TW200425768A - Flexible MENS transducer and manufacturing method thereof, and flexible MENS wireless microphone - Google Patents

Flexible MENS transducer and manufacturing method thereof, and flexible MENS wireless microphone Download PDF

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Publication number
TW200425768A
TW200425768A TW092126657A TW92126657A TW200425768A TW 200425768 A TW200425768 A TW 200425768A TW 092126657 A TW092126657 A TW 092126657A TW 92126657 A TW92126657 A TW 92126657A TW 200425768 A TW200425768 A TW 200425768A
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flexible
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TW092126657A
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TWI235011B (en
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Yun-Woo Nam
Suk-Han Lee
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Samsung Electronics Co Ltd
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    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
    • H04R31/00Apparatus or processes specially adapted for the manufacture of transducers or diaphragms therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00015Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
    • B81C1/00134Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems comprising flexible or deformable structures
    • B81C1/00182Arrangements of deformable or non-deformable structures, e.g. membrane and cavity for use in a transducer
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/01Manufacture or treatment
    • H10N30/09Forming piezoelectric or electrostrictive materials
    • H10N30/098Forming organic materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/20Piezoelectric or electrostrictive devices with electrical input and mechanical output, e.g. functioning as actuators or vibrators
    • H10N30/204Piezoelectric or electrostrictive devices with electrical input and mechanical output, e.g. functioning as actuators or vibrators using bending displacement, e.g. unimorph, bimorph or multimorph cantilever or membrane benders
    • H10N30/2041Beam type
    • H10N30/2042Cantilevers, i.e. having one fixed end
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/20Piezoelectric or electrostrictive devices with electrical input and mechanical output, e.g. functioning as actuators or vibrators
    • H10N30/204Piezoelectric or electrostrictive devices with electrical input and mechanical output, e.g. functioning as actuators or vibrators using bending displacement, e.g. unimorph, bimorph or multimorph cantilever or membrane benders
    • H10N30/2047Membrane type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B2201/00Specific applications of microelectromechanical systems
    • B81B2201/02Sensors
    • B81B2201/0257Microphones or microspeakers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B2201/00Specific applications of microelectromechanical systems
    • B81B2201/03Microengines and actuators
    • B81B2201/032Bimorph and unimorph actuators, e.g. piezo and thermo
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B2203/00Basic microelectromechanical structures
    • B81B2203/01Suspended structures, i.e. structures allowing a movement
    • B81B2203/0118Cantilevers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B2203/00Basic microelectromechanical structures
    • B81B2203/01Suspended structures, i.e. structures allowing a movement
    • B81B2203/0127Diaphragms, i.e. structures separating two media that can control the passage from one medium to another; Membranes, i.e. diaphragms with filtering function
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
    • H04R1/00Details of transducers, loudspeakers or microphones
    • H04R1/20Arrangements for obtaining desired frequency or directional characteristics
    • H04R1/32Arrangements for obtaining desired frequency or directional characteristics for obtaining desired directional characteristic only
    • H04R1/40Arrangements for obtaining desired frequency or directional characteristics for obtaining desired directional characteristic only by combining a number of identical transducers
    • H04R1/406Arrangements for obtaining desired frequency or directional characteristics for obtaining desired directional characteristic only by combining a number of identical transducers microphones
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
    • H04R17/00Piezoelectric transducers; Electrostrictive transducers
    • H04R17/02Microphones
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
    • H04R2420/00Details of connection covered by H04R, not provided for in its groups
    • H04R2420/07Applications of wireless loudspeakers or wireless microphones

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Signal Processing (AREA)
  • Micromachines (AREA)
  • Piezo-Electric Transducers For Audible Bands (AREA)
  • Pressure Sensors (AREA)
  • Details Of Aerials (AREA)
  • Piezo-Electric Or Mechanical Vibrators, Or Delay Or Filter Circuits (AREA)

Abstract

A flexible wireless MEMS microphone includes a substrate of a flexible polymeric material, a flexible MEMS transducer structure formed on the substrate by PECVD, an antenna printed on the substrate for communicating with an outside source, a wire and interface circuit embedded in the substrate to electrically connect the flexible MEMS transducer and the antenna, a flexible battery layer electrically connected to the substrate for supplying power to the MEMS transducer, and a flexible bluetooth module layer electrically connected to the battery layer. The flexible MEMS transducer includes a flexible substrate, a membrane layer deposited on the substrate, a lower electrode layer formed on the membrane layer, an active layer formed by depositing a piezopolymer on the lower electrode layer, an upper electrode layer formed on the active layer, and a first and a second connecting pad electrically connected to the lower and upper electrode layers, respectively.

Description

200425768200425768

五 一、【發明所屬之技術領域】 本發明與一微機電系統結構及其製造方法有關;更特 別地,本發明係關於形成於一撓性基板上之一撓性微機電 系統轉換器及其製造方法、與組成該撓性微機電系統轉換 器之一撓性微機電系統無線麥克風。 、 二、【先前技術】 ^ ’依照極小裝置之需求,吾人將利用微加工技術之半導 體製程科技應用於整合微裝置上。微機電系統(微機電) 領域為製造及測試微小感測器或致動器、與利用用於半導 體=耘特別疋積體電路科技上之微切削技術之機電結構等 領域’其具有微米m )級之尺寸。 應用於微機電上之該微加工技術大別為兩範疇, 微加工範疇為利用體型矽基蝕刻之體型矽基加工;第二微 加工範’為利用切上沉積—多晶碎、氮切及氧化石夕薄 膜並根據了形成結構之預定模型而進行㈣之面型石夕基加 工。例如·形成利用一微機電程序所製造之超小型 風,係藉該體型矽基加工技術所形成之隔膜轉換器而 成。 、σ <51. [Technical field to which the invention belongs] The present invention relates to a micro-electro-mechanical system structure and a manufacturing method thereof; more particularly, the present invention relates to a flexible micro-electro-mechanical system converter formed on a flexible substrate, and a flexible micro-electro-mechanical system converter formed thereon. Manufacturing method, and a flexible MEMS wireless microphone constituting one of the flexible MEMS converters. 2. Prior Technology ^ ‘According to the needs of very small devices, we will use the semi-conducting system technology of micro-processing technology to integrate micro-devices. The field of micro-electro-mechanical systems (MEMS) is the field of manufacturing and testing tiny sensors or actuators, and the use of electromechanical structures such as micro-cutting technology for semiconductors and special integrated circuit technology. Grade size. The micro-machining technology applied to micro-electromechanics is divided into two categories. The micro-machining category is bulk silicon-based processing using bulk silicon-based etching. The second micro-processing paradigm is to use cut-on deposition-polycrystalline crushing, nitrogen cutting and The oxidized stone thin film is processed with a surface-shaped stone based on a predetermined model for forming a structure. For example, the formation of ultra-small winds manufactured using a micro-electromechanical program is made by a diaphragm converter formed by the body's silicon-based processing technology. , Σ <

〜队例电得供窃二戳囬團。如圖所 機電轉換器包含一氮化…膜層、以圓化所; ^牡矽(si )晶圓上之上下電極,在矽晶 >成一虱化矽薄膜及一氧化矽層之該CVD程序為一需要~ The team's case must be returned to the group for theft. As shown in the figure, the electromechanical converter includes a nitride film layer to round the substrate; the silicon substrate (Si) wafer has upper and lower electrodes, and the CVD silicon film and a silicon oxide layer of the CVD Program as needed

第8頁 200425768 五、發明說明(2) _ 理溫度約780至850 X:之高溫程序·,因此,吾人不可λ 除了石夕晶圓外之撓性聚合物材料以作為該基板材料% 同時’隨著資訊與通訊產業之發展,對手接 資訊終端之需求亦與曰倶增,此種需求之增加部H而因= 安裝於各種不同領域如醫藥、服務、娛樂、軍事、’、=此 通訊等之資訊終端應用。為便於使用此些資訊終端及 ,,元件在移動性及耐用性上應具有優越特性;特 : 為貫現耐用系統,吾人需要一撓性系統結構;因此,五 ίί將一功能性結構及其他導電組件整合於-撓性基:之 吾人以金屬薄膜或聚合物材料作為撓性基板,i =料較適用於電子系統,而金屬薄膜因具5〇。。二? 低辄圍之低熔點,故當聚合物材料賊更 中,聚合物材料並不適合作為:it電之製造程序 p皮十a 一 f馮忒基板如晶圓之材料,因該 要兩於該聚合物材料熔點之程序溫度 所二且::優越性能與整合度特…微機ί ίΐ :五”係藉包括至少5〇ot之高溫程序之方法而 合物)材二柞:不使用一撓性系統結構所需之高分子(聚 口物)材枓作為該基板。 八Page 8 200425768 V. Description of the invention (2) _ High temperature program with a processing temperature of about 780 to 850 X: Therefore, we must not λ use flexible polymer materials other than Shixi wafers as the substrate material at the same time ' With the development of the information and communication industry, the demand for hand-to-hand information terminals has also increased. This increase in demand is due to installation in various fields such as medicine, services, entertainment, military, and this communication. And other information terminal applications. In order to facilitate the use of these information terminals and components, the components should have superior characteristics in terms of mobility and durability; Special: In order to achieve durable systems, we need a flexible system structure; therefore, five functional and other structures The conductive component is integrated on a flexible base: I use a metal thin film or a polymer material as the flexible substrate, i = material is more suitable for electronic systems, and the metal thin film is 50. . two? Low melting point and low melting point, so when the polymer material is more stable, the polymer material is not suitable as: it electrical manufacturing process p skin ten a f fong 忒 substrate such as wafer material, because it should be two or more than the polymerization The temperature of the program material melting point is: The superior performance and the degree of integration are special ... Microcomputers ίΐ: Five "is a combination of methods including a high temperature program of at least 50ot) Material two: Do not use a flexible system The polymer (polymer) material required for the structure is used as the substrate.

)以Ϊ 《 一傳統微機電結構係藉化學氣相沉積(CVD 以CVD $成」>膜而形成,接著再利用蝕刻程序;然而,因 用柄^/成一向效薄膜需要在極高溫度下進行,故盔法使 用低熔點基板,如聚合物、玻璃等。 200425768 五、發明說明(3) 為克服此問題,如圖2所示之一傳統方去艮 撓性裝置,其係以一矽微機電程序在一矽其^可產生— 感測器裝置30,自該矽基板〗0背部之矽良二f 〇上形成一 再沉積-聚合物11,·然而,此方法有缺點:因著 含一高溫程序之該傳統微機電製程, 二和用包 行了 一聚合物程序,故增加了整體t 7 v騾額外進 體裟転之複雜性與成本。 三、【發明内容】 因此,為解決至少上述某些問題,本發明一杏 特色即為:利用電漿加強化學氣相沉積法⑽CV二二之 :撓2合物基板上形成一微機電轉換器,以提二在 性、撓性及可摺疊性特徵之麥克風。 /、 '柔 為提供本發明之一特★ Η η Μ ^ β 寻色本發明一貫施例提供了一# 上之 膜層上沉積一導電材料所形:已°巧之該膜層:藉在該 端電極声上沉藉厭兩 之一下端電極層、藉在該下 活性層上沉積-導電材料 成 A 1±層藉在该 端電極層電性連接之一第一4f之一上端電極層、與該下 層電性連接之一第二連接墊片妾墊片、以及與該上端電極 更佳地’該轉換可φ 6 約10 之氮化石夕或氧化功更包含在該基板上塗佈厚度小於 更佳地,該基護層。 亞胺或金屬薄膜所形成由一雨分子(聚合物)材料如聚醯 ΐ::有其;ΐ一撓性材料基板、沉積於該基‘ = = 凸起部分之該膜層、藉在: 第10頁 200425768) Based on "A traditional micro-electromechanical structure is formed by chemical vapor deposition (CVD is formed by CVD)", and then the etching process is used; however, due to the use of handles, it is necessary to use extremely high temperatures at high temperatures. The helmet method uses a low melting point substrate such as polymer, glass, etc. 200425768 V. Description of the invention (3) To overcome this problem, as shown in Figure 2, one of the traditional square-shaped flexible devices is based on a Silicon micro-electro-mechanical procedures can be produced on a silicon substrate—a sensor device 30, from which the silicon substrate 2 on the back of the silicon substrate f0 is repeatedly deposited—the polymer 11; however, this method has disadvantages: The traditional micro-electromechanical process of a high-temperature process, and Erwa used a polymer process, so the complexity and cost of the overall t 7 v (extra integration) are increased. III. [Content of the Invention] Therefore, in order to solve At least some of the above problems, a feature of the present invention is: the use of plasma enhanced chemical vapor deposition method CV 22: forming a micro-electromechanical converter on the flexible substrate to improve the flexibility Foldable microphone. / 、 '柔Provide one of the features of the present invention. Η η Μ ^ β color search consistent embodiment of the present invention provides a conductive layer deposited on the film layer on the #: the film layer has been clever: by the end electrode sound Shen borrows one of the lower end electrode layers, and deposits a conductive material into an A 1 ± layer by depositing on the lower active layer. One of the first 4f upper end electrode layers is electrically connected to the end electrode layer, and is electrically connected to the lower layer. One of the second connection pads, the gaskets, and the upper electrode is better, the conversion can be φ 6 about 10 nitride nitride oxide or oxidation work, and the coating thickness on the substrate is smaller than the better, The base protective layer. The imine or metal film is formed by a rain molecular (polymer) material such as polyfluorene :: have it; a flexible material substrate, the film deposited on the base '= = convex portion Layer, Borrow: Page 10 200425768

更佳地,該基板係利用P E C V D以沉積氮化石夕至厚产 於約5/zm而形成之。 旱度 更佳地,該下端電極層及該上端電極層係由包括 (如鋁)及厚度約介於〇. 〇1 #„1至5 //m間之導電性匕产人屬 中所選擇出之材料所形成。 | 〇物 更佳地’該活性層係由沉積一由包含PVDp、 PVDF-TrEF、TrEF、聚脲、聚醯亞胺及耐綸之群組中所琴 出之壓電聚合物而形成,其厚度約介於! = 其長度約介於50 //m至looo 間,如此可具有 至100 kHz之共振頻率。 ;2More preferably, the substrate is formed using P E C V D to deposit nitride to a thickness of about 5 / zm. More preferably, the lower electrode layer and the upper electrode layer are selected from the group consisting of (for example, aluminum) and a conductive layer having a thickness of about 0.01 # „1 to 5 // m 〇 物 为其 好的。 The active layer is formed by depositing a piezoelectric element formed by a group including PVDp, PVDF-TrEF, TrEF, polyurea, polyimide, and nylon. Polymer, its thickness is about! = Its length is about 50 // m to looo, so it can have a resonance frequency of up to 100 kHz.; 2

更佳地,該轉換器可更包括由沉積氮化矽或氧化石夕 厚度約介於1 //111至10 所形成之一上端保護層,以 該上端及下端電極層及該活性層。 更佳 包含金屬 為提 撓性轉換 層;以電 形成一膜 層,接著 及一上端 圖案化; 接至該上 層。該方 及導電 供本發 器之方 漿加強 層,接 形成圖 電極層 形成連 端電極 法可更 第一連 性聚合 明另一 法,包 化學氣 著形成 案,在 ’並依 接至該 層之一 包含在 接墊片 物等類 特色, 含:在 相沉積 圖案; 該下端 此順序 下端電 第二連 沉積該 及該第二連 之材料所形 本發明之一 一撓性基板 法(PECVD ) 在該膜層上 電極層上依 將該上端電 極層之一第 接墊片;以 犧牲層前, 接墊片係由選自 成。 實施例提供製造 上形成一犧牲 在該犧牲層上 沉積一下端電極 序沉積一活性層 極層及該活性層 一連接墊片與連 及移除該犧牲 先利用PECVD沉More preferably, the converter may further include an upper protective layer formed by depositing silicon nitride or oxidized silicon with a thickness of about 1 // 111 to 10, the upper and lower electrode layers, and the active layer. More preferably, a metal is used as a flexible conversion layer; a film layer is formed electrically, followed by patterning at an upper end; and connected to the upper layer. The square and conductive paste reinforcement layer of the hair generator are connected to form a picture electrode layer to form a terminal electrode method, which can be used for the first continuous polymerization and another method, including a chemical vapor deposition case. One of the layers includes features such as a spacer, including: depositing a pattern in the phase; the lower end in this order and the lower end being electrically deposited secondly and the second continuous material forming a flexible substrate method of the present invention ( PECVD) connecting a pad to one of the upper electrode layers on the electrode layer above the film layer; before the sacrificial layer, the pad is selected from the group consisting of. The embodiment provides a method of forming a sacrificial layer on the sacrificial layer, depositing a terminal electrode on the sacrificial layer, sequentially depositing an active layer and the active layer, connecting a pad and connecting and removing the sacrificial layer.

第11頁 200425768 五、發明說明(5) 積氮化♦或氧切以形成—下端保護層。 ^佳地,為形成該犧牲層,吾人 基板上且厚度達小於的Λ s η Λ 攸孟师於d 置而以、、t蝕刿$护紅、·々 #m,並根據該膜層之所欲配 置而以屋蝕刻或乾蝕刻將其形成圖案。 ^佳地,為形成該膜層,吾人#pecvd將氮化 於〜犧牲層並以乾蝕刻將其形成圖案。 / 、 $佳X為形成該活性層’吾人以旋轉 式,將一壓電聚合物如PVDF、PVDF_TrEF、TrEF ^、、毛方Page 11 200425768 V. Description of the invention (5) Nitriding or oxygen cutting to form a lower protective layer. ^ Preferably, in order to form the sacrificial layer, the thickness of Λ s η Λ on the substrate is less than Λ s η Λ and the thickness is less than or equal to 护 护 护 刿 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 # 护The desired configuration is patterned by house etching or dry etching. Preferably, in order to form the film layer, our #pecvd will be nitrided to a sacrificial layer and patterned by dry etching. /, $ 佳 X is to form the active layer ’We rotate a piezoelectric polymer such as PVDF, PVDF_TrEF, TrEF ^, and Mao Fang

:醯亞胺及耐綸等類沉積於該下端電極 T ίο ,並以澄蝕刻或乾蝕刻將其形成圖案。運J於力 上端;ΐ:電:層方層以覆蓋該 層係利用PECVD以將氮化石夕或氧化/沉帛至厚度 10…並利用溼蝕刻或乾蝕刻將該沉積層形成圖案而形 成之。 更佳地、’該第-連接墊片係以溼蝕刻或乾蝕刻將在該 上鈿保護層連接至該下端電極層之部份形成圖案;盆上 沉積一金屬層或一導電性聚合物層;以及利用溼蝕^ 触刻將該沉積層形成圖案;更佳地,該第二連接塾片係以 溼蝕刻或乾蝕刻將在該上端保護層連接至該上端電極層之 部份形成圖案;在其上沉積一金屬層或一導電性聚合物 層;以及利用溼蝕刻或乾蝕刻將該沉積層形成圖案。 為提供本發明又另一特色,本發明之一實施j列提供一 挽性無線微機電麥克風’包含··一撓性聚合物材料基板;: Ethyleneimine and nylon are deposited on the lower electrode T ίο, and they are patterned by clear etching or dry etching. Yun J at the upper end of the force; ΐ: electricity: layer by layer to cover the layer is formed by using PECVD to nitride or oxidize / sink the nitride to a thickness of 10 ... and use wet or dry etching to pattern the deposited layer . More preferably, 'the first-connection pad is formed by patterning a portion where the upper protective layer is connected to the lower electrode layer by wet etching or dry etching; a metal layer or a conductive polymer layer is deposited on the pot And forming a pattern on the deposited layer by wet etching ^ contacting; more preferably, the second connection tab is patterned by wet etching or dry etching to connect the upper protective layer to the upper electrode layer; A metal layer or a conductive polymer layer is deposited thereon; and the deposited layer is patterned using wet or dry etching. In order to provide yet another feature of the present invention, one implementation of the present invention provides a pull-wireless wireless micro-electro-mechanical microphone 'including a flexible polymer material substrate;

200425768 五 發明說明(6) 以電漿加強化學氣相沉積法(pECVD )形成於該基板上之 一挽性微機電轉換器結構;印刷於該基板上用以與外界溝 I之天線,埋入於該基板且與該撓性微機電轉換器及該 =線電性連接之一電線與界面電路;與該基板電性連接^ $供該微機電轉換器動力之一撓性電池層;以及與該電池 層電性連接之一撓性藍牙模組。 更佳地,該基板係由一高分子(聚合物)材料如聚醯 料+ & ^佳地,該電池層為一聚合物電池如薄紙般厚之撓 =能電池;更佳地,該撓性微機電轉換器包括一膜 乃八2丨:端電極層、一壓電聚合物活性層、-上端電極層 、隶I i Μ接至該下端電極層及該上端電極層之第一與第二 ^ ^ ,其依序以電漿加強化學氣相沉積法(PEC VD ) /儿、,並將其上形成一犧牲層之該基板圖案化。 換器更ΐ:上在”性基板上形成該撓性微機電轉 板可/ 一 π — ^ 、、友、且埋入泫電線與界面電路,故該基 預定角度。疋度下進行折疊,如小於約1 80度範圍之一 為提供本發明再另—鮮$ 撓性微機電無線麥克風,.本;明之-實施例提供- 聚加強化學氣相沉積;二.)一::基板,其具有以電 轉換器結構;印刷於Α 形成之一撓性微機電 接並與外界源及埋入;:轉換器結構電性連 使該撓性微機電轉換号及 線與界面電路溝通,俾 與該撓性基板電性連接:形成電通路之-天線; 運接之一撓性電池層;以及依序沉積至 第13頁 200425768 五、發明說明(7) 一預定厚度之一 更佳地,該 範圍之一預定角 結構之邊形切割 一預定角度下折 再將該折疊切塊 為供本發 提供一製造撓性 成一犧牲層;以 序將一膜層、_ 依序將該上端電 案,沉積一上端 層及該活性層; 極層及該上端電 層圖案化,以形 片及與該上端電 層圖案化以暴露 該方法可更 PECVD < —方法 ί 之一材料沉積至 護層。 更佳地,該 膜層藉沉積一氮 方式沉積一壓電 藍牙模組層。 撓性微機電無線麥克風可在小於約1 8 〇度 度下進行折疊;最好吾人依照一所欲三維 該撓性微機電無線麥克風,並將該切塊在 疊,以將其形成至該所欲三維結構,接著 組合成該三維結構。 明一更進一步之特色,本發明之一實施例 轉換器之方法’包括:在一撓性基板上形 電漿加強化學氣相沉積(PECVD )程序依 下端電極層、一活性層及一上端電極層; 極層、該活性層及該下端電極層形成圖 保護層以覆蓋遠上端電極層、該下端電極 將該上端保護層形成圖案以連接該下端電 極層;沉積一連接墊片層並將該連接墊片 成與δ亥下知電極層相連接之^^第一連接塾 極層相連接之一第二連接墊片;及將該膜 該犧牲層並接著移除該犧牲層。 包含在沉積該犧牲層之前,以選擇自 Θ將選擇自包括氮化矽與氧化石夕等類其中 該撓性基板上並濺鍍之,以形成一下端保 犧牲層之厚度小於約1 〇 # m ;更佳地,該 化矽而形成之;更佳地,吾人藉旋轉塗佈 聚合物於该下端電極層上,以形成厚度小200425768 Fifth invention description (6) An inductive micro-electro-mechanical converter structure formed on the substrate by plasma enhanced chemical vapor deposition (pECVD); an antenna printed on the substrate for external trench I and buried A flexible battery layer on the substrate and electrically connected to the flexible microelectromechanical converter and the = line; electrically connected to the substrate; a flexible battery layer for powering the microelectromechanical converter; and A flexible Bluetooth module is electrically connected to the battery layer. More preferably, the substrate is made of a high molecular (polymer) material such as poly + +, preferably, the battery layer is a polymer battery such as thin paper, which is thick and flexible = capable battery; more preferably, the The flexible micro-electro-mechanical converter includes a membrane electrode 8: a terminal electrode layer, a piezoelectric polymer active layer, an upper electrode layer, and a first electrode connected to the lower electrode layer and the upper electrode layer. The second step is to use a plasma enhanced chemical vapor deposition (PEC VD) method in sequence, and pattern the substrate on which a sacrificial layer is formed. The converter is more flexible: the flexible micro-electromechanical transfer board can be formed on a flexible substrate, which can be embedded in a wire and interface circuit, so the base is folded at a predetermined angle. If one of the ranges less than about 180 degrees is to provide the present invention, another is a flexible micro-electromechanical wireless microphone. This; Mingzhi-provided by the embodiment-poly-enhanced chemical vapor deposition; two.) One: substrate, which It has an electrical converter structure; one of the flexible micro-electromechanical devices printed on A is connected to the external source and embedded; the electrical structure of the converter makes the flexible micro-electromechanical conversion number and line communicate with the interface circuit. The flexible substrate is electrically connected: an antenna forming an electrical path; a flexible battery layer connected to the flexible substrate; and sequentially deposited on page 13 200425768 V. Description of the invention (7) One of a predetermined thickness is better, the One of the ranges of a predetermined angle structure is cut at a predetermined angle and then folded down and then folded into pieces to provide a manufacturing flexibility for the hair into a sacrificial layer; a film layer, _ sequentially the upper end of the order, Depositing an upper layer and the active layer; an electrode layer and the upper layer Patterning, patterning, and patterning with the upper electrical layer to expose the method can deposit one of the PECVD < -method materials to the protective layer. More preferably, the film layer deposits a piezoelectric by depositing a nitrogen method. Bluetooth module layer. The flexible MEMS wireless microphone can be folded at less than about 180 degrees; it is best for me to three-dimensionally flex the flexible MEMS wireless microphone and stack the cut pieces to It is formed to the desired three-dimensional structure, and then combined to form the three-dimensional structure. A further feature, a method of the converter according to an embodiment of the present invention, includes: forming a plasma on a flexible substrate to enhance chemical vapor deposition The (PECVD) procedure is based on a lower electrode layer, an active layer, and an upper electrode layer; the electrode layer, the active layer, and the lower electrode layer form a pattern protective layer to cover the far upper electrode layer, and the lower electrode forms a pattern on the upper protective layer. To connect the lower electrode layer; depositing a connection pad layer and forming the connection pad into a second connection pad connected to the first connection electrode layer connected to the lower electrode layer; and The film sacrifices the layer and then removes the sacrificial layer. Contains before the sacrificial layer is deposited, it is selected from Θ to be selected from the flexible substrate including silicon nitride and oxidized silicon, and is sputtered to The lower end protection sacrificial layer is formed with a thickness of less than about 10 m; more preferably, the silicon is formed; more preferably, I spin-coat a polymer on the lower end electrode layer to form a small thickness

200425768 五、發明說明(8) 於約10 /zm之該活性層,其中該壓電聚合物可為pVDF、 PVDF-TrEF、TrEF、聚脲、聚醯亞胺或耐綸;更佳地,吾 人形成之該上端保護層之厚度小於約1 〇 # m。 四、【實施方式】 於20 02年9月26日提出申請且標題為「撓性微機電無 線轉換器及其製造方法與撓性微機電無線麥克風」之韓國 專利申請案號2 0 0 2 - 5 8 3 1 3,茲將其全部納入以為參考。 本發明今將參照附圖更完整說明於後,其中將顯示本 發明之較佳實施例。然而,本發明可以各種不同形式實 行’吾人並不應限於以此處所列之實施例解釋之。當然, 吾人提供此些實施例係冀本發明可更臻透徹完整,並可將 本發明領域充分地傳達於熟稔於此技術者;須了解吾人指 一層「在」另一層或另一基板上,即意謂其可直接在其^ 層或其他基板上’或者可存在插入層,而各處之數字係 表與其同類之元件。 圖3係根據本發明一實施例之 隔膜型轉換器之橫截 面圖;圖4係根據本發明一實施例之一懸臂樑型轉換器之 橫截面圖。如圖3及4所示,係根據本發明一實施例之°一 換器包含一撓性基板1 00,其上利用電漿加強化學 積法(PECVD )或濺鍍法沉積氮化矽或氧化發,以形 : 下端保護層110 ’以及包含由PECVD且在低溫下所开彡 一 膜層220、一下端電極層230、一活性層24g (若為二壓一 聚合物更佳)、一上端電極層250及連接塾片μ i'及2 7 2。200425768 V. Description of the invention (8) The active layer is about 10 / zm, wherein the piezoelectric polymer may be pVDF, PVDF-TrEF, TrEF, polyurea, polyimide, or nylon; more preferably, we The thickness of the upper protective layer is less than about 10 m. 4. [Implementation] Korean Patent Application No. 2 0 02-filed on September 26, 2002 and titled "Flexible MEMS Wireless Converter and Manufacturing Method and Flexible MEMS Wireless Microphone" 5 8 3 1 3, all of which are hereby incorporated by reference. The invention will now be described more fully hereinafter with reference to the accompanying drawings, in which preferred embodiments of the invention will be shown. However, the present invention may be embodied in various forms, and should not be construed as being limited to the embodiments set forth herein. Of course, I provide these examples in order that the present invention can be more thorough and complete, and can fully convey the field of the present invention to those skilled in this technology; we must understand that I mean one layer "on" another layer or another substrate, That means it can be directly on its ^ layer or other substrates' or there can be an intervening layer, and the numbers everywhere are the same as its components. Fig. 3 is a cross-sectional view of a diaphragm-type converter according to an embodiment of the present invention; Fig. 4 is a cross-sectional view of a cantilever-type converter according to an embodiment of the present invention. As shown in Figs. 3 and 4, a converter according to an embodiment of the present invention includes a flexible substrate 100 on which silicon nitride or oxide is deposited using plasma enhanced chemical deposition (PECVD) or sputtering. Hair, shape: lower end protective layer 110 'and a film layer 220, lower end electrode layer 230, an active layer 24g (preferably a second pressure polymer), an upper end, which is opened by PECVD at a low temperature. The electrode layer 250 and the connecting tabs μ i ′ and 2 7 2.

200425768 五、發明說明(9) ㈣膜型或懸臂樑型轉換器案例中,一犧牲層係形成於該 基板100上,該膜層再形成於其上,接著利用 該犧牲層’以形成該膜層220之突起部分在 隔膜型或懸臂樑型轉換器案例中,移除在該膜層下方之^ J牲層係由透過-敞邊移除該犧牲層而完成,在隔膜型轉 換盎之案例中,吾人係利用蝕刻及注通 於該膜層上形成預定之通孔。 m齊H亥通孔而 之程Π至據本發明製造該懸臂樑型轉換器 t粒序之一貫施例中之階段。諸- ::懸臂樑型,製造懸臂樑型轉換器之示範程d:: 圖5A至5E說明之。 斤7將多…、 美柄二'51所* ’該撓性轉換器之該製造程序由在-撓性 土板1 0 0上塗佈一下端保護層 ^ ^ ^ ^1 00 ^ 合物)材料,如聚醯亞胺$ 1M 匕3回刀子(聚 電子系統如麥克;侧 用PECVD或濺鍍法塗佈氮戈4。二亥下鈿保護層110係利 該下端伴1 ^彳η伸虱化矽或虱化矽而形成,更佳地, 鍍程Γ 2 t之厚度小於約1〇_。利用該PECVD或賤 程序丨該;*可f在約40〇 °c或更低之低溫程序下完成該 層間之:著端Si!1 二之功用在於保護該基板100並促進 *圖⑽所進行沉積。 100上,吾人、〜籍一#塗佈该下端保護層110之該撓性基板 長度凸起部分儿之、一胺思牲層21 〇,其將用於形成具有一預定 膜層’該犧牲層2 1 0係藉塗佈一厚度小200425768 V. Description of the invention (9) In the case of a film type or cantilever type converter, a sacrificial layer is formed on the substrate 100, the film layer is formed thereon, and then the sacrificial layer is used to form the film In the case of a diaphragm or cantilever type converter, the protrusion of the layer 220 is removed under the film layer. The J layer is completed by removing the sacrificial layer through the open edge. In the case of a diaphragm type conversion, In our case, we use etching and injection to form a predetermined through hole in the film layer. The process from m to H through holes is to a stage in the embodiment of manufacturing the cantilever type converter according to the present invention. Zhuo :: Cantilever beam type, the demonstration process of manufacturing cantilever beam type converter d :: Figures 5A to 5E illustrate it. Jin 7 will be more ..., beautiful handle II '51 * * The manufacturing process of the flexible converter consists of coating a protective layer on the flexible soil plate 100 (^ ^ ^ ^ 1 00 ^ compound) Materials, such as polyimide $ 1M 3 daggers (Polyelectronic systems such as Mike; side coated with nitrogen gas by PECVD or sputtering method. The protective layer 110 of the lower layer of the helium is designed to benefit the lower end with 1 ^ 彳 η extension It is formed by lice silicon or lice silicon, and more preferably, the thickness of the plating process Γ 2 t is less than about 10 °. Using the PECVD or low-level procedure 丨 this; * may be at a low temperature of about 40 ° C or lower The completion of this layer under the program: the function of the terminal Si! 1 is to protect the substrate 100 and promote the deposition of * Figure 上. On the 100, I, ~ Ji Yi # coated the flexible substrate of the lower protective layer 110 The length of the raised portion is a amine layer 21 0, which will be used to form a layer with a predetermined film. The sacrificial layer 2 1 0 is coated with a small thickness.

第16頁 200425768 五、發明說明(ίο)Page 16 200425768 V. Description of the Invention (ίο)

於約1 0 // m之聚醯亞胺而形成,接著即根據該膜層之一所 欲配置將該聚醯亞胺圖案化,隨後一膜層2 2 〇即沉積於該 圖案化之犧牲層210上,該膜層220係利用PECVD在低溫程 序下塗佈氮化矽而形成,更佳地,該膜層2 2 〇之厚度小於 約5 /zm ;其次,一下端電極層23〇係沉積於該膜層22〇上, 该下端電極2 3 0係利用沉積一金屬如鋁或導電性聚合物並 以渔餘刻或乾姓刻將該沉積層圖案化而形成;接著吾人將 一活性層2 4 0塗佈於該下端電極層2 3 〇及該膜層2 2 〇上,該 活性層240係以旋轉塗佈或蒸發方式,塗佈一壓電聚合物 如PVDF、PVDF-TrEF、TrEF、聚脲、聚醯亞胺及耐綸等類 而形成,更佳地,該活性層24〇之厚度約介於i 間且其長度介於5 〇 # m至1 〇 〇 〇 # m間,更佳地,該活性層 240之共振頻率約介於! fjz至1〇〇 kHz間。 、、如圖5C所示,隨即將一上端電極層250沉積於該壓電 =性層240上,該上端電極層25〇係利用沉積一金屬如鋁或 導電性聚合物並以溼蝕刻或乾蝕刻將該沉積層圖案化而形 ^更佳地,母一该下端電極層230及該上端電極層25〇之 ίΐ約均介於〇· 〇1 至5 V"1間,此時吾人亦將該壓電聚It is formed at about 10 // m of polyimide, and then the polyimide is patterned according to the desired configuration of one of the film layers, and then a film layer 2 2 0 is deposited on the patterned sacrifice. On the layer 210, the film layer 220 is formed by coating silicon nitride under a low temperature procedure using PECVD. More preferably, the thickness of the film layer 2 2 0 is less than about 5 / zm; secondly, the lower end electrode layer 23 0 system Deposited on the film layer 22, the lower end electrode 230 is formed by depositing a metal such as aluminum or a conductive polymer and patterning the deposited layer with a fisherman's mark or a dry name; then I will A layer 2 40 is coated on the lower electrode layer 2 3 0 and the film layer 2 2 0. The active layer 240 is spin-coated or evaporated to coat a piezoelectric polymer such as PVDF, PVDF-TrEF, TrEF, polyurea, polyimide, nylon and the like. More preferably, the thickness of the active layer 24o is between about i and its length is between 50 # m and 100mm. More preferably, the resonance frequency of the active layer 240 is between about! fjz to 100 kHz. As shown in FIG. 5C, an upper electrode layer 250 is then deposited on the piezoelectric layer 240. The upper electrode layer 250 is formed by depositing a metal such as aluminum or a conductive polymer and wet etching or drying The etching patterned the deposited layer to form a shape. More preferably, the mother electrode, the lower electrode layer 230 and the upper electrode layer 25 are approximately between 0 · 〇1 to 5 V ", at this time I will also The piezoelectric polymer

否物層利用溼蝕刻或乾蝕刻圖案化,以形成該活 2 4 0。 曰 ,次’如圖5D所示,一上端保護層,係由沉積i化 ίϋ匕矽至厚度約介於1 "m至10…以覆蓋該上端與 電極層230與250及該活性層240而形成之,如此該壓 電聚合物活性層240在以蝕刻移除該犧牲層21〇期間方可受The material layer is patterned using wet etching or dry etching to form the active 2 4 0. That is, as shown in FIG. 5D, an upper protective layer is formed by depositing silicon nitride to a thickness of about 1 " m to 10 ... to cover the upper end and the electrode layers 230 and 250 and the active layer 240. It is formed such that the piezoelectric polymer active layer 240 can only be subjected to during the removal of the sacrificial layer 21 by etching.

第17頁 200425768 五、發明說明(11) 到保護;於形成該上端保護層260後 m以期分別與該上端電極層25。及該下端成電連極接= 相連,該連接墊片271、272传利用將=盾⑽電力 八s,丨、φ s # Z以係利用將邊上端保護層260在 ;化ί / :上端電極層250及該下端電極層230之部分圖 再;ΐ圖其=佈一金屬如銘或導電性聚合物而形成, 如圖5Ε所示,以乾银刻移除該犧牲層21〇,即 兀成形成该撓性懸臂樑型微機電轉換器。 棘換,ΐ 6ί為說明根據本發明另一實施例之-懸臂樑型 轉換裔之製造程序階段之截面圖。 如圖6Α所示,-下端保護層11〇係利用電聚加強化學 ,目=法(ΡΕ叫或㈣法以於一撓性基板1〇〇上沉積 氮化矽或氧化矽而形成;其次,如圖6Β所示,一犧牲層 係安藉沉積厚度小於約1〇"m之聚醯亞胺後並將該聚醯亞 胺圖案化而形成。 如圖6C所示,在形成該犧牲層21〇後,一膜層22〇、一 pH電極層23〇、一活性層240及一上端電極層250依序以 山·冗積於該犧牲層210上;其次,如圖6D所示,將該上 鈿電極層250及該活性層240圖案化;再如圖6E所示,將該 下端電極層230圖案化。 山隨後如圖6F所示,沉積一上端保護層26〇以覆蓋該上 端電極層250、該下端電極層230及該活性層24();於沉積 該上端保護層260後,如圖6G所示,將該上端保護層26〇圖 案化以與該下端電極層230及該上端電極層25〇電力相連;Page 17 200425768 V. Description of the invention (11) to protection; after the upper end protective layer 260 is formed, it is expected to be separated from the upper end electrode layer 25, respectively. And the lower end is electrically connected = connected, the connection pads 271, 272 pass through the shield = shield power eight s, 丨, φ s # Z to use the upper side of the protective layer 260; A part of the electrode layer 250 and the lower electrode layer 230 is reproduced; ie, it is formed by arranging a metal such as an indium or a conductive polymer, as shown in FIG. 5E, removing the sacrificial layer 21 with dry silver, that is, Wucheng forms the flexible cantilever type MEMS converter. The changeover is a cross-sectional view illustrating a manufacturing process stage of a cantilever beam type conversion system according to another embodiment of the present invention. As shown in FIG. 6A, the lower protective layer 11 is formed by using electropolymerization to strengthen the chemistry, and the method is to form a silicon nitride or silicon oxide by depositing it on a flexible substrate 100; secondly, As shown in FIG. 6B, a sacrificial layer is formed by depositing polyimide having a thickness of less than about 10 m and patterning the polyimide. As shown in FIG. 6C, the sacrificial layer is formed. After 20, a film layer 22, a pH electrode layer 23, an active layer 240, and an upper electrode layer 250 are sequentially stacked on the sacrificial layer 210; secondly, as shown in FIG. 6D, The upper electrode layer 250 and the active layer 240 are patterned, and then the lower electrode layer 230 is patterned as shown in FIG. 6E. Subsequently, as shown in FIG. 6F, an upper protective layer 26 is deposited to cover the upper electrode. Layer 250, the lower electrode layer 230, and the active layer 24 (); after the upper protective layer 260 is deposited, as shown in FIG. 6G, the upper protective layer 26 is patterned to correspond to the lower electrode layer 230 and the upper end The electrode layer is electrically connected at 25 °;

第18頁 200425768 五、發明說明(12) 將一金屬層或導電聚合物層沉積於兮P園本儿 谓%邊已圖案化之上總禪螬 層260上,再將其圖案化以形成盥m鈿保濩 ^ 从兴邊下端電極層2 3 0相連接 之一第一連接墊片272以及與該上她雷技^ΟΓ:Λ 土 ,、次上鈿電極層2 5 0之連接部分 相連接之一第二連接墊片271;复吹,杯闰βτ ^ 丹-人,如圖6 I 所示,將該 膜層220圖案化以暴露該犧牲層21〇, m <曰^ 1 υ,/主入蝕刻劑以移除該 犧牲層2 1 0 ’如此即完成一撓性微機電轉換器。 至於該撓性微機電轉換器之製造方法,如圖5Α至冗所 示’吾人可將該撓性微機電轉換器結構層分別沉積及圖案 $ ^或如圖6Α至6J所示,可先沉積該層後再分別將其圖案 根據上述製造方法,吾人可能利用一低溫程序(如 PECVD)而在一撓性基板1〇〇 (如聚合物)上形成一轉換器 結構20 0,故在根據本發明一實施例之該轉換器結構2〇〇 中’沉積薄層係利用PECVD或濺鍍法完成,並非利用需要 約780°C至85 0 °C高溫程序之CVD,其間此需求溫度水平差 異之原因與個別程序所使用之能源有關。特別地,該 PECVD程序以電漿作為反應所需能源,然而該傳統cvd程序 係使用熱能’故可降低該熱能且薄膜可於PECV])之一低溫 程序下形成;更特別地,吾人可能在低溫下沉積構成該轉 換器結構2 0 0之薄層,因此允許使用一撓性聚合物基板 1 ’是故根據本發明可製造出一柔軟材料之撓性麥克 風。 本發明之應用更提供一種關於根據本發明一實施例之 自由撓性麥克風,圖7係關於圖4所示該懸臂樑型轉換器之 第19頁 200425768 五、發明說明(13) ------ 一皮膚型撓性無線微機電麥克風之示意圖。如圖7所示, 利用該撓性微機電轉換器之該撓性麥克 撓性基板上形成一微機電轉換器結構2。。製手備:成,:上 ,在該基板100之一側印刷一薄膜天線3〇〇以期與外源 ϊ ί二且埋入一電線與界面電路40 0以與該薄膜天線300及 该撓性微機電轉換器200電性連接;將所產生之該基板100 及與该撓性基板100電性連接之一電池層500製成薄板,以 供給電源至該微機電轉換器200及一撓性藍牙模組層6〇(); 更佳地,該電池層500為一聚合物電池且具有紙般之厚 度’如撓性聚合物太陽能電池。 如此,將具有由一預定厚度之該電池層500及該撓性 藍牙模組層6 00所形成之該轉換器2 00之該基板1〇〇製成 板所製備而得之該撓性微機電麥克風,可作為一皮/ 性微機電麥克風,此一皮膚型撓性微機電麥克風在各方= 均為自由撓性,且其可用於耐用裝置上。 σ 此外,因5亥撓性基板1 0 0可在一預定角度下折叠, 根據本發明之該撓性無線麥克風可包裝成一三維形1狀’; 佳地,該預定角度係在小於約丨80度範圍内,圖8 丄 撓性無線麥克風範例之示意圖。如圖8所示,一撓性^/ 電轉換器結構20 0形成於一撓性基板100上,一天線=械 刷於該撓性基板100上,且有一電線與界面電路4〇〇 印、 該撓性基板100内;接著吾人即根據一麥克風包裝之一入於 4人二維形狀切割該撓性基板1 0 0,且將其於一預定角 所 折逢並組合成該所欲二維形狀,以形成一三維麥克 下 200425768 五、發明說明(14) 因其上形成5亥挽性微機電轉換器之該基板1 〇 〇具紙般 :寺5 :其可根據該麥克風所欲包裝成之三維結構切割並 折疊,再組合成該包裝之所欲三維結構。 夕坊ΐ 可將含有在該基板形成薄板狀 /曰 及该藍牙模組層600之該皮膚型麥克風進行 t割且全部折疊在一起,並組合成一三維結構,以形成一 電麥克風’或者如圖8所示’將該挽性電池 二Ο—及该i牙模組層6〇〇組合成一三維結構。吾人根據一 200人、US之一發展圖,切割其上設有該轉換器結構 ^ ' 及電線與界面電路40 0之該基板,且在一預 Γ ^«度下進行折疊,並組合該撓性電池層500及該藍牙模 ;:600之該三維結構,以形成-三維微機電麥 撓性微機電無線麥克風可於猫—么ώ成电/兄紙口系 在小於約18G度更佳 於—預定角度下折疊,若範圍能 更特別地’根據本發明—^ . 用-撓性聚合物基板’ 例,:麥克風結構因使 成薄板之該基板且合 風包農成-所欲三維結構。& —維麥克風,再將該麥克 序製ϊΐ;:述故=發明,因一轉換器結構可由低溫程 能撓性聚合物基板;如⑶,吾人可 柔軟性、撓性、可折疊性 口厌移動性 性麥克風系統;再者,有優越特性之撓 u碍具具有撓性其可折疊性,故吾 第21頁 200425768 五、發明說明(15) 人可能包裝可失 及一三維麥克風 裝結構。更進— 依照需要自由& 另外’因根 製備成各種適肖 可應用於可包裝 此一挽性微機電 本發明之較 目,但其僅以— 於此;因此,—^ 如以下申請專利 形狀及細節。 帶於身 ;因此 步地, 變其形 4康号务 之形狀 成所欲 轉換器 佳實施 般及描 般習於 範圍所 上之具所欲厚度之一 ,可自由 如此所得 狀0 設計出各種 之麥克風既 明一實施例之該撓性 ,故其可作為一皮膚 形狀之一撓性微機電 之方法上。 例已發表於此,雖應 述性觀念使用並解釋 此技術者須了解:在 陳述之領域及精神下 皮膚型麥克風 不同形狀之包 谷易攜帶又可 麥克風可自由 型麥克風,亦 轉換器及製造 用到特殊項 之,然非限制 不偏離本發明 ,可變化各種Page 18 200425768 V. Description of the invention (12) A metal layer or a conductive polymer layer is deposited on the total Zen pattern layer 260, which has been patterned on the edge, and then patterned to form a toilet. m 钿 保 濩 ^ One of the first connection pads 272 connected to the lower electrode layer 2 3 0 of Xingbian and the connection part of the upper electrode layer ^ Γ: Λ soil, and the connection part of the second upper electrode layer 2 5 0 One of the second connection pads 271; double blow, cup 闰 βτ ^ Dan-person, as shown in FIG. 6I, the film layer 220 is patterned to expose the sacrificial layer 21, m < ^ 1 υ , / Mainly enter an etchant to remove the sacrificial layer 2 1 0 ', thus completing a flexible MEMS converter. As for the manufacturing method of the flexible micro-electromechanical converter, as shown in FIG. 5A to “red,” I can deposit the structural layer of the flexible micro-electromechanical converter and pattern it separately, or as shown in FIG. 6A to 6J, it can be deposited first This layer is then patterned according to the above manufacturing method. We may use a low temperature procedure (such as PECVD) to form a converter structure 200 on a flexible substrate 100 (such as a polymer). According to an embodiment of the invention, the converter structure 2000 is used to deposit thin layers by PECVD or sputtering, instead of using CVD, which requires a high temperature procedure of about 780 ° C to 8500 ° C, and the difference in temperature levels required during this time. The reason is related to the energy used by individual processes. In particular, the PECVD procedure uses plasma as the energy required for the reaction, but the traditional cvd procedure uses thermal energy, so it can reduce the thermal energy and the film can be formed under one of the low temperature procedures of PECV]); more specifically, we may The thin layer forming the converter structure 2000 is deposited at a low temperature, thus allowing the use of a flexible polymer substrate 1 ′. Therefore, a flexible microphone can be manufactured according to the present invention. The application of the present invention further provides a free flexible microphone according to an embodiment of the present invention. FIG. 7 is about page 19, 200425768 of the cantilever type converter shown in FIG. 4. V. Description of the invention (13) ---- -A schematic diagram of a skin-type flexible wireless MEMS microphone. As shown in FIG. 7, a micro-electromechanical converter structure 2 is formed on the flexible microphone flexible substrate using the flexible micro-electro-mechanical converter. . Hand-made preparation: Cheng: On, print a thin-film antenna 300 on one side of the substrate 100 with a view to external sources and embed a wire and interface circuit 400 to communicate with the thin-film antenna 300 and the flexibility The MEMS converter 200 is electrically connected; the produced substrate 100 and a battery layer 500 electrically connected to the flexible substrate 100 are made into a thin plate to supply power to the MEMS converter 200 and a flexible Bluetooth Module layer 60 (); more preferably, the battery layer 500 is a polymer battery and has a paper-like thickness, such as a flexible polymer solar cell. In this way, the flexible micro-electromechanical device prepared by preparing the substrate 100 having the converter 2000 formed by the battery layer 500 and the flexible Bluetooth module layer 600 with a predetermined thickness is made into a board. The microphone can be used as a skin / micro-electro-mechanical microphone. This skin-type flexible micro-electro-mechanical microphone is freely flexible on all sides, and it can be used on durable devices. σ In addition, since the flexible substrate 100 can be folded at a predetermined angle, the flexible wireless microphone according to the present invention can be packaged into a three-dimensional shape 1; Preferably, the predetermined angle is less than about 80 Within the range, Figure 8 is a schematic diagram of an example of a flexible wireless microphone. As shown in FIG. 8, a flexible electrical converter structure 200 is formed on a flexible substrate 100, an antenna = a mechanical brush on the flexible substrate 100, and a wire and an interface circuit 400 stamp, Inside the flexible substrate 100; then I cut the flexible substrate 100 in a two-dimensional shape according to one of a microphone package and cut it at a predetermined angle and combined it into the desired two-dimensional shape. Shape to form a three-dimensional microphone. 200425768 V. Description of the invention (14) Because the substrate on which the 5 helical micro-electromechanical converter is formed is like a paper: Temple 5: It can be packaged according to the microphone The three-dimensional structure is cut and folded, and then assembled into the desired three-dimensional structure of the package. Xifangΐ The skin-type microphone containing a thin plate formed on the substrate / the Bluetooth module layer 600 can be t-cut and all folded together, and combined into a three-dimensional structure to form an electric microphone 'or as shown in the figure As shown in FIG. 8, the three-dimensional structure is combined with the battery 20- and the module module layer 600. I cut the substrate with the converter structure ^ 'and the wire and interface circuit 40 0 on it according to a development chart of a 200 person, one of the US, and folded it at a predetermined Γ ^ «degree, and combined the flexure Battery layer 500 and the Bluetooth module: 600 of the three-dimensional structure to form-three-dimensional micro-electro-mechanical flexible micro-electro-mechanical wireless microphone can be used in cats-Modal Electric / Brother paper mouth is better than less than about 18G degrees —Folding at a predetermined angle, if the range can be more particularly 'according to the present invention— ^. Use-flexible polymer substrate', for example, the microphone structure is made of a thin plate of the substrate and the wind is formed into a desired three-dimensional structure. . & —dimensional microphone, and then make the microphone sequence:;: narrative = invention, because a converter structure can be flexible polymer substrate with low temperature range; such as ⑶, we can be flexible, flexible, foldable mouth Annoying mobile microphone system; furthermore, the flexure that has superior characteristics prevents it from being flexible and foldable, so I p. 21 200425768 V. Description of the invention (15) People may lose packaging and a three-dimensional microphone mounting structure . Going forward — as required freely & In addition, 'individual root preparations can be used to package various kinds of micro-electromechanical devices of the present invention, but it is only here — therefore; Shape and detail. Bring it in your body; therefore, change its shape to one of the desired thicknesses of the best implementation and description of the converter. You can freely design the various shapes The microphone has the flexibility of an embodiment, so it can be used as a flexible micro-electromechanical method for skin shape. The example has been published here. Although the descriptive concept should be used and explained, those skilled in the art must understand: in the stated field and spirit, the skin-shaped microphones of different shapes are easy to carry, and the microphones can be free microphones. To the special items, but without limitation, it does not deviate from the present invention, and various changes can be made.

第22頁 圖式簡單說明 五、【圖式簡單說明』 本發明之上述及其餘 細說明較佳實施例而較^ =及優勢將因參照其附圖並詳 懂,其中: 自用技術中之一般技術更顯而易 =::I I傳統微機電轉換器之橫截面圖。 Μ ^傳統撓性微機電轉換器之橫截面圖。 面圖:…發明一實施例之一隔膜型轉換器之横截 圖4係根據本發明一實施例之一懸臂樑型轉換 截面圖。 〜子只 圖5Α至5Ε為說明圖4中所示之該懸臂樑型轉換器之 造程序階段之橫截面圖。 圖6Α至6 J為說明根據本發明另一實施例之一懸臂樑型 轉換器之製造程序階段之截面圖。 圖7係關於圖4所示該懸臂樑型轉換器之一皮膚型撓性 無線微機電麥克風之示意圖。 圖8係關於圖4所示該懸臂樑型轉換器之一三維無線麥 克風包裝之示意圖。Brief description of the drawings on page 22. [Simplified illustration of the drawings] The above and other detailed descriptions of the present invention are compared with the preferred embodiments, and the advantages will be referred to the drawings and understood in detail, of which: General in self-use technology Technology is more obvious and easy = :: II Cross-sectional view of traditional MEMS converter. M ^ cross-sectional view of a conventional flexible micro-electro-mechanical converter. Figure 4: Cross section of a diaphragm type converter according to an embodiment of the invention Figure 4 is a sectional view of a cantilever type converter according to an embodiment of the invention. 5A to 5E are cross-sectional views illustrating the manufacturing process stages of the cantilever type converter shown in FIG. 4. 6A to 6J are cross-sectional views illustrating the manufacturing process stages of a cantilever beam type converter according to another embodiment of the present invention. FIG. 7 is a schematic diagram of a skin-type flexible wireless MEMS microphone as one of the cantilever-type converters shown in FIG. 4. FIG. 8 is a schematic diagram of a three-dimensional wireless microphone package of the cantilever type converter shown in FIG. 4.

元#符號說明: 100 基板 110 下端保護層 20 0 轉換器結構 210 犧牲層Element # symbol description: 100 substrate 110 lower protective layer 20 0 converter structure 210 sacrificial layer

第23頁 200425768 圖式簡單說明 220 膜層 230 下端電極層 2 4 0 活性層 250 上端電極層 260 上端保護層 271 連接墊片 272 連接墊片 300 天線 400 電線與界面電路 50 0 電池層 6 0 0 藍牙模組層Page 23 200425768 Brief description of the diagram 220 Film layer 230 Lower electrode layer 2 4 0 Active layer 250 Upper electrode layer 260 Upper protective layer 271 Connection gasket 272 Connection gasket 300 Antenna 400 Wire and interface circuit 50 0 Battery layer 6 0 0 Bluetooth module layer

第24頁Page 24

Claims (1)

zuuh-aj /υο zuuh-aj /υο 六 包含: 且該膜層具一預定長度 導電性材料而 壓電聚合物而 一導電性材料 性連接;以及 性連接。 機電轉換器, 機電轉換器, 成。 機電轉換器, 機電轉換器, 一金屬薄膜所 機電轉換器, 機電轉換器, 申請專利範圍 種撓性微機電轅拖 :撓性材料基板轉換’ —膜層,其沉積 之凸起部分; Θ基板上 下端電極層,盆 形成; ,、由在該膜層上沉積一 形成;活性層,其由在該下端電極上沉積- 而形成·#電極層’其由在該活性層上沉積 —第一連接墊片,其與該下端電極層電 第一連接塾片,其與該上端電極層電 2 _·如申凊專利範圍第1項所述之撓性微 更包含塗佈於該基板上之一下端保護層。 3 ·如申請專利範圍第2項所述之撓性微 其中該下端保護層係由氮化矽或氧化矽所形 4 ·如申請專利範圍第2項所述之撓性微 其中該下端保護層之厚度小於約1 0 # m。 5 ·如申請專利範圍第1項所述之撓性微 其中該基板係由一高分子(聚合物)材料或 形成。 6 ·如申請專利範圍第5項所述之撓性微 其中該高分子(聚合物)材料為聚醢亞胺。 7.如申請專利範圍第1項所述之撓性微 第25頁 200425768 六、申請專利範圍 其中該膜層係由氮化矽所形成。 8 ·如申請專利範圍第1項所述之撓性微機電轉換器, 其中該膜層之厚度小於約5 //m。 9 ·如申請專利範圍第2項所述之撓性微機電轉換器, 其中4下端電極層及該上端電極層係由包含金屬與導電性 聚合物之群組中所選出之材料所形成。 器 器 間 器 間 1〇·如申請專利範圍第9項所述之撓性微機電轉換 其中該金屬為鋁。 11. 如申請專利範圍第1項所述之撓性微機電轉換 其中該下端電極層之厚度約介於0.01 Am至5/zm之 12. 如申請專利範圍第1項所述之撓性微機電轉換 其中遠上端電極層之厚度約介於0.01 //m至5 /zm之 13·如申請專利範圍第1項所述之撓性微機電轉換 器’其中該壓電聚合物係由包含pvDF、pvDF-TrEF、 TrEF、聚脉、聚醯亞胺及耐綸之群組中所選出。 器 14·如申睛專利範圍第1項所述之撓性微機電轉換 其中該活性層之厚度約介於1 /z m至1 0 // m之間。 器 間 15·如申請專利範圍第1項所述之撓性微機電轉換 其中該活性層之共振頻率約介於1 Hz至1〇〇 kHz之 器 16·如申請專利範圍第丨項所述之撓性微機電轉換 ’其中該活性層之長度約介於5 0 // m至1 0 0 〇 # m之間<zuuh-aj / υο zuuh-aj / υο six include: and the film layer has a predetermined length of conductive material and piezoelectric polymer and a conductive material are sexually connected; and sexually connected. Electromechanical converter Electromechanical converters, electromechanical converters, electromechanical converters of a metal thin film institute, electromechanical converters, patent application scope of flexible micro-electromechanical drags: flexible material substrate conversion '— film layer, its deposited convex portion; Θ substrate The upper and lower end electrode layers are formed by pots; and are formed by depositing on the film layer; an active layer is formed by depositing on the lower electrode-and an electrode layer is formed by depositing on the active layer-first The connection pad is electrically connected to the lower electrode layer, and the first connection tab is electrically connected to the upper electrode layer. The flexibility as described in item 1 of the patent application range further includes coating on the substrate. Lower protective layer. 3 · The flexible micro device as described in item 2 of the scope of the patent application, wherein the lower protective layer is formed by silicon nitride or silicon oxide 4 · The flexible micro device as described in item 2 of the scope of the patent application, wherein the lower protective layer The thickness is less than about 1 0 # m. 5 · The flexibility as described in item 1 of the patent application range wherein the substrate is made of a polymer (polymer) material or. 6 · The flexibility as described in item 5 of the patent application range wherein the polymer (polymer) material is polyimide. 7. Flexibility as described in item 1 of the scope of patent application Page 25 200425768 6. Scope of patent application Wherein the film layer is formed of silicon nitride. 8. The flexible micro-electro-mechanical converter according to item 1 of the scope of patent application, wherein the thickness of the film layer is less than about 5 // m. 9. The flexible micro-electro-mechanical converter according to item 2 of the scope of the patent application, wherein the lower electrode layer and the upper electrode layer are formed of a material selected from the group consisting of a metal and a conductive polymer. Device device Device device 10. The flexible micro-electro-mechanical conversion as described in item 9 of the scope of patent application, wherein the metal is aluminum. 11. The flexible micro-electro-mechanical conversion as described in item 1 of the patent application range, wherein the thickness of the lower electrode layer is between about 0.01 Am and 5 / zm. 12. The flexible micro-electro-mechanical device as described in item 1 of the patent application range The thickness of the far upper electrode layer is about 0.01 // m to 5 / zm. 13 The flexible micro-electromechanical converter described in the first item of the patent application scope, wherein the piezoelectric polymer is composed of pvDF, Selected from the group pvDF-TrEF, TrEF, Polypulse, Polyimide, and Nylon. Device 14. The flexible micro-electromechanical conversion as described in item 1 of the Shen-Jin patent range, wherein the thickness of the active layer is between about 1 / z m and 1 0 // m. Device 15 · A flexible micro-electromechanical converter as described in item 1 of the scope of the patent application, a device in which the resonance frequency of the active layer is between about 1 Hz and 100 kHz 16. · As described in the item of scope of the patent application Flexible Micro-Electro-Mechanical Conversion 'wherein the length of the active layer is between about 5 0 // m to 1 0 0 〇 # m < 第26頁 200425768 六、申請專利範圍 17.如申 器 更包含一 該活性層。 18·如申 器,其中該上 19.如申 器,其中該上 20·如申 器,其中該第 與導電性聚合 21. 一種 在一撓性 請專利範圍第1項所述之撓性微機電轉換 上端保護層,以覆蓋該上端及下端電極層與 請專利範 端保護層 請專利範 端保護層 請專利範 一連接墊 物之群組 撓性微機 基板上形 加強化學 利用電漿 化,以於該犧牲層上沉 於該膜層 案化; 依序將一 上,並依序將 形成一連 至該上端電極 移除該犧 2 2· 如申 之製造方法, 於沉積該 上沉積一 活性層及 該上端電 接至該下 層之第二 牲層。 睛專利範 更包含: 犧牲層前 圍第1 7項所述之撓性微機電轉換 係由氮化矽或氧化矽所形成。 圍第1項所述之撓性微機電轉換 之厚度約介於1 //m至10 //m之間。 圍第1項所述之撓性微機電轉換 片及δ亥第一^連接塾片係由包含金屬 中所選出之材料所形成。 電轉換器之製造方法,包括: 成一犧牲層; 氣相沉積法(PECVD )再將其圖案 積一膜層; 下端電極層,並將該下端電極層圖 一上端電極層沉積於該下端電極層 極層及該活性層圖案化; ^電極層 連接墊片及-連接 連接塾片;以及 圍第2 1項所述之媸/W: 之授〖生试機電轉換器 m ’禾J 用 PECVD 沉積氮化矽或氧化 200425768 六、申請專利範圍 石夕,以形成一下端保護層。 2 3·如申請專利範圍第2 1項所述之撓性微機電轉換器 之製造方法,其中形成該犧牲層係根據該膜層之一所欲配 置’於該基板上塗佈一聚醯亞胺層,並以溼錄刻或乾餘刻 將所塗佈之該聚醯亞胺層圖案化而達成。 24·如申請專利範圍第2 1項所述之撓性微機電轉換器 之製造方法,其中所形成之該犧牲層厚度小於約1 〇 # m。 2 5.如申請專利範圍第2 1項所述之撓性微機電轉換器 之製造方法,其中形成該膜層包含: 利用電漿加強化學氣相沉積法(PECVD )於該犧牲層 上沉積一氮化石夕層;以及 以乾蝕刻將所沉積之該氮化矽層圖案化。 26·如申請專利範圍第21項所述之撓性微機電轉換器 之製造方法,其中形成該活性層包含: 利用旋轉塗佈或蒸發法於該下端電極層上沉積一壓電 聚合物層;以及 以溼蝕刻或乾蝕刻將所沉積之該壓電聚合物層圖案 化。 " 27·如申請專利範圍第26項所述之撓性微機電轉換器 之製造方法,其中該壓電聚合物係由包含PVDF、 、° PVDF-TrEF、TrEF、聚脲、聚醯亞胺及耐綸之群組中所 出。 、 、 28·如申請專利範圍第21項所述之撓性微機電 之製造方法,其中所形成之該活性層之厚度小於約丨〇 #益Page 26 200425768 VI. Scope of Patent Application 17. The device further includes an active layer. 18. The application device, where the above 19. The application device, where the above 20. The application device, where the first and the conductive polymer 21. A kind of flexibility as described in item 1 of the patent application scope The upper protective layer of electromechanical conversion covers the upper and lower electrode layers and the patented end protective layer. So that the sacrificial layer is deposited on the film layer; sequentially, one is formed in sequence, and an electrode connected to the upper end is formed in order to remove the sacrificial 2 2 · Rushen manufacturing method, an activity is deposited on the deposited layer The layer and the upper end are electrically connected to the second animal layer of the lower layer. The patent scope also includes: The flexible micro-electromechanical conversion described in item 17 of the front of the sacrificial layer is made of silicon nitride or silicon oxide. The thickness of the flexible micro-electromechanical conversion described in item 1 is about 1 // m to 10 // m. The flexible micro-electro-mechanical conversion sheet and the delta-first connection tab described in item 1 are formed of a material selected from the group consisting of metals. A method for manufacturing an electrical converter includes: forming a sacrificial layer; vapor deposition (PECVD) and patterning a film layer thereon; a lower electrode layer, and depositing the lower electrode layer and an upper electrode layer on the lower electrode layer The electrode layer and the active layer are patterned; ^ electrode layer connection pads and-connection connection tabs; and 媸 / W described in item 21: the test electromechanical converter m 'he J deposited by PECVD Silicon nitride or oxidation 200425768 Sixth, the scope of patent application Shi Xi, to form a lower end protective layer. 2 3. The method for manufacturing a flexible micro-electro-mechanical converter as described in item 21 of the scope of patent application, wherein the formation of the sacrificial layer is based on a desired configuration of one of the film layers, and a polyurethane is coated on the substrate. The amine layer is obtained by patterning the coated polyimide layer with wet recording or dry etching. 24. The method for manufacturing a flexible micro-electro-mechanical converter according to item 21 of the scope of patent application, wherein the thickness of the sacrificial layer formed is less than about 10 m. 2 5. The method for manufacturing a flexible micro-electro-mechanical converter as described in item 21 of the scope of patent application, wherein forming the film layer comprises: using plasma enhanced chemical vapor deposition (PECVD) to deposit a layer on the sacrificial layer A nitride nitride layer; and patterning the deposited silicon nitride layer by dry etching. 26. The method for manufacturing a flexible micro-electro-mechanical converter according to item 21 of the scope of application, wherein forming the active layer comprises: depositing a piezoelectric polymer layer on the lower electrode layer by spin coating or evaporation; And the deposited piezoelectric polymer layer is patterned by wet etching or dry etching. " 27. The method for manufacturing a flexible micro-electro-mechanical converter as described in item 26 of the scope of patent application, wherein the piezoelectric polymer is composed of PVDF, PVDF-TrEF, TrEF, polyurea, polyimide And nylon. 28. The method for manufacturing a flexible micro-electromechanical device as described in item 21 of the scope of patent application, wherein the thickness of the active layer formed is less than about 丨 〇 # 益 200425768 六、申請專利範圍 m 〇 2 9·如申請專利範圍第2 1項所述之撓性微機電轉換器 之製造方法,更包含: 形成一上端保護層,以覆蓋該上端及下端電極層與該 活性層;其中該上端保護層係利用PECVI)沉積氮化石夕或氧 化石夕,接著再以溼蝕刻或乾蝕刻將該沉積層圖案化而形 成。 3〇·如申請專利範圍第29項所述之撓性微機電轉換器 之製造方法,其中所形成之該上端保護層之厚度小於約1 〇 β m 。 31·如申請專利範圍第2 1項所述之撓性微機電轉換器 之製造方法,其中形成該第一連接墊片包括: 以渔蝕刻或乾蝕刻將該上端保護層在其連接至該下端 保護層之部分圖案化; 在其上沉積一金屬層或一導電性聚合物層;以及 以溼蝕刻或乾蝕刻將該沉積層圖案化。 3 2·如申請專利範圍第21項所述之撓性微機電轉換器 之製造方法,其中形成該第二連接墊片包括: 以溼蝕刻或乾蝕刻將該上端保護層在其連接至該上端 保護層之部分圖案化; 在其上沉積一金屬層或一導電性聚合物層,·以及 以溼蝕刻或乾蝕刻將該沉積層圖案化。 33. 一種撓性無線微機電麥克風,包含: 一撓性聚合物材料基板;200425768 6. Scope of patent application m 〇 2 9 · The manufacturing method of the flexible micro-electromechanical converter as described in item 21 of the scope of patent application, further comprising: forming an upper end protection layer to cover the upper and lower electrode layers and The active layer; wherein the upper protective layer is formed by depositing nitrided stone oxide or oxidized stone with PECVI), and then patterning the deposited layer by wet etching or dry etching. 30. The method for manufacturing a flexible micro-electro-mechanical converter according to item 29 of the scope of patent application, wherein the thickness of the upper protective layer formed is less than about 10 β m. 31. The method for manufacturing a flexible micro-electro-mechanical converter according to item 21 of the scope of patent application, wherein forming the first connection pad includes: connecting the upper end protective layer to the lower end by means of fish etching or dry etching. A portion of the protective layer is patterned; a metal layer or a conductive polymer layer is deposited thereon; and the deposited layer is patterned by wet etching or dry etching. 3 2 · The method for manufacturing a flexible micro-electro-mechanical converter according to item 21 of the scope of patent application, wherein forming the second connection pad includes: connecting the upper protective layer to the upper end by wet etching or dry etching. Part of the protective layer is patterned; a metal layer or a conductive polymer layer is deposited thereon; and the deposited layer is patterned by wet etching or dry etching. 33. A flexible wireless micro-electro-mechanical microphone, comprising: a flexible polymer material substrate; 第29頁 200425768Page 29 200425768 一撓性微機電轉換器結構,其係利用電漿加 $ 相沉積法(PECVD )而形成於該基板上; 子亂 一天線,其印刷於該基板上,係用於與一 一電線與界面電路,其埋入於該基板内, 機電轉換器及該天線電性連接; 外源溝通; 可與撓性微 一撓性電池層,其與該基板電性連接 源之該微機電轉換器;以及 ’係用於供應電 克風 克風 一撓性藍牙模組層,其與該電池層電性連接。 34.如申請專利範圍第33項所述之撓性無線微機電麥 ’其中該基板係由一高分子(聚合物)材料所形成。 35·如申請專利範圍第34項所述之撓性無線微機電麥 ’其中該南分子(聚合物)材料為聚酿亞胺。A flexible micro-electromechanical converter structure is formed on the substrate by using plasma plus phase deposition (PECVD); a random antenna is printed on the substrate and is used to interface with a wire A circuit embedded in the substrate, the electromechanical converter and the antenna are electrically connected; external source communication; the micro-electromechanical converter that can be connected to a flexible micro-flexible battery layer and electrically connected to the substrate; And 'is used to supply a flexible Bluetooth module layer of electric wind and wind, which is electrically connected to the battery layer. 34. The flexible wireless micro-electro-mechanical microphone according to item 33 of the scope of the patent application, wherein the substrate is formed of a polymer (polymer) material. 35. The flexible wireless micro-electro-mechanical device according to item 34 of the scope of the patent application, wherein the southern molecular (polymer) material is polyimide. 36·如申請專利範圍第33項所述之撓性無線微機電麥 見風,其中該電池層為一具紙般厚度之聚合物電池。 37·如申請專利範圍第33項所述之撓性無線微機電麥 風’其中該電池層為一撓性太陽能電池。 3 8.如申請專利範圍第3 3項所述之撓性無線微機電麥 風’其中撓性微機電轉換器包含: 山—膜層、一下端電極層、一壓電聚合物活性層、一上 $ $極層、及分別連接至該下端電極層與該上端電極層之 二連接墊片與第二連接墊片,其係利用電漿加強化學氣 /儿積法(PECVD )依序沉積並在形成一犧牲層之該基板 上進行圖案化而得。 39·如申請專利範圍第33項所述之撓性無線微機電麥36. The flexible wireless micro-electro-mechanical device described in item 33 of the scope of patent application, wherein the battery layer is a paper-like polymer battery. 37. The flexible wireless micro-electro-mechanical microphone according to item 33 of the scope of the patent application, wherein the battery layer is a flexible solar cell. 3 8. The flexible wireless micro-electro-mechanical microphone as described in item 33 of the scope of the patent application, wherein the flexible micro-electro-mechanical converter includes: a mountain-film layer, a lower electrode layer, a piezoelectric polymer active layer, a The upper electrode layer and the two connection pads and the second connection pad connected to the lower electrode layer and the upper electrode layer, respectively, are sequentially deposited by using a plasma enhanced chemical gas / child deposition method (PECVD) and It is obtained by performing patterning on the substrate forming a sacrificial layer. 39. Flexible wireless microelectromechanical device as described in item 33 of the scope of patent application 第30頁 200425768 六、申請專利範圍 克風,其中該撓性基板可在一預定角度下進行折疊,且該 基板上形成該微機電轉換器、印刷有該天線、且埋入該電 線與界面電路。 ^ 40·如申請專利範圍第33項所述之撓性無線微機電麥 克風’其中該預定角度之範圍小於約1 8 0度。 41· 一種撓性無線微機電麥克風,包含: 一撓性基板,其具有利用電漿加強化學氣相沉積法 (PECVD )所形成之一撓性微機電轉換器結構·,一印刷於 該基板上之天線,其與該微機電轉換器結構電性連接,且 用於與一外源溝通;一埋於該基板下之電線與界面電路, 其可與撓性微機電轉換器及該天線電性連接; 一撓性電池層,其與該撓性基板電性連接;以及 一撓性藍牙模組層,其依序沉積至一預定厚度。 42.如申請專利範圍第41項所述之撓性無線微機電麥 克風,其中撓性無線微機電麥克風可在一預定角度下進行 45· —種撓性微機電轉換器之製造方法 在一撓性基板上形成一犧牲層; 43·如申請專利範圍第41 克風’其中該預定角度之範圍 44·如申請專利範圍第41 克風,其中撓性無線微機電麥 之邊形切割,並將該切塊在一 該折疊切塊組合成該三維結構 項所述之撓性無線微機電麥 小於約1 8 0度。 項所述之撓性無線微機電麥 克風係依照一所欲三維結構 預定角度下折疊,接著再將 而形成。 包括:Page 30 200425768 6. The scope of patent application is Kefeng, where the flexible substrate can be folded at a predetermined angle, and the micro-electro-mechanical converter is formed on the substrate, the antenna is printed, and the wires and interface circuits are embedded. . ^ 40. The flexible wireless micro-electro-mechanical microphone according to item 33 of the scope of patent application, wherein the range of the predetermined angle is less than about 180 degrees. 41 · A flexible wireless micro-electro-mechanical microphone comprising: a flexible substrate having a flexible micro-electro-mechanical converter structure formed by a plasma enhanced chemical vapor deposition method (PECVD), and printed on the substrate An antenna that is electrically connected to the MEMS converter structure and is used to communicate with an external source; a wire and interface circuit buried under the substrate can be electrically connected to the flexible MEMS converter and the antenna Connection; a flexible battery layer electrically connected to the flexible substrate; and a flexible Bluetooth module layer sequentially deposited to a predetermined thickness. 42. The flexible wireless micro-electro-mechanical microphone according to item 41 of the scope of patent application, wherein the flexible wireless micro-electro-mechanical microphone can be performed at a predetermined angle of 45 · —a method for manufacturing a flexible micro-electro-mechanical converter in a flexible A sacrificial layer is formed on the substrate; 43. If the scope of the patent application is 41 grams, the range of the predetermined angle is 44. If the scope of the patent application is 41 grams, the edge of the flexible wireless micro-electromechanical wheat is cut, and The dicing is combined with the folded dicing to form the flexible wireless micro-electro-mechanical microphone described in the three-dimensional structure item, which is less than about 180 degrees. The flexible wireless micro-electro-mechanical microphone according to the item is folded at a predetermined angle according to a desired three-dimensional structure, and then formed. include: 200425768 六、申請專利範圍 利用電漿加強化學氣相沉積法(PECVI))將一膜層、 一下端電極層、一活性層及一上端電極層依序沉積於該犧 牲層上; 依序將該上端電極層、該活性層、及該下端電極層圖 案化; 沉積一上端保護層,以覆蓋該上端電極層、該下端電 極層與該活性層; 將與該下端電極層及該上端電極層連接之該上端保護 層圖案化,沉積一連接墊片層並將該連接墊片層圖案化, 以形成一連接至該下端電極層之第一連接墊片及一連接至 φ 該上端電極層之第二連接塾片;以及 將該膜層圖案化以暴露該犧牲層並移除該犧牲層。 46·如申請專利範圍第45項所述之撓性微機電轉換器 之製造方法,更包含: °° 於沉積該犧牲層前,以選自pECVD及濺鍍之一方法, 在該撓性基板上沉積自包括氮化矽及氧化矽之群組中所選 出之其中之一材料,以形成一下端保護層。 4 7·如申請專利範圍第4 5項所述之撓性微機電轉換器 之製造方法,其中該犧牲層之厚度小於約丨〇 # m。 、° 48·如申請專利範圍第45項所述之撓性微機電轉換器 · 之製造方法,其中該膜層係由沉積氮化矽而形成。 斋 ,49·如申請專利範圍第45項所述之撓性微機電轉換器 之製造方法,其中該活性層係利用旋轉塗佈或蒸發法於, 下知電極層上沉積一壓電聚合物層而形成。 ;200425768 VI. Application scope: Plasma enhanced chemical vapor deposition (PECVI) method is used to sequentially deposit a film layer, a lower electrode layer, an active layer and an upper electrode layer on the sacrificial layer; The upper electrode layer, the active layer, and the lower electrode layer are patterned; an upper protective layer is deposited to cover the upper electrode layer, the lower electrode layer and the active layer; and will be connected to the lower electrode layer and the upper electrode layer Pattern the upper protective layer, deposit a connection pad layer and pattern the connection pad layer to form a first connection pad connected to the lower electrode layer and a first connection pad connected to φ the upper electrode layer Two connecting cymbals; and patterning the film layer to expose the sacrificial layer and remove the sacrificial layer. 46. The method for manufacturing a flexible micro-electro-mechanical converter according to item 45 of the scope of patent application, further comprising: °° Before the sacrificial layer is deposited, a method selected from pECVD and sputtering is applied to the flexible substrate. A material selected from the group consisting of silicon nitride and silicon oxide is deposited thereon to form a lower protective layer. 47. The method for manufacturing a flexible micro-electro-mechanical converter as described in item 45 of the scope of the patent application, wherein the thickness of the sacrificial layer is less than about 0 #m. ° 48. The manufacturing method of the flexible micro-electromechanical converter according to item 45 of the scope of the patent application, wherein the film layer is formed by depositing silicon nitride. Zhai, 49. The method for manufacturing a flexible micro-electro-mechanical converter as described in item 45 of the scope of patent application, wherein the active layer is a spin-on coating or evaporation method, and a piezoelectric polymer layer is deposited on the electrode layer. And formed. ; 200425768 六、申請專利範圍 50.如申請專利範圍第49項所述之撓性微機電轉換器 之製造方法,其中該壓電聚合物係由包含PVDF、 PVDF-TrEF、TrEF、聚脲、聚醯亞胺及耐綸之群組中所選 出。 51·如申請專利範圍第4 5項所述之撓性微機電轉換器 之製造方法,其中該活性層之厚度小於約1 〇 A m。 52·如申請專利範圍第45項所述之撓性微機電轉換器 之製造方法,其中該上端保護層之厚度小於約1 0 // m。200425768 6. Application for patent scope 50. The method for manufacturing a flexible micro-electromechanical converter as described in item 49 of the scope of patent application, wherein the piezoelectric polymer is composed of PVDF, PVDF-TrEF, TrEF, polyurea, polyfluorene Selected from the group of imine and nylon. 51. The method for manufacturing a flexible micro-electro-mechanical converter according to item 45 of the scope of patent application, wherein the thickness of the active layer is less than about 10 A m. 52. The method for manufacturing a flexible micro-electro-mechanical converter according to item 45 of the scope of patent application, wherein the thickness of the upper protective layer is less than about 10 // m. 第33頁Page 33
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