TW200536482A - Harmful insect controlling agent, powdery insecticide preparation and behavior disturbing agent for isopods - Google Patents

Harmful insect controlling agent, powdery insecticide preparation and behavior disturbing agent for isopods Download PDF

Info

Publication number
TW200536482A
TW200536482A TW93137109A TW93137109A TW200536482A TW 200536482 A TW200536482 A TW 200536482A TW 93137109 A TW93137109 A TW 93137109A TW 93137109 A TW93137109 A TW 93137109A TW 200536482 A TW200536482 A TW 200536482A
Authority
TW
Taiwan
Prior art keywords
oil
insecticidal
agent
pest control
control agent
Prior art date
Application number
TW93137109A
Other languages
Chinese (zh)
Inventor
Tatsuei Ito
Toshiya Matsui
Hajime Tamura
Hiromitsu Adachi
Yuko Sato
Original Assignee
Earth Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Earth Chemical Co filed Critical Earth Chemical Co
Publication of TW200536482A publication Critical patent/TW200536482A/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12Powders or granules
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/22O-Aryl or S-Aryl esters thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Toxicology (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates an insect pest control agent capable of effectively controlling insect pests living outdoors through the sustaining effect of behavior disruptive agent, which enhances the efficiency of contact of insecticide with insect pests such as isopods living outdoors, thereby attain highly effective extermination even the insecticidal powdery formulation containing a low concentration of insecticidal component can exert excellent quick-acting capability; and a behavior disruptive agent that can induce disruption of behavior, such as behavior of scrambling out, to force isopods out of a space under stone, etc. The invention provides an insect pest control agent which is characterized by mixing of a powder containing an insecticidal component with a particulate containing an insect pest behavior disruptive agent, and an insecticidal powdery formulation which is characterized in that an insecticidal component in the state of being dissolved in a solvent of extremely low volatility is present on a powder surface, and furthermore, provides an isopod behavior disruptive agent which is characterized in that an ethereal oil from plant and/or flagrance component thereof is contained as an active ingredient.

Description

200536482 九、發明說明: 【發明所屬之技術領域】 本發明關於適用於防除棲息於野外之害蟲之害蟲防除 劑’更詳細地,本發明關於藉由使害蟲之行動攪亂劑之效 果持久,從而可以有效地防除棲息於野外之害蟲。 本發明還關於速效性優異之殺蟲粉體狀製劑。 本發明進一步關於使單孔目等之等足類誘使爬出行動 (驅逐效果)等之行動攪亂劑。 【先前技術】 為了防除單孔目和潮蟲亞目等棲息於野外之害蟲,將含 有权**成分之殺蟲粉劑散佈到地面。 J而由於所使用之殺蟲成分對害蟲有驅避效果,所以 可能得不到原本應有之殺蟲效果。 因此為了使害蟲與殺蟲成分更好地接觸,嘗試將誘引200536482 IX. Description of the invention: [Technical field to which the invention belongs] The present invention relates to a pest control agent suitable for controlling pests that inhabit in the wild. In more detail, the present invention relates to the effect of making the action of the pest disturbing agent lasting, so that it can Effectively control pests inhabiting the wild. The present invention also relates to an insecticidal powdery preparation having excellent fast-acting properties. The present invention further relates to action scramblers such as monopods to induce crawl-out actions (expulsion effect) and the like. [Previous technology] In order to prevent pests inhabiting the wild, such as monopods and sub-orders of algae, spread insecticide powder containing the right ingredient to the ground. J. Because the insecticidal ingredients used have a repellent effect on pests, the insecticidal effect originally expected may not be obtained. Therefore, in order to better contact the pests with the insecticidal components, try to attract

等(例如,特開2002_326903號公報)。 百滅寧以外, 等(例如,特j 另方面,除了蟑螂以外’藏在陰影位置且難以與殺蟲 98009 200536482 劑接觸之害蟲中;^一 _ I胃 ^ 虿 疋早孔目等之等足類。等足類大容 藏在野外之石頭下 夕 蟲,所以呈有Γ 蟲劑難以較好地接觸害 m :=Γ提高驅除效果等問題。然而,雖然上述 細_等對蟑螂顯示出特別有效之作用,作曰 未知為可對等足類產生行動攪亂之物質。 仁疋 另外’已知藉由使用特定之殺蟲成分作 速效地擊倒宝蟲而A 乃欢风刀月b ° 仃救触之殺蟲粉劑(例如,朱昭日本特 開2001-199813號公報)。 …、、、日本特 然而’在現有之殺蟲粉劑中,由於殺蟲效 成分之濃度,所以在极、、曲择:* 依賴於叙虫虫 在低/辰度下速效性有減弱之趨勢。 因此,本發明之第一目的係為了提高棲息於野外 於殺蟲劑之接觸效率,從 口 半從而更有效地驅除害蟲, 動攪亂劑持續效果,而处古4 果“有效地防除棲息於野外之害蟲之 害蟲防除劑。复今,担糾 &amp; ^ 拴供一種即使殺蟲成分為低濃度也能 , 钆政性之权触粉體狀製劑。然後,為了將等 足類從石頭下等趕出,而担 提仏月b誘使等足類爬出行動等 動攪亂之行動攪亂劑。 【發明内容】 本毛月者們為了實現上述目的,經過認真研究之结果, =藉由將害蟲之行動攪亂劑搭載在固體載體上而成 :為粒 L:使害蟲之行峨劑之效果持久,藉由將該粒 有殺蟲成分之粉體混合而散佈,可以提高害蟲之 防除效果。而且,藉由將将* 猎由將救轴成分以溶解於特定溶劑中之 悲子在於粉體表面,可以得到具有速效性之殺蟲效果, 98009 200536482 再藉由使用具有植物精油和/或其香氣成分,發現可以對等 足類誘發所期望之行動攪亂,從而完成本發明。 即本發明包含以下害蟲防除劑、殺蟲粉體狀製劑及等 足類行動攪亂劑。 人(1) 一種害蟲防除劑,其特徵為使含有殺蟲成分之粉體與 含有害蟲行動攪亂劑之粒狀體混合而成者。 (2) 如上述(1)記載之害蟲防除劑,其特徵在於:粒狀體含 有害蟲行動攪亂劑和固定劑。 (3) 如上述(1)或(2)記載之害蟲防除劑,其特徵在於:粒狀 體之含ϊ為該粒狀體與粉體之總量之〇1〜3〇重量%。 (4) 如上述(丨)〜(3)任一項記載之害蟲防除劑,其特徵在 於:可以藉由目視識別粉體與粒狀體。 (5) 如上述(1)〜(4)任一項記載之害蟲防除劑,其特徵在 於:殺蟲成分係以溶於難揮發性溶劑之狀態而存在於粉體 表面。 (6) 如上述(5)記載之害蟲防除劑,其特徵在於:殺蟲成分 在溶解前之狀態下為固體。 (7) 如上述(1)〜任一項記載之害蟲防除劑,其特徵在 於:行動攪亂劑含有植物精油和/或其香氣成分作為有效成 分,且對等足類有效。 (8) 如上述(7)記載之害蟲防除劑,其特徵在於:植物精油 和/或其香氣成分為選自冬青油、雜薰衣草油、檸檬草油、 茶樹油、肉桂油、決明子油、水揚酸曱酯、L-香芹酮和肉 桂醛組成之群中之1種或2種以上。 98009 200536482 (9) -種殺蟲粉體狀製劑’其特徵在於:殺蟲成分係以溶 解於難揮發性溶劑之狀態而存在於粉體表面。 (10) -種等足類之行動㈣劑,其特徵在於·含有植物 精油和/或其香氣成分作為有效成分。 【實施方式】 本發明之害蟲防除劑係將含有殺蟲成分之粉體於含有害 *虫行動擾亂切(以下’簡稱為&quot;行動授遵L劑&quot;)之粒狀體混合而 成。 含有殺蟲成分之粉體’例如’可以如下得到··在砂磨機 中,將殺蟲成分、無機粉體、黏合劑混合後,根據需要加 入適量增量劑混合’使所得之混合物藉由過篩而除去粒子 與垃圾後作為預混合物,脾甘 將其在適量之增量劑中稀釋混合 ::::此時’也可以使用於溶劑一 ^ 且=!=中使用之殺蟲成分,可以為對所期望之害蟲 除广合物4,例如’可以使用天然除蟲菊醋、 赛:普寧、福塔盧寧、亞減寧、反式福多寧、烈 / U等、石夕芬寧、d,d_T99_石夕芬寧、 芬普洛斯、希福寧、代塔滅寧、必芬寧、芬巴特 为日帕令、希普歐芬、滅芬寧、普托寧、、s_18 、 等之η亞二 基甲酸酷系化合物;甲基嚼二嗤 地耐福:等tr物;醯胺福馬特等之續醯胺系化合物; 蘭專之類煙酸系化合物;馬普寧、幽普寧、。比琳普 98009 200536482 羅芬等之昆蟲成長控制化合物;克芬比、芬普尼、S-1991 (住 友化學工業社製造),也可以使用此等物質之異構體,衍生 物等。其中,為了可以速效地擊倒棲息於野外之各種害蟲, 可以使用具有優異殺蟲效果之安丹。此等物質可以使用i 種也可以將2種以上混合使用,相對於害蟲防除劑之總量 (即’含有殺蟲成分之粉體與含有行動攪亂劑之粒狀體之總 量)為0.01〜15重量%,較佳為0el〜1〇重量。/❶,相對於害蟲防 除劑之總量亦可考慮調整粉體添加量。 另外,如果使含有該殺蟲成分之粉體之粒徑小於丨〇〇網 目’則可以提高與害蟲之接觸頻率,所以殺蟲效果優異, 較佳。 另外,殺蟲成分以溶於難揮發性溶劑之狀態存在於粉體 表面’在使用時’粉末整體可以為濕潤之狀態。所述之上 述濕潤狀態,例如,可以列舉,在濾紙中(Ν0·2)散佈少量油 溶性色素(Plast Blue 8540 ;有本化學社製造),在其上放置 搭載有約3 g本發明之製劑之濾紙(No.2),觀察放置24小時 後前述色素之溶解、發色;或者在搭載本發明之製劑之濾 紙上轉印色素之狀態。由此,係為了將殺蟲成分覆蓋在粉 體表面,而且為了使殺蟲成分長時間存在,且蟲子無論接 觸製劑之何處殺蟲成分也可以起作用。此處,如果使用安 丹等固體殺蟲成分,則可以顯著地發揮本發明之效果,所 以較佳。本發明又關於以上述狀態將殺蟲成分搭載於載體 上之殺蟲粉體狀製劑。 上述殺蟲成分相對於本發明之殺蟲粉體狀製劑總量,較 98009 -10- 200536482 更佳為0. 〇 5〜2重量%。 佳為使用0.01〜5重量〇/〇 ^作為本發明之殺蟲粉體狀製劑中使用之難揮發性溶劑, 較佳為在常溫、常壓條件下難以揮發、且對所使用之殺蟲 成分有作為溶劑功能之物質。例如,可以列舉聚氧乙烯基 油烤㈣等非離子型界面活性劑,·肉豆謹酸異丙基醋等脂 肪酸m等烴,·癸二酸二辛基醋等二元酸醋等,也可 以將1種或2種以上混合使用。另外,脂肪酸醋、煙、二元 酸醋由於為疏水性,所以在野外使用的情況下有利。 、相對於本發明之製劑之總量,難揮發性溶劑之用量較佳 為0.1〜10重置%,更佳為〇.5〜6重量藉由使難揮發性溶劑 之用量在該範圍内’可以在上述情況下使用時,良好地保 持在濕潤狀態下。另外’如果不足〇.1重量%,則各粉體難 以被溶於難揮發性溶劑形成之殺蟲成分覆蓋❶如果大於ι〇 重量%,則製劑中容易產生粒子等,在製造上、使用上有 問題,所以不佳。 另一方面,含有行動攪亂劑之粒狀體係藉由浸潰、吹附 等將行動攪亂劑搭載在固體載體上,再經過製粒、粉碎等, 知到所期望之粒狀體。在本發明之害蟲防除劑中,所述之 粒狀體包含粉體、顆粒、粉末、微細粒子等形狀,如果使 其粒徑可以藉由1〜100網目篩網,則可以充分保留行動攪亂 劑,所以較佳。而且,在將行動攪亂劑保留在載體上直到 飽和之情況下,相對於害蟲防除劑總量,該粒狀體之用量 可以為0.1〜30重量%。 作為行動攪亂劑可以使用植物精油和/或其香氣成分。可 98009 -11 - 200536482 以使用,例如,白扁柏油 油、松葉油、於技4 , 柏油、檜油、翌檜油、岩柏 油、㈣悉 岡松油、松油、夕…、“Etc. (for example, Japanese Patent Application Laid-Open No. 2002_326903). In addition to Baifening, etc. (For example, in addition to the special cockroaches, in addition to cockroaches, the pests are hidden in the shadow and difficult to contact with the insecticidal agent 98009 200536482; ^ 一 _ I stomach ^ 虿 疋 Early boreholes, etc. Isopods are large enough to hide in the wild under the stone, so there is a problem that it is difficult for Γ insecticides to contact well and harm m: = Γ to improve the repellent effect. However, although the above-mentioned fine _ etc. show a special effect on cockroaches The effective effect is known as a substance that can cause action disturbance to the equivalent foot species. In addition, 疋 is also known to use a specific insecticidal ingredient to quickly knock down treasure insects and A is Huan Feng Dao Yue b ° 仃Rescue insecticide powder (for example, Zhu Zhao Japanese Patent Laid-Open Publication No. 2001-199813) .... ,,,, Japan. However, in the existing insecticide powders, due to the concentration of the insecticidal effect components, the Qu Zhe: * Depends on the tendency of the parasites to decrease the fast-acting ability at low / catch levels. Therefore, the first object of the present invention is to improve the contact efficiency of insecticides inhabiting the wild, which is more effective from the mouth. Repels pests in the ground Fruit, while the ancient 4 fruit "effectively control insect pests inhabiting wild insects. Reintroduction, rectification & ^ Tethered to a powder even if the insecticidal ingredients are low concentration, the right to touch the powder Then, in order to drive the isopods out of the stone, etc., they will be used to disturb the actions of the isopods to induce the crawling out of the isopods. [Summary of the invention] In order to achieve this, As a result of careful research on the above purpose, = by mounting the action disturbing agent of the pest on a solid carrier: granules L: making the effect of the insect agent's eel agent lasting. The powder is mixed and dispersed, which can improve the pest control effect. In addition, by dissolving the ingredients of the rescue shaft and dissolving the sorrow in a specific solvent on the surface of the powder, a fast-acting insecticidal effect can be obtained. 98009 200536482 By using plant essential oils and / or aroma components, it is found that the desired action can be disturbed by the equivalent foot species, thereby completing the present invention. That is, the present invention includes the following pest control agents, insecticide powder preparations and Foot action disturbance agent. Human (1) A pest control agent, characterized by mixing powder containing insecticidal ingredients with granules containing action insect disturbance agent. (2) As described in (1) above The insect pest control agent is characterized in that the granular body contains a pest action disturbing agent and a fixing agent. (3) The insect pest control agent according to the above (1) or (2), wherein the granular body contains maggots of: The total amount of the granules and the powder is 0.001 to 30% by weight. (4) The pest control agent according to any one of the above (丨) to (3), characterized in that the powder can be visually recognized (5) The pest control agent according to any one of (1) to (4) above, wherein the insecticidal component exists on the surface of the powder in a state of being dissolved in a hardly volatile solvent. . (6) The pest control agent according to (5) above, wherein the insecticidal component is solid in a state before being dissolved. (7) The pest control agent according to any one of (1) to (1) to (1), characterized in that the action disturbance agent contains a plant essential oil and / or an aroma component thereof as an effective ingredient and is effective for the equivalent foot class. (8) The pest control agent according to (7) above, wherein the plant essential oil and / or its aroma component is selected from the group consisting of wintergreen oil, miscellaneous lavender oil, lemongrass oil, tea tree oil, cinnamon oil, cassia oil, and water. One or more of the group consisting of salicyl acetate, L-carvone and cinnamaldehyde. 98009 200536482 (9)-A kind of insecticidal powder preparation 'is characterized in that the insecticidal component exists on the surface of the powder in a state of being dissolved in a hardly volatile solvent. (10) A kind of action tincture of the foot type, characterized in that it contains plant essential oil and / or its aroma component as an active ingredient. [Embodiment] The pest control agent of the present invention is obtained by mixing a powder containing a pesticidal component with a granular body containing a pest action disturbance cut (hereinafter referred to as "action action compliance agent L"). The powder containing the insecticidal ingredient 'for example' can be obtained as follows: In a sand mill, after mixing the insecticidal ingredient, the inorganic powder, and the binder, add an appropriate amount of an extender as needed to mix it, so that the resulting mixture can be obtained by After sieving to remove particles and garbage as a premix, spleen is diluted and mixed in an appropriate amount of extender :::: At this time, it can also be used as the insecticidal ingredient in solvent ^ and =! =, It can be used to remove the complex 4 from the desired pest, for example, 'Natural pyrethrum can be used, Sai: Puning, Fortalunin, Attenin, Trans-Fudonin, Lie / U, etc., Shi Xifen Ning, d, d_T99_ Shi Xifenning, Finpross, Sifonning, Detamuning, Bifennin, Finbart are Riparin, Shipufen, Mifenning, Putonin, s_18 , Etc. η-diene carboxylic acid cool compounds; methyl chexamidine dinaphthol: etc. TR; amines fumarte and other sulfonamides; nicotinic acid compounds such as orchid; Mapunin, Youpuning . Billing's 98009 200536482 Insect growth control compounds such as Rofin; Kefenbi, Fempney, S-1991 (manufactured by Sumitomo Chemical Industries, Ltd.). Isomers and derivatives of these substances can also be used. Among them, in order to quickly knock down various pests inhabiting the wild, andan with excellent insecticidal effect can be used. These substances can be used in i type or in combination of two or more types. The total amount of the pest control agent (that is, the total amount of the powder containing the insecticidal component and the granule containing the action disturbance agent) is 0.01 ~ 15% by weight, preferably 0el to 10% by weight. / ❶, relative to the total amount of pest control agents can also consider adjusting the amount of powder added. In addition, if the particle size of the powder containing the insecticidal component is smaller than the OO mesh ', the frequency of contact with the insects can be increased, so the insecticidal effect is excellent, which is preferable. In addition, the insecticidal component is present on the surface of the powder in a state of being dissolved in a hardly volatile solvent. 'In use,' the entire powder may be in a wet state. The above-mentioned wet state includes, for example, a small amount of an oil-soluble pigment (Plast Blue 8540; manufactured by Chem. Co., Ltd.) is dispersed in a filter paper (N0 · 2), and about 3 g of the preparation of the present invention is placed thereon. Filter paper (No. 2), and observe the dissolution and color development of the aforementioned pigments after being left for 24 hours; or the state of transferring the pigments on the filter paper on which the formulation of the present invention is mounted. This is because the insecticidal component is coated on the surface of the powder, and the insecticidal component is kept for a long time, and the insecticidal component can function regardless of where the insect touches the preparation. Here, it is preferable to use a solid insecticidal component such as andan because the effect of the present invention can be significantly exhibited. The present invention also relates to an insecticidal powdery preparation in which the insecticidal component is mounted on a carrier in the above-mentioned state. 〇 5〜2 重量 %。 The insecticidal component relative to the total amount of the insecticidal powder preparation of the present invention, more preferably than 98009 -10- 200536482 is 0. 〇 5 ~ 2 wt%. It is preferable to use 0.01 to 5 weight 0 / 〇 ^ as the hardly volatile solvent used in the insecticidal powdery preparation of the present invention, preferably it is difficult to volatilize under normal temperature and pressure conditions, and the insecticidal component used is A substance that functions as a solvent. For example, non-ionic surfactants such as polyoxyvinyl oil roasted tincture, hydrocarbons such as fatty acids m such as myristic acid isopropyl vinegar, dibasic acids such as dioctyl sebacate, and the like One type or two or more types can be mixed and used. In addition, fatty acid vinegar, tobacco, and dibasic acid vinegar are advantageous for use in the field because they are hydrophobic. With respect to the total amount of the preparation of the present invention, the amount of the hardly volatile solvent is preferably 0.1 to 10% by reset, and more preferably 0.5 to 6 weight by making the amount of the hardly volatile solvent within this range. When used under the above conditions, it is well maintained in a wet state. In addition, if it is less than 0.1% by weight, it is difficult for each powder to be covered with an insecticidal component formed by dissolving in a volatile solvent. If it is more than ι0% by weight, particles and the like are easily generated in the preparation. There is a problem, so it is not good. On the other hand, in a granular system containing a mobile scrambler, the mobile scrambler is mounted on a solid carrier by impregnation, blowing, etc., and then granulated, pulverized, etc., to obtain a desired granular body. In the pest control agent of the present invention, the granular body includes powder, granules, powder, fine particles and other shapes. If the particle size can be passed through a 1 to 100 mesh screen, the action disturbance agent can be fully retained. , So better. Moreover, in the case where the action disturbing agent is left on the carrier until it is saturated, the amount of the granules may be 0.1 to 30% by weight relative to the total amount of the pest control agent. As a disturbance agent, a vegetable essential oil and / or an aroma component can be used. May 98009 -11-200536482 for use, for example, white tar tar oil, pine leaf oil, Yuji 4, tar, tartar oil, tartar oil, rock tar tar, azalea oil, pine oil, evening…

油知油、香柏木油、丁香頁必4A 迷叠香油、桂皮油、香葉天竺二、、柏二宜丁香油、桂油、 玫瑰木油、氣尾草油、松油、^ /由、山倉子油、 薄荷油”卜油、香户…油、春黃菊油、 呼薄$ 香知油、歐薄荷油、決明子油、 44何油、八角菌香油、茶樹油 ^ 夂音、辇始&amp; 丁才豕草油、雜薰衣草油、 、月/ 4植物精油,α _蒎 箱品醇^、”口」 ㈠品醇、々 檸檬稀、按油醇、薄荷醇、、广㈣、杜松稀、掉腦、 ,,.^ ^ /二一 v v、檜烯、曰扁柏醇、 :J、皮醛、沈香醇、笨甲醇、L-香序酮、香茅、水 價值等植物精油的香氣成分。也可以將此等物質的! 種或2種以上混合使用。 此等物質對等足類特別有效。本發明又關於含有此等植 物精油和/或其香氣成分為有效成分之等足類行動攪亂 劑。此處所述之等足類行動攪亂係指誘使等足類從石頭下 等爬出之行動(驅逐效果),誘使在向石頭等前進途中回頭向 反方向前進等U形轉動行動,阻止從石頭下爬出後再返回石 頭下等之再進入,或者阻止在石頭下等長時間逗留之定點 行動等。 在本發明之害蟲防除劑中,相對於害蟲防除劑之總量, 行動攪亂劑之含量為〇.〇1〜2〇重量%,較好為〇〇5〜1〇重量 % ’可以考慮粒狀體相對於害蟲防除劑總量之添加量,以 及相對於行動攪亂劑之载體之搭載量而調整行動攪亂劑之 -J2- 98009 200536482 含量。 在前述植物精油和/或香氣成分中,為了誘使爬出行動, 例如’可以使用綠薄荷油、薄荷油、水揚酸甲酯、苯乙醇、 橙化醇、萜品醇、苯甲醇。 /外’為了誘使定點阻礙,例如,可以使用冬青油、雜 薰衣草油、擰檬草油、茶樹油、八角菌香油、水揚酸甲酯。 此外,為了誘使U形行動,例如,可以使用肉桂油、冬青 油、決明子油、薄荷油、綠薄荷油、茶樹油、迷迭香油: 才*油L•香芹酮、肉桂駿、水楊酸甲酯。 其中,特佳為使用可以誘使所有行動攪亂之水揚酸甲酯。 作為用於本發明之害蟲防除劑、殺蟲粉體狀製劑或者等 足類之行動㈣劑中使用之固體載體,可以使用,例如, 滑石、蠟石、陶土、碳酸鈣、膨潤土、矽石、長石、含水 二氧化矽、酸性黏土、矽藻土粉末、輕石粉末、沸石、放 射鈉沸石等礦物質粉末;木屑、穀物澱粉、絲綢粉末等動 物飼料粉末;葡萄糖、蔗糖、乳糖等糖類;碳酸鈉、硫酸 鈉、氣化鉀、硫酸銨、硝酸銨、磷酸銨等無機鹽類;纖維 素、吸油性聚合物、其他各種高分子化合物等有機粉末等。 此體可以使用i種或2種以上。其中,在粉體中,從難 以飛散、不溶於雨水等,較佳為礦物質粉末,特佳為滑石、 黏土、矽石、長石、陶土…卜,作為在害蟲防除劑中用 於含有行動攪亂劑之粒狀體,由於矽藻土燒結體、沸石 放射鈉沸石等吸油性優異,所以較佳。作為吸油性,可以 為1 %以上,較佳為3%以上。 98009 -13- 200536482 本發明之等足類杆叙坡&lt; ^ 仃動祝亂劑除了使用上述固體载 體而形成粉劑或顆粒劑等製 饈戰 rt、栌盤 ^外,逛可以使用水、醇類、 戍烷類、石蠟類、二醇類 予親 化氣、壓縮氣體等之Χ使用液 液劑、1丨H 、 形成氣霧劑、泵式喷霧劑、 ^ Μ 礼劑、塗布劑等製劑。 劑她旦/ 而且,在製劑中,相對於製 Μ總里,行動攪亂劑 辰 Λ , 1Λ^ 3里為0·〇5重量%以上,更佳Λ 〇 · 1〜10重量。/。。 又住马 在上述行動攪亂劑中,如φ m ^ W 4dr 併用固定劑’則害蟲的行動 攪亂效果持久,所以較佳。 m 酸 辛酯、己二酸二異壬基 作為固定劑可以使用癸 S旨、己二酸二辛酯等二元酸 -- 乙二醇等多㈣,十六燒醇、二丙:%、二乙二醇、二 gt , ^ 肉丑蔻醇、異丙烯醇等低級 酉予正構石臘烴、石蠟等繇栌咕從 ^ ^ 凡蛭專。此等物質可以使用1 種也可以將2種以上混合使用, 0.5M0倍量。 帛彳目對於行_亂劑,使用 另外’在害蟲防除劑中, ^ 讲触L 4 馬了使行動攪亂劑搭載於固體 載體上後進行塗布’如果使用石蠟 ★,Λ/τ 卞/、旋* 3予、界面活性 劑#’則由於可以得到適當 揮發與持純,所以較佳。 二卜’如果含有殺蟲成分之粉體與含有行動卿之粒 狀體可以目視識別殺蟲成 ^ 則了以备易地確認行動攪亂 之政佈狀&quot;以較佳。例如,可以使兩者在色調、大 小、形狀以及此4之組合且右 ^ 00 . . ^ ,、有差”。另外,只要能得到本 &quot;明之害蟲防除劑即可,並不限於上述製造方法。 在本毛月之害蟲防除劑、殺蟲粉體狀製劑或等足 98009 -]4- 200536482 類行動授亂劑中,根據需要還可以適當添加以下所示之添 加劑。例如,添加m-甲苯甲酸' 富馬酸、胡椒基酸、掉腦 酸、水楊酸、笨甲酸、苯乙酸、山梨酸、酒石酸、肉㈣ 等殺蟲成分之穩定劑;P0E院基喊、_脂肪㈣等界面活 性劑;乳酸醋、聚乙烯基料烧嗣、碳酸丙二醋等溶解助 背J,胡椒基丁醚、N-辛基二環庚烯二羧醯胺(MGK264)、1,广 氧基二[2,3,3,3_四氯丙燒](S421)等增效劑;羊毛脂等展開 劑;水揚酸苯酉旨、經基二苯甲g同等紫外線吸收劑;bha、 BHT等抗氧化劑;石夕油等疏水劑;多_、甲基丙稀酸月桂 酉曰等除臭^ ’綠色標記類香料、水果標記類香料等香料。 本發明之害蟲P方除劑和等足類行動搜亂冑,例如可以對 早孔目、潮蟲亞目、千足蟲、百足蟲、娱虫公、^ λ、犧、 换蛛等棲息於野外之等足類等害蟲有用。本發明之殺蟲粉 體狀製劑還可以對蟑螂等害蟲有用。而且,在使用時,可 以以平面狀、線狀、點狀適量地散佈到土壤或地板下。此 外’行動攪亂劑之用量較佳為〇 · 1 g/m2以上。 &lt;實施例&gt; 實施例1 虫製備表1中記載之害蟲防除劑。含有實施例1中使用之殺 蟲成分之粉體使用1〇〇網目之物質,含有行動攪亂劑(水: 酸甲酯)之粒狀體使用5·5網目之物質。將约化所製備之各製 劑分別均勻地在直徑1〇〇mm之玻璃皿中展開,之後不加蓋 之條件下放置24小時。之後,使用氣相色譜分析各 ^中之行動授乱劑之量。然後’相對於行動授亂劑之初 98009 -15- 200536482 ) 期值計鼻出殘留率(% 成分 粉 體 安丹 ^~— \WfW^ &quot;Oil, oil, cedar oil, clove page 4A rosemary oil, cinnamon oil, gerbera oleander, cypress oil, cinnamon oil, rosewood oil, sage oil, pine oil, ^ / by, Shancangzi oil, peppermint oil "Bu oil, Kato ... oil, chamomile oil, Huhu $ fragrant oil, European peppermint oil, cassia oil, 44 He oil, octagonal sesame oil, tea tree oil ^ 夂 音, 辇 始 & Dingcai yarrow oil, mixed lavender oil, 月 / 4 plant essential oil, α _ 蒎 box alcohol ^, "mouth" ㈠ 品 alcohol, 々 lemon dilute, press oil alcohol, menthol, patchouli, juniper The aroma of plant oils such as dilute, diminished, ^^^ / bi-vv, limonene, lindenyl alcohol,: J, cortex, agarol, benzyl alcohol, L-xianganone, citronella, water value, etc. ingredient. You can also use one or more of these substances! These substances are particularly effective for isopods. The present invention also relates to a foot-action disturbing agent containing such plant essential oils and / or its aroma components as active ingredients. The isopod action disruption mentioned here refers to the action of enticing the isopod to crawl out from under the stone (expulsion effect), induce the U-turn action such as turning back in the opposite direction while advancing to the stone, etc., to prevent Climb out of the stone and then return to the stone and wait to enter again, or prevent fixed-point actions such as staying under the stone for a long time. In the pest control agent of the present invention, the content of the action disturbing agent is from 0.01 to 20% by weight, preferably from 0.05 to 10% by weight relative to the total amount of the pest control agent. -J2- 98009 200536482 content of the action disturber with respect to the total amount of the pest control agent and the amount of the carrier of the action disturber. Among the aforementioned plant essential oils and / or aroma components, in order to induce crawling action, for example, 'mint oil, peppermint oil, methyl salicylate, phenylethanol, orange alcohol, terpineol, and benzyl alcohol can be used. In order to induce fixed-point obstruction, for example, holly oil, miscellaneous lavender oil, lemongrass oil, tea tree oil, octagonal sesame oil, and methyl salicylate can be used. In addition, in order to induce U-shaped actions, for example, cinnamon oil, holly oil, cassia oil, peppermint oil, green peppermint oil, tea tree oil, rosemary oil: only oil * carvone, cinnamon, salicylic acid Acid methyl ester. Among them, it is particularly preferable to use methyl salicylate which can induce all actions to be disturbed. As the solid carrier used in the pest control agent, insecticidal powder preparation or the like action tincture of the present invention, for example, talc, waxite, clay, calcium carbonate, bentonite, silica, Mineral powder such as feldspar, hydrous silica, acid clay, diatomaceous earth powder, pumice powder, zeolite, radioactive zeolite; animal feed powder such as wood chips, grain starch, silk powder; sugars such as glucose, sucrose, lactose; carbonic acid Inorganic salts such as sodium, sodium sulfate, potassium gasification, ammonium sulfate, ammonium nitrate, and ammonium phosphate; organic powders such as cellulose, oil-absorbing polymers, and various other polymer compounds. This body can be used in i or two or more kinds. Among them, in powder, it is difficult to scatter, insoluble in rainwater, etc., preferably mineral powder, especially talc, clay, silica, feldspar, pottery clay, etc., as a pest control agent for containing action disturbance Granules of the agent are preferred because they have excellent oil absorption properties such as diatomaceous earth sintered bodies, zeolites, and sodium zeolites. The oil absorption may be 1% or more, and preferably 3% or more. 98009 -13- 200536482 In addition to using the above solid carrier to form powders or granules, the equivalent foot rod pole slope of the present invention &lt; Alcohols, pinanes, paraffins, glycols, pre-affinity gases, compressed gases, etc. Use liquid and liquid agents, 1H, aerosol-forming agents, pump sprays, ceremonial agents, coating agents And other preparations. In addition, in the preparation, the action disturbing agent Chen Λ, 1 Λ ^ 3 is more than 0.05% by weight, and more preferably Λ 〇 · 1 to 10% by weight relative to the total preparation. /. . In the above-mentioned action disturbing agent, if φ m ^ W 4dr is used in combination with a fixing agent, the action of the pest disturbing effect is long-lasting, so it is preferable. m Octyl acid and diisononyl adipate can be used as fixatives. Dibasic acids such as decyl succinate and dioctyl adipate-polyfluorene such as ethylene glycol, cetyl alcohol, dipropyl:%, di Lower grades such as ethylene glycol, two gt, myristyl alcohol, isopropenyl alcohol, and so on are paraffin paraffin, paraffin, and so on. These substances can be used singly or in combination of two or more. The amount is 0.5M0 times. For the chaos agent, use another "In the pest control agent, ^ touch L 4 horses and apply the action scrambler on a solid carrier and apply it." If paraffin is used, Λ / τ 卞 /, spin * 3 予 , surfactant # 'is better because it can get proper volatilization and purity. "If the powder containing the insecticidal ingredient and the granules containing the action secretary can visually identify the insecticidal formation, then it is better to confirm the political shape of the action disruption". For example, you can make the two in the hue, size, shape, and combination of these 4 and right ^ 00.. ^, There is a difference. "In addition, as long as this &quot; mingling pest control agent can be obtained, it is not limited to the above manufacturing Method. In the insect pest control agent, insecticide powder preparation or isopod 98009-] 4-200536482 action disordering agent of this hair month, the following additives can be added as needed. For example, m- Toluic acid 'Fumaric acid, piperonic acid, cerebroic acid, salicylic acid, stearic acid, phenylacetic acid, sorbic acid, tartaric acid, carnitine, and other insecticidal ingredient stabilizers; P0E Academy base, _ fatty acid and other interfaces Active agent; lactic acid vinegar, polyethylene base, propylene carbonate, etc., dissolution aid J, piperonyl butyl ether, N-octyl dicycloheptene dicarboxamide (MGK264), 1, oxydiamine [2,3,3,3_tetrachloropropane] (S421) and other synergists; lanolin and other developing agents; salicylic acid, benzoic acid, and equivalent ultraviolet absorbers based on dibenzoyl g; bha, BHT, etc. Antioxidants; Hydrophobic agents such as Shixi oil; poly-, methacrylic lauric acid and other deodorants ^ 'Green-labeled perfume, water Marking spices and other spices. Pesticides and other isopods of the present invention can be used to search for crickets, for example, early holes, Hydroptera, Millipede, Millipede, Fungus, ^ λ, Sacrifice, It is useful to change spiders and other pests that inhabit in the wild, such as equipods. The insecticidal powdery preparation of the present invention can also be useful to pests such as cockroaches. In addition, it can be spread in a flat, linear, or dot-like manner during use. To the soil or the floor. In addition, the amount of the "action disturbing agent" is preferably 0.1 g / m2 or more. &Lt; Example &gt; Example 1 Insect preparation The pest control agent described in Table 1 is included. It is used in Example 1. For the insecticidal powder, use 100-mesh material, and for the granules containing the action disturbing agent (water: methyl acid ester), use the 5.5-mesh material. Unrolled in a glass dish with a diameter of 100 mm, and then left for 24 hours without a lid. After that, the amount of the action scrambling agent in each sample was analyzed by gas chromatography. 98009 -15- 200536482) Period value nasal residual rate (% An Dan body divided powder ^ ~ - \ WfW ^ &quot;

表中單位為重量% 留率 ^式驗結果記載於表2中。本發明之害蟲防除劑可以確認行動 攪^ Μ之殘留率(%)較高,害蟲之行動攪亂效果持久。特別 係藉由於倂用固定劑’可以大幅度地提高行動攪亂劑之殘 結果The unit in the table is% by weight. The retention rate is shown in Table 2. The pest control agent of the present invention can confirm that the residual rate (%) of the action disturbance is high, and the action disturbance effect of the pest is durable. Especially because the use of fixatives ’can greatly improve the residue of mobile disturbers.

Μ下,表示本發明之害蟲防除劑之製劑例 98009 16- 200536482 &gt;-9-^弇· t*% 鷂 粉體 J i 成分 固定劑 (癸二酸二異辛基酯) 固定劑 (己二酸二異丙基酯) 水揚酸曱酯 輕石(吸油率3%以上) 沸石(吸油率3%以上) 燒結矽藻土 (吸油率3%以上) 粦 石夕油 硬脂酸鎂 苯甲酸 必芬松夕、、7工 &gt; 千才&gt;) 曱基噁二唑(y卜丰寸&gt;^7、/ &gt;) 百滅寧 地耐福蘭(夕/于7予&gt;) 安丹 U) 〇 H-k b yi 〇 87.28 o U) o Ο s K) b 製劑例1 U) 〇 H-^ o Lh b 87.88 o Lo o ο •s K) b 〇 |製劑例2 b 一 o b 87.88 o U) o p •s K&gt; b ο •私 製劑例3 〇 1—^ b Lh Ο 87.88 o L) o •私 p s to b ο *4^ 製劑例4 Lk) 〇 h—k b 87.88 o L〇 o o s [Ό 〇 〇 *4^ 製劑例5 U) b H-* b ο b 82.88 o U) o •私 o •s to b 〇 •私 |製劑例6 I to ο o Η-^ Lh b 78.88 o L) o *4^ o s to o 〇 4^ [製劑例7 I -17-Below M, formulation examples of the pest control agent of the present invention 98009 16- 200536482 &gt; -9- ^ 弇 · t *% 鹞 powder J i component fixing agent (diisooctyl sebacate) fixing agent (hexane Diisopropyl diacid) Pyrite salicylate (more than 3% oil absorption) Zeolite (more than 3% oil absorption) Sintered diatomaceous earth (more than 3% oil absorption) Vermiculite oil magnesium stearate Bifensonate formate, 7G &gt; Chicai &gt;) Amidoxazole (y Bu Fenginch) ^ 7, / &gt;) Pirfenadine fulan (Yu / Yu 7yu &gt;) ) Andan U) 〇Hk b yi 〇87.28 o U) o 〇 s K) b Preparation Example 1 U) 〇H- ^ o Lh b 87.88 o Lo o ο • s K) b 〇 | Preparation Example 2 b a ob 87.88 o U) op • s K> b ο • Private preparation example 3 〇1— ^ b Lh 〇 87.88 o L) o • Private ps to b ο * 4 ^ Preparation example 4 Lk) 〇h-kb 87.88 o L〇 oos [Ό 〇〇 * 4 ^ Formulation Example 5 U) b H- * b ο b 82.88 o U) o • Private o • s to b 〇 • Private Example 6 I to ο o Η- ^ Lh b 78.88 o L) o * 4 ^ os to o 〇4 ^ [Preparation Example 7 I -17-

98009 200536482 實施例2 •試驗方法 在玻璃板(15 Cmxl5 cm)上畫直徑9 cm之圓,使用篩在其 中均勻地散佈約0.2 g表4記載之待試製劑。然後,在散佈之 位置上,罩上底部設置有開口之塑膠杯(2〇〇 ml),並使開口 向上,從前述開口放入10隻德國蟑螂。之後,計算隨時間 被擊倒之害蟲之數量,計算KT5〇(害蟲之5〇%被擊倒之時間 (分鐘))、ΚΤ90(害蟲之90%被擊倒之時間(分鐘))。重複進行 2次試驗,結果以其平均值表示。而且,待試製劑係將表巾譽 所示之殺蟲成分溶於溶劑後’加入滑石中均勾地混合、放 置24小時後使用。98009 200536482 Example 2 • Test method Draw a circle with a diameter of 9 cm on a glass plate (15 cm x 15 cm), and use a sieve to uniformly spread about 0.2 g of the test preparation described in Table 4 in it. Then, in the scattered position, a plastic cup (200 ml) with an opening at the bottom was set on the cover, and the opening was upward, and 10 German cockroaches were placed from the opening. After that, count the number of pests that were knocked down over time, and calculate KT50 (the time when 50% of the pests are knocked down (minutes)) and TK90 (the time that 90% of the pests are knocked down (minutes)). The test was repeated twice, and the result was expressed as an average value. In addition, the preparation to be tested was prepared by dissolving the insecticidal ingredient shown in the table towel as a solvent ', adding it to the talc, mixing it, and leaving it for 24 hours before use.

表中單位為重量% •試驗結果Units in the table are% by weight • Test results

試驗結果如表5所示,本發明之製劑(實施例㈣之 ΚΤ50、ΚΤ90均比比較例β早,即使殺蟲成分為低濃度,也 方面’在使用乙醇時(參考例Α), 由於乙醇揮發性較高’所以放置24小時後乙醇揮發,安丹 為結晶狀,並未發現擊倒害蟲數量提高。而且,在使用石夕 98009 -18 - 200536482 油時(芩考例B),由於不能溶解安 數量提高。 以發現擊倒之害蟲The test results are shown in Table 5. The preparations of the present invention (KT50 and KT90 of Example 均 are earlier than Comparative Example β). Even when the insecticidal component is at a low concentration, when using ethanol (Reference Example A), ethanol High volatility ', so after 24 hours of ethanol volatilization, Andan is crystalline, and no increase in the number of knockdown pests was found. In addition, when using Shixi 98009 -18-200536482 oil (Examination Case B), Dissolved amount increased to detect knockdown pests

實施例3 •試驗方法 -以表6中所記載之難揮發性溶劑代替實施例£之煤油,進 行與實施例2同樣之試驗。 •試驗結果 即使使用煤油以外之難揮發性溶 同樣地殺蟲成分在低濃度下,也 試驗結果如表6中所示 劑溶解安丹(實施例G〜J) 可以具有優異之速效性。 結果Example 3 • Test method-The hardly volatile solvent described in Table 6 was used instead of the kerosene of Example 1. The same test as in Example 2 was performed. • Test results Even if a volatile solvent other than kerosene is used, the same insecticidal ingredients are used at a low concentration. The test results are shown in Table 6. The agent dissolves andan (Examples G to J) can have excellent fast-acting properties. result

貫施例4 :爬出行動之评價 •試驗方法 ~ΚΤ90(^μΓ VL9~~一 ❿ ΊόΤ 在_ W之塑膠製容器中,全面鋪上約2 深之石夕藻 土 ’在其中央約3 cmx3 cm位置上設置多個石頭。接著,使 用喷霧器使土與石頭举卜士你 , 、 ^ 、碩木上水後,放入供試蟲(5隻潮蟲亞目 或5又單孔目)’在2 5 〇c之條件下放置到塑膠罩中。在^小 98009 - 19- 200536482 時後’可以確認所有的供試蟲都藏到石頭下,在其周圍撒 上約5g待試藥劑(浸潰1%表7所示行動攪亂劑之粉劑”確認 供試蟲是否爬出。 • 5式驗結果 爬出^隻,X表示i隻也沒有攸出。浸潰本發明之行動擾亂 劑之藥劑均誘使爬出行動。盆φ 山1丁勒共T,水杨酸甲酯之效果優異。 表7攸出行動之評價Implementation Example 4: Evaluation and Test Method of Climbing Action ~ KT90 (^ μΓ VL9 ~~ 一 ❿ ΊόΤ In a plastic container of _W, approximately 2 deep Shixue algae soil 'is placed in its center. Set multiple stones at 3 cmx3 cm position. Next, use a sprayer to apply soil and stones to the priests,, ^, and Shuki, and put them into the test insect (5 tide beetle or 5 and single) (Hole mesh) 'Placed in a plastic cover under the condition of 25.0c. After ^ 98009-19- 200536482 hours', you can confirm that all the test insects are hidden under the stone, and sprinkle about 5g around it Test agent (powder that impregnates 1% of the action scrambler shown in Table 7 "to confirm whether the test insect crawled out. • The test result of type 5 crawled out ^ only, X said that i only did not emerge. Action to impregnate the present invention The agents of the scrambler induce the action to climb out of the pot. The pot φ 1 is less than the total T, and the effect of methyl salicylate is excellent. Table 7 Evaluation of the action

實施例5 :定點阻礙之評價 •試驗方法 試驗結果如表7所記載。表中,〇表示攸出5隻,△表示 用丙酮分別將表8所干* 釋 ’、仃動攪亂劑稀釋到5%,製備稀Example 5: Evaluation of fixed-point obstruction • Test method The test results are shown in Table 7. In the table, 0 indicates that 5 were used, and △ indicates that the dry * release in Table 8 and the stirrer were diluted to 5% with acetone to prepare a thin solution.

梓液。另外,在不銹鋼P 戶约1 、為内(100 cmx50 cm)全面鋪上深 沒約1 cm之紅土,在苴 個位置上,放置约心葉:了^ 每處腐葉土用種類不同之所後’在母處腐葉土上,對 試蟲可以自由選擇前述、傷之行動授㈣浸潰,使供 為供試蟲之50隻潮蟲亞目:、之狀態。同時於其中放入作 又哪雜亞目盥 。 各種腐葉土中之供試蟲;/早孔目,調查2小時後藏入 數,將所得之值作為定㈣里’將該數量除以全部供試蟲 ‘” ;&lt; (%),從而求得定點率。試驗重 98009 '20、 200536482 複進行2次。 •試驗結果 試驗結果如表8所記載,藉由浸潰本發明之等足類行動攪 亂劑,可以抑制供試蟲對腐土葉之定點率,所以可以認為 係產生定點阻礙。其中,冬青油、雜薰衣草油、檸檬草油、 茶樹油、水楊酸甲酯效果優異。 表8定點阻礙之評價 供試藥劑 潮蟲亞目 單孔目 冬青油 0% 0% 雜薰衣草油 0% 0% 檸檬草油 0% 0% 茶樹油 0% 0% 水楊酸曱酯 0% 0% 八角茴香油 - 1-10% 香茅 1 〜10% - 綠薄荷油 1 〜10% - 決明子(力7シ十一)油 1 〜10% - 歐薄荷油 1 〜10% 香樟油 - 1 〜10% 夕口 7卜油 - 1 〜10% 薄荷油 - 10 〜20% 春黃菊油 1-10% 1 〜10% L-香芹酮 1 〜10% 1 〜10% r? U &gt; 夕°一油 1-10% 1 〜10% 松油 1-10% 1 〜10% 七彳^油 1-10% 1 〜10% 玫瑰木油 10 〜20% 1 〜10% 鳶尾草油 10 〜20% 1 〜10% 薰衣草油 10 〜20% 1 〜10% 香葉天竺癸油 10 〜20% 1 〜10% 桂皮油 10 〜20% 1 〜10% 迷迭香油 10 〜20% 1 〜10% 苯曱醇 20 〜30% 10 〜20% 桂油 30 〜40% 1 〜10% 丁香油 30 〜40% 20 〜30% 柏油 30 〜40% 10 〜20% 丁香葉油 30 〜40% 10 〜20% 沈香醇 30 〜40% 10 〜20%Zi fluid. In addition, the stainless steel P households are fully covered with red clay with a depth of about 1 cm, and the inner heart (100 cmx50 cm) is fully covered, and the heart leaf is placed in one position: ^ Each rotten leaf soil is of a different type. On the rotten leaf soil of the mother place, the test insects can freely choose the aforementioned and wounded actions to immerse and impregnate, so that the 50 insect moth suborders of the test insects are: At the same time put in it as a Zanziamite toilet. Test insects in various rotten leaf soils; / Early hole order, investigate the number of hidden insects after 2 hours, and use the value obtained in Dingzhang as 'divide the number by all test insects' "; &lt; (%), The fixed point rate was obtained. The test weight was 98009 '20 and 200536482 was repeated twice. • Test results The test results are as described in Table 8. By impregnating the isopod action disrupter of the present invention, the test insects can be inhibited against rotten leaves. It can be considered that there are fixed-point obstacles. Among them, holly oil, miscellaneous lavender oil, lemongrass oil, tea tree oil, and methyl salicylate are excellent. Table 8 Evaluation of fixed-point obstacles Perennial Holly Oil 0% 0% Mixed Lavender Oil 0% 0% Lemongrass Oil 0% 0% Tea Tree Oil 0% 0% Salicyl Acetate 0% 0% Star Anise Oil-1-10% Lemongrass 1 ~ 10 %-Green Peppermint Oil 1 ~ 10%-Cassia Seed (Force 7 Eleven) Oil 1 ~ 10%-European Peppermint Oil 1 ~ 10% Camphor Oil— 1 ~ 10% Xikou 7 Oil— 1 ~ 10% Mint Oil-10 ~ 20% Chamomile oil 1-10% 1 ~ 10% L-Carvone 1 ~ 10% 1 ~ 10% r? U &gt; Xi ° One oil 1-10% 1 ~ 10% pine oil 1-10% 1 ~ 10% Hepstick oil 1-10% 1 ~ 10% Rosewood oil 10 ~ 20% 1 ~ 10% Iris oil 10 ~ 20% 1 ~ 10% Lavender oil 10 ~ 20% 1 ~ 10% Geranium sesame oil 10 ~ 20% 1 ~ 10% Cinnamon oil 10 ~ 20% 1 ~ 10% Rosemary oil 10 ~ 20% 1 ~ 10% Phenyl alcohol 20 ~ 30% 10 ~ 20% Cinnamon oil 30 ~ 40% 1 ~ 10% Clove oil 30 ~ 40% 20 ~ 30% Asphalt 30 ~ 40% 10 ~ 20% Clove leaf oil 30 ~ 40% 10 ~ 20% Agarwood alcohol 30 ~ 40% 10 ~ 20%

98009 -21 - 200536482 柏木油 30-40% 桉油 40 〜50% 20% 夕4 A k 7卜油 60-70% 20 〜30% 桂皮醛 60^70% ^ ___30-40% 註)數值為定點率 實施例6 ·· U形行動之評價 •試驗方法 在200 ml之塑膠製容器内之側壁與側壁底部共2個位置 上,黏附直徑8 mm之濾紙,將其浸潰在}从表9所示之行動 攪亂劑中。接著,將2隻單孔目放入容器,觀察2分鐘内 形行動,計算驅避率(%)。試驗重複進行4次。❿且,此處 所述之丁動係指向前述渡紙前進之單孔目&amp;變方向而 向反方向前進之此等行動。 •試驗結果98009 -21-200536482 cypress oil 30-40% eucalyptus oil 40 ~ 50% 20% eve 4 A k 7 oil 60-70% 20 ~ 30% cinnamaldehyde 60 ^ 70% ^ ___ 30-40% Note) The value is fixed point Example 6 · Evaluation of U-shaped action • Test method At a total of 2 positions on the side wall and the bottom of the side wall in a 200 ml plastic container, a filter paper with a diameter of 8 mm was adhered and immersed in} from Table 9 Shows the action in a disturbing agent. Next, two monoculars were put into the container, and the shape action was observed within 2 minutes to calculate the repellent rate (%). The test was repeated 4 times. Moreover, the movement described here refers to such actions that the aforementioned single hole mesh &amp; change direction and advance in the opposite direction. •test results

98009 20053648298009 200536482

與實施例4之爬出行動之 载之試驗方法同樣地 n 為待试藥劑使用市售粉劑與在該粉劑中添 加1重量%水揚酸甲酿形成之粉劑(本發明)。另外,供試蟲 使用潮蟲亞目與單孔目各10隻。然後,撒播待試藥劑,: 36小時後,觀察在石頭外死亡之供試蟲之數量,計算出其 比例(%)。試驗重複進行2次。 '試驗結果 試驗結果如表10所記載,藉由使用含有本發明之行動授 亂劑之粉劑,在石頭外死亡之供試蟲增多,可以認為係水 楊酸甲酯誘使爬出行動等行動攪亂。另外,觀察從試驗開 始到12小時後,供試蟲之狀況,由於使用含有本發明之行 動攪亂劑之粉劑擊倒數量明顯增加,可以認為係與殺蟲劑 更良好地接觸所致。 表10殺蟲效果之評價 供試蟲 本發明 市售粉劑 單孔目 80 〜90% 20^40% '~- 潮蟲亞目 60% 20 〜40% 98009 -23- 200536482 雖然參照詳細且特定之實施方式對本發明進行說明,曰 是本領域技術人員應當瞭解,在不脫離 但 ^ t &amp; %之精神與範 圍之況下,可以進行各種改變和修正。 本申請係基於2004年5月10曰申請之日本專利申 願2_-139616),2_年5月1〇日中請之日本專利申:案特 願綱-㈣…與2004年5月21曰申請之曰本專利=牵 (特願2004-15 1341)而提出,在此處可月一 為參照。 引入以作 工業實用性 〇 本發明之害蟲防除劑由於可以使害蟲之行動授亂劑效果 持久’所以可以增大害蟲與殺蟲成分之接觸機會,從而可 以有效地防除棲息於野外之害蟲。 此外,即使殺蟲成分之濃度較低,可以使害蟲較早地被 擊倒而I揮出優異之速效性。前述效果在使用溶解前狀 態為固體之殺蟲成分時特別明顯。而且,亦可減少散佈時 之飛揚。 ^ 而且’藉由行動縣劑,可以使等足類誘使如下之行動· 授亂:誘使從石頭下攸出之行動(驅逐效果)、誘使U形行 動、阻礙再進入、阻礙定點行動等。而且’藉由與殺蟲劑 倂用’由於可以更好地與殺蟲劑接觸,從而提高驅除效果。 98009 -24-The test method is the same as that of the crawling action in Example 4. n A commercially available powder is used for the test agent and a powder formed by adding 1% by weight of salicylic acid to the powder (the present invention). In addition, 10 insects were used for the test insects, the suborder Aquimonida and the order Mona. Then, the test agent was broadcasted: 36 hours later, the number of test insects that died outside the stone was observed, and the proportion (%) was calculated. The test was repeated twice. 'Test results The test results are described in Table 10. By using the powder containing the action disordering agent of the present invention, the number of test insects that died outside the stone increased, and it was considered that methyl salicylate induced the action such as crawling out of the action. Disturb. In addition, from the beginning of the test to 12 hours, the condition of the test insects was observed, and since the number of knockdowns using the powder containing the action disturbance agent of the present invention was significantly increased, it can be considered that the contact with the insecticide was better. Table 10 Evaluation of insecticidal effects Test insects The commercially available powder of the present invention is a single-hole mesh 80 ~ 90% 20 ^ 40% '~-algae suborder 60% 20 ~ 40% 98009 -23- 200536482 Although detailed and specific The embodiments describe the present invention, that is, those skilled in the art should understand that various changes and modifications can be made without departing from the spirit and scope of ^ t &amp;%. This application is based on Japanese Patent Application No. 2_-139616 filed on May 10, 2004), and Japanese Patent Application filed on May 10, 2_: Case Special Application Outline -㈣ ... with May 21, 2004 This application is filed with Japanese Patent No. 2004-15 1341, which is hereby incorporated by reference. Introduced for industrial applicability 〇 The pest control agent of the present invention can make the action of insect pests long-lasting, so it can increase the chance of contact between pests and insecticidal ingredients, which can effectively control pests inhabiting the wild. In addition, even if the concentration of the insecticidal component is low, the insect pest can be knocked down earlier and I can produce excellent quick-acting properties. The aforementioned effect is particularly noticeable when an insecticidal component in a solid state before dissolution is used. It also reduces flying during dispersal. ^ Moreover, by acting the prefecture agent, the equivalent actions can induce the following actions: Instability: induce action from the stone (deportation effect), induce U-shaped action, prevent re-entry, hinder fixed-point action Wait. In addition, 'by using with insecticide' can improve the repellent effect because it can better contact with the insecticide. 98009 -24-

Claims (1)

200536482 十、申請專利範圍: 1. :::蟲防除劑,其特徵在於:係將含有殺蟲成分之粉 豆人s有害蟲行動授亂劑之粒狀體混合而成者。 2. 如清求項!之害蟲防除劑,其特徵在於:粒狀體含有害蟲 打動攪亂劑和固定劑。 3. 如:求項1或2之害蟲防除劑,其特徵在於··粒狀體之含量 為該粒狀體與粉體總量之0.1〜3〇重量〇/〇。 4. 如+請求項卜3中任一項之害蟲防除劑,其特徵在於:可以 藉由目視識別粉體與粒狀體。 5. 如請求項1〜4中任-項之害蟲防除劑,其特徵在於:殺蟲 成分係轉於難揮發性溶劑之狀“存在於粉體表面。 &amp; ^請求項5之害蟲防除劑’其特徵在於:殺蟲成分在溶解 剷之狀態下為固體。 7.如請求項Η中任-項之害蟲防除劑,其特徵在於:行動 攪亂劑含有植物精油和/或其香氣成分為有效成分,且對 等足類有效。 &amp;如請求項7之害蟲防除劑’其特徵在於:行動授亂劑之植 ,精油和/或其香氣成分為選自冬青油、雜薰衣草油、擰 檬草油、茶樹油、肉桂油、決明子(力y 十―)油、水楊 酸甲醋、香芽酮和肉桂I组成之群中之!種或2種以上。 9. 一種殺蟲粉體狀製劑’其特徵在於:殺蟲成分係以溶解於 難揮發性溶劑之狀態而存在於粉體表面。 10· -種等足類之行動授亂劑,其特徵在於:含有植物精油 和/或其香氣成分作為有效成分。 98009.doc 200536482 七、指定代表圖: (一) 本案指定代表圖為:(無) (二) 本代表圖之元件符號簡單說明: 八、本案若有化學式時,請揭示最能顯示發明特徵的化學式: (無) 98009.doc200536482 10. Scope of patent application: 1. ::: Insect control agent, which is characterized by mixing granules of powder containing insecticidal ingredients Peas-Man's pest control agent. 2. If you want to find items! The insect pest control agent is characterized in that the granular body contains a pest disturbing agent and a fixing agent. 3. For example, the pest control agent according to item 1 or 2, characterized in that the content of the granules is 0.1 to 30% by weight of the total amount of the granules and powders. 4. The pest control agent according to any one of the above claims, characterized in that powders and granules can be identified visually. 5. The pest control agent according to any one of claims 1 to 4, which is characterized in that the insecticidal ingredient is converted to a hardly volatile solvent and exists on the surface of the powder. &Amp; ^ The pest control agent according to claim 5 'It is characterized in that the insecticidal ingredient is solid in the state of dissolving the shovel. 7. The insect pest control agent according to any one of item Η in the claim, characterized in that the action disturbing agent contains plant essential oil and / or its aroma component is effective &Amp; The pest control agent of claim 7 is characterized in that the plant is an action scavenger, and the essential oil and / or its aroma component is selected from the group consisting of wintergreen oil, miscellaneous lavender oil, and lemon. Grass oil, tea tree oil, cinnamon oil, cassia seed (Li y ten-) oil, methyl salicylate, vanillone and cinnamon I! One or two or more. 9. An insecticidal powder Formulation 'is characterized in that the insecticidal component is present on the surface of the powder in a state of being dissolved in a hardly volatile solvent. 10 · -A kind of foot action disordering agent, characterized in that it contains plant essential oil and / or Aroma ingredients are used as active ingredients. 7. Designated representative map: (1) Designated representative map in this case is: (None) (2) Brief description of the component symbols of this representative map: 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: (None ) 98009.doc
TW93137109A 2004-05-10 2004-12-01 Harmful insect controlling agent, powdery insecticide preparation and behavior disturbing agent for isopods TW200536482A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2004139618 2004-05-10
JP2004139616 2004-05-10
JP2004151341 2004-05-21

Publications (1)

Publication Number Publication Date
TW200536482A true TW200536482A (en) 2005-11-16

Family

ID=35319960

Family Applications (1)

Application Number Title Priority Date Filing Date
TW93137109A TW200536482A (en) 2004-05-10 2004-12-01 Harmful insect controlling agent, powdery insecticide preparation and behavior disturbing agent for isopods

Country Status (3)

Country Link
JP (1) JP4278654B2 (en)
TW (1) TW200536482A (en)
WO (1) WO2005107458A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6001947B2 (en) * 2012-07-31 2016-10-05 アース製薬株式会社 匍匐 Pest control formulation and pesticidal method
JP6035078B2 (en) * 2012-08-07 2016-11-30 アース製薬株式会社 Method for producing a rosemary oil extract in which repellent components for at least one of polypods and mites are purified and concentrated

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5589201A (en) * 1978-12-28 1980-07-05 Nakanihon Koku Kk Vermin extermination and its device with aerial application or release of attractant and aerial dusting of insecticide
JP2551775B2 (en) * 1986-05-19 1996-11-06 武田薬品工業株式会社 Agrochemical solid formulation
JP3066664B2 (en) * 1991-04-05 2000-07-17 アース製薬株式会社 Pest disrupter
JP3556981B2 (en) * 1994-10-27 2004-08-25 フマキラー株式会社 Ant repellent
JP3909779B2 (en) * 1995-06-16 2007-04-25 アース製薬株式会社 Pest attracting method and pest controlling method
JP3772994B2 (en) * 1995-06-22 2006-05-10 バイエルクロップサイエンス株式会社 Pesticide granule for paddy field
JP2002060308A (en) * 2000-08-17 2002-02-26 Jukankyo Kojo Jumoku Seibun Riyo Gijutsu Kenkyu Kumiai Expelling and repelling agent of animal and pest insect, and gradual releasant
JP4614404B2 (en) * 2000-11-22 2011-01-19 フマキラー株式会社 Pest repellent and pest repellent method using the same

Also Published As

Publication number Publication date
JP4278654B2 (en) 2009-06-17
WO2005107458A1 (en) 2005-11-17
JPWO2005107458A1 (en) 2008-03-21

Similar Documents

Publication Publication Date Title
JP5840477B2 (en) Ant control agent
CN1322110A (en) Synergistic and residual pesticidal compositions contaiing plant essential oils
JPS62500935A (en) Long-acting pyrethrum/pyrethroid-based insecticide with added silicone stabilizer
JP2006516625A (en) Herbicidal composition containing clove oil
WO2015116801A2 (en) Compositions and methods for capturing, killing or repelling bed bugs
EP2315527A1 (en) Broad spectrum animal repellent and method
JP4813870B2 (en) 粉 Pest control powder
US20190327952A1 (en) Tick trap and method of trapping ticks
WO1987000728A1 (en) Acaricide
Perrin Improving insecticides through encapsulation
JP5638930B2 (en) Atsushi Kasukame attractant composition, sustained-release attractant and capture device
CN1953659A (en) Insect pest control agent, insecticidal powdery formulation and isopod behavior disruptive agent
TW200826841A (en) An agro-horticultural pesticidal composition
TW200536482A (en) Harmful insect controlling agent, powdery insecticide preparation and behavior disturbing agent for isopods
JP4901070B2 (en) Method for producing granular repellent
CN105530812A (en) Insect repellent and insect repelling method
KR20220100636A (en) Combination of phenothrine and pralethrine
JP2004196727A (en) Communication disruptive agent for trigonotylus caelestialium(kirkaldy)
TW200904327A (en) Rodent repellent and method for repelling rodents using the same
JP6539077B2 (en) German cockroach attractant preparation
CN105685083A (en) Health insecticidal composition containing meperfluthrin and fipronil
US20100304968A1 (en) process of manufacture for deer repellant, pest and rodent control, weed-killer, fungicide and insecticide, and combinations thereof in powder and liquid spray formulations
JP2005200394A5 (en)
JP3235911B2 (en) Pest repellent
RU2214093C2 (en) Preparation for protection against keratophages