TW200522875A - Method for processing aquatic products - Google Patents

Method for processing aquatic products Download PDF

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Publication number
TW200522875A
TW200522875A TW093137799A TW93137799A TW200522875A TW 200522875 A TW200522875 A TW 200522875A TW 093137799 A TW093137799 A TW 093137799A TW 93137799 A TW93137799 A TW 93137799A TW 200522875 A TW200522875 A TW 200522875A
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Taiwan
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aquatic products
fish
processing
pressure
scope
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TW093137799A
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Chinese (zh)
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Jinnai Hirofumi
Ikeda Tomohiro
Kunio Nonaka
Teruhisa Tateda
Atsuo Nakagawa
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Miyajima Shoyu Kk
Maruha Corp
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Publication of TW200522875A publication Critical patent/TW200522875A/en

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Abstract

Provided is a method for processing marine foods without damaging originally palatability and taste so that even their bones become eatable. Remove internal organs of a raw marine material, open it by cutting, washing the same with saline, dry the same under a reduced pressure, subsequently heat the same under pressure in a non-sealed packed state, ripen the same in a chilled state and freeze the same. The processed food can be directly subjected to secondary processing such as cooking, baking, frying.

Description

(1) (1)200522875 九、發明說明 【發明所屬之技術領域】 本發明係關於一種水産食品之加工方法,其係將用於 不損害以魚類爲主的各種水産品原來具有的食感和味道, 以至於骨頭都可食用且供於煮、烤、炸等食用之二次加工 ,可以按照常法進行二次加工。 【先前技術】 作爲連骨頭都可食用的水産加工品係經由殺菌釜(高 壓釜),經受1 00°c以上的濕熱加熱,以賦予商業上無菌性 的密封容器裝食品中,使用熱密封的容器製造的包覆了塑 膠膜和鋁箔的膜的所謂之殺菌(retort)食品(根據日本罐頭 協會的殺菌食品委員會的定義)。 但是,以往的加壓殺菌食品是在密閉包裝狀態下進行 處理,因此,無論何種食品材料都存在傾向於相同的食感 和味道的缺點。 爲了對此進行改進,一直以來提出了許多方法。例如 ,在專利文獻1中,揭示出在魚的側面設置乾燥的海藻片 ,將其裝在塑膠袋中,減壓密封,高溫加熱,冷卻而製得 魚的包裝體。但是,由於在密閉包裝狀態下對魚體進行殺 菌處理,因從魚體滲出的滴汁成爲水煮狀態,所以存在會 顯著損害外觀的問題。另外,將魚體密閉包裝在塑膠袋等 中進行殺菌處理時,在之後冷卻時,産生溫度差和壓力差 ,包裝袋就會膨脹,也存在魚體本身的形狀不完整的問題 -5- (2) (2)200522875 欲解決在該密閉包裝狀態下的殺菌處理伴隨而來的問 題,在專利文獻2中揭示出於非密閉包裝狀態下進行加熱 處理,處理時將從魚體滲出的滴汁與魚體分離,於維持魚 體本來的形狀的狀態下使其冷凍。但是,於該非密閉包裝 狀態下的殺菌處理本身需要過度處理,另外,由於魚香味 都作爲滴汁流出,會使味道變差,還由於殺菌處理後急速 冷凍,對魚體的損害大,因此存在只能得到與魚本來具有 的食感,味道完全不一樣的結果的缺點。 [專利文獻1]特開平1 1-346 722號公報 [專利文獻2]特開2002_335914號公報 【發明內容】 欲解決發明之課題 本發明欲解決之課題係製得到於以往之密閉包裝狀態 下處理得到的殺菌水産品在形態上、味覺上存在的缺點, 可以維持水産品本來具有的味覺且可以直接進行烤、煮、 炸等二次加工之水産食品。 本發明的特徵在於除去洗淨應當處理的水産品不必要 的部分後,減壓乾燥,減壓乾燥後於非密閉狀態加壓加熱 處理,分離排出從水産品滲出的滴汁,然後在冷卻溫度範 圍內熟化。 以下,以水産品爲魚體的情況爲例進行說明。 減壓乾燥處理係欲於冷凝原來的食感和味道的同時, -6 - (3) (3)200522875 調節水分的處理,於該減壓乾燥處理時,應當處理的水産 物是魚體時,除去魚鱗、內臟,根據竹莢魚、秋刀魚等産 品的最終形態,切開,直至切成魚片(中間切開)’將魚體 用7〜15%的食鹽水進行鹽水洗滌。 但是,過度的乾燥會喪失魚的汁液,故需要注意。該 減壓乾燥條件依據魚的種類而有些許不同,希望在8 6 · 1 -96.3kPa的減壓下,於25-35°C下進行60〜100分鐘。 減壓乾燥處理後的加壓加熱處理係將魚體於非密閉包 裝狀態下進行。其中所謂的非密閉包裝狀態係指不用塑膠 袋和金屬容器等密封魚體,加壓加熱處理時,從魚體滲出 的滴汁可與魚體分離而排出的狀態。 加壓加熱處理係將先施行了減壓乾燥處理的魚體於非 密閉包裝狀態下配置在加壓加熱處理裝置中,於該裝置內 封入加熱蒸汽。於加壓加熱處理裝置中,設置蒸汽導入排 出口和迴圈路線以使蒸汽均勻遍佈裝置全部。 加壓加熱處理的條件係只要魚體的骨頭部分變得十分 柔軟,可以將其連骨頭整個食用那樣的條件,就沒有特別 的限定,但也因魚體和魚的種類有所不同,例如,如果是 國產竹莢魚這樣的小型魚的話,於壓力68.6〜149.1kPa, 最佳爲 81.4 〜1 18.7kPa、溫度 1 05 - 1 20 °C,最佳爲 1 15-120 °C,於處理時間20-5 0分鐘下處理。 這樣,連骨頭部分一起食用時,可以製得極其良好的 食感。而且根據先前的條件,只要是減壓乾燥的魚體,即 使在加壓加熱處理後,也可以更好地保持魚體的形狀。 (4) 200522875 另外,在該加壓加熱條件下,由於爲非密閉容器包裝 狀態,雖然不能達到完全的殺滅菌,但附著在魚體上的細 菌數顯著減少,細菌數不會上升。 冷卻熟化係不會使加壓加熱處理的魚體受到損傷 '爲 了促進水分的均勻化和香味的冷凝的步驟。通常’最佳於 2-1 0°C的溫度範圍下冷卻3-9小時。經由該步驟,沒有進 一步使魚體有急劇的溫度變化,經過緩慢冷卻’組織損傷 少,於是在冷卻溫度範圍,可以促進水分緩慢的轉移和香 β 味的熟化。 然後,對冷卻熟化的魚體實施冷凍處理,優選盡可能 是急速冷凍,以便能夠保持整個魚體的形狀。例如,在1 小時以內冷凍,直至芯溫一 18〜一 25 °C爲好。 冷凍處理步驟後的魚體不會産生冷卻時的壓力差,可 以保持魚的形狀且使水分均勻化和香味熟化,在維持魚原 來的食感和味道的同時,於冷凍狀態下不解凍而經過烤、 炸、煮等二次加工以供食用。 β 可把以往作爲加工食品用是規格外,大部分用作飼料 或者一直廢棄處理的竹莢魚、蝶魚(比目魚的一種)、秋刀 魚、沙丁魚等小形水産品作爲食品材料,連骨頭一起美味 食用地加以有效利用。 另外’由於在加壓加熱處理步驟,對魚體施行充分的 高壓或加熱處理’所以二次加工時,無需充分升高魚體的 芯溫,也可以防止過度的加熱引起的過於焦糊和乾巴巴等 等。 -8- (5) 200522875 另外,如果經過真空包裝機包裝該二次加工品的話, 用微波爐或開水煮,可以製成容易連骨頭都可食用的烤魚 或煮魚。 另外,對於老人或孩子,也可以得到更安全、營養價 値也豐富、易於食用,特別是補鈣的水産加工品° 而且,在製造魚貝類加工品時,降低了切塊、去骨等 人力費用成本,去骨損失的精肉和暗色魚背上的肉等也可 供食用,作爲食品材料成品率提高。 鲁 可以大量地減少在以往成爲問題的在水産品一次加工 場産生的處理廢棄物量。 【實施方式】 以下,以實施例說明本發明的實施形態。但是,本發 明不受此等實施例的任何限定。 [實施例1] · 把北海道産的冷凍的秋刀魚作爲原料,將按照本發明 處理的實施例與在密閉包裝中進行加壓加熱處理的比較例 經由感觀試驗比較。 (實施例) 首先,將冷凍的秋刀魚除去魚鱗和內臟後,進行切開 加工’用鹽水洗淨後’作爲前處理,用減壓乾燥處理裝置 (阿思系統設計)’於9 1.2kPa的減壓下,於3 0。(:下減壓乾 -9 - (6) (6)200522875 燥處理70分鐘。接著,在加壓加熱處理裝置(三星股份有 限公司製作SCF120 10FVW)中設置90gcmxl00cm的不銹鋼 製的網,在該網上排列減壓乾燥處理的魚體,在蒸汽壓力 90.2kPa、溫度1 18°C下,處理20分鐘。在加壓加熱處理中 ,使從魚體滲出的滴汁流出到加壓加熱處理的下方。加壓 加熱處理後之秋刀魚於5°C x4小時的條件下,於冷卻熟化 後,急速冷凍。 (比較例) 與實施例一樣,進行切開加工,鹽水洗淨後,不進行 前處理的減壓乾燥處理,密閉包裝在耐熱性塑膠袋內,並 排列在相同的加壓加熱處理裝置內的不銹鋼製的網上,在 和實施例相同的條件下,加熱處理,冷卻熟化後,冷凍。 (比較評價) 用烤爐燒烤實施例和比較例各自的魚體的表面約3 0秒 ,分別評價食感和味道。結果表示於表1中。如該表所示 ,本發明的實施例的”秋刀魚”的外觀、形狀、味道、食感 都非常優異,就連在衛生方面,通常活菌數也爲3 00以下 (0),沒有問題。與此相反,比較例的’’秋刀魚"均爲水煮 狀態,難於保持其形狀。另外,即使進行烤等加工,魚原 來的食感和味道也都消失了。 (7) 200522875 【表1】 實 施 例 比 較 例 外 觀 沒 有 魚 肉 不 兀 整 、 破 碎 從 魚 體 滲出的 水 分 積 存 % 皮 剝 離 等 外 觀 上 大 的 在 容 器 內且通 過 加 熱 形 變 化 〇 成 者 的 狀態。 色 加 壓 引 起 的 白 色 部 分 j 形 成 和 水分一 起 煮 的 感 稍 微 有 點丨 變1 色爲茶色。 覺 , 明 顯和處 理 -1上 刖 的 外 觀 不 同 0 食 感 骨 頭 柔 軟 到 兀 全 不 用 擔 所 謂 的 π罐頭” 的 味 道 和 心 的 程 度 ° [ 肉質硬。 食 感 0 味 道 有 人 稍 微 感 到 加 壓 加 熱 所 謂 的 "罐頭” 的 味 道 和 臭 有 人 兀 全 沒 有 感 受 食 感 0 殺菌味 強 烈 〇 到 〇 細 菌數 3 00> (開 丨始 幾 乎 沒 有 )° 3 00> (開 丨始幾ΐ L沒 :有 〇 整 體 整 體 上 維 持 良 好 的 狀 態 隹 1、、 肉 不 完整且 呈 水 煮 狀 〇 態 〇(1) (1) 200522875 IX. Description of the invention [Technical field to which the invention belongs] The present invention relates to a method for processing aquatic food, which is intended to be used without damaging the original food texture and taste of various aquatic products including fish. Taste, so that bones are edible and used for secondary processing such as cooking, roasting, frying, etc., can be processed in accordance with common methods. [Prior art] Aquatic processed products that are edible even with bones are subjected to moist heat above 100 ° C through a sterilization autoclave (autoclave) to impart commercial sterility to hermetically sealed container-packed food. Containers are so-called retort foods, which are covered with plastic and aluminum foil films (as defined by the Japan Canned Food Association's Retort Food Committee). However, conventional pressurized sterilized foods are processed in a hermetically sealed package. Therefore, no matter which food material is used, they have the disadvantage that they tend to have the same texture and taste. In order to improve this, many methods have been proposed. For example, in Patent Document 1, it is disclosed that a dried seaweed sheet is provided on the side of the fish, which is packed in a plastic bag, sealed under reduced pressure, heated at high temperature, and cooled to obtain a fish package. However, since the fish body is sterilized in a hermetically sealed state, the dripping juice leaking from the fish body is in a boiled state, and there is a problem that the appearance is significantly impaired. In addition, when the fish body is hermetically packed in a plastic bag or the like for sterilization treatment, the temperature and pressure difference will occur when the fish body is cooled afterwards, and the packaging bag will swell, and the shape of the fish body itself is incomplete. -5- ( 2) (2) 200522875 In order to solve the problems associated with the sterilization treatment in this closed packaging state, Patent Document 2 discloses that heat treatment is performed in a non-closed packaging state, and dripping juice leaking from the fish body during processing Separate from the fish body and freeze it while maintaining the original shape of the fish body. However, the sterilization treatment in the non-closed packaging state itself requires excessive treatment. In addition, the flavor of the fish flows out as dripping juice, which will deteriorate the taste. It also has rapid damage after the sterilization treatment, which damages the fish body. The only drawback is that the result is completely different from the original texture and taste of the fish. [Patent Document 1] Japanese Unexamined Patent Publication No. 1 1-346 722 [Patent Document 2] Japanese Unexamined Patent Publication No. 2002_335914 [Summary of the Invention] Problems to be Solved by the Invention The problems to be solved by the present invention are processed in a conventional sealed package. The obtained sterilized aquatic product has shortcomings in form and taste. The aquatic food can maintain the original taste of the aquatic product and can be directly subjected to secondary processing such as roasting, cooking, and frying. The present invention is characterized by removing unnecessary parts of the aquatic product to be processed, and then drying under reduced pressure. After the reduced pressure is dried, the heat treatment is performed under pressure in a non-closed state, and the dripping juice leaking out of the aquatic product is separated and discharged. Ripening within range. In the following, the case where aquatic products are fish is used as an example. The reduced-pressure drying treatment is intended to condense the original food texture and taste, and at the same time -6-(3) (3) 200522875 is a treatment to adjust the moisture content. In this reduced-pressure drying treatment, when the fish product to be treated is fish, it is removed. Fish scales and offal are cut according to the final shape of horse mackerel, saury and other products until cut into fish fillets (cut in the middle). The fish body is washed with 7 to 15% saline. However, excessive drying will lose fish juice, so you need to be careful. The reduced-pressure drying conditions are slightly different depending on the type of fish, and it is desirable to perform the reduced pressure drying at 8 6 · 1 -96.3 kPa at 25-35 ° C for 60 to 100 minutes. The pressure heating treatment after the reduced-pressure drying treatment is performed in a non-hermetically packed state. The so-called non-hermetic packaging state refers to a state in which the fish body is not sealed with a plastic bag, a metal container, or the like, and dripping juice leaking from the fish body can be separated from the fish body and discharged during the pressure heating treatment. The pressure heating treatment is a method in which the fish body subjected to the reduced pressure drying treatment is placed in a non-hermetically packed state in a pressure heating treatment device, and heating steam is sealed in the device. In the pressurized heat treatment device, a steam introduction and discharge port and a loop path are provided so that the steam is evenly distributed throughout the device. The conditions of the pressure heating treatment are not particularly limited as long as the bones of the fish body become very soft and the whole bones can be eaten. However, there are also differences in the types of fish and fish, for example, If it is a small fish such as domestic horse mackerel, the pressure is 68.6 ~ 149.1kPa, the best is 81.4 ~ 1 18.7kPa, the temperature is 1 05-1 20 ° C, the best is 1 15-120 ° C, in the processing time 20-5 0 minutes to process. In this way, when the bones are eaten together, an excellent food texture can be obtained. Furthermore, according to the previous conditions, as long as the fish body is dried under reduced pressure, the shape of the fish body can be better maintained even after the pressure heating treatment. (4) 200522875 In addition, under this pressure heating condition, because it is packed in a non-closed container, although complete sterilization cannot be achieved, the number of bacteria attached to the fish body is significantly reduced, and the number of bacteria does not increase. The cooling and curing system does not damage the fish body under pressure and heat treatment. This is a step to promote the homogenization of moisture and the condensation of flavor. Normally, it is best to cool for 3-9 hours at a temperature range of 2-1 0 ° C. Through this step, there is no further rapid temperature change of the fish body, and there is less tissue damage after slow cooling. Therefore, in the cooling temperature range, it is possible to promote the slow transfer of water and ripening of the aroma of scented β. Then, the frozen-cooked fish body is subjected to a freezing treatment, preferably as quick as possible, so as to maintain the shape of the entire fish body. For example, freeze within 1 hour until the core temperature is between 18 and 25 ° C. After the freezing process, the fish body does not generate a pressure difference during cooling. It can maintain the shape of the fish, homogenize the moisture and ripen the flavor. While maintaining the original texture and taste of the fish, it will pass without freezing in the frozen state. Baking, frying, cooking and other secondary processing for consumption. β It can be used as processed food outside the specifications. Most of the small-scale aquatic products such as horse mackerel, butterflyfish (a type of flounder), saury, sardine, etc., which are mostly used as feed or have been discarded, can be used as food materials. To make effective use of it. In addition, since the fish body is subjected to sufficient high pressure or heat treatment in the pressure heating treatment step, the secondary processing does not need to sufficiently raise the core temperature of the fish body, and it can also prevent excessive burnt and dryness caused by excessive heating. Baba and so on. -8- (5) 200522875 In addition, if the secondary processed product is packed in a vacuum packaging machine, it can be cooked in a microwave oven or boiled water to make grilled or boiled fish that is easy to eat even the bones. In addition, for the elderly or children, it is also safer, nutrient value rich, easy to eat, especially aquatic processed products supplemented with calcium °. Moreover, when manufacturing fish and shellfish processed products, labor costs such as cutting and deboning are reduced. Cost, boneless fine meat and meat on the back of dark-colored fish are also available for consumption, which improves the yield of food materials. Lu can significantly reduce the amount of waste processed in the aquatic product processing plant, which has been a problem in the past. [Embodiment] Hereinafter, an embodiment of the present invention will be described with examples. However, the present invention is not limited in any way by these examples. [Example 1] Using frozen saury from Hokkaido as a raw material, a comparative example in which an example treated according to the present invention was subjected to a pressure heating treatment in a sealed package was compared with a sensory test. (Example) First, the frozen saury was removed from the scales and the internal organs, and then subjected to incision processing 'after washing with brine' as a pretreatment, and using a reduced-pressure drying treatment apparatus (designed by Ass system) at a pressure of 9 1.2kPa Next, at 30. (: Drying under reduced pressure-9-(6) (6) 200522875 Drying treatment for 70 minutes. Next, a 90gcmx100cm stainless steel net was set in a pressure heat treatment device (SCF120 10FVW manufactured by Samsung Co., Ltd.), The fish bodies which are dried under reduced pressure are arranged on the top, and are processed for 20 minutes at a steam pressure of 90.2 kPa and a temperature of 1 18 ° C. In the pressure heating treatment, the dripping juice exuding from the fish body is discharged below the pressure heating treatment. Saury after heat treatment under pressure at 5 ° C x 4 hours, after being cooled and matured, it is rapidly frozen. (Comparative example) The cutting process was performed in the same manner as in the example. After the brine was washed, the pretreatment was not reduced. The pressure-drying treatment is hermetically packed in a heat-resistant plastic bag and arranged on a stainless steel net in the same pressure heat treatment device. Under the same conditions as the examples, the heat treatment, cooling and aging, and freezing. Comparative evaluation) The surfaces of the fish bodies of the examples and the comparative examples were grilled in an oven for about 30 seconds, and the food texture and taste were evaluated respectively. The results are shown in Table 1. As shown in this table, the examples of the present invention are " autumn Saury "is excellent in appearance, shape, taste, and texture. Even in terms of hygiene, the number of viable bacteria is usually less than 300 (0). There is no problem. On the contrary," Saury "in the comparative example It is in a boiled state, and it is difficult to maintain its shape. In addition, even after processing such as roasting, the original texture and taste of the fish have disappeared. (7) 200522875 [Table 1] Examples Comparative Examples Appeared without fish meat being incomplete and broken The accumulation of water exuded from the fish body% skin peeling and other large appearance in the container and change the shape by heating. The white portion j formed by color pressure is slightly slightly cooked with water 丨 change color It ’s brown. It ’s obviously different from the appearance of the -1 upper palate. 0 The texture of the bones is so soft that it does n’t need to bear the so-called π canned food. Heating so-called " Canned "tastes and odors. No one feels the food. 0 Strong germicidal taste. 0 to 0. Number of bacteria. 3 00 > (Almost no beginning) ° 3 00 > Maintain a good overall condition (1), the meat is incomplete and boiled.

[實施例2] 將使用九州産的冷卻狀態的竹莢魚的實施例的感觀檢 查結果和氨基酸分析結果與比較例進行比較評價。 (實施例) 與除去魚鱗、內臟,進行切開加工,進行鹽水洗淨後 ,作爲前處理,在91 .2kPa的減壓下,於35°C,減壓乾燥 -11 - (8) (8)200522875 7 0分鐘。之後’與實施例1的情況一樣,進行加壓加熱處 理,再之後,進行5 °C X 3小時的冷卻熟化後,於-3 5艺冷 凍。 (比較例) 與實施例相同’除去魚鱗、內臟,進行切開加工、鹽 水洗淨後’沒有前處理,與上述實施例相同,進行加壓加 熱處理和冷卻熟化後,冷凍。 (比較評價) 用烤爐燒烤實施例和比較例之色體的表面,供感觀試 驗和氨基酸分析。其結果表不於表2中。如該表所示,本 發明的實施例沒有皮剝離、破碎、魚體彎曲等缺陷。與此 相反,比較例係以看到明顯的外在損傷,視覺上不令人滿 意。另外,即使對於食感和味道,經過減壓乾燥的前處理 和加壓加熱處理後的冷卻熟化步驟的本發明的實施例也保 有適度的水份,也能感覺到魚肉的彈性和新鮮感。與此相 反,比較例水分稍多,且魚肉缺乏彈性感。 另外,表3顯示出作爲兩個試樣的營養指標的”氨基酸 分析値"。 如該表所示,如果將實施例的游離氨基酸的總値設定 爲1 0 0的話,比較例減少到約9 4 % ,表明氨基酸(蛋白質) 流失了。 -12- (9)200522875 表2 實 施 例 比 較 例 外 觀 沒 有 隹 、、 肉 不 兀 整 破 全 部 的 檢 驗物大 致 上 都 碎 Λ 皮 剝 離 等 外 觀 上 存 在 不 兀 整、破 碎 \ 皮 大 的 變 化 〇 剝 離 等 某 等損傷 〇 顏 色 加 壓 引 起 的 白 色 部 分 與 左 邊 的 樣品相 比 較 稍 〇 微 有 點 變 色 爲 茶 色 顔 色 變 化 更大。 食 感 骨 頭 柔 軟 到 兀 全 不 用 骨 頭 柔 軟 到完全 不 用 擔 擔 心 的 程 度 〇 肉 質 硬 心 的 程 度 但感受 到 肉 質 〇 柔 軟 〇 味 道 有 人 稍 微 感 到 加 壓 加 有 人 稍 微 感到加 壓 加 熱 熱 臭 有 人 兀 全 沒 有 臭 有 人 完全沒 有 感 受 感 受 到 〇 到 〇 水 分(測定 68.70% 73 .20% 値 ) 整 體 整 體 上 維 持 良 好 的 狀 外 觀 上 損 傷顯著 〇 以 後 態 〇 的 作 業 也 難於操作 〇[Example 2] The sensory inspection results and amino acid analysis results of the examples using cold state horse mackerel from Kyushu were compared and evaluated with the comparative examples. (Example) After removing fish scales and viscera, cutting and processing, and washing with brine, as a pretreatment, dry at 35 ° C under reduced pressure of 91.2 kPa under reduced pressure-11-(8) (8) 200522875 7 0 minutes. Thereafter, as in the case of Example 1, heat treatment was carried out under pressure, and after that, it was cooled and aged at 5 ° C for 3 hours, and then frozen at -35 ° C. (Comparative example) The same as in the example, "the fish scales and the internal organs were removed, and the cutting process was performed, and the salt water was washed." There was no pretreatment. In the same manner as in the above-mentioned example, pressure heat treatment and cooling and aging were performed, and then frozen. (Comparative evaluation) The surfaces of the color bodies of Examples and Comparative Examples were grilled in an oven for sensory test and amino acid analysis. The results are shown in Table 2. As shown in the table, the examples of the present invention are free from defects such as peeling, breaking, and bending of fish. In contrast, the comparative examples are visually unsatisfactory to see obvious external damage. In addition, even if the embodiment of the present invention is subjected to a pre-drying process under reduced pressure and a cooling and aging step after pressurized heat treatment with respect to food texture and taste, the embodiment of the present invention retains a moderate amount of water, and the elasticity and freshness of the fish can be felt. In contrast, the comparative example had slightly more water, and the fish lacked elasticity. In addition, Table 3 shows the "amino acid analysis" as a nutrition index for the two samples. As shown in this table, if the total value of the free amino acids in the examples is set to 100, the comparative example is reduced to about 94%, indicating the loss of amino acids (proteins). -12- (9) 200522875 Table 2 Examples Comparative Examples There are no appearances, and the meat is not completely broken. All the test objects are roughly broken. Incomplete, broken, and large skin changes. Some damage such as peeling. The white part caused by color pressure is slightly different from the sample on the left. The color is slightly changed to the brown color. The bones are so soft that they are not used at all. The bones are soft to the point where there is no need to worry about it. The flesh is hard and hard, but the flesh is felt. The flesh is soft. Some people feel a little pressure and some people feel the heat of pressure heating is smelly. Some people are not smelly at all. Some people did not feel it at all. They felt 〇 to 〇 moisture content (measured 68.70% 73.20% 値). The whole body maintained a good appearance. The damage was significant on the outside. The work in the post state 〇 was also difficult to operate.

-13- (10)200522875 [表3] 實施例 比較例 牛磺酸 121.7 115.6 羥基脯氨酸 0.0 0.0 天冬氨酸 4.7 4.1 蘇氨酸 18.6 17.1 絲氨酸 8.5 8.2 谷氨酸 27.5 22.8 脯氨酸 17.6 17.4 甘氨酸 12.9 12.5 丙氨酸 26.0 24.7 胱氨酸 5.6 5.4 擷氨酸 19.3 17.1 蛋氨酸 9.4 8.5 異亮氨酸 12.8 12.3 亮氨酸 22.9 22.6 酪氨酸 4.4 4.4 苯基氨酸 12.2 10.4 賴氨酸 44.8 38.7 組氨酸 109.7 108.4 精氨酸 10.9 9.7 總計 489.5 460.0-13- (10) 200522875 [Table 3] Examples Comparative Examples Taurine 121.7 115.6 Hydroxyproline 0.0 0.0 Aspartic acid 4.7 4.1 Threonine 18.6 17.1 Serine 8.5 8.2 Glutamate 27.5 22.8 Proline 17.6 17.4 Glycine 12.9 12.5 Alanine 26.0 24.7 Cystine 5.6 5.4 Trancine 19.3 17.1 Methionine 9.4 8.5 Isoleucine 12.8 12.3 Leucine 22.9 22.6 Tyrosine 4.4 4.4 Phenyline 12.2 10.4 Lysine 44.8 38.7 Histidine Acid 109.7 108.4 Arginine 10.9 9.7 Total 489.5 460.0

-14- (11) 200522875 [實施例3] 基於本發明,將挪威産冷凍的青花魚減壓乾燥,於非 密閉狀態下加壓加熱處理,分離排出從水産物中滲出的滴 汁,然後,於冷卻溫度範圍熟化,將該實施例與沒冷卻處 理的比較例進行比較評價。 (實施例) 將冷凍的青花魚除去內臟和加工成魚片’進行鹽水洗 ® 淨,在91.2kPa的減壓下,進行35°C x7〇分鐘的減壓乾燥 處理後,與實施例1相同進行加壓加熱處理,於5 °C中從0 分鐘至720分鐘之間,冷卻熟化,其後冷凍。隨著冷卻熟 化的經過時間,測定水份移動和總水份量的變化’調查經 過時間中感觀檢查的新鮮感、味道、口感的變化。 (比較例) 省略實施例中的冷卻熟化處理,進行與實施例相同的 處理。 (比較評價) 分別將實施例和比較例得到的魚,以烤爐燒烤表面’ 將水份移動之狀態用島津製作所的電子式水分計EB-340MOC(加熱器溫度5 5 0 °C、時間45分鐘),通過魚體的中 心部的長度方向(中心部)和沿魚體邊緣的方向(端部)進行 樣品分析,剩餘之一部份經由觀能檢查’混合其剩餘之全 -15- (12)200522875 體,採取一部份測計總水份量。其結果示於表4。-14- (11) 200522875 [Example 3] Based on the present invention, frozen frozen mackerel made in Norway was dried under reduced pressure, heated under pressure in a non-sealed state, and the dripping juice exuding from the water product was separated and discharged. The cooling temperature range was aged, and this example was compared and evaluated with a comparative example without cooling treatment. (Example) After removing the internal organs of frozen mackerel and processing it into fish fillets, wash it with brine and wash it under a reduced pressure of 91.2 kPa, and then perform a reduced pressure drying process at 35 ° C x 70 minutes, which is the same as in Example 1. It is pressurized and heat-treated, and is cooled and aged at 0 ° C to 720 minutes at 5 ° C, and then frozen. As the elapsed time of cooling and maturing, the changes in water movement and total water content were measured 'to investigate the changes in freshness, taste, and mouthfeel of the sensory inspection over time. (Comparative example) The cooling and aging process in the examples was omitted, and the same processes as in the examples were performed. (Comparative evaluation) Shimadzu Corporation's electronic moisture meter EB-340MOC (heater temperature 5 5 0 ° C, time 45) Minutes), analyze the sample through the length of the central part of the fish body (the central part) and the direction along the edge of the fish body (the end part), and the remaining part is subjected to a visual inspection to mix the remaining parts -15- ( 12) 200522875 body, take part to measure the total water content. The results are shown in Table 4.

•16- 200522875 (13)• 16- 200522875 (13)

寸撇Inch

m 鐲 騎 飽 中心與端部在新鮮感上稍有 差別 I_ -► 中心與端部在新鮮感上有少 許差別 視覺味道上都是均一的感覺 (口感上也具新鮮感) 視覺和味道上都感覺柔軟 (口感上也具新鮮感) ► 具有均一感,但全體稍微產 生乾燥 有感覺 總水份 52.10% 52.05% 52.25% 52.50% 52.3 5% 52.25% 5 1.95% 52.00% T-H <N 52.08% 5 1.70% 5 1.70% 5 1.70% 水分差 v〇 m CN r-H τ—Η 〇\ 〇 卜 〇 0.8 % 卜 〇 VO 〇 次 ο 寸 〇 0.4% m 〇 m ο •S 佩 端部 家 〇 yr\ 卜 次 V—Η 00 τ-Η in Os 卜 yn VO 卜 yn 次 寸 Η to 卜 ir> 欲 ?—4 中心部 次 as m <Ν 寸 衣 v〇 (N 卜 (N 次 Ό <Ν 次 (N m CN 次 <N 次 (Ν 欲 00 as r-H 〇 CN 5 1 . 8 % 熟化時間 0.0小時 七 ο f-H 2.0小時 ί i_ 3.0小時 4.0小時 5.0小時 6.0小時 7.0小時 8.0小時 9.0小時 1 0.0小時 1 1.0小時i 1 2.0小時 ο 60分 1_ 120分 1 80分 240分 3 00分 3 6 0分 420分 480分 540分 600分 6 6 0分 720 分 1 f-H CN 寸 v〇 卜 00 ON 〇 1—Η (N -17- (14) 200522875 從表4可以淸楚看出’實施例的場合’熟化時間爲〇時 在中心和端部存在很大的水份差,但是隨著時間的延 長,慢慢地中心部與端部的差別變沒有了且總水份量也下 降。 這些認爲是通過熟化中心部的水分移動到端部,由此 謀求內部水份之均一化,且經由來自表面緩慢的乾燥的相 乘效果,保留新鮮感、同時口感上變得柔軟。另外,從資 ® 料和感官實驗可知,中心部與端部的水分差在〇·4〜〇·9% 的範圍,另外,總水分量爲52.08〜52.50%的範圍,感官 上最好,熟化時間上最佳爲3〜9小時的範圍。 與此相對,比較例的場合,與實施例的熟化時間〇分 鐘相同的結果,即,在中心部與端部之間産生水分差,結 果在新鮮感上産生差別。 經過原子吸光活測定基於本發明處理冷凍的竹莢魚( 荷蘭産)和冷凍的青花魚(挪威産)的魚體和一般市售的竹 β 莢魚和青花魚的鈣含量。該測定結果示於表5中。該表所 示的値表示每100g檢驗物含有鈣的値。如該表所示,對 於本發明,與市售的竹莢魚對比,顯然竹莢魚含有1 〇倍的 鈣,青花魚(切去頭部)也含有近5倍的鈣。根據該結果, 只要魚能連骨頭都能吃,那麽在每天的飮食中,可以攝取 充分的鈣,對於生長發育的孩子和骨質趨於軟弱的老年人 ,能夠成爲非常有價値的商品。 -18- (15) 200522875 表5 竹莢魚切開 青花魚切開(無頭) 加壓處理過(連骨頭) 5 8 5.6mg 1 1 8 · 7mg 通常的魚(只限可食部份) 5 7 . Omg 2 5 mg 鈣含有率 10.27 4.75 按照上述實施例1的處理方法處理的竹莢魚、秋刀魚 、蝶魚,再加上青花魚作爲原料分別進行表6所示的二次 · 加工以供食用。加壓加熱處理後的魚體表面的活菌數均爲 3 〇 〇以下。如表6所示,採用任意一種二次加工的調理方法 ’無論何種魚,都沒有像以往的殺菌食品的”殺菌味,,,無 論哪種魚,都絲毫不用擔心骨頭,可以食用,食感、味道 都良好。m There is a slight difference in the sense of freshness between the center and the end of the bracelet. I_ -► There is a little difference in the sense of freshness between the center and the end. The visual taste is uniform (the taste is also fresh). The visual and taste are both Feels soft (freshness in taste) ► Has a uniformity, but the whole is slightly dry. Feels total moisture 52.10% 52.05% 52.25% 52.50% 52.3 5% 52.25% 5 1.95% 52.00% TH < N 52.08% 5 1.70% 5 1.70% 5 1.70% Moisture difference v〇m CN rH τ—Η 〇 \ 〇〇〇〇% 〇〇〇 〇 ο inch 〇0.4% m 〇m ο • S Pei Duanjia 〇yr \ 次 次V—Η 00 τ-Η in Os yn yn VO yn yn times Η to ir > Desire? —4 Central part times as m < N inch clothes v〇 (N ((N times Ό < N times (N times m CN times < N times (N for 00 as rH 〇CN 5 1. 8% ripening time 0.0 hours seven ο fH 2.0 hours ί i 3.0 hours 4.0 hours 5.0 hours 6.0 hours 7.0 hours 8.0 hours 9.0 hours 1 0.0 hours 1 1.0 Hours i 1 2.0 hours ο 60 minutes 1_ 120 minutes 1 80 minutes 240 minutes 3 00 minutes 3 6 0 minutes 420 minutes 480 minutes 540 minutes 600 minutes 6 6 0 720 points 1 fH CN inch v〇b 00 ON 〇1—Η (N -17- (14) 200522875 From Table 4, it can be clearly seen that the 'when the embodiment is applied', when the ripening time is 0, there are very The large moisture difference, but as time goes on, the difference between the central part and the end part gradually disappears and the total moisture content also decreases. These are considered to be due to the moisture in the central part being matured and moved to the end part. It seeks to homogenize the internal moisture, and through the synergistic effect of slow drying from the surface, it retains the freshness and softens the taste. In addition, from the materials and sensory experiments, it can be seen that the moisture at the center and the ends are poor. In the range of 0.4 to 0.9%, the total moisture content is in the range of 52.08 to 52.50%, which is best on the senses and the best on the maturation time is in the range of 3 to 9 hours. In this case, the same result as the maturation time of the example was 0 minutes, that is, a difference in moisture was generated between the central portion and the end portion, resulting in a difference in freshness. Atomic absorption was determined based on the treatment of frozen horse mackerel according to the invention (Made in Holland) and cold Bamboo β horse mackerel and mackerel calcium content of mackerel (Norway production) of fish and generally commercially available. The measurement results are shown in Table 5. The radon shown in the table indicates that radon containing calcium per 100 g of the test substance. As shown in this table, for the present invention, it is clear that horse mackerel contains 10 times as much calcium as commercial horse mackerel, and mackerel (cut head) also contains nearly 5 times as much calcium. According to this result, as long as fish can eat even bones, sufficient calcium can be ingested daily, and it can be a very valuable product for children who grow and develop and whose bones tend to be weak. -18- (15) 200522875 Table 5 Horse mackerel cut mackerel cut (headless) Pressurized (bones) 5 8 5.6mg 1 1 8 · 7mg Normal fish (only edible portion) 5 7 Omg 2 5 mg Calcium content rate 10.27 4.75 The horse mackerel, saury, and butterfly fish treated in accordance with the processing method of Example 1 above, plus mackerel as raw materials, are subjected to secondary processing as shown in Table 6 for consumption . The number of live bacteria on the surface of the fish body after the pressure heat treatment was all 3,000 or less. As shown in Table 6, using any one of the secondary processing methods' no matter what kind of fish, there is no "sterilizing taste" like conventional sterilized foods. No matter what kind of fish, you do n’t have to worry about bones. Feeling and taste are good.

-19- 200522875 (16) 9揪 味道 插QR 制。0 。酿§Η ¢: ·$) Dj^ 惡舾φ 酲逻识 ^ πή 鏟E # BE ♦( S If Z$ 嵌 制向脑 騮R 插DR 啪。〇 0 _鈿 ^ φ 鼷裰枳 Θ _挪 «昍# 旺鹌S ^ 3长 舶1?锊 # 1? rm1 勘· 騾腰 φ{ ιφϋ 胺忌 昍鼷 -#Ρ 你 0 ife ^ 05 _ K~ _ 驿刼装) 鰥。# 聽撇撇 紫截铌 # 1¾(啪 鼷ί® 3 m 张 S 縱。 §旺 濶爱 岷振 •洲< 嵌插 胡z$ 令\。他 mm^ _张# _ s撇 鋰顥怩 S § 2$ 繼魆I? 你fe -^ m Φ 癒靼链 皂蝦:g 豳辛)K ^nm 頰张舭。 熙! ·鈀匪 mil 卿· 鼷臊 细〔_ 昍鵾 版K K _ K*·够 驿刼爱 鰥。# 燧撇撇 瘵黻镝 鼷挪ζί 食感 L_ - Ιφπ κ- 皆》漱 難痤 nr) · 擓I喊 商 ° 神I餾& 鼷坦鼷 _ Κ·帐 ^ ^ m 靶龌_1 難盛1¾ a mj ^ 7; 1» 蹈威:; 燄e ^鹌 面。碎S 鏺醎。ϋ 聛臌驿 鈀S酿雔 S 敝刼 U -K # ,鼷 m。 郵疵 騾制 怨瘸。 昍Φ圃 隸IS鼷 •R令 酉讓 神Μ丨 趔。。 辛1 Κ你 ·» ^1°7¾ SE # tg 制 IBS g 妮_ Μ # IS ζ$ 洒芻苌 雜-· S 丑 ΠΓ tttj 砂 ★ 餾 m ΑΑ. 0η» Tx wt 蝈 #; 卿 徙。 傲。旺如 ,駿截贈 你疵,K 处g e W S岖抝y Φ起郵臌 链濶镯鹌 驺Η靼, m β ^ m S $5 择嘛 帐辛) Κ # 要。 租1疵 鼷#: 徙濁。 旺汆勸 戥铌ϋ S m Μ_ φ: 炎 诞> φ: m tm 后 J 1 1 U S 51 S 魚的種類二 3=—— •Φ; ^-- R ^_ 疵 _ _ — 疵 Iff -20- (17) 200522875 產業上之利用可能性 本發明也適用於以往不適用殺菌食品中的小魚類,經 過任意的二次加工即可食用。 經本發明的方法製得的魚可以在冷凍狀態下,進行所 謂的’’烤•煮•炸"各種二次加工、可適用的水産品,不限 於鮭魚、竹莢魚、青花魚、花鯽魚、蝶魚、秋刀魚、沙丁 魚、鱈、鯛魚、嬉等魚的種類,也適用於大型魚、螃蟹、 蝦類、貝類。 如果以本發明的方式商品化,可以提供前所未有的高 附加價値的水産加工品。 -21 --19- 200522875 (16) 9 揪 Taste Insert QR system. 0. Brewing §Η ¢: · $) Dj ^ Evil 酲 酲 Logic ^ πή Shovel E # BE ♦ (S If Z $ Insert the DR into the brain 骝 R. 〇0 _ 钿 ^ φ 鼷 裰 枳 Θ _ Norwegian «昍 # wangquai S ^ 3 long ship 1? 1 # 1? Rm1 Kan · 骡 waist {{ιφϋ 昍 鼷 昍 鼷 #-# Ρ you 0 ife ^ 05 _ K ~ _ station 刼 装) 鳏. # 听 羞 羞 紫 断 铅 # 1¾ (鼷 鼷 3 3 m Zhang S portrait. §Wang 岷 Ai Zhen Zhen • Zhou & 嵌 Insertion Hu z $ 令 \. 他 mm ^ _ 张 # _ s S § 2 $ Following 魆 I? You fe-^ m Φ 靼 靼 chain soap shrimp: g 豳 辛) K ^ nm cheeks. Hee! · Mil Qing, Palladium banditist 鼷 臊 鼷 臊 〔〔昍 鵾 昍 鵾 版 K K _ K * · is enough 刼 刼 爱 刼. # 燧 duction 瘵 黻 镝 鼷 瘵 黻 镝 鼷 ζ Feeling L_-Ιφπ κ-》 漱 Swallowing acne nr) · 擓 I shouting quotient ° God I && 鼷 坦 鼷 _ Κ · 帐 ^ ^ m 龌 龌 _1 difficulty Sheng 1¾ a mj ^ 7; 1 »Wu Wei :; Yan e ^ Quamen. Crush S 鏺 醎. ϋ 聛 臌 站 Palladium S 雔 S 敝 刼 U -K #, 鼷 m. Post flaws control resentment.昍 Φ 圃 IS 鼷 • R 令 酉 让 神 M 丨 趔. . Xin 1 Κ 你 · »^ 1 ° 7¾ SE # tg IBS g Ni_ Μ # IS ζ $ Spread 苌 Miscellaneous-S ugly ΠΓ tttj Sand ★ Distillate m ΑΑ. 0η» Tx wt 蝈 #; Qing Migration. proud. Wang Ru, Jun intercepts your defects, g e W S 岖 拗 y Φ from the post 臌 chain 濶 chain quail m, m β ^ m S $ 5 嘛 好 帐 辛) Κ # Yes. Leasing 1 defect Wang Meng advises niobium m S m Μ_ φ: birthday > φ: m tm after J 1 1 US 51 S Fish type 2 3 = —— • Φ; ^-R ^ _ Flaw_ _ — Flaw Iff- 20- (17) 200522875 Industrial Applicability The present invention is also applicable to small fishes that were not previously suitable for sterilization foods, and can be eaten after any secondary processing. The fish prepared by the method of the present invention can be so-called `` roasted, boiled, fried '' in a frozen state, and various secondary processed and applicable aquatic products are not limited to salmon, horse mackerel, mackerel, and mackerel. , Butterfly fish, saury, sardine, cod, snapper, bream and other types of fish, also suitable for large fish, crab, shrimp, shellfish. If commercialized in the manner of the present invention, it is possible to provide an aquatic processed product with an unprecedentedly high added value. -twenty one -

Claims (1)

200522875 (1) 十、申請專利範圍 1. 一種水産品之加工方法,該方法爲不損害水産品原 來具有的食感和味道、連芯骨都可食用的水産品之加工方 法’其特徵爲包含除去並洗淨應該處理的水産品中不需要 之部份後’減壓乾燥,減壓乾燥後,於非密閉的狀態下進 行加壓加熱,再進一步於冷卻溫度範圍中熟化之步驟。 2 ·如申請專利範圍第1項中水産品之加工方法,其中 前述減壓乾燥於86.1-96.3 kPa下,於25-35 °C的溫度範圍 內進行60-100分鐘。 3 ·如申請專利範圍第丨項或第2項所述的水産品之加工 方法’其中前述加壓加熱於68.6- 1 49.lkPa下,於105-120 °C的溫度範圍內進行20-50分鐘。 4·如申請專利範圍第丨項至第3項中任一項所述的水産 品之加工方法,其中前述冷卻熟化於2_ 10 °C的溫度範圍內 進行3 - 9小時。 5·如申請專利範圍第1項至第4項中任一項所述的水産 品之加U:方法,其中,熟化後附加急速冷凍之步驟。 6·如申請專利範圍第1項至第5項中任一項所述的水産 品之加:L方法,其中熟化後或急速冷凍後的水産品用於供 食用之二次加工。 -22- 200522875 七、指定代表圖: (一) 、本案指定代表圖為··無 (二) 、本代表圖之元件符號簡單說明: Μ μ200522875 (1) X. Application for patent scope 1. A method for processing aquatic products, the method is a method for processing aquatic products that does not damage the original food texture and taste of aquatic products, and even edible core bones. After removing and washing the unnecessary part of the aquatic product to be treated, the product is dried under reduced pressure, dried under reduced pressure, and then heated under pressure in a non-sealed state, and further matured in a cooling temperature range. 2 · The method for processing aquatic products in item 1 of the scope of patent application, wherein the above-mentioned drying under reduced pressure is performed at 86.1-96.3 kPa for 60-100 minutes at a temperature range of 25-35 ° C. 3 · The method of processing aquatic products as described in item 丨 or item 2 of the scope of patent application 'wherein the aforementioned pressure heating is performed at 68.6-1 49.lkPa and within the temperature range of 105-120 ° C 20-50 minute. 4. The method for processing aquatic products according to any one of items 丨 to 3 in the scope of the patent application, wherein the aforementioned cooling and aging is performed at a temperature range of 2-10 ° C for 3-9 hours. 5. The method of adding U to aquatic products according to any one of claims 1 to 4 of the scope of patent application: a method in which a step of rapid freezing is added after aging. 6. Addition of aquatic products as described in any one of items 1 to 5 of the scope of patent application: Method L, wherein the aquatic products after ripening or rapid freezing are used for secondary processing for consumption. -22- 200522875 VII. Designated Representative Map: (1). The designated representative map in this case is ... None. (2) The component symbols of this representative map are simply explained: Μ μ 八、本案若有化學式時,請揭示最能顯示發明特徵的化學 式:無8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: None
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JPS565072A (en) * 1979-06-26 1981-01-20 Kibun Kk Processing of small-sized fish
JPH0761244B2 (en) * 1987-07-15 1995-07-05 株式会社スワーク Fish food manufacturing method
JPH02142453A (en) * 1988-11-22 1990-05-31 Urashima Shokuhin Kogyo Kk Production of process sardine food production
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JPH09173023A (en) * 1995-12-27 1997-07-08 Shoichi Watanabe Cooking of roasted fish eatable till bone
JPH11346722A (en) * 1998-06-04 1999-12-21 C & C:Kk Packed body of fish having seaweed sheet and its production
JP3781946B2 (en) * 2000-05-23 2006-06-07 株式会社ニツセン Processed fish product manufacturing method and fish processing apparatus
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