TW200930549A - A method for manufacturing an in-mold coated product and an apparatus for forming an in-mold coated product - Google Patents

Abstract

A mold for forming an in-mold coated product, having a rear face-forming mold (3), a front face-forming mold (1), and a coating film-forming mold (2), is used. With the rear face-forming mold holding a molded product (22), the rear face-forming mold and the front face-forming mold are opened. The front face-forming mold opposing to the rear face-forming mold is switched to the coating film-forming mold. The rear face-forming mold holding the molded product and the coating film-forming mold are closed. Then, a coating cavity (14) for coating the molded product with thermosetting coating material is formed between the molded product and the coating film-forming mold.

Description

200930549 IX. OBJECTS OF THE INVENTION: TECHNICAL FIELD The present invention relates to a method for manufacturing a mold-in-mold article and a device for forming a mold-in-mold 5, which are formed on a surface of a molded article and a cavity surface formed in a mold. After the thermosetting coating material is injected between them, the thermosetting coating material is cured in the mold, and the thermosetting coating material is adhered to and integrated with the surface of the molded article. [Prior Art; J. Background Art] A conventional mold for use in a mold for painting is disclosed in Japanese Patent Laid-Open Publication No. 2001-96573, which is incorporated herein by reference. A structure in which the mold direction is almost non-conical and parallel to the male and female portions, and the structure in which the male mold is extended and the cavity space is deeply formed inward (also referred to as a shared edge structure or a salivation structure) And the technique of injecting the coating material only after opening a small pitch and preventing the state from leaking out of the paint of the cavity (refer to FIG. 1 to FIG. 11D). Figure 11A

1st to 11th, 101 is a solid mold, 1〇2 is a movable mold disposed opposite to the fixed mold (8), and 103 is a coated material injection machine capable of injecting the covering material 105 between the fixed mold 101 and the movable mold 102, 104 It is a resin molded article. In the above-mentioned structure, there is a slight mismatch angle α in the common edge portion 106. When the field only opens a small distance, the common edge portion is 1〇. 6 5 200930549 The covering material 105 leaks from the cavity, and there is a problem that the coated article in the mold may cause burrs caused by the covering material 105. In the case where the side surface portion of the resin molded article is also modified, the angle of the sharpening of the side surface portion is increased, and when the mold is opened slightly (refer to Fig. 11B), it is compared with the top surface portion in the tree 5 grease. Since the distance between the molded article 104 and the mold 10 is smaller, the thickness of the covering member 105 on the side surface is thinner than that of the top surface (refer to the uc diagram and the ut diagram). Further, since the step of injecting the covering material 1〇5 after the resin molding is performed, there is a problem that the number of shots per unit time becomes small (the cycle time becomes long). SUMMARY OF THE INVENTION An object of the present invention is to provide a method for producing an in-mold coating product and an in-mold coating product forming apparatus which do not require opening of the respective mold faces without causing the above-mentioned problems. Means for Solving the Problem In order to achieve the above objectives, the present invention includes the following features. According to a first aspect of the present invention, a mold for manufacturing an in-mold coating product is provided by using an in-mold coating product including a mold for forming a surface, a mold for forming a surface, and a mold for forming a coating film, and the manufacturing method is the same. The thermosetting coating material is integrally coated on the molded article by the following steps: (1) The inner mold forming mold and the surface forming mold are closed, and a molding cavity for forming a molded product is formed in the inner surface to form a crucible. (11) The molding resin is filled in the molding cavity and cooled and solidified to form the molded article; (the state in which the mold is formed to maintain the molded article is described) The inner shape forming tool and the surface forming mold are opened; 200930549 (iv) forming a state in which the mold is opposed to the surface forming mold from the inside, and switching to a state in which the inner mold forming mold and the coating film forming mold are opposed to each other; v) retaining the mold forming mold of the molded article and the coating film forming mold to mold the mold, and forming a mold on the molded article and the coating film Forming a molding cavity for coating the molded article with a thermosetting coating; and (vi) injecting the thermosetting coating into the coating cavity and curing the same. According to the second aspect of the present invention The method for producing an in-mold coating product according to the first aspect, wherein the thermosetting coating material used in the step (vi) contains an acrylic-based oligomer or an unsaturated polyester resin, and Any one of the ethylenically unsaturated monomers copolymerized with the above components; and a one-liquid type coating of an organic peroxide initiator having a crosslinking efficiency of 8 or more. 15 20 According to the third aspect of the present invention' Provided is a method for producing an in-mold coating product according to the first or second aspect, wherein the thermosetting coating material is injected into the coating cavity and cured by the step (vi). The thickness of the coating layer is 10 to 100 m. According to the fourth aspect of the present invention, a method of manufacturing the in-mold coating product as in any of the first to third modes is provided, and from the foregoing Forming the mold and arranging the surface to form a mold When the mold is formed in a state in which the mold is formed to face the coating film forming mold, the rotatable movable disk to which the injection molding machine for forming the mold is fixed is rotated, and the surface facing the mold forming surface is formed. The mold is exchanged to form the coating film 7 200930549. According to the fifth aspect of the present invention, a method for manufacturing an in-mold coating of any of the first to third aspects of the first to third aspects is provided, and is formed from the inside. When the mold is in a state in which the mold is opposed to the surface forming mold, and the inside forming mold 5 is in a state opposed to the coating film forming mold, the injection molding machine in which the surface forming mold and the coating film forming mold are fixed may be used. The rotating movable disk is rotated, and the surface forming mold facing the inside forming mold is exchanged to form the coating film forming mold. According to a sixth aspect of the present invention, there is provided a method for producing a one-side coating in a mold according to the fourth aspect, comprising: not only the inner molding die includes a first inner molding die, and the second inner molding die And simultaneously performing the above steps (1) to (ii) using one of the two inner forming molds to form a mold and the surface forming mold, and using the other inner forming mold and the coating film to form the mold (v)~ (vi) Steps. According to a seventh aspect of the present invention, there is provided a method of producing an in-mold coating article according to any one of the first to third aspects, wherein a mold is formed in a state in which the mold is opposed to the surface forming mold. When the mold is formed in a state in which the mold is formed to face the coating film forming mold, the inner mold is disposed between the surface forming mold and the coating film forming mold, and the inner surface of the mold is formed with the surface and the inner surface. Each of them has a state in which the shape of the cavity can be formed, and the inside is formed into a mold exchange table by rotation to exchange the surface forming mold opposite to the inner mold forming mold to form the coating film forming mold. According to the eighth aspect of the present invention, any state as in the first to third modes is provided.

a method of manufacturing the in-mold coated article, wherein the state in which the mold is formed opposite to the surface forming mold is switched to the state in which the inner mold is opposed to the coating film forming mold, The inside forming mold is disposed between the surface forming mold and the coating film forming mold, and the inner forming mold has a state in which the surface thereof has a shape capable of forming a cavity, and the surface of the inner mold forming surface and the front surface are formed by rotation. The mold or the former "Gu Yu Lai has the opposite direction, that is, the former surface forming mold opposite to the front (four) surface forming mold is exchanged into the above-mentioned coating film forming mold. 10 15

According to a ninth aspect of the present invention, there is provided a method for producing an in-mold coated article according to any of the first to third aspects, wherein a mold is formed from the inside and a state of opposing the surface forming mold is provided. And switching to a shape in which the mold is formed in the opposite direction to the coating film forming mold, and the mold in the mold forming mold further includes a related tool, and the table (4) is molded: the mold is formed on the coating film. The above (4) forming a mold and the mold for closing the mold between the mold and the surface of the mold and the above-mentioned Tu Qing Cheng mold - _ silk, difficult to turn the above table _ money and the former lion secret with the aforementioned (4) Forming the money, the above-mentioned mold-making model, and the surface forming mold tooling: =: Sample: 'Providing the shame-like shape of the mold surface formed as shown in the first or second form and the above-mentioned: The top sheet and the surface of the aforementioned molded article are subjected to body formation. According to the ninth aspect of the present invention, there is provided a method for producing an inner coating of a mold 9 200930549 as described in the ninth aspect, wherein a green sheet is formed between the coating film forming mold and the inner mold. At the same time as the aforementioned thermosetting coating layer, the aforementioned forming is simultaneously integrated into the sheet. According to a twelfth aspect of the present invention, there is provided an in-mold coating product forming apparatus comprising: a mold for forming an in-mold coating comprising a mold for forming a surface, a mold for forming a surface, and a film forming mold; Forming and mold-opening the mold with the surface, and forming the mold and the coating film and opening the mold by moving the mold to the inside or forming the mold and the coating film Forming the movement of the mold, and forming a state in which the mold is described in the inner surface of the mold, and the state in which the mold is opposed is switched to a switching mechanism in which the mold forming surface and the coating film forming mold are opposed to each other; 15 injecting a resin into the inner surface to form a mold and the surface is formed. a resin injection machine for forming a molded article in the mold cavity formed; and a hardening paint is injected into the coating cavity formed by the mold and the coating film to be solidified in the mold cavity formed by the coating film The thermosetting coating layer-body is coated on the coating injection machine of the above-mentioned molded article. According to a thirteenth aspect of the present invention, there is provided a mold-shaped wire according to the twelfth aspect, wherein the inner forming mold includes an i-th inner forming mold and a second inner forming mold. 20 200930549 forming a rotating disk in which a mold and a second inner mold are formed therein, and rotating one of the first inner mold and the second inner mold to form a mold pair with the surface by rotation of the rotary disk The position of the direction 'at the same time, any one of the molds is located at a position opposite to the coating film forming mold, and the rotation of the rotating disk causes the second inner forming die to be exchanged with the second inner forming die, and Thereby, the surface forming mold is exchanged with the coating film forming mold with respect to each of the first inner mold forming mold and the second inner mold forming mold. According to a fifteenth aspect of the present invention, there is provided a method for producing a 10-coating article in a mold according to the first aspect, and in the step (10), the thermosetting coating material is injected into the coating cavity, and the injection is completed. The thermosetting coating material that has been injected is simultaneously pressurized, and then cured, whereby the thermosetting coating layer is integrally coated on the molded article. According to a sixteenth aspect of the present invention, there is provided a method of producing a coated article in a mold 15 as set forth in the fifteenth embodiment, wherein in the state in which the molded article has a tab portion and a product portion, the step (7) is formed. The thickness of the coating cavity on the surface of the tab portion is formed to be greater than or equal to the thickness of the coating cavity formed on the surface of the product portion. According to the πth aspect of the present invention, there is provided a coating product forming apparatus in a mold 20 according to the twelfth aspect, wherein the inner forming mold includes a compression block, is disposed around the compression block, and is opposite to the compression block. Moving the outer peripheral plate, after the thermosetting coating material is injected into the face cavity by the coating machine, the compression block is opposed to the compression block by the closing operation of the movable disk of the mold closing mechanism at the same time as the injection end The outer peripheral plate is 11 to 200930549; the coating film is formed on the mold side to move and the injected thermosetting coating is pressed, and the coating film forming mold is further disposed and temperature-adjustable to allow the coating to be applied. The temperature adjuster that does not allow the aforementioned thermosetting paint to harden. According to the eighteenth aspect of the present invention, the in-mold coating product forming device described in the πth aspect is provided, and the sliding sleeve between the compression block and the outer peripheral plate is formed along the aforementioned forming of the molded article. The cavity forming surface configuration of the aforementioned compression block of the cavity. According to a nineteenth aspect of the present invention, the present invention provides the in-mold coating product forming apparatus according to the seventeenth or eighteenth aspect, wherein the inner molding die includes the first inner molding die and the second inner molding die. According to a second aspect of the present invention, there is provided a method of producing an in-mold coated article according to the fifteenth or sixteenth aspect, and in the step (vi), the thermosetting-

The chemical coating material is injected into the coating cavity, and at the same time as the end of the injection, when the injected thermosetting coating is applied, the mold having the inside has a compression block and is disposed around the compression block and can be In the step (1), the inner shape <Q mold and the surface forming mold are closed, and the mold cavity for forming the molded product is formed in the inner surface to form a mold. Between the compressed block and the outer peripheral plate and the surface forming mold, in the step (4), the molded article is formed by the compressed block in which the mold is formed, and the inner mold and the surface are formed into a mold. In the above step (v), the inner mold forming mold holding the molded article and the coating film forming mold are closed, and the molded article for coating the molded product by the thermosetting paint 12 200930549 The hole is formed between the molded article and the outer peripheral plate of the coating, and in the step (5), the aforementioned coating is applied to the front side. At the same time, with respect to the foregoing: by the peripheral plate, the press is moved to the side of the coating film forming mold, and the above-mentioned hot-hardenable coating material is added and cured, thereby curing the thermosetting paint layer. Covered with the aforementioned molded article. According to the ninth state of the present invention, a mold as described in (4)

a method of manufacturing the inner coating αα, and in the step (vi), the sliding sleeve between the compressed block and the outer peripheral plate is along the mold of the compressed block forming the 10-shaped cavity of the molded article. The hole forming surface is disposed, whereby the thermosetting paint is injected into the coating cavity in a state where the molded article covers the sliding sleeve. According to a twelfth aspect of the present invention, there is provided a method of producing a cookware in a cooker according to the fifteenth or sixteenth aspect, wherein the mold is formed in a state in which the mold is opposed to the surface of the surface of the fifteenth surface, and the inside is switched to the inside. When the mold is formed in a state in which the mold is opposed to the coating film forming mold, the surface forming mold and the coating film forming mold are fixed, or the movable disk of the injection molding machine in which the mold is formed inside or the rotating disk mounted on the movable disk is rotated. And the mold forming mold which is opposed to the above-mentioned inner mold forming mold is switched into the above-mentioned coating film shape 20 into a mold. According to a thirteenth aspect of the present invention, there is provided a method of manufacturing a mold-in-mold article according to the fifteenth or sixteenth aspect, wherein the inner mold forming mold comprises a first inner mold and a second inner mold, and simultaneously The above (i) to (9) steps are formed using one of the two inner mold forming molds, and the aforementioned (V) ~ (using the other - forming the mold and the forming film to form the mold) (V) ~ ( Vi) Steps. According to a twenty-fourth aspect of the present invention, there is provided a method for producing a varnished inner coating according to the fifteenth or sixteenth aspect, wherein the thermosetting five-coating material is injected into the coating cavity in the step (10); Before the result of the curing, the thickness of the thermosetting coating layer is 10 to 300. Advantageous Effects of Invention The method for producing an in-mold coated article of the present invention and the in-mold coating product forming apparatus have the above-described excellent effects of the crucible 10 because the above-described steps are included. According to the first aspect and the second aspect of the present invention, when the mold is formed and the coating film is formed into a mold, the mold is completely free of voids and can be fixed with a strong mold closing force, so that even High-pressure injection thermosetting: Coatings, thermosetting coatings do not leak from the coating cavity, and burrs caused by the thermosetting coating layer do not occur in the mold 15 inner coating. Further, since the shape of the coating film forming mold can be arbitrarily set, the thermosetting coating layer can be formed on the side surface of the molded article in accordance with the predetermined film thickness. Further, according to the sixth aspect and the 23rd aspect of the present invention, the thermosetting paint layer can be formed on the surface of the other molded article 20 during the molding of one molded article, thereby increasing the unit time per unit time. The number of shots. Further, according to the second aspect of the present invention, the single-liquid type coating material is excellent in hardenability, adhesion, appearance, and weather resistance, and as a result, the curing time can be shortened, and the problem of adhesion, appearance, and weather resistance is considered. There is an effect that a resin molding material which is not suitable for the in-mold coating method can also be applied. Further, according to the third aspect of the present invention, there is an effect that a thermosetting resin coating film which is difficult to form a film such as two-color molding can be formed on the surface. BRIEF DESCRIPTION OF THE DRAWINGS These and other objects and features of the present invention will be apparent from the description of the appended claims. In the drawings, Fig. 1A is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold in the first embodiment of the present invention. ® Fig. 1B is a cross-sectional view showing the steps of a method of manufacturing the in-mold coated article according to the first embodiment of the present invention. Fig. 1C is a cross-sectional view showing the steps of the manufacturing method of the in-mold coated article according to the first embodiment of the present invention. Fig. 1D is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold article according to a first embodiment of the present invention. 15 Fig. 1E is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold article according to a first embodiment of the present invention. Fig. 1F is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold article according to a first embodiment of the present invention. Fig. 1G is a cross-sectional view showing the steps of a method of manufacturing the in-mold coating product according to the first embodiment of the present invention. Fig. 1H is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold article according to a first embodiment of the present invention. Fig. 2A is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. 15 200930549 Fig. 2B is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating of the first embodiment of the present invention. Fig. 2C is a plan view showing the steps of the method for producing a mold-in-mold according to the first embodiment of the present invention. 5 Fig. 2D is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating of the first embodiment of the present invention. Fig. 2E is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 2F is a cross-sectional view showing the steps of the method for producing the in-mold coating of the first embodiment of the present invention. Fig. 2G is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 2H is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. Fig. 3A is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 3B is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 3C is a cross-sectional view showing the steps of the method for producing the in-mold coating of the first embodiment of the present invention. Fig. 3D is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 3E is a plan view showing the steps of the method for producing a mold-in-mold according to the first embodiment of the present invention. 200930549 5 Fig. 3F is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating material according to the first embodiment of the present invention. Fig. 3G is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 3 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 4 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 4 is a cross-sectional view showing the steps of the method for producing the in-mold coating of the first embodiment of the present invention. Fig. 4C is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. Fig. 4D is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 4 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold coated article according to the first embodiment of the present invention. Fig. 4F is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. Fig. 4G is a cross-sectional view showing the steps of the method for producing the in-mold coating of the first embodiment of the present invention. Fig. 4 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 5 is a plan view showing the steps of the method for producing a mold-in-mold according to the first embodiment of the present invention. 17 200930549 Fig. 5B is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating material according to the first embodiment of the present invention. Fig. 5C is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. 5 is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating material according to the first embodiment of the present invention. Fig. 6A is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 6B is a cross-sectional view showing the steps of the method for producing the in-mold coating of the first embodiment of the present invention. Fig. 6C is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 6D is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 6E is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 6F is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. Fig. 6G is a cross-sectional view showing the steps of the method for producing the in-mold coating of the first embodiment of the present invention. Fig. 6H is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. Fig. 7A is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. 200930549 5 FIG. 7B is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating material according to the first embodiment of the present invention. Fig. 7C is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. Fig. 7D is a plan view showing the steps of the method for producing a mold-in-mold according to the first embodiment of the present invention. Fig. 7E is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 7F is a plan view showing the steps of the method for producing the in-mold coating of the first embodiment of the present invention. Fig. 7G is a plan view showing the steps of the method for producing a mold-in-mold according to the first embodiment of the present invention. Fig. 7H is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. Fig. 8 is a schematic view showing a manufacturing method of the in-mold coating material according to the first embodiment of the present invention and a coating injection machine used in the in-mold coating product forming apparatus. Fig. 9 is a cross-sectional view showing the molding of the in-mold coating according to the first embodiment of the present invention, in order to obtain the molding of the in-mold decorative article. Fig. 10 is a cross-sectional view showing the in-mold coating of the in-mold coated article obtained by the method for producing an in-mold coating according to the first embodiment of the present invention. Fig. 11A is a cross-sectional view showing the steps of the manufacturing method of the conventional in-mold coating product, 19 200930549. Fig. 11B is a cross-sectional view showing the steps of the above-described conventional method of manufacturing a coated article in a mold. Fig. 11C is a cross-sectional view showing the steps of the above-described conventional method of manufacturing a coated article in a mold. Fig. 11D is a cross-sectional view showing the steps of the above-described conventional method of manufacturing a coated article in a mold. Fig. 12A is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold article according to a second embodiment of the present invention. Fig. 12B is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 12C is a cross-sectional view showing the steps of the method for producing a mold-in-mold according to the second embodiment of the present invention. Fig. 12D is a cross-sectional view showing the steps of the method for producing the in-mold coating of the second embodiment of the present invention. Fig. 12E is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 12F is a plan view showing the steps of the method for producing a mold-in-mold according to the second embodiment of the present invention. 20 Fig. 12G is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Figure 13 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Figure 14 is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating of the second embodiment of the present invention in the second embodiment of the present invention. Fig. 15 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Figure 16 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 17 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 18 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 19 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Figure 20 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 21 is a cross-sectional view showing the steps of the method for producing the in-mold coating of the second embodiment of the present invention. Fig. 22 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 2 is a schematic view showing a method of manufacturing an in-mold coating product according to the second embodiment of the present invention and a coating material injection machine 20 used in the in-mold coating product forming apparatus. Fig. 24 is a cross-sectional view showing the in-mold coated article obtained by the method for producing a mold-in-mold according to the second embodiment of the present invention. Figure 25 is a cross-sectional view showing the steps of a conventional method of manufacturing a coated article in a mold. 21 200930549 Fig. 25B is a cross-sectional view showing the steps of the above-described conventional method of manufacturing a coated article in a mold. Fig. 25C is a cross-sectional view showing the steps of the above-described conventional method of manufacturing a coated article in a mold. 5 Fig. 25D is a cross-sectional view showing the steps of the above-described conventional method of manufacturing a coated article in a mold. Fig. 26 is a block diagram showing the relationship between the method of manufacturing the in-mold coating material according to the first and second embodiments of the present invention, the control device used in the in-mold coating product forming apparatus, and the respective driving devices. [Embodiment] BEST MODE FOR CARRYING OUT THE INVENTION Before the present invention is described, the same reference numerals are given to the same elements in the drawings. The embodiment of the present invention will be described in detail with reference to the drawings. (First embodiment) FIG. 1A to FIG. 1H are cross-sectional views showing the steps of a method of manufacturing a mold-in-applied product according to a first embodiment of the present invention. 2A to 2H are cross-sectional views showing the steps of the method of manufacturing the in-mold coated article according to the first embodiment of the present invention. 3A to 3H are cross-sectional views showing the steps of the method of manufacturing the in-mold coated article of the first embodiment of the present invention 20, respectively. 4A to 4H are cross-sectional views showing the steps of the method of manufacturing the in-mold coated article according to the first embodiment of the present invention. 5A to 5D are cross-sectional views showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. 6A to 6H are cross-sectional views showing the steps of the method of manufacturing the in-mold coated article of the first embodiment of the present invention 200930549, respectively. Fig. 7A to Fig. 7H are sectional views respectively showing the steps of the method of manufacturing the inner coated article of the first embodiment of the present invention. Fig. 8 is a schematic view showing a method of producing an in-mold coating product according to the first embodiment and a coating injection machine used in the in-mold coating product forming apparatus. Fig. 9 is a cross-sectional view showing the method of manufacturing the in-mold coating according to the first embodiment of the present invention, for the purpose of understanding the molding of the in-mold decorative article. The figure φ is a cross-section of the in-mold coating product obtained by the method for producing a mold in the mold according to the first embodiment of the present invention, which is obtained by painting the upper part of the mold. A mold is formed on the surface on which the surface of the molded article 22 is formed, 2 is a coating film forming mold for forming a coating film of the molded article 22, 3 is a mold for forming the inside of the molded article 22, and 4 is a third inside. Forming the mold, 5 is the second inner mold, 6 is the mold for closing, u is the forming cavity, 15 12 is the first forming cavity, U is the second forming cavity, 14 is the coating cavity, 15 φ For the first coating cavity, 16 is the second coating cavity, 21 is the thermosetting coating layer, 22 is the molded article, 23 is the first molded article, 24 is the second molded article, and 25 is the mold coating. Product, 26 is the first in-mold coating, 27 is the second in-mold coating, 28 is the in-mold coating, 31 is the fixed disc, 32 is the movable disc, 33 is the 2〇 movable disc rotating shaft, 34 For the rotating disc, 41 is the paint injection machine, 42 is the paint injection unit, 43 is the paint tank, 71 is formed into a film at the same time, 72 is a base sheet, 73 is Mold layer, the gettering layer 74 is stripped, the upper layer 75 is painted, the anchor layer 76, adhesive layer 77, layer 78 is a replication. First, the manufacturing method of the in-mold coating product according to the first embodiment of the present invention will be described with reference to a cross-sectional description of a mold for molding a mold in a mold used in the production method. In the in-mold coating product forming mold used in the method for producing a mold-in-mold article according to the first embodiment of the present invention, the surface forming mold 1 and the coating film forming mold 2 are formed on the inside. The mold 3 is formed inside to form the shape of the inside of the molded article 22. The surface forming mold 丨 is used to form the surface shape of the molded article 22. The coating film forming mold 2 is used to form the thermosetting coating layer 21 on the surface of the molded article 22. In the inside of the drawing, the mold 3 is formed, and the surface is opened. The individual irregularities of the mold 1 and the coating film forming mold 2 are merely examples, and the shape is not limited to only ◎ 10 . First, the mold 3 and the surface forming mold W are closed by using the mold closing mechanism 121 or 123 of the injection molding machine 124, and the forming cavity 11 for forming the * molded article 22 is formed therein to form the mold 3 and the surface. Forming: between the molds 1 (refer to the first. At this time, when the mold 3 is formed as a fixed mold 15 and the surface forming mold 1 is a movable mold, the mold is formed by the surface of the injection molding machine 124 connected to the surface forming mold 1. The mold closing mechanism 121 can be used to move the surface forming mold 1. Conversely, the Tuqingcheng mold 2 is a mold, and when the mold 3 is formed as a movable mold, the shots are formed by joining the insides to form #~, 3 The inside of the forming machine 124 forms a die-cutting machine 20 structure 123 for moving the mold 3 to be moved therein. The person, the injection molding machine 123 fills the molding resin into the molding cavity 11, and cools and solidifies it. In the meantime, the molded article 22 can be obtained (see Fig. 1). At this time, a sheet 71 (see Fig. 9) is formed between the surface forming mold 1 and the inside forming mold 3, and the molded article 22 is formed. Simultaneously 24 200930549 The time-lapse forming sheet 71 is formed on the surface of the molded article 22, whereby the molded article 22 can be formed while the upper edge sheet 71 is formed on the surface of the molded article 22. * In the state in which the mold 3 is formed to hold the molded article 22, the mold is formed inside and the mold is formed by using the closing mechanism 121 or 123 of the injection molding machine 124 (refer to the ic diagram). The surface forming mold 1 can be separated from the molded product 22. At this time, the mold 3 is formed as a fixed mold, and when the surface forming mold 1 is a movable mold, the surface forming mold is formed by forming a mold closing mechanism 121 which is movable on the surface. i. The surface forming 1 cooker 1 is a fixed mold, and when the mold 3 is formed as a movable mold, the mold 3 is formed by the mold opening mechanism 123 which is movable inside, and the mold 3 is moved inside. In the meantime, the mold 3 is formed in order to hold the molded product 5, for example, the ejector pin is drilled into the molded article 22, and the molded article 22 1 is placed in a state in which the injection pin is hugged, or the molded article 22 is formed into a claw. When the molded article 22 is pushed out without causing the tilt pin to be pushed, the molded product 22 is not separated from the inner mold forming mold 3. Next, an injection molding machine 124 which will be described later is used. Rotating the movable disk 32 and the rotating disk rotating device 122R to rotate or move the mold 3 on the inside, and exchange the surface forming mold 1 with the mold 3 to form a coating film 幵> into the mold 2 (refer to Qing). As a result, the exchanged lacquering mold 2 replaces the surface forming mold 丨 and is placed at a position opposed to the mold 3 formed therein. In other words, the mold 3 is formed in a state in which the mold 3 is opposed to the surface forming mold, and the mold 3 is placed in a state in which the mold 3 and the coating film forming mold 2 are opposed to each other. An example of a mold changer 25 200930549 configuration (switching mechanism) can be realized by the rotation of the movable disk 32 and the rotary disk rotating device. Next, the mold 3 and the coating film forming mold 2 are closed by using the mold closing mechanism 123 or 122 of the injection molding machine 124, and the coating mold for coating the heat-cured European paint into the product 22 is used. The cavity 14 is formed on the surface 5 of the molded article 22 and the inner surface of the coating film forming mold 2 (refer to _). At this time, when the mold 3 is formed as a fixed mold, and the coating film forming mold 2 is a movable mold, the mold is attached to the coating film of the injection molding machine 124 of the coating film forming mold 2 to form a mold closing mechanism 122. The film forming mold 2 moves. On the other hand, when the coating film forming mold 2 is a fixed mold and the mold 3 is formed as a movable mold, the mold opening mechanism 123 is formed by the inner surface of the inner surface of the inner surface of the inner surface of the inner surface of the inner surface of the inner surface. Next, a thermosetting coating material is injected into the coating cavity 14 from the thermosetting coating material injection device 125 and cured, and the thermosetting coating layer 21 is coated on the surface of the molded article 22, and The in-mold coating product 25 is manufactured (refer to Fig. 15 11?). At this time, the sheet 71 is formed between the coating film forming mold 2 and the inner forming mold 3, and the sheet 71 is formed, and the sheet 71 is formed while forming the thermosetting coating layer 21, whereby the sheet 71 can be formed. The in-mold coating has been painted © the upper part of the mold, that is, the in-mold coating. Next, in a state in which the mold 3 is held in the mold 3, and the mold closing mechanism 123 or 123 of the injection molding machine 124 is used, the mold 3 and the surface forming mold 1 are opened (see Fig. 1G). As a result, the coating film forming mold 2 can be separated from the in-mold coating material 25. Next, the rotary mold 32 and the rotary disk rotating device 122R, which will be described later in the injection molding machine 124, are used to rotate or move the mold 3, which is to be used in conjunction with the ?1φ shape (4). The mold 2 is exchanged to form a surface changer 1 (refer to the first drawing). As a result, the exchanged surface forming mold 1 is placed in a position opposed to the inside forming mold 3 instead of the coating film forming mold 2. Thereafter, the steps of FIG. 1A are continued. 5 ❹ 10 15 ❹ 20 In this way, the in-mold coating product 25 can be manufactured by performing a series of steps of the first to the mth drawings. When the shock absorber 25 in the mold is successively manufactured, the steps of 1A to 1H are sequentially repeated as long as the first step is continued. A toggle-type closing mechanism or a direct-pressing closing mechanism of the injection molding machine 124 can be used as the closing mechanism ΐ2, 122, 123 for opening and closing the mold. In the drawings of the present invention, for the sake of simplicity and ease of understanding, the mold closing mechanism 丨21 which can be used for forming the mold, the mold closing mechanism 123 for forming the mold, and the movable mechanism of the coating mold can be used. 122 is only described in the "partial drawing" and is not shown in the other figures. Further, the thermosetting paint injection device 125 and the rotary disk rotating device and the mold temperature adjusting devices (1), 111, and 112 which will be described later are also simplified and easy to understand 'only described in the partial pattern'. In the other @中图图>(> The coating film forming mold 2 is different in shape from the surface forming mold 1, and is designed such that the coating film forming mold 2 (particularly the portion facing the mold 3 inside) has an outer shape, for example. When the surface forming mold 1 is large (for example, when the surface for forming the cavity is concave °p), the size or depth of the concave portion is set to be large, or when the surface for forming the molding cavity is a convex portion, the convex portion is formed. The size is set to be small or the height is set to be large, 27 200930549, and a portion which is not in contact with the molded article 22 can be formed. This portion which is not in contact with the molded article 22 corresponds to the coating cavity 14. The coating cavity 14 is applied. The shape is appropriately set in accordance with the desired type (for example, shape, etc.) or thickness of the thermosetting coating layer 21. The coating cavity 14 may cover the entire surface of the molded article 22, and may be formed only in the molded article 22. One part of the surface. Again, as will be described later In the sample state, a compression mechanism is provided for the product portion of the cavity 14 of the coating film forming mold 2, no flaws are formed on the surface of the thermosetting paint layer 21, and the coating film 2 can be formed. The fine shape of the surface of the cavity 14 is surely rewritten to the thermosetting coating layer 21. q 10 Further, the mold material forming the mold 3, the surface forming mold 1 and the coating film forming mold 2 may be the same material (for example, metal). It is also possible to use a different material (for example, a metal). ' Further, the injection port of the molding resin may be disposed on the surface of the mold to form a side of the mold - (refer to FIGS. 1A to 1c). Further, the mold 3 may be formed on the inside. (Refer to Fig. 2A to Fig. 2H.) The second to the second embodiment are modified according to the first embodiment, and only the injection point of the molding resin is provided on the surface of the surface forming mold, and the first point is 1A~ Since the steps 1H to 211 are different from the steps ◎1A to 1H, respectively, the description will be omitted. Further, the injection position of the thermosetting paint can be set in the center of the painting cavity 14. 2〇 (refer to Figure 1E and _), this situation In the shape, the trace of the nozzle pin remains. Therefore, when the appearance of the no-nozzle pin mark is required, the lock hole or the mark mounting position or the like can be used or the temporary product portion can be placed on the outer side of the product to be placed therein. Further, both the surface forming mold 1 and the coating film forming mold 2 can be used as the mirror 28 200930549 surface mold 'or both sides of the mold. χ, the mold 3 can be formed inside to form a protrusion, etc. 5 ❹ 10 15 Φ 20 The mold temperature of the mold 3 and the surface of the mold 1 is appropriately set by the mold temperature adjusting machine 113. The mold temperature is adjusted by the mold temperature adjusting machine 112 to form the mold temperature of the mold 2. The medium for forming the mold 3, the surface forming mold 丨, and the coating film forming mold 2 by means of the mold temperature adjusting machine 、3, 111 and 112 for heat exchange may be water or oil adjusted by the mold temperature. In the machines 113 and 111, the temperature of each of the molds 3 and the surface of the mold is set according to the material of the molding resin, and the temperature is set to a temperature suitable for normal formation, and the coating film is applied according to the material of the thermosetting coating material. The mold temperature of the mold 2 is set to a temperature at which the thermosetting paint hardens in a few seconds. Further, in order to cause a malfunction in the mold operation, the mold temperature of the coating film forming mold 2 can be set to be the same as the mold temperature of the inner mold forming mold 3 and the surface forming mold mold. Hereinafter, a method of exchanging the surface forming mold 1 opposed to the inside forming mold 3 into the coating film forming mold 2 will be described by way of a few examples. First, in the method of exchanging the surface forming mold 1 opposed to the inside forming mold 3 into the coating film forming mold 2, there is a rotary disk rotating device using the injection molding machine 124 to which the movable rotating shaft 33 of the movable plate 32 is coupled. (For example, the motor) 122R, a method of rotating the movable disk of the injection molding machine in which the mold 3 is formed is fixed (see FIG. 3D and FIG. 3H). In other words, as shown in the third embodiment, the first inner mold 4 and the second inner mold 5 are fixed to the disk-shaped rotary movable disk 32 of the injection molding machine 124. The surface forming mold 29 200930549 1 and the coating film forming mold 2 are fixed to the fixed tray of the injection molding machine i24, and the center of the movable tray 32 is rotated to suppress the rotation of the rotary disk rotating device 122R. In this way, by rotating the rotating disk: the driving of the 122R, the movable disk 32 is rotated around the central axis, and the first inner forming mold 4 and the second inner forming mold 5 are alternately placed on the mth surface to form the mold 4. The position of the mold 5 is formed in the second inner portion, and the mold can be formed by changing the surface of the mold to be formed on the surface of the mold. '

Specifically, in the step shown in FIG. 3A, the first inner forming mold 4 10 is placed on the upper side of the movable platen 32, and is opposed to the mold 1 fixed on the surface of the fixed disk 31, and is implemented in the same manner as in FIG. A step of. The second inner forming mold 5 is placed on the lower side of the movable platen 32 to face the coating film forming mold 2 fixed to the fixed disk 31, and the same steps as in the first embodiment are carried out. In other words, the first and second surface forming molds 4 and the surface forming mold 1 are closed on the upper side of the movable disk 32 by using, for example, the injection molding machine 124 closing mechanism 123 or 121, and the first molding for forming the molded article 22 is formed. The cavity 12 is formed between the first inner mold forming mold 4 and the surface forming mold 1. On the lower side of the movable disk 32, for example, the mold closing mechanism 123 or 122 of the injection molding machine 124 is used, and the second inner mold 5 for holding the second molded article 24 and the coating film forming mold 2 are closed. The second coating cavity 16 for coating the second molded article 24 with the thermosetting 20-coating material is formed between the surface of the second molded article 24 and the inner surface of the coating film forming mold 2. Thus, in the step of Fig. 3A, the steps 1A and 1E are simultaneously performed. Moreover, the above description is easy to understand, and it is described that the mold closing mechanism 123 or 121 and the mold closing mechanism 123 or 122 are respectively used on the upper side and the lower side of the movable disk 32. However, it is actually possible to use the movable disk 32 connected to the 30303030. The mold closing mechanism 123, or any one of the mold closing mechanisms (2) or 122 attached to the fixed tray 3i. When the fixed disk 31 is moved and the mold is closed, the movable disk 32 is made to perform only the rotation actor who changes the position of the second inner mold forming mold 4 and the second inner mold forming mold 5. In addition, the following description is also the same. 5 ❹ 10 15 ❷ 20 Next, in the third drawing, the mold 1 is formed on the upper surface of the upper inner surface forming mold 4 and the fixed disk 31 on the upper side of the movable disk 32, and the same steps as in the first drawing can be performed. The second inner surface on the lower side of the movable disk 32 forms the coating film forming mold 2 on the lower side of the mold 5 and the fixed disk 31, and the same steps as in the first F-figure can be performed. In other words, the molding resin is filled in the first molding cavity 12 by the injection molding machine 124 on the upper side of the movable disk 32, and the second molded article 23 can be obtained by cooling and solidifying. Further, the thermosetting paint is injected into the second coating cavity 16 from the thermosetting coating material injection device on the upper side of the movable platen 32, whereby the surface of the second molded article 24 can be integrally covered with the thermosetting coating layer 21, Further, the second in-mold coating product 27 can be manufactured. Therefore, in the third step, the steps of the 16th step and the 11th step are simultaneously performed. Next, in the step shown in Fig. 3C, a mold is formed on the upper surface of the mold 4 and the upper surface of the fixed disk 31 in the i-th inner side of the movable disk 32, and the same steps as in Fig. 1C are carried out. The mold 2 is formed on the upper side of the lower side of the movable disk 32 by the coating film forming mold 2 on the upper side of the fixed disk 31, and the same steps as in the igth diagram are performed. In other words, in the state in which the molded article 4 is held by the first inner mold 4 on the upper side of the movable disk 32, the first inner mold 4 and the surface forming mold are opened using, for example, the mold closing mechanism 123 or 121 of the injection molding machine 124. mold. In the state in which the molded article 4 is held by the first inner mold 4 on the lower side of the movable platen 32, the mold 5 and the coating film are formed in the second 31 2009 30549 by using, for example, the mold closing mechanism 123 or 121 of the injection molding machine 124. The mold 2 is formed to open the mold. Therefore, in the step of FIG. 3C, the steps of FIG. 1C and the steps of FIG. 1G are simultaneously performed. Next, in the step shown in Fig. 3D, the mold 1 is formed on the upper surface of the mold 1 and the upper surface of the fixed disk 31 on the upper side of the movable disk 32, and the same steps as in Fig. 1D are performed. The second inner surface of the lower side of the movable disk 32 forms the mold 5 and the coating film on the lower side of the fixed disk 31 forms the mold 2, and the same steps as in the first embodiment are performed. That is, the 'rotating movable disk 32 is rotated by the rotary disk rotating device 122R of the injection molding machine 124, and the second inner forming mold 5 is formed on the upper side of the movable platen 32 to face the surface forming mold ,, and under the movable disk 32. The side structure 10 is formed so that the first inner mold 4 and the coating film forming mold 2 face each other, and the first inner mold 4 and the second inner mold 5 are exchangeable. In other words, the surface forming mold 1 opposed to the first inner forming mold 4 is exchanged to form the coating film forming mold 2, and the coating forming mold 2 opposed to the second inner forming mold 5 is exchanged to form the surface forming mold 1. Therefore, in the step of the 3D diagram, the steps of the 1D 15th diagram and the 1Hth diagram are simultaneously performed. Then, in the step shown in Fig. 3E, the mold 1 is formed on the upper surface of the mold 2 and the upper surface of the fixed disk 31 in the second inner surface of the movable disk 32, and the same steps as in Fig. 1A are carried out. The first inner mold forming mold 4 on the lower side of the movable platen 32 forms a mold 2 with the coating film on the lower side of the fixed disk 31, and the same steps as in Fig. 1E are performed. In other words, on the upper side of the movable platen 32, the second inner mold 5 and the surface forming mold 1 are closed by using, for example, the mold closing mechanism 123 or 121 of the injection molding machine 124, and the second molded article 24 is formed. 2 The molding cavity 13 is formed between the cooker 5 and the surface forming mold 1 in the second inner surface. Further, on the lower side of the movable platen 32, for example, the mold closing mechanism 123 or 122 of the injection molding machine 124 is used, and 200930549, the first inner mold 4 and the coating film forming mold 2 holding the first molded article 23 are closed, and The first coating cavity 15 for coating the first molded article 23 with a thermosetting paint is formed between the surface of the first molded article 23 and the inner surface of the coating film forming mold 2. In this way, in the step of FIG. 3E, the steps of step 5 and step 1E of the FIG. Next, in the step shown in Fig. 3F, the mold 1 is formed on the upper surface of the mold 2 and the upper surface of the fixed disk 31 on the upper side of the movable disk 32, and the same steps as in Fig. 1B are carried out. The first inner mold forming mold 4 on the lower side of the movable disk 32 forms a mold 2 with the coating film on the lower side of the fixed disk 31, and the same steps as in the figure of Fig. 10 are carried out. In other words, the molding resin 124 is filled in the second molding cavity 13 by the injection molding machine 124 on the upper side of the movable disk 32, and is cooled and solidified to obtain the second molded article 24. Further, on the lower side of the movable platen 32, the thermosetting paint is injected into the second coating die hole 5 from the thermosetting paint injection device 125, and is solidified so that the surface of the first molded article 23 is integrally covered with heat. The curable coating layer 21 can be used to manufacture the first in-mold coating article 26. In this way, the steps of Fig. 1B and the steps of Fig. 1F are simultaneously performed in the step of Fig. 3F. Next, in the step shown in Fig. 3G, the mold 1 is formed on the upper surface of the mold 2 and the upper surface of the fixed disk 31 on the upper side of the movable disk 32, and the same steps as in Fig. 1C are carried out. The mold 1 formed on the lower surface of the lower surface of the movable disk 32 and the coating film on the lower side of the fixed disk 31 forms the mold 2, and the same steps as in the first drawing are performed. In other words, in the state in which the second molded article 24 is held by the second inner forming mold 5 on the upper side of the movable platen 32, the second inner forming die 5 and the surface forming die are formed by, for example, the mold closing mechanism 123 or 121 of the injection molding machine 124. Open the mold. Further, on the lower side of the movable platen 32, the first inner mold is formed by the mold 4 in the second inner side, and the first inner side is held by the mold closing mechanism 123 or 122 of the injection molding machine 124, for example. The mold 4 is formed and the coating film forming mold 2 is opened. In this way, in the step of FIG. 3G, the steps of the first step (the step of the figure and the step of the first step G) are simultaneously performed. 5 Next, in the step shown in the figure 3H, the second inside of the upper side of the movable disk 32 is formed. The mold 5 is formed with a mold 与 on the upper surface of the fixed disk 31, and the same steps as in the first DD are performed. The inside of the second side of the lower surface of the movable disk 32 forms a coating film 2 for forming the mold 4 and the lower side of the fixed disk 31, The same steps as in the first embodiment are carried out. That is, the rotary movable disk 32 is rotated by the rotation of the injection molding machine 124 by the rotation device 122R, and the first inner mold is formed on the upper side of the movable disk 32 to form the mold 4 and the surface forming mold. 1 is opposed, and the second inner forming mold 5 and the coating film forming mold 2 are formed on the lower side of the movable platen 32, and the second inner forming mold 5 and the first inner forming mold 4 are exchangeable. In other words, In the second inner forming mold 5, the surface forming mold is exchanged to form the coating film forming mold 2, and the coating film forming mold 2 opposed to the first inner forming mold 4 is exchanged to form the surface forming mold 1. Therefore, Step 3H, and implement the 1D map at the same time Steps of the first and second figures. In this way, as in the steps of FIGS. 3A to 3H, the thermosetting coating layer 2〇21 can be formed on the surface of other molded articles during the formation of one molded article. The effect of increasing the number of shots per unit time is increased. Further, there is a method of manufacturing the in-mold coating which can replace the steps of FIGS. 3A to 3H described above, that is, instead of fixing the molds 4 and 5 formed therein. The movable disk 32 of the molding machine 124 is injected, and the surface forming die 丨 and the coating film forming die 2 are fixed to the movable disk 32 of the injection molding machine 124, and the movable 200930549 disk 32 is rotated, and the surface is formed with respect to the inside. The method of exchanging the mold 1 and the coating film forming mold 2 is formed (refer to FIG. 4D's FIG. 4H). Further, the detailed operations in the respective steps are the same as those described above, and therefore only the corresponding steps are omitted, and the detailed description thereof is omitted. 5. Specifically, in the step shown in FIG. 4A, the surface forming mold 1 is placed on the upper side of the movable plate 32, and is opposed to the mold 4 which is fixed to the inside of the fixed plate 3, and Implementation and In the same step as in Fig. 1A, the coating film forming fixture 2 is placed at the lower side of the movable disk 32, and the mold 5 is formed opposite to the inside of the fixed disk 31 > Steps 10 In the step of Fig. 4B, the steps of Fig. 1A and the steps of Fig. 1 are simultaneously performed. Next, in the step shown in Fig. 4B, the mold 1 is formed on the surface on the upper side of the movable disk 32. The mold 4 is formed in the first inner surface on the upper side of the fixed disk 31, and the same steps as those in Fig. 1B are performed. The coating film forming mold 2 15 on the lower side of the movable disk 32 and the second inner surface on the lower side of the fixed disk 31 form the mold 5 Implement the same steps as in Figure 11. In the step of FIG. 4B, the steps of FIG. 1B are simultaneously performed and

I Steps in Figure 1F. Then, in the step shown in Fig. 4C, the first inner mold 4 is formed on the upper surface of the movable disk 32 on the upper surface of the mold 1 and the fixed disk 31, and the same steps as in Fig. 1C are performed. The coating film forming mold 2 on the lower side of the movable disk 32 forms the mold 5 on the second inner surface on the lower side of the fixed disk 31, and the same steps as in the igth diagram are performed. The steps of Fig. 1C and the steps of Fig. 1G are carried out simultaneously in the step '' of the Fig. 4C'. Next, in the step shown in the figure, the table 35 200930549 on the upper side of the movable plate 32 and the lion 1 in the same figure as the first DD form the mold 4, and the disk is fixed. Forming the mold 5 in the second inner side of the lower side of the same side, and implementing the second step. That is, the rotary movable disk 32 is formed by the injection molding machine (3), and the mold 4 is formed, and the mold 4 is formed in the opposite direction, and the surface is formed on the lower side of the movable disk 32 to form the mold 1 and the second inside. The mold 5 is formed to face each other, and the surface shape is interchangeable with the coating film forming mold 2. In other words, the mold is formed by the formation of the mold, the surface of the ten-way, and the mold 1 are exchanged into a coating film forming mold 2, and the coating film forming mold 2 is formed by the formation of the mold 2 and the second inner forming mold 5 to form a surface. Mold 1. Therefore, in the step of Fig. 4D, the steps of Fig. 1D and Fig. 1H are simultaneously performed. In the step shown in Fig. 4E, the mold 4 is formed on the upper side of the coating film forming mold 2 on the upper side of the movable disk 32 and the upper side of the fixed disk 31, and the same steps as in Fig. 1A are carried out. The second inner mold 5 is formed on the lower surface of the movable disk 32 on the lower surface of the mold 1 and the fixed disk 31, and the same steps as in the first embodiment are carried out. In the step of Fig. 4E, the steps of Fig. 1A and the steps of Fig. 1E are simultaneously performed. Next, in the step shown in Fig. 4F, the mold 2 is formed on the upper side of the movable film 32, and the mold 2 is formed on the upper side of the upper side of the fixed disk 31, and the same steps as in Fig. 1B are carried out. The mold 2 is formed on the surface on the lower surface side of the movable disk 32, and the second inner mold 5 is formed on the lower side of the fixed disk 31, and the same steps as in Fig. 11 are performed. In the steps of this supplementary diagram, the steps of Fig. 1B and the steps of Fig. 1F are simultaneously performed. 36 200930549 Next, in the step shown in Fig. 4G, the mold 4 is formed on the upper side of the coating film forming mold 2 on the upper side of the movable disk 32 and the first inner surface of the fixed disk 31, and the same steps as in Fig. 1C are carried out. The mold 1 is formed on the surface on the lower side of the movable disk 32, and the second inner mold 5 is formed on the lower side of the fixed disk 31, and the same steps as in the above-described drawings are carried out. In the step of Fig. 4G, the steps of the lc diagram and the step of the 1G diagram are simultaneously performed. Next, in the step shown in Fig. 4H, the coating film on the upper side of the movable disk 32 forms the first inner mold 4 on the upper side of the mold 2 and the fixed disk 31, and the same steps as in the first DD are performed. The surface on the lower side of the movable disk 32 forms a mold 2 and a second inner mold 5 on the lower side of the fixed disk 31, and the same steps as in the above-described drawings are carried out. In other words, the rotary movable disk 32 is rotated by the rotary disk rotating device 122R of the injection molding machine 124, and the surface forming mold 1 is formed on the upper side of the movable disk 32 so as to face the first inner mold 4 and on the lower side of the movable disk 32. The coating film forming mold 2 is opposed to the second inner forming mold 5, and the surface forming mold 8 is exchanged with the coating forming mold 2. In other words, it will form a mold with the i-th inside.

The coating film forming mold 2 is exchanged to form a mold 丨, and the surface forming mold 1 opposed to the second inner forming mold 5 is exchanged to form a coating film forming mold 2. Therefore, in the step of Fig. 4h, the steps of Fig. 1D and the steps of Fig. 1H are simultaneously performed. 20 Here, in the above several examples, the mold 3 is formed in two, but it may be *1 horses or two or more. When two or more lining molds 3 are used, 'the mold can be formed simultaneously with the surface forming mold 1 and the mold cavity 11 for forming the molded product can be formed at the same time. Between 1st, a step of forming a molded article 22 by filling a molding resin in a molding cavity 11 in 37 200930549 and cooling and solidifying it (refer to a mold on the upper side of each movable disk 32 in FIGS. 3A and 3B), and The other mold forming mold for holding the other molded product and the coating film forming mold are closed, and the coating cavity 14 for forming the thermosetting paint coating molded article is formed into the mold 2 and the coating film forming mold 2 The step of injecting and curing the thermosetting coating into the coating cavity 14 (refer to the mold on the lower side of each movable disk 32 in FIGS. 3A and 3B). By the structures shown in FIGS. 3A to 3H and 4A to 4H, the heat 0 10 curable coating layer 21 can be formed on the surface of the other molded article during the formation of one molded article, so that it can be increased. The number of shots per unit time. When two or more inner molds are used, the shapes of the molds formed inside each may be the same, for example, whether or not the members for forming the cavity portions of the molded article have different shapes. Further, a plurality of molds can be formed as a body. 15 or 'As shown in Fig. 5A to Fig. 5D, the mold 3 can be formed between the surface forming mold i and the coating lining 2, and the surface and the inside thereof respectively have a shape capable of forming a cavity. . The inner surface of the shape is formed into a mold 3, and a rotary disk 34 which is rotatably driven by the rotary disk rotating device 122R of the injection molding machine 124 is formed. According to such a configuration, the rotary disk 34 is rotated by (10) degrees by rotating the device body, whereby the inner surface of the mold 3 can be formed with respect to the rotary surface, and the mold can be formed by changing the surface. The film forming mold 2' can form a mold 3 by inserting a plurality of inner molds 3 with respect to the surface tool 1 and the coating film forming mold 2 (refer to FIG. 5D) / 4, step 5A. The surface (the right (four) side of the mold 3 formed in the inside of the 5th and 8th drawings of 200930549) is opposite to the surface of the fixed plate. And ride with the first Α__ step. The inside of the mold 3 is formed (the surface on the left side of the mold 3 is formed on the inside of the fifth drawing), and the coating film which is fixed to the movable disk 32 is placed oppositely to form a mold, and the same steps as in the fifth step are performed. The step of the fifth drawing is performed simultaneously with the steps of the first drawing and the steps of the first drawing. ❹ 10 15 m 20 Next, in the step shown in Fig. 5, the surface of the mold 3 is formed (the surface on the right side of the mold 3 is formed on the inside of the fifth drawing) and the surface of the fixed (four) is formed = 1 'and the Side (four). The inside is formed inside (the surface on the left side of the mold 3 is formed in the inside of the fifth figure) = the mold 2, the _ is performed and the __ step. This detail is a step of the first step and the first step. Next, in the step shown in Fig. 5C, the surface of the mold 3 (the surface on the right side of the mold 3 is formed) and the surface of the disk 31 are formed to be the same as the step lc_. The inside of the inside of the mold 3 is formed to form the surface on the left side of the mold 3, and the coating film of the fixed disk = the mold 2' is simultaneously subjected to the same steps as in the first G-figure. The 'step' of the πth figure simultaneously performs the steps of the first C-figure and the first g-figure. Next, in the step shown in the fifth step, the phantom surface (the right drain surface of the first mold 3) is formed on the surface of the fixed disk 31 (the same step as the first drawing). The mold 3 is formed therein. Inside, the surface on the left side of the mold 1 in which the mold 3 is formed) and the coating film of the fixed disk 31 are formed, and the same steps as in the figure (4) are simultaneously performed. The step of the πth diagram simultaneously performs the steps of the ic diagram and the step of the 1G diagram. 39 200930549 In the modification of the A to 5D, the shapes of the respective cavities may be the same or may be different. Further, in order to rotate the mold 3 formed therein, the rotary disk 34 which is formed in the support by forming the mold 3 and rotated in the horizontal plane by the rotary disk rotating device 122R may be used (that is, in this case, the first to fifth figures are made) 5 can be seen from the floor plan). In the method of the modification of Figs. A to 5D, the thermosetting coating layer 21 can be formed on the surface of another molded article while forming one molded article, so that the number of shots per unit time can be increased.

Alternatively, it may be constructed such that the inner forming mold 3 is disposed between the surface forming mold 10 1 and the coating film forming mold 2, and the inner forming mold 3 has only a surface having a shape capable of forming a cavity. The inner forming mold 3 having such a shape is supported by a rotary table 34 which is rotatably driven by a rotary disk rotating device 122R of the injection molding machine 124. According to such a configuration, the rotary disk 34 is rotated by 180 degrees by the rotation of the rotary disk, whereby the surface of the mold 3 is formed to face the surface of the mold 15 or the coating film forming mold 2, and is formed opposite to the inside. mold

A method of forming a mold with a surface of 3 and an exchangeable surface forming a mold 丨 and a coating film (refer to Fig. 6D, 6H圊). The steps shown in Figs. 6A to 6C, in which the surface of the mold 3 is formed (the surface on the right side of the mold 3 is formed in the inside of the 6A to 6C drawings), and the surface of the fixed disk 31 is fixed to the Shore 30. Forming the mold 1 and performing the steps shown in the 6D diagram of the same as the 1A to 疋AA, and the 1C, and forming the surface of the mold 3 (the inner mold 3 is formed) The surface on the right side is located in a state of being opposed to the fixed surface of the mold 1 by the rotating disk, and the rotating disk rotating device 1 40 200930549 causes the square turntable to rotate 34% (10) degrees* to form the mold 3 to rotate (10) degrees. The surface of the inside of the mold 3 is opened (the surface on the left side of the mold 3 is formed on the inside of the sixth drawing), and is placed in the same position as the first and second views of the movable mold 32. Steps. 5

In the steps shown in Figs. 6E to 6G, the surface of the mold 3 is formed therein (the surface on the left side of the mold 3 is formed on the inside), and the coating film is fixed in the opposite direction; the coating film of the movable plate 32 is formed into the mold 2, and Steps of the π~(1) diagram. In the step shown in Fig. 6H, the surface of the mold 3 is formed from the inside (the surface on the left side of the mold 6 is formed on the left side of the 6g), and is placed in a state of being opposed to the coating mold 2 fixed to the movable tray 3i by rotation. The disc rotating device kisses the (four) disc 34 by 180 degrees to rotate the inner mold 3 (10), and the surface of the surface forming mold 3 (the surface on the right side of the mold 3 in the sixth drawing) is located and fixed to the fixed tray 31. The surface forming mold is in the opposite positional state, and the same steps as in the first FIG. 1 are performed.

According to the above aspect, since the moldable mold is thinner than the method of the fifth example, it can be installed in an injection molding machine having a small opening and closing modulus. Alternatively, a mold for forming a mold for forming a mold in a mold can be formed, and a mold for closing mold 6 for the movable disk 32 can be formed. The mold is formed on the surface and the mold is opened. The mold 2 is placed inside to form the mold 3 and the mold. Between the molds 6 and the surface forming mold 1 and the coating medium forming mold 2 are fixed in the front and back. In this way, the surface forming device i and the coating film forming device 2 which can be constructed to be (4) can be supported by the rotary disk 34 which is rotatably driven by the rotary disk rotating device u2R of the molding machine 124. According to such a configuration, the rotary disk 34 is rotated by 18 degrees by rotating the 200930549 rotary device 122R, whereby the mold 1 and the coating film forming mold 2 and the inner (4) mold 3 or the mold for closing mold are formed by the rotation of the surface forming mold 1 and the coating film. 6 pairs of 'can be switched and exchanged position method (refer to the claw diagram, map). The so-called sling 6 is tilted back to the movable plate 32 of the closing mechanism 122 of the rifling machine 124, and is used to apply the closing force to the surface forming mold 1 and the coating film forming mold 2 after the mold is closed. Mold. The steps shown in Figs. 7A to 7C are fixed to the surface of the rotating disk to form the mold m to form the mold 3 in the opposite direction, and the fourth step is the same as the first to the first drawing. 10 15 20

In the step shown in Fig. 7D, a state in which the spacer 1 is placed opposite to the inner mold 3 is formed from the surface fixed to the surface of the rotary disk, and the rotary disk 34 is rotated by 180 degrees by the rotary disk rotating device 122R to form a surface mold. The film-forming die 2 is rotated by 180 degrees, and the film forming mold 2 is placed in a state in which the mold 3 is fixed to the inside of the fixed disk 31, and the same steps as in the first step are performed.

In the steps shown in Figs. 7E to 7G, the coating film forming mold 2 is disposed opposite to the mold 3 fixed to the inside of the fixed plate 31, and the same steps as those of the first at 1G drawing are performed. In the step shown in Fig. 7H, the surface of the coating film forming mold 2 and the mold 3 fixed to the inside of the solid mold 31 are disposed opposite to each other, and the rotary disk 34 is rotated by 180 degrees by rotating the disk 2 = disk 122R to form a surface. The mold 丨 and the 犋-shaped mold 2 are rotated by 180 degrees, and the surface is fixed so that the surface of the rotary disk 34 is raised by 1 and the inner mold 3 is disposed opposite to each other, and the same step as the first molding is performed. 42 200930549 5 ❹ 10 15 Φ 20 Further, the method of rotating the rotating movable disk 32 of the injection molding machine 123 of the SI wire Φ-shaped money rig and the coating rig 2 (refer to the 4th to 8th drawings) And the mold for forming the in-mold coating product is more related to the mold 6, and the surface-shaped reducing tool 1 and the coating-type lowering device 2 are disposed inside to form the mold 3 and the mold for closing the mold 6 and the surface is formed into a mold. The coating film forming mold 2 is fixed to the front and back body, and can be exchanged by being rotated in a state of being opposed to the mold 3 or the mold closing mold 6 (see FIG. 7A to FIG. 3). Since the gate can be disposed in the inner surface of the molded article 22 in which the mold 3 is formed, the mold-in-the-mold article 25 having an excellent appearance can be obtained even if the thermosetting paint layer 21 is thin. Next, a thermosetting coating which is used in the method for producing an in-mold coating material according to the above-described third embodiment of the present invention is used to inject a coating material as a thermosetting coating material. The machine 41 injects the correct amount of one shot into the painting cavity 14 at a moderate pressure. The material of the thermosetting coating material may be an unsaturated polyester tree eucalyptus epoxy acrylate vinegar oligomer or a urethane acetoacetate vinegar oligomer or the like which can be hardened by a peroxide catalyst. The composition of the bonding material is the main liquid type coating & epoxy resin/polyamine curing system, or the polyol tree sapphire/polyisocyanate hardening system, etc., and the main agent/hardener is mixed before the injection mold - liquid coatings, etc. Among them, as a material of the thermosetting coating material, an oligomer having an acrylic group or an unsaturated polyester resin, and any one of the ethylenically unsaturated monomers copolymerizable with such a knife are crosslinked. The single-liquid type coating of the organic peroxide initiator having an efficiency of 8 or more is excellent in hardening property, appearance, and weather resistance, and can shorten the hardening time, and the problem of adhesion, appearance, and weather resistance from 43 200930549 It is very good from the viewpoint of being applicable to a resin molding material in which the in-mold coating method cannot be applied. The viscosity of the thermosetting coating is in the range of 2000 to 7000 mPa·s, and 5 can be appropriately set depending on the type or thickness. In particular, in the third embodiment of the present invention, the mold 3 and the coating film forming mold 2 are formed to have almost no voids outside the cavity, and the mold can be fixed by a strong mold closing pressure, so that even a thermosetting paint is provided. It is advantageous to have a very low viscosity which is easily leaked, and the thermosetting paint does not leak from the coating cavity 14. ^ 10 The paint injection machine 41 constitutes a pressure applied to the upper portion of the paint tank 43, and the correct amount of the thermosetting paint to be injected is sent from the paint tank 43 to the paint having the structure of the measuring machine ft, the injection function, and the valve opening and closing function. The structure of the injection unit (refer to Figure 8). Next, the inner shape of the molded product 22 is formed: the mold 3 and the coating film forming mold 2 are closed, and the molding cavity 14 for coating the molded article 22 with the thermosetting paint is formed on the molded article 22 and coated. The stage between the film forming molds 2 'the coating injection unit 42 advances to directly contact the coating film to form a mold

The structure in which the thermosetting paint is injected into the mold cavity 2 through the coating film forming mold 2 is injected. In the position setting of the coating material injection unit 42, the injection opening of the thermosetting coating material provided in the coating film forming mold 2 can be provided on the surface of the injection molding machine 124 fixed to the fixing tray 31 (see FIGS. 3A to 3H). And the coating injection unit 42 is arranged in parallel with the resin injection unit having the injection molding machine m as an example of a tree hiding machine. Moreover, the thermosetting coating material injection opening provided in the coating film forming mold 2 can be provided on the opposite surface of the mold 3 formed on the inside (see FIG. 44 200930549 to the seventh drawing), and the coating material injection unit 4 2 can be The resin injection unit is disposed along the vertical direction. The injection time of the thermosetting paint is about 〇1 to 1 sec, and is appropriately set depending on the material of the hot material or the size of the coating cavity 14. The 5' main inlet pressure of the thermosetting paint is set to a range of about 10 to 400 kgf/cm2. However, in order to prevent burrs or bubbles in the coating film, it is preferable to set the pressure to be high. In particular, in the case of the first embodiment of the present invention, the inside forming mold 3 and the coating film forming mold 2 are completely free from voids other than the coating cavity 14, and can be fixed with a strong closing force, so that even at a high pressure The heat-curable coating is injected, and the thermosetting coating does not leak from the coating cavity 14. Next, the molding resin used in the method for producing a mold-in-mold according to the first embodiment of the present invention will be described. The molding resin is not particularly limited as long as the injection molding resin or the engineering plastic which is usually thermoplastic, and the thermosetting resin material 15 is preferably formed, and is preferably formed into a form which is easy to form and which is in close contact with the thermosetting coating material. Specific examples of the molding resin include propylene-butadiene-styrene resin (ABS resin), polyamine-based resin, polyethylene resin, polyester resin, polypropylene resin, and poly-pair. A butylene phthalate resin or a polycarbonate resin. 20 The molding resin is filled in the forming die by a resin injection machine. An injection molding machine 124 can be used as the resin injection machine. Briefly, between the surface forming mold 丨 and the inner forming mold 3 or between the coating film forming mold 2 and the inner forming mold 3, a forming hem upper sheet 71' is disposed to obtain the painted inner mold. The mold is painted on the surface of the 45 200930549 product and the film 71 is drawn. The forming and drawing sheet 71 is formed by forming at least the upper layer 75 on the base sheet 72, and has a hot pressing at the time of injection molding of the molding resin or injection of the thermosetting coating, so as to include the overwriting of the upper layer 75. The layer 78 is overprinted from the base sheet 72 with the upper 5 sheets of the function of molding the resin. The forming and drawing sheet 71 may be provided as needed to lift the adhesive layer 77 to the molding resin or the thermosetting coating, or to peel the upper layer 75 from the base sheet 72 to be in close contact with the thermosetting coating layer 21. The release layer 74 and the anchor layer 76 for improving the adhesion between the layers, the release layer 73 for assisting the release of the base sheet 72 and the release layer 74, and the like (see Fig. 9). 10 In the case where the upper layer 75 is formed into a single layer or a plurality of layers in a desired pattern, a metal vapor layer or the like is formed to form a new pattern having a metallic luster. Further, the substrate piece 72 may remain on the molded article 22, and the base sheet 72 may be in close contact with the thermosetting paint layer 21, or may remain on the surface of the painted article in the mold. In this case, the peeling layer is not formed. 74 and release layer 73. Hereinafter, an embodiment of a more specific example than the above-described first embodiment will be described. (Example 1) An in-mold coating product 25 was produced using a mold 20 for forming an in-mold coating comprising a mold 3 for forming a mold having a mold and a mold, and a mold forming mold 2 and a film forming mold 2, respectively. The mold 3 was formed with respect to the mold temperature set at 5{rc and attached to the inside of the rotary disk 34, and the same mold temperature was set at 50. (: After the surface forming mold 1 is closed, the mold is closed at a closing pressure of 22 ton, and after the forming of the forming cavity 11, the heated and melted heat-resistant ABS resin is filled in the forming cavity 11 and cooled for 40 seconds. And the surface forming mold 1 is opened, and the molded article 22 having a rectangular parallelepiped shape having a length of 100 mm, a length of 5 mm, and a height of 3 mm is obtained in a state in which the mold 3 is held therein by the 200930549 5 ❹ 10 15 20 20. Secondly, it will be maintained. The inside of the molded article 22 is formed to rotate the mold 3 by 18 degrees, and the surface of the molded article 22 in which the mold 3 is formed is held, and is switched (exchanged) into a cavity and has a shape of a length of 100.5 mm, a length of 50.5 mm, and a height of 3.2 mm. When the mold temperature is set to 95 C, the coating film forming mold 2 is opposed to each other, and the mold 3 and the coating film forming mold 2 are closed after the mold is closed, and the mold is closed, and the molded product 22 and the coating film are formed. A coating cavity 14 is formed between the molds 2. Next, a thermosetting coating (made by Dainippon Paint Co., Ltd.: / 歹 only 8 〇〇〇 viscosity 3 OOO mPa·s) is injected into the coating die 4 and kept Curing the thermosetting coating for 4 seconds When the coating film forming mold 2 is opened, the in-mold coating product 25 in which the thermosetting coating layer 21 is integrally coated on the molded article 22 is obtained (see FIGS. 5A to 5D). When the thermosetting coating material is injected, The thermosetting coating material does not leak from the coating cavity 14. The obtained in-mold coating material 25 does not cause burrs caused by the thermosetting coating layer 21, and the film of the thermosetting coating layer 21 is sufficiently formed on the side surface portion. It is excellent in thickness, hardenability, adhesion, appearance, and weather resistance. Moreover, the number of shots per unit time is also 18 times, which improves productivity. Example 2 The mold 3 is formed into a non-rotating disk 34. In the mold, the first inner mold 4 and the second inner mold 5 are formed in the fixed mold 31 of the injection molding machine 124, and the surface forming mold 1 and the coating film forming mold 2 are assembled. When the molding machine 124 rotates the movable disk 32, the surface forming mold 1 is opened, and the first molded article 23 is obtained, and the first molded article 23 is held in the state of the first inner shape 47 200930549, and the second molded product is the second inner mold forming mold 5. After, the rotary injection molding machine The rotating movable disk 32 is formed in the same manner as in the embodiment except that the first film forming mold 4 (the second inner forming mold 5) and the coating film forming mold 2 are closed at the position where the coating film forming mold 2 is assembled to the first surface forming mold 1. 5, the first in-mold coating product 26 and the second in-mold coating product 27 are obtained (see FIGS. 4A to 4H). When the thermosetting coating is injected, the thermosetting coating is not coated from the first coating. The cavity 15 and the second coating cavity 16 are leaked out. The obtained in-mold coating product 25 does not cause burrs caused by the thermosetting coating layer 21, and the film of the thermosetting coating layer 21 is sufficiently formed on the side surface portion. Thick, hardenability, adhesion, and excellent appearance and weather resistance. Moreover, the number of shots per unit time is also 1.9 times higher and productivity is improved. Example 3 15 20

The entire part of the product of the coating film forming mold cavity 2 is set as a jacket, and the inside of the mold 3 and the coating film forming mold 2 are closed, and then the mold is closed to inject the thermosetting paint into the coating cavity 14, The oil pressure compresses the sleeve of the product portion of the coating film forming mold 2 into the mold 3 and compresses the outer shape of the coating cavity 14 into a length of l〇〇.〇5 mm, a length of 50.08 mm, and a height of 3.〇4 mm. When the thermosetting coating material was mainly applied to the in-mold coating product in the same manner as in Example ,, the thermosetting coating material did not leak from the first coating mold = 14. The obtained in-mold coating product 25 does not have a burr formed by the thermosetting coating layer 1 and has a medium thickness of the thermosetting coating layer 21 on the side surface portion. "Curability, adhesion, appearance, and resistance. Excellent climate. [Embodiment 4] The forming and drawing sheet 71 is disposed on the surface of the mold forming surface of the injection molding machine 124, which is fixed on the surface of the mold 30, and the ABS resin is filled in the molding cavity 11 to obtain the surface overwritten layer 78. After the formed rectangular parallelepiped molded article 22 is formed, the inside of the molded article 22 is formed to form the mold 3. Rotate 180 degrees, switch to the side of the coating forming mold 2, and form the mold 3 and the coating film 5 to form a mold. (2) After the mold was closed, the mold was closed, and the in-mold coated article 25 was obtained in the same manner as in Example 1 except that the coating cavity 14 was formed. When a thermosetting coating is applied, the thermosetting coating does not leak from the coating cavity 14. The obtained in-mold coated article 25 does not cause burrs caused by the thermosetting coating layer 21, and the molded article 22 and the thermosetting coating layer 21 are formed by forming a copying layer 78 of the upper edge sheet 1G 71. In the mold upper coating material 28 (see FIG. 2), the film of the thermosetting coating layer 21 is sufficiently thick on the side surface portion: it is thick, and is excellent in curability, adhesion, appearance, and weather resistance. According to the first embodiment described above, the thermosetting paint does not leak from the coating cavity, and the in-mold coated article 25 can be prevented from being burrs caused by the thermosetting coating 15 layer 21. © That is, using a mold (4) coated with a mold 3, a surface forming mold 1 and a coating film forming mold 2, the mold is formed by forming a mold and a mold on the surface by (1) forming a mold and forming a mold. The forming mold surface forming mold of the product 22 is formed between the inside forming mold 3 and the surface forming mold 110, and (ii) the molding resin is filled into the forming cavity 11 and cooled and solidified to form a molded article 22, (Hi) The inner mold 3 and the surface forming mold 1 are opened in a state in which the inner mold 3 holds the molded product 22, and (iv) a mold is formed on the surface opposite to the inner mold 3; Switching (exchange) into a coating film forming mold 2' (v) to form a mold 3 and a coating film forming mold 2 49 200930549 to mold the inside of the molded article 22, and to coat the molded article 22 for the thermosetting paint. The mold cavity 14 is formed between the molded article 22 and the coating film forming mold 2, and (vi) the thermosetting paint is injected into the coating cavity 14 to be solidified, whereby the thermosetting paint layer 21 can be produced. The in-mold coating product 25 of the molded article 22 is covered. Therefore, when the mold 3 is formed and the coating film forming mold 2 is closed, the coating cavity 14 is completely free of gaps and can be fixed with a strong mold closing force. Therefore, even if a thermosetting paint is injected at a high pressure, thermosetting property is obtained. The paint does not leak from the coating cavity _14, and the burrs caused by the thermosetting coating layer do not occur in the in-mold coating. Further, since the shape of the mold 2 can be arbitrarily set, the thermosetting paint layer 21 can be formed on the side surface of the molded article 22 in accordance with the film thickness. Further, it is also possible to construct a mold 3 (4, 5) having at least two inner portions, and to perform the above steps (1) to (ii) using the inner mold 4 or 5 and the surface forming mold 1, and to use another The above steps (v) to (vi) of forming the mold 5 or 4 and coating the film 15 to form the mold 2 are carried out. As a result, the thermosetting coating layer 21 can be formed on the surface of the other molded article 24 during the molding of one molded article 23, so that the number of shots per unit time can be increased. X 'thermosetting coating The thermosetting coating is any one of an ethylenically unsaturated monomer containing an oligomer or an unsaturated polyester resin containing an acrylic group 20 and copolymerizable with the above components, and crosslinking efficiency. When the single-liquid type coating material is an organic peroxylized one starting agent of 8 or more, the single-liquid type coating material is excellent in hardenability, adhesion, appearance, and weather resistance, and as a result, the hardening time can be shortened, and the adhesion is ' In view of the appearance and the weather resistance, there is an effect that the resin molding material which cannot be used for the in-mold coating method of 50 200930549 can be applied. In addition, when the thickness of the coating cavity is set to 10 to 1 Å/m, the thermosetting resin coating film which is difficult to form a film such as two-color molding can be formed on the surface. (Second Embodiment) Before the method of manufacturing the in-mold coating product and the in-mold coating product forming apparatus according to the second embodiment of the present invention, the second embodiment will be described with reference to FIGS. 12A to 24; Implement a problem specific to the situation. In the conventional method of coating in the mold, the two mold cavity molds of the injection cavity die 3〇1 and the decorative die cavity die 304 are used to project the molded article 303 by the die cavity die 3〇1. After the forming, the cavity mold is exchanged, and the cavity formed by the gap is formed on the surface of the molded product in the decorative mold cavity 3〇4, and the coating material for the decoration composed of the liquid thermosetting composition is pressed. A mold exchange which is formed by forming a decorative film 305 on the surface of the molded article 305, and a method of forming and decorating the molded article is disclosed in the patent document (No. 3,988,660) (see FIG. 25A). Figure 25D). However, the coating material for decoration of the liquid thermosetting composition is largely shrunk by hardening. The shrinkage ratio may be much larger than the shrinkage ratio of the general molding resin when the shrinkage ratio is 5% or more. Therefore, there is a problem that 瑕 20 瑕 appears on the surface of the molded article. An object of the second embodiment of the present invention is to provide a method of manufacturing an in-mold coating article and an in-mold coating product forming apparatus which do not cause the above problems even if the coating material shrinks. In the second embodiment of the present invention, the method for producing an in-mold coating product and the in-mold coating product forming apparatus of the present invention are described in detail below. Fig. 12A to Fig. 12G are cross-sectional views showing the steps of a method of manufacturing a mold-in-mold article according to a second embodiment of the present invention. Fig. 13 is a cross-sectional view showing the steps (steps of Fig. 12A) of the method for producing the in-mold coated article according to the second embodiment of the present invention. Fig. 14 is a cross-sectional view showing the steps (steps of Fig. 12B) of the method for producing the in-mold coated article of the second embodiment of the present invention. Fig. 15 is a cross-sectional view showing the steps (step 12C) of the method of manufacturing the in-mold coating material according to the second embodiment of the present invention. Fig. 6 is a cross-sectional view showing the steps (steps of Fig. 120) of the method of manufacturing the in-mold coated article of the second embodiment of the present invention. Fig. 17 is a cross-sectional view showing the steps (steps of Fig. 12E) of the method for producing the in-mold coated article according to the second embodiment of the present invention. Fig. 18 is a cross-sectional view showing the steps (steps of Fig. 12F) of the method for producing a mold-coated article according to the second embodiment of the present invention. Fig. 19 is a cross-sectional view showing the steps (steps of Fig. 12G) of the method for producing the in-mold coating of the second embodiment of the present invention. Fig. 20 is a cross-sectional view showing the steps of a method of manufacturing the in-mold coated article according to the second embodiment of the present invention. Fig. 21 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold article according to the second embodiment of the present invention. Fig. 22 is a cross-sectional view showing the 20th step of the method for producing a mold-in-mold according to the second embodiment of the present invention. Fig. 23 is a schematic view showing a method of producing a mold-in-coat article according to the second embodiment of the present invention and a coating injector used in the in-mold coating product forming apparatus. Fig. 24 is a plan view showing the in-mold coated article obtained by the method for producing a mold-in-mold according to the second embodiment of the present invention. Fig. 25 is a cross-sectional view showing a method of manufacturing a conventional in-mold coating. 52 200930549 5 ❹ 10 15 ❹ 20 In the figure, 201 is the surface forming mold, 202 is the coating film forming mold, 2〇3 is the inside forming mold, 204 is the compression block, 205 is the outer peripheral plate, and 2〇6 is the mounting plate, 207 It is a coil spring, 211 is a sliding sleeve, 212 is a sliding sleeve, 213 is a forming die 6, 214 is a coating cavity, 221 is a thermosetting coating layer, 222 is a molded article, 223 is a tab portion, and 224 is a product portion. , 225 is the mold coating, 241 is the paint injection machine, 242 is the paint injection unit, 243 is the paint tank, and 244 is the paint gate. The sliding sleeves 211 and 212 are disposed between the compressing block 204 and the sliding surface of the outer peripheral plate 2〇5, and a gap between the resin and the coating material that is not impregnated to the extent that the sliding block 204 and the outer peripheral plate 205 are easily slid. First, the method of manufacturing the in-mold coating of the second embodiment of the present invention will be described with reference to the mold for molding a mold in the mold used in the production method. In the mold-in-mold forming mold for use in the method for producing a mold-in-mold coating according to the second embodiment of the present invention, the mold for forming the inside of the mold 203, the surface forming mold 2〇1, and the coating film forming mold 2〇2 are included. . The mold 203 formed therein is used to form the inner shape of the molded article 222. The surface forming mold 2〇1 is used to form the surface shape of the molded article 222. The coating film forming mold 2 2 is used to form the thermosetting coating layer 221 on the surface of the molded article 222. The individual concave-convex shapes of the surface forming mold 203, the surface forming mold 2〇1, and the coating film forming mold 2〇2 in the drawing are merely examples, and are not limited to these shapes. The inside mold 2 is formed as shown in Fig. 13, and the outer peripheral plate 2〇5 having the compression block 204, the periphery thereof, the mounting plate 206 for fixing the compression block 2〇4, and the outer peripheral plate 2〇 can be used. 5 and the mounting plate 2〇6, the outer peripheral plate 2〇5 can be given a spring energy such as the coil spring 2〇7. An example of this is 53 200930549. There are a plurality of coil springs 207. The mold 202 can be formed using the paint gate 244 as a coating film. In the second embodiment, the compression block 204, the outer peripheral plate 2〇5, the mounting plate 206, and the spring body of the coil spring 207 constitute an example of a compression mechanism disposed in the product portion of the molding cavity 214 of the coating film forming die 202. 5 is to solve the above problems. First, the mold 203 and the surface forming mold 201 are closed by using the mold closing mechanism 123 or 121 of the injection molding machine 124, and the mold cavity 213 for forming the molded product 222 is formed inside to form the mold 2〇3 and The surface is formed between the molds 201 (see FIG. 12A and FIG. 13). That is, the molding cavity 213 is formed between the compression block 2〇4 and the outer peripheral plate 205 and the surface forming mold 201 by the closed mold ©10 operation. On the other hand, the outer peripheral plate 2〇5 is pressed against the surface forming surface of the mold 201 by the imparting ability of the plurality of coil springs 207 as an example of the elastic body. At this time, the mold 2 is formed as a fixed mold, and when the surface forming mold 201 is a movable mold, the surface forming mold 201 is moved by the mold closing mechanism 121 which is formed by the surface forming mold 15. On the other hand, when the surface forming mold 201 is a fixed mold and the inside of the mold 2 is formed as a movable mold, the mold 203 is moved by the mold closing mechanism 123 in which the mold is formed. Then, the molding resin is filled in the molding cavity 2 213 by the injection molding machine 124, and is cooled and solidified to obtain a molded article 222 (see Fig. 12 and Fig. 14). Then, the mold 203 and the surface forming mold 201 are opened by using the mold closing mechanism 123 or 121 of the injection molding machine 124 in a state in which the mold 2 is held in the mold 2 〇 3 (see FIG. 12C and 15). Figure). 54 200930549 Thereby, the surface forming mold 2 () 1 is separated from the molded product 222. At this time, the mold 2G3 is formed as a fixed mold, and when the surface forming mold 2 (1) is a movable mold, the mold is formed by the surface forming mold. The mold mechanism 12 is moved to move the surface forming mold 201. On the other hand, the 'surface forming mold 2G1 is a S1 fixed mold, and the inner 5 ❹ 10 15 ❹ 20 surface forming mold 2G3 is configurable, and the mold 2 〇 3 is moved inside by forming the mold closing mechanism 123 which is movable inside. . Here, it is necessary to hold the molded article 222 for forming the mold 2〇3 therein, for example, by projecting the injection pin into the molded article 222, and the molded article 222 is placed in a state in which the injection pin is caught, or the molded article 222 is formed into a claw portion or the like. In the undercut shape, once the molded article 222 is pushed out, the molded article 222 is not separated from the inside forming die 3〇3 without causing the tilting 4 to operate. Next, the rotary movable platen 32 and the rotary disk rotating device 122R of the injection molding machine 124 are used to rotate or move the inner mold 2() 3, whereby the mold facing the mold 2〇3 is formed by the surface. The mold 2〇1 is replaced (exchanged) into a coating _ into a mold 2〇2 (refer to the 12th figure, the first off). A method of exchanging the mold 203 formed therein with another inside mold or a method of exchanging the mold forming mold 201 and the coating film forming mold 202 will be described later. Next, the mold closing mechanism 123 or 121 of the injection molding machine 丨 24 is used to hold the mold 2 〇 3 for forming the molded article 222 and the coating film forming mold 201 to be closed, and the molded article for thermosetting paint is applied. The coating cavity 214 of 222 is formed between the molded article 222 and the coating film forming die 202 (see FIG. 12E and FIG. 17). That is, 'the molding 55 222 on the compression block 204 by the mold closing operation and the coating die 55 are formed between the outer circumferential plate 205 and the coating film forming die 202. 200930549 VIII 3 3 'The outer peripheral plate 2 〇 5 is used as The majority of the coil springs 2〇7 of the elastic body are biased to the opposite side of the coating film forming mold. The paint-injecting device 244 of one of the heat-curing paint injection devices 125 is injected into the coating cavity 214 and is finished with the mold cavity 214 (refer to FIG. 12F, In the mold, the in-mold coated article 225 can be produced by simultaneously pressing the thermosetting coating material to be applied to the molded article 222 (see FIGS. 12G and 19). Here, the term "simultaneously" means that the timing of starting the pressurization may be © H) a problem-free range of formation and may be before the end of the injection or after the end of the injection. In order to pressurize the injected thermosetting coating material, for example, the mold closing mechanism 123 or 122' of the injection molding machine 124 is used by the movable disk 32 of the injection molding machine 124 (in FIG. 19, for example, adjacent to the left side of the mounting plate) Movement of the arrangement: the movement of the disk 32) toward the mold closing direction (for example, in the figure, the movable disk 32 (mounting plate 2〇6) is formed by the closing mold 15 mechanism 123 with respect to the coating film on the fixed side to form the mold 202. The movement to the right, or the movement of the coating film forming mold 202 with respect to the fixed side movable plate 32 (mounting plate 2〇6) by the closing mechanism 122, or the left side movement With the mold closing mechanism 123 and the movable disk 32 (mounting plate 206) facing the coating film forming mold 2〇2 and moving to the right, the coating film forming mold 202 faces the movable disk 32 by the 2〇 closing mechanism 122. (the operation of moving the mounting plate 206 to the left), the coil spring 207 is compressed by the coating film forming mold 2〇2, and as a result, the compression block 2〇4 is relatively moved toward the coating film forming mold 202 with respect to the outer peripheral plate 205. It can be (refer to Figure 12G, Figure 19). Preferably, the sliding sleeve 211 between the compression block 204 and the outer peripheral plate 205 is placed along the cavity forming surface of the compression block 204 formed into the forming cavity 213 of the shape 56 。 30 30 30 30 ( ( As a result, when the molded article 222 is formed in the molding cavity 213, the end portion of the sliding sleeve 211 is covered with the molded article 222 (see FIGS. 12 to 18 and the like), and the compression block 204 is oriented with respect to the outer peripheral plate 205. When the coating film forms the mold side movement 5, the thermosetting paint does not intrude into the sliding sleeve 211. Next, after the thermosetting coating layer 221 is coated on the surface of the molded article 222, the movable plate 124 or the coating film forming die 202 of the injection molding machine 124 is oriented toward the mold opening using, for example, the mold closing mechanism 123 or 122 of the injection molding machine 124. The direction is moved, so that the compression block 204 is moved to be separated from the coating film forming mold 202 while maintaining the mold closing state by the contraction of the contracted coil spring 2〇7. After that, the inside of the in-mold coating product 225 is held by the inside forming mold 2〇3, and the mold forming unit 203 and the coating film forming mold 2〇2 are opened by using the mold closing mechanism 123 or 122 of the injection molding machine 124 (refer to 2〇图,第21图). Thereby, the coating film forming mold 202 is separated from the in-mold coating article 225. Next, the in-mold coated article 225 is taken out, and the inner turn forming mold 203 is rotated or moved using the red rotary movable disk 32 and the rotary disk rotating device 122R of the injection molding machine 124, and the inner mold 2 is formed to face the mold. The mold is replaced (exchanged) from the coating film forming mold 202 into a surface forming mold 2〇1 (refer to Fig. 22 20). Next, the mold closing mechanism 123 or 121 of the injection molding machine 124 is used to close the mold to complete a series of molding cycles (see FIGS. 12A and 13). In this way, the in-mold coating article 225 can be manufactured by performing a series of steps of the 12A to 12G drawings. When the in-mold coating product 225 is continuously produced, the steps of the 12th to 12th steps may be sequentially repeated in accordance with the steps of the 12th and 3rd drawings. The mold closing mechanisms 121, 122, and 123 for performing mold opening and closing are the same as those of the first embodiment, and for example, a curved mold closing mechanism or a direct pressure type closing mechanism of the injection molding machine 124 can be used. 5 The shape of the coating film forming mold 202 is different from that of the surface forming mold 201, and the outer shape of the coating film forming mold 2〇2 (particularly the portion facing the surface on which the mold 2〇3 is formed) is larger than the surface forming mold 201 (for example) When the surface for forming the mold cavity is a concave portion, the size or depth of the concave portion is set to be large, or when the surface for forming the vibration mold cavity is a convex portion, the size of the convex portion is set small or high. The 1 degree is set to be low, and is set to form a portion that does not come into contact with the molded article 222. This portion which is not in contact with the molded article 222 corresponds to the coating cavity 214. The shape of the coating cavity 214 is appropriately set in accordance with the desired pattern (e.g., opening, etc.) or thickness of the thermosetting coating layer 221 . The coating cavity 214 may cover the entire surface of the molded article 222 or may be formed only on a part of the surface of the molded article 222. Further, the material forming the surface forming mold 2, the coating film forming mold 202, and the compression block 204, the outer peripheral plate 205, and the mounting plate 206 forming the mold 203 may be the same metal or different metals. Further, the injection port of the molding resin may be provided on the surface forming mold 2〇1 (see Figs. 12 to 15 and 22) or may be provided on the inside to form the mold 20 203 side. Further, a coil spring 207 made of metal, rubber or the like can be used as the elastic body between the outer circumference 2〇5 and the mounting plate 206 (see Figs. 13 to 22). Further, the paint gate 244 at the injection position of the thermosetting paint may be disposed at the center of the surface of the coating cavity 214. However, since the paint injection mark remains in the case of 58 200930549 5 ❹ 10 15 ❹ 20 In-mold coating 222 The surface 'is therefore disposed in the keyhole or the mark mounting position or the like in the case where the appearance of the paint-free trace is required, or the molded article 222 is formed by the tab portion 223 and the product portion 224, and the paint gate is provided. The 244 is provided on the tab portion 223 (see Fig. 14). In this case, it is important that the thickness of the coating cavity 214 to be formed on the surface of the tab portion 223 is thicker than the thickness of the coating cavity 214 to be formed on the surface of the product portion 224 (refer to Fig. 17). ). The upper limit of the thickness of the coating cavity 214 to be formed on the surface of the tab portion 223 is not particularly limited. However, in order to prevent the molding cycle from being practically long, it is preferable to form the surface of the product portion 224. The thickness of the coating cavity 214 is within 150%. More preferably, the thickness of the coating cavity 214 formed on the surface of the tab portion 223 is set to be within 120% to 150% of the thickness of the coating cavity 214 to be formed on the surface of the product portion 224. By setting in this way, the amount of shrinkage in the thickness direction of the thermosetting paint layer 221 formed on the surface of the product portion 224 is smaller than the amount of shrinkage in the thickness direction of the thermosetting paint layer 221 formed on the surface of the tab portion 223. The shrinkage of the thermosetting coating layer 221 to be formed on the surface of the product portion 224 is not hindered. Here, it is explained that the position of the sliding sleeve 212 becomes the position on the outer circumference of the tab portion at the position of the tab portion, but since the sliding sleeve 212 is sealed by the molded article 222, the thermosetting paint does not intrude into the sliding sleeve 212. Medium (refer to Figure 19). Further, both of the surface forming mold 201 and the coating film forming mold 202 may be a mirror mold 'or both of them may be a grain mold, or either one may be a mirror mold and the other may be a texture mold. . Further, the mold 203 can be formed inside to form a protrusion or the like. The mold temperature at which the mold 203 and the surface forming mold 201 are formed can be appropriately set by the mold temperature adjusting machine 113 and in. The mold temperature of the coating film forming mold 2〇2 can be appropriately set by the mold temperature adjusting machine 112. The medium for forming the mold 203, the surface forming mold 201, and the coating film forming mold 2〇2, respectively, by the mold temperature adjusting machine 113, ill, and 112, may be water or may be oil. By the mold temperature adjusting machines ιι 3 and 1U, the coating film forming mold 202 is formed at a suitable temperature for forming the mold 203 and the surface forming mold 2〇1 in accordance with the material of the molding resin. The mold temperature may be set to a temperature at which the thermosetting coating hardens within a few seconds depending on the material of the thermosetting coating material. Further, in order to prevent mold failure from occurring, the mold temperature of the coating film forming mold 202 can be set to be the same as the temperature of each of the mold forming unit 2〇3 and the surface forming mold 201. In the following, a plurality of methods for exchanging (replacement) a mold facing the mold 2 〇 3 from the surface forming mold 2〇1 into a coating film forming mold 15 202 by exemplifying a plurality of exchange mechanisms will be exemplified. First, a method of exchanging a mold opposed to the mold 203 formed therein from the surface forming mold 201 into a coating film forming mold 202 includes a movable disk 32 for setting the injection molding machine 124 in which the mold 203 is fixed, or a movable disk. The method of rotating the rotary disk 34. In this case, for example, in the case where the rotary disk 34 of the mold 4 or 5 is formed on the inside of the 20th 3D view of the first embodiment, the movable disk rotating shaft 33 of the movable disk 32 is coupled to the rotary disk rotating device 122R of the injection molding machine 124. . According to such a configuration, the rotary disk 34 is rotated by the rotary disk rotating device 122R, and the rotary disk 34 is rotated, and the mold 203 is formed inside, and the mold facing the mold 203 can be formed into a mold from the surface. Transfer 200930549 to the coating film forming mold 202, or vice versa. Further, instead of the above-described exchange method, there is a case where the inner mold 203 is fixed to the movable disk 32 of the injection molding machine 124, and the surface forming mold 201 and the coating film forming mold 2 are fixed to the injection molding. The case of the movable disk 32 of the machine 5 I24. According to such a configuration, for example, in the case where the surface forming mold of the 4Dth drawing of the first embodiment is fixed and the rotary disk 34 of the coating film forming mold 2 is fixed, the movable disk 32 or the rotary disk 34 provided on the movable disk 32 is rotated. A method of exchanging the surface forming mold 2〇1 with the coating film forming mold 202 with respect to the inside of the mold 2〇3. 10 Here, in the above several examples, the mold 203 may be formed in one or only two or more. When two or more inner molds 203 are formed, it is possible to simultaneously mold one inner mold 2〇3 and the surface forming mold 201, and form a molding cavity 213 for forming a molded article in the inside. Between the 203 and the surface forming mold 201, the molding resin 15 is filled in the opening cavity 213, and is cooled and solidified to form a molded article 222 (for example, see the third embodiment and the third embodiment of the first embodiment). The mold on the upper side of each movable disk 32 of the figure, and the other mold forming mold for holding other molded articles and the coating film forming mold 202 are closed, and the coating mold for coating the molded article with the thermosetting paint is used. The hole 214 is formed between the molded article and the coating film forming mold 202. The step of injecting the thermosetting coating into the coating cavity 214 and pressurizing the injected thermosetting coating at the same time as the injection is completed (for example, refer to The molds on the lower side of each of the movable plates 32 in the third embodiment and the third embodiment of the first embodiment. With such a configuration, the thermosetting coating layer 221 can be formed on the surface of the product 3030 during the formation of one molded article, so that the number of shots per unit time can be increased. When two or more inner portions are used to form the die, the shapes of the molds formed in each of the inner portions may be all the same, for example, the members for forming the cavity portions of the molded article may have different shapes. Further, a plurality of molds can be formed as a body. Alternatively, as shown in Fig. 5A to Fig. 5D of the first embodiment, the inner mold 2G3 may be disposed on the surface forming mold 2G1 and the coating film forming mold 2G2d (4). They have the shape of opening y into eight. Forming the inner mold having the shape into the mold can be rotated by the rotary disk rotating device of the injection molding machine 124

10 rotating disk 34. According to such a configuration, the rotary disk 34 is rotated by 180 degrees by the rotary disk rotating device i22R, whereby the exchangeable surface forming mold 2〇1 and the coating film forming mold are formed with respect to the inside surfaces of the mold 2〇3 formed inside. 2〇2', a method of exchanging a plurality of inner forming molds 203 with respect to the surface forming mold 15 2〇1 and the coating film forming mold 202 (refer to the fifth drawing of the i-th embodiment).

The shape of each cavity may be the same or may be different. Further, in order to rotate the mold 203 formed therein, for example, the rotary disk which is rotated in the horizontal plane by the formation of the mold 2〇3 in the support and by the rotary disk rotating device 122R is 20 (i.e., in this case, the first embodiment) The A picture to the 5D picture can be viewed as a plan view). In such a method, the thermosetting coating layer 221 can be formed on the surface of the other molded article during the formation of one molded article, so that the number of shots per unit time can be increased. 62 200930549 When the mold is rotated or moved by the rotary disk rotating device 122R, the injection nozzle of the injection molding machine 124 and the injection nozzle of the thermosetting paint injection device 125 (the paint injection unit M2, etc.) The structure of the attached mold is rotated or moved to maintain the relationship with the injection molding machine 5 I24 or the hot-hard coating device 125. Therefore, it is preferable to make the wire-cutting machine 124 The nozzle for resin molding or the mold for the thermosetting paint injection device (2) rotates or moves the mold that is not connected. In addition, as shown in the seventh embodiment and the seventh embodiment of the first embodiment, the surface forming mold 2〇1 and the coating film forming mold 202 are fixed in a state in which the surface is formed in the same manner as the first surface forming mold 203. In the rotary disk 34, the surface is formed into a mold 2G1 «The silk money 2 is opposed to the inner mold 2〇3 and is exchangeable. Next, a thermosetting coating material using the k-forming method in the in-mold coating of the second embodiment of the present invention will be described. The thermosetting paint is injected into the coating cavity 214 from the paint injection machine 241 as an example of the heat-curing material injection device 125 at an appropriate pressure with an appropriate amount of the --shot amount. ^About the material of the thermosetting coating, there may be an unsaturated polyester tree eucalyptus epoxy acrylate vinegar oligomer, or urethane acetoacetic acid sorbing a low 20, etc. The single-liquid type coating of the main component of the material which is hardened by the catalyst and the epoxy resin/polyamine hardening system, or the polyol tree eucalyptus/polyisocyanate curing system, etc. before injection into the mold Mixed main agent / hard two-liquid type coating, etc. Among them, as a material of the thermosetting coating material, 匕3 has an acryl-based oligomer or an unsaturated polyester resin, or any of the ethylenically unsaturated monomers which can be copolymerized with σ, such as 63 200930549. The one-liquid type coating of the organic peroxide initiator having a cross-linking efficiency of 8 or more is excellent in hardening/adhesion, appearance, and weather resistance, and can shorten the hardening time, and the adhesion and the weather resistance are improved. The problem is that it is very good from the viewpoint of being applicable to a resin molding material in which the in-mold 5 coating method cannot be applied. The viscosity of the thermosetting coating is in the range of 2000 to 7000 mPa·s, and can be appropriately set depending on the type or thickness. In particular, in the second embodiment 4 of the present invention, the mold (2) and the coating film forming mold 2G2 have almost no voids outside the crucible 10 in the cavity, and the mold can be fixed by a strong mold closing pressure. It is advantageous in that it has a very low viscosity even if the thermosetting coating is easily leaked, and the heat hardening property is not leaked from the coating cavity 214. The paint injection machine 241 constitutes a pressure that applies pressure to the upper portion of the paint tank 243, and the correct amount of the thermosetting paint that is injected one-time, is sent from the paint tank 243 to a structure having a machine of 15 °, an injection function, and a valve opening and closing function. The configuration of the paint injection unit 242 (refer to Fig. 23). The position of the paint injection unit 242 can be set inside the coating film forming mold ® 202 (refer to Figs. 16 to 21). In addition, the injection port of the thermosetting coating material provided in the coating film forming die 202 is provided on the surface of the mold 2〇3 which is formed in 20 pairs, and the coating material injection unit 42 and the resin injection machine are provided as injection molding. The resin injection unit of the machine 124 is disposed in the vertical direction. In this case, the mold 203 and the coating film forming mold 202 are closed in the mold-preserving product 222, and the coating mold hole 214 is formed on the molded product 222 and the coating film in the thermosetting paint coating molded article 222. Forming the step 64 200930549 between the molds 202, the paint injection unit 242 advances to directly contact the coating film forming mold, and the thermosetting paint is injected into the coating cavity 214 through the coating gate provided in the coating film forming mold 2〇2. structure. The nozzle tip end portion of the paint injection unit 242 is adjusted to about 3 Torr by the mold temperature adjusting machine 112. (: By this, it is possible to prevent the thermosetting coating from being solidified by the heat of the mold 5. The injection time of the thermosetting coating is about 1 to 10 seconds, depending on the material of the hot material or the size of the coating cavity 214. The injection pressure of the thermosetting coating material may be set within a range of about 1 〇 to 4 〇〇 kgf/cm 2 , but the pressure is set to be high in order to prevent burrs or bubbles in the coating film. In particular, in the second embodiment of the present invention, the inside forming mold 203 and the coating film forming mold 202 have almost no voids outside the coating cavity 214 and can be fixed by strong mold closing pressure. The mold, therefore, even if the thermosetting coating is injected at a high pressure, the thermosetting coating does not leak out of the coating cavity 214. 15 The thickness of the finally formed thermosetting coating layer 221 is preferably 10 to 300/zm. According to the second embodiment of the present invention, even if the thickness of the thermosetting coating layer 221 is made thick, no flaws are generated. Here, the thickness of the thermosetting coating layer 221 is set to 1〇//m or more is for It is true that the thermosetting coating is filled in the cavity. Further, in order to set the hardening speed of the thermosetting 20 coating to be fast to set the molding cycle to be short, and to prevent flaws even in an uncompressed state, the final formation is performed. The thickness of the thermosetting coating layer 221 is preferably 10 〜 〇〇 / / m. Further, from the viewpoint of obtaining sufficient surface hardness in the case where compression has been performed, the finally formed thermosetting coating layer 221 The thickness of the molding resin used in the above-described second embodiment of the present invention, in which the molding resin is a general thermoplastic injection molding resin or engineering plastic, is described. The thermosetting type of the molding resin material or the like is not particularly limited, but it is preferably a mold which is easy to form and which is in close contact with the thermosetting coating material 5. Specifically, examples of the molding resin include propylene/moon-butyl Alkene-styrene resin (ABS resin), polyamine resin, polyethylene resin, polyester resin, polypropylene resin, polybutylene terephthalate resin, or polycarbon The ester resin is filled in the molding cavity 213 by a resin injection machine. The injection molding machine 124 can be used as a resin injection machine for β 10 . According to the second embodiment of the present invention, not only the prior art In the second embodiment of the present invention, the method of manufacturing the in-mold coating product of the second embodiment of the present invention is to use a mold 203 having a back surface, a surface forming mold 2, and The coating film forms an in-mold coating of the I5 mold 202 to form a mold, and (1) the inner mold forming mold 203 and the surface forming mold mold 201 are closed, and the forming mold hole 213 for forming the molded product 222 is formed therein to form the mold 2. 〇3 and the surface forming mold 2 Ο Ο , ( ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii ii In the state of 20, the mold 203 and the surface forming mold 2〇1 are opened, and (iv) the mold is formed from the surface forming mold 2〇1 to the coating film forming mold 2G2 in order to mold the mold facing the mold 203. The inner forming mold 2 () 3 is switched (exchanged) with the other inner forming mold 203, or the surface forming mold 2 〇 and the coating film forming mold 2 〇 2 are switched (exchanged), and (v) the molded milk is maintained. The inner shape 66 200930549 is formed by the mold 203 and the coating film forming mold 2〇2, and the coating cavity 214 for the thermosetting paint coating molded article 222 is formed on the molded article 222 and the coating film forming mold. Between 2 and 2, (vi) the thermosetting coating material is injected into the coating cavity 214, and the injected thermosetting 5 coating material is pressurized at the same time as the end of the injection. As a result, even if the thermosetting coating layer 221 on the surface is shrunk, the in-mold coating 225 having a flawless surface can be obtained. Further, in the method of manufacturing a mold-in-mold article according to the second embodiment of the present invention, the molded article 222 has the tab portion 223 and the product portion 224, and the shape 10 can be formed on the surface of the tab portion 223. The 4 degree formation of the hole 214 is thicker than the thickness of the coating cavity 214 formed on the surface of the product portion 224. According to such a configuration, the amount of shrinkage in the thickness direction of the thermosetting paint layer 221 formed on the surface of the product portion 224 is smaller than the amount of shrinkage in the thickness direction of the thermosetting paint layer 221 formed on the surface of the tab portion 223. The shrinkage of the thermosetting paint layer 221 formed on the surface of the 15 product portion 224 is not hindered. Further, the fin portion 223 may be provided outside the product portion 224. Therefore, the paint gate 244 is placed on the tab portion 223 so that the paint injection mark does not remain on the surface of the in-mold coated article 225. In the in-mold coating product forming apparatus of the second embodiment of the present invention, the sliding sleeves 211, 212 between the compressed 20 piece 204 and the outer peripheral plate 205 can be placed on the forming cavity face forming the molded article 222, that is, along the The cavity forming surface of the compression block 2〇4 of the cavity 213 is disposed. By this, when the compressed block is moved toward the coating film forming mold side with respect to the outer peripheral plate 2〇5, the thermosetting paint can be prevented from entering the sliding sleeves 211 and 212. 67 200930549 An embodiment of a more specific example of the second embodiment described above will be described below. [Example 5] An in-mold coating product was produced by using a mold-in-mold 5 including a mold 203 having a mold having a surface and a cavity inside, a surface forming mold 2〇1, and a coating film forming mold 2〇2. 225. The inner molding die 203 to be used includes a mounting plate 206 to which the compression block 2〇4 can be fixed, and a coil spring 207 between the outer circumferential plate 205 and the mounting plate 2〇6. The coating film forming mold 202 is a one having a built-in paint injection unit 242 and having a paint gate 244. Further, the sliding sleeve 211 which is formed between the compression block 204 and the outer peripheral plate 205 is disposed along the cavity forming surface of the compression block 204 which is formed into the molding cavity 213 of the 10-shaped product 222. A mold 203 is formed in one of the molds 203 which is fixed to the inside of the mold 203 which is fixed to the rotary disk 34 of the movable platen 32 of the injection molding machine 124, and is formed with respect to the same mold temperature. After the mold 201 is formed on the surface of the mold to form a mold cavity 213, the heat-resistant ABS resin which has been heated and melted is filled into the mold cavity 213, and after cooling for 40 seconds, the mold 203 is opened. Thus, the molded article 222 having a rectangular parallelepiped shape having a length i〇〇mm, a length of 50 mm, and a height of 3 mm is in a state in which the mold 203 is held inside. Next, the mold 203 for holding the inside of the molded article 222 is rotated by 180 degrees, and the 2 〇 surface of the molded article 222 which holds the mold 203 therein is switched (exchanged) into a cavity, and the shape is 100.5 mm in length and 50.5 in length. Mm, height 3.2 mm and mold temperature set at 1〇5. (: The coating film forming mold 2〇2 is opposed to each other, and the inside forming mold 203 and the coating film forming mold 202 are closed, and the coating cavity 214 is formed between the molded product 222 and the coating film forming mold 202. Secondly, 'Injecting a thermosetting coating (manufactured by Nippon Paint Co., Ltd. 200930549 7 7 8000 viscosities 3000 mPa · s) into the coating cavity 214, and moving the movable disk in the mold closing direction at the same time as the injection is completed, and is thermosetting. The coating is pressed and held for 40 seconds to cure the thermosetting coating. When the thermosetting coating is pressurized, the thermosetting coating does not invade the sliding sleeve between the compression block 2〇4 and the outer peripheral plate 2〇5 5 . In the step 211, the in-mold coating article 225 in which the thermosetting coating layer 221 is integrally coated on the molded article 222 is obtained by opening the coating forming die 202 (see Fig. 24). The obtained in-mold coating article 225 is obtained. [Embodiment 6] The molded article 222 is composed of a tab portion 223 and a product portion 224, and is formed to be formed in the product portion in addition to the thickness of the coating cavity formed on the surface of the tab portion 223. 224 surface coating cavity thickness is not more than the implementation In the same manner as in Example 5, the in-mold coated article 225 is obtained by cutting the tab portion 223 with the paint injecting mark (see Fig. 24). The compression of the thermosetting coating layer 221 is not hindered, and the obtained is obtained. In the first embodiment and the second embodiment, in order to smoothly and automatically perform a series of steps of the manufacturing method, as shown in Fig. 26, it can be constructed. The control device 1000 is controlled by the control device 1000. For example, in the first embodiment, the control device 1000 may be configured to form a rotating 20 disk rotating device 122R, an injection molding machine 124, and a thermosetting paint injection device 125. (coating machine 41) and mold temperature adjusting machines 111, 112, 113, and controlling individual operations and successive series of operations. Further, in the second embodiment, control device 1000 can also be configured to perform connection. The mold closing mechanism 121, 122, 123, the rotary disk rotating device 12211, 69 200930549, the injection molding machine 124, the thermosetting paint injection device 125 (paint injection machine 241), and the mold temperature adjustment The machines ill, 112, and 113 control the individual operations and the continuous series of operations. Further, the configuration or the modification of any of the above various embodiments and the modifications 5 can be combined as appropriate. Industrial Applicability The method for producing an in-mold coating product and the in-mold coating product forming device of the present invention are used when a mold is formed and a coating film is formed to form a mold. The cavity is completely free of gaps and can be fixed with a strong mold closing force. Therefore, even if a high-pressure injection thermosetting paint does not need to open the mold surface, the thermosetting paint does not leak from the coating cavity, and No coating in the mold - the so-called excellent effect of the burrs caused by the thermosetting coating layer, - for the communication equipment such as mobile phones, electronic information equipment, home appliances, 15 parts, automotive interiors It is useful in some parts or in the manufacture of molds such as interior decorations. The present invention has been described with reference to the preferred embodiments of the present invention, and various modifications and changes can be made by those skilled in the art. It is to be understood that such modifications and variations are intended to be included within the scope of the present invention as defined by the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1A is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold article according to a third embodiment of the present invention. 70 200930549 Fig. 1B is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold article according to a first embodiment of the present invention. Fig. 1C is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold article according to a first embodiment of the present invention. 5 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold article according to a first embodiment of the present invention. Fig. 1E is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold article according to a first embodiment of the present invention. Fig. 1F is a cross-sectional view showing the steps of a method of manufacturing the in-mold coated article 10 according to the first embodiment of the present invention. Fig. 1G is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold article according to a first embodiment of the present invention. Fig. 1H is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold article according to a first embodiment of the present invention. Fig. 2A is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 2B is a plan view showing the steps of the method for producing a mold-in-mold according to the first embodiment of the present invention. Fig. 2C is a cross-sectional view showing the steps of the method for producing the in-mold coating of the first embodiment of the present invention. Fig. 2D is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 2E is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. 71 200930549 Fig. 2F is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating material according to the first embodiment of the present invention. Fig. 2G is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. 5 Fig. 2H is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating material according to the first embodiment of the present invention. Fig. 3A is a plan view showing the steps of the method for producing a mold-in-mold according to the first embodiment of the present invention. Fig. 3B is a cross-sectional view showing the steps of the method for producing the in-mold coating of the first embodiment of the present invention. Fig. 3C is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. Fig. 3D is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 3E is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating material according to the first embodiment of the present invention. Fig. 3F is a cross-sectional view showing the steps of the method for producing a mold-in-mold according to the first embodiment of the present invention. Fig. 3G is a cross-sectional view showing the steps of the method for producing the in-mold coating of the first embodiment of the present invention. Fig. 3H is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. Fig. 4A is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. 200930549 Fig. 4 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 4C is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. 5 10 15 10 20 Fig. 4D is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating material according to the first embodiment of the present invention. Fig. 4 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 4F is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. Fig. 4G is a cross-sectional view showing the steps of the method for producing a mold-in-mold according to the first embodiment of the present invention. Fig. 4 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 5 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 5 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 5C is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. Fig. 5D is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 6 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. 73 200930549 Fig. 6B is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating material according to the first embodiment of the present invention. Fig. 6C is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating of the first embodiment of the present invention. Fig. 6D is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 6E is a cross-sectional view showing the steps of the method for producing a mold-in-mold according to the first embodiment of the present invention. Fig. 6F is a cross-sectional view showing the steps of the method for producing the in-mold coating of the first embodiment of the present invention. Fig. 6G is a cross-sectional view showing the steps of the method of manufacturing the article in the above-described first embodiment of the present invention. Fig. 6 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 7 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 7B is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 7C is a cross-sectional view showing the steps of the method for producing the in-mold coating of the first embodiment of the present invention. Fig. 7D is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 7E is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. 74 200930549 5 Fig. 7F is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating of the first embodiment of the present invention. Fig. 7G is a cross-sectional view showing the steps of the method for producing the in-mold coating material according to the first embodiment of the present invention. Fig. 7 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the first embodiment of the present invention. Fig. 8 is a schematic view showing a method of producing a mold-in-coat article according to the first embodiment of the present invention and a paint injector for use in a mold-in-mold coating product forming apparatus. Fig. 9 is a cross-sectional view showing the method of manufacturing the in-mold coating according to the first embodiment of the present invention, in order to obtain the in-mold decorative article and to draw a cross-sectional view of the sheet. Fig. 10 is a cross-sectional view showing the in-mold coating of the in-mold coating which is obtained by the method for producing an in-mold coating according to the first embodiment of the present invention. Ο Fig. 11 is a cross-sectional view showing the steps of a conventional method of manufacturing a coated article in a mold. Fig. 11 is a cross-sectional view showing the steps of the above-described conventional method of manufacturing a coated article in a mold. Fig. 11C is a cross-sectional view showing the steps of the above-described conventional method of manufacturing a coated article in a mold. Fig. 11D is a cross-sectional view showing the steps of the above-described conventional method of manufacturing a coated article in a mold. Fig. 12 is a cross-sectional view showing the steps of the manufacturing method of the mold in the mold of the second embodiment of the present invention. Fig. 12B is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 12C is a cross-sectional view showing the steps of the method for producing the in-mold coating of the second embodiment of the present invention. Fig. 12D is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 12E is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 12F is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 12G is a cross-sectional view showing the steps of the method for producing the in-mold coating of the second embodiment of the present invention. Fig. 13 is a cross-sectional view showing the steps of the method for producing the in-mold coating of the second embodiment of the present invention. Figure 14 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 15 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 16 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 17 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Figure 18 is a cross-sectional view showing the steps of the method of manufacturing the in-mold coating of the second embodiment of the present invention. Fig. 19 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. 5 Ο 10 15 ❹ 20 Fig. 20 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Figure 21 is a cross-sectional view showing the steps of a method of manufacturing a mold-in-mold according to the second embodiment of the present invention. Fig. 22 is a plan view showing the steps of the method for producing a mold-in-mold according to the second embodiment of the present invention. Fig. 2 is a schematic view showing a method of producing a mold-in-coat article according to the second embodiment of the present invention and a paint injection machine used in the in-mold coating product forming apparatus. Fig. 24 is a cross-sectional view showing the in-mold coated article obtained by the method for producing an in-mold coating according to the second embodiment of the present invention. Figure 25 is a cross-sectional view showing the steps of a conventional method of manufacturing a coated article in a mold. Fig. 25 is a cross-sectional view showing the steps of the above-described conventional method of manufacturing a coated article in a mold. Fig. 25C is a cross-sectional view showing the steps of the above-described conventional method of manufacturing a coated article in a mold. Fig. 25D is a cross-sectional view showing the steps of the above-described conventional method of manufacturing a coated article in a mold. Fig. 26 is a block diagram showing the relationship between the method of manufacturing the in-mold coated article of the first and second embodiments of the present invention and the control of the in-mold coating product forming apparatus of the present invention 77 200930549, the driving device, and the like. . [Description of main component symbols] l···Surface forming mold 3l···Fixed disc 2...Coating film forming mold 32...The movable disc 3...The inside of the movable mold 3...The movable disc rotating shaft 4...The first inner forming mold 34...Rotating disc 5...The second inner forming mold 41...the paint injection machine 6···the mold closing mold 42...the paint injection unit ll···the molding cavity 43...the coating tank 12...the first forming cavity 71...formed and formed at the same time Sheet 13...second forming cavity 72...base sheet 14...coating cavity 73...release layer 15...first coating cavity 74...peeling layer 16...second coating cavity 75".painting upper layer 2l ··· thermosetting coating layer 76...staggered layer 22...molded article 77...adhesion layer 23...first molded article 78...replicated layer 24...second molded article 1U,112,113···mold temperature adjusting machine 25... In-mold coatings m, 122, 123... closing mechanism 26... first in-mold coating 122R... rotating disk rotating device 27···24th inner coating 124... injection molding machine 28·· ·In-mold painting and painting 125... thermosetting coating injection device

78 200930549 201···surface forming mold 202...coating film forming mold 203...forming mold 204 therein...compression block 205...outer peripheral plate 206...mounting plate 207...coil spring 211...slip sleeve 212...slip sleeve 213···forming mold Hole 214...coating cavity 22l·.. thermosetting coating layer 222...molding article 223...protrusion portion 224...product portion 225...in-mold coating article 241...coating injector 242...coating injection unit 243...painting tank 244... paint gate 79

Claims (1)

200930549 X. The scope of application for patents: 1. The manufacturing method of the molds in the molds, the molds, the table (4) the molds and the paint ships 1 into the molds, and the molds for forming the molds in the molds. By the following steps: #埶5 shape: a layer of carbon thermosetting coating layer-body is formed on the inside of the hole to form a mold between the mold and the surface forming mold; (9) filling the forming tree material into the forming cavity and making it Cooling and solidifying to form the molded article (10), wherein the inner mold forming mold and the surface forming mold are opened in a state in which the inner mold is formed to hold the molded product; (iv) forming a mold opposite to the surface from the front surface forming mold The state is switched to a state in which the mold is formed to face the coating film forming mold, and (V) the mold forming mold of the molded article and the coating film forming mold are closed, and the molded article and the coating are applied to the molded article. Forming a mold cavity for coating the molded article with a thermosetting paint between the film forming molds; and 2(vi) the aforementioned thermosetting paint Into the mold cavity and curing the coating. 2. The method for producing an in-mold coating according to the first aspect of the invention, wherein the thermosetting coating used in the step (vi) contains an oligomer containing an acrylic acid group or an unsaturated polyester resin. And a single-liquid type coating of an organic peroxide initiator having a cross-linking efficiency of 8 in combination with any of the above-mentioned components: 200930549^. 3. The manufacturing method of the in-mold coating of the patent application No. 2 or 2, 5 〇 10 15 ❹ wherein the thermosetting coating (4) is coated and cured in the above (10) frequency The thickness of the thermosetting coating layer is 10 to 100 &quot; m. 4. In the case of applying for the patent Gu Di丨 or the manufacturing method of the money in the mold of the two items, wherein the former miscellaneous mold and the above-mentioned table_the opposite direction of the tilting are switched to the inside forming mold and the coating film forming mold pair In the state of the orientation, the rotatable movable disk to which the injection molding machine for forming the mold is fixed is rotated, and the surface forming mold facing the inside molding mold is exchanged to form the coating film forming mold. 5. The method of manufacturing a mold inner coating product according to the scope of the patent application, wherein a state in which the mold is formed opposite to the surface forming mold is switched from the inside forming mold to the front side forming mold and the coating medium forming mold. In the state, the rotatable movable disk to which the surface forming mold and the coating film forming mold are fixed is rotated, and the surface forming mold facing the inside forming mold is exchanged to form the coating film forming mold. 6. The method of manufacturing an in-mold coating according to the fourth aspect of the invention, wherein the inner forming mold comprises an i-th inner forming mold and a second inner forming mold, and simultaneously forming the mold using the two inner portions. The steps (i) to (1) in which the mold is formed on the surface and the surface are formed, and the steps (v) to (vi) are described before the mold is formed using the mold and the coating film. 7. If the scope of the patent application is i 哎 哎 从 从 ( ( 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四When the mold is formed in the opposite direction to the coating film forming mold, the front surface and the surface of the coating film are formed to have a surface and a surface, respectively, and the inner mold is formed by the inner mold. In the state of the shape of the cavity, the root is formed by the rotation, and the inside of the mold is changed, and the inside of the watch is exchanged to form the mold into the mold forming mold by the mold forming the surface opposite to the inside of the machine. 8. The manufacturing method of the in-mold coating product according to the first or second aspect of the patent scope, wherein the front-facing (four) into the wealth (four) the opposite-shaped rolling knife is replaced with the inner forming mold and the coating film forming mold And the mold for forming the inner surface is disposed between the surface forming mold and the other tree, and the inner mold is formed in a state in which the surface has a shape capable of forming a cavity, and the inner surface of the mold is formed by the rotation. The surface forming tool is opposed to the coating film forming mold, and the surface forming mold which is opposed to the above-mentioned middle (four) is exchanged to form the coating film forming mold. 9 . The method of manufacturing a molded article of the first or second item, wherein a state in which the mold is formed opposite to the surface forming mold is switched from the inside to the inside forming mold and the aforementioned coating forming mold In the opposite state, the in-mold coating mold further includes a mold for the mold and the surface-shaped yarn is transferred to the mold to be used in a mold. 82 200930549 5 == face forming mold and the mold for closing mold And forming a mold with the surface described above and the state of the coating-forming mold by rotating the front surface of the mold, and forming the mold with the inner surface or the mold for the mold: = opposite surface Forming a mold Si 刖 film forming mold T eye seeking range ❹ 10 15 10 20 method m 1 <manufacturing method of the inner coating of the cooker' is more on the same table (4). FI is formed before formation. * A k becomes /. At the same time, the surface of the aforementioned forming edge and the surface of the above-mentioned molded article were formed. The manufacturing method of the in-mold coating product of the application scope of the patent scope, ^ is formed between the coating film forming mold and the inner-shaped spacer, and the sheet is formed while forming the thermosetting coating layer. At the same time, the film is integrated. 12·—A mold forming device for forming a mold, comprising: a mold for painting a mold in a mold, comprising a mold for forming a mold, a surface forming mold and a coating film; and a mold closing mechanism, wherein the mold is formed in the mold Forming a mold with the foregoing surface to mold and mold, and forming the mold and the mold forming mold to mold and mold the mold; ▲ switching mechanism, by moving the mold to form the mold or forming the surface The mold and the lacquering mold move, and the state in which the stalk forming mold and the surface forming mold face each other are switched to a state in which the inner forming mold and the coating film forming mold are opposed to each other; 83 200930549 Shuyue S injection machine, a resin is injected into the forming cavity formed by forming the mold and the surface forming mold to form a molded article; and the coating injection machine is formed by injecting a thermosetting coating into the inner shape forming mold and the coating film forming mold. The formed mold cavity is cured and cured, and the thermosetting paint layer is integrally coated with the molded article. 13. The in-mold coating product forming apparatus according to claim 12, wherein the inner forming mold has a first inner forming mold and a second inner forming mold. The in-mold coating product forming apparatus according to claim 13, wherein the switching mechanism includes a rotating disk that supports the first inner mold and the second inner mold, and the rotary disk Rotating, in the first inner mold forming mold and the second inner mold forming mold, the mold is located at a position facing the surface forming mold, and at least one of the molds 15 is located opposite to the coating film forming mold. Positioning, and rotating the rotating inner disk to exchange the second inner forming mold with the second inner forming mold, thereby forming a mold for each of the first inner mold and the second inner mold The aforementioned surface forming mold is exchanged with the aforementioned coating film forming mold. The method of manufacturing the in-mold coating according to the first aspect of the invention, wherein in the step (vi), the thermosetting coating material is injected into the coating cavity and is pressurized at the same time as the end of the injection. The injected thermosetting coating material is then solidified, whereby the thermosetting coating layer is integrally coated on the molded article. The method of manufacturing a mold-in-coat article according to the fifteenth aspect of the invention, wherein the molded article has a tab portion and a product portion, and the step is formed in the step The thickness of the coating cavity on the surface of the tab portion is formed to be greater than or equal to the thickness of the coating die formed on the surface of the product portion. [817] The in-mold coating forming device of the invention, wherein the inner forming mold comprises a shrinking block, and is located around the dust shrinking block The sheet injection machine injects the thermosetting coating into the coating cavity and then "injects," and "bundles" simultaneously, and the compressed block is opposed to the outer periphery by the closing operation of the movable disk of the aforementioned mechanism. The plate is moved toward the coating film forming mold side to pressurize the injected thermosetting coating material, and f is disposed in the coating film forming mold and is temperature-adjustable, and the K coating injection machine does not allow the heat to be applied. A thermostat that hardens the hardenable coating. 18: The product in the mold of the 17th item of the patent range, wherein the sliding sleeve between the block and the outer peripheral plate is disposed along a cavity forming surface which forms the aforementioned compressed block of the cavity. 19.·申申:: In the mold of item (4) of the profit range, the mold formed in the description of the inside of the mold has the mold formed in the first (1) and the mold formed in the second inner portion. 2. :, in the manufacturing method of the in-mold coating of the 15th or 16th item, in the step (vi), when the thermosetting coating is injected, the '', the mold is eight' and At the same time as the end of the injection, the pressure has been injected 85 200930549 5 10 15 when the thermosetting coating is formed, the mold is formed in the foregoing, and the outer peripheral plate is located on the outer peripheral plate of the front (four) shrinking block. In the above (1) and (4), the inner mold is formed and the surface mold is formed between the outer peripheral plate and the surface forming mold before the front mold is formed in the front surface. And in the step (iii), the foregoing molded piece in which the mold is formed is held in a state in which the molded article is held, the inner mold is formed to form a mold with the surface, and the mold is formed in the step (V). In the above-mentioned product, a mold and a coating film forming mold are formed, and the molded article H is molded by the thermosetting paint to form the mold and the coating film forming mold. Between the outer peripheral plates, in the step (10), the heat-curing material is injected into the coating cavity and the end of the injection: at the same time, the compressed block is moved toward the coating film forming mold side with respect to the front material peripheral plate. 〇 二 、 ^ ^ ^ ^ ^ ^ 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已 已The method wherein, in the step (vi), the bone sleeve is configured to "form" the cavity forming surface of the aforementioned molding cavity of the molded article of the molded article between the compressed block and the outer peripheral plate In this case, the thermosetting coating material is injected into the coating cavity in the above-mentioned fine product. The manufacturing method and system of the in-mold coating product of the patented Fan Yuan. When the mold is formed in a state in which the mold is formed in the opposite direction to the surface forming mold, and the mold forming mold and the coating film forming mold pair 20 200930549 are formed, the surface forming mold and the coating film forming mold are formed. Alternatively, the movable disk of the injection molding machine in which the mold is formed in the above or the rotary disk mounted on the movable disk is rotated, and the surface forming mold which is formed opposite to the inside of the mold is switched to the coating film forming mold 5 23. The method of manufacturing an in-mold coating according to claim 15 or 16, wherein the inner forming mold has a first inner forming mold and a second inner forming mold, and simultaneously forming the mold using the two inner portions. In the one of the crucibles, the steps (1) to (ii) of forming the mold and the surface are formed, and the steps of forming the mold by using the other mold and the coating film to form the mold are the steps (v) to (vi). 24. The method of manufacturing an in-mold coating according to claim 15 or 16, wherein in the step (vi), the thermosetting coating is injected into the coating cavity and solidified. The thickness of the aforementioned thermosetting 15 coating layer formed is 10 to 300 #m. 〇 87