6RPH, and the final treatment unit is incinerator to purify v〇Cs; the third picture is The apparatus used in the third embodiment uses the factory VOCs as DMF (l〇〇%) as the exhaust source of the VOC, and the inlet temperature and humidity thereof: 25~4〇>c and 35~6〇%RH, and The thickness of the activated carbon fiber concentrated runner is 〇4m (Example 3), and the wind surface ratio of the runner ==5:1 (adsorption: desorption), and the desorption temperature is controlled between 15〇22〇22′′ The number of rotations is controlled by Ho, and the final processing unit is a condensing absorber to recover the DMF solvent; and then the conventional concentrated revolving wheel (without the data processor of the present invention refers to the monitoring of the mathematical relationship (1)), and the invention of the present invention The method used in the test was carried out, and the results are shown in the following Table 1. 18 201023964 Table Comparative Example 1 Example 1 Comparative Example 2 Example 2 Comparative Example 3 Example 3 Comparison of rate and energy consumption Optimized operation control iif single 70 desorption windmill flat + average energy consumption and desorption average consumption is all-in-one and 70%~97〇/〇90% 70%~90° /〇85% 70%~90% 95% 100% <50% 100% <40% 100% ^40% 100% <90% 100% <75% 100% <50%

,,^ " --<50% :上表-可知,以f知操作方法操作濃縮轉輪,其轉 巧=率係為70%〜97% ’效能不定,且所需之終處理 ; = = ί ’並且該脫附風車平均耗電量及脫附熱 ㈣較^ “,制本發日种之—觀於漢縮 轉輪系統最佳化運轉控制之方法及裝置,可依據操作者之 ^求而訂定轉輪處理效率’対纽減少終處理單元耗能 一半以上’亦可減低顏所需之耗能量,並本發明中係利 用一即時數據處理器來進行監控,可以大幅減少礙務人員 之工作負擔’面對工|製程負載情況所造成之進流漢度變 化亦能直接進行各項參數調整,使得彿石濃縮轉輪系統 操作上更簡潔、方便。 _本發明在上文中已以較佳實施例揭露,然熟習本項技 術者應理解的是,該實施例僅用於描繪本發明,而不應解 讀為限制本發明之範圍。應注意的是,舉凡與該實施例等 效之變化與置換,均應設為涵蓋於本發明之範疇内。因 此,本發明之保護範圍當以下文之申請專利範圍所界定者為準。 【圖式簡單說明】 201023964 第一圖為本發明濃縮轉輪系統最佳化運轉控制之方法之 一具體實施步驟圖。 第二圖為本發明濃縮轉輪系統最佳化運轉控制裝置之一 具體實施例。 第三圖為本發明濃縮轉輪系統最佳化運轉控制裝置之另 一具體實施例。 【主要元件符號說明】 10 濃縮轉輪 12 第一風車 ❿ 14 第二風車 32 廢氣流量計 34 脫附風量流量計 36 脫附溫度計 38 作動器 42 總碳氫化合物分析儀 44 總碳氫化合物分析儀 ◎ 46 變頻器 48 變頻 50 驅動馬達 52 第一熱交換器 54 第二熱交換器 60 焚化爐 70 終處理單元 80 數據處理器 20 201023964,, ^ "--<50%: above table - it can be seen that the operation of the concentrated revolver by f knowing the operation method, the transfer rate = 70% ~ 97% 'efficiency, and the final treatment required; = = ί 'and the average power consumption of the decoupled windmill and the desorption heat (4) are better than the "however" method, which is based on the operator's method and device for optimal operation control of the Hansui wheel system. The processing efficiency of the reel is set to reduce the energy consumption of the final processing unit by more than half, which can also reduce the energy consumption required by the color, and the present invention utilizes an instant data processor for monitoring, which can be greatly reduced. The workload of the obstructing staff's influx of the influx caused by the workmanship and process load conditions can also directly adjust the parameters, making the Fossil Concentrated Wheel System more compact and convenient to operate. The present invention has been disclosed in the preferred embodiments, and it should be understood by those skilled in the art that the present invention is not intended to limit the scope of the present invention. It should be noted that The equivalent changes and substitutions should be set to cover this Therefore, the scope of protection of the present invention is defined by the scope of the following patent application. [Simple description of the drawings] 201023964 The first figure is one of the methods for optimizing the operation control of the concentrated wheel system of the present invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The second figure is a specific embodiment of the optimized operation control device for the concentrated reel system of the present invention. The third embodiment is another specific embodiment of the optimal operation control device for the concentrated reel system of the present invention. [Main component symbol description] 10 Concentrated runner 12 First windmill ❿ 14 Second windmill 32 Exhaust flow meter 34 Desorption air flow meter 36 Desorption thermometer 38 Actuator 42 Total hydrocarbon analyzer 44 Total hydrocarbon analyzer ◎ 46 Inverter 48 Inverter 50 Drive motor 52 First heat exchanger 54 Second heat exchanger 60 Incinerator 70 Final processing unit 80 Data processor 20 201023964

i 廢氣氣流 II 乾淨氣流 III 冷卻或脫附入口氣流 IV 高溫脫附氣流 V 燃料或電能或熱能等輸入能源 21i Exhaust gas flow II Clean air flow III Cooling or desorption of inlet gas flow IV High temperature desorption gas flow V Fuel or input energy such as electrical energy or heat 21

Claims (1)

201023964 七、申請專利範圍: 1、一種用於濃縮轉輪系統最佳化運轉控制之方法,其係提 供該濃縮轉輪系統中各控制因子之一數學關係式(1)如 下: N y^{t-c *)x (r)fl 473 J =K 其中: N=濃縮轉輪之轉速(RPH); t =濃縮轉輪之厚度(m); r =濃縮倍率; Td =脫附溫度(K=°C+273.15); C=入口總碳氫化合物之濃度值(ppm); Vp =吸附入口風速(m/s);及 數值a、b、c、d、c*及常數K係依據不同濃縮轉輪 及實廠場合經數次操作即可求得其值。 2、 如申請專利範圍第1項所述之方法,其中該脫附溫度係 界於 150°C 至 300°C。 3、 如申請專利範圍第1項所述之方法,其中該濃縮轉輪之 轉速係界於1至10 RPH & 4、 如申請專利範圍第1項所述之方法,其中該濃縮轉輪之 轉輪型式可為轉環式或轉盤式。 5、 如申請專利範圍第1項所述之方法,其中該濃縮轉輪上 塗覆之多孔性吸附劑可為沸石、活性碳、矽膠或活性氧 化紹。 22 201023964 6、 如申請專利範圍第1至5項任一項所述之方法,其中該 方法之實施步驟為: ⑷設定去除效率如)之一目標值; (b) 選定脫附溫度(Td)值; (c) 依據人口總权氣化合物之值(C)及選定之吸附入 口風速(Vp),調整濃縮轉輪之轉速(N); - (d)媒認去除效率(ηκ)是否大於等於目標值; (e)調整脫附風量(即調整濃縮倍率);以及 ® (f)去除效率〇?R)等於目標值。 7、 如申請專利範圍第6項所述之方法,其中該去除效率係 界於 70%至 99.9%。 ' 8、 如申請專利範圍第ό項所述之方法,其中除該步騍(&)讯 定去除效率之一目標值及(f)去除效率等於目標值之次^ 不可變動外’步驟(b)至步驟(e)中之各項因子皆可變動其 選定或調整次序。 、 φ 9、一種用於濃縮轉輪系統最佳化運轉控制之裝置,其係用 以執行如如申請專利範圍第1項至第8項所述之方法, 其係包含: 一濃縮轉輪,用以吸附VOCs,且包含一吸附區、— 再生脫附區及一冷卻區; 一第一風車’係抽送VOCs廢氣流經該濃縮轉輪之 吸附區; 一第一熱交換器,係提供該濃縮轉輪之再生脫附區 脫附氣流之熱源以加熱該濃縮轉輪之再生脫附區; 23 201023964 一第二風車,用於抽送來自該第一熱交換器之熱 氣,以自該濃縮轉輪之脫附區脫附VOCs ; 一第二熱交換器,係用以加熱該經脫附之VOCs ; 一焚化爐,以燃燒淨化VOCs ;以及 一數據處理器,以監控相關運轉參數。 10、 一種用於濃縮轉輪系統最佳化運轉控制之裝置,其係用 以執行如申請專利範圍第1項至第8項所述之方法,其 係包含: 一濃縮轉輪,用以吸附VOCs,且包含一吸附區及® 一再生脫附區; 一第一風車,係抽送VOCs廢氣流經該濃縮轉輪之 吸附區; 一第一熱交換器,係提供該濃縮轉輪之再生脫附區 脫附氣流之熱源以加熱該濃縮轉輪之再生脫附區; 一第二風車,用於抽送來自該第一熱交換器之熱 氣,以自該濃縮轉輪之脫附區脫附VOCs ; q 一終端處理單元,以淨化VOCs ;以及 一數據處理器,以監控相關運轉參數。 11、 如申請專利範圍第10項所述之裝置,其中該終端處理 單元係進一步包含一冷凝器、一焚化爐及一觸媒氧化 器。 12、 如申請專利範圍第9項至第11項任一項所述之裝置, 其中該熱交換器可為間接加熱式或直接加熱式之熱交 換器。 24201023964 VII. Patent application scope: 1. A method for optimal operation control of a concentrated reel system, which provides a mathematical relationship (1) of each control factor in the concentrated reel system as follows: N y^{ Tc *)x (r)fl 473 J =K where: N = speed of the concentrated runner (RPH); t = thickness of the concentrated runner (m); r = concentration ratio; Td = desorption temperature (K = ° C+273.15); C=injection total hydrocarbon concentration value (ppm); Vp=adsorption inlet wind speed (m/s); and values a, b, c, d, c* and constant K are based on different concentration The wheel and the factory can be used to obtain the value after several operations. 2. The method of claim 1, wherein the desorption temperature is between 150 ° C and 300 ° C. 3. The method of claim 1, wherein the condensing wheel has a rotational speed of 1 to 10 RPH & 4. The method of claim 1, wherein the concentrating runner The runner type can be a rotary ring or a rotary table. 5. The method of claim 1, wherein the porous adsorbent coated on the concentration wheel is zeolite, activated carbon, silicone or active oxidizing. The method of any one of claims 1 to 5, wherein the method of performing the method is: (4) setting a removal efficiency such as a target value; (b) selecting a desorption temperature (Td) (c) Adjusting the rotational speed of the concentrated runner (N) based on the value of the population's total weight gas compound (C) and the selected adsorption inlet wind speed (Vp); - (d) Whether the medium removal efficiency (ηκ) is greater than or equal to Target value; (e) Adjust the amount of desorption air (ie, adjust the concentration ratio); and ® (f) the removal efficiency 〇 R) equals the target value. 7. The method of claim 6, wherein the removal efficiency is between 70% and 99.9%. 8. The method of claim 2, wherein the step (&) specifies one of the removal efficiency target values and (f) the removal efficiency is equal to the target value. b) Each of the factors in step (e) may be changed in its selection or adjustment order. And φ9, a device for optimizing operation control of a concentrating reel system, for performing the method according to the first to eighth aspects of the patent application, comprising: a concentrated reel, For adsorbing VOCs, and comprising an adsorption zone, a regeneration desorption zone and a cooling zone; a first windmill' is for pumping VOCs exhaust gas through the adsorption zone of the concentration runner; a first heat exchanger provides the The regeneration desorption zone of the concentration runner desorbs the heat source of the gas stream to heat the regeneration desorption zone of the concentration wheel; 23 201023964 a second windmill for pumping hot gas from the first heat exchanger to transfer from the concentration The desorption zone of the wheel desorbs VOCs; a second heat exchanger is used to heat the desorbed VOCs; an incinerator is used to purify the VOCs; and a data processor is used to monitor the relevant operating parameters. 10. A device for optimal operation control of a concentrated reel system for performing the method of claim 1 to claim 8, comprising: a concentrated reel for adsorption VOCs, and comprising an adsorption zone and a regeneration desorption zone; a first windmill for pumping VOCs exhaust gas through the adsorption zone of the concentration runner; a first heat exchanger for providing regeneration of the concentration runner a heat source for desorbing the gas stream to heat the regeneration desorption zone of the concentration wheel; a second windmill for pumping hot gas from the first heat exchanger to desorb VOCs from the desorption zone of the concentration wheel q A terminal processing unit to purify VOCs; and a data processor to monitor relevant operating parameters. 11. The apparatus of claim 10, wherein the terminal processing unit further comprises a condenser, an incinerator, and a catalyst oxidizer. 12. The apparatus of any one of clauses 9 to 11, wherein the heat exchanger is an indirect heated or directly heated heat exchanger. twenty four
TW97149892A 2008-12-19 2008-12-19 Optimal operation control method and apparatus applied to concentration wheel system TW201023964A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI680794B (en) * 2017-09-11 2020-01-01 大陸商中微惠創科技(上海)有限公司 VOC processing system, its controller and its operating method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI680794B (en) * 2017-09-11 2020-01-01 大陸商中微惠創科技(上海)有限公司 VOC processing system, its controller and its operating method

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